Geology Reports⌕ Search

Geology topics

Leah E. Morgan

Publications and source records attributed to Leah E. Morgan.

At least 19 recordsLinked to original sources

USGS Geochron—A database of geochronological and thermochronological dates and data—Technical documentation

Geochronological and thermochronological data are essential for constraining the timing and rates of geological processes, supporting geologic mapping, natural hazard assessment, and resource exploration. The U.S. Geological Survey (USGS) Geochron Database is a centralized, relational database that integrates USGS and State geological survey data in accordance with the National Geologic Mapping Act of 1992 and its reauthorizations. This report documents the structure and development of the database, including its standardized schema, controlled vocabularies, and protocols for compiling legacy and newly published data. The database is designed to adhere to FAIR (Findable, Accessible, Interoperable, and Reusable) data principles and currently (2026) includes data from a wide range of geochronological and thermochronological methods. Public access is provided through the USGS Geochron Database Explorer, a browser-based geographic information system (GIS) interface, and through versioned data releases available on ScienceBase, which provide sample-level summary data and detailed analytical information. The USGS Geochron Database is structured to be extensible, supporting the inclusion of additional methods and data types as they are compiled. This format ensures long-term utility and aligns with the Mapping Act’s directive to create a national archive of geochronological information that adds interpretive value to geologic map data. Its design reflects a commitment to data transparency, scientific reproducibility, and national geoscience priorities.

Data Report↗

USGS Geochron Database

Introduction Geochronology helps us understand Earth’s history by determining when important events, like volcanic eruptions, the rise of mountains, the formation of mineral resources, and changes in the landscape, happened. Geochronological data directly support geologic mapping and can inform decisions about geologic hazard mitigation, natural resource management, and infrastructure resilience. The U.S. Geological Survey (USGS) Geochron database provides access to more than 300,000 published, publicly available age measurements from more than 40,000 geological samples. This database is the result of a collaborative effort with State geological surveys and geoscientists from across the globe. The USGS Geochron database is the most comprehensive collection of geochronological data available for the United States. Users can view data through an interactive map explorer, download datasets, and integrate data into geospatial software or other analysis tools.

Fact Sheet↗

Utilization of multiple geochronology techniques to constrain the age of laterization and mineralization of the world-class Mount Weld rare earth element deposit, Western Australia

Pervasive chemical weathering on stable cratons may form thick regoliths and elemental enrichment, but constraining the age of regolith formation is challenging. In this study we utilize multiple geochronological techniques on different minerals from the world-class Mount Weld rare earth element (REE) deposit, formed by lateritic weathering of a carbonatite, to constrain the age of formation and provide insight into landscape evolution. The oldest dates, ca. 100 to 38 Ma, are from Lu-Hf dating of churchite [HREE(PO 4 )·2(H 2 O)], a heavy REE phosphate mineral. Growth bands on individual minerals show a younging outwards. 40 Ar/ 39 Ar geochronology of cryptomelane [K(Mn 4+ ,Mn 2+ )₈O₁₆] yielded dates from ca. 40 to 27 Ma. Similarly, (U-Th)/He geochronology of goethite [FeO(OH)] yielded dates ranging from ca. 45 to 19 Ma. Integrating results into regional constraints, suggests 1) churchite formed by mineral saturation in a karst-like setting below the water table from ca. 100 to 40 Ma, 2) with minor uplift and erosion, cryptomelane and goethite formed at or near the water table between ca. 45 and 19 Ma, 3) after ca. 15 to 10 Ma chemical weathering within the profile had ended. Other studies document that the region experienced minimal uplift and a wet, warm climate from ca. 100 Ma to 15 Ma. These conditions and the high carbonate content of the carbonatite promote extensive chemical weathering, a deep weathering profile, and the preservation of the weathered section. This study highlights the use of multiple geochronological techniques utilizing different minerals to provide insight into how laterites form and to constrain the timing and history of the formation of this important mineral deposit.

Western Australia↗

Constraining the onset of carboniferous cyclicity in the Arkoma Basin of the Midcontinent, North America: Implications for calibrating a globally significant latest Bashkirian transgression

Cyclothems are defined by the repeat juxtaposition of littoral and open marine successions over short stratigraphic distances (meters to 10's of meters) and are interpreted to be driven by glacioeustatic forcing of sea level during the late Paleozoic Ice Age. The concept of cyclothems was defined in the Midcontinent region of the United States. However, correlating the Midcontinent region to other cyclic successions is difficult, which is the result of no geochronologic control for the Midcontinent biostratigraphic framework. We present the first high-resolution U Pb zircon CA-ID-TIMS and feldspar 40 Ar/ 39 Ar age control for the onset of Midcontinent cyclothem deposition in the Arkoma Basin, Arkansas USA. Geochronologic control is obtained from a volcaniclastic unit preserved in the newly recovered Dare Creek #1 core. We integrate these data with biostratigraphic, lithostratigraphic and trace element analyses to investigate the timing, stratigraphic and geochemical response to late Paleozoic climate forcing. The lowermost Atoka Formation is associated with the onset of five high frequency transgressive-regressive cycles, which are defined by nearshore sandstones juxtaposed on top of offshore marine mudstones and are associated with changes in salinity and redox conditions. The Trace Creek Member of the lower Atoka Formation hosts a thick, organic-rich black shale, which defines the last and maximum transgression of the lower Atoka Formation in the Arkoma Basin, in the latest Bashkirian. Base-level records from time equivalent stratigraphic successions from Arrow Canyon, Nevada, U.S.A. and the Donets Basin, Ukraine also record a maximum transgression in the latest Bashkirian. The synchroneity of maximum flooding events from multiple basins which span the low latitudes in the latest Bashkirian support that cyclothem deposition was controlled by allostratigraphic forcing mechanisms, likely glacioeustatic forcing resulting from dynamic glaciation in high-latitude Gondwana.

Arkansas, Oklahoma↗

Bayesian calibration of the 40K decay scheme with implications for 40K-based geochronology

The K/Ar and 40 Ar/ 39 Ar geochronometers are based on the naturally occurring radionuclide 40 K. Their precision and accuracy are limited by uncertainties on the 40 K decay constants and, in the case of the 40 Ar/ 39 Ar geochronometer, the isotopic composition of neutron fluence monitors. To address these limitations, we introduce a Bayesian calibration of the 40 K decay scheme. We formulate robust priors for all model parameters including partial 40 K decay constants, 238 U and 235 U decay constants, and age offset parameters to account for phenomena that can perturb apparent U-Pb and 40 Ar/ 39 Ar ages. We then harness a set of complementary 40 Ar/ 39 Ar, 238 U/ 206 Pb, and 235 U/ 207 Pb data from well- characterized geological samples with ages from 1.919 ka to 2000 Ma to derive Bayesian estimates of the 40 K decay constants. Posterior values for the partial 40 K decay constants are λ β - "> λ β - = (4.9252 ± "> ± 0.0054) × "> × 10 −10 yr −1 , λ β + "> λ β + = (5.6658 ± "> ± 0.1543) × "> × 10 −15 yr −1 , λ EC ∗ "> λ EC0 = (5.7404 ± "> ± 0.0053) × "> × 10 −11 yr −1 , and λ EC 0 "> λ EC0 = (4.9060 ± "> ± 0.2942) × "> × 10 −13 yr −1 (uncertainties reported at the 68 % (1 σ "> σ ) credible interval). These combine to a total 40 K decay constant λ tot "> λ tot = (5.5042 ± "> ± 0.0054) × "> × 10 −10 yr −1 . Model estimates of the 238 U and 235 U decay constants are statistically indistinguishable from those reported by Jaffey et al. (1971) . Posterior values of the 40 K decay constants and the 40 Ar*/ 40 K isotopic composition of Fish Canyon sanidine (FCs) define a K/Ar FCs age of 28.183 ± "> ± 0.017 Ma (1 σ "> σ ). Significantly, Bayesian calibrated 40 Ar/ 39 Ar ages align with astronomically tuned ages throughout the Cenozoic and with 238 U/ 206 Pb and 235 U/ 207 Pb ages in the Mesozoic, Paleozoic, and Proterozoic, as well as having comparable precision to the 238 U/ 206 Pb method. Thus, Bayesian calibration of the 40 K decay scheme and the K/Ar age of FCs reconciles the 40 Ar/ 39 Ar, U-Pb, and astronomical chronometers.

Geochimica et Cosmochimica Acta↗

Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho

The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.

Idaho↗

Enhancing mineral systems exploration through geochronology, thermochronology, and isotope analysis: USGS Geochron and USGS Isotope databases

A mineral systems approach to mineral exploration provides a comprehensive framework for understanding ore deposit formation by examining the geodynamic, magmatic, hydrothermal, and sedimentary processes responsible for mineralization, alteration, and remobilization of economic mineral deposits. Temporal and thermal constraints on ore genesis are crucial for refining mineral system models and guiding predictive exploration strategies. Geochronology and thermochronology offer invaluable insights into the timing and thermal evolution of ore-forming processes, whereas isotopic analyses provide critical information on the source and geochemical history of ore-forming fluids. Combining these methodologies have proven highly effective for mineral exploration in regions like Australia, however, their combined application has been limited in the United States. To apply these tools to mineral systems-based exploration, the U.S. Geological Survey (USGS) has developed two products: (1) The USGS Geochron Database, and (2) the USGS Isotope Database. These databases provide centralized repositories of geo/thermochronological dates and data (Geochron Database) and both radiogenic and stable isotope data (Isotope Database) generated by the USGS and partners over the past decades. Integrating these datasets together and with traditional exploration approaches provides the mineral exploration community with powerful tools for determining the temporal and thermal histories of ore systems and identifying metallogenic source provinces.

Continental United States↗

40Ar/39Ar geochronology supporting mineral resources research at USGS Denver

The 40 Ar/ 39 Ar geochronology method is used to date potassium-bearing rocks and minerals, based on the decay of 40 K to 40 Ar, which provides important temporal constraints for geological events. The USGS Denver Argon Geochronology Laboratory dates samples from a variety of projects, mainly in the USGS Mineral Resource Program and the National Cooperative Geologic Mapping Program, facilitating in-depth research into the timing of geological events and processes. Recent applications of this method include geochronological studies in the Yellow Pine district, revealing mineralization ages that range from 51 to 70 Ma, and investigations into the Bear Lodge alkaline complex, providing insights into the timing of REE carbonatite formation. Additionally, studies at Alunite Ridge highlight the method's potential for understanding concealed mineral deposits. Ongoing projects continue to leverage 40 Ar/ 39 Ar data to enhance understanding of geologic frameworks and mineral resources, underpinning its importance in modern geochronology and mineral resource assessment.

Conference Paper↗

Mantle melting in regions of thick continental lithosphere: Examples from Late Cretaceous and younger volcanic rocks, Southern Rocky Mountains, Colorado (USA)

Major- and trace-element data together with Nd and Sr isotopic compositions and 40 Ar/ 39 Ar age determinations were obtained for Late Cretaceous and younger volcanic rocks from north-central Colorado, USA, in the Southern Rocky Mountains to assess the sources of mantle-derived melts in a region underlain by thick (≥150 km) continental lithosphere. Trachybasalt to trachyandesite lava flows and volcanic cobbles of the Upper Cretaceous Windy Gap Volcanic Member of the Middle Park Formation have low εNd(t) values from −3.4 to −13, 87 Sr/ 86 Sr(t) from ~0.705 to ~0.707, high large ion lithophile element/high field strength element ratios, and low Ta/Th (≤0.2) values. These characteristics are consistent with the production of mafic melts during the Late Cretaceous to early Cenozoic Laramide orogeny through flux melting of asthenosphere above shallowly subducting and dehydrating oceanic lithosphere of the Farallon plate, followed by the interaction of these melts with preexisting, low εNd(t), continental lithospheric mantle during ascent. This scenario requires that asthenospheric melting occurred beneath continental lithosphere as thick as 200 km, in accordance with mantle xenoliths entrained in localized Devonian-age kimberlites. Such depths are consistent with the abundances of heavy rare earth elements (Yb, Sc) in the Laramide volcanic rocks, which require parental melts derived from garnet-bearing mantle source rocks. New 40 Ar/ 39 Ar ages from the Rabbit Ears and Elkhead Mountains volcanic fields confirm that mafic magmatism was reestablished in this region ca. 28 Ma after a hiatus of over 30 m.y. and that the locus of volcanism migrated to the west through time. These rocks have εNd(t) and 87 Sr/ 86 Sr(t) values equivalent to their older counterparts (−3.5 to −13 and 0.7038–0.7060, respectively), but they have higher average chondrite-normalized La/Yb values (~22 vs. ~10), and, for the Rabbit Ears volcanic field, higher and more variable Ta/Th values (0.29–0.43). The latter are general characteristics of all other post– 40 Ma volcanic rocks in north-central Colorado for which literature data are available. Transitions from low to intermediate Ta/Th mafic volcanism occurred diachronously across southwest North America and are interpreted to have been a consequence of melting of continental lithospheric mantle previously metasomatized by aqueous fluids derived from the underthrusted Farallon plate. Melting occurred as remnants of the Farallon plate were removed and the continental lithospheric mantle was conductively heated by upwelling asthenosphere. A similar model can be applied to post–40 Ma magmatism in north-central Colorado, with periodic, east to west, removal of stranded remnants of the Farallon plate from the base of the continental lithospheric mantle accounting for the production, and western migration, of volcanism. The estimated depth of the lithosphere-asthenosphere boundary in north-central Colorado (~150 km) indicates that the lithosphere remains too thick to allow widespread melting of upwelling asthenosphere even after lithospheric thinning in the Cenozoic. The preservation of thick continental lithospheric mantle may account for the absence of oceanic-island basalt–like basaltic volcanism (high Ta/Th values of ~1 and εNd[t] > 0), in contrast to areas of southwest North America that experienced larger-magnitude extension and lithosphere thinning, where oceanic-island basalt–like late Cenozoic basalts are common.

Geosphere↗

Paleogene sedimentary basin development in southern Nevada, USA

The cause of the transition from Mesozoic and early Cenozoic crustal shortening to later extension in the western United States is debated. In many parts of the extant Sevier hinterland, now the Basin and Range Province, the sedimentary sections that provide the most direct record of that transition remain poorly studied and lack meaningful age control. In this paper, we present field characterization supported by U-Pb detrital zircon and 40 Ar/ 39 Ar feldspar ages for ten sections across southern Nevada. We describe a newly identified basin, here named the Fallout Hills basin, which preserves >1.0 km of sedimentary deposits as old as middle Eocene, ca. 48 Ma. Deposition occurred during the 20 m.y. (million years) before the 27.60 ± 0.03 Ma Monotony Tuff blanketed much of south-central Nevada, based on 47.6 Ma and younger detrital zircon maximum depositional ages (MDAs) from near the Pintwater and Spotted Ranges. Elsewhere in southern Nevada, prevolcanic Cenozoic strata commonly form thinner (~100 m), isolated exposures that yield detrital zircon MDAs ≤10 m.y. older than (and in some cases essentially the same age as) the ca. 27–28 Ma ignimbrites that cap the sections. A variable but overall upward-fining facies pattern is observed in both the Fallout Hills basin and the thinner sections. These localized patterns imply topographic changes that are unlikely to reflect plate-scale processes and are not consistent with large-magnitude extension. Instead, variable uplift due to magmatism combined with antecedent topographic relief from thrust faulting and subsequent erosion likely provided accommodation for these deposits.

Nevada↗

Kesem-Kebena-Dulecha study area, Ethiopia

In 1988 and 1989, the Paleoanthropological Inventory of Ethiopia (PIE) field expedition discovered numerous localities of prehistoric significance across Ethiopia (WoldeGabriel et al., 1992). One of the regions surveyed by the Inventory team was the Dulecha administrative district (Gabi Rasu), Afar Zone (Fig. 1). The surveyed area (geographic reference: 9.407° N, 40.057° E) includes the watershed vicinity of the Kesem and Kebena Rivers (tributaries of the Awash River) where Plio-Pleistocene outcrops flank the Awash floodplain parallel to the river and west of the Dofan Volcano. The Fentale Vlcano lies SSW of the Kesem-Kebena-Dulecha area, immediately south of where the Main Ethiopian Rift opens into a floodplain, and offset drainages north of the Dulecha River delimit the area on the north. The Kesem-Kebena-Dulecha area was unknown paleoanthropologically prior to the PIE’s fieldwork, which designated localities with KK (Kesem Kebena) and a unique integer for the locality. The PIE named localities from KK 1 to KK 7, ranging in age from Pliocene (KK 1 and KK 2) through later Pleistocene. Localities are identified by the white, numbered circles on Fig. 1. We continue to follow the nomenclature established by the PIE for consistency’s sake. The most significant discovery of the PIE was the Acheulean lithic and faunal assemblages at the KK 6 locality (Table 1). The PIE took several geological samples, and those from the KK 6 area date to c. 1.0 million years ago (Ma), nearly identical in age to the Harreya Pumice Unit of the Daka Member of the Bouri Formation (Gilbert & Asfaw, 2008).

Book chapter↗

First observation of the ground-state electron-capture of 40K

Potassium-40 is a widespread, naturally occurring isotope whose radioactivity impacts estimated geological ages spanning billions of years, nuclear structure theory, and subatomic rare-event searches—including those for dark matter and neutrinoless double-beta decay. The decays of this long-lived isotope must be precisely known for its use as a geochronometer, and to account for its presence in low-background experiments. There are several known decay modes for potassium-40, but a predicted electron-capture decay directly to the ground state of argon-40 has never been observed. The existence of this decay mode impacts several fields, while theoretical predictions span an order of magnitude. Here we report on the first, successful observation of this rare decay mode, obtained by the KDK (potassium decay) Collaboration using a novel combination of a low-threshold x-ray detector surrounded by a tonne-scale, high-efficiency γ -ray tagger at Oak Ridge National Laboratory. A blinded analysis reveals a distinctly nonzero ratio of intensities of ground-state electron-captures ( I EC 0 ) over excited-state ones ( I EC ∗ ) of I EC 0 / I EC ∗ = 0.0095 stat ± 0.0022 sys ± 0.0010 (68% CL), with the null hypothesis rejected at 4 σ [Stukel et al. , Phys. Rev. Lett. 131 , 052503 (2023) ]. In terms of branching ratio, this unambiguous signal yields I EC 0 = 0.098 % stat ± 0.023 % sys ± 0.010 % , roughly half of the commonly used prediction. This first observation of a third-forbidden unique electron capture improves our understanding of low-energy backgrounds in dark-matter searches and has implications for nuclear-structure calculations. For example, a shell-model based theoretical estimate for the neutrinoless double-beta decay half-life of calcium-48 is increased by a factor of 7 + 3 − 2 . Our nonzero measurement shifts geochronological ages by up to a percent; implications are illustrated for Earth and solar system chronologies.

Physical Review C↗

Rare 40K decay with implications for fundamental physics and geochronology

Potassium-40 is a widespread, naturally occurring isotope whose radioactivity impacts subatomic rare-event searches, nuclear structure theory, and estimated geological ages. A predicted electron-capture decay directly to the ground state of argon-40 has never been observed. The KDK (potassium decay) collaboration reports strong evidence of this rare decay mode. A blinded analysis reveals a nonzero ratio of intensities of ground-state electron-captures ( I EC 0 ) over excited-state ones ( I EC ∗ ) of I EC 0 / I EC ∗ = 0.0095 stat ± 0.0022 sys ± 0.0010 (68% C.L.), with the null hypothesis rejected at 4 σ . In terms of branching ratio, this signal yields I EC 0 = 0.098 % stat ± 0.023 % sys ± 0.010 % , roughly half of the commonly used prediction, with consequences for various fields [L. Hariasz et al. , companion paper, Phys. Rev. C 108 , 014327 (2023) ].

Physical Review Letters↗

Community for data integration 2019 project report

The U.S. Geological Survey Community for Data Integration annually supports small projects focusing on data integration for interdisciplinary research, innovative data management, and demonstration of new technologies. This report provides a summary of the 14 projects supported in fiscal year 2019 and outlines their goals, activities, and accomplishments. Proposals in 2019 were encouraged to address the optional disciplinary theme of biosurveillance of emerging invasive species and health threats.

Open-File Report↗

Geologic map and hydrogeologic investigations of the upper Santa Cruz River basin, southern Arizona

This report includes an updated geologic map and cross sections of the upper Santa Cruz River basin, southern Arizona. The map and cross sections describe the geometry, thickness, and structure of the Miocene to Holocene units which form the main aquifers in the basin. The report also includes results of new hydrogeologic studies including (1) mapping and defining depth to bedrock based on geophysical data in the map area to better define the geometry and structure of the basin aquifers, (2) describing newly recognized hydrologically significant faults in the Peck Canyon and Sopori Wash areas, and (3) evaluating groundwater sources and hydrogeology of the Potrero Creek wetlands.

Arizona↗

Constraints on near-ridge magmatism using 40Ar/39Ar geochronology of enriched MORB from the 8°20' N seamount chain

Our understanding of the spatial-temporal-compositional relationships between off-axis magmatism and mid-ocean ridge spreading centers is limited. Determining the 40 Ar/ 39 Ar ages of mid-ocean ridge basalt (MORB) lavas erupting near mid-ocean ridges (MOR) has been a challenge due to the characteristically low K 2 O contents in incompatible element-depleted normal MORB (NMORB). High-precision 40 Ar/ 39 Ar geochronology is used here to determine ages of young, basaltic lavas erupted along the 8°20' N seamount chain west of the East Pacific Rise (EPR) axis that have a range of incompatible element enrichments (EMORB) suitable for 40 Ar/ 39 Ar geochronology (e.g., K 2 O contents > 0.3 wt%). 40 Ar/ 39 Ar ages were determined in 29 well-characterized basalts sampled using HOV Alvin and dredging. Detailed geochronology and geochemical analyses provide important constraints on the timing, distribution, and origins of lavas that constructed this extensive volcanic lineament relative to magmatism beneath the adjacent EPR axis. Seamount eruption ages are up to ∼1.6 Ma younger than the underlying lithosphere, supporting a model of prolonged off-axis magmatism for at least 2 Myrs at distances as great as ∼90 km from the ridge axis. Increasing geochemical heterogeneity with eruption distance reflects the diminishing effect of sub-ridge melt focusing. The range of geochemically distinct lavas erupted at given distances from the ridge highlights the dynamic nature of the near-ridge magmatic environment over Myr timescales. Linear ridge-like (EPR-parallel) morphotectonic features erupt the youngest and most incompatible element-enriched lavas of the entire seamount chain, indicating there is a recent change in the influence of mantle heterogeneity and off-axis melt metasomatism on the near-ridge lithospheric mantle. Changes in seamount morphologies are attributed to counter-clockwise rotation and southward migration of the nearby Siqueiros transform over the last few million years.

Earth and Planetary Science Letters↗

Potassium-39-derived 36Ar production during fission-neutron irradiation and its effect on 40Ar/39Ar ages

Various interference reactions producing unwanted Ar isotopes from K, Ca, Cl and Ar require correction to satisfy the 40 Ar/ 39 Ar age equation. Using GEANT4, we design and build a model Cadmium Lined In Core Irradiation Tube (CLICIT) irradiation facility, as used in the Oregon State TRIGA Reactor (OSTR). We illustrate the complexity of the irradiation of geologic samples within this framework and determine an overlooked production channel of 36 Ar. The production of 36 Ar is fed from the 39 K(n, α ) 36 Cl nuclear channel, 36 Cl subsequently decays to 36 Ar ( 39 K(n, α, β ) 36 Ar). Simulations in this work using a 235 U fission neutron energy spectrum and modelled CLICIT facility, determine a production ratio for this reaction ( 36 Cl/ 39 Ar) K = 0.40 ± 0.01 (1 σ ); greater than an order of magnitude larger than any other K interference. The magnitude of the resulting age bias for an unknown sample will be a function of the integrated neutron flux, the length of irradiation (fluence), the time elapsed since irradiation, and the age relationship between the unknown and neutron fluence monitor. We show using the raw data of (Niespolo et al., 2017) that the age of Alder Creek sanidine can be modified to be ca. 0.1% older (1 σ ), at the 2σ level of current analytical precision for the Alder Creek age for this study. The 39 K(n, α , β ) 36 Ar inference should be incorporated into routine data analysis and may be especially important in the intercalibration of the 40 Ar/ 39 Ar system with other chronometers (e.g., 206 Pb/ 238 U).

Geochimica et Cosmochimica Acta↗

First principles calibration of 40Ar abundances in 40Ar/39Ar mineral neutron fluence monitors: Methodology and preliminary results

The accuracy and traceability of geochronometers are of vital importance to questions asked by many Earth scientists. The widely applied 40 Ar/ 39 Ar geochronometer relies on the co-irradiation of samples with neutron fluence monitors (reference materials) of known ages; the ages and uncertainties of these monitors are critical to our ability to apply this chronometer. Previously, first principles, astronomical and optimisation calibrations have been made. The first principles method for determining the age of monitor minerals is the K-Ar method, which involves measurement of their 40 K and 40 Ar* abundances. The AQuA (Absolute Quantities of Argon) pipette system, which emits calibrated quantities of 40 Ar* via the ideal gas law, was used to calibrate the sensitivity of the system across a range of source pressures and estimate 40 Ar* abundances in neutron fluence monitors. These 40 Ar abundances were combined with existing 40 K abundance data for these monitors. Ages for HD-B1 and MD2 (GA1550) biotite fluence monitors were calculated and combined with intercalibration data for HD-B1 and Fish Canyon sanidine (FCs) to determine ages for FCs. Current results do not have the targeted accuracy when compared with previous calibrations; however, we show how the extensive methodology development presented here can be used towards making reliable future measurements.

Geostandards and Geoanalytical Research↗