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Leah E. Morgan

Publications and source records attributed to Leah E. Morgan.

42 records · Page 3Linked to original sources

Elemental, isotopic, and geochronological variability in Mogollon-Datil volcanic province archaeological obsidian, southwestern USA: Solving issues of intersource discrimination

Solving issues of intersource discrimination in archaeological obsidian is a recurring problem in geoarchaeological investigation, particularly since the number of known sources of archaeological obsidian worldwide has grown nearly exponentially in the last few decades, and the complexity of archaeological questions asked has grown equally so. These two parallel aspects of archaeological investigation have required more exacting understanding of the geological relationship between sources and the more accurate analysis of these sources of archaeological obsidian. This is particularly the case in the North American Southwest where the frequency of archaeological investigation is some of the highest in the world, and the theory and method used to interpret that record has become increasingly nuanced. Here, we attempt to unravel the elemental similarity of archaeological obsidian in the Mogollon-Datil volcanic province of southwestern New Mexico where some of the most important and extensively distributed sources are located and the elemental similarity between the sources is great even though the distance between the sources is large. Uniting elemental, isotopic, and geochronological analyses as an intensive pilot study, we unpack this complexity to provide greater understanding of these important sources of archaeological obsidian.

New Mexico↗

Characteristics and 40Ar/39Ar geochronology of the Erdenet Cu-Mo deposit, Mongolia

The Early to Middle Triassic Erdenet porphyry Cu-Mo deposit, in northern Mongolia, developed in a continent-continent arc collision zone, within the Central Asian orogenic belt. The porphyry system is related to multiple intrusions of crystal-crowded biotite granodiorite porphyry, which formed a composite stock about 900 m in diameter, with multiple porphyritic microgranodiorite dikes. Wall rocks are Late Permian to Early Triassic, medium-grained granodiorite, with similar whole-rock geochemistry, mineralogy, and composition to the granodiorite porphyry. Whole-rock analysis of the granodiorite porphyry and wall rocks shows that these rocks cannot be discriminated, but both have depleted middle heavy rare earth elements and Y, typical of fertile porphyry magmatic suites. At the current pit level (1,250 m elev), early porphyry-style quartz veins (A and B type) are locally infilled by pyrite-chalcopyrite, with subordinate bornite, but most of the chalcopyrite occurs in D veins that constitute more than 50% of the Cu grade (~0.5 wt % Cu). The 0.3 wt % Cu shell resembles a molar tooth, enveloping the granodiorite porphyry, with deeper roots extending down the wal-rock contacts. Molybdenite occurs in monomineralic veins, and in finely laminated to massive quartz-molybdenite veins. The most important alteration is quartz-muscovite, which occurs as relatively coarse (100–500 μ m) alteration selvages (1–5 cm) that envelop D veins. The D veins cut illite ± kaolinite-smectite (or intermediate argillic) alteration. Intermediate argillic alteration, together with abundant pink anhydrite (commonly hydrated to gypsum), extends from at least 1,300- to 900-m elevation in the deepest drill holes, and has overprinted early potassic alteration, or relatively unaltered red granodiorite. Meter-wide zones of kaolinite cut the anhydrite-gypsum at all levels. There is an abrupt transition outward from the intermediate argillic alteration to chlorite-epidote (propylitic) alteration, at 50 to 200 m from the granodiorite porphyry contact, although D veins (and chalcopyrite) extend outward to the propylitic zone. The Erdenet porphyry system, was overprinted by advanced argillic alteration, which outcrops 2 km northwest of the pit, and forms a lithocap that extends over 10 × 2.5 km. It is characterized by residual quartz, andalusite, Na-Ca and K-alunite, diaspore, pyrophyllite, zunyite, topaz, dickite, and kaolinite. The upper part of the porphyry Cu-Mo deposit (removed by mining), comprised a bornite-chalcocite enriched zone up to 300 m thick with an average grade of 0.7 wt % Cu and up to 5 wt % Cu locally. Based on hypogene bornite-chalcocite mineral textures and high-sulfidation state mineralogy, the enriched zone is inferred to be of hypogene origin, but modified by supergene processes. Consequently, it may be related to formation of the lithocap. Previous Re-Os dates of 240.4 and 240.7 ± 0.8 Ma for molybdenite in quartz veins are comparable to new 40 Ar/ 39 Ar dates of 239.7 ± 1.6 and 240 ± 2 Ma for muscovite that envelops D veins. One 40 Ar/ 39 Ar date on K-alunite from the lithocap of 223.5 ± 1.9 Ma suggests that it may be about 16 m.y. younger than Erdenet, but this result needs to be verified by further dating.

Economic Geology↗

Instrumentation development for In Situ 40Ar/39Ar planetary geochronology

The chronology of the Solar System, particularly the timing of formation of extra-terrestrial bodies and their features, is an outstanding problem in planetary science. Although various chronological methods for in situ geochronology have been proposed (e.g., Rb-Sr, K-Ar), and even applied (K-Ar), the reliability, accuracy, and applicability of the 40 Ar/ 39 Ar method makes it by far the most desirable chronometer for dating extra-terrestrial bodies. The method however relies on the neutron irradiation of samples, and thus a neutron source. Herein, we discuss the challenges and feasibility of deploying a passive neutron source to planetary surfaces for the in situ application of the 40 Ar/ 39 Ar chronometer. Requirements in generating and shielding neutrons, as well as analysing samples are described, along with an exploration of limitations such as mass, power and cost. Two potential solutions for the in situ extra-terrestrial deployment of the 40 Ar/ 39 Ar method are presented. Although this represents a challenging task, developing the technology to apply the 40 Ar/ 39 Ar method on planetary surfaces would represent a major advance towards constraining the timescale of solar system formation and evolution.

Geostandards and Geoanalytical Research↗

Episodic formation of the world-class Waihi epithermal Au-Ag vein system, Hauraki Goldfield, New Zealand

The world-class Waihi vein system in New Zealand has produced more than 248,400 kg Au and 1.43 million kg Ag. New high-precision 40Ar/39Ar dates of adularia from different veins show that some veins formed at different times (6.15 Ma Martha vs. 5.83 and 5.85 Ma Empire and Welcome, respectively), even though they have similar mineralogy. The Martha vein formed over a period of approximately 150,000 years. The Moonlight vein, which has a different ore mineral assemblage, appears to have formed over a longer time interval that spanned formation of the Martha, Welcome, and Empire veins. These dates suggest that some veins in the Waihi vein system formed relatively quickly during only part of the lifetime of the hydrothermal system, whereas other veins may have formed over longer periods of time. However, the Au endowment of the Martha vein exceeds the Au endowment of the Moonlight vein, indicating that the total lifetime of the vein-forming hydrothermal system does not determine metal endowment.

Conference Paper↗

Preservation of ancient impact ages on the R chondrite parent body: 40 Ar/ 39 Ar age of hornblende-bearing R chondrite LAP 04840

The hornblende- and biotite-bearing R chondrite LAP 04840 is a rare kind of meteorite possibly containing outer solar system water stored during metamorphism or postshock annealing deep within an asteroid. Because little is known regarding its age and origin, we determined 40 Ar/ 39 Ar ages on hornblende-rich separates of the meteorite, and obtained plateau ages of 4340(±40) to 4380(±30) Ma. These well-defined plateau ages, coupled with evidence for postshock annealing, indicate this meteorite records an ancient shock event and subsequent annealing. The age of 4340–4380 Ma (or 4.34–4.38 Ga) for this and other previously dated R chondrites is much older than most impact events recorded by ordinary chondrites and points to an ancient event or events that predated the late heavy bombardment that is recorded in so many meteorites and lunar samples.

Meteoritics and Planetary Science↗

Pressure disequilibria induced by rapid valve closure in noble gas extraction lines

Pressure disequilibria during rapid valve closures can affect calculated molar quantities for a range of gas abundance measurements (e.g., K-Ar geochronology, (U-Th)/He geochronology, noble gas cosmogenic chronology). Modeling indicates this effect in a system with a 10 L reservoir reaches a bias of 1% before 1000 pipette aliquants have been removed from the system, and a bias of 10% before 10,000 aliquants. Herein we explore the causes and effects of this problem, which is the result of volume changes during valve closure. We also present a solution in the form of an electropneumatic pressure regulator that can precisely control valve motion. This solution reduces the effect to ∼0.3% even after 10,000 aliquants have been removed from a 10 L reservoir.

Geochemistry, Geophysics, Geosystems↗