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At least 433 records · Page 24Linked to original sources

Pesticides in groundwater in the Anacostia River and Rock Creek watersheds in Washington, D.C., 2005 and 2008

The U.S. Geological Survey (USGS), in cooperation with the District Department of the Environment, conducted a groundwater-quality investigation to (a) determine the presence, concentrations, and distribution of selected pesticides in groundwater, and (b) assess the presence of pesticides in groundwater in relation to selected landscape, hydrogeologic, and groundwater-quality characteristics in the shallow groundwater underlying the Anacostia River and Rock Creek watersheds in Washington, D.C. With one exception, well depths were 100 feet or less below land surface. The USGS obtained or compiled ancillary data and information on land use (2001), subsurface sediments, and groundwater samples from 17 wells in the lower Anacostia River watershed from September through December 2005, and from 14 wells in the lower Anacostia River and lower Rock Creek watersheds from August through September 2008. Twenty-seven pesticide compounds, reflecting at least 19 different types of pesticides, were detected in the groundwater samples obtained in 2005 and 2008. No fungicides were detected. In relation to the pesticides detected, degradate compounds were as or more likely to be detected than applied (parent) compounds. The detected pesticides chiefly reflected herbicides commonly used in urban settings for non-specific weed control or insecticides used for nonspecific haustellate insects (insects with specialized mouthparts for sucking liquid) or termite-specific control. Detected pesticides included a combination of pesticides currently (2008) in use, banned or under highly restricted use, and some that had replaced the banned or restricted-use pesticides. The presence of banned and restricted-use pesticides illustrates their continued persistence and resistance to complete degradation in the environment. The presence of the replacement pesticides indicates the susceptibility of the surficial aquifer to contamination irrespective of the changes in the pesticides used. A preliminary review of the data collected in 2005 and 2008 indicated that differences in the surficial geology, land use (as a surrogate for pesticide use), and above-average precipitation for most of 2004 through 2008, as well as differences in the number and performance of USGS laboratory methods used, could have led to more pesticides detected in groundwater samples collected in 2008 than in groundwater samples collected in 2005. Thus, although data from both years of collection were used for interpretive analysis, emphasis was placed on the analysis of the data obtained in 2008. The presence of pesticides in shallow groundwater (less than approximately 100 ft (feet), or 30 m (meters), below land surface) indicated at least the upper surficial aquifer in Washington, D.C. was susceptible to contamination. One or more herbicides or insecticides were detected in groundwater samples collected from 50 percent of the shallow wells sampled in 2005, and from 62 percent of the shallow wells sampled in 2008. Differences among types of pesticides in shallow groundwater were apparent. The most frequently detected class of herbicides was the s-triazine compounds—atrazine, simazine, or prometon, or the atrazine-degradate compounds—2-chloro-4-ethylamino-6-amino-s-triazine (desethylatrazine or CIAT) and 2-chloro-4-isopropylamino-6-amino-s-triazine (hydroxyatrazine or OIET). The next most frequently detected classes of herbicides were the chloroacetanilides, including metolachlor and acetochlor, and the ureic herbicides, including diuron (and degradate, 3,4-dichloroaniline), fluometuron, metsulfuron methyl, sulfameturon, bromacil, and tebuthiuron. Insecticides also were detected, but less frequently than herbicides, with one or more insecticides present in groundwater samples from 38 percent of shallow wells sampled in 2008. Detected insecticides included parent or degradate compounds commonly used for either nonspecific or haustellate (sucking) insects, including chlorpyrifos and dichlorodiphenyldichloroethane (p,p’-DDD; a degradate of dichlorodiphenyltrichloroethane, DDT), and for termite control, including dieldrin, chlordane, heptachlor epoxide, (a degradate of heptachlor), fipronil, and the sulfone and sulfide degradates of fipronil. The concentrations of individual pesticides in shallow groundwater in both years were low. Maximum concentrations were no greater than a few tenths of a microgram per liter (μg/L); typical concentrations often were less than 0.1 μg/L. Multiple pesticides, however, commonly were present in groundwater. For example, in 2008, approximately 88 percent (7 of 8) of the wells that yielded a sample with at least one detectable pesticide contained five or more pesticides. The highest number of detections occurred in a groundwater sample from well WE Ca 32, which is located in a highly developed urban area; this sample contained 15 different pesticide residues. In relation to human and aquatic health, no pesticide concentration in either 2005 or 2008 exceeded Federal drinking-water standards. Groundwater samples from a few sites, however, contained levels of chiefly banned or restricted-use pesticides that exceeded other human-health and (or) aquatic-health guidelines. For example, concentrations of dieldrin in 2008 groundwater samples from three wells—WE Ca 32 (0.028 μg/L), WE Ba 11 (0.016 μg/L), and WW Ac 8 (0.014 μg/L)—fell within the range of concern for 2004 Federally approved non-regulatory USGS Health-Based Assessment benchmarks (0.002 to 0.2 μg/L), and exceeded earlier (1999) Federal criteria for drinking water (0.000052 μg/L). Other individual compounds whose concentrations exceeded 1999 Federal guidelines for samples from one or more of these three sites, or another site, included p,p’-DDD, dichlorodiphenyldichloroethylene (p,p’-DDE; another degradate of DDT), chlordane, and heptachlor epoxide. Pesticide concentrations in groundwater also were compared to three aquatic-health guidelines for freshwater (United States, Great Lakes, or Canada). One or more of these guidelines were exceeded in groundwater samples obtained in 2005 or 2008 for one or more of the compounds chlordane, dieldrin, heptachlor epoxide, p,p’-DDE, p,p’-DDD, and chlorpyrifos. The spatial distribution of pesticides in the shallow groundwater appeared to be related, in part, to land use, a surrogate for pesticide use. Although most of the wells sampled in this study are in parklands or other relatively open and accessible space, multiple pesticides most often were detected in 2008 groundwater samples collected from wells where a considerable percentage (in excess of 60 percent) of the land within a 500-m radius is developed space (residential, commercial, or other urban infrastructure). Insecticides were detected in wells surrounded by at least 50 percent, and most commonly by more than 80 percent, development. Well WE Ca 32, the site associated with the highest number of pesticide residues in groundwater (8 herbicides and 7 insecticides), is in a small residential park, where 99 percent of the surrounding land is well-maintained residential and commercial development. The vertical distribution of detected pesticides in shallow groundwater appeared to be related, in part, to depth below land surface, surficial-bedrock type, and differences in the chemistry of shallow groundwater. Pesticides were detected at relatively shallow depths in wells that may not have fully penetrated the shallow aquifer. For wells in which at least one pesticide was detected, the median depth below land surface to the top of the well screen was 5.8 m, and the maximum depth was 8.5 m. Among the types of surficial materials in which wells were completed—alluvium, terrace deposits, or Potomac Formation sub- or outcrops in the Coastal Plain Province, and saprolite or fractured bedrock (Laurel and Sykesville Formations) underlying saprolite in the Piedmont Province—no pesticides were detected in groundwater associated with wells completed in the alluvium or fractured bedrock. Detections occurred in some but not all wells completed in the other surficial materials. Overall, the pattern in occurrence appeared related to the local permeability of these sediments and groundwater chemistry. Groundwater with multiple pesticide detections tended to occur in permeable sediments (absent any appreciable overlying clay, silt, or clay-silt layers), in conjunction with other common urban contaminants (elevated chloride in excess of tens to hundreds of milligrams per liter (mg/L), and oxic, rather than reduced, groundwater as evidenced by elevated (in excess of 5 mg/L) concentrations of nitrate). The results of this investigation were compared to results from two other similar and recent studies on pesticide occurrence in the shallow aquifer. These included a study in the nearby Maryland and Delaware Coastal Plain Physiographic Province and one in the Maryland and Virginia Piedmont Physiographic Province. Results from these studies were similar to the current study in relation to (a) the types, frequencies, concentrations, and mixtures of pesticides detected; (b) compounds that exceeded human-and aquatic-health criteria; and (c) the occurrence and distribution of pesticides within the surficial aquifer in relation to depths, sediment types, and groundwater chemistries.

Washington D.C.

Geology and ground-water resources of the Ahtanum Valley, Yakima County, Washington

The Ahtanum Valley covers an area of about 100 square miles in an important agricultural district in central Yakima County, Wash. Because the area is semiarid, virtually all crops require irrigation. Surface-water supplies are inadequate in most of the area, and ground water is being used increasingly for irrigation. The purpose of this investigation was the collection and interpretation of data, pertaining to ground water in the area as an aid in the proper development and management of the water resources. The occurrence and movement of ground water in the Ahtanum Valley are directly related to the geology. The valley occupies part of a structural trough (Ahtanum-Moxee subbasin) that is underlain by strongly folded flow layers of a thick sequence of the Yakima basalt. The upper part of the basalt sequence interfingers with, and is conformably overlying by, sedimentary rocks of the Ellensburg formation which are as much as 1,000 feet thick. These rocks are in turn overlying unconformably by cemented basalt gravel as much as 400 feet thick. Unconsolidated alluvial sand and gravel, as much as 30 feet thick, form the valley floor. Although ground water occurs in each of the rock units within the area, the Yakima basalt and the unconsolidated alluvium yield about three-fourths of the ground water currently used. Wells in the area range in depth from a few feet to more than 1,200 feet and yield from less than 1 to more than 1,030 gallons per minute. Although water levels in water-table wells usually are shallow--often less than 5 feet below the land surface--levels in deeper wells tapping confined water range from somewhat above the land surface (in flowing wells) to about 200 feet below. Wells drilled into aquifers in the Yakima basalt, the Ellensburg formation, and the cemented gravel usually tap confined water, and at least 12 wells in the area flow or have flowed in the past. Ground-water levels fluctuate principally in response to changes in stream levels, variations in the flow of irrigation ditches and in rates of water application, variations in local precipitation, and seasonal differences in withdrawals from wells. Annual fluctuations of levels generally are less than 10 feet except in localities of heavy pumping. Periodic measurements of water levels in two observation wells in the area indicate, locally at least, a persistent decline in artesian pressures in confined basalt aquifers, although the record is too short to show whether withdrawal by pumping has reached, or is nearing, an optimum balance with recharge. The aquifers are recharged by precipitation, by infiltration from streams, and by ground-water underflow into the area. Ground water is discharged by seepage to streams, by evapotranspiration, by springs and seeps at the land surface, and, artificially, by withdrawal from wells. It is estimated that the seepage discharge to the Yakima River from the area studied may range from about 20,000 to 25,000 acre-feet per year. The consumptive waste of ground water by phreatophytes probably exceeds 4,000 acre-feet per year and may represent a large reclaimable source of water in the area. The annual withdrawal of ground water from wells in the area for domestic, industrial, irrigation, public, and stock supplies is estimated to be 6,300 acre-feet. The chemical quality of the ground water generally is satisfactory for most purposes, although the water from many wells is harder than is desirable for domestic use.

Washington

Correlations of turbidity to suspended-sediment concentration in the Toutle River Basin, near Mount St. Helens, Washington, 2010-11

Researchers at the U.S. Geological Survey, Cascades Volcano Observatory, investigated alternative methods for the traditional sample-based sediment record procedure in determining suspended-sediment concentration (SSC) and discharge. One such sediment-surrogate technique was developed using turbidity and discharge to estimate SSC for two gaging stations in the Toutle River Basin near Mount St. Helens, Washington. To provide context for the study, methods for collecting sediment data and monitoring turbidity are discussed. Statistical methods used include the development of ordinary least squares regression models for each gaging station. Issues of time-related autocorrelation also are evaluated. Addition of lagged explanatory variables was used to account for autocorrelation in the turbidity, discharge, and SSC data. Final regression model equations and plots are presented for the two gaging stations. The regression models support near-real-time estimates of SSC and improved suspended-sediment discharge records by incorporating continuous instream turbidity. Future use of such models may potentially lower the costs of sediment monitoring by reducing time it takes to collect and process samples and to derive a sediment-discharge record.

Washington

Periodic floods from glacial Lake Missoula into the Sanpoil arm of glacial Lake Columbia, northeastern Washington

At least 15 floods ascended the Sanpoil arm of glacial Lake Columbia during a single glaciation. Varves between 14 of the flood beds indicate one backflooding every 35 to 55 yr. This regularity suggests that the floods came from an ice-dammed lake that was self-dumping. Probably the self-dumping lake was glacial Lake Missoula, Montana, because the floods accord with inferred emptyings of that lake in frequency and number, apparently entered Lake Columbia from the east, and produced beds resembling backflood deposits of Lake Missoula floods in southern Washington.

Geology

Report of committee on glaciers, April 1939

The Committee on Glaciers at present is constituted as follows: Harry Fielding Reid—Professor‐Emeritus of Geology, Johns Hopkins University (former member of the International Glacier Commission), 608 Cathedral Street, Baltimore, Maryland William H. Hobbs—Professor‐Emeritus of Geology, University of Michigan (until recently Vice‐ President of the International Glacier Commission, at present associate member), Ann Arbor, Michigan J. E. Church—Professor of Classics, University of Nevada (President of the International Commission of Snow, and Chairman of the Committee on Snow of the Section of Hydrology, American Geophysical Union), Reno, Nevada Colonel Lawrence Martin—Chief of the Division of Maps, Library of Congress, Washington, D. C. Wm. Osgood Field, Jr.—Explorer, 18 West Twelfth Street, New York, N.Y. Earl A. Trager—Chief of the Naturalist Division, National Park Service, Washington, D. C. Glenn L. Parker—District Engineer, Water Resources Branch, United States Geological Survey, 406 Federal Building, Tacoma, Washington Oliver Kehrlein—Chairman, Committee on Glacier Studies, Sierra Club, 1050 Mills Tower, San Francisco, California Kenneth N. Phillips—Associate Hydraulic Engineer, Water Resources Branch, United States Geological Survey, Chairman, Research Committee of the Mazamas, 606 Post‐Office Building, Portland, Oregon William S. Cooper—Professor of Botany, University of Minnesota, Minneapolis, Minnesota Gerald FitzGerald, Senior Topographic Engineer, Alaska Branch, United States Geological Survey, Washington, D.C. Laurence M. Gould, Professor of Geology, Carleton College, Northfield, Minnesota François E. Matthes, Chairman , Senior Geologist, Section of Glacial Geology, United States Geological Survey (titular member of the International Glacier Commission), Washington, D.C. In 1938, as in previous years, the Committee devoted its energies primarily to the collecting of data on the variations in length and volume of American glaciers, it being felt that the maintenance of a continuous record of these variations is of prime importance, not only to hydrology and glaciology, but, as has become increasingly evident recently, also to climatology, geomorphology, geography, ecology, history, and archaeology. As the time available for the work of the Committee is limited and does not permit covering the entire field of glaciology, it seems best to devote it before all else to this line of research which yields results of value to so many different sciences. Besides, the gathering of data on glacier‐oscillations is not a one‐man job that can be taken up or dropped at convenience from time to time, but is an organized and far‐flung enterprise whose success depends upon the faithful cooperation of many volunteer workers located in different parts of the country. Such an enterprise, once launched, must be kept running or it will disintegrate and the precious enthusiasm of the field‐workers will be lost.

Eos, Transactions, American Geophysical Union

Data compilation for assessing sediment and toxic chemical loads from the Green River to the lower Duwamish Waterway, Washington

Between February and June 2013, the U.S. Geological Survey collected representative samples of whole water, suspended sediment, and (or) bed sediment from a single strategically located site on the Duwamish River, Washington, during seven periods of different flow conditions. Samples were analyzed by Washington-State-accredited laboratories for a large suite of compounds, including polycyclic aromatic hydrocarbons and other semivolatile compounds, polychlorinated biphenyl Aroclors and the 209 congeners, metals, dioxins/furans, volatile organic compounds, pesticides, butyltins, hexavalent chromium, and total organic carbon. Chemical concentrations associated with bulk bed sediment (<2 mm) and fine bed sediment (<62.5 μm) fractions were compared to chemical concentrations associated with suspended sediment. Bulk bed sediment concentrations generally were lower than fine bed sediment and suspended-sediment concentrations. Concurrent with the chemistry sampling, additional parameters were measured, including instantaneous river discharge, suspended-sediment concentration, sediment particle-size distribution, and general water-quality parameters. From these data, estimates of instantaneous sediment and chemical loads from the Green River to the Lower Duwamish Waterway were calculated.

Washington

Geologic Setting and Hydrogeologic Units of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers approximately 44,000 square miles of northeastern Oregon, southeastern Washington, and western Idaho. The area supports a $6 billion per year agricultural industry, leading the Nation in production of apples and nine other commodities (State of Washington Office of Financial Management, 2007; U.S. Department of Agriculture, 2007). Groundwater availability in the aquifers of the area is a critical water-resource management issue because the water demand for agriculture, economic development, and ecological needs is high. The primary aquifers of the CPRAS are basalts of the Columbia River Basalt Group (CRBG) and overlying basin-fill sediments. Water-resources issues that have implications for future groundwater availability in the region include (1) widespread water-level declines associated with development of groundwater resources for irrigation and other uses, (2) reduction in base flow to rivers and associated effects on temperature and water quality, and (3) current and anticipated effects of global climate change on recharge, base flow, and ultimately, groundwater availability. As part of a National Groundwater Resources Program, the U.S. Geological Survey began a study of the CPRAS in 2007 with the broad goals of (1) characterizing the hydrologic status of the system, (2) identifying trends in groundwater storage and use, and (3) quantifying groundwater availability. The study approach includes documenting changes in the status of the system, quantifying the hydrologic budget for the system, updating the regional hydrogeologic framework, and developing a groundwater-flow simulation model for the system. The simulation model will be used to evaluate and test the conceptual model of the system and later to evaluate groundwater availability under alternative development and climate scenarios. The objectives of this study were to update the hydrogeologic framework for the CPRAS using the available geologic mapping and well information and to develop a digital, three-dimensional hydrogeologic model that could be used as the basis of a groundwater-flow model. This report describes the principal geologic and hydrogeologic units of the CPRAS and geologic map and well data that were compiled as part of the study. The report also describes simplified regional hydrogeologic sections and unit extent maps that were used to conceptualize the framework prior to development of the digital 3-dimensional framework model.

Idaho, Oregon, Washington

Petrogenesis and geological history of a uranium source rock: a case study in northeastern Washington, U.S.A.

A small (4 km 2 ) drainage basin in northeastern Washington contains highly uraniferous groundwater and highly uraniferous peaty sediments of Holocene age. The U is derived from granitic bedrock that underlies the entire drainage basin and that contains 9–16 ppm U. This local bedrock was studied by petrographic, chemical and isotopic methods to determine conditions of its petrogenesis and post-emplacement history that may have contributed to its present high U content and source-rock capability. The original magma was derived by anatexis of Precambrian continental crust of probable mixed metaigneous and metasedimentary character. Mineral-melt partitioning controlled the enrichment of U in chemically evolved phases of the crystallizing melt. Following emplacement in the upper crust at ∼100Ma, the pluton interacted with meteoric-hydrothermal water at ambient temperatures 300°C. Locally intense fracturing promoted alteration, and fracturing and alteration probably continued during later regional uplift in the Eocene. Regional uplift was followed by low-temperature alteration and weathering in the middle to late Tertiary. The combined result of hydrothermal alteration and low-temperature alteration and weathering was the redistribution of U from primary mineral hosts such as allanite to new sites on fracture surfaces and in secondary minerals such as hematite. Zones of highly fractured and altered rock show the most obvious evidence of this process. A model is proposed in which high-angle fractures beneath the drainage basin were the sites of Tertiary supergene enrichments of U. Recent glacio-isostatic uplift has elevated these older enriched zones to shallow levels where they are now being leached by oxidizing groundwater. The chemistry, mineralogy, texture and geological history of this U source-rock suggest criteria for locating other granitic terrane that may contain uraniferous waters and associated young surficial U deposits. The details of U distribution and mobility at this site also apply to the general topic of U mobility in granitic rocks.

Washington