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Mid-infrared diffuse reflectance spectroscopic examination of charred pine wood, bark, cellulose, and lignin: Implications for the quantitative determination of charcoal in soils

Fires in terrestrial ecosystems produce large amounts of charcoal that persist in the environment and represent a substantial pool of sequestered carbon in soil. The objective of this research was to investigate the effect of charring on mid-infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred organic matter in soils. Four materials (cellulose, lignin, pine bark, and pine wood) and char from these materials, created by charring for various durations (1 to 168 h) and at various temperatures (200 to 450 °C), were studied. Mid-infrared spectra and measures of acidity (total acids, carboxylic acids, lactones, and phenols as determined by titration) were determined for 56 different samples (not all samples were charred at all temperatures/durations). Results showed spectral changes that varied with the material, temperature, and duration of charring. Despite the wide range of spectral changes seen with the differing materials and length/temperature of charring, partial least squares calibrations for total acids, carboxylic acids, lactones, and phenols were successfully created (coefficient of determination and root mean squared deviation of 0.970 and 0.380; 0.933 and 0.227; 0.976 and 0.120; and 0.982 and 0.101 meq/g, respectively), indicating that there is a sufficient commonality in the changes to develop calibrations without the need for unique calibrations for each specific material or condition of char formation.

Applied Spectroscopy↗

Occurrence of pesticides in water, sediment, and soil from the Yolo Bypass, California

The objective of this study was to evaluate the potential sources of pesticides to the Yolo Bypass, including those that could potentially impact critical life stages of resident fish. To assess direct inputs during inundation, pesticide concentrations were analyzed in water and suspended and bed sediment samples collected from source watersheds during high-flow events. To understand inputs from direct application on fields, pesticides were also measured in soils collected from several sites within the Bypass. Thirteen current-use pesticides were detected in water samples collected in 2004 with the highest pesticide concentrations observed at the input sites to the Bypass during high-flow. Hexazinone and simazine were detected at all sites and at some of the highest concentrations. In bed and suspended sediments collected in 2004 and 2005, thirteen current-use pesticides were detected along with DDT and its metabolites. Trifluralin, DDE, and DDT were highest in the bed sediments, whereas oxyfluorfen and thiobencarb were highest in the suspended sediments. With the exception of the three organochlorine insecticides, suspended sediments had higher pesticide concentrations compared to bed sediments, indicating the potential for pesticide transport especially during high-flow events. Soil samples were dominated by DDT and its degradates but also contained a variety of current-use pesticides typically at lower concentrations. The types of pesticides detected in water and sediments were correlated with agricultural application in each watershed. Understanding the distribution of pesticides between the water and sediment is important in assessing their fate and transport within the Bypass, and in evaluating the exposure and potential effects to resident fish.

California↗

Simulation of broadband ground motion including nonlinear soil effects for a magnitude 6.5 earthquake on the Seattle fault, Seattle, Washington

The Seattle fault poses a significant seismic hazard to the city of Seattle, Washington. A hybrid, low-frequency, high-frequency method is used to calculate broadband (0-20 Hz) ground-motion time histories for a M 6.5 earthquake on the Seattle fault. Low frequencies (1 Hz) are calculated by a stochastic method that uses a fractal subevent size distribution to give an ω -2 displacement spectrum. Time histories are calculated for a grid of stations and then corrected for the local site response using a classification scheme based on the surficial geology. Average shear-wave velocity profiles are developed for six surficial geologic units: artificial fill, modified land, Esperance sand, Lawton clay, till, and Tertiary sandstone. These profiles together with other soil parameters are used to compare linear, equivalent-linear, and nonlinear predictions of ground motion in the frequency band 0-15 Hz. Linear site-response corrections are found to yield unreasonably large ground motions. Equivalent-linear and nonlinear calculations give peak values similar to the 1994 Northridge, California, earthquake and those predicted by regression relationships. Ground-motion variance is estimated for (1) randomization of the velocity profiles, (2) variation in source parameters, and (3) choice of nonlinear model. Within the limits of the models tested, the results are found to be most sensitive to the nonlinear model and soil parameters, notably the over consolidation ratio.

Washington↗

Biological soil crusts across disturbance-recovery scenarios: effect of grazing regime on community dynamics

Grazing represents one of the most common disturbances in drylands worldwide, affecting both ecosystem structure and functioning. Despite the efforts to understand the nature and magnitude of grazing effects on ecosystem components and processes, contrasting results continue to arise. This is particularly remarkable for the biological soil crust (BSC) communities (i.e., cyanobacteria, lichens, and bryophytes), which play an important role in soil dynamics. Here we evaluated simultaneously the effect of grazing impact on BSC communities (resistance) and recovery after livestock exclusion (resilience) in a semiarid grassland of Central Mexico. In particular, we examined BSC species distribution, species richness, taxonomical group cover (i.e., cyanobacteria, lichen, bryophyte), and composition along a disturbance gradient with different grazing regimes (low, medium, high impact) and along a recovery gradient with differently aged livestock exclosures (short-, medium-, long-term exclusion). Differences in grazing impact and time of recovery from grazing both resulted in slight changes in species richness; however, there were pronounced shifts in species composition and group cover. We found we could distinguish four highly diverse and dynamic BSC species groups: (1) species with high resistance and resilience to grazing, (2) species with high resistance but low resilience, (3) species with low resistance but high resilience, and (4) species with low resistance and resilience. While disturbance resulted in a novel diversity configuration, which may profoundly affect ecosystem functioning, we observed that 10 years of disturbance removal did not lead to the ecosystem structure found after 27 years of recovery. These findings are an important contribution to our understanding of BCS dynamics from a species and community perspective placed in a land use change context.

Ecological Applications↗

Legacy effects in linked ecological-soil-geomorphic systems of drylands

A legacy effect refers to the impacts that previous conditions have on current processes or properties. Legacies have been recognized by many disciplines, from physiology and ecology to anthropology and geology. Within the context of climatic change, ecological legacies in drylands (eg vegetative patterns) result from feedbacks between biotic, soil, and geomorphic processes that operate at multiple spatial and temporal scales. Legacy effects depend on (1) the magnitude of the original phenomenon, (2) the time since the occurrence of the phenomenon, and (3) the sensitivity of the ecological–soil–geomorphic system to change. Here we present a conceptual framework for legacy effects at short-term (days to months), medium-term (years to decades), and long-term (centuries to millennia) timescales, which reveals the ubiquity of such effects in drylands across research disciplines.

Frontiers in Ecology and the Environment↗

Health status and relative exposure of mule deer and white-tailed deer to soil contaminants at the rocky mountain arsenal

We evaluated the health of 18 radio-collared deer [13 mule deer ( Odocoileus hemionus ) and 5 white-tailed deer ( O. virginianus )] from the Rocky Mountain Arsenal, near Denver, Colorado, USA, a Superfund site contaminated with a variety of materials, including organochlorine pesticides, metals, and nerve gas production by-products. Radio-collared deer were tracked for 1 to 3 years (1989–1992) to identify relative exposure to contaminants based on telemetry locations plotted on grid maps depicting known soil contaminant concentrations. At the end of the study, all animals were in fair or good body condition at the time of necropsy. Mean ages of mule deer and white-tailed deer were 7.4 (range 4–12) and 10.6 years (range 5–17), respectively. At necropsy, tissues were collected from the deer for serology, histopathology, and analysis for eight chlorinated hydrocarbons and two metals. Detectable residues of mercury were found in the kidneys of 10 deer (range 0.055–0.096 μg/g), dieldrin was found in fat ( n = 9) (range 0.02–0.72 μg/g), liver ( n = 4) (range 0.017–0.12 μg/g), and brain ( n = 1, 0.018 μg/g), and DDE was found in the muscle of one animal (0.02 μg/g). Relative exposure estimates derived from telemetry and soil contamination data were correlated with tissue levels of dieldrin ( p < 0.001) and mercury ( p = 0.05). Two mule deer had severe testicular atrophy, and one of these animals also had antler deformities. The prevalence of antibodies against epizootic hemorrhagic disease serotype 2 was 85%.

Colorado↗

Catchment disturbance and stream metabolism: Patterns in ecosystem respiration and gross primary production along a gradient of upland soil and vegetation disturbance

Catchment characteristics determine the inputs of sediments and nutrients to streams. As a result, natural or anthropogenic disturbance of upland soil and vegetation can affect instream processes. The Fort Benning Military Installation (near Columbus, Georgia) exhibits a wide range of upland disturbance levels because of spatial variability in the intensity of military training. This gradient of disturbance was used to investigate the effect of upland soil and vegetation disturbance on rates of stream metabolism (ecosystem respiration rate [ER] and gross primary production rate [GPP]). Stream metabolism was measured using an open-system, single-station approach. All streams were net heterotrophic during all seasons. ER was highest in winter and spring and lowest in summer and autumn. ER was negatively correlated with catchment disturbance level in winter, spring, and summer, but not in autumn. ER was positively correlated with abundance of coarse woody debris, but not significantly related to % benthic organic matter. GPP was low in all streams and generally not significantly correlated with disturbance level. Our results suggest that the generally intact riparian zones of these streams were not sufficient to protect them from the effect of upland disturbance, and they emphasize the role of the entire catchment in determining stream structure and function. ?? 2005 by The North American Benthological Society.

Journal of the North American Benthological Societ↗

Field method for the determination of zinc in soils

A method is described for the field estimation of total zinc in soils. A small sample of soil is fused with potassium bisulfate, the fused mass dissolved in water, buffered at pH 4 to 5.5 with acetate buffer, and sodium thiosulfate added to form complex ions with metals that might cause interference. Measured increments of the sample solution are added to a carbon-tetrachloride-dithizone solution, with vigorous shaking after each addition, until a standard color is obtained in the organic phase. Under favorable conditions up to 60 determinations per day can be made by one man. Comparisons of data obtained by the field method with accurate laboratory analyses of the same samples indicate that the method is sufficiently reliable for reconnaissance surveys.

Economic Geology↗

A case study of soil gases as an exploration guide in glaciated terrain: Crandon massive sulfide deposit, Wisconsin

The Crandon massive sulfide deposit is covered by as much as 65 m of glacial drift. Soil gas was sampled at a depth of 0.5 m along several traverses over the deposit. Gases showing anomalies that correlate with the underlying deposit include CO 2 , CH 4 , and O 2 . CO 2 and CH 4 show positive anomalies with a background/anomaly ratio as high as 1 to 25, whereas O 2 shows negative anomalies. Oxidation of the sulfides with the production of sulfate is the probable chemical reaction producing some of the gas anomalies. The CH 4 anomalies may result from thermal cracking of hydrocarbon precursors. These results indicate that measurement of soil gases should provide a useful exploration tool in glacial terrain.

Economic Geology↗

A comparison of four geophysical methods for determining the shear wave velocity of soils

The Missouri Department of Transportation (MoDOT) routinely acquires seismic cone penetrometer (SCPT) shear wave velocity control as part of the routine investigation of soils within the Mississippi Embayment. In an effort to ensure their geotechnical investigations are as effective and efficient as possible, the SCPT tool and several available alternatives (crosshole [CH]; multichannel analysis of surface waves [MASW]; and refraction microtremor [ReMi]) were evaluated and compared on the basis of field data acquired at two test sites in southeast Missouri. These four methods were ranked in terms of accuracy, functionality, cost, other considerations, and overall utility. It is concluded that MASW data are generally more reliable than SCPT data, comparable to quality ReMi data, and only slightly less accurate than CH data. However, the other advantages of MASW generally make it a superior choice over the CH, SCPT, and ReMi methods for general soil classification purposes to depths of 30 m. MASW data are less expensive than CH data and SCPT data and can normally be acquired in areas inaccessible to drill and SCPT rigs. In contrast to the MASW tool, quality ReMi data can be acquired only in areas where there are interpretable levels of "passive" acoustic energy and only when the geophone array is aligned with the source(s) of such energy.

Environmental & Engineering Geoscience↗

Soil-test N recommendations augmented with PEST-optimized RZWQM simulations

Improved understanding of year-to-year late-spring soil nitrate test (LSNT) variability could help make it more attractive to producers. We test the ability of the Root Zone Water Quality Model (RZWQM) to simulate watershed-scale variability due to the LSNT, and we use the optimized model to simulate long-term field N dynamics under related conditions. Autoregressive techniques and the automatic parameter calibration program PEST were used to show that RZWQM simulates significantly lower nitrate concentration in discharge from LSNT treatments compared with areas receiving fall N fertilizer applications within the tile-drained Walnut Creek, Iowa, watershed (>5 mg N L-1 difference for the third year of the treatment, 1999). This result is similar to field-measured data from a paired watershed experiment. A statistical model we developed using RZWQM simulations from 1970 to 2005 shows that early-season precipitation and early-season temperature account for 90% of the interannual variation in LSNT-based fertilizer N rates. Long-term simulations with similar average N application rates for corn (Zea mays L.) (151 kg N ha-1) show annual average N loss in tile flow of 20.4, 22.2, and 27.3 kg N ha -1 for LSNT, single spring, and single fall N applications. These results suggest that (i) RZWQM is a promising tool to accurately estimate the water quality effects of LSNT; (ii) the majority of N loss difference between LSNT and fall applications is because more N remains in the root zone for crop uptake; and (iii) year-to-year LSNT-based N rate differences are mainly due to variation in early-season precipitation and temperature. Copyright ?? 2010 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

Plant-based plume-scale mapping of tritium contamination in desert soils

Plant-based techniques were tested for field-scale evaluation of tritium contamination adjacent to a low-level radioactive waste (LLRW) facility in the Amargosa Desert, Nevada. Objectives were to (i) characterize and map the spatial variability of tritium in plant water, (ii) develop empirical relations to predict and map subsurface contamination from plant-water concentrations, and (iii) gain insight into tritium migration pathways and processes. Plant sampling [creosote bush, Larrea tridentata (Sessé & Moc. ex DC.) Coville] required one-fifth the time of soil water vapor sampling. Plant concentrations were spatially correlated to a separation distance of 380 m; measurement uncertainty accounted for <0.1% of the total variability in the data. Regression equations based on plant tritium explained 96 and 90% of the variation in root-zone and sub-root-zone soil water vapor concentrations, respectively. The equations were combined with kriged plant-water concentrations to map subsurface contamination. Mapping showed preferential lateral movement of tritium through a dry, coarse-textured layer beneath the root zone, with concurrent upward movement through the root zone. Analysis of subsurface fluxes along a transect perpendicular to the LLRW facility showed that upward diffusive-vapor transport dominates other transport modes beneath native vegetation. Downward advective-liquid transport dominates at one endpoint of the transect, beneath a devegetated road immediately adjacent to the facility. To our knowledge, this study is the first to document large-scale subsurface vapor-phase tritium migration from a LLRW facility. Plant-based methods provide a noninvasive, cost-effective approach to mapping subsurface tritium migration in desert areas.

Vadose Zone Journal↗

Long-term soil-water tension measurements in semi-arid environments: A method for automated tensiometer refilling

Tensiometer-equipped data acquisition systems measure and record positive and negative soil-water pressures. These data contribute to studies in hillslope hydrology, including analyses of rainfall runoff, near-surface hydrologic response, and slope stability. However, the unique ability of a tensiometer to rapidly and accurately measure pre- and post-saturation subsurface pressures requires maintenance techniques that have precluded their application to unattended sensor networks in semiarid regions. Under suction, the de-aired water in the tensiometer is drawn from a porous cup. Under positive pressure, dissolved gases from pore water infiltrates the cup. Over time, both contribute to unreliable readings and/or poor signal response through cavitation. To address this problem, we used commercially available equipment to develop a simple system of solenoid valves and a water reservoir that enable automated in situ tensiometer refilling. We tested the system at two post-wildfire hydrologic monitoring sites in the Angeles National Forest, southern California. We present example results from 3 mo of monitoring and show how the tensiometers can be refilled by a remote trigger. By remotely refilling the tensiometer, we were able to continuously monitor quasi-saturated soil pore-water pressures without making repeated and costly maintenance visits.

Vadose Zone Journal↗

Geochemistry and Soils of the Big Smoky Valley Fens, Nevada

Fens are groundwater-fed wetlands that can provide habitat for plants and animals. Due to anthropogenic activities and climate change, many fens around the world are at risk. This paper presents the results of a study of the hydrology and geochemistry of fens in Big Smoky Valley, central Nevada to support the Bureau of Land Management’s activities in the area. A water sample from the largest fen in the study area was analyzed for its water chemistry and compared to a nearby alluvial aquifer and hot spring. The high SiO 2 concentration of the fen sample implies that the fen water may originate from geothermal water. A soil core was taken to analyze radiocarbon age and soil type. A majority of the core was composed of silt and clay interlayered with water-filled voids. Changes in the character of the clay with depth suggest that there may have been changes in the depositional environment over time. Radiocarbon dating of Ruppia seeds showed longevity of the fen, with the minimum 14 C age of the core as 4,375±40 years. This paper provides reconnaissance-level information on the Big Smoky Valley fens, but further information would be needed to better understand the source of water to the fens or how the fen environment has changed over time with climate.

Nevada↗

Soil relative dating of moraine and outwash-terrace sequences in the northern part of the upper Arkansas Valley, central Colorado, U.S.A.

Profile development indices for soils developed in moraines and outwash near Twin Lakes and in outwash near Leadville support the correlation of moraines with subdued morphology and two high outwash terraces with the Bull Lake glaciation (ca. 130-160 ka) and the correlation of hummocky moraines and two low outwash terraces with the Pinedale glaciation (ca. 14-47 ka). Elsewhere in the northern part of the upper Arkansas Valley, glacial sequences are correlated by mapping outwash terraces near the mouths of major tributaries of the Arkansas River. Near Twin Lakes, indices for soils on low, outer lateral moraines suggest that the older Pinedale glaciers extended beyond the margin of high, younger Pinedale lateral moraines with hummocky topography. A few subdued moraines near Twin Lakes and Leadville probably record one or more glaciations significantly older than the Bull Lake. The downvalley extent of Pinedale glaciers in the Mosquito Range on the east side of the Arkansas Valley is uncertain: most likely, Pinedale glaciers were almost as extensive as Bull Lake glaciers but built no prominent terminal moraines at their maximum positions.

Colorado↗

Spatial and temporal variation in soil and vegetation impacts on campsites

We studied the impacts of camping on soil and vegetation at Delaware Water Gap national Recreation Area. We assessed the magnitude of impact on campsites that varied in amount of use and in topographic position. We also evaluated change over a 5-yr period on long-established, recently opened, and recently closed campsites, as well as on plots subjected to experimental trampling. Campsite impacts were intense and spatially variable. Amount of use and topographic position explained some of this variation. Soil and vegetation conditions changed rapidly when campsites were initially opened to use and when they were closed to use. Changes were less pronounced on the long-established campsites that remained open to use. In the trampling experiments, impact varied greatly with trampling intensity and between vegetation types. An open-canopy grassland vegetation type was much more resistant to trampling than a forb-dominated forest vegetation type. Campsite impacts increased rapidly with initial disturbance, stabilized with ongoing disturbance, and–in contrast to what has been found in most other studies–decreased rapidly once disturbance was terminated. Implications of these results for campsite management strategies, such as use concentration or dispersal, and rotation or closure of campsites, are discussed.

New Jersey, Pennsylvania↗

Clonal foraging in perennial wheatgrasses: A strategy for exploiting patchy soil nutrients

1. Foraging by means of plasticity in placement of tillers in response to low- and high-nutrient patches was examined in the rhizomatous wheatgrass Elymus lanceolatus ssp. lanceolatus . Its ability to exploit soil nutrient patches was compared to that of the closely related but caespitose E. lanceolatu s ssp. wawawaiensis . 2. Clones of 14 genets of each taxon were planted in boxes consisting of two 30 × 30 cm cells: the `origin cell' where clones were planted, and the adjacent `destination cell', with each cell containing soil with either low or high levels of nutrients. 3. The rhizomatous taxon, which can produce intravaginal, short-rhizome and long-rhizome tillers, preferentially produced short-rhizome and intravaginal tillers in high-nutrient destination cells. Effects of nutrient status of the origin cell as well as of the destination cell on total tiller numbers indicated clonal integration, yet tiller placement responded to local conditions. 4. Roots of both taxa accessed nutrients in destination cells (the caespitose subspecies by root growth only), and above-ground biomass of both taxa increased to a similar extent with high-nutrient destination cells. With the patch sizes used in this experiment, root growth was as important as ramet placement in exploiting nutrients in destination cells. 5 There was no relationship between degree of plasticity in ramet placement and biomass of the clone when high-nutrient destination cells were present.

Journal of Ecology↗