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At least 19 recordsLinked to original sources
USGS2023

Global review reveals how disparate study motivations, analytical designs, and focal ions limit understanding of salinization effects on freshwater animals

Global salinization of freshwaters is adversely affecting biotic communities and ecosystem processes. We reviewed six decades (1960–2020) of literature published on animal responses to increased salinities across different taxonomic and ecological contexts and identified knowledge gaps. From 585 journal articles, we characterized 5924 responses of mollusks, crustaceans, zooplankton, non-arthropod invertebrates (NAI), insects, fishes, and amphibians to salinization. Insects and fishes were the most studied taxa; Na + and Cl − were the most studied ions − . Collectively, concentrations of the ions examined typically spanned five orders of magnitude. Species' invasiveness was a key motivation for studying mollusks, crustaceans, and fishes; threats of urbanization and road salts were key motivations for studying NAI, zooplankton, and amphibians. Laboratory studies were more common than field studies for most taxa. Focal life stages in laboratory studies varied widely but juveniles and adults were represented similarly in field studies. Studies of mollusks, NAI, and crustacean focused on adults; studies of zooplankton, insects, fishes, and amphibians focused on juveniles. Organismal- and population-level responses measuring solute uptake, internal chemistry, body condition, or ion concentrations predominated laboratory studies; population- and assemblage-level responses measuring abundance, spatial distribution, or assemblage composition predominated field studies. Negative responses to salinization predominated but positive and unimodal responses were apparent across all taxa and organizational levels. Key topics for further research include a) salinity responses by more taxa, b) responses to especially toxic ions (i.e., potassium, bicarbonate, sulfate, magnesium), c) mechanisms causing positive and unimodal responses, d) traits underpinning responses, e) effects transcending organizational levels, f) ion-specific response thresholds, and g) interactions between salinity and other stressors. Our review suggests inter-taxa variation in sensitivity to salinization reflects occurrence of certain biological traits, including gill-breathing, semi-permeable skin, multiple life stages, and limited mobility. We propose a traits-based framework to predict salinization sensitivity from shared traits. This evolutionary approach could inform management aimed at preventing or reducing adverse impacts of freshwater salinization.

Science of the Total Environment↗
USGS2019

Isotopes matter

Two years ago, the King’s Centre for Visualization in Science (KCVS) at The King’s University, Edmonton released a new digital interactive version of the IUPAC Periodic Table of the Elements and Isotopes with accompanying educational resources at an International Conference on Chemistry Education. It can be found at www.isotopesmatter.com. The effort was part of an IUPAC project . The science behind this new table was developed by Inorganic Chemistry Division scientists working for over a decade on an earlier IUPAC project . These projects were joint efforts between the IUPAC Committee on Chemistry Education (CCE) and the Inorganic Chemistry Division.

Chemistry International↗
USGS2013

The influence of global climate change on the scientific foundations and applications of Environmental Toxicology and Chemistry: Introduction to a SETAC international workshop

This is the first of seven papers resulting from a Society of Environmental Toxicology and Chemistry (SETAC) international workshop titled “The Influence of Global Climate Change on the Scientific Foundations and Applications of Environmental Toxicology and Chemistry.” The workshop involved 36 scientists from 11 countries and was designed to answer the following question: How will global climate change influence the environmental impacts of chemicals and other stressors and the way we assess and manage them in the environment? While more detail is found in the complete series of articles, some key consensus points are as follows: (1) human actions (including mitigation of and adaptation to impacts of global climate change [GCC]) may have as much influence on the fate and distribution of chemical contaminants as does GCC, and modeled predictions should be interpreted cautiously; (2) climate change can affect the toxicity of chemicals, but chemicals can also affect how organisms acclimate to climate change; (3) effects of GCC may be slow, variable, and difficult to detect, though some populations and communities of high vulnerability may exhibit responses sooner and more dramatically than others; (4) future approaches to human and ecological risk assessments will need to incorporate multiple stressors and cumulative risks considering the wide spectrum of potential impacts stemming from GCC; and (5) baseline/reference conditions for estimating resource injury and restoration/rehabilitation will continually shift due to GCC and represent significant challenges to practitioners.

Environmental Toxicology and Chemistry↗
USGS2026

PFAS mixture composition and internal exposure profiles shape biological responses under field-realistic exposure

Per- and polyfluoroalkyl substances (PFAS) occur as complex mixtures, yet mixture-dependent biological effects under environmentally realistic exposure conditions remain poorly understood. We conducted multiyear (2018, 2019, 2021) continuous-flow, field-based exposures of male fathead minnows ( Pimephales promelas ) using a low-PFAS reference well (REF; sum of measured PFAS (∑PFAS) 0.1–0.2 μg L –1 ) and PFAS-contaminated groundwater from a fire-training area (FTA) at Joint Base Cape Cod, Massachusetts. Dilution treatments enabled separation of concentration and mixture effects. Groundwater from well FTA1 was perfluorooctanesulfonate (PFOS) dominated (∑PFAS 10–31 μg L –1 ), whereas groundwater from well FTA2 had higher concentrations and was enriched in perfluorooctanoate (PFOA) and diverse precursors (∑PFAS ∼ 80 μg L –1 ). Despite comparable plasma ∑PFAS and PFOS in FTA1–100% and FTA2–50% on day-7, cumulative mortality reached approximately 35% in FTA2–50% and 17% in FTA2–100%, and secondary sex trait expression was reduced by approximately 65–80% relative to REF, whereas sperm motility effects were mixture- and time-dependent. Plasma PFAS profiles were dominated by perfluorohexanesulfonate (PFHxS), PFOS, and sulfonamide precursors. Liver transcriptomics from REF-acclimated fish revealed robust disruption of metabolic, mitochondrial, and endocrine pathways that link PFAS mixture chemistry and internal exposure profiles to organismal outcomes, and testis transcriptomics provided complementary insight into reproductive impairment. These results indicate that PFAS mixture composition and internal exposure profiles, including precursor-associated differences, are important determinants of ecotoxicological outcomes under field-realistic conditions.

Massachusetts↗
USGS2011

Atomic weights: No longer constants of nature

Many of us were taught that the standard atomic weights we found in the back of our chemistry textbooks or on the Periodic Table of the Chemical Elements hanging on the wall of our chemistry classroom are constants of nature. This was common knowledge for more than a century and a half, but not anymore. The following text explains how advances in chemical instrumentation and isotopic analysis have changed the way we view atomic weights and why they are no longer constants of nature

Chemistry International↗
USGS2011

IUPAC Periodic Table of the Isotopes

For almost 150 years, the Periodic Table of the Elements has served as a guide to the world of elements by highlighting similarities and differences in atomic structure and chemical properties. To introduce students, teachers, and society to the existence and importance of isotopes of the chemical elements, an IUPAC Periodic Table of the Isotopes (IPTI) has been prepared and can be found as a supplement to this issue.

Chemistry International↗
USGS2022

The role of pH up-regulation in response to nutrient-enriched, low-pH groundwater discharge

Coral reefs and their ecosystems are threatened by both global stressors, including increasing sea-surface temperatures and ocean acidification (OA), and local stressors such as land-based sources of pollution that can magnify the effects of OA. Corals can physiologically control the chemistry of their internal calcifying fluids (CF) and can thereby regulate their calcification process. Specifically, increasing aragonite saturation state in the CF (Ω CF ) may allow corals to calcify even under external low saturation conditions. Questions remain regarding the physiological processes that govern the CF chemistry and how they change in response to multiple stressors. To address this knowledge gap, the boron δ 11 B and B/Ca were analyzed in tropical corals, Porites lobata, collected at submarine groundwater seeps impacted by the release of treated wastewater in west Maui, Hawai'i, to document the interactions between high nutrient / low pH seep water on CF carbonate chemistry. Results show substantial up-regulation of pH and dissolved inorganic carbon (DIC) with respect to seawater in P. lobata corals collected from within the wastewater impacted area at Kahekili Beach Park compared to the control site at Olowalu Beach. The Ω CF was 9 to 10 times higher than ambient seawater Ω, and 13 to 26% higher than in corals from the control site and from values previously observed in tropical Porites spp. corals. Such elevated up-regulation suggests that corals exposed to nutrient-enriched, low pH effluent sustain CF supersaturated with respect to aragonite, possibly as an internal coping mechanism to combat multiple stressors from land-based sources of pollution. This elevated up-regulation has implications to coral vulnerability to future climate- and ocean-change.

Hawaii↗
USGS2011

Guidelines and recommended terms for expression of stable-isotope-ratio and gas-ratio measurement results

To minimize confusion in the expression of measurement results of stable isotope and gas-ratio measurements, recommendations based on publications of the Commission on Isotopic Abundances and Atomic Weights of the International Union of Pure and Applied Chemistry (IUPAC) are presented. Whenever feasible, entries are consistent with the Système International d'Unités, the SI (known in English as the International System of Units), and the third edition of the International Vocabulary of Basic and General Terms in Metrology (VIM, 3rd edition). The recommendations presented herein are approved by the Commission on Isotopic Abundances and Atomic Weights and are designed to clarify expression of quantities related to measurement of isotope and gas ratios to ensure that quantity equations instead of numerical value equations are used for quantity definitions. Examples of column headings consistent with quantity calculus (also called the algebra of quantities) and examples of various deprecated usages connected with the terms recommended are presented.

Rapid Communications in Mass Spectrometry↗
USGS2011

Neither a year nor an annus can be a derived unit in the SI

The year is not a unit of the SI. The only SI unit of measurement for time is the second. The word “annus” or “annum” does not appear anywhere in the current SI document. The word “year” is not in the table of “Non-SI units accepted for use with the International System of Units,” nor in the table of “Non-SI units whose values in SI units must be obtained experimentally,” nor even in the table of “Other non-SI units.” The year can be found, however, through the list of “Other non-SI units not recommended for use.” This heading directs the reader to a National Institute of Standards and Technology (NIST) list where three kinds of year (365 days, sidereal, and tropical) are given with conversion to seconds, but are set in type to indicate “in general not to be used in NIST publications.” Table 1 summarizes some of the uses of the year in other publications. For example, in the IUPAC chemistry document, the year is not a constant; in the International Astronomy Union Style Guide, the year (Julian) is a constant.

Chemistry International↗
USGS1960

Chemical equilibrium diagrams for ground-water systems/les graphiques de l'équilibre chimique pour les systèmes des eaux souterrainnes

Chemical equilibrium in water in contact with calcite is expressed by means of a pH grid overlay on a log-log plot of activities of bicarbonate vs. calcium ions. Solubility of ferrous iron and the solid-phase minerals that would be stable in a solution containing activities of 10 ppm of sulfate and 100 ppm of bicarbonate or related species is expressed by means of a stability-field diagram with pH as abscissa and redox potential as ordinate.The diagrams can be used to tell whether water injected in recharge wells may form precipitates that may plug the aquifer and have other uses in studies of natural water chemistry.

International Association of Scientific Hydrology ↗
USGS1998

Catalog of the historically active volcanoes of Alaska

Alaska hosts within its borders over 80 major volcanic centers that have erupted during Holocene time (< 10,000 years). At least 29 of these volcanic centers (table 1) had historical eruptions and 12 additional volcanic centers may have had historical eruptions. Historical in Alaska generally means the period since 1760 when explorers, travelers, and inhabitants kept written records. These 41 volcanic centers have been the source for >265 eruptions reported from Alaska volcanoes. With the exception of Wrangell volcano, all the centers are in, or near, the Aleutian volcanic arc, which extends 2500 km from Hayes volcano 145 km west of Anchorage in the Alaska-Aleutian Range to Buldir Island in the western Aleutian Islands (fig. 1). The volcanic arc, a subduction-related feature associated with underthrusting of the Pacific plate beneath the North American plate is divided between oceanic island arc and continental margin segments, the boundary occurring at about 165° W longitude (fig. 1). An additional 7 volcanic centers in the Aleutian arc (table 2; fig. 1 A) have active fumarole fields but no reported historical eruptions. This report discusses the location, physiography and structure, eruptive history, and geology of those volcanoes in Alaska that have experienced one or more eruptions that have been recorded in the written history (i.e., in historical time). It is part of the group of catalogs entitled Catalogue of Active Volcanoes of the World published beginning in 1951 under the auspices of the International Association of Volcanology and Chemistry of the Earth's Interior (IAVCEI). A knowledge of the information contained in such catalogs aids in understanding the type and scale of activity that might be expected during a particular eruption, the hazards the eruption may pose, and even the prediction of eruptions. The catalog will thus be of value not only to the inhabitants of Alaska but to government agencies concerned with emergency response, air traffic operations, and weather, as well as to industry and scientists. The combination of the hazard posed by volcanic ash to jet aircraft and the heavy use of international air routes located parallel to, and on either side of, the Aleutian volcanic arc means that even remote volcanoes in Alaska now pose significant hazards to life and property. Although this report is concerned with historical eruptions from Alaskan volcanoes, other volcanoes in Alaska have erupted in the past 10,000 years and might therefore be expected to erupt again. Several Holocene volcanic centers in the Aleutian arc have no reported historical activity. Elsewhere in Alaska the Bering Sea basalt fields cover large areas of the Yukon Delta, Seward Peninsula, and several of the islands of the Bering Sea. Holocene centers also occur in the Wrangell Mountains and in isolated occurrences in the interior and southeastern Alaska. Eruptions from these centers have occurred within the past several hundred years but none were transcribed in the written record. Moodie and others (1992), however, report oral traditions among the Northern Athapaskan Indians of the southwestern Yukon Territory that may record the second and younger deposition of the White River Ash circa A.D. 720. This lobe of the White River Ash was deposited during the paroxysmal eruption of Churchill volcano in the Wrangell Mountains of eastcentral Alaska (McGimsey and others, 1992; Richter and others, 1995).

Alaska↗
USGS1983

Seismicity at Fuego, Pacaya, Izalco, and San Cristobal Volcanoes, Central America, 1973-1974

Seismic data collected at four volcanoes in Central America during 1973 and 1974 indicate three sources of seismicity: regional earthquakes with hypocentral distances greater than 80 km, earthquakes within 40 km of each volcano, and seismic activity originating at the volcanoes due to eruptive processes. Regional earthquakes generated by the underthrusting and subduction of the Cocos Plate beneath the Caribbean Plate are the most prominent seismic feature in Central America. Earthquakes in the vicinity of the volcanoes occur on faults that appear to be related to volcano formation. Faulting near Fuego and Pacaya volcanoes in Guatemala is more complex due to motion on a major E-W striking transform plate boundary 40 km north of the volcanoes. Volcanic activity produces different kinds of seismic signatures. Shallow tectonic or A-type events originate on nearby faults and occur both singly and in swarms. There are typically from 0 to 6 A-type events per day with b value of about 1.3. At very shallow depths beneath Pacaya, Izalco, and San Cristobal large numbers of low-frequency or B-type events are recorded with predominant frequencies between 2.5 and 4.5 Hz and with b values of 1.7 to 2.9. The relative number of B-type events appears to be related to the eruptive states of the volcanoes; the more active volcanoes have higher levels of seismicity. At Fuego Volcano, however, low-frequency events have unusually long codas and appear to be similar to tremor. High-amplitude volcanic tremor is recorded at Fuego, Pacaya, and San Cristobal during eruptive periods. Large explosion earthquakes at Fuego are well recorded at five stations and yield information on near-surface seismic wave velocities (??=3.0??0.2 km/sec.). ?? 1983 Intern. Association of Volcanology and Chemistry of the Earth's Interior.

Bulletin Volcanologique↗
USGS1980

Oxygen isotopic determinations of sequentially erupted plagioclases in the 1974 magma of Fuego Volcano, Guatemala

Plagioclases in the 1974 high-Al basalt from Fuego Volcano have ??O18 values of +6.0 to +8.5 per mil. Meteoric water cannot have played a significant role in Fuego's magma. Large, weakly zone clear phenocrysts had ??O18 values in the accepted mantle range, while patchyzoned and oscillatory-zoned plagioclases inferred to have formed later and shallower levels have slightly heavier oxygen isotopic ratios. ?? 1980 Intern. Association of Volcanology and Chemistry of the Earth's Interior.

Bulletin Volcanologique↗
USGS2022

The centenary of IAVCEI 1919–2019 and beyond: The people, places, and things of volcano geodesy

Over the first century of the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI), volcano geodesy grew from roots as an accidental and incidental system of measurements to an important method for monitoring volcanic activity and forecasting eruptions. The first practitioners in volcano geodesy were experts in other disciplines, and it was not until the latter half of the twentieth century that specialists in the field emerged—scientists who developed new methods, measured geodetic change at volcanoes, and quantitatively interpreted the results in terms of magmatic processes. Much of the early work in the field was restricted to a few volcanoes and involved techniques that had been adapted from other applications; relatively few methods were developed specifically for use on volcanoes. These volcanoes, however, provided the natural laboratories needed to advance the field. By the start of the twenty-first century, geodetic studies, especially using space-based techniques, contributed to the recognition of deformation and gravity change at hundreds of volcanoes on Earth. In coming years, IAVCEI researchers will focus on comprehensive exploitation of the growing volumes of geodetic data to better model, forecast, and track activity at volcanoes worldwide. Meanwhile, the field needs to become more diverse, better representing people who live in the shadows of volcanoes around the globe.

Bulletin of Volcanology↗
USGS2010

Dissolution-reprecipitation of igneous zircon in mid-ocean ridge gabbro, Atlantis Bank, Southwest Indian Ridge

Zircons recovered from oceanic gabbro exposed on Atlantis Bank, Southwest Indian Ridge, typically display oscillatory and sector zoning consistent with igneous crystallization from mafic magmas. In one rock (of twenty investigated), weak-oscillatory-zonation patterns are overprinted by secondary textural features characterized by mottled, convoluted and wavy internal zonation patterns that are frequently associated with secondary micron- to submicron-scale micro-porosity. These zircons are hosted in a felsic vein that intruded an oxide gabbro, both of which are cross-cut by monomineralic amphibole- and quartz-rich veinlets. Zircons with weak-oscillatory-zonation patterns record a weighted-average 206 Pb/ 238 U age of 12.76 ± 0.20 Ma (mswd = 1.5), and have high trace element concentrations [e.g., ΣREEs (∼ 0.4–2.2 wt.%), Y (∼ 0.6–2.8 wt.%), P (∼ 0.4–0.9 wt.%)], and Th/U (0.1–0.5). These zircons are anomalously old (≥1 Myr) relative to the magnetic age for this portion of oceanic crust (11.75 Ma). In contrast, zircons with non-igneous, secondary textures have a younger weighted-average 206 Pb/ 238 U age of 12.00 ± 0.16 Ma (mswd = 1.7), and have lower trace element concentrations [e.g., ΣREEs (∼ 0.2–0.8 wt.%), Y (∼ 0.3–1.0 wt.%), P (∼ 0.1–0.3 wt.%)], and slightly lower Th/U (0.1–0.3). The weighted-average age of these zircons is similar to the magnetic anomaly age, and other 206 Pb/ 238 U ages of nearby rocks. We do not observe a correlation between crystallographic misorientation, internal texture, or trace element chemistry. We suggest that the decrease in trace element concentrations associated with the development of non-igneous alteration textures is attributed to the purging of non-essential structural constituent cations from the zircon crystal lattice at amphibolite-facies conditions. The mechanism of alteration/re-equilibration was likely an interface-coupled dissolution–reprecipitation processes that affected pre-existing, anomalously old zircons during shallow-level magmatic construction of Atlantis Bank at ∼ 12.0 Ma.

Chemical Geology↗
USGS2021

The Independent Volcanic Eruption Source Parameter Archive (IVESPA, version 1.0): A new observational database to support explosive eruptive column model validation and development

Eruptive column models are powerful tools for investigating the transport of volcanic gas and ash, reconstructing past explosive eruptions, and simulating future hazards. However, the evaluation of these models is challenging as it requires independent estimates of the main model inputs (e.g. mass eruption rate) and outputs (e.g. column height). There exists no database of independently estimated eruption source parameters (ESPs) that is extensive, standardized, maintained, and consensus-based. This paper introduces the Independent Volcanic Eruption Source Parameter Archive (IVESPA, ivespa.co.uk), a community effort endorsed by the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Commission on Tephra Hazard Modelling. We compiled data for 134 explosive eruptive events, spanning the 1902-2016 period, with independent estimates of: i) total erupted mass of fall deposits; ii) duration; iii) eruption column height; and iv) atmospheric conditions. Crucially, we distinguish plume top versus umbrella spreading height, and the height of ash versus sulphur dioxide injection. All parameter values provided have been vetted independently by at least two experts. Uncertainties are quantified systematically, including flags to describe the degree of interpretation of the literature required for each estimate. IVESPA also includes a range of additional parameters such as total grain size distribution, eruption style, morphology of the plume (weak versus strong), and mass contribution from pyroclastic density currents, where available. We discuss the future developments and potential applications of IVESPA and make recommendations for reporting ESPs to maximize their usability across different applications. IVESPA covers an unprecedented range of ESPs and can therefore be used to evaluate and develop eruptive column models across a wide range of conditions using a standardized dataset.

Journal of Volcanology and Geothermal Research↗
USGS2023

The Volcanic Hazard Maps Database: An initiative of the IAVCEI Commission on Volcanic Hazards and Risk

In this work we present the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Commission on Volcanic Hazards and Risk (CVHR) Volcanic Hazard Maps Database and the accompanying volcanichazardmaps.org website. Using input from a series of IAVCEI CVHR Working Group on Hazard Mapping workshops, we developed a classification scheme and terminology framework for categorizing, discussing, naming, and searching for hazard maps. ≥ The database and website aim to serve as a resource for the volcanology community to explore how different aspects of hazard map development and design have been addressed in different countries, for different hazard processes, and for different intended purposes and audiences. Additionally, they act as a tool for presenting hazard map options to stakeholder groups and serve as a learning resource that can be incorporated into educational materials and training courses. In this work, we present the database and website, discuss the classification scheme, explore the enormous diversity of hazard maps, and suggest ways that the database and website can be used by the volcanic hazard mapping community.

Journal of Applied Volcanology↗