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At least 19 recordsLinked to original sources

Rare earth element and rare metal inventory of central Asia

Rare earth elements (REE), with their unique physical and chemical properties, are an essential part of modern living. REE have enabled development and manufacture of high-performance materials, processes, and electronic technologies commonly used today in computing and communications, clean energy and transportation, medical treatment and health care, glass and ceramics, aerospace and defense, and metallurgy and chemical refining. Central Asia is an emerging REE and rare metals (RM) producing region. A newly compiled inventory of REE-RM-bearing mineral occurrences and delineation of areas-of-interest indicate this region may have considerable undiscovered resources.

Fact Sheet

Mineral resource of the month: molybdenum

Molybdenum is a metallic element that is most frequently used in alloy and stainless steels, which together represent the single largest market for molybdenum. Molybdenum has also proven invaluable in carbon steel, cast iron and superalloys. Its alloying versatility is unmatched because its addition enhances material performance under high-stress conditions in expanded temperature ranges and in highly corrosive environments. The metal is also used in catalysts, other chemicals, lubricants and many other applications.

Geotimes

Hydrologic data for the Fristoe Unit of the Mark Twain National Forest, southern Missouri, 1988-93

Background hydrologic data were collected from 1988 to 1993 in the Fristoe Unit of the Mark Twain National Forest. Water-quality data collected from area streams, springs, and wells were analyzed using trilinear diagrams, stiff diagrams, boxplots, and summary statistics. The water is a calcium- magnesium-bicarbonate type. Streams generally have slightly larger potassium, barium, and total organic carbon concentrations than spring or well water. Well water has larger bicarbonate and zinc concen- trations and larger variability in sodium, chloride, and nitrate concentrations than stream and spring water samples. The bulk mineralogy for streambed material is primarily coarse grain quartz. Quantitative elemental (chemistry) analysis on the less than 63 micrometer fraction of bulk material was performed. The heavy mineral concentrate in the streambed material was analyzed using semi- quantitative optical mineralogy and 37-element semi- quantitative emission spectrography. Water levels were measured in 57 area wells in the spring and fall from 1990 to 1993 to determine ground-water level fluctuations. Ground-water fluctuations ranged from less than 1.0 to 205.1 feet in these wells. Continuous water-level recorders were installed on three area wells. Depth to water ranged from 289.68 to 333.39 feet in the lower Eleven Point well, which is completed in the Ozark aquifer. Depth to water ranged from 78.73 to 90.20 feet in Ozark Lead Well 1 which is completed in the Ozark aquifer and St. Francois confining unit. Depth to water ranged from 127.53 to 135.67 feet in Ozark Lead Well 2, which is completed in the St. Francois confining unit and the St. Francois aquifer.

Open-File Report

Intraspecific trait variability in wild populations predicts neither variability nor performance in a common garden

Dryland restoration requires plant materials capable of performing well despite difficult growing conditions. Selecting plant materials with higher intraspecific trait variability (ITV) may support successful outcomes by enhancing the performance of those materials in restoration settings. However, maintaining ITV from wild populations is not well understood and requires further investigation if ITV is to be incorporated into native plant materials, which are often developed from wild-collected seed grown in agricultural settings. We used two perennial plant species to explore whether (1) ITV measured at field sites predicts ITV in a common garden, (2) rankings of ITV among populations remain stable over time, and (3) higher levels of ITV promote survival and reproductive effort in a common garden. We measured ITV in specific leaf area and height for Bouteloua curtipendula and Heterotheca villosa at field sites and over 2 years in a common garden, as well as survival and flower production in the common garden. We also calculated climate distance between field sites, where seeds were originally sourced, and the common garden to account for the impact of climatic differences on ITV. We found that (1) ITV measured at field sites did not predict ITV in the common garden, (2) rankings of ITV across populations were inconsistent, and (3) relationships between ITV and performance were rare and differed by species. Our findings indicate that the utility of ITV in wild populations as a predictive tool may be limited.

Restoration Ecology

Dynamic material flow analysis of tantalum in the United States from 2002 to 2020

Tantalum has received considerable attention due to risks associated with its supply chain. In 2020 ∼70% of global tantalum supply originated in Africa, with 40% produced in the Democratic Republic of Congo alone. The United States has relied entirely on imports since the 1950s. However, quantifying total domestic consumption is problematic because refined tantalum compounds do not have unique tariff codes resulting in significant trade volumes not properly documented. Furthermore, tantalum incorporated into finished goods is not tracked as tantalum. Thus, estimates only capture a fraction of total consumption. We performed a material flow analysis to quantify total domestic tantalum consumption from 2002 to 2020. Our results indicate that consumption may be up to 250% more than previously estimated. Our detailed results allow quantification of tantalum stocks in-use as well as coming out of use any year, providing valuable insight to industry and policymakers for addressing potential supply security issues.

Resources, Conservation & Recycling

Physical property changes in hydrate-bearing sediment due to depressurization and subsequent repressurization

Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed, at least briefly, to non-in situ conditions during recovery. To examine the effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes, and speeds of the original and depressurized/repressurized samples are compared. X– ray computed tomography images track how the gas-hydrate distribution changes in the hydrate-cemented sands owing to the depressurizaton/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

Journal of Geophysical Research B: Solid Earth

Analyses of water, core material, and elutriate samples collected near Yazoo City, Mississippi (Yazoo Headwater Project)

Five core-material-sampling sites were chosen by the U.S. Army Corps of Engineers to represent areas of proposed dredging activity. Four receiving-water sites also were selected to represent the water that will contact the proposed dredged material. Chemical and physical analyses were performed upon core material and native-water samples from these sites as well as upon elutriate samples of specific sediment-receiving water systems. The results of these analyses are presented without interpretation.

Mississippi

Availability of ground water in parts of the Acoma and Laguna Indian Reservations, New Mexico

The need for additional water has increased in recent years on the Acoma and Laguna Indian Reservations in west-central New Mexico because the population and per capita use of water have increased; the tribes also desire water for light industry, for more modern schools, and to increase their irrigation program. Many wells have been drilled in the area, but most have been disappointing because of small yields and poor chemical quality of the water. The topography in the Acoma and Laguna Indian Reservations is controlled primarily by the regional and local dip of alternating beds of sandstone and shale and by the igneous complex of Mount Taylor. The entrenched alluvial valley along the Rio San Jose, which traverses the area, ranges in width from about 0.4 mile to about 2 miles. The climate is characterized by scant rainfall, which occurs mainly in summer, low relative humidity, and large daily fluctuations of temperature. Most of the surface water enters the area through the Rio San Jose. The average annual streamflow past the gaging station Rio San Jose near Grants, N. Mex. is about 4,000 acre-feet. Tributaries to the Rio San Jose within the area probably contribute about 1,000 acre-feet per year. At the present time, most of the surface water is used for irrigation. Ground water is obtained from consolidated sedimentary rocks that range in age from Triassic to Cretaceous, and from unconsolidated alluvium of Quaternary age. The principal aquifers are the Dakota Sandstone, the Tres Hermanos Sandstone Member of the Mancos Shale, and the alluvium. The Dakota Sandstone yields 5 to 50 gpm (gallons per minute) of water to domestic and stock wells. The Tres Hermanos sandstone Member generally yields 5 to 20 gpm of water to domestic and stock wells. Locally, beds of sandstone in the Chinle and Morrison Formations, the Entrada Sandstone, and the Bluff Sandstone also yield small supplies of water to domestic and stock wells. The alluvium yields from 2 gpm to as much as 150 gpm of water to domestic and stock wells. Thirteen test wells were drilled in a search for usable supplies of ground water for pueblo and irrigation supply and to determine the geologic and hydrologic characteristics of the water-bearing material. The performance of six of the test wells suggests that the sites are favorable for pueblo or irrigation supply wells. The yield of the other seven wells was too small or the quality of the water was too poor for development of pueblo or irrigation supply to be feasible. However, the water from one of the seven wells was good in chemical quality, and the yield was large enough to supply a few homes with water. The tests suggest that the water in the alluvium of the Rio San Jose valley is closely related to the streamflow and that it might be possible to withdraw from the alluvium in summer and replenish it in winter. The surface flow in summer might be decreased by extensive pumpage of ground water, but on the other hand, more of the winter flow could be retained in the area by storage in the ground-water reservoir. Wells could be drilled along the axis of the valley, and the water could be pumped into systems for distribution to irrigated farms. The chemical quality of ground water in the area varies widely from one stratigraphic unit to another and laterally within each unit and commonly the water contains undesirably large amounts of sulfate. However, potable water has been obtained locally from all the aquifers. The water of best quality seemingly is in the Tres Hermanos Sandstone Member of the Mancos Shale and in the alluvium north of the Rio San Jose. The largest quantity of water that is suitable for irrigation is in the valley fill along the Rio San Jose. Intensive pumping of ground water from aquifers containing water of good quality may draw water of inferior chemical quality into the wells.

Water Supply Paper

EFFECT OF AN ACID RAIN ENVIRONMENT ON LIMESTONE SURFACES.

Salem limestone samples were exposed to weathering for 1 y in several urban and one rural environments. Samples exposed in the rural location were chemically indistinguishable from the freshly quarried limestone, whereas all samples collected from urban exposure sites developed gypsum stains on the ground-facing surfaces where the stones were not washed by precipitation. The gas-solid reaction of SO//2 with calcite was selected for detailed consideration. It appears from the model that under arid conditions, the quantity of stain deposited on an unwashed surface is independent of atmospheric SO//2 concentration once the surface has been saturated with gypsum. Under wet conditions, surface sulfation and weight loss are probably dominated by mechanisms involving wet stone. However, if the rain events are frequent and delimited by periods of dryness, the quantity of gypsum produced by a gas-solid reaction mechanism should correlate with both the frequency of rain events and the atmospheric SO//2 level.

Materials Performance

Effects of acid rain and sulfur dioxide on marble dissolution

Acid precipitation and the dry deposition of sulfur dioxide (SO2) accelerate damage to carbonate-stone monuments and building materials. This study identified and quantified environmental damage to a sample of Vermont marble during storms and their preceding dry periods. Results from field experiments indicated the deposition of SO2 gas to the stone surface during dry periods and a twofold increase in marble dissolution during coincident episodes of low rain rate and decreased rainfall pH. The study is widely applicable to the analysis of carbonate-stone damage at locations affected by acid rain and air pollution.

Materials Performance

Pollution damage to the Powell Building, Reston, Virginia

Concrete column segments of the Powell Building (Reston, VA) exposed to the elements and wetted by precipitation were `cleaned' and roughened, but sheltered portions of the columns retained their smoothness and pollution accumulates, similar to observations for limestone, marble, and sandstone. Weathering effects on the columns were dominated by precipitation run-off and not the acidity of the precipitation. The process may be dry deposition of sulfur dioxide (SO2) and nitric oxides (NOx) that formed soluble salts in the presence of humid air or dew, salts that were removed by precipitation run-off.

Materials Performance

Assessing lunar rare earth element resources

Rare Earth Elements (REEs) are increasingly attracting attention globally due to their pivotal role in enhancing the performance of various hightech devices. Small amounts of these elements greatly improve the performance of materials, making magnets stronger, lenses clearer, lights brighter, batteries last longer, etc. Here we examine the notion that REEs from the Moon might compete with mining on Earth.

Conference Paper

Rapid estimation of minimum depth-to-bedrock from lidar leveraging deep-learning-derived surficial material maps

Previously glaciated landscapes often share similar surficial characteristics, including large areas of exposed bedrock, blankets of till deposits, and alluvium-floored valleys. These materials play significant roles in geologic and hydrologic resources, geohazards, and landscape evolution; however, the vast extents of many previously glaciated landscapes have rendered comprehensive, detailed field mapping difficult. While recent advances in remote sensing have facilitated mapping of surficial materials and landforms, manual map creation has remained a time-intensive task. The development of convolutional neural networks (CNNs) for image classification has provided a new opportunity for rapid characterization of digital elevation models, thus enabling efficient mapping of surficial materials and landforms. We have developed a methodology that leverages existing geologic maps and high-resolution (1–3 m) lidar data to train a U-Net CNN to classify alluvium and exposed bedrock in previously glaciated regions. Coupled with U.S. Geological Survey-developed geomorphometry tools capable of approximating stream incision depths, these classifications can be used to estimate the minimum thicknesses of stream-proximal hillslope sediments in areas where streams have undergone minimal incision into bedrock. We validate this approach in the context of the Neversink River watershed, a subbasin of the Delaware River Basin and significant water source for New York City. Evaluation of deep learning model performance demonstrates substantial agreement with manually drawn maps of alluvium and exposed bedrock. Validation of the minimum sediment thickness map using borehole data and passive seismic measurements shows the greatest performance for shallow materials and decreased performance in deep sediments, as well as in areas where bedrock exposures were too small to be resolved by lidar. To resolve these issues and create more accurate surficial maps, we are training new CNNs with additional geologic data and exploring advanced approaches for estimating depths of stream incision.

Delaware, New Jersey, New York, Pennsylvania

Predicting performance for ecological restoration: A case study using Spartina altemiflora

The success of population-based ecological restoration relies on the growth and reproductive performance of selected donor materials, whether consisting of whole plants or seed. Accurately predicting performance requires an understanding of a variety of underlying processes, particularly gene flow and selection, which can be measured, at least in part, using surrogates such as neutral marker genetic distances and simple latitudinal effects. Here we apply a structural equation modeling approach to understanding and predicting performance in a widespread salt marsh grass, Spartina alterniflora, commonly used for ecological restoration throughout its native range in North America. We collected source materials from throughout this range, consisting of eight clones each from 23 populations, for transplantation to a common garden site in coastal Louisiana and monitored their performance. We modeled performance as a latent process described by multiple indicator variables (e.g., clone diameter, stem number) and estimated direct and indirect influences of geographic and genetic distances on performance. Genetic distances were determined by comparison of neutral molecular markers with those from a local population at the common garden site. Geographic distance metrics included dispersal distance (the minimum distance over water between donor and experimental sites) and latitude. Model results indicate direct effects of genetic distance and latitude on performance variation among the donor sites. Standardized effect strengths indicate that performance was roughly twice as sensitive to variation in genetic distance as to latitudinal variation. Dispersal distance had an indirect influence on performance through effects on genetic distance, indicating a typical pattern of genetic isolation by distance. Latitude also had an indirect effect on genetic distance through its linear relationship with dispersal distance. Three performance indicators had significant loadings on performance alone (mean clone diameter, mean number of stems, mean number of inflorescences), while the performance indicators mean stem height and mean stem width were also influenced by latitude. We suggest that dispersal distance and latitude should provide an adequate means of predicting performance in future S. alterniflora restorations and propose a maximum sampling distance of 300 km (holding latitude constant) to avoid the sampling of inappropriate ecotypes. ?? 2010 by the Ecological Society of America.

Ecological Applications

A new sampler for the collection and retrieval of dry dust deposition

Atmospheric dust can influence biogeochemical cycles, accelerate snowmelt, and affect air, water quality, and human health. Yet, the bulk of atmospherically transported material remains poorly quantified in terms of total mass fluxes and composition. This lack of information stems in part from the challenges associated with measuring dust deposition. Here we report on the design and efficacy of a new dry deposition sampler (Dry Deposition Sampling Unit (DSU)) and method that quantifies the gravitational flux of dust particles. The sampler can be used alone or within existing networks such as those employed by the National Atmospheric Deposition Program (NADP). Because the samplers are deployed sterile and the use of water to remove trapped dust is not required, this method allows for the recovery of unaltered dry material suitable for subsequent chemical and microbiological analyses. The samplers were tested in the laboratory and at 15 field sites in the western United States. With respect to material retention, sampler performance far exceeded commonly used methods. Retrieval efficiency was >97% in all trials and the sampler effectively preserved grain size distributions during wind exposure experiments. Field tests indicated favorable comparisons to dust-on-snow measurement across sites ( r 2 0.70, p < 0.05) and within sites to co-located aerosol data ( r 2 0.57–0.99, p < 0.05). The inclusion of dust deposition and composition monitoring into existing networks increases spatial and temporal understanding of the atmospheric transport on materials and substantively furthers knowledge of the effects of dust on terrestrial ecosystems and human exposure to dust and associated deleterious compounds.

Arizona, California, Colorado, Idaho, Nevada, Utah

Crushed cement concrete substitution for construction aggregates; a materials flow analysis

An analysis of the substitution of crushed cement concrete for natural construction aggregates is performed by using a materials flow diagram that tracks all material flows into and out of the cement concrete portion of the products made with cement concrete: highways, roads, and buildings. Crushed cement concrete is only one of the materials flowing into these products, and the amount of crushed cement concrete substituted influences the amount of other materials in the flow. Factors such as availability and transportation costs, as well as physical properties, that can affect stability and finishability, influence whether crushed cement concrete or construction aggregates should be used or predominate for a particular end use.

Circular

Effectiveness of common fish screen materials for protecting lamprey ammocoetes—Influence of sweeping velocities and decreasing flows

In previous tests of the effectiveness of four common fish screen materials for excluding lamprey ammocoetes, we determined that woven wire (WW) allowed substantially more entrainment than perforated plate (PP), profile bar (PB), or Intralox (IL) material. These tests were simplistic because they used small vertically-oriented screens positioned perpendicular to the flow without a bypass or a sweeping velocity (SV). In the subsequent test discussed in this report, we exposed ammocoetes to much larger (2.5-m-wide) screen panels with flows up to 10 ft3 /s, a SV component, and a simulated bypass channel. The addition of a SV modestly improved protection of lamprey ammocoetes for all materials tested. A SV of 35 cm/s with an approach velocity (AV) of 12 cm/s, was able to provide protection for fish about 5–15 mm smaller than the protection provided by an AV of 12 cm/s without a SV component. The best-performing screen panels (PP, IL, and PB) provided nearly complete protection from entrainment for fish greater than 50-mm toal length, but the larger openings in the WW material only protected fish greater than 100-mm total length. Decreasing the AV and SV by 50 percent expanded the size range of protected lampreys by about 10–15 mm for those exposed to IL and WW screens, and it decreased the protective ability of PP screens by about 10 mm. Much of the improvement for IL and WW screens under the reduced flow conditions resulted from an increase in the number of lampreys swimming away from the screen. Fish of all sizes became impinged (that is, stuck on the screen surface for more than 1 s) on the screens, with the rate of impingement highest on PP (39– 72 percent) and lowest on WW (7–22 percent). Although impingements were common, injuries were rare, and 24-h post-test survival was greater than 99 percent. Our results refined the level of protection provided by these screen materials when both an AV and SV are present and confirmed our earlier recommendation that WW screens be replaced with more effective materials. Future work should focus on determining the risks associated with other screen types (for example, rotary drum screens, horizontal flat plate screens) and exploring the effectiveness of higher SV:AV ratios, because it may help expand the range of sizes protected by the best performing materials.

Open-File Report

Analyses of water, core material, and elutriate samples collected near Sicily Island, Louisiana (Sicily Island area levee project)

Samples consisting of composited core material were collected from five areas by the U.S. Army Corps of Engineers and analyzed by the U.S. Geological Survey to provide data on the impact of proposed channel excavation and levee construction in the Sicily Island area, Louisiana. Samples of receiving water from the five areas, selected to represent the water that will contact the proposed dredged material of the levee fill material, also were collected. Chemical and physical analyses were performed on samples of core material and native water and on elutriate samples of specific core material-receiving water mixtures. The results of these analyses are presented without interpretation.

Louisiana