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Leah E. Morgan

Publications and source records attributed to Leah E. Morgan.

At least 37 records · Page 2Linked to original sources

Late Jurassic-Early Cretaceous orogenic gold mineralization in the Klamath Mountains, California: Constraints from 40Ar/39Ar dating of hydrothermal muscovite

The Klamath Mountains gold province is the second most important historical producer in California, having produced more than 7 Moz of gold from both lode and placer sources. Hydrothermal muscovite grains from gold-bearing veins provide the first 40 Ar/ 39 Ar age constraints indicative of a protracted period of mineralization in the Klamath Mountains. The data indicate that the window for orogenic gold mineralization in the Klamath Mountains was from ∼160–140 Ma, coinciding in age with the oldest orogenic gold deposits in the Sierra Nevada foothills province to the south, although mineralization continued in the latter along the Mother Lode belt for another 20–30 million years. Despite the broad age overlap between hydrothermal activity and magmatism, the former relates to a regional thermal event, and there is no genetic link between the two. Instead, a correlation exists between the timing of lode gold formation and discrete tectonic events, changes in stress regime, and fault movement. The maximum age corresponds to a major plate reorganization in the Pacific basin and initial gold mineralization continuing into the Sierra Nevada foothills gold province to the south. The minimum age corresponds to the westerly lateral offset of the Klamath Mountains from the Sierra Nevada and the then-active arc, marking the termination of both magmatism and gold-producing hydrothermal activity in the Klamath Mountains. Lode gold mineralization in the Klamath Mountains is compatible with a crustal source of metals and fluids that were released during metamorphic devolatilization and focused via hydrothermal fluid flow along regional faults.

California↗

Early Neoproterozoic gold deposits of the Alto Guaporé province, southwestern Amazon craton, western Brazil

The Alto Guaporé gold province, southwestern Amazon craton, contains gold deposits that have been mined since the beginning of the 18th century and these deposits, together, have modern-day, pre-mining gold resources of at least 1.8 Moz. The ore is associated with quartz vein systems along the southeastern part of the Aguapei belt, a ~35-km-wide and ~500-km-long, NNW-trending shear zone formed due to reactivation of a terrane-bounding suture. The Aguapei belt evolved by ca. 1150 to 1100 Ma rifting and deposition of siliciclastic sediments in an aulacogen basin, followed by deformation and low-grade metamorphism of the sedimentary sequences during 1100 to 900 Ma terrane collision along the craton margin. The deformation was characterized by a compressional regime until ca. 950 Ma and transition to a transpressional setting during the final 50 m.y. The gold deposits are hosted in a variety of structures that are second-order to the main Aguapei shear zone. The Ernesto and Pau-a-Pique deposits are located ~40 km apart and at jogs along the Aguapei belt. They are marginal to pre-ore igneous rocks, with Ernesto hosted in the basal part of the metasedimentary Fortuna Formation that overlies tonalite and Pau-a-Pique at the contact between metasedimentary rocks and diorite. Three deformational phases comprise the compressional (D 1 to D 2 ) to transpressional (D 3 ) tectonic events. In the Pau-a-Pique deposit and the deeper level of the Ernesto deposit, the ore-bearing veins are bedding parallel and follow D 2 strike-slip and reverse fault zones, respectively. However, the veins formed during D 3 reactivation of the older structures by an array of oblique accommodation faults. In contrast, ores at shallower levels of Ernesto, both in discordant and bedding-parallel veins, are hosted within a ~20-m-thick rigid metaconglomerate with associated dilation due to the structural complexity as sedimentary rocks of the Aguapei Group were folded around the dome-shaped roof of the pre-ore tonalite. The ores in both deposits, as well as in many other deposits of the province, are characterized by disseminated and vein-hosted pyrite. Gold occurs mainly as inclusions in the pyrite, with other hydrothermal phases comprising muscovite, Fe-Ti oxides, and minor apatite, chalcopyrite, and galena. Fluid inclusion data, coupled with stable isotope geochemistry and geothermometry, indicate that gold precipitated from a low-salinity, CO 2 -rich fluid at ~300°C and ~2.5 kbar. The source for the fluid and gold was the interbedded pelites during devolatilization of the Aguapei Group sequence. The aqueous-carbonic fluid inclusions and the narrow range of δ 18 O values of quartz (12 ± 1 ‰ ) from many auriferous veins from the central part of the province represent a regional ore-forming fluid. The broad range of δ D for hydrous minerals (–116 to –55 ‰ ) reflects influx of small amounts of meteoric water into the steeply dipping shear zones during postgold exhumation. The 40 Ar/ 39 Ar geochronology from hydrothermal muscovite indicates a widespread hydrothermal event along the belt between 928 and 920 Ma. Collectively, the geological, geochronological, and geochemical data suggest that metamorphic fluids migrated laterally into and then upward along the Aguapei belt and deposited gold in lower-order structures where strain gradients existed between lithounits. The province has many characteristics of large orogenic gold provinces worldwide and represents a highly prospective and underexplored target region for early Neoproterozoic gold, a time period that generally is not well endowed in gold ores.

Alto Guaporé gold province, Amazon craton↗

Gondwanic inheritance on the building of the western Central Andes (Domeyko Range, Chile): Structural and thermochronological approach (U-Pb and 40Ar-39Ar)

Tectonics inheritance controls the evolution of many orogens. To unravel the role of the Gondwanan heritage (late Paleozoic to Triassic) over the building of the Central Andes in northern Chile (Domeyko Range), we performed detrital U‐Pb zircon and 40 Ar/ 39 Ar muscovite geochronology along with structural analyses (kinematics and structural balancing). 40 Ar/ 39 Ar dating of detrital muscovite reveals contrasting cooling histories for the Paleozoic basement of Triassic rift sub‐basins, indicating that NW‐striking crustal structures segmented the Andean forearc since at least the middle Permian, likely related to an accretional fabric developed along SW Gondwana. These structures can be inferred based on scattered faults, gravimetric data, and basement age disruptions. During the Late Triassic, NS‐striking master faults and secondary NW‐ to NNW‐striking faults configured an oblique rift, primarily driven by subduction dynamics. We suggest that along SW Gondwana, the slab‐pull would have controlled the development of subduction‐related rift basins close to the trench whereas Triassic inland rifts were mainly driven by Pangea‐breakup stresses. Compressional tectonics began in the Late Cretaceous, yet the inversion of the Triassic rift would have started during the Eocene with the inception of the metallogenic‐fertile transpressional Domeyko fault system. Thus, the structural style of this range was determined by the architecture of the Triassic rift, where the inversion of deep‐seated faults accounted for west‐vergent thick‐ and thin‐skinned structures. Pre‐Andean NW‐striking structures also accommodated tectonic rotations during the Incaic orogeny (Eocene‐Oligocene) and may delimit the rupture zone of large earthquakes, suggesting an underestimated role of such ancient discontinuities in Andean neotectonics.

Tectonics↗

Constraining central Himalayan (Nepal) fault geometry through integrated thermochronology and thermokinematic modeling

Constraining the subsurface structural geometry of the central Himalaya continues to prove difficult, even after the 2015 Gorkha earthquake and the resulting insights into the trajectory of the Main Himalayan thrust (MHT). To this end, we apply a thermokinematic model to evaluate four possible balanced cross section geometries based on three estimates of the MHT in central Nepal. We compare the effect of different décollement and duplex geometries on predicted cooling ages and compare these to new and published ages. We find that the best‐fit geometry able to reproduce the cooling ages at the surface is a hinterland‐dipping duplex, which has been translated over a mid‐crustal ramp located ~110 km north of the Main Frontal thrust. We find that the temporal evolution of the duplex and MHT mid‐crustal ramp both play an integral role in producing the observed cooling ages, implying that the common assumption that the active décollement and ramp geometry solely control the distribution of cooling ages is incorrect. Furthermore, results indicate that the Ramgarh‐Munsiari thrust was emplaced between 17 and ~10 Ma, followed by the Trishuli thrust. Duplex growth occurs between 6.5 Ma and 0.75 Ma, with its constituent thrust sheets moving at variable rates between 10 – 42 mm/yr. Young out‐of‐sequence thrusting (5 km of displacement) in the hinterland produces a slightly improved fit to the cooling ages. Finally, the resulting thermal field modeled from our best‐fit geometry suggests a possible basis for the nucleation and rupture characteristics of the Gorkha earthquake.

Himalayan Fault↗

Conditions and timing of high-grade metamorphism and ductile deformation of the southern segment of the Central Anatolian Ophiolite

Ophiolitic fragments scattered over a wide area of Central Anatolia exhibit varying degrees of metamorphism, from unmetamorphosed to upper amphibolite facies, although geochemical similarities suggest they are all part of the Central Anatolian Ophiolite (CAO). Magmatic crystallization of oceanic crust in the CAO at ~ 91 Ma coincided with high-grade metamorphism of rocks that underlie the southern, highest grade part of the CAO, raising questions about the tectonic relationship of the ophiolite to underlying metasedimentary and plutonic rocks. New geochronology results show that the 40 Ar/ 39 Ar hornblende age of amphibolite-facies metagabbro in the high-grade metamorphic part of the CAO is ~ 87 Ma, similar to hornblende ages from amphibolite in the underlying Niğde metamorphic/plutonic massif. Biotite in a deformed quartzofeldspathic rock associated with high-grade meta-ophiolitic rocks yielded an 40 Ar– 39 Ar age of ~ 78 Ma, similar to biotite ages from the Niğde Massif. Hornblende in gabbro from unmetamorphosed CAO yielded an older 40 Ar/ 39 Ar age of ~ 90 Ma, similar to the previously determined crystallization age of the ophiolite. These data indicate that the southern part of the ophiolite was incorporated into and therefore metamorphosed and deformed with the orogenic mid-crust now exposed in the Niğde metamorphic–plutonic complex, whereas the northern, unmetamorphosed part of the ophiolite was obducted onto the continent. This distinct difference in different parts of the ophiolite may indicate oblique collision or irregularities in the continental margin, resulting in part of the ophiolite being incorporated into the orogenic crust and subsequently exhumed and cooled with it, and another part being obducted.

Anatolia↗

Interpreting and reporting 40Ar/39Ar geochronologic data

The 40 Ar/ 39 Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth’s formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing 40 Ar/ 39 Ar dates with analytical uncertainties of ∼0.1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful “age” from a measured “date” or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of 40 Ar/ 39 Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting 40 Ar/ 39 Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of 40 Ar/ 39 Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity.

GSA Bulletin↗

Detrital record of the late Oligocene – Early Miocene mafic volcanic arc in the southern Patagonian Andes (~51 °S) from single-clast geochronology and trace element geochemistry

Retroarc foreland basins are important archives of continental arc magmatism and upper plate deformational processes that control the evolution of continental lithosphere. However, resolving source areas in foreland basin infill dominated from mixed mafic and recycled sediment using conventional methods such as detrital zircon geochronology poses a challenge to thorough analysis due to lower zircon fertility and the higher susceptibility to weathering of mafic lithologies. Here, we integrate whole rock 40 Ar/ 39 Ar geochronology and major and trace element geochemistry data from volcanic clasts from the lower Miocene infill of the Magallanes-Austral Basin and local Sierra Baguales intrusive rocks to understand the distribution of mafic sources and Neogene changes in arc magmatism in between multiple ridge subduction events in the southern Patagonian Andes. Potential source areas for the coarse-grained mafic detritus include the Eocene plateau lavas, the Late Jurassic-Miocene Southern Patagonian batholith, and the Late Jurassic Sarmiento Ophiolitic Complex. Published detrital zircon U-Pb age spectra suggest that all three sources are viable contributors to the basin, though the paucity of Jurassic and Eocene zircons preclude these as major sources. Here, new 40 Ar/ 39 Ar dating of the volcanic clasts from the early Miocene Río Guillermo Formation reveals latest Oligocene to early Miocene eruptive ages (∼25-22 Ma), indicating syndepositional eruption with the ancestral Río Guillermo fluvial sedimentation. A single dated clast yields a Late Cretaceous age (∼102 Ma). The clasts are dominantly basaltic andesite with Ba/Ta ∼500-1000, La/Ta >20, and Ba/La >15, indicating an arc-derived melt source. We propose that the clasts record a Miocene mafic continental arc source area in the Patagonian Andes, which has since been removed by erosion and is thus sparsely represented in the batholith. Furthermore, we suggest that this early Miocene phase of arc volcanism, which postdates Eocene and Oligocene backarc magmatism and pre-dates middle Miocene to recent Chile Ridge backarc magmatism, reflects a return to normal arc volcanism along the Patagonian margin following a cessation due to ridge subduction and subsequent slab window migration. New geochemistry and 40 Ar/ 39 Ar data from a basaltic dike in the Sierra Baguales, which crosscuts the Cenozoic stratigraphic section, records plateau magmatism ∼16 Ma associated with incipient Chile Ridge slab window volcanism.

Patagonian Andes↗

Geologic map of the Poncha Pass area, Chaffee, Fremont, and Saguache Counties, Colorado

This report presents a 1:24,000-scale geologic map, cross sections, and descriptive and interpretative text for the Poncha Pass area in central Colorado. The map area is irregular in shape, covering all of one 7 ½' quadrangle (Poncha Pass) and parts of five others (Mount Ouray, Maysville, Salida West, Salida East, and Wellsville). The map boundaries were drawn to cover all of the “Poncha mountain block,” our designation for the approximately 15-kilometer-long northwestern end of the Sangre de Cristo Mountains. The map conveys the areal distribution of (1) Proterozoic basement rocks forming the core of the Poncha mountain block, (2) overlying Eocene and Oligocene volcanic rocks, (3) Miocene and younger basin-fill deposits, (4) Quaternary surficial glacial and alluvial deposits, and (5) faults and folds affecting all of the above units. The Poncha mountain block, which lies within the Rio Grande rift, is topographically and geologically distinctive. Generally, the Rio Grande rift is internally characterized by subsided structural basins or grabens and subdued, low-relief topography rather than elevated mountain blocks. The intrarift, topographically high Poncha mountain block spans the axial part of the rift and separates the low-lying basins of the west-tilted upper Arkansas River half graben and east-northeast-tilted San Luis half graben. These distinctive aspects of the Poncha mountain block were the primary motivations to conduct geologic mapping in the area. Important questions addressed by geologic mapping and related studies in the Poncha Pass area include (1) what were the structural controls and tectonic mechanism(s) that resulted in development of the Poncha mountain block in an intrarift environment; (2) did surface uplift of the Poncha block occur during rift development in the Neogene and Quaternary, and at what rate(s); (3) how was extensional strain accommodated and relayed across the Poncha block between the opposite-polarity rift basins and flanking mountain blocks; (4) is there a clear Laramide deformational signal in rocks of the map area; and (5) have earlier Laramide contractional structures, if they exist, influenced later rift-related extensional deformation through reactivation or strain localization. Prior to our mapping, the geology of much of the Poncha Pass area had only been mapped in reconnaissance fashion, reflecting the area’s poor bedrock exposures, poor access due to the rugged terrain, and geologic complexity. The map presented here provides new details of the geology of this difficult area and helps elucidate the development of the Poncha block and improves understanding of the geologic framework and geologic history of the area.

Colorado↗

The influence of foreland structures on hinterland cooling: evaluating the drivers of exhumation in the eastern Bhutan Himalaya

Understanding, and ideally quantifying, the relative roles of climatic and tectonic processes during orogenic exhumation is critical to resolving the dynamics of mountain building. However, vastly differing opinions regarding proposed drivers often complicate how thermochronometric ages are interpreted, particularly from the hinterland portions of thrust belts. Here we integrate three possible cross section geometries and kinematics along a transect through the eastern Bhutan Himalaya with a thermal model (Pecube-D) to calculate the resulting thermal field and predict potential ages. We compare predicted ages to a suite of new and published cooling ages. Our results argue for ramp-focused exhumation of the Main Central Thrust (MCT) from 16 to 14 Ma at shortening rates of 40-55 mm/yr, followed by slower rates (25 mm/yr) during the last 50 km of MCT displacement and growth of the Lesser Himalayan (LH) duplex from 14-11 Ma. Emplacement of frontal LH thrust sheets occurred rapidly (55-70 mm/yr) between ~11 and 9 Ma, followed by a decrease in shortening rates to ~10 mm/yr during motion on the Main Boundary Thrust (MBT). Modern shortening rates (17 mm/yr) and out-of-sequence motion on the MBT from 0.5 Ma to present reproduce the young cooling ages near the MBT. We show that the dominant control on exhumation patterns in a fold-thrust belt results from the evolution of ramps and emphasize that the geometry and kinematics of structures driving hinterland exhumation need to be evaluated with their linked foreland structures to ensure the viability of the proposed geometry, kinematics and thus cooling history.

Tectonics↗

Petrology of volcanic rocks associated with silver-gold (Ag-Au) epithermal deposits in the Tonopah, Divide, and Goldfield Mining Districts, Nevada

Miocene calc-alkaline volcanic rocks, part of the southern segment of the ancestral Cascades magmatic arc, are spatially, temporally, and likely genetically associated with precious metal epithermal deposits in the Tonopah, Divide, and Goldfield Districts of west-central Nevada. In the Tonopah mining district, volcanic rocks include the Mizpah Trachyte, Fraction Tuff, and Oddie Rhyolite; in the Divide mining district, they include the Heller Tuff, Brougher Rhyolite, trachyandesite of Red Mountain, Divide Andesite, and volcanics of Donovan Peak (which includes rhyolite, dacite, and rhyodacite units); in the Goldfield mining district they include the Milltown Andesite, an unnamed porphyritic andesite, and latite. All these rocks are porphyritic and contain phenocryst assemblages that include plagioclase, pyroxene, hornblende, biotite, quartz, alkali feldspar, and olivine. These mostly subalkaline, metaluminous, calc-alkalic, and magnesian rocks range from basaltic trachyandesite to rhyolite and contain 54 to 78 weight percent silicon dioxide. In the Divide mining district, the Divide Andesite and the volcanics of Donovan Peak are compositionally distinct from volcanic rocks in the other two mining districts. These rocks define a somewhat more restricted range of silicon dioxide content; are more alkalic; have greater titanium dioxide, sodium oxide, barium, hafnium, lanthanum, niobium, tantalum, yttrium, ytterbium, and zirconium abundances; and lower magnesium oxide, strontium, and vanadium abundances. Elevated zirconium contents are particularly characteristic of these rocks, which are also distinctly younger than most of the rocks in the other two mining districts. The alkalic character (principally higher sodium oxide abundances) and elevated zirconium contents characteristic of the Divide Andesite and the volcanics of Donovan Peak suggest that distinctive sources and (or) processes contributed to the petrogenesis of these rocks. In the Tonopah, Divide, and Goldfield mining districts the geochemistry of Oligocene and Miocene volcanic rocks constrain the processes that contributed to the petrogenesis of these rocks. Specifically, major oxide compositional variation among these rocks is consistent with crystallization and fractionation of the observed phenocryst minerals. In addition, these rocks have negatively sloping rare-earth element patterns consistent with partial melting in a high-pressure, garnet stable regime. Elevated strontium concentrations and small negative europium anomalies are consistent with partial melting in a plagioclase-unstable setting. However, larger negative europium anomalies among the more silica-rich volcanic rocks indicates a progressively greater role for plagioclase fractionation among these rocks. The importance of hornblende in the petrogenesis of these rocks is reflected in subtly U-shaped middle rare-earth element pattern segments. Increasing lead/cerium and decreasing phosphorus pentoxide/potassium oxide with increasing silicon dioxide are characteristic of these volcanic rocks. These characteristics and their distinctive pre-Cenozoic xenolith content suggest a significant role for crustal contamination in their petrogenesis. Diagnostic textural features preserved by phenocrysts, especially plagioclase, constitute additional evidence that open-system behavior, including reservoir-scale mixing, recharge, and assimilation, was critical to the petrogenesis of volcanic rocks in the Tonopah, Divide, and Goldfield mining districts.

Nevada↗

Petrographic, geochemical, and geochronologic data for cenozoic volcanic rocks of the Tonopah, Divide, and Goldfield Mining Districts, Nevada

The purpose of this report is to summarize geochemical, petrographic, and geochronologic data for samples, principally those of unmineralized Tertiary volcanic rocks, from the Tonopah, Divide, and Goldfield mining districts of west-central Nevada (fig. 1). Much of the data presented here for the Tonopah and Divide districts are for samples collected by Bonham and Garside (1979) during geologic mapping in and around those districts, whereas much of that for samples from the Goldfield district were obtained by Ashley (1974; 1979; 1990a). Additional data were derived from samples collected between 2012–2015, as part of the Mineral Resources Program funded project titled: “Magmatic-tectonic history and component sources of major precious metal deposits in the southern Walker Lane”. A small amount of additional geochemical data for samples from each of the districts were compiled from other sources. Individual sample collectors are identified by appropriate entries in the “Collector” field (appendix 1) and published sources of geochemical data are defined by entries in the “Chem_Src” data field (appendix 1).

California, Nevada↗

A supervolcano and its sidekicks: A 100 ka eruptive chronology of the Fish Canyon Tuff and associated units of the La Garita magmatic system

Establishing temporal constrains on major volcanic eruptions is limited by the precision of existing geochronometers. Prior work on the La Garita caldera, created by the eruption of the Fish Canyon Tuff, failed to resolve temporal differences between pre-, syn-, and post-collapse eruptive units. Here, we report 40Ar/39Ar geochronologic data supporting a ca. 100 ka eruptive history of the La Garita caldera, and resolving the timing of the precaldera Pagosa Peak Dacite , syncaldera Fish Canyon Tuff, and postcaldera Dacite of Nutras Creek. Minimizing uncertainty in neutron fluence by rotating samples during irradiation and employing Bayesian statistical interpretation of analytical data enables resolution of the ca. 60 ka precaldera eruptive history and a hiatus of 0 - 20 ka prior to the eruption of postcaldera lavas. The improved precision demonstrated using these methods provides previously unresolvable temporal constraints on physical processes in the La Garita magmatic system and underscores the potential of unraveling other closely-spaced events in geologic time.

Geology↗

Multiproxy Cretaceous-Paleogene boundary event stratigraphy: An Umbria-Marche basin-wide perspective

The complete and well-studied pelagic carbonate successions from the Umbria-Marche Basin (Italy) permit the study of the event-rich stratigraphical interval around the Cretaceous-Paleogene (K-Pg) boundary (e.g., Deccan volcanism, boundary impact, Paleocene recovery and climate). To test the robustness of various proxy records (bulk carbonate δ13C, δ18O, 87Sr/86Sr and Ca, Fe, Sr and Mn concentrations) inside the Umbria-Marche basin, several stratigraphically equivalent sections were investigated (Bottaccione Gorge, Contessa Highway, Fornaci East quarry, Frontale, Morello and Petriccio Core). Besides the classical Gubbio sections of Bottaccione and Contessa, the new Morello section is put forward as an alternative location for this stratigraphical interval as it is less altered by burial diagenesis. Elemental profiles (Ca, Fe, Sr, Mn) acquired by handheld X-Ray Fluorescence (pXRF) efficiently provide regional chemostratigraphical and paleoenvironmental information. The Deccan volcanism, the K-Pg boundary, the characteristic pattern of the Sr/Ca profile across the boundary driven by the extinction and recovery of coccolithophores, and the Dan-C2 hyperthermal event are examples of such recorded paleoenvironmental events. Moreover, cyclostratigraphic analyses of proxies of detrital input (magnetic susceptibility and Fe concentrations) show the imprint in the sedimentary record of a 2.4 Myr eccentricity minimum around 66.45-66.25 Ma and suggest that the occurrence of the Dan-C2 hyperthermal event was astronomically paced.

Umbria-Marche basin↗

Revisiting Herto: New evidence of Homo sapiens from Ethiopia

Localities in the radiometrically dated Upper Herto Member of Ethiopia’s Bouri Formation continue to produce new data that complement and extend initial reports of fossils and artifacts published in 2003. Results of these revisits are reported here and include the in situ recovery of artifacts from the same sediments containing hominid fossils. We evaluate the absolute and relative temporal placement of the Herto discoveries in light of new field observations and in the context of new data from the Omo Kibish Formation of southern Ethiopia. The Upper Herto Member stone tool assemblage includes artifacts normally typologically attributed to both Acheulean and Middle Stone Age industries or technocomplexes. These discoveries and other aspects of continuing Herto research help to elucidate the timing and patterns of technological, behavioral, and anatomical change in Africa during the evolution of our species.

Book chapter↗

Geologic map of the San Antonio Mountain area, northern New Mexico and southern Colorado

The geologic map of the San Antonio Mountain area in northern New Mexico and southern Colorado is located along the west-central part of the San Luis Valley. The San Luis Valley is the geomorphic expression of the San Luis Basin, an extensional basin associated with the northern Rio Grande rift. Deposits within the map area record volcanic, sedimentary, and tectonic processes over the last ~33 million years. Oldest exposed deposits include Oligocene volcanic rocks associated with the southeast San Juan Mountains locus of volcanism within the Southern Rocky Mountains volcanic field. Overlying deposits of the Southern Rocky Mountains volcanic field are volcaniclastic sedimentary rocks interbedded with predominantly basaltic lava flows of Oligocene to Miocene age. Basalt to rhyolite volcanic rocks of the Pliocene to Pleistocene Taos Plateau volcanic field unconformably overlie Oligocene to Miocene volcanic and sedimentary deposits. Superposed on the Tertiary deposits are Pleistocene to Holocene alluvial and colluvial deposits. North- to northwest-trending faults displace rocks within the map area. Magnitude of deformation is broadly correlative with age of the deposits inasmuch as Oligocene to Miocene rocks display a greater degree of fault displacement and east tilting than Pliocene volcanic rocks. Within the map area, faults displace Oligocene to Miocene deposits 10–30 meters with generally down-to-west offset, and the units dip eastward 3–7 degrees. Pliocene volcanic rocks exhibit shallower eastward dips inferred primarily from the slope of upper lava flow surfaces that dip eastward from 1–3 degrees and lava flows are generally displaced less than 5 meters.

Colorado, New Mexico↗

Reverse weathering in marine sediments and the geochemical cycle of potassium in seawater: Insights from the K isotopic composition (41K/39K) of deep-sea pore-fluids

In situ Al-silicate formation, also known as “reverse weathering,” is an important sink of many of the major and minor cations in seawater (e.g. Mg, K, and Li). However, the importance of this sink in global geochemical cycles and isotopic budgets of these elements remains poorly constrained. Here, we report on the potassium isotopic composition ( 41 "> 41 K/ 39 "> 39 K) of deep-sea sediment pore-fluids from four (Integrated) Ocean Drilling Program sites (1052, U1378, U1395 and U1403) to characterize potassium isotopic fractionation associated with the formation of authigenic Al-silicate minerals in marine sediments and its role in elevating the 41 "> 41 K/ 39 "> 39 K of seawater relative to bulk silicate Earth. Isotopic ratios are obtained by high-resolution multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) in cold plasma conditions with a long-term external reproducibility of ca. 0.17‰. We find that, although all sites are characterized by pore-fluid K concentrations that decline with increasing depth, their K isotopic profiles vary systematically from site-to-site; at sites characterized by rapid sedimentation rates , pore-fluid profiles of 41 "> 41 K/ 39 "> 39 K are relatively invariant whereas at sites characterized by slow sedimentation rates, 41 "> 41 K/ 39 "> 39 K declines with depth by up to 1.8‰. Results from 1-D diffusion-advection-reaction models suggest that these differences may result from a complex interplay between sedimentation rate and fractionation of K isotopes during diffusion, Al-silicate authigenesis , and ion exchange. Model simulations suggest fractionation factors between 0.9980 and 1.0000 for reverse weathering reactions in deep-sea sediments. Although deep-sea sites do not constitute major sinks of K in seawater, some of the processes responsible for K isotopic fractionation at these sites (diffusion and Al-silicate authigenesis) likely play a role in determining the 41 "> 41 K/ 39 "> 39 K of seawater.

Geochimica et Cosmochimica Acta↗

High-precision 41K/39K measurements by MC-ICP-MS indicate terrestrial variability of δ41K

Potassium is a major component in continental crust, the fourth-most abundant cation in seawater, and a key element in biological processes. Until recently, difficulties with existing analytical techniques hindered our ability to identify natural isotopic variability of potassium isotopes in terrestrial materials. However, measurement precision has greatly improved and a range of K isotopic compositions has now been demonstrated in natural samples. In this study, we present a new technique for high-precision measurement of K isotopic ratios using high-resolution, cold plasma multi-collector mass spectrometry. We apply this technique to demonstrate natural variability in the ratio of 41 K to 39 K in a diverse group of geological and biological samples, including silicate and evaporite minerals, seawater, and plant and animal tissues. The total range in 41 K/ 39 K ratios is ca. 2.6‰, with a long-term external reproducibility of 0.17‰ (2, N=108). Seawater and seawater-derived evaporite minerals are systematically enriched in 41 K compared to silicate minerals by ca. 0.6‰, a result consistent with recent findings1, 2. Although our average bulk-silicate Earth value (-0.54‰) is indistinguishable from previously published values, we find systematic δ 41 K variability in some high-temperature sample suites, particularly those with evidence for the presence of fluids. The δ 41 K values of biological samples span a range of ca. 1.2‰ between terrestrial mammals, plants, and marine organisms. Implications of terrestrial K isotope variability for the atomic weight of K and K-based geochronology are discussed. Our results indicate that high-precision measurements of stable K isotopes, made using commercially available mass spectrometers, can provide unique insights into the chemistry of potassium in geological and biological systems.

Journal of Analytical Atomic Spectrometry↗

40Ar/39Ar geochronology and petrogenesis of the Table Mountain Shoshonite, Golden, Colorado, U.S.A.

The Upper Cretaceous and Lower Paleogene Table Mountain Shoshonite lava flows and their proposed source, the Ralston Buttes intrusions, provide insight into the volcanic history of the Colorado Front Range. This study affirms the long-held hypothesis linking the extrusive Table Mountain lava flows and their intrusive equivalents at Ralston Buttes through major- and trace- element geochemistry. Systematic 40 Ar/ 39 Ar geochronology from all flows and intrusive units refines the eruptive history, improves precision on previously reported ages, and provides tighter constraints on the position of the K-Pg boundary in this location. Four flows are recognized on North and South Table mountains outside of Golden, Colorado. Flow 1 (66.5 ± 0.3 Ma, all ages reported with 2σ uncertainty) is the oldest, most compositionally distinct flow and is separated from younger flows by approximately 35 m of sedimentary deposits of the Denver Formation. Stratigraphically adjacent flows 2 (65.8 ± 0.2 Ma), 3 (65.5 ± 0.3 Ma), and 4 (65.9 ± 0.3 Ma) are compositionally indistinguishable. Lavas (referred to here as unit 5) that form three cone-shaped structures (shown by this study to be volcanic vents of a new unit 5) on top of North Table Mountain are compositionally similar to other units, but yield an age almost 20 m.y. younger (46.94 ± 0.15 Ma). Geochemistry and geochronology suggest that the rim phase of the Ralston plug (65.4 ± 0.2 Ma) is a reasonable source for flows 2, 3, and 4. All units are shoshonites—potassic basalts containing plagioclase, augite, olivine, and magnetite phenocrysts—and plot in the continental-arc field in tectonic discrimination diagrams. A continental-arc setting coupled with Late Cretaceous to early Paleogene ages suggest the high-K magmatism is associated with Laramide tectonism.

Colorado↗