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At least 217 records · Page 12Linked to original sources
USGS2001

Occurrence of cyanazine compounds in groundwater: Degradates more prevalent than the parent compound

A recently developed analytical method using liquid chromatography/mass spectrometry was used to investigate the occurrence of cyanazine and its degradates cyanazine acid (CAC), cyanazine amide (CAM), deethylcyanazine (DEC), and deethylcyanazine acid (DCAC) in groundwater. This research represents some of the earliest data on the occurrence of cyanazine degradates in groundwater. Although cyanazine was infrequently detected in the 64 wells across Iowa sampled in 1999, cyanazine degradates were commonly found during this study. The most frequently detected cyanazine compound was DCAC (32.8%) followed by CAC (29.7%), CAM (17.2%), DEC (3.1%), and cyanazine (3.1%). The frequency of detection for cyanazine or one or more of its degradates (CYTOT) was more than 12-fold over that of cyanazine alone (39.1% for CYTOT versus 3.1% for cyanazine). Of the total measured concentration of cyanazine, only 0.2% was derived from its parent compound - with DCAC (74.1%) and CAC (18.4%) comprising 92.5% of this total. Thus, although DCAC and CAC had similar frequencies of detection, DCAC was generally present in higher concentrations. No concentrations of cyanazine compounds for this study exceeded water-quality criteria for the protection of human health. Only cyanazine, however, has such a criteria established. Nevertheless, because these cyanazine degradates are still chlorinated, they may have similar toxicity as their parent compound - similar to what has been found with the chlorinated degradates of atrazine. Thus, the results of this study documented that data on the degradates for cyanazine are critical for understanding its fate and transport in the hydrologic system. Furthermore, the prevalence of the chlorinated degradates of cyanazine found in groundwater suggests that to accurately determine the overall effect on human health and the environment from cyanazine its degradates should also be considered. In addition, because CYTOT was found in 57.6% of the samples collected from alluvial aquifers, about 2-5 times more frequently than the other major aquifer types (glacial drift, bedrock/karst, bedrock/nonkarst) under investigation, this finding has long-term implications for the occurrence of CYTOT in streams. It is anticipated that low-level concentrations of CYTOT will continue to be detected in streams for years after the use of cyanazine has terminated (scheduled for the year 2000 in the United States), primarily through its movement from groundwater into streams during base-flow conditions.

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USGS2001

Short-term variability and long-term change in the composition of the littoral zone fish community in Spirit Lake, Iowa

We assessed short-term variability and long-term change in the composition of the littoral fish community in Spirit Lake, Iowa. Fish were sampled in several locations at night with large beach seines during spring, summer and fall of 1995–1998. Long-term changes were inferred from comparison with a similar study conducted over 70 y earlier in Spirit Lake. We found 26 species in the littoral zone. The number of species per sample ranged from 4 to 18, averaging 11.8. The average number of species per sample was higher at stations with greater vegetation density. A distinct seasonal pattern was evident in the number of species collected per sample in most years, increasing steadily from spring to fall. Patterns of variability within our 1995–1998 study period suggest that: (1) numerous samples are necessary to adequately characterize a littoral fish community, (2) sampling should be done when vegetation and young-of-year densities are highest and (3) sampling during a single year is inadequate to reveal the full community. The number of native species has declined by approximately 25% over the last 70 y. A coincident decline in littoral vegetation and associated habitat changes during the same period are likely causes of the long-term community change.

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USGS2001

Mississippi Basin Carbon Project: Upland soil database for sites in Nishnabotna River basin, Iowa

The conversion of land from its native state to an agricultural use commonly results in a significant loss of soil carbon (Mann, 1985; Davidson and Ackerman, 1993). Globally, this loss is estimated to account for as much as 1/3 of the net CO 2 emissions for the period of 1850 to 1980 (Houghton and others, 1983). Roughly 20 to 40 percent of original soil carbon is estimated to be lost as CO 2 as a result of agricultural conversion, or "decomposition enhancement". Global models use this estimate along with land conversion data to provide agricultural contributions of CO 2 emissions for global carbon budgets (Houghton and others, 1983; Schimel, 1995). Soil erosion rates are significantly (10X) higher on croplands than on their undisturbed equivalents (Dabney and others, 1997). Most of the concern over erosion is related to diminished productivity of the uplands (Stallings, 1957; McGregor and others, 1969; Rhoton, 1990) or to increased hazards and navigability of the lowlands in the late 1800's to early 1900's. Yet because soil carbon is concentrated at the soil surface, with an exponential decline in concentration with depth (Harden et al, 1999), it is clear that changes in erosion rates seen on croplands must also impact soil carbon storage and terrestrial carbon budgets as well. As yet, erosional losses of carbon are not included in global carbon budgets explicitly as a factor in land conversion nor implicitly as a portion of the decomposition enhancement. However, recent work by Lal and others (1995) and by Stallard (1998) suggests that significant amounts of eroded soil may be stored in man-made reservoirs and depositional environments as a result of agricultural conversion. Moreover, Stallard points out that eroding soils have the potential for replacing part of the carbon trapped in man-made reservoirs. If true, then the global carbon budget may grossly underestimate or ignore a significant sink term resulting from the burial of eroded soil.

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USGS2001

Water resources data, Iowa, water year 2000, Volume 1. surface water--Mississippi River Basin

Water resources data for water year 2000 for Iowa consists of records of stage, discharge, and water quality of streams; stage and contents of lakes and reservoirs; and water levels and water quality of ground water. This report, in two volumes, contains stage or discharge records for 126 gaging stations; stage or contents records for 9 lakes and reservoirs; water-quality records for 4 gaging stations; sediment records for 12 gaging stations; and water levels for 167 ground-water observation wells. Also included are peak-flow data for 93 crest-stage partial-record stations, water-quality data from 45 municipal wells, and precipitation data collected at 6 gaging stations and 2 precipitation sites. Additional water data were collected at various sites not included in the systematic data-collection program, and are published here as miscellaneous measurements and analyses. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Iowa.

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USGS2001

Effects of remedial grouting on the ground-water flow system at Red Rock Dam near Pella, Iowa

Previous studies have shown direct evidence of under-seepage at Red Rock Dam on the Des Moines River near Pella, Iowa. Underseepage is thought to occur primarily on the northeast side of the dam in the lower bedrock of the St. Louis Limestone, which consists of discontinuous basal evaporite beds and an overlying cavity zone. Because of concerns about the integrity of the dam, the U.S. Army Corps of Engineers initiated a remedial grouting program in September 1991. To assess the effectiveness of the remedial grouting program and to evaluate methods for future assessments, a study was conducted by the U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers. Potentiometric surface maps of the overburden and bedrock indicate that the direction of ground-water flow on the northeast side of the dam has changed little from pre-grout to post-grout periods. A comparison of water levels, between a pre-grout date and a post-grout date, shows that water levels decreased but that the decrease may be more attributable to changes in dam operations than to remedial grouting. Waterlevel data for the same two dates indicate that a more gradual potentiometric surface exists on the northeast side of the dam than on the southwest side of the dam, which suggests that the hydraulic connection between Lake Red Rock and downgradient bedrock wells still is greater on the northeast side of the dam than on the southwest side. Hydrographs for some wells on the northeast side of the dam indicated a departure from pre-grout trends at approximately the same time grouting was initiated. To varying degrees, hydrographs for the same wells then appear to return to a trend similar to pre-grout years, possibly as a result of new flow paths developing over time after remedial grouting. Spearman correlation coefficients computed for water levels in wells, pool, and tailwater indicate that some areas on the northeast side of the dam appear to be less under the influence of changing pool elevations after grouting than before grouting. This suggests that the hydraulic connection between the Red Rock pool and some downgradient areas has decreased. Analysis of water samples collected from selected wells on the northeast side of the dam shows significant increases in sulfate concentrations beginning about the same time remedial grouting was done upgradient from the wells, possibly indicating that flow paths were cut off to these wells, thereby reducing the amount of mixing with fresh reservoir water. Observable changes in chloride concentrations or trends as a result of remedial grouting were not apparent. Analysis results for hydrogen and oxygen stable isotope samples collected since 1995 indicate large seasonal fluctuations of isotope ratios in the tailwater (assumed representative of the reservoir). Similar but more subdued fluctuations were observed at some wells, but other wells appeared to have little seasonal change. Stable sulfur isotope results indicate the presence of distinct water types between Lake Red Rock and in ground water from downgradient bedrock wells. Sulfur isotope values from samples from a bedrock well located upgradient from the grout curtain indicate a mixture of pool and ground water, whereas samples from downgradient overburden wells have values similar to the pool. Samples from the bedrock wells downgradient from the grout curtain have sulfur isotope values similar to a value obtained from analysis of a gypsum and anhydrite core sample. Hydrographs, statistical analysis of waterlevel data, and water-chemistry data suggest that underseepage on the northeast side of the dam has been reduced but not completely eliminated. Some areas appear to have been affected to a greater degree and for a longer period of time than other areas. Future monitoring of water levels, water chemistry, and stable isotopes can aid in the evaluation of the long-term effectiveness of remedial grouting.

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USGS2001

Simulated ground-water flow and water quality of the Mississippi River alluvium near Burlington, Iowa, 1999

The City of Burlington, Iowa, obtains some of its public water supply by withdrawing ground water from the Mississippi River alluvium, an alluvial aquifer adjacent to the Mississippi River. The U.S. Geological Survey, in cooperation with the City of Burlington, conducted a hydrologic study of the Mississippi River alluvium near Burlington in 1999 to improve understanding of the flow system, evaluate the effects of hypothetical pumping scenarios on the flow system, and evaluate selected water-quality constituents in parts of the alluvium. A steady-state, ground-water flow model was constructed for a 7-square-mile area of the alluvium using October 1999 hydrologic conditions to help conceptualize the flow system, identify sources of water to the alluvium, and assess potential effects from additional hypothetical ground-water withdrawals from the lower alluvium. The model was discretized into a 70-row by 68-column grid using cells measuring 200 feet by 200 feet. Three model layers were used to represent flow in the upper part of the alluvium, lower part of the alluvium, and bedrock. The primary sources of ground water to the alluvium were subsurface flow from areas of the alluvium adjacent to the modeled area, recharge from precipitation, subsurface flow from Flint River streamchannel deposits adjacent to the alluvium, and river leakage. The primary components of outflow from the flow system were river leakage, municipal ground-water withdrawals (pumpage), and leakage to drainage ditches. Three hypothetical pumping scenarios were used to assess the potential effects of increased ground-water withdrawals from the lower part of the alluvium: (1) pumping a second existing municipal well at a rate of 0.5 million gallons per day, (2) pumping a hypothetical well completed in an area between the city water-treatment facility and Flint River at a rate of 1.0 million gallons per day, and (3) pumping a hypothetical well completed in an area south of the Flint River at a rate of 1.0 million gallons per day. Maximum additional simulated drawdown in the upper alluvium ranged from less than 3 feet (for scenario 1) to about 9 feet (for scenario 3). Maximum additional simulated drawdown in the lower alluvium ranged from about 12 feet (for scenario 1) to about 34 feet (for scenario 3). Water budgets for each scenario indicated future additional withdrawals from the flow system near Burlington’s existing municipal wells would significantly increase the amount of river leakage into the flow system. Water samples collected from the alluvium indicated ground water can be classified as a calcium-magnesium-bicarbonate type. Reducing conditions likely occur in some localized areas of the alluvium, as suggested by relatively large concentrations of dissolved iron (4,390 micrograms per liter) and manganese (2, 430 micrograms per liter) in some ground-water samples. Nitrite plus nitrate was detected at concentrations greater than or equal to 8 milligrams per liter in three samples collected from observation wells completed in close proximity to cropland; the nitrite plus nitrate concentration in one groundwater sample exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level for nitrate in drinking water (10 milligrams per liter as N). Triazine herbicides (atrazine, cyanazine, propazine, simazine, and selected degradation products) and chloroacetanilide herbicides (acetochlor, alachlor, and metolachlor) were detected in some water samples. A greater number of herbicide compounds were detected in surface-water samples than in ground-water samples. Herbicide concentrations typically were at least an order of magnitude greater in surfacewater samples than in ground-water samples. The Maximum Contaminant Level for alachlor (2 micrograms per liter) was exceeded in a sample from Dry Branch Creek at Tama Road and for atrazine (3 micrograms per liter) was exceeded in samples collected from Dry Branch Creek at Tama Road and the county drainage ditch at Tama Road.

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USGS2001

Ammonia in ground water from the Mississippi River alluvium, Fort Madison, Iowa

The U.S. Geological Survey, in cooperation with the City of Fort Madison, conducted a study of the potential sources and possible processes that might produce ammonia in ground water from the Mississippi River alluvium near Fort Madison, Iowa. High ammonia concentrations of 3.0 to 6.4 milligrams per liter were detected in water produced from municipal well Fort Madison #4 from 1992 through 1996. Total organic carbon concentrations of about 5 milligrams per liter were also reported during the same time period. Water-level measurements from two municipal wells and one well at Iowa State Penitentiary were used to determine that the general direction of ground-water flow during the two days of sampling was from northeast to southwest toward wells Fort Madison #4 and Fort Madison #5. Continuous pumping of other nearby wells probably influenced the direction of ground-water flow on these days. Because of a till confining unit separating the Mississippi River and the alluvial aquifer, it is uncertain to what extent induced recharge occurs to the alluvial aquifer from the river. Water samples were collected from three municipal wells, two industrial wells, one watersupply well at the Iowa State Penitentiary, one domestic well, two creeks, and the Mississippi River. Tritium analytical results indicate that the time of recharge was after 1953 for water from the municipal wells (where tritium samples were collected). The ammonia concentration, 5.1 milligrams per liter, was considerably higher in ground water collected from well Fort Madison #4 compared to samples collected from other wells. The dissolved organic carbon concentration was also highest in ground water collected from well Fort Madison #4 (5.5 milligrams per liter) although samples from other wells were also relatively high, 2.6 to 5.3 milligrams per liter. The most likely process producing the high ammonia concentration in ground water in the vicinity of well Fort Madison #4 is decomposition of organic matter (ammonification). Nitrogen isotope values, when compared to nitrogen isotope values found in ground water in the vicinity of some of the other wells, indicate the possibility that a higher percentage of the ammonia found in ground water in the vicinity of well Fort Madison #4 may be from human and(or) other animal wastes. Higher concentrations of dissolved phosphorus, orthophosphate, and a higher chloride-to-sodium mole ratio found in ground water sampled from well Fort Madison #4 could be indicative of a sewage or septic source. Potential sources include existing or abandoned septic systems, leaking sanitary sewer lines, commercial or residential waste-disposal sites, and agricultural runoff upgradient from well Fort Madison #4, or possibly, bed sediments of the Mississippi River.

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USGS2001

Ground water near Newton, Jasper County, Iowa

The U.S. Geological Survey, in cooperation with the city of Newton, Iowa, conducted an investigation of the ground-water resources of Jasper County, Iowa, near Newton during 1999-2001. The purpose of the investigation was to provide additional information on the South Skunk River alluvial aquifer from which Newton obtains its present municipal supply and to summarize the available information on other groundwater resources in the county. The South Skunk River alluvial aquifer consists of unconsolidated deposits of sand and gravel of glacial and fluvial origin. These deposits overlie bedrock composed primarily of shale and limestone of Pennsylvanian or Mississippian age. Information on the South Skunk River alluvial aquifer and other Jasper County alluvial aquifers is limited to a few test holes in a few locations. Additional thickness and lithologic information was collected using seismic refraction and test hole drilling to increase the understanding of the South Skunk River alluvial aquifer near Newton. Water-level and water-quality information also was collected. The alluvial deposits along the South Skunk River near Newton range from less than 30 to more than 60 feet thick. Three areas of deposits exceeding 60 feet thick occur near the present city of Newton well field about 5,000 feet west of the present well field, at the present well field, and about 5,000 feet southeast of the present well field. Ground water in the South Skunk River alluvial aquifer near the Newton well field flows toward the municipal well field. Ground-water levels on the well-field side of the South Skunk River were lower than water levels in the river, indicating flow from the river toward the well field. The water quality in the South Skunk River and the alluvial aquifer was similar, except most ground-water samples contained low dissolved oxygen concentrations. The low dissolved-oxygen concentrations in ground water resulted in high concentrations of iron and manganese in some locations and reduced forms of nitrogen.

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USGS2001

Water quality assessment of the Eastern Iowa Basins: Basic water chemistry of rivers and streams, 1996-98

The U.S. Geological Survey began data-collection activities in the Eastern Iowa Basins study unit of the National Water-Quality Assessment Program in September 1995 with the purpose of determining the status and trends in water quality of water from the Wapsipinicon, Cedar, Iowa, and Skunk River basins. From March 1996 through September 1998, monthly surface-water samples were collected from 11 sites on the study's rivers and streams representing three distinct physiographic regions, the Des Moines Lobe, the Iowan Surface, the Southern Iowa Drift Plain, and one subregion, the Iowan Karst. These water samples were analyzed for basic water chemistry, including, but not limited to the following cations: sodium, potassium, magnesium, calcium, and silica; anions: chloride, fluoride, sulfate, and bicarbonate; and two metals - iron and maganese. Although none of the concentrations of the constituents exceeded health advisories or drinking-water regulations, extremely high or low concentrations could potentially affect aquatic life. Calcium, magnesium, and potassium are essential elements for both plant and animal life; manganese is an essential element in plant metabolism; and silica is important in the growth of diatom algae. Calcium had the largest median concentration of 61 milligrams per liter (mg/L) of the cations, and the largest maximum concentration of 100 mg/L. Bicarbonate had the largest median concentration of 210 mg/L of the anions, and the largest maximum concentration of 400 mg/L. Basic water-quality differences related to physiographic differences and seasonality were evident in streams and rivers in the Eastern Iowa Basins. Of the three major landforms, water samples from sites within the Des Moines Lobe, the youngest landform in the study area, had significantly higher median concentrations of calcium (85 mg/L), magnesium (28 mg/L), sulfate (28 mg/L), fluoride (0.31 mg/L), and silica (16 mg/L). The Des Moines Lobe region is calcium magnesium bicarbonate-rich due to the Paleozoic source rocks (limestones and shales) in the bedrock. Water samples from sites within the Southern Iowa Drift Plain had higher median concentrations of sodium (12 mg/L), potassium (3.2 mg/L), and chloride (21 mg/L). Concentrations also varied according to the time of year. Grouping the data into four seasonal periods, water samples collected during the months of October, November, and December, had higher median concentrations of calcium, magnesium, and chloride, then samples collected during other quarters of the year. Water quality in the streams during this low-flow period (October through December) is representative of that in the contributing aquifers.

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USGS2001

Occurrence, distribution, and transport of nutrients in Eastern Iowa Rivers

Eleven streams in the Wapsipinicon, Cedar, Iowa, and Skunk River basins in eastern Iowa were sampled monthly from March 1996 through September 1998 to assess the occurrence, distribution, and transport of nitrogen, phosphorus, and suspended sediment as part of the U.S. Geological Survey's National Water-Quality Assessment Program. At least one form of dissolved nitrogen and phosphorus was detected in every sample collected. Nitrate accounted for 92 percent of the dissolved nitrogen. About 22 percent of the samples contained nitrate that exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level of 10 milligrams per liter (mg/L) as nitrogen in drinking water. The median concentration of total nitrogen for surface water in the study area was 7.2 mg/L. Dissolved phosphorus was predominately in the form of orthophosphate. The median total phosphorus concentration for the study area was 0.22 mg/L. About 75 percent of the total phosphorus concentrations exceeded the U.S. Environmental Protection Agency recommended total phosphorus concentration of 0.10 mg/L or less to minimize algal growth in streams not discharging directly into lakes or impoundments. Median suspended-sediment concentration for the study area was 82 mg/L. Nitrogen, phosphorus, and suspended-sediment concentrations varied annually and seasonally. Nitrogen, phosphorus, and suspended-sediment concentrations increased each year of the study due to increased precipitation and runoff. Concentrations were typically higher in the spring after fertilizer application and runoff. In winter, nitrogen concentrations typically increased when there was little instream assimilation by aquatic plants and algae. Nitrogen and phosphorus concentrations decreased in late summer when there was less runoff and instream assimilation of nitrogen and phosphorus by aquatic plants and algae was high. Suspended-sediment concentrations were highest in early summer during runoff and lowest in January when there was ice cover with very little overland flow contributing to rivers and streams. Streams draining small- to medium-sized watersheds that have uniform land use and geology had significantly (p < 0.05) higher total dissolved-nitrogen concentrations (median, 8.2 mg/L) than did samples from large rivers (median, 6.2 mg/L) that drain basins with mixed land use and geology. Samples from large rivers typically had significantly (p< 0.05) higher total phosphorus and suspended-sediment concentrations than did samples from small rivers and streams. Concentrations varied between drainage basins due to land use and physiography. Basins that are located in areas with a higher percentage of row-crop agriculture typically had samples with higher nitrogen concentrations than did basins with less row-crop agriculture. In addition, basins that drain the Southern Iowa Drift Plain and the Des Moines Lobe typically had samples with higher total phosphorus and suspended-sediment concentrations than did basins that drain other landform regions. Total nitrogen and total phosphorus loads were typically proportional to the size of the drainage basin. Total nitrogen loads increased each year from 1996 through 1998 in conjunction with increased concentrations and runoff. However, total phosphorus loads in the Skunk River Basin decreased in 1997 due to less runoff. Total phosphorus loads followed the same pattern as total nitrogen loads with increases in 1998. Total nitrogen and total phosphorus loads varied seasonally and the highest loads typically occurred in early spring and summer after fertilizer application and runoff. Loads were lowest in January and September when there was little runoff to transport nitrogen and phosphorus to the rivers and streams. Total nitrogen loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 97,000, 120,000, and 230,000 metric tons respectively. Total phosphorus loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 6,900, 4,600, and 8,800 metric tons, respectively. The highest nitrogen and phosphorus yields typically occurred in streams draining small watersheds that were dominated by a single land use and geology. Sampling sites located in drainage basins with higher row-crop percentage typically had higher nitrogen and phosphorus yields. Sites that were located in the Des Moines Lobe and the Southern Iowa Drift Plain typically had higher phosphorus yields probably due to more erodible soils and steeper slopes.

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USGS2001

Quality of water in alluvial aquifers in eastern Iowa

The goal of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is to assess the status and trends in the quality of the Nation's surface and ground water, and to better understand the natural and human factors affecting water quality. The Eastern Iowa Basins study unit encompasses an area of about 50,500 square kilometers (19,500 square miles) in eastern Iowa and southern Minnesota and is one of 59 study units in the NAWQA program. Land-use studies are an important component of the NAWQA program, and are designed to assess the concentration and distribution of water-quality constituents in recently recharged ground water associated with the most significant land use and hydrogeologic settings within a study unit. The focus of the land-use study in the Eastern Iowa Basins study unit is agricultural and urban land uses and alluvial aquifers. Agriculture is the dominant land use in the study unit. Urban areas, although not extensive, represent important potential source areas of contaminants associated with residential, commercial, and industrial activities. Alluvial aquifers are present throughout much of the study unit, and constitute a major ground-water supply that is susceptible to contamination from land-use activities. Ground-water samples were collected from monitoring wells at 31 agricultural and 30 urban sites in the Eastern Iowa Basins study unit during June-August 1997 to evaluate the effects of land use and hydrogeology on the water quality of alluvial aquifers. Calcium, magnesium, and bicarbonate were the dominant ions in most samples and were likely derived from solution of carbonate minerals (calcite and dolomite) present in alluvial detrital deposits. Tritium-based ages indicate ground water was most likely recharged after the 1950's at all but one sampling site. Agricultural and urban land-use areas have remained relatively stable in the study area since the 1950's, therefore the effects of current land use should be reflected in ground water sampled during this study. Sodium and chloride concentrations were significantly higher in samples from urban areas, where roads are more numerous and road salts may be more frequently applied, than in agricultural areas. Nitrate was detected in 94 percent of samples from agricultural areas and 77 percent of samples from urban areas. Nitrate concentrations were significantly higher in agricultural areas than in urban areas and exceeded the U.S. Environmental Protection Agency maximum contaminant level for drinking water (10 milligrams per liter as N) in 39 percent of samples from agricultural areas. Nitrate concentrations in samples from urban areas did not exceed the maximum contaminant level. Greater usage of fertilizers in agricultural areas most likely contributes to higher nitrate concentrations in samples from those areas. Pesticides were detected in 84 percent of samples from agricultural areas and 70 percent from urban areas. Atrazine and metolachlor were the most frequently detected pesticides in samples from agricultural areas; atrazine and prometon were the most frequently detected pesticides in samples from urban areas. None of the pesticide concentrations exceeded U.S. Environmental Protection Agency maximum contaminant levels or lifetime health advisories for drinking water. Pesticide degradates were detected in 94 percent of samples from agricultural areas and 53 percent from urban areas. Metolachlor ethane sulfonic acid and deethylatrazine were the most frequently detected metabolites in samples from agricultural areas; metolachlor ethane sulfonic acid and alachlor ethane sulfonic acid were the most frequently detected degradates in samples from urban areas. Total degradate concentrations were significantly higher in samples from agricultural areas than in samples from urban areas. Total pesticide concentrations (parent compounds) tended to be higher in samples from agricultural areas; however, this difference was not statistically significant. Degradates constituted the major portion of the total residue concentration in the alluvial aquifer. Volatile organic compounds were detected in 40 percent of samples from urban areas and 10 percent from agricultural areas. Methyl tert-butyl ether was the most commonly detected volatile organic compound and was present in 23 percent of samples from urban areas. Elevated concentrations (greater than 30 micrograms per liter) of methyl tert-butyl ether and BTEX compounds (benzene, toluene, ethylbenzene, and xylene) in two samples from urban areas suggest the possible presence of point-source gasoline leaks or spills. Factors other than land use may contribute to observed differences in water quality between and within agricultural and urban areas. Nitrate, atrazine, deethylatrazine, and deisopropylatrazine concentrations were significantly higher in shallow wells with sample intervals nearer the water table and in wells with thinner cumulative clay thickness above the sample intervals, suggesting that longer flow paths allow for greater residence time and increase opportunities for sorbtion, degradation, and dispersion which may contribute to decreases in nutrient and pesticide concentrations with depth. Nitrogen speciation was influenced by redox conditions. Nitrate concentrations were significantly higher in ground water with dissolved-oxygen concentrations in excess of 0.5 milligrams per liter. Ammonia concentrations were higher in ground water with dissolved-oxygen concentrations of 0.5 milligrams per liter or less, however, this relation was not statistically significant. The amount of available organic matter may limit denitrification rates. Elevated nitrate concentrations (greater than 2.0 mg/L) were significantly related to lower dissolved organic carbon concentrations in water samples from both agricultural and urban areas. A similar relation between nitrate concentrations (in water) and organic carbon concentrations (in aquifer material) also was observed but was not statistically significant.

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USGS2001

Occurrence and distribution of pesticides in streams of the Eastern Iowa Basins, 1996-98

The U.S. Geological Survey began collection of water samples in streams of the Eastern Iowa Basins in 1996 for the analysis of pesticides and pesticide degradates as part of the National Water Quality Assessment Program (NAWQA). This study provides some of the first large scale monitoring data on pesticides and pesticide degradates in Eastern Iowa. Three hundred and forty-four samples were collected from 1996-98 to document the occurrence, distribution, and transport of pesticide compounds. Pesticide analysis included 80 pesticide compounds and 10 pesticide degradates. The Eastern Iowa Basins study encompasses about 50,500 square kilometers (19,500 square miles) and is drained by four major rivers--the Wapsipinicon, Cedar, Iowa, and Skunk. Agriculture accounts for approximately 93 percent of the land use in the study area. The most commonly detected pesticides were those most heavily used on crops. The triazine (atrazine and cyanazine) and chloroacetanilide (alachlor, acetochlor, and metolachlor) pesticides are some of the most heavily used (by weight) historically and during the period of data collection 1996-98. Atrazine and metolachlor were detected in all samples. Acetochlor, alachlor, and cyanazine were detected in more than 70 percent of all surface-water samples. Few non-agricultural herbicides were detected. One exception, prometon was detected in more than 80 percent of the samples at very low concentrations (less than 0.1 micrograms per liter). Pesticide degradates were some of the most frequently detected pesticide compounds in the study. Four pesticide degradates--metolachlor ethane sulfonic acid (metolachlor ESA), alachlor ethane sulfonic acid (alachlor ESA), metolachlor oxanilic acid (metolachlor OA), and acetochlor ethane sulfonic acid (acetochlor ESA) were detected in more than 75 percent of the samples. A few insecticides that may pose potential risk to aquatic invertebrates were detected in streams from May through September, the months when most application normally occurs. Carbofuran was the most commonly detected insecticide (16 percent of all samples). Although detected in less than 20 percent of all samples, carbofuran was detected in 68 percent of the samples in June. When present, carbofuran concentrations were generally less than 0.80 micrograms per liter. Chloropyrifos was detected in about seven percent of the samples. As with other insecticides, chlorpyrifos was detected most frequently in June (30 percent). The highest concentration was 0.06 micrograms per liter. Diazinon, a common urban insecticide found in other NAWQA studies throughout the Nation, was detected in only 2 percent of the samples in the Eastern Iowa Basins study. Pesticides were found to occur in mixtures with several compounds rather than individually. Four or more parent pesticide compounds were detected in 91 percent of the water samples and seven or more parent compounds were detected in 46 percent of the water samples. Four or more pesticide degradates were detected in 93 percent of the water samples and seven or more pesticide degradates were detected in 46 percent of the water samples. Commonly applied parent pesticide compounds (acetochlor, alachlor, atrazine, cyanazine, and metolachlor) were generally detected at low concentrations with median concentrations ranging from 0.01 to 0.22 micrograms per liter. The median concentrations for the pesticide degradates were larger than their parent compounds. Median concentrations for the pesticide degradates ranged from 0.07 to 3.7 micrograms per liter. Acetochlor, alachlor, atrazine, cyanazine and metolachlor pesticides compounds were present at least an order of magnitude or higher in the late spring and summer than at other times of the year. The maximum measured concentrations for acetochlor, atrazine, cyanazine and metolachor were approximately 11 to 48 micrograms per liter (the maximum for alachlor was 0.56 micrograms per liter). In contrast, maximum measured concentrations for the total pesticide degradates were lower than their parent compounds and ranged from approximately 0.7 to 12 micrograms per liter. The maximum measured concentration of a single pesticide compound was for atrazine at 48 micrograms per liter. Seasonal patterns of atrazine, acetochlor, alachlor, cyanazine, and metolachlor generally show peak concentrations following application in May and June and decreasing during remainder of the growing season. In addition, a small secondary peak in atrazine, acetochlor, alachlor, cyanazine, and metolachlor concentrations occurred at all sites in late winter. This secondary peak may be attributed to early "winter thaw" that can release pesticide residue from soil, making pesticides available to be transported to surface water by snowmelt and early spring rains. Pesticide degradates account for a significant portion of the total pesticide load at all sites. Eighty-one percent of the total pesticide load in samples from Iowa River near Rowan, Wolf Creek near Dysart, and the Iowa River at Wapello were as pesticide degradates. The pesticide degradates for the triazine compounds tended to follow the load pattern of the parent pesticide compounds closely throughout the year. In general, the degradate loads calculated for the triazine compounds were smaller than loads calculated for their parent pesticides. The loads for the chloroacetanilide degradate compounds were larger than those for the parent pesticides. The loads for alachlor were found to be small or nonexistent. Alachlor has been heavily used in the past, but since 1995 has been largely replaced by acetochlor or other herbicides. The loads for all degradates were higher than the parent compounds during the winter months. Overland flow may be diminished during the winter months, but shallow sub-soil drainage and ground-water flow may be a source of many pesticide degradates during the late fall and winter. Occurrence of pesticide compounds varied by landform region. The triazine herbicides, atrazine and cyanazine and their degradates were present in significantly greater concentrations in the Southern Iowa Drift Plain (predominantly loess soils) than either the Des Moines Lobe or the Iowan Surface (predominantly till soils). Less atrazine and cyanazine are applied to till soils because of pH and organic carbon content. Alachlor, metolachlor, and acetochlor have often been used to offset triazine pesticide reductions in area with till soils.

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USGS2000

Finding minimal herbicide concentrations in ground water? Try looking for their degradates

Extensive research has been conducted regarding the occurrence of herbicides in the hydrologic system, their fate, and their effects on human health and the environment. Few studies, however, have considered herbicide transformation products (degradates). In this study of Iowa ground water, herbicide degradates were frequently detected. In fact, herbicide degradates were eight of the 10 most frequently detected compounds. Furthermore, a majority of a herbicide's measured concentration was in the form of its degradates &mdash; ranging from 55 to over 99%. The herbicide detection frequencies and concentrations varied significantly among the major aquifer types sampled. These differences, however, were much more pronounced when herbicide degradates were included. Aquifer types presumed to have the most rapid recharge rates (alluvial and bedrock/karst region aquifers) were those most likely to contain detectable concentrations of herbicide compounds. Two indirect estimates of ground-water age (depth of well completion and dissolved-oxygen concentration) were used to separate the sampled wells into general vulnerability classes (low, intermediate, and high). The results show that the herbicide detection frequencies and concentrations varied significantly among the vulnerability classes regardless of whether or not herbicide degradates were considered. Nevertheless, when herbicide degradates were included, the frequency of herbicide compound detection within the highest vulnerability class approached 90%, and the median total herbicide residue concentration increased over an order of magnitude, relative to the parent compounds alone, to 2 &mu;g/l. The results from this study demonstrate that obtaining data on herbicide degradates is critical for understanding the fate of herbicides in the hydrologic system. Furthermore, the prevalence of herbicide degradates documented in this study suggests that to accurately determine the overall effect on human health and the environment of a specific herbicide its degradates should also be considered.

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USGS2000

Late Albian Kiowa-Skull Creek marine transgression, lower Dakota Formation, eastern margin of Western Interior Seaway, U.S.A

An integrated geochemical-sedimentological project is studying the paleoclimatic and paleogeographic characteristics of the mid-Cretaceous greenhouse world of western North America. A critical part of this project, required to establish a temporal framework, is a stratigraphic study of depositional relationships between the Albian-Cenomanian Dakota and the Upper Albian Kiowa formations of the eastern margin of the Western Interior Seaway (WIS). Palynostratigraphic and sedimentologic analyses provide criteria for the Dakota Formation to be divided into three sedimentary sequences bounded by unconformities (D 0 , D 1 , and D 2 ) that are recognized from western Iowa to westernmost Kansas. The lowest of these sequences, defined by unconformities D 0 and D 1 , is entirely Upper Albian, and includes the largely nonmarine basal Dakota (lower part of the Nishnabotna Member) strata in western Iowa and eastern Nebraska and the marine Kiowa Formation to the southwest in Kansas. The gravel-rich fluvial deposits of the basal part of the Nishnabotna Member of the Dakota Formation correlate with transgressive marine shales of the Kiowa Formation. This is a critical relationship to establish because of the need to correlate between marine and nonmarine strata that contain both geochronologic and paleoclimatic proxy data. The basal gravel facies (up to 40 m thick in western Iowa) aggraded in incised valleys during the Late Albian Kiowa-Skull Creek marine transgression. In southeastern Nebraska, basal gravels intertongue with carbonaceous mudrocks that contain diverse assemblages of Late Albian palynomorphs, including marine dinoflagellates and acritarchs. This palynomorph assemblage is characterized by occurrences of palynomorph taxa not known to range above the Albian Kiowa-Skull Creek depositional cycle elsewhere in the Western Interior, and correlates to the lowest of four generalized palynostratographic units that are comparable to other palynological sequences elsewhere in North America. Tidal rhythmites in mudrocks at the Ash Grove Cement Quarry in Louisville (Cass County), Nebraska record well-developed diurnal and semimonthly tidal cycles, and moderately well developed semiannual cycles. These tidal rhythmites are interpreted to have accumulated during rising sea level at the head of a paleoestuary that experienced at least occasional mesotidal conditions. This scenario places the gravel-bearing lower part of the Nishnabotna Member of the Dakota Formation in the mouth of an incised valley of an Upper Albian transgressive systems tract deposited along a tidally influenced coast. Furthermore, it provides a depositional setting consistent with the biostratigraphic correlation of the lower part of the Nishnabotna Member of the Dakota Formation to the marine Kiowa Formation of Kansas.

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USGS2000

The relationship of nitrate concentrations in streams to row crop land use in Iowa

The relationship between row crop land use and nitrate N concentrations in surface water was evaluated for 15 Iowa watersheds ranging from 1002 to 2774 km 2 and 10 smaller watersheds ranging from 47 to 775 km 2 for the period 1996 to 1998. The percentage of land in row crop varied from 24 to >87% in the 15 large watersheds, and mean annual NO 3 -N concentrations ranged from 0.5 to 10.8 mg/L. In the small watersheds, row crop percentage varied from 28 to 87% and mean annual NO 3 -N concentrations ranged from 3.0 to 10.5 mg/L. In both cases, nitrate N concentrations were directly related to the percentage of row crop in the watershed ( p < 0.0003). Linear regression showed similar slope for both sets of watersheds (0.11) suggesting that average annual sudace water nitrate concentrations in Iowa, and possibly similar agricultural areas in the midwestern USA, can be approximated by multiplying a watershed's row crop percentage by 0.1. Comparing the Iowa watershed data with similar data collected at a subwatershed scale in Iowa (0.1 to 8.1 km 2 ) and a larger midcontinent scale (7300 to 237 100 km 2 ) suggests that watershed scale affects the relationship of nitrate concentration and land use. The slope of nitrate concentration versus row crop percentage decreases with increasing watershed size.

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USGS2000

Volumes of recent floods and potential for storage in upland watershed areas of Iowa

Substantial flooding at various locations throughout the United States, particularly during and after the Upper Mississippi River Basin flood of 1993, has resulted in analysis and discussion of both structural and nonstructural methods of watershed management to control flooding. The Upper Mississippi River Basin flood of 1993 resulted in the formulation of a Scientific Assessment and Strategy Team (SAST) to assist and advise decision makers about the positive and negative effects of flood-control measures and habitat restoration (Scientific Assessment and Strategy Team, 1994). SAST recognized the role of upland processes and the interconnectivity of a management strategy on other parts of the river system. If upland areas are considered for inclusion in an overall management strategy related to flooding, an analysis of watershed that have been flooded and the amount of runoff generated during those floods is needed. During the autumn of 1997, the U.S. Geological Survey (USGS), in cooperation with the U.S. Environmental Protection Agency, began a study to determine the volume of water associated with recent flood events in parts of the Midwestern United States and a preliminary evaluation of the potential upland areas for storage of flood-waters in selected watersheds. This analysis, although preliminary, may be useful in determining the feasibility of conducting additional, more detailed studies into the role of upland areas in a watershed management strategy. The methods and results of this preliminary hydrologic study are presented in this report.

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