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At least 1,567 records · Page 87Linked to original sources
USGS2006

Questa baseline and pre-mining ground-water quality investigation. 20. Water chemistry of the Red River and selected seeps, tributaries, and precipitation, Taos County, New Mexico, 2000-2004

As part of a multi-year project to infer the pre-mining ground-water quality at Molycorp's Questa mine site, surface-water samples of the Red River, some of its tributaries, seeps, and snow samples were collected for analysis of inorganic solutes and of water and sulfate stable isotopes in selected samples. The primary aim of this study was to document diel, storm event, and seasonal variations in water chemistry for the Red River and similar variations in water chemistry for Straight Creek, a natural analog site similar in topography, hydrology, and geology to the mine site for inferring pre-mining water-quality conditions. Red River water samples collected between 2000 and 2004 show that the largest variations in water chemistry occur during late summer rainstorms, often monsoonal in nature. Within hours, discharge of the Red River increased from 8 to 102 cubic feet per second and pH decreased from 7.80 to 4.83. The highest concentrations of metals (iron, aluminum, zinc, manganese) and sulfate also occur during such events. Low-pH and high-solute concentrations during rainstorm runoff are derived primarily from alteration 'scar' areas of naturally high mineralization combined with steep topography that exposes continually altered rock because erosion is too rapid for vegetative growth. The year 2002 was one of the driest on record, and Red River discharge reflected the low seasonal snow pack. No snowmelt peak appeared in the hydrograph record, and a late summer storm produced the highest flow for the year. Snowmelt was closer to normal during 2003 and demonstrated the dilution effect of snowmelt on water chemistry. Two diel sampling events were conducted for the Red River, one during low flow and the other during high flow, at two locations, at the Red River gaging station and just upstream from Molycorp's mill site. No discernible diel trends were observed except for dissolved zinc and manganese at the upstream site during low flow. Straight Creek drainage water was sampled periodically from 2001 to 2004 at the down stream end of surface drainage near the point at which it disappeared into the debris fan. This water has a minimal range in pH (2.7 to 3.2) but a substantial concentration range in many solutes; for example, sulfate concentrations varied from 525 to 2,660 mg/L. Many elements covary with sulfate suggesting that dilution is the primary control of the range in solute concentrations. A transect of water samples higher in the scar area were collected in October of 2003. They had a lower range in pH (2.44 to 3.05) and higher solute concentrations than those collected periodically from lower in the catchment. Water isotopes for the upper transect samples indicated slight evaporation, and in part, may account for the higher solute concentrations. Drainage waters also were collected from Hottentot, Junebug, Hansen, Little Hansen, and Goat Hill Gulch drainages. Most constituents from other scar drainage waters showed ranges of concentration similar to those of the Straight Creek waters. An exception was water collected from Goat Hill Gulch, which has some of the highest concentrations of any surface-water sample collected but also contained waste-rock leachates.

New Mexico↗
USGS2002

Water-quality data analysis of the upper Gunnison River watershed, Colorado, 1989-99

Water-quality data from October 1969 to December 1999 for both surface water and ground water in the upper Gunnison River watershed were retrieved and compiled from the U.S. Geological Survey National Water Information System and the U.S. Environmental Protection Agency Storage and Retrieval databases. Analyses focused primarily on a subset of these data from October 1989 to December 1999. The upper Gunnison River watershed is located west of the Continental Divide in the Southern Rocky Mountains physiographic province. Surface-water-quality data were compiled for 482 sites in the upper Gunnison River watershed. Most values of surface-water temperature, dissolved oxygen, and pH were within Colorado Department of Public Health and Environment (CDPHE) in-stream standards. Calcium bicarbonate type water was the most spatially dominant water type in the basin. Nutrients were most commonly sampled along the Slate River and East River near Crested Butte and along the Gunnison River from the confluence of the East and Taylor Rivers to the western edge of the watershed. Median ammonia concentrations were low, with many concentrations less than laboratory reporting levels. All nitrate concentrations met the CDPHE in-stream standard of 10 milligrams per liter. More than 30 percent of stream sites with total phosphorus data (23 of 61 sites) had concentrations greater than the U.S. Environmental Protection Agency (USEPA) recommendation for controlling eutrophication. Ammonia concentrations at a site on the Slate River near Crested Butte had a statistically significant upward trend for the 1995–99 period. The Slate River near Crested Butte site is located immediately downstream from the towns of Crested Butte and Mount Crested Butte and may reflect recent population growth or other land-use changes. However, the rate of change of the trend is small (0.017 milligram per liter per year). Although a multiple comparison test showed nitrate concentrations were statistically different between agriculture and forest sites and between agriculture and urban land-use classified sites, median concentrations were low among all land-use settings. Median concentrations of total phosphorus were greatest in rangeland areas and least in urban areas. No significant differences were identified for median concentrations of total phosphorus in agriculture and forest land-use areas. Median concentrations of arsenic, lead, mercury, selenium, and silver were low or below reporting levels throughout the watershed. Aluminum, cadmium, copper, lead, manganese, and zinc concentrations were elevated near the town of Crested Butte and on Henson Creek upstream from Lake City, which may be explained by upstream areas of historical mining. Samples for six trace elements exceeded standards: cadmium, copper, lead, manganese, silver, and zinc. A downward trend (3 micrograms per liter per year) was identified for the dissolved iron concentration at a site on the Gunnison River at County Road 32 downstream from the city of Gunnison. Streambed-sediment samples from areas affected by historical mining also had elevated concentrations of some trace elements. Chlorophyll- a concentrations in samples from Blue Mesa Reservoir and streams in the Crested Butte and Gunnison areas were typical of unenriched to moderately enriched conditions. Median concentrations of 5-day biochemical oxygen demand concentrations for sites between Crested Butte and Blue Mesa Reservoir were less than 2 milligrams per liter. Occasional high (greater than 200 counts per 100 milliliters) concentrations for fecal coliform were determined at selected sites within the study area. However, median concentrations were less than 100 counts per 100 milliliters except for the Squaw Creek and Cimarron River areas in the western part of the watershed. Ground-water-quality data have been collected by the U.S. Geological Survey from 99 wells. Many wells were completed in aquifers composed of Holocene-age valley fill and alluvium. Most field properties were within the USEPA Secondary Drinking Water Regulations (SDWR) range for treated drinking water, except for 2 (of 40) pH samples. Calcium bicarbonate was the predominant water type in nearly all aquifers except for the aquifers composed of volcanic rock, which had more sodium and sulfate mixed water types. Wells with sulfate concentrations exceeding the SDWR of 250 milligrams per liter were completed in aquifers composed of volcanic rock near Lake City. Dissolution and oxidation of sulfide minerals in these aquifers may explain the elevated sulfate concentrations in ground water at these locations. Nutrient concentrations in ground water were generally low, and median concentrations for ammonia, nitrite, and dissolved phosphorus were below reporting levels. All nitrate concentrations in the samples were below the USEPA drinking-water maximum contaminant level of 10 mg/L. No statistical difference was found in nitrate concentrations among the four land-use classifications (agriculture, forest, rangeland, and urban). Trace elements in ground water were generally below the USEPA SDWR. Three iron samples exceeded the USEPA SDWR of 300 micrograms per liter at two wells located near the city of Gunnison and at a well south of the town of Powderhorn near the Cebolla River. Nine of 39 manganese samples exceeded the USEPA SDWR of 50 micrograms per liter and were collected from aquifers composed of Holocene-age valley fill and alluvium near Gunnison and Crested Butte and in one well near the Cebolla River. Radon gas is a natural radioactive decay product of uranium. All 39 radon samples collected from ground water in the watershed exceeded the proposed USEPA drinking-water maximum contaminant level of 300 picocuries per liter and ranged from 426 to 3,830 picocuries per liter.

Colorado↗
USGS2013

Cobalt-rich ferromanganese crusts from the Central Pacific

Ferromanganese crusts coat most hard substrates on seamounts, ridges, and plateaus in the centralPacific basin. Crusts from less than 2500 m water depth are rich in Mn, Co, Ni, Pb, and Pt. Samples we collected from the EEl of the Hawaiian, Johnston, Palmyra, and Marshall Islands are discussed. Necker Ridge in the Hawaiian EEl has the greatest average crust thickness of 4 em. The dominant mineral in all crusts is o-Mn02' Substrate rocks are dominantly volcanic breccia. Slumping and turbidity currents on the flanks of the submarine edifices partly control crust thicknesses by burial and dissolution or erosion. Regional variations in crust chemistry and mineralogy can be related to various oceanographic and geologic conditions. Of the areas examined in Some detail, the EEl of Johnston, Palmyra, and the Marshall Islands hold the greatest economic potential.

Conference Paper↗
USGS1981

Differentiation of delta-front and barrier lithofacies of the Upper Cretaceous Pictured Cliffs Sandstone, southwest San Juan Basin, New Mexico.

This Sandstone represents a regressive littoral marine unit deposited during the final retreat of the Cretaceous epeiric sea. Differences in rock type, internal and penecontemporaneous deformation structures, textural sequences, mineral composition and trace fossil content permit recognition of laterally contemporaneous delta-front and barrier lithofacies. The delta-front lithofacies consists of distal bar, distributary mouth bar, and distributary channel deposits. The barrier lithofacies consists of shoreface, beach, washover channel, tidal inlet, tidal channel, and ebb-tidal delta deposits; these lithofacies are coarsening-upward sequences of shale, siltstone and sandstone, locally scoured in the upper part by fining-upward channel deposits.-from Authors

Mountain Geologist↗
USGS2004

Non-invasive exploration in an environmentally sensitive world

Modern remote sensing provides a means for locating and characterizing exposed mineralized systems in many parts of the world. These capabilities are non-invasive and help target specific areas for more detailed exploration. An example of how remote sensing technology can be used is evident from a study of the Questa Mining District, New Mexico. Analysis of low spectral resolution data from the Landsat Thematic Mapper satellite system clearly shows the regional distribution of two broad mineral groups often associated with mineralized systems: clay-carbonate-sulfate and iron oxides-iron hydroxides. Analysis of high spectral resolution data from the Airborne Visible and Infrared Imaging System (AVIRIS) shows the occurrence and distribution of many individual mineral species that characterize the pattern of hydrothermally altered rocks in the district.

Conference Paper↗
USGS1986

Geology of the Harrisonburg and Bridgewater quadrangles, Virginia

The Harrisonburg and Bridgewater quadrangles comprise an area of approximately 117 square miles in Rockingham County in northwestern Virginia.This area is in the western part of the Shenandoah Valley, a portion of the Valley and Ridge physiographic province, and contains parts of three major geologic structures-the Staunton and North Mountain thrust faults and the Massanutten synclinorium.The roeks within the two quadrangles are folded and faulted limestones, dolomites, shales, and sandstones of Paleozoic age. These rocks have been divided into groups, formations, and members that include the Elbrook and Conococheague formations (Cambrian), the Stonehenge Formation, the Beekmantown Group, the New Market Limestone, and the Lineolnshire, Edinburg, and Martinsburg formations (Ordovieian), the Massanutten Sandstone and the Bloomsburg Formation (Silurian), and probably Upper Silurian and Iower and Middle Devonian limestones and shales that are not exposed but are judged to be on Massanutten Mountain. Triassic diabase dikes and Eocene volcanic pipes intrude the Paleozoic sequence locally. Much of the sequenee is eovered by alluvium or talus of Quaternary age. Selected strata of the Cambrian and Ordovician carbonate roek sequence are sources for road aggregate, agricultural lime, concrete aggregate, dimension stone, tettazzo, portland cement, flux stone, and pellet lime. Some of the carbonate rocks may be potential sources of lead and zinc minerals. Ordovician shale formations have potential for structural clay products.

Virginia↗
USGS2012

Cambrian–Ordovician sedimentary rocks of Alaska

Cambrian-Lower Ordovician carbonate rocks that likely formed as part of the Laurentian continental margin, and may thus have been part of the Cambrian-Ordovician great American carbonate bank, occur in east-central Alaska in the Nation Arch area. These strata accumulated on the southwestern margin (present-day coordinates) of the Yukon stable block, a broad area of early Paleozoic carbonate platform deposition in the northern Yukon Territory, and constitute two successions. The first consists of approximately 900 m (∼2950 ft) of shallow-water limestone and dolostone that are in part silicified, laminated, oolitic, and pisolitic, and make up the lower member of the Jones Ridge Limestone. Conodonts, trilobites, archaeo-cyathids, and brachiopods indicate an age of Early Cambrian to early Early Ordovician (Tremadoc; Ibexian) and have Laurentian biogeographic affinities. Upper Ordovician bio-clastic limestone (the upper member of the Jones Ridge Limestone) unconformably overlies these strata. A roughly coeval, but somewhat deeper water, succession crops out near the Jones Ridge Limestone and consists of, in ascending order, the Funnel Creek Limestone, Adams Argillite, and Hillard Limestone. The Funnel Creek (15-400 m [50-1310 ft] thick) is mainly nonfossilif-erous, extensively silicified, commonly oolitic limestone and dolostone and is assumed to be Lower Cambrian in age. It is overlain by argillite, siltstone, cross-laminated quartzite, and oolitic to sandy limestone of the Adams Argillite (90-180 m [295-550 ft] thick). This unit contains the trace fossil Oldhamia and Lower Cambrian archaeocyathids and trilobites that have Siberian affinities. The Hillard (30-150 m [100-490 ft] thick) is chiefly limestone, with local ooids, edgewise and boulder conglomerate, and phosphatic horizons, and likely formed in a platform-margin setting. Trilobites and brachiopods from this unit are Early Cambrian to earliest Ordovician in age and have mainly Laurentian affinities. Slope and/or basinal rocks of the Road River Formation that are as old as Early Ordovician (early middle Arenig; Ibexian) unconformably overlie the Hillard Limestone. Abrupt facies transitions between the two Nation Arch area carbonate successions may reflect relatively steep paleoslopes and/or telescoping of facies by imbricate thrust faults. Carbonate strata of Cambrian–Ordovician age are also found north of the Nation Arch area in the Porcupine terrane. These rocks have been little studied, and their precise Stratigraphic succession and paleogeographic setting are uncertain. The few fossil collections indicate mainly Laurentian affinities and include Cambrian(?) trilobites and Lower and Middle Ordovician conodonts. Lower Paleozoic strata of the Porcupine terrane probably formed at or near the northwestern edge (present-day coordinates) of the Yukon stable block. Cambrian–Ordovician carbonate strata occur widely in northern Alaska (parts of the Arctic Alaska, York, and Seward terranes) and interior Alaska (Farewell terrane). These rocks share distinctive lithologic and faunal features and were deposited in a range of shallow-shelf to basinal environments. Carbonate platform successions in northern and interior Alaska include fossils of both Laurentian and Siberian biotic provinces and may have formed on a single crustal fragment that rifted away from the Siberian craton during the late Proterozoic. These Alaskan strata were most likely in faunal exchange with, but not physically attached to, the great American carbonate bank. Lower–Middle Ordovician carbonate and siliciclastic rocks are also found in the White Mountains, Livengood, and Ruby terranes of interior Alaska, the Alexander terrane in southeastern Alaska, and the Goodnews terrane in southwestern Alaska. These successions were likely not attached to Laurentia during their deposition, although some authors have proposed Laurentian origins for the White Mountains and Livengood terranes. Little detailed information is available on the resource potential of Cambrian–Ordovician successions in Alaska. Most have low porosity and are too thermally mature to be prospective for oil and gas, although a few units in east-central and northern Alaska may have some potential as petroleum source and reservoir rocks. Strata of this age have potential for metallic mineral resources; strata-bound Zn-Pb ± Ag occurrences are known in the Funnel Creek Limestone in east-central Alaska, as well as several units of possible Cambrian and/or Ordovician age in northern and interior Alaska.

Alaska↗
USGS2013

Integrated geophysical imaging of a concealed mineral deposit: a case study of the world-class Pebble porphyry deposit in southwestern Alaska

We combined aeromagnetic, induced polarization, magnetotelluric, and gravity surveys as well as drillhole geologic, alteration, magnetic susceptibility, and density data for exploration and characterization of the Cu-Au-Mo Pebble porphyry deposit. This undeveloped deposit is almost completely concealed by postmineralization sedimentary and volcanic rocks, presenting an exploration challenge. Individual geophysical methods primarily assist regional characterization. Positive chargeability and conductivity anomalies are observed over a broad region surrounding the deposit, likely representing sulfide minerals that accumulated during multiple stages of hydrothermal alteration. The mineralized area occupies only a small part of the chargeability anomaly because sulfide precipitation was not unique to the deposit, and mafic rocks also exhibit strong chargeability. Conductivity anomalies similarly reflect widespread sulfides as well as water-saturated glacial sediments. Mineralogical and magnetic susceptibility data indicate magnetite destruction primarily within the Cu-Au-Mo mineralized area. The magnetic field does not show a corresponding anomaly low but the analytic signal does in areas where the deposit is not covered by postmineralization igneous rocks. The analytic signal shows similar lows over sedimentary rocks outside of the mineralized area, however, and cannot uniquely distinguish the deposit. We find that the intersection of positive chargeability anomalies with analytic signal lows, indicating elevated sulfide concentrations but low magnetite at shallow depths, roughly delineates the deposit where it is covered only by glacial sediments. Neither chargeability highs nor analytic signal lows are present where the deposit is covered by several hundred meters of sedimentary and volcanic rocks, but a 3D resistivity model derived from magnetotelluric data shows a corresponding zone of higher conductivity. Gravity data highlight geologic features within the deposit, including shallow diorite sills that locally contain higher-grade mineralization. The results thus show ways in which an integrated survey approach might be used to distinguish zones of potentially economic mineralization.

Alaska↗
USGS2021

Diagenetic barite-pyrite-wurtzite formation and redox signatures in Triassic mudstone, Brooks Range, northern Alaska

Mineralogical and geochemical studies of interbedded black and gray mudstones in the Triassic part of the Triassic-Jurassic Otuk Formation (northern Alaska) document locally abundant barite and pyrite plus diverse redox signatures. These strata, deposited in an outer shelf setting at paleolatitudes of ~45 to 60°N, show widespread sedimentological evidence for bioturbation. Barite occurs preferentially in black mudstones (TOC = 0.93–6.46 wt%), forming displacive euhedral crystals with pyrite inclusions and rims, and late albite inclusions or intergrowths. Pyrite also occurs as small (3–20 μm) framboids, discontinuous laminae, euhedral and anhedral crystals, and replacements of barite and fossils (mainly radiolarians). Paragenetically early wurtzite is present as clusters of very small (1–3 μm) aggregates of radiating crystals 0.5 to 1.0 μm long with cores of organic matter that overgrow framboidal pyrite; later wurtzite forms 10- to 30-μm bladed crystals. Equant grains (3–30 μm) and small (20 μm) angular clusters of zinc sulfide that include <1-μm-long, comb-like structures are sphalerite or wurtzite, or both. Minor siderite forms euhedral crystals intergrown with albite that enclose wurtzite and barite. Illite shows intergrowths with sphalerite; rare K-feldspar is intergrown with barite. Formation of these minerals and assemblages is attributed to early diagenetic processes. Whole-rock geochemical data for 15 samples show large ranges in redox proxies including Post Archean Average Shale (PAAS)-normalized enrichment factors (EFs) for V, U, Mo, and Re, and Al-normalized ratios for V, U, and Mo. Results for most black mudstones, with or without abundant barite and/or pyrite, suggest deposition within an oxygen minimum zone. Cerium anomalies, PAAS-normalized and calculated on a detrital-free basis, range widely from 0.49 to 0.96 and may reflect diagenetic overprinting by Ce-depleted fluids. Considering data for both black and gray mudstones, the overall geochemical pattern together with evidence from pyrite framboid sizes suggest that redox conditions fluctuated greatly from euxinic to oxic, like the redox profiles reported for modern shelf sediments offshore Peru and Namibia. The euxinic redox signatures in some Otuk black mudstones may correlate with widespread Early to Middle Triassic ocean anoxic events proposed for other regions. Calculations of median EFs for trace elements in Otuk black mudstones reveal both enrichments and depletions. Normalizations to the median composition of the three least-mineralized black mudstones show that barite- and/or pyrite-rich samples display large (>50%) positive changes for Li (+80.4%), V (+75.6%), Sr (+75.9%), Ba (+790%), Cu (+92.1%), Ni (+169%), Ag (+156%), Au (+3091%), As (+109%), Sb (+476%), and Se (+205%); Zn shows a moderate positive change of +42.1%. Moderate negative changes are evident only for Ge (−47.2%) and W (−30.6%). The local enrichments may reflect one or more factors including redox variations in bottom waters and pore fluids, element mobility during diagenesis, and selective fractionation into minerals such as barite, pyrite, and wurtzite. Anomalously low U/Al and UEF values, compared to those for other modern and ancient organic-rich sediments and sedimentary rocks, are attributed to increased solubility and loss of U during bioturbation-related oxygenation in the subsurface. Physicochemical constraints on barite, pyrite, and wurtzite formation are informed by use of a pH-fO2 plot constructed at 10 °C. Based on paragenetic evidence for multistage deposition of these three minerals, together with the presence of illite intergrown with ZnS and K-feldspar with barite, proposed diagenetic trends involve an increase in pH and fO2 related to the ingress of sulfate-rich pore fluids during bioturbation, followed by a return to lower then higher pH and fO2 conditions linked to carbon, sulfur, barium, and iron cycling during diagenesis. Labile Ba of marine pelagic origin was mobilized from organic-rich sediment upward to the sulfate-methane transition zone where barite precipitated during the interaction of reduced Ba- and CH4-rich fluids with sulfate-bearing pore fluids. The formation of paragenetically early wurtzite (ZnS) crystals, as well as locally high EF values for Cu, Ni, Ag, and Au, is attributed to metal enrichment of pore fluids, with sources being derived in part from water-column deposition from hydrothermal plumes related to coeval Triassic seafloor vent systems including a volcanogenic massive sulfide deposit in British Columbia and the Wrangellia Large Igneous Province in Alaska.

Alaska↗
USGS1985

Geology and regional setting of the Al Masane ancient mine area, southeastern Arabian Shield, Kingdom of Saudi Arabia

Stratiform zinc-copper massive-sulfide deposits at Al Masane occur in thin dolomitic interbeds within Proterozoic felsic crystal tuff and mafic flows and volcaniclastics. These strata dip steeply westward and are underlain by shale and shaly graywacke to the east and overlain by lapilli crystal tuff to the west. This section is part of the Habawnah fold or mineral belt that extends from the Wadi Wassat area southward into Yemen. Western parts of the Habawnah fold belt, including the Al Masane area, are characterized by a bimodal assemblage of of phenocryst-poor basalts and sodic rhyolite crystal tuff, and by zinc-copper mineral deposits. Strata in the eastern part of the belt, mostly east of the Ashara fault zone, contain abundant phenocryst-rich mafic volcanic rocks, little felsic crystal tuff, and barren or locally nickeliferous massive pyrite deposits. Stratified rocks and gabbro sills of the Al Masane area were isoclinally folded and metamorphosed to the greenschist facies. Structural analysis indicates that foliation, lineation, joints, major and minor folds, and one of three sets of faults formed during a single east-west compressional deformational episode. Axial-plane foliation dips steeply westward and is usually coincident with bedding. Lineation plunges steeply to the northwest throughout the map area and is parallel to the intersection of joints of two major sets and to the intersection of these joints with foliation. Major folds have north-trending, gently plunging axes to which the axis of a minor fold set is essentially parallel. A second minor fold-set has a steeply plunging axis parallel to lineation. The Saadah massive-sulfide body is elongated by a fold of this system. Unmetamorphosed Proterozoic felsic sills, quartz monzonite and gabbro plutons, porphyritic diorite dikes, mafic dikes, and basalt dikes, in that apparent order, have intruded the stratified section. Basalt dikes are offset by southwestward-dipping reverse faults and by faults parallel to bedding. Malachite and metal-oxide-bearing gossans in the Al Masane area were mined in ancient times. Radiocarbon dating of charcoal in slag indicates that the ores were smelted about 1,200 years ago. Gossans are depleted in copper, silver, and zinc, relative to underlying sulfide, by factors of about 0.33, 0.2, and 0.08, respectively. Evaluation of numerous analyses of gossans, carbonates, and silicate rocks indicates that exploration for zinc-copper massive-sulfide deposits in the region should center on detailed geochemical studies of dolomitic beds. Dolomitization of host siliceous shales and tuffs and the formation of the massive-sulfide bodies at Al Masane probably caused by submarine fumarolic hydrothermal activity during periods of relative volcanic quiescence. Further work in the Al Masane region should include a study of the dolomitized areas and a search for other potential alteration "pipe" products (e.g. chlorite) as a guide to location of proximal deposits. Zinc-copper deposits at Al Masane and in the Dhahar-Al Hajrah and Kutam-Farah Garan areas have characteristics in common and are associated with felsic volcanic centers in the western bimodal part of the Habawnah mineral belt. They probably have parallel origins related to sea-floor volcanism. Deposits at Al Masane and Dhahar-Al Hajrah are possibly in the same general stratigraphic interval. Characteristics and distribution of altered rocks at Kutam suggest that the observed structural control of mineralization may represent remobilization. Chemical characteristics of volcanic rocks at Al Masane and elsewhere, along with features such as zinc-copper-iron sulfide mineralization, rhyolite-basalt bimodality, and the quartz phenocryst-rich nature of the felsic rocks, are compatible with an unusually primitive tholeiitic island-arc origin for the strata and mineral deposits of the Habawnah mineral belt.

Open-File Report↗
USGS2017

Strontium isotopic systematics of mineralized and background water samples, Montezuma Mining District, Colorado

Surface and groundwater samples within the Montezuma mining district were sampled to evaluate the use of strontium isotopic compositions as signatures of different water types. Waters draining Precambrian metamorphic units had distinctly higher 87Sr/ 86Sr values (0.72893 to 0.73833) than waters draining Tertiaryage plutonic rocks (0.71064 and 0.71114). Waters draining mine workings along Tertiary-age mineralized veins in Precambrian metamorphic units had isotopic compositions between these two endmembers such that Sr isotopic composition could not be used as a unique signature of mining-related waters.

Conference Paper↗
USGS1974

Stratigraphy and nahcolite resources of the saline facies of the Green River Formation, Rio Blanco County, Colorado

Based on a study of 10 drill cores, a sequence of oil shale and associated nahcolite, nearly 2,000 feet thick, in the lacustrine Green River Formation (Eocene) in the Piceance Creek basin, Rio Blanco County, Colo., was divided in ascending order into zones 1 to 13, B-groove, Mahogany zone (with lower, middle, and upper parts), and A-groove at the top. The odd-numbered zones and the Mahogany zone are mappable subsurface units of relatively thick oil shale and are distinguished from the even-numbered zones and A- and B-grooves which are thinner units of oil shale of lower grade. Large amounts of nahcolite found in zones 5 to 12 occur in (1) coarse-grained crystalline aggregates scattered through oil shale, (2) laterally continuous units of fine-grained crystals disseminated in oil shale, (3) brown microcrystalline beds, and (4) white coarse-grained beds that grade laterally into halitic rocks toward basin center. The original .upper limit of the nahcolite and halitic rocks is not yet completely known, but the present top is marked by a dissolution surface. Above this surface the rocks, extending from zones 11 or 12 upward into the Mahogany zone, form a water-saturated 'leached zone,' a geohydrologic unit in which large amounts of water-soluble minerals probably mostly nahcolite, and halite, were removed by ground-water dissolution. Rocks in the leached zone, mostly oil shale, are commonly broken and fractured and contain crystal cavities and solution breccias. Several solution breccias can be traced laterally into unleached beds of nahcolite and halite. Although evidence of salines is found in rocks above A-groove, the original saline facies that includes most of the bedded deposits extends from zone 5 upward into A-groove. Potentially ruinable beds of white nahcolite as much as 12 feet thick are found at depths of 1,560 or more feet below the surface. Some thicker beds of high-grade nahcolite are believed to be too close to the dissolution surface for safe room-and-pillar mining. Probably the most economical method of mining nahcolite would be as a coproduct of a shale-oil industry. Removal of nahcolite prior to retorting increases significantly the grade of oil shale by as much as 1.6 times, Several zones are more than 300 feet thick and average 30 or more weight percent nahcolite. Resources of nahcolite per square mile range as high as 489 million short tons. The total nahcolite resource in the basin is conservatively estimated at 32 billion short tons, which makes it the secondlargest deposit of sodium carbonate known .in the world.

Open-File Report↗
USGS1994

Dissolved volatile concentrations in an ore-forming magma

Infrared spectroscopic measurements of glass inclusions within quartz phenocrysts from the Plinian fallout of the 22 Ma tuff of Pine Grove show that the trapped silicate melt contained high concentrations of H2O and CO2. Intrusive porphyries from the Pine Grove system are nearly identical in age, composition, and mineralogy to the tephra, and some contain high-grade Mo mineralization. Assuming that the porphyry magmas originally contained similar abundances of volatile components as the erupted rocks, they would have been saturated with fluid at pressures far greater than those at which the porphyries were emplaced and mineralized. The data are consistent with formation of Climax-type Mo porphyry deposits by prolonged fluid flux from a large volume of relatively Mo-poor (1-5 ppm) magma. -from Author

Geology↗
USGS1966

Mines and prospects, Idaho Springs district, Clear Creek and Gilpin counties, Colorado -- Descriptions and maps

The Idaho Springs mining district forms an important segment of the Front Range mineral belt, a northeast-trending zone of coextensive intrusive rocks and hydrothermal ore deposits of early Tertiary age. This belt, which is about 50 miles long, extends from the region just west of Boulder southwestward across the Front Range. From 1859, when placer gold was discovered in Idaho Springs and lode gold in Central City, through 1959, ores valued at about $ 200 million were shipped from a 50-square-mile area that includes the Idaho Springs and adjacent districts to the north, west, and southwest. The adjacent Central City district, which produced ores valued at more than \$ 100 million, is clearly the most important district in the mineral belt. The Idaho Springs district from 1860 to 1959 produced ores valued at about $65 million, and the districts to the west and southwest produced smaller amounts. Gold has accounted for about 60 percent of the value of the ore, but in some areas silver provides the chief values, and copper, lead, and zinc add value to the ores in most areas. Mining activity in the Idaho Springs and adjacent districts was at its 'heyday' in the late 1800's, it declined sharply after 1914, it was somewhat renewed during the 1930's, and it greatly declined during World War II. In the 1950's uranium prospecting stimulated some mining activity. No uranium was produced, however, and at the close of the decade only one mine--the Bald Eagle--was being worked for its precious- and base-metal ores. In this report, 135 mines and prospects are described. The mines and prospects described are those that were accessible at the time of this study, as well as a few inaccessible properties for which some information was available. Most of the data for the inaccessible or unimportant properties were obtained from Bastin and Hill (1917) and Spurr, Garrey, and Ball (1908). The following list shows, in alphabetical order, the names of about 325 openings of mines and prospects, their coordinate location on the district map (fig. 1), the page of this report on which their description starts, and the number of the illustration, if any, referring to them.

Colorado↗
USGS2020

Precious and base metal mineralization within the lower stratigraphy of the Stillwater Complex: New targets defined and old targets revisited

Group Ten Metals is exploring for base and precious metals within the Stillwater Complex, a 2.7 Ga layered mafic/ultramafic intrusion, host to the world-class Sibanye platinum group element (PGE) mines. Group Ten controls approximately 25 kilometers of strike length of prospective mafic and ultramafic rocks in the western portion of the Complex. The property includes multiple target types and individual prospects. Stillwater Complex magmatic stratigraphy is divided into three major series based on the proportions of cumulus minerals—Basal, Ultramafic and Banded. Group Ten explores primarily within the lower third of the intrusion, from the Basal Series at the footwall contact, upwards into the Ultramafic Series which is divided into a lower Peridotite Zone and an upper Bronzitite Zone. Rocks of the Peridotite Zone are repetitive, laterally continuous and layered sequences of olivine, chromite and pyroxene cumulates. This model was developed in the eastern portion of the Complex. Mapping in the western portion of the Complex indicates that the Peridotite Zone is thinner than to the east and with cyclic units not as regularly developed. Group Ten has reviewed data from over 50 years of historical exploration in light of different commodity focus, land positions, analytical menus, and petrogenetic models to define a series of exploration targets. A six hole, 1,600 meter diamond drilling program targeting the Iron Mountain sector was completed in 2019; results are discussed in more detail below. At Iron Mountain the primary targets are Ni-Cu-PGE magmatic sulfides located within the Basal Series and lower Peridotite Zone, near the basal contact of the Complex. Important objectives included establishing the PGE tenor of sulfide mineralization drilled by AMAX in the 1970’s and penetrating basement rock rafts known to conceal mineralized (but not previously analyzed) ultramafic rocks beneath. Drilling also tested the PGE-enriched A-B chromitite package which rests stratigraphically above the previously tested zones. At Chrome Mountain, magmatic layering was disturbed or destroyed over large areas along a WNW axis that may be an artifact of early magma chamber deformation or result from much later, Laramide tectonism. Correlation of marker units, for example chromitite seams, are problematic in the disturbed area; these rocks are termed the Hybrid Unit. In addition, normal igneous stratigraphy appears to be intruded by discordant dunite masses, pyroxenite pegmatoids and magmatic breccias. This unusual assemblage of rock types is accompanied by significant and previously underappreciated PGE mineralization related to chromite schlieren and minor but persistent base metal sulfides.

Conference Paper↗
USGS1950

The Leyden uranium prospect, Jefferson County, Colorado

The Leyden uranium prospect is in sec. 28, T, 2 S., R. 70 W, Jefferson County, Cplo, Examination of the property was made in February 1950. Uranium was first reported in this locality in 1875 by Captain E. L. Berthoud, who noted uranium minerals associated with the main coal bed. The Old Leyden coal mine workings have long been abandoned and caved, but specimens of the uranium-bearing rock can be seen on the old dump 700 feet to the south. The mineralized coal bed is 10 to 12 feet thick and occurs near the base of the Laramie formation of Upper Cretaceous age. Uranium minerals are present in the form of yellow incrustations and inclusions in fractured and partly silicified coal. Petrographic studies indicate that the silica and uranium minerals were deposited after deposition and carbonization of the coal. Secondary uranium minerals also were found by C. R. Butler along the outcrop of the sandstones in the Laramie formation. No uranium minerals were found in place by the writer, but four samples from the dump contained 0.001, 0,005, 0.17 and 0.69 percent uranium.

Colorado↗
USGS2020

Preliminary bedrock geologic map of the Lahore 7.5-minute quadrangle, Orange, Spotsylvania, and Louisa Counties, Virginia

Introduction Bedrock geologic mapping of the Lahore, Va., 7.5-minute quadrangle was completed as part of a broader project, undertaken jointly between the U.S. Geological Survey, the Virginia Division of Geology and Mineral Resources, and other Federal and State agencies to better understand the causative mechanisms of the magnitude-5.8 (M5.8) earthquake that occurred near Mineral, Va., on August 23, 2011. This project involved detailed mapping of eight quadrangles in the epicentral region of the Mineral, Va., earthquake in order to improve our understanding of the geologic framework of the central Virginia seismic zone, which has a long record of historical and prehistoric seismicity. The Lahore 7.5-minute quadrangle contains the contact between Ordovician to Silurian, dioritic and granodioritic rocks of the Lahore and Ellisville plutons and older metasedimentary and metavolcanic rocks. The Lahore quadrangle is northeast of the Ferncliff and Louisa, Va., quadrangles, where the Shores complex is intruded by the Ellisville pluton along the pluton’s southwestern margin. The new mapping in the Lahore quadrangle shows that the Shores complex continues northeast of the Ellisville pluton. A northeast-trending mafic- and ultramafic-bearing belt within the Shores complex is a fault-bounded accretionary zone (accretionary wedge) between rocks of the Chopawamsic Formation and Laurentian slope-and-rise deposits. In the Lahore quadrangle, this belt contains several mappable, northeast- to southwest-trending mafic bodies and also includes small exposures of gabbro and talc schist. The Lahore quadrangle contains structures of both early- and late-Paleozoic age that correspond to the Taconic and Alleghanian orogenies. Taconic (Late Ordovician) S 1 schistosity in layered rocks is typically fine-grained and parallel to compositional layering, when present. Alleghanian (Pennsylvanian) S 2 schistosity is coarser and more micaceous than S 1 and is locally accompanied by a lineation that is represented by mineral lineations, micro-crenulations, or mullion fabric, and represents the hinges of F 2 folds. A foliation in the plutonic rocks is represented by an equilibrium assemblage of aligned mafic minerals and is early Paleozoic in age. Metamorphic grade in the non-plutonic rocks of the Lahore quadrangle ranges from lower-greenschist to the northwest to upper-greenschist to the southeast, as represented by mineral assemblages in non-plutonic rocks. The biotite isograd may be, in part, lithologically controlled by the contact between the informally-named Hardware and Byrd Mill formations, and locally affected by contact metamorphism by the Lahore pluton (western part of map). The Taconic garnet isograd is defined by the sparse presence of small (less than 1 millimeter), euhedral garnet crystals. Both the biotite and garnet isograds continue along strike to the southwest into the Ferncliff and Louisa quadrangles, where the isograds have been identified as Ordovician age (Taconic orogeny) based on muscovite, biotite, and amphibole 40 Ar/ 39 Ar cooling ages. Regionally, the most common trend and plunge of joints is northwest and subvertical, respectively, and orthogonal to the regional strike of foliation. Early Mesozoic extension may have reactivated the Harris Creek fault (southeast corner of map), a late Paleozoic (Alleghanian orogeny) transpressional fault that marks the contact between granodiorite of the Ellisville pluton and the Chopawamsic Formation.

Virginia↗
USGS2005

Questa baseline and premining ground-water quality investigation. 8. Lake-sediment geochemical record from 1960 to 2002, Eagle Rock and Fawn Lakes, Taos County, New Mexico

Geochemical studies of lake sediment from Eagle Rock Lake and upper Fawn Lake were conducted to evaluate the effect of mining at the Molycorp Questa porphyry molybdenum deposit located immediately north of the Red River. Two cores were taken, one from each lake near the outlet where the sediment was thinnest, and they were sampled at 1-cm intervals to provide geochemical data at less than 1-year resolution. Samples from the core intervals were digested and analyzed for 34 elements using ICP–AES (inductively coupled plasma–atomic emission spectrometry). The activity of 137 Cs has been used to establish the beginning of sedimentation in the two lakes. Correlation of the geochemistry of heavy-mineral suites in the cores from both Fawn and Eagle Rock Lakes has been used to develop a sedimentation model to date the intervals sampled. The core from upper Fawn Lake, located upstream of the deposit, provided an annual sedimentary record of the geochemical baseline for material being transported in the Red River, whereas the core from Eagle Rock Lake, located downstream of the deposit, provided an annual record of the effect of mining at the Questa mine on the sediment in the Red River. Abrupt changes in the concentrations of many lithophile and deposit-related metals occur in the middle of the Eagle Rock Lake core, which we correlate with the major flood-of-record recorded at the Questa gage at Eagle Rock Lake in 1979. Sediment from the Red River collected at low flow in 2002 is a poor match for the geochemical data from the sediment core in Eagle Rock Lake. The change in sediment geochemistry in Eagle Rock Lake in the post-1979 interval is dramatic and requires that a new source of sediment be identified that has substantially different geochemistry from that in the pre-1979 core interval. Loss of mill tailings from pipeline breaks are most likely responsible for some of the spikes in trace-element concentrations in the Eagle Rock Lake core. Enrichment of Al 2 O 3 , Cu, and Zn occurred as a result of chemical precipitation of these metals from ground water upstream in the Red River. Comparisons of the geochemistry of the post-1979 sediment core with both mine wastes and with premining sediment from the vicinity of the Questa mine indicate that both are possible sources for this new component of sediment. Existing data have not resolved this enigma.

New Mexico↗