Geology ReportsSearch

SEARCH · Geology Reports

Results for “Journal of Hydrology X”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 recordsLinked to original sources

Probability of streamflow permanence model (PROSPER): A spatially continuous model of annual streamflow permanence throughout the Pacific Northwest

The U.S. Geological Survey (USGS) has developed the PRObability of Streamflow PERmanence (PROSPER) model, a GIS raster-based empirical model that provides streamflow permanence probabilities (probabilistic predictions) of a stream channel having year-round flow for any unregulated and minimally-impaired stream channel in the Pacific Northwest region, U.S. The model provides annual predictions for 2004-2016 at a 30-m spatial resolution based on monthly or annually updated values of climatic conditions and static physiographic variables associated with the upstream basin. Predictions correspond to any pixel on the channel network consistent with the medium resolution National Hydrography Dataset channel network stream grid. Total annual precipitation and percent forest cover were consistently the most important predictor variables among global and most subregional models, which had error rates between 17 and 22%. Probabilities were converted to wet and dry streamflow permanence classes with an associated confidence. Wet and dry classifications were used to derive descriptors that characterize the statistical and spatial distribution of streamflow permanence in three focal basins. Predicted dry channel segments account for 52 to 92% of the stream network across the three focal basins; streamflow permanence decreased during climatically drier years. Predictions are publicly available through the USGS StreamStats platform. Results demonstrate the utility of the PROSPER model as a tool for identifying areas that may be resilient or sensitive to drought conditions, allowing for management efforts that target protecting critical reaches. Importantly, PROSPER’s successful predictive performance can be improved with new datasets of streamflow permanence underscoring the importance of field observations.

Idaho, Montana, Nevada, Oregon, Utah, Washington

Timescales of water-quality change in a karst aquifer, south-central Texas

Understanding the drivers and timescales over which groundwater quality changes informs groundwater management, use, and protection. To better understand timescales of water-quality change over short (daily to monthly) and long (seasonal to decadal) timescales, the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Enhanced Trends Network (ETN) program instrumented and sampled three wells in the Edwards aquifer in south-central Texas. The wells were instrumented to provide high-frequency continuous (subhourly) water-quality data (temperature, pH, specific conductance, and dissolved oxygen), which were augmented by the collection of discrete samples (about 6 per year) for a range of geochemical constituents (including selected isotopes and age tracers). ETN data (2013–2017) are considered with data from additional sites for the same time period, and also historical records (over more than 80 years) of climatic and hydrologic conditions. During the four-year study, hydrologic conditions transitioned from very dry to very wet. Sites in the updip/unconfined part of the aquifer showed notable changes in water level and geochemistry (1) in response to rainfall/recharge events, and (2) over the multiyear dry/wet cycle. Sites in the downdip/confined part of the aquifer showed changes in water level/spring discharge over similar timescales, although the response is more muted. Geochemistry at the downdip/confined sites, however, varied slowly and minimally, indicating that the geochemical response of the deeper aquifer is decoupled from recent hydrologic responses. Changes at the updip/unconfined sites reflect mixing with recent recharge, whereas the downdip/confined sites were dominated by mineral-solution reactions resulting from longer (decadal) residence times. Mean groundwater ages interpreted from measured age tracers and lumped parameter models range from 7 to >700 years (where mixed with premodern downdip water) but were mostly modern. The aquifer is characterized by updip-to-downdip trends in geochemistry with respect to water-rock interaction and groundwater age. Fourier spectral analysis of historical records indicate hydrologic variability has occurred at dominant periods of 30 and 15 years; in conjunction with age tracers, these results provide insight into timescales at which the aquifer’s public supply is vulnerable to changes in the water quality of recharge.

Texas

Effects of John Martin Reservoir on water quality and quantity: Assessment by chemical, isotopic, and mass-balance methods

Water quality and quantity can be influenced by transit through and storage in reservoirs. Assessing such effects can be challenging, however, because of mixing and residence times, and inter-annual net storage and release from both the reservoir itself and surrounding porosity. Here, different methodologies were used to assess the effect of John Martin Reservoir (JMR), located on the Arkansas River, on water volumes and the problematic constituents salinity (total dissolved solids, TDS), selenium (Se), and uranium (U). Methodologies addressed short-term (16 months) and long-term (31 years) effects depending upon data availability. Evaporation was assessed by using isotopes of water to determine 12% short-term evaporation, and by pan evaporation and changes in storage to determine 11% long-term evaporation. Salinity, Se, and U mass balance were assessed by using chloride (Cl−) as an index by which to measure short-term gains or losses between inflows and outflows in the short term. Chloride gain from ungaged inflows skewed those results to overestimate retention. Continuous monitoring of discharge and specific conductance for inflows and outflows, along with discrete sampling for dissolved constituents were used to compute long-term, load-based mass balance. Mild gains of TDS (34,000 ± 15,000 Mg/yr) and U (0.1 ± 0.5 Mg/yr) in JMR were detected. Although the additions are small relative to uncertainty, they indicate little to no retention of TDS and U and likely additions from ungaged inflows. In contrast, an average of 0.6 ± 0.2 Mg/yr or 23% of gaged inflow Se was removed in JMR. The study illustrates the benefit of long-term records for assessing the influence of reservoirs for which net storage and release keep them from approaching steady-state conditions.

Colorado

Changing climate drives future streamflow declines and challenges in meeting water demand across the southwestern United States

Society and the environment in the arid southwestern United States depend on reliable water availability, yet current water use outpaces supply. Water demand is projected to grow in the future and climate change is expected to reduce supply. To adapt, water managers need robust estimates of future regional water supply to support management decisions. To address this need, we estimate future streamflow in seven water resource regions in the southwestern U.S. using a new SPAtially Referenced Regressions On Watershed attributes (SPARROW) streamflow model. We present streamflow projections corresponding to input data from seven climate models and two greenhouse gas Representative Concentration Pathways (RCP4.5 and 8.5) for three, thirty-year intervals centered on the 2030s, 2050s, and 2080s, and for a historical thirty year interval centered on the 1990s. Across water resource regions, about half of the RCP4.5 models (51%) and two thirds of the RCP8.5 models (67%) indicate decreases in streamflow in the 2080s relative to the historical period. Models project maximum decreases in streamflow of 36–80% in all water resource regions for all periods and RCPs relative to historical streamflow, and maximum streamflow decreases of up to 20–45% in the 2080s at sites along the Colorado River used for measuring compliance with interstate and international water agreements. Headwaters are projected to experience the greatest declines, with substantial downstream implications. Among these estimates, the streamflows from models forced with RCP8.5 tend to be lower than those forced with RCP4.5. Not all climate models, times, and RCPs project widespread streamflow declines. The most ubiquitous streamflow increases are projected to occur in the 2030s under RCP4.5. Later time periods and enhanced greenhouse gas forcings indicate smaller regions of streamflow increase and lower accumulated streamflows, suggesting that limiting or reducing greenhouse gas concentrations could support future water availability. Although some possible streamflow increases are promising, the modest and spatially limited increases in streamflow projected for later time periods are still unlikely to be sufficient to meet the projected water demand. These results inform the likelihood of future water agreement compliance, and support developing strategies to balance water supply and demand.

Arizona, California, Colorado Idaho, Nevada, New M

Simulation experiments comparing nonstationary design-flood adjustments based on observed annual peak flows in the conterminous United States

While nonstationary flood frequency analysis (NSFFA) methods have proliferated, few studies have rigorously compared them for modeling changes in both the central tendency and variability of annual peak-flow series, also known as the annual maximum series (AMS), in hydrologically diverse areas. Through Monte Carlo experiments, we appraise five methods for updating estimates of 10- and 100-year floods at gauged sites using synthetic records based on sample moments and change trajectories of observed AMS in the conterminous United States (CONUS). We compare two methods that consider changes in both central tendency and variability - a Gamma generalized linear model estimated with weighted least squares and the Generalized Additive Model for Location, Scale, Shape (GAMLSS) - with a distribution-free approach (quantile regression), and baseline cases assuming stationarity or only changes in central tendency. ‘Trend-space’ plots identify realistic AMS changes for which modeling trends in both central tendency and variability were warranted based on fractional root mean squared errors (fRMSE). They also reveal statistical properties of AMS under which NSFFA models perform especially well or poorly. For instance, quantile regression performed especially well (poorly) under strong negative (positive) skewness. Although the nonstationary LP3 distribution accommodates most AMS with trends well, the sensitivity of NSFFA model performance to different sample moments and trends suggests the need for more flexibility in prescribing design-flood adjustments in the CONUS. A follow-up comparison of regional NSFFA models pooling at-site AMS would further illuminate NSFFA guidance, especially for AMS with properties less conducive to NSFFA modeling, such as positive skewness and increasing variability.

Journal of Hydrology X

Predictions and drivers of sub-reach-scale annual streamflow permanence for the upper Missouri River basin: 1989-2018

The presence of year-round surface water in streams (i.e., streamflow permanence) is an important factor for identifying aquatic habitat availability, determining the regulatory status of streams, managing land use change, allocating water resources, and designing scientific studies. However, accurate, high resolution, and dynamic prediction of streamflow permanence that accounts for year-to-year variability at a regional extent is a major gap in modeling capability. Herein, we expand and adapt the U.S. Geological Survey (USGS) PRObability of Streamflow PERmanence (PROSPER) model from its original implementation in the Pacific Northwest (PROSPER PNW ) to the upper Missouri River basin (PROSPER UM ), a geographical region that includes mountain and prairie ecosystems of the northern United States. PROSPER UM is an empirical model used to estimate the probability that a stream channel has year-round flow in response to climatic conditions (monthly and annual) and static physiographic predictor variables of the upstream basin. The structure and approach of PROSPER UM are generally consistent with the PROSPER PNW model but include improved spatial resolution (10 m) and a longer modeling period. Average model accuracy was 81 %. Drainage area, upstream proportion as wetlands, and upstream proportion as developed land cover were the most important predictor variables. The PROSPER UM model identifies decreases in streamflow permanence during climatically drier years, although there is variability in the magnitude across basins highlighting geographically varying sensitivity to drought. Variability in the response of perennial streams to drought conditions among basins in the study area was also observed.

Montana, North Dakota, South Dakota, Wyoming

Connecting diverse disciplines to improve understanding of surface water-groundwater interactions

Laura K. Lautz is a premier mentor, collaborator, and researcher at the intersection of natural hydrologic systems and humans. Her research has shifted the paradigm around measuring and understanding the impacts of surface water and groundwater interactions across spatial and temporal scales. She has done this by testing and refining new methods and by collaborating with, training, supporting, and mentoring diverse scientists. Here, we review her research across five themes, summarizing the prior status of the field, what Lautz contributed, as well as new directions in the field inspired by her work. Lautz’s research expanded our understanding of the impacts of stream restoration on surface water-groundwater interactions, where she tested new field methods and showed that restoration structures increase hyporheic exchange, locally altering biogeochemical function of the streambed. She refined novel methods for measuring surface water-groundwater exchanges and worked to make these methods easily accessible through freely available software. Her research group greatly expanded the use of heat as a quantitative tracer of hydrologic processes via the well-used VFLUX and HFLUX programs. Her research evaluated the impacts of surface water-groundwater interactions in urban streams, showing the substantial fluxes of nutrients and chloride that can move through those exchanges and the potential for groundwater to help buffer contamination. To assess groundwater impacts on streamflow below tropical glaciers, she used a wide range of field methods to reveal the sensitivity of these systems to climate change. Finally, she built tools to quantify natural brine contamination of drinking water wells in areas that may later be subject to high-volume hydraulic fracturing, creating a needed ‘pre-fracking’ dataset. Through this process, she identified multiple sources of salinity that are already reaching wells in these systems. Overall, this research has been done with a focus on mentoring and training the next generation of hydrologists, including work to specifically train for careers beyond academia, and facilitating early career scientists to realize their innate potentials. With former trainees in careers across industry, government, and academia, Dr. Laura K. Lautz is now working to build cross-disciplinary research at even larger scales, across federal research units, guaranteeing that an even larger impact on hydrology is still to come.

Journal of Hydrology X

Use of Doppler velocity radars to monitor and predict debris and flood wave velocities and travel times in post-wildfire basins

The magnitude and timing of extreme events such as debris and floodflows (collectively referred to as floodflows) in post-wildfire basins are difficult to measure and are even more difficult to predict. To address this challenge, a sensor ensemble consisting of noncontact, ground-based (near-field), Doppler velocity (velocity) and pulsed (stage or gage height) radars, rain gages, and a redundant radio communication network was leveraged to monitor flood wave velocities, to validate travel times, and to compliment observations from NEXRAD weather radar. The sensor ensemble (DEbris and Floodflow Early warNing System, DEFENS) was deployed in Waldo Canyon, Pike National Forest, Colorado, USA, which was burned entirely (100 percent burned) by the Waldo Canyon fire during the summer of 2012 ( MTBS, 2020 ). Surface velocity, stage, and precipitation time series collected during the DEFENS deployment on 10 August 2015 were used to monitor and predict flood wave velocities and travel times as a function of stream discharge (discharge; streamflow). The 10 August 2015 event exhibited spatial and temporal variations in rainfall intensity and duration that resulted in a discharge equal to 5.01 cubic meters per second (m 3 /s). Discharge was estimated post-event using a slope-conveyance indirect discharge method and was verified using velocity radars and the probability concept algorithm. Mean flood wave velocities – represented by the kinematic celerity ( c k = 2.619 m e t e r s p e r s e c o n d , m / s ± 0.556 p e r c e n t "> 𝑐 𝑘 = 2.619 𝑚𝑒𝑡𝑒𝑟𝑠 𝑝𝑒𝑟 𝑠𝑒𝑐𝑜𝑛𝑑, m/s ± 0.556 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and dynamic celerity ( c d = 3.533 m / s ± 0.181 p e r c e n t a n d t h e i r u n c e r t a i n t i e s "> 𝑐 𝑑 = 3.533 m/s ± 0.181 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and their uncertainties were computed. L-moments were computed to establish probability density functions (PDFs) and associated statistics for each of the at-a-section hydraulic parameters to serve as a workflow for implementing alert networks in hydrologically similar basins that lack data. Measured flood wave velocities and travel times agreed well with predicted values. Absolute percent differences between predicted and measured flood wave velocities ranged from 1.6 percent to 49 percent and varied with water slope, hydraulic radius, and depth. The kinematic celerity was a better predictor for steep slopes and wide flood plains associated with the Upper Waldo and Middle Waldo radar streamgages; whereas, the dynamic celerity was a better surrogate for shallow slopes and incised channels such as the Lower Waldo radar streamgage. The method demonstrates the potential extensibility of a post-wildfire warning system by (1) leveraging multiple systems (i.e., weather radar, near-field velocity and stage radars, and rain gages) for accurate and timely warnings of debris and floodflows, (2) establishing an order of operations to site, install, and operate near-field radars and conventional rain gages to record floodflows, forecast travel times, and document geomorphic change in this basin and hydrologically similar basins that lack data, and (3) communicating data operationally with the Colorado Department of Transportation engineering staff, National Weather Service forecasters, and emergency managers.

Colorado

Practical application of time-lapse camera imagery to develop water-level data for three hydrologic monitoring sites in Wisconsin during water year 2020

Using camera imagery to measure water level (camera-stage) is a well-researched area of study. Previous camera-stage studies have shown promising results when implementing this technology with tight constraints on test conditions. However, there is a need for a more comprehensive evaluation of the extensibility of camera-stage to practical applications. Therefore, the aim of this study was to test a camera-stage method under a wide variety of test conditions to better understand the successes and challenges of using this technology in real-world scenarios. In this study, this approach was tested during Water Year 2020 at three existing U.S. Geological Study (USGS) stream gaging stations in south central Wisconsin that had existing USGS water-level instrumentation. The specific reference objects tested were white pipes and a concrete wall. Since successful application of camera-stage relies on use of suitable images, all captured images in this study were visually inspected to determine suitability for application of camera-stage. Camera-stage measurements were then computed only on images deemed suitable and the results were compared with ground-truth stage values to determine the accuracy. For the purposes of this study, camera-stage values within ±0.10 ft of the actual stage were considered acceptable. One major challenge highlighted was the potential difficulty in obtaining suitable imagery, with the proportion of suitable images varying greatly between the four trials from 38 % to 92 %. The results from applying camera-stage to suitable images were encouraging though, with 79 % to 99 % of evaluated camera-stage values qualifying as acceptable among the four test trials.

Wisconsin

A generalized design flood estimation framework under stationary and non-stationary scenarios

With the ever-ongoing debate over the death of stationarity in flood time series, developing methods for flood frequency analysis that can address both stationarity and non-stationarity simultaneously has become increasingly important for design flood estimation. Existing non-stationary flood frequency analysis (NFFQ) methods are either limited to providing time-varying conditional flood quantile estimates or lack closed-form expression to estimate the design flood over the planning period. We propose a novel framework, MM-NFFQ, that introduces marginal moments (MM) estimation techniques to provide a closed-form expression to estimate design flood under non-stationarity. We demonstrate MM-NFFQ using the LP3 distribution for estimating conditional moments, but in principle, it can work for any 3-parameter distribution. We first show the proposed MM-NFFQ collapses to stationary flood frequency analysis analytically using synthetic data and then demonstrate the MM-NFFQ approach for two basins exhibiting non-stationarity in their flood time series. We further extend the analysis to selected 40 basins across CONUS and find that arid basins exhibit higher deviation from stationarity. Thus, the proposed MM-NFFQ framework can estimate traditional flood frequency curves for both, stationary and non-stationary flood processes, and can also be utilized to analyze the changes in conditional moments and marginal moments over different planning horizons.

Journal of Hydrology X

Implications of fire-induced evapotranspiration shifts for recharge-runoff generation and vegetation conversion in the western United States

Wildfire has been shown to increase, decrease, or have no detectable effect on actual evapotranspiration (ETa) fluxes in the western United States. Where disturbance-induced shifts are significant, source-water hydrology may be impacted as ETa constitutes the largest outgoing water flux in much of the arid West. We conducted pixel-scale analysis of 30-m ETa data and various meteorologic and landscape variables at 13 burn scars to understand how wildfire disturbance impacted hillslope-to-burn scar-scale hydrology and vegetation conversion. Significant fire-induced ETa reductions (between approximately −15 to −50%) were detected at nine burn scars through the tenth post-fire year, while ETa recovery rate varied substantially by ecoregion and pre-fire vegetation type. Along elevation gradients, both climate and land disturbance influenced the location of runoff/recharge generation zones, and more net water was generated from a snow-dominated burn scar in dry post-fire years than in wet pre-fire years. However, especially in arid locations where ETa is water-limited, compensatory ETa pathways may be more likely to dampen fire effects on total basin water yield where intact vegetation is located between the disturbance footprint and the basin outlet. Relationships between post-fire ETa shifts and early-successional vegetation conversion were also tracked. The majority of burn scars with significant fire-induced ETa reductions experienced conversion patterns typical of the western United States following stand-replacing disturbance, with forests converting to shrub/scrub and/or grassland/herbaceous cover through at least the end of the study period (eight to 15 years depending on date of the fire event). This could have important implications for high-elevation, snow-dominated watersheds – some of the most critical source water areas - as previous research indicates that wildfire activity is moving upslope and into vegetation communities that have not evolved to withstand fire. Finally, we show that much of the Colorado River Basin’s high-yield source water areas are vulnerable to the fire-induced ETa reductions and vegetation conversion observed herein. As such, water managers in the Colorado River Basin can anticipate changes in burn scar hydrology and snowpack mechanics following fire disturbance.

Journal of Hydrology X

Linking hydraulic properties of fire-affected soils to infiltration and water repellency

Heat from wildfires can produce a two-layer system composed of extremely dry soil covered by a layer of ash, which when subjected to rainfall, may produce extreme floods. To understand the soil physics controlling runoff for these initial conditions, we used a small, portable disk infiltrometer to measure two hydraulic properties: (1) near-saturated hydraulic conductivity, K f and (2) sorptivity, S ( θ i ), as a function of initial soil moisture content, θ i , ranging from extremely dry conditions ( θ i < 0.02 cm 3 cm −3 ) to near saturation. In the field and in the laboratory replicate measurements were made of ash, reference soils, soils unaffected by fire, and fire-affected soils. Each has a different degrees of water repellency that influences K f and S ( θ i ). Values of K f ranged from 4.5 × 10 −3 to 53 × 10 −3 cm s −1 for ash; from 0.93 × 10 −3 to 130 × 10 −3 cm s −1 for reference soils; and from 0.86 × 10 −3 to 3.0 × 10 −3 cm s −1 , for soil unaffected by fire, which had the lowest values of K f . Measurements indicated that S ( θ i ) could be represented by an empirical non-linear function of θ i with a sorptivity maximum of 0.18–0.20 cm s −0.5 , between 0.03 and 0.08 cm 3 cm −3 . This functional form differs from the monotonically decreasing non-linear functions often used to represent S ( θ i ) for rainfall–runoff modeling. The sorptivity maximum may represent the combined effects of gravity, capillarity, and adsorption in a transitional domain corresponding to extremely dry soil, and moreover, it may explain the observed non-linear behavior, and the critical soil-moisture threshold of water repellent soils. Laboratory measurements of K f and S ( θ i ) are the first for ash and fire-affected soil, but additional measurements are needed of these hydraulic properties for in situ fire-affected soils. They provide insight into water repellency behavior and infiltration under extremely dry conditions. Most importantly, they indicate how existing rainfall–runoff models can be modified to accommodate a possible two-layer system in extremely dry conditions. These modified models can be used to predict floods from burned watersheds under these initial conditions.

Journal of Hydrology

Examining the influence of heterogeneous porosity fields on conservative solute transport

It is widely recognized that groundwater flow and solute transport in natural media are largely controlled by heterogeneities. In the last three decades, many studies have examined the effects of heterogeneous hydraulic conductivity fields on flow and transport processes, but there has been much less attention to the influence of heterogeneous porosity fields. In this study, we use porosity and particle size measurements from boreholes at the Boise Hydrogeophysical Research Site (BHRS) to evaluate the importance of characterizing the spatial structure of porosity and grain size data for solute transport modeling. Then we develop synthetic hydraulic conductivity fields based on relatively simple measurements of porosity from borehole logs and grain size distributions from core samples to examine and compare the characteristics of tracer transport through these fields with and without inclusion of porosity heterogeneity. In particular, we develop horizontal 2D realizations based on data from one of the less heterogeneous units at the BHRS to examine effects where spatial variations in hydraulic parameters are not large. The results indicate that the distributions of porosity and the derived hydraulic conductivity in the study unit resemble fractal normal and lognormal fields respectively. We numerically simulate solute transport in stochastic fields and find that spatial variations in porosity have significant effects on the spread of an injected tracer plume including a significant delay in simulated tracer concentration histories.

Journal of Contaminant Hydrology

Quasi-horizontal circulation cells in 3D seawater intrusion

The seawater intrusion process is characterized by the difference in freshwater and seawater density that causes freshwater to float on seawater. Many confined aquifers have a large horizontal extension with respect to thickness. In these cases, while buoyancy acts in the vertical direction, flow is confined between the upper and bottom boundaries and the effect of gravity is controlled by variations of aquifer elevation. Therefore, the effective gravity is controlled by the slope and the shape of the aquifer boundaries. Variability in the topography of the aquifer boundaries is one case where 3D analysis is necessary. In this work, density-dependent flow processes caused by 3D aquifer geometry are studied numerically and specifically, considering a lateral slope of the aquifer boundaries. Sub-horizontal circulation cells are formed in the saltwater entering the aquifer. The penetration of the saltwater can be quantified by a dimensionless buoyancy number that measures the lateral slope of the aquifer relative to freshwater flux. The penetration of the seawater intrusion wedge is controlled more by this slope than by the aquifer thickness and dispersivity. Thus, the slope must be taken into account in order to accurately evaluate seawater intrusion.

Journal of Hydrology

Spring onset variations and trends in the continental United States: past and regional assessment using temperature-based indices

Phenological data are simple yet sensitive indicators of climate change impacts on ecosystems, but observations have not been made routinely or extensively enough to evaluate spatial and temporal patterns across most continents, including North America. As an alternative, many studies use weather-based algorithms to simulate specific phenological responses. Spring Indices (SI) are a set of complex phenological models that have been successfully applied to evaluate variations and trends in the onset of spring across the Northern Hemisphere’s temperate regions. To date, SI models have been limited by only producing output in locations where both the plants’ chilling and warmth requirements are met. Here, we develop an extended form of the SI (abbreviated SI-x) that expands their application into the subtropics by ignoring chilling requirements while still retaining the utility and accuracy of the original SI (now abbreviated SI-o). The validity of the new indices is tested, and regional SI anomalies are explored across the data-rich continental United States. SI-x variations from 1900 to 2010 show an abrupt and sustained delay in spring onset of about 4–8 d (around 1958) in parts of the Southeast and southern Great Plains, and a comparable advance of 4–8 d (around 1984) in parts of the northern Great Plains and the West. Atmospheric circulation anomalies, linked to large-scale modes of variability, exert modest but significant roles in the timing of spring onset across the United States on interannual and longer timescales. The SI-x are promising metrics for tracking spring onset variations and trends in mid-latitudes, relating them to relevant ecological, hydrological, and socioeconomic phenomena, and exploring connections between atmospheric drivers and seasonal timing.

International Journal of Climatology

Visible and near-infrared (0.4-2.5 μm) reflectance spectra of playa evaporite minerals

Visible and near-infrared (VNIR; 0.4&ndash;2.4 &mu;m) reflectance spectra were recorded for 35 saline minerals that represent the wide range of mineral and brine chemical compositions found in playa evaporite settings. The spectra show that many of the saline minerals exhibit diagnostic near-infrared absorption bands, chiefly attributable to vibrations of hydrogen-bonded structural water molecules. VNIR reflectance spectra can be used to detect minor hydrate phases present in mixtures dominated by anhydrous halite or thenardite, and therefore will be useful in combination with X ray diffraction data for characterizing natural saline mineral assemblages. In addition, VNIR reflectance spectra are sensitive to differences in sample hydration state and should facilitate in situ studies of minerals that occur as fragile, transitory dehydration products in natural salt crusts. The use of spectral reflectance measurements in playa studies should aid in mapping evaporite mineral distributions and may provide insight into the geochemical and hydrological controls on playa mineral and brine development.

Journal of Geophysical Research

Topographic effects on flow path and surface water chemistry of the Llyn Brianne catchments in Wales

Topographic shape is a watershed attribute thought to influence the flow path followed by water as it traverses a catchment. Flow path, in turn, may affect the chemical composition of surface waters. Topography is quantified in the hydrological model TOPMODEL as the relative frequency distribution of the index ln(atanB), where a is the upslope area per unit contour that drains past a point and tanB is the local surface slope. Spatial distributions of ln(atanB) were calculated for eight catchments in Wales on a 25 m x 25 m grid. Among the catchments, mean observed stream H+ concentration during high flow periods was highly correlated with the mean of the ln(atanB) distribution. The steady-state gain of a transfer function (time series) model relating H+ to discharge was positively correlated with the mean of the ln(atanB) distribution. These results suggest that during high flow periods, both the average stream acidity and the magnitude of fluctuations in H+ are conditioned by the topographic shape of the catchment. By performing a sensitivity analysis on TOPMODEL, we also show that as the mean of the ln(atanB) distribution for a catchment increases, so does its theoretical likelihood to produce significant quantities of surface and near-surface runoff. Our observed results in the Llyn Brianne catchments are consistent with this theoretical expectation in that surface or near-surface runoff is often higher in acidity than are deeper sources of hillslope runoff.

Wales

Sample size and the detection of a hump-shaped relationship between biomass and species richness in Mediterranean wetlands

Questions: What is the observed relationship between biomass and species richness across both spatial and temporal scales in communities of submerged annual macrophytes? Does the number of plots sampled affect detection of hump-shaped pattern? Location: Don??ana National Park, southwestern Spain. Methods: A total of 102 plots were sampled during four hydrological cycles. In each hydrological cycle, the plots were distributed randomly along an environmental flooding gradient in three contrasted microhabitats located in the transition zone just below the upper marsh. In each plot (0.5 m x 0.5 m), plant density and above- and below-ground biomass of submerged vegetation were measured. The hump-shaped model was tested by using a generalized linear model (GLM). A bootstrap procedure was used to test the effect of the number of plots on the ability to detect hump-shaped patterns. Result: The area exhibited low species density with a range of 1 - 9 species and low values of biomass with a range of 0.2 - 87.6 g-DW / 0.25 m2. When data from all years and all microhabitats were combined, the relationships between biomass and species richness showed a hump-shaped pattern. The number of plots was large enough to allow detection of the hump-shaped pattern across microhabitats but it was too small to confirm the hump-shaped pattern within each individual microhabitat. Conclusion: This study provides evidence of hump-shaped patterns across microhabitats when GLM analysis is used. In communities of submerged annual macrophytes in Mediterranean wetlands, the highest species density occurs in intermediate values of biomass. The bootstrap procedure indicates that the number of plots affects the detection of hump-shaped patterns. ?? IAVS; Opulus Press.

Journal of Vegetation Science