Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “Rock Products”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,513 records · Page 84Linked to original sources

Geology and ground-water resources of Cerro Gordo County, Iowa

The basic geologic framework underlying Cerro Gordo County consists of an igneous or metamorphic Precambrian basement complex overlain by, in ascending order, consolidated sedimentary rocks of Precambrian, Cambrian, Ordovician, Devonian, Mississippian, and Cretaceous age, and unconsolidated sand, gravel, and clay of Quaternary age. Structurally the county is in the northern part of the Iowan Basin, and the sedimentary units of Cambrian through Devonian age dip southward at 9 to 14 feet per mile. Three major glacial advances, the Nebraskan, Kansan, and Wisconsin, covered all or part of the county during the Pleistocene Epoch and left behind glacial drift consisting of 0 to 125 feet of till and related outwash deposits. De posits of Holocene age, aside from surficial soil, are thin and scattered. Ground water occurs in the sedimentary units of Cambrian through Mississippian age and in the glacial drift and outwash deposits of Quaternary age. The chief aquifers, in ascending order, are the deep Cambrian sandstones, Jordan aquifer, St. Peter Sandstone, Devonian and Mississippian limestones and dolomites, and the Pleistocene glacial drift and related interglacial deposits. Units between the St. Peter Sandstone and the Devonian limestones, the Platteville, Decorah, Galena, and Maquoketa Formations, are of low permeability and are considered to be an aquiclude in comparison to the overlying and under lying units. The deep Cambrian sandstones will yield about 60 gpm (gallons per minute) to an individual well; the Jordan aquifer about 1,200 gpm; the St. Peter Sandstone 30 to 200 gpm; the Devonian limestones and dolomites 120 to 200 gpm; and the glacial outwash or shallow bedrock generally will yield 10 gpm or more. The Jordan aquifer supplies large quantities of water for municipal and industrial use at Mason City. Pumping tests on wells tapping the Jordan in that area show that the aquifer has a transmissibility of about 35,000 gallons per day per foot and a storage coefficient of 2 x 10 -4 Pumping in the Mason City area from 1912 to 1969 has produced about 200 feet of draw down in the areas of maximum withdrawal. Ground water in Cerro Gordo County is of suitable chemical quality for domestic, industrial, or municipal use. The total dis solved solids ranges from 152 mg/l (milligrams per liter) in water from the shallow bedrock to 885 mg/l in water from the deep Cambrian sandstones. Water from the Jordan, which is the most productive aquifer in the county, generally contains less than 500 mg/l dissolved solids. Ground water is the major source of water supplies throughout Cerro Gordo County. The majority of wells in the county are used for domestic and stock supplies, but the largest withdrawals of water are for municipal and industrial supplies. Municipal pumpage in the county in 1968 was about 1.5 billion gallons; industrial pumpage was about 1.8 billion gallons and most of the water was obtained from the Jordan aquifer. If future development of water from the Jordan aquifer is to be to the best economical advantage, careful consideration should be given to the location, capacity, and pumping schedules of proposed wells and nearby existing wells so that local overdevelopment or excessive interference do not occur.

Iowa↗

Microfossil biostratigraphy of prograding Neogene platform-margin carbonates, Bahamas: Age constraints and alternatives

Benthic and planktic foraminifera and calcareous nannofossils were recovered in shallow-water carbonate rock cores from two continuous boreholes drilled 7.5 km apart on the west platform margin of the Great Bahama Bank. The microfossils define six biostratigraphic units in each hole. One unit in each hole represents a correlative condensed section. Seven foraminiferal biozones are recognized in 11 of the units between the holes: middle Miocene Globorotalia fohsi robusta Zone N12, late Miocene G. acostaensis Zone N16 and G. humerosa Zone N17, early Pliocene G. margaritae evoluta Subzone N19, late Pliocene G. exilis Subzone N21 and, tentatively, G. tosaensis tosaensis Zone N21, and early Pleistocene G. crassaformis viola Subzone N22. The twelfth unit is inferred to be of G. crassaformis viola Subzone N22 age. The oldest unit is onshore, the youngest is offshore. As presently interpreted, the nannofossil and foraminiferal zonations are partially correlative. Although the microfossils unequivocally constrain the series ages of the sediments, the incompleteness of the fossil record allows for alternative biozonal age models within the series. The Miocene and Pliocene biozones are common to both holes, but the greatest similarities between the holes are the significant mixing of middle and late Miocene, and late Miocene-early Pliocene faunas, the greatly condensed intervals at the Miocene/Pliocene boundary, and the early Pliocene influx of deep-water benthic and pelagic foraminifera. Of particular importance is the tentative recognition of late Pliocene G. tosaensis tosaensis Zone N21 in one borehole. Subsequent data not available to this phase of the study indicate that much of the zone is likely missing. Its absence will lend support to speculations of a regional unconformity in the Bahamas. The microfossils indicate that (1) several transgressions occurred from the middle Miocene to at least the earliest Pleistocene (greater than 11.5–greater than 0.46 Ma), during which banktop-derived sediments accumulating at the margin prograded the platform seaward; (2) a condensed interval on the bank top may represent a late Miocene lowstand, a period of sediment bypassing, or a lack of accommodation space; (3) the slope received thin layers of pelagic sediments in a condensed interval during the late Miocene and early Pliocene, while the bank top accommodated early Pliocene (4.2–3.4 Ma) deep-water indicators prior to a likely period of exposure (2.35 - 1.89 Ma); (4) two cycles of banktop sediment production and starvation occurred during the Pliocene; (5) the Pliocene transgression was punctuated by stillstands or low-amplitude reversals during which parts of biozones did not accumulate; and (6) the sediments containing the most complete microfossil-datum record are the thin pelagic strata that mark interruptions in the regular shedding of transgressive deposits from the platform. Sedimentation-rate patterns varied but were generally higher offshore than onshore.

Marine Micropaleontology↗

Studies of the Chesapeake Bay impact structure - Introduction and discussion

The late Eocene Chesapeake Bay impact structure on the Atlantic margin of Virginia is the largest known impact crater in the United States, and it may be the Earth's best preserved example of a large impact crater that formed on a predominantly siliciclastic continental shelf. The 85-kilometer-wide (53-milewide) crater also coincides with a region of saline ground water. It has a profound influence on ground-water quality and flow in an area of urban growth. The USGS-NASA Langley corehole at Hampton , Va., is the first in a series of new coreholes being drilled in the crater, and it is the first corehole to penetrate the entire crater-fill section and uppermost crystalline basement rock. The Langley corehole is located in the southwestern part of the crater's annular trough. A comprehensive effort to understand the crater's materials, architecture, geologic history , and formative processes, as well as its influence on ground water, includes the drilling of coreholes accompanied by high-resolution seismic-reflection and seismic-refraction surveys, audio-magnetotelluric surveys, and related multidisciplinary research. The studies of the core presented in this volume provide detailed information on the outer part of the crater, including the crystalline basement , the overlying impact -modified and impact -generated sediments (physical geology, paleontology, shocked minerals, and crystalline ejecta), and the upper Eocene to Quaternary postimpact sedimentary section (stratigraphy, paleontology, and paleoenvironments). The USGS-NASA Langley corehole has a total depth below land surface of 635.1 meters (m; 2,083.8 feet (ft)). The deepest unit in the corehole is the Neoproterozoic Langley Granite. The top of this granite at 626.3 m (2,054.7 ft) depth is overlain by 390.6 m (1,281.6 ft) of impact -modified and impact -generated siliciclastic sediments. These crater-fill materials are preserved beneath a 235.6-m-thick (773.12-ft-thick) blanket of postimpact sediments. A high-resolution seismic-reflection and seismic-refraction profile that crosses the Langley drill site is tied to the core by borehole geophysical logs, and it reveals the details of extensional collapse structures in the western annular trough. Electrical cross sections based on audio-magnetotelluric (AMT) soundings image a nearly vertical zone of high resistivity at the outer margin of the annular trough, possibly indicating fresh ground water at that location, and they show impedance trends that match the curvature of the structure . They also image the subsurface contact between conductive sediments and resistive crystalline basement , showing that the depth to crystalline basement is relatively constant in the western part of the annular trough. Chemical and isotopic data indicate that saline ground water of the Virginia inland saltwater wedge or bulge is a mixture of freshwater and seawater, and evidence for a mixing zone at the crater's outer margin supports the concept of differential flushing of residual seawater to create the bulge. Ground-water brine in the central part of the crater was produced by evaporation, and brine production from the heat of the impact is at least theoretically possible.

Chesapeake Bay↗

Sediment supply to San Francisco Bay, water years 1995 through 2016: Data, trends, and monitoring recommendations to support decisions about water quality, tidal wetlands, and resilience to sea level rise

Knowledge of the status and trends of sediment supply to San Francisco Bay is critically important for management decisions about dredging, marsh restoration, flood control, contaminants, water clarity (in relation to primary production), and sea level rise. Several sitespecific studies of sediment supply to San Francisco Bay have been conducted, but no synthesis of recent studies is available. The purpose of this report is to synthesize the best available data and knowledge to answer a few of the key study questions related to sediment supply to the Bay (listed below). This synthesis report was prepared jointly by the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP) and the U. S. Geological Survey (USGS) with funding from both organizations. The project is meant to be a step in the development of a more comprehensive sediment management and monitoring strategy for the Bay. What are the magnitudes and sources of fine and coarse sediment transported to San Francisco Bay? Net sediment supply to San Francisco Bay from terrestrial sources during the most recent 22- year period (water years [WY] 1995-2016) was 1.9+/-0.8 Mt/yr (1 Mt is one million metric tonnes or 1 billion kilograms). Sixty-three percent of the sediment supply was from small tributaries that drain directly to the Bay. Net supply from the Central Valley (measured at Mallard Island) was 37% of the total supply. Bedload supply, after accounting for dredging, removals, storage in flood control channels, and errors in measurements was indistinguishable from zero. For a 30-year “climate normal” reference period of WY 1981-2010 (a period assumed to be representative of current climatic conditions), we estimate the total sediment supply would be 2.0 Mt/yr of which 70% would come from small tributaries. The delivery points are Mallard Island for sediment from the Delta and the head of tide of each small tributary or outfall for sediment from the small tributaries. The finding that, on average, small tributaries have supplied more sediment to the Bay than the Delta is important but not new (McKee et al., 2013). During the Gold Rush and perhaps through to the 1980s, 80% or more of the supply was estimated to be from the Central Valley (Porterfield, 1980). But land and water management have continued to evolve (Krone, 1996) and the sediment wave associated with the Gold Rush has diminished (Schoellhamer, 2011). In addition, the coastal mountains of California and around the Bay are steep, tectonically active and composed of relatively erodible marine sedimentary and metasedimentary rocks, in contrast to the Central Valley watershed that is dominated by highly indurated granitic, metasedimentary, and metavolcanic rocks in the western-facing slopes of the Sierra Nevada Mountains (McKee et al., 2013). Also, water management is quite different between the Central Valley rivers and small tributaries. About 48% of the Central Valley watershed is upstream from dams that are designed to capture, delay and diminish discharge from spring snowmelt and so eliminate or damp many of the peak flows that are normally crucial for sediment transport. Another factor contributing to the importance of small tributaries for sediment supply is the way that they deliver sediment. Annual discharge from small tributaries is very small in comparison to the volume of the Bay (around one-fifth of a Bay volume on average), and the load that small tributaries supply is delivered through hundreds of channels and outfalls via wetland sloughs to the mudflats on the margin of the Bay. Therefore, the majority of this sediment delivered from Bay Area small tributaries is more likely to be trapped in these tidal channels or the margins of the Bay. In contrast, supply from the Central Valley enters the Bay through one large river channel at the head of the estuary (functionally adjacent to Mallard Island, near Pittsburg, CA) with an average annual discharge volume that is more than twi

California↗

Geology and geochemistry of jasperoids from the Gold Bar district, Nevada

Gold Bar is one of several Carlin-type gold mining districts located in the Battle Mountain-Eureka trend, Nevada. It is composed of one main deposit, Gold Bar; five satellite deposits; and four resources that contain 1.6 Moz (50 t) of gold. All of the deposits and resources occur at the intersection of north-northwest- and northeast-trending high-angle faults in slope facies limestones of the Devonian Nevada Group exposed in windows through Ordovician basin facies siliciclastic rocks of the Roberts Mountains allochthon. Igneous intrusions and magnetic anomalies are notably absent. The Gold Bar district contains a variety of discordant and stratabound jasperoid bodies, especially along the Wall Fault zone, that were mapped and studied in some detail to identify the attributes of those most closely associated with gold ore and to constrain genetic models. Four types of jasperoids, J0, J1, J2, and J3, were distinguished on the basis of their geologic and structural settings and appearance. Field relations suggest that J0 formed during an early event. Petrographic observations, geochemistry, and ??18O values of quartz suggest it was overprinted by the hydrothermal event that produced ore-related J1, J2, and J3 jasperoids and associated gold deposits. The greater amount of siliciclastic detritus present in J0 jasperoids caused them to have higher ??18O values than J1,2,3 jasperoids hosted in underlying limestones. Ore-related jasperoids are composed of main-ore-stage replacements and late-ore-stage open-space filling quartz with variable geochemistry and an enormous range of ??18O values (24.5 and -3.7???). Jasperoids hosted in limestones with the most anomalous Au, Ag, Hg, ??(As, Sb, Tl) concentrations and the highest ??18O values are associated with the largest deposits. The 28??? range of jasperoid ??18O values is best explained by mixing between an 18O-enriched fluid and an 18O-depleted fluid. The positive correlation between the sizes of gold deposits and the ??18O composition of jasperoids indicates that gold was introduced by the 18O-enriched fluid. The lowest calculated ??18O value for water in equilibrium with late-ore-stage quartz at 200??C (-15???) and the measured ??D value of fluid inclusion water extracted from late-ore-stage orpiment and realgar (-116???) indicate that the 18O-depleted fluid was composed of relatively unexchanged meteoric water. The source of the 18O-enriched ore fluid is not constrained. The ??34S values of late-ore-stage realgar, orpiment, and stibnite (5.7-15.5???) and barite (31.5-40.9???) suggest that H2S and sulfate were derived from sedimentary sources. Likewise, the ??13C and ??18O values of late-stage calcite (-4.8 to 1.5??? and 11.5 to 17.4???, respectively) suggest that CO2 was derived from marine limestones. Based on these data and the apparent absence of any Eocene intrusions in the district, Gold Bar may be the product of a nonmagmatic hydrothermal system. ?? Springer-Verlag 2006.

Mineralium Deposita↗

California State waters map series—Benthic habitat characterization in the region offshore of Morro Bay, California

Coastal and Marine Ecological Classification Standard geoform, substrate, and biotic component geographic information system products were developed for the California State waters of south-central California in the region offshore of Morro Bay. The study was motivated by interest in development of offshore wind-energy capacity and infrastructure in Federal waters offshore. The Bureau of Ocean Energy Management, in coordination with the State of California and many other members of the California Intergovernmental Renewable Energy Task Force, issued calls for information in 2018 for the study area offshore of Morro Bay, California. The study area is adjacent to a nuclear power plant (currently scheduled for decommissioning) with a developed electric grid connection, and in an area of high wind resource potential. The Bureau of Ocean Energy Management is the lead agency responsible for planning and leasing in the U.S. Exclusive Economic Zone and funded this project to assess baseline conditions of, and the potential effects on, the seafloor environment. This project, carried out by the U.S. Geological Survey, resulted in three data releases for individual map blocks that are part of the California State Waters Map Series: (1) Offshore of Point Estero, (2) Offshore of Morro Bay, and (3) Offshore of Point Buchon. The study area consists of 341 square kilometers (km 2 ) of multibeam echo sounder (MBES) data acquired by Fugro, Inc., in 2010. Towed camera-sled video was acquired in 2012 to supervise the classification of the MBES data into habitats. There were 935 annotations of organisms and habitat made from 22 video transects. Using video observations of habitat as ground truth, derivatives of the MBES data were classified into 3 seafloor character types (hard-rugged, hard-flat, and soft-flat), 25 modifier groups, and 9 geoforms. The study area substrate is predominantly soft-flat sediment (mud and fine sand) covering 191.3 km 2 (56.1 percent) of the area. Hard-flat substrate areas, predominantly coarse sediment in scour depressions, cover 52.2 km 2 (15.3 percent) of the study area. The hard-rugged substrate areas are primarily outcrops of layered sedimentary bedrock and constitute 97.5 km 2 of the study area (28.6 percent). After classification of bathymetry and backscatter raster images according to substrate, false-positive hard areas produced by noise artifacts were removed by manual editing. Nine geoforms were then identified in the analysis. The predominant geoforms mirror the seafloor character results, shelf geoforms (flat areas covered in soft sediment), rock outcrop geoforms (hard, rugged areas), and scour depression geoforms (flat areas covered in coarse sediment formed by bottom currents).

California↗

Igneous differentiation in arcs

This chapter assesses crystallization-differentiation of convergent-margin magmas both from the standpoints of natural rock suites and from laboratory phase-equilibrium experiments. Crystallization-differentiation of dry subalkaline and alkaline basalts are summarized at the beginning for reference and context. Experiments crystallizing arc basalts through andesites at middle to upper crustal pressures (100–400 MPa), saturated either with H 2 O or mixed H 2 O-CO 2 , produce liquid lines of descent similar to arc igneous suites, with higher f O 2 s giving results closer to calc-alkaline magma series. Early enrichment of melts in SiO 2 with little or no enrichment in FeO* (total Fe as FeO) comes about by the combined effects of H 2 O suppressing crystallization of plagioclase relative to olivine, shifting plagioclase to more calcic – therefore lower SiO 2 – compositions, and suppressing silicate minerals to greater extents than Fe-rich spinel. Also contributing to SiO 2 enrichment is crystallization near the liquidus of higher proportions of olivine relative to calcic clinopyroxene, compared with MORB, but it is unclear if this is brought about by H 2 O or elevated pressure. Exhumed arc terranes, however, generally fail to expose evidence for primitive liquids having reached and differentiated at middle to upper crustal depths, at least in any abundance. Instead, most differentiation in arcs appears to take place in the lower crust or near the crust-mantle transition, and although hydrous experiments at such pressures produce liquids broadly similar to arc suites in their SiO 2 enrichment, the experimental liquids differ in becoming peraluminous at early stages of differentiation while melts have basaltic, basaltic andesitic, or andesitic SiO 2 concentrations. Crystallization of abundant calcic clinopyroxene close to the liquidus causes the high-pressure experimental liquids to become peraluminous with only small increases in SiO 2 concentration. In contrast, natural arc volcanic and plutonic suites become gradually less metaluminous with increasing SiO 2 , crossing to peraluminous at dacitic to rhyolitic SiO 2 concentrations. Hybridism, encompassing magma-mixing, assimilation of old crust, and incorporation of near-solidus melts from only shortly older deep, antecedent arc intrusions may accompany natural crystallization-differentiation, preventing melts from attaining peraluminous compositions at low-SiO 2 concentrations. If so, then nearly all arc suites are to substantial extents composites, rather than preserving simple, progressive liquid lines of descent. Some comments and assessments are also made on the participation of garnet in arc differentiation and on the production of arc batholiths.

Book chapter↗

Geologic evolution, sedimentation, and paleoenvironments of the Angola Basin and adjacent Walvis Ridge: Synthesis of results of Deep Sea Drilling Project Leg 75

The section recovered at Site 530 (Holes 53OA and 530B) consists of eight sedimentary units and one basalt unit. The composition of the basalt recovered in Hole 53OA is distinct from typical mid-ocean ridge basalts (MORBs) but is similar to that of Hawaiian tholeiites and basalt from the central part of Walvis Ridge. Throughout most of its history, the southern Angola Basin received large volumes of redeposited material in the form of turbidites and, most recently, debris-flow deposits. Most of this material was derived from Walvis Ridge to the south, but thickness trends of acoustic units suggest that some of the sediment was derived from the African continental margin to the east. The basal sedimentary unit (Albian to Santonian) at Site 530 contains 262 beds of black shale that are interbedded with green and red claystone. Black shale makes up less than 10% of the total section, but in two cores of early Turonian age, black shale beds compose about 50% of the section. The black shales contain up to 19% organic carbon (average of about 5%) that is mainly of autochthonous marine origin but with significant contributions from terrigenous organic matter. The origin of these more- and less-reduced interbedded lithologies with varying amounts and types of organic matter, and variable amounts of pelagic, hemipelagic, and turbiditic sediment is complex and cannot be explained by any one simple process. Many factors affecting the concentration of dissolved oxygen in the bottom waters of the Angola Basin varied throughout the middle Cretaceous to produce bottom-water conditions that fluctuated between mildly oxic and oxygen-deficient, but most of the time bottom-waters and sediment-interstitial waters were sufficiently oxic to permit the accumulation of red oxidized sediment. A relatively complete sedimentary record of the Cretaceous/Tertiary boundary was recovered within a sequence of mudstone and marlstone turbidites in Hole 530A. There is a significant increase in the concentration of iridium above background levels at the boundary. High concentrations of many other elements also occur within the same stratigraphic interval as the iridium anomaly. Furthermore, there is a marked decrease in CaCO3 in the Tertiary strata above the iridium anomaly which suggests that the production of shallow-water carbonate also may have been affected by whatever caused elevated concentrations of iridium and other elements. These observations are consistent with the asteroid-impact theory proposed to explain the worldwide occurrence of an iridium anomaly at the Cretaceous/Tertiary boundary. The Cenozoic history of the Angola Basin was controlled mainly by (1) restriction of bottom-water flow from the south by Walvis Ridge; (2) development of glaciation on Antarctica; (3) opening of circulation passages in the southern oceans; (4) rapid turnover of cold, nutrient-rich waters that resulted in high productivity of diatoms; (5) influx of terrigenous sediment mainly by turbidity currents; and (6) production and preservation of carbonate sediment. The most distinctive Cenozoic event recorded in the section at Site 530 is the beginning of extensive glaciation on Anarctica and concomitant initiation of modern thermohaline bottom-water circulation that is manifested as a middle Eocene to middle Oligocene unconformity or compressed section accompanied by a drastic decrease in accumulation of CaCO3. Diatom abundances in HPC cores from Walvis Ridge (Site 532) and Angola Basin (Hole 53OB) indicate that Benguela upwelling in these areas began in the late Miocene, reached a peak in the late Pliocene to early Pleistocene, and declined thereafter. Short-term variations in sediment composition at Site 532 are manifested as cyclic variations in concentrations of clay, CaCO3, and organic carbon with average periodicities of about 30-60 k.y. The main variability that produced the cycles probably was the influx of terrigenous clastic material which diluted the CaCO3. The sediment at Site 532 also contains several percent organic carbon that is dominantly of marine origin, but with significant terrigenous components. Data from multichannel seismic, gravity, and magnetic surveys were used to define the regional stratigraphic and structural evolution of Walvis Ridge and adjacent Cape and Angola basins. Six structural provinces are recognized, four on Walvis Ridge and two additional provinces that correspond to the Cape and Angola basins. The two eastern structural provinces on Walvis Ridge are underlain by continental crust. The two western structural provinces are underlain by oceanic basement. Two main directions of faults are evident in seismic profiles, one trending N 10° and one trending N 60°. The N 60° trend corresponds to the general orientation of the northern and southern flanks of Walvis Ridge as well as to the dominant direction of fracture zones. During the first phase of separation of Africa from South America (ca. 120-130 m.y. ago), a voluminous mass of volcanics was emplaced simultaneous with the emplacement of basalt in the Parana Basin of Brazil and the Kaokoveld Region of South Africa. This period of volcanism also formed the series of seaward-dipping internal basement reflectors that are characteristic of the two structural provinces of Walvis Ridge. A system of fault blocks developed in the brittle upper part of the newly formed crust. During the second phase of rifting, which ended before late Aptian, more tilted fault blocks were created in the upper brittle stratified continental crust. Magnetic lineations in basement rocks in the Angola and Cape basins in the vicinity of Walvis Ridge are not distinct but suggest that oceanic crust began to be emplaced between 120 and 112 m.y. ago (Barremian to early Aptian). At least part of the oceanic crust of the central plateau of eastern Walvis Ridge (structural province 3) may have been emplaced before any oceanic crust formed in the adjacent basins. A ridge jump occurred during the late Aptian to early Albian in the southern part of the Angola Basin which translated the previously formed oceanic crust and its overlying evaporite deposits on the South American side. Several ridge jumps occurred on both sides of Walvis Ridge during the Late Cretaceous and early Tertiary to produce a 500-km-long segment of mid-ocean ridge.

Initial Reports of the D.S.D.P.↗

Mines and prospects of the Butte 1° x 2° Quadrangle, Montana

The Butte quadrangle, in the Northern Rocky Mountains of southwestern Montana, has had a long, productive, and colorful mining history. Butte, the city from which the quadrangle takes its name, is located in the most famous mining district of the quadrangle. This district, the Butte or Summit Valley district, has been described as the "richest hill on earth" and is one of the richest and most productive mining districts of the world. The quantity of metals produced from this district alone are far greater than the combined total of all commodities from all other mining districts of the quadrangle. However, many districts other than Butte have had significant production as compared to other mining districts of the Northern Rocky Mountains. The dollar value of production from the Butte district is more than $6 billion (Miller, 1973) and that of the combined total of production from the other districts in the quadrangle is more than $400 million. These values are based on actual metal prices at the time of production. The totals would be many times larger if converted to present day commodity prices. Mineral occurrence data for a total of 1111 mines, prospects, and mineral occurrences have been compiled for the Butte quadrangle. These mineralized sites are found throughout the quadrangle but most are concentrated in the major mining districts; 78 percent are clustered in 46 established mining districts and the remaining 22 percent are more widely scattered in 24 geographic areas (fig. 1). Only small areas of the quadrangle lack significant mines, prospects, or mineral occurrences. The locations of mines and prospects are shown on maps (pl. 1 and 2) and a brief description of each site is given in a table arranged by mining district or geographic area (table 1) (all tables are at end of report). This table gives a brief description of each district or area and details of each site within the district or area including site number, name and alternate name(s), location by latitude and longitude, commodities present, description of the site, and sources of data. Data for this report come from the U.S. Geological Survey Mineral Resource Data System (MRDS; this was formerly known as the Computerized Resource Information Bank (CRIB)), from many published and unpublished sources, and from geologic field work. The Butte quadrangle is in southwestern Montana and is bounded by latitudes 46° and 47° N. and longitudes 112° and 114° W. The city of Butte is near the southern edge and in the southeastern corner of the quadrangle. Helena, the state capital of Montana, is located on the eastern edge and Missoula is located near the northwestern corner of the quadrangle. Most of the area of the quadrangle is in Granite, Powell, Lewis and Clark, and Jefferson Counties and the remaining area includes parts of Missoula, Ravalli, Deer Lodge, and Silver Bow Counties. The quadrangle includes a number of major and minor mountain ranges separated by intermontane valleys. The continental divide trends nearly north-south through the eastern part of the quadrangle to a point near Butte, then trends generally east-west near the southern boundary of the quadrangle, west of Butte. East of the divide the drainages are tributary to the Missouri River and west of the divide the drainages are tributary to the Clark Fork, which heads in the vicinity of Butte. The geology of the Butte quadrangle is very complex. Sedimentary and igneous rocks range in age from Proterozoic to Tertiary. Most of the pre-Tertiary sedimentary rocks are structurally complex due to widespread faulting and folding. Due to thrust faulting, complete sequences of these sedimentary units are not generally present in the quadrangle and the thicknesses and lithologies are variable from one thrust plate to another. The oldest rocks in the quadrangle are sedimentary rocks of the Belt Supergroup of Middle Proterozoic age. They form very thick sequences, are exposed over a large percentage of the area of the quadrangle, and include formations of the lower, middle, and upper parts of the Belt. Individual formations are as much as 13,000 ft thick (C. A. Wallace, unpub. data) and the maximum thickness of the Belt Supergroup in the quadrangle may be similar to that of the entire sequence near Alberton, Montana, to the northwest of the Butte quadrangle where it exceeds 67,000 ft (Harrison, 1972). In many areas of the quadrangle these Precambrian rocks are overlain by thin to moderately thick sequences of Cambrian to Permian sedimentary rocks. The maximum thickness of the Paleozoic section is about 8,000 ft (C. A. Wallace, unpub. data). A relatively thick sequence of Mesozoic sedimentary rocks, predominantly Cretaceous in age, which is found mostly in the central part of the quadrangle, overlies the Paleozoic rocks. If complete, the Mesozoic sequence would total about 28,000 ft (C. A. Wallace, unpub. data). The Butte quadrangle is located in a structurally complex region. Most of the Butte quadrangle is in the southern part of the Montana Disturbed Belt, a tectonic belt in the Northern Rocky Mountains characterized by northwest-trending faults and intense deformation. An element of the Disturbed Belt, called the Sapphire Thrust System occupies most of the western two-thirds of the quadrangle. Sedimentary rocks of Cretaceous and older ages in the Sapphire Thrust System have been complexly folded and faulted. Plutonic rocks, which intrude the sedimentary units, and volcanic rocks of Cretaceous and Tertiary ages are widespread in the quadrangle. Most of these are post-thrusting but some may be pre- or syn-tectonic and involved in the thrusting and folding. Most of the mineral wealth in the quadrangle, in the form of hydrothermal ore deposits, is genetically related to Cretaceous granitic plutonism. Igneous activity decreased but continued into Tertiary time, at least until the Oligocene. In the Butte quadrangle the Cenozoic Era was important for normal faulting, volcanism, sedimentation, glaciation, and the formation of many important mineral deposits. Many normal faults were especially active during the Miocene and Pliocene and some were active into the Quaternary. Volcanic rocks of Eocene and Oligocene age cover large areas and are genetically related to several important mining districts. During Cenozoic time, thick accumulations of Tertiary basin-fill sediments, Pleistocene glacial till and outwash, and Holocene alluvium and colluvium were deposited. The Cenozoic was important for the formation of placer deposits valuable mainly for gold but some have produced important quantities of sapphires and tungsten. This map is part of a folio of maps of the Butte 1° x 2°quadrangle, Montana, prepared under the Conterminous United States Mineral Assessment Program (CUSMAP). Other maps to be published as part of this folio are a geologic map, geochemical maps, geophysical maps, maps of linear features and limonitic alteration interpreted from satellite and airborne radar data, and mineral resource assessment maps.

Montana↗

Hydrology of area 59, northern Great Plains and Rocky Mountain coal provinces, Colorado and Wyoming

Hydrologic information and analysis aid in decisions to lease federally owned coal and to prepare necessary Environmental Assessments and Impact Study reports. This need has become even more critical with the enactment of Public Law 95-87, the "Surface Mining Control and Reclamation Act of 1977." This act requires an appropriate regulatory agency to issue permits, based on the review of permit-application data to assess hydrologic impacts. This report, which partially fulfills this requirement, is one in a series of nationwide coal province reports that present information thematically, through the use of a brief text and accompanying maps, graphs, charts, or other illustrations for single hydrologic topics. The report broadly characterizes the hydrology of Area 59 in north-central Colorado and southeastern Wyoming. The report area, located within the South Platte River basin, covers a 16,000-square-mile area of diverse geology, topography, and climate. This diversity results in contrasting hydrologic characteristics. The South Platte River, the major stream in the area, and most of its tributaries originate in granitic mountains and flow into and through the sedimentary rocks of the Great Plains. Altitudes range from less than 5,000 feet to more than 14,000 feet above sea level. Precipitation in the mountains may exceed 40 inches annually, much of it during the winter, and produces deep snowpacks. Snowmelt during the spring and summer produces most streamflow. Transmountain diversion of water from the streams on the western slope of the mountains also adds to the streamflow. Precipitation in the plains is as little as 10 inches annually. Streams that originate in the plains are ephemeral. Streamflow quality is best in the mountains, where dissolved-solids concentrations are generally small. Concentrations increase in the plains as streams flow through sedimentary basins, and as urbanization and irrigation increase. The quality of some mountain streams is affected by drainage from previous metalmining areas, as indicated by greater trace-element concentrations and smaller pH values. However, the large trace-element concentrations decrease rapidly downstream from the metal-mining areas. Because the climate is semiarid in most of the area, the soils are not adequately leached; therefore, flows in ephemeral streams usually have larger concentrations of dissolved solids than flows in perennial streams. Ground water is available throughout the area; yields range from less than 0.1 gallons per minute in the fractured granite aquifer in the mountains to more than 2,000 gallons per minute in the alluvial aquifer of the South Platte River valley. Major bedrock aquifers in order of decreasing age are the Laramie-Fox Hills, Arapahoe, Denver, and Dawson; these aquifers are used for municipal, domestic, and livestock supplies. Alluvial aquifers supply the high-yield irrigation wells. The best quality ground water is found at the center of the major bedrock aquifers, where dissolved-solids concentrations are less than 200 milligrams per liter. The poorest-quality water is usually found near the edges of these aquifers. Water in the coal-bearing Laramie and Denver Formations is locally affected by coal deposits, causing dissolved-solids concentrations to be relatively large. Only one coal mine is now operating in Area 59, the Coors Energy Company surface coal mine, which produced 100,000 short tons of subbituminous coal from the Upper Cretaceous Laramie Formation in 1982. Past coal-mining operations removed more than 130 million tons of coal and lignite from Area 59,99 percent of which came from underground mines. The largest coal production was in Weld and Boulder Counties, Colorado. Hydrologic problems related to surface mining are erosion, sedimentation, decline in water levels, disruption of aquifers, and degradation of water quality. Because the semiarid mine areas have very little runoff, and the major streams have large buffer and dilution capacities, the effects of mining on surface water is minimal. However, effects on ground water may be much more severe and long-lasting.

Colorado, Wyoming↗

A brief Oligocene period of flood volcanism in Yemen: Implications for the duration and rate of continental flood volcanism at the Afro-Arabian triple junction

40 Ar 29 Ar dating of mineral separates and whole-rock (WR) samples has established that basaltic continental flood volcanism (CFV) began between 30.9 and 29.2 Ma in northwestern and southwestern Yemen, respectively. Rhyolitic volcanism commenced at 29.0–29.3 Ma throughout Yemen. Lower basaltic lavas were erupted every 10–100 kyr, whereas upper bimodal volcanic units were erupted every 100–500 kyr, which reflects generation of rhyolitic magmas from basalts that resided for longer periods in lithospheric magma chambers than during the early phase of exclusively mafic magmatism. The youngest dated flood volcanic units were erupted between 26.9 and 26.5 Ma throughout Yemen. The duration of preserved CFV defined by 40 Ar 29 Ar dating (4.4 myr) contrasts with the wide range of WR K Ar dates previously obtained in Yemen (> 50 myr). 40 Ar 39 Ar "> 40Ar39Ar step-heating studies of WR samples has shown that this discrepancy is due to the disturbed Ar systematics of volcanic samples. Most samples have experienced post-crystallization loss of radiogenic Ar and/or contain excess Ar, with only ca. 25% of the WR K Ar dates within 1–2 myr of true crystallization ages. WR K Ar data can be screened for reliability using the radiogenic Ar yield and 40 K 36 Ar "> 40K36Ar ratio, which reflect the Ar retentivity of the sample, the likelihood that alteration has disturbed a sample's Ar systematics, and the susceptibility of the sample to a finite amount of Ar loss or the presence of a finite amount of excess Ar. Examination of existing WR KAr data in the Ethiopian part of this flood volcanic province, using these parameters, suggests that much of these data are also misleading. Two phases of flood volcanism are inferred in Ethiopia and Eritrea at 38-30 Ma and ca. 20 Ma. The older phase is equivalent to that in Yemen, and is consistent with the progression in basal volcanic ages obtained in Yemen moving from north to south. The younger phase is related to the onset of upper crustal extension and incipient Red Sea-Gulf of Aden rifting. The sequence of events — surface uplift (?), flood magmatism and subsequent upper crustal extension — in Yemen is consistent with the involvement of a mantle plume at the Afro-Arabian tripe junction. However, the overall eruption rate for this flood volcanic province is only 0.03 km 3 /yr, much slower than that postulated for other plume-related provinces such as the Deccan or Siberian Traps, but perhaps comparable to the Paraná-Etendeka province, which also contains significant amounts of rhyolitic volcanic products like those of Yemen-Ethiopia. The highly variable eruption rates in individual provinces must reflect the very different character of individual plumes, or the control of lithospheric structure and plate tectonic stresses on the surface manifestations of plumes. The long duration of CFV and large amounts of rhyolitic volcanism at the Afro-Arabian triple junction may be attributed to the relatively slow separation of the African and Arabian plates compared with, for example, the rifting of India and the Deccan Traps.

Earth and Planetary Science Letters↗

Effects of Simulated Land-Use Changes on Water Quality of Lake Maumelle, Arkansas

Lake Maumelle is one of two principal drinking-water supplies for the Little Rock and North Little Rock metropolitan areas. Lake Maumelle and the Maumelle River (its primary tributary) are more pristine than most other reservoirs and streams in the region. However, as the Lake Maumelle watershed becomes increasingly more urbanized and timber harvesting becomes more frequent, concerns about the sustainability of the quality of the water supply also have increased. Two models were developed to partially address these concerns. A Hydrological Simulation Program-FORTRAN model was developed using input data collected from October 2004 through 2008. A CE-QUAL-W2 model was developed to simulate reservoir hydrodynamics and selected water quality using the simulated output from the Hydrological Simulation Program-FORTRAN model from January 2005 through 2008. The Hydrological Simulation Program-FORTRAN watershed model was calibrated to five streamflow-gaging stations, and in general, these stations characterize a range of subwatershed areas with varying land-use types. Continuous streamflow data, discrete sediment concentration data, and other discrete water-quality data were used to calibrate the Lake Maumelle Hydrological Simulation Program-FORTRAN model. The CE-QUAL-W2 reservoir model was calibrated to water-quality data and reservoir pool altitude collected during January 2005 through December 2008 at three lake stations. In general, the overall simulation for the Hydrological Simulation Program-FORTRAN and CE-UAL-W2 models matched reasonably well to the measured data. In general, simulated and measured suspended-sediment concentrations during periods of base flow (streamflows not substantially influenced by runoff) agree reasonably well for Williams Junction (with differences-simulated minus measured value-generally ranging from -14 to 19 mg/L, and percent difference-relative to the measured value-ranging from -87 to 642 percent) and Wye (differences generally ranging from -2 to 14 mg/L, -62 to 251 percent); however, the Hydrological Simulation Program-FORTRAN model generally does not match the suspended-sediment concentrations for all stations during periods of stormflow (streamflow substantially influenced by runoff). Generally, this is also the case for fecal coliform bacteria numbers and total organic carbon and nutrient concentrations. In general, water temperature and dissolved-oxygen concentration simulations followed measured seasonal trends for all stations with the largest differences occurring during periods of lowest water temperatures (for temperature) or during the periods of lowest measured dissolved-oxygen concentrations (for dissolved oxygen). For the CE-QUAL-W2 model, simulated vertical distributions of temperatures and dissolved-oxygen concentrations agreed with measured distributions even for complex temperature profiles. Considering the oligotrophic-mesotrophic (low to intermediate primary productivity and associated low nutrient concentrations) condition of Lake Maumelle, simulated algae, phosphorus, and ammonia concentrations compared well with generally low measured values.

Scientific Investigations Report↗

Antigenic profiling of Yersinia pestis infection in the Wyoming coyote (Canis latrans)

Although Yersinia pestis is classified as a "high-virulence" pathogen, some host species are variably susceptible to disease. Coyotes (Canis latrans) exhibit mild, if any, symptoms during infection, but antibody production occurs postinfection. This immune response has been reported to be against the F1 capsule, although little subsequent characterization has been conducted. To further define the nature of coyote humoral immunity to plague, qualitative serology was conducted to assess the antiplague antibody repertoire. Humoral responses to six plasmid-encoded Y. pestis virulence factors were first examined. Of 20 individual immune coyotes, 90% were reactive to at least one other antigen in the panel other than F1. The frequency of reactivity to low calcium response plasmid (pLcr)-encoded Yersinia protein kinase A (YpkA) and Yersinia outer protein D (YopD) was significantly greater than that previously observed in a murine model for plague. Additionally, both V antigen and plasminogen activator were reactive with over half of the serum samples tested. Reactivity to F1 was markedly less frequent in coyotes (35%). Twenty previously tested antibody-negative samples were also examined. While the majority were negative across the panel, 15% were positive for 1-3 non-F1 antigens. In vivo-induced antigen technology employed to identify novel chromosomal genes of Y. pestis that are up-regulated during infection resulted in the identification of five proteins, including a flagellar component (FliP) that was uniquely reactive with the coyote serum compared with immune serum from two other host species. Collectively, these data suggest that humoral immunity to pLcr-encoded antigens and the pesticin plasmid (pPst)-encoded Pla antigen may be relevant to plague resistance in coyotes. The serologic profile of Y. pestis chromosomal antigens up-regulated in vivo specific to C. latrans may provide insight into the differences in the pathogen-host responses during Y. pestis infection.

Wyoming↗

Geohydrology of the Vamoosa-Ada aquifer east-central Oklahoma with a section on chemical quality of water

The Vamoosa-Ada aquifer, which underlies an area of about 2,320 mi 2 , consists principally of the Vamoosa Formation and the overlying Ada Group of Pennsylvanian age. Rocks comprising the aquifer were deposited in a nearshore environment ranging from marine on the west to nonmarine on the east. Because of changes in depositional environments with time and from place to place, the aquifer is a complex sequence of fine- to very fine-grained sandstone, siltstone, shale, and conglomerate, with interbedded very thin limestone. The aggregate thickness of water-bearing sandstones is greatest south of the Cimarron River, where it reaches a maximum of 550 ft in the vicinity of Seminole. North of the Cimarron River, the average aggregate thickness of the sandstones is about 100 ft, but locally it may be as much as 200 ft. Transmissivity values derived from seven aquifer tests made for this study range from 70 to 490 ft 2 per day; values decrease from south to north with decreasing sandstone thickness. Hydraulic-conductivity values range from 2 to 4 ft per day. Storage coefficients for the confined part of the aquifer, as determined from four aquifer tests made during 1944, have an average value of 0.0002. The average storage coefficient for the unconfined part of the aquifer is estimated at 0.12, based on an analysis of geophysical logs and grain-size data. The specific capacity of wells tested is generally less than 1 gallon per minute per foot of drawdown. An approximate hydrologic budget for the aquifer for 1975 gives values, in acre-feet per year, of 93,000 for recharge, 233,000 for runoff, and 2,003,000 for evapotranspiration. The total of these values is almost equal to the average annual precipitation of 2,330,000 acre-ft per year. The estimated amount of water containing a maximum of 1,500 milligrams per liter of dissolved solids stored in the aquifer is estimated at 60 million acre-ft. Of this amount, an estimated 36 million acre-ft is available for use. The quality of water in the Vamoosa-Ada aquifer generally is suitable for municipal, domestic, and stock use. Of 55 water samples analyzed in the laboratory, about 75 percent were of the sodium bicarbonate or sodium calcium bicarbonate type; the remainder were of the sodium sulfate, calcium sulfate, sodium chloride, or indeterminate types. Laboratory and on-site chemical-quality data indicate that mineralization of both ground and surface waters is greater than normal in some areas. Water samples from 7 wells and 12 stream sites had concentrations of bromide exceeding 1 milligram per liter; the only known source of bromide in the area is brine associated with petroleum production.

Oklahoma↗

Hydrogeologic framework, water levels, and selected contaminant concentrations at Valmont TCE Superfund Site, Luzerne County, Pennsylvania, 2020

The Valmont TCE Superfund Site, Luzerne County, Pennsylvania is underlain by fractured and folded sandstones and shales of the Pottsville and Mauch Chunk Formations, which form a fractured-rock aquifer recharged locally by precipitation. Industrial activities at the former Chromatex Plant resulted in trichloroethene (TCE) contamination of groundwater at and near the facility, which was identified in 1987 and led to listing as a Superfund site by the U.S. Environmental Protection Agency (EPA) in 1989. To address the problem of TCE concentrations in nearby residential wells that exceed the maximum contaminant level (MCL) of 5 micrograms per liter (μg/L), alternate water supplies were provided. A 2015 review of initial characterization and subsequent remediation by the EPA identified the need for an updated understanding of the complex hydrogeology and the conceptual site model. Additional contaminants present in groundwater at the site include some other volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFAS), predominantly consisting of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) present in concentrations that exceeded the EPA Health Advisory (HA) level of 5 nanograms per liter (ng/L) for combined PFOA and PFOS. In response to a request from the EPA in 2019, the U.S. Geological Survey (USGS) prepared cross sections and maps to provide more information about the hydrogeologic framework at and near the site and assist in improving the conceptual site model using water level and contaminant data collected by the EPA in 2020. The cross sections present lithologic correlations from available geophysical logs collected in wells from 2002 to 2014; they show alternating intervals of relatively elevated and reduced natural gamma activity that correspond to changes in lithology, with water-bearing zones and well screens commonly located at lithologic contacts, sometimes near thin coal seams. Water-bearing zones commonly are associated with fractures at or near lithologic contacts but also may be associated with fractures at or near apparent faulting. Recent (March 2020) water-level data shown on cross sections and maps indicate large downward vertical gradients and apparent radial gradients laterally to the northeast, northwest, and southwest that generally following topography. Recent (February to March 2020) data for TCE groundwater concentration shown on cross sections and maps indicate the highest TCE concentrations (greater than 3,000 μg/L and as much as 75,000 μg/L) and combined PFOA and PFOS concentrations (greater than 1,000 ng/L and up to at least 2,350 ng/L) are from shallow (less than 60 feet [ft] below land surface [bls]) and intermediate depth (60 to 100 ft bls) wells near the center of the former Chromatex Plant. TCE and PFAS (as combined PFOA and PFOS) contamination is present at greater depths, as much as 304 ft bls, as evidenced by samples collected from one well (a reconstructed former production well) near the plant, that contained concentrations of about 240 μg/L and 508 ng/L, respectively. The 2020 data also indicate that TCE and PFAS concentrations which exceed drinking-water MCL or HA levels are present in groundwater depths of less than 200 ft in an area that extends predominantly in a northeast direction from the former Chromatex Plant, and is apparently influenced by hydraulic gradients, lithology, and geologic structure.

Pennsylvania↗

Vanadium

Vanadium is used primarily in the production of steel alloys; as a catalyst for the chemical industry; in the making of ceramics, glasses, and pigments; and in vanadium redox-flow batteries (VRBs) for large-scale storage of electricity. World vanadium resources in 2012 were estimated to be 63 million metric tons, which include about 14 million metric tons of reserves. The majority of the vanadium produced in 2012 was from China, Russia, and South Africa. Vanadium is extracted from several different types of mineral deposits and from fossil fuels. These deposits include vanadiferous titanomagnetite (VTM) deposits, sandstone-hosted vanadium (with or without uranium) deposits (SSV deposits), and vanadium-rich black shales. VTM deposits are the principal source of vanadium and consist of magmatic accumulations of ilmenite and magnetite containing 0.2 to 1 weight percent vanadium pentoxide (V 2 O 5 ). SSV deposits are another important source; these deposits have average ore grades that range from 0.1 to greater than 1 weight percent V 2 O 5 . The United States has been and is currently the main producer of vanadium from SSV deposits, particularly those on the Colorado Plateau. Vanadium-rich black shales occur in marine successions that were deposited in epeiric (inland) seas and on continental margins. Concentrations in these shales regularly exceed 0.18 weight percent V 2 O 5 and can be as high as 1.7 weight percent V 2 O 5 . Small amounts of vanadium have been produced from the Alum Shale in Sweden and from ferrophosphorus slag generated during the reduction of phosphate to elemental phosphorus in ore from shales of the Phosphoria Formation in Idaho and Wyoming. Because vanadium enrichment occurs in beds that are typically only a few meters thick, most of the vanadiferous black shales are not currently economic, although they may become an important resource in the future. Significant amounts of vanadium are recovered as byproducts of petroleum refining, and processing of coal, tar sands, and oil shales may be important future sources. Vanadium occurs in one of four oxidation states in nature: +2, +3, +4, and +5. The V 3+ ion has an octahedral radius that is almost identical to that of (Fe 3+ ) and (Al 3+ ) and, therefore, it substitutes in ferromagnesian minerals. During weathering, much of the vanadium may partition into newly formed clay minerals, and it either remains in the +3 valence state or oxidizes to the +4 valence state, both of which are relatively insoluble. If erosion is insignificant but chemical leaching is intense, the residual material may be enriched in vanadium, as are some bauxites and laterites. During the weathering of igneous, residual, or sedimentary rocks, some vanadium oxidizes to the +5 valence state, especially in the intensive oxidizing conditions that are characteristic of arid climates. The average contents of vanadium in the environment are as follows: soils [10 to 500 parts per million (ppm)]; streams and rivers [0.2 to 2.9 parts per billion (ppb)]; and coastal seawater (0.3 to 2.8 ppb). Concentrations of vanadium in soils (548 to 7,160 ppm) collected near vanadium mines in China, the Czech Republic, and South Africa are many times greater than natural concentrations in soils. Additionally, if deposits contain sulfide minerals such as chalcocite, pyrite, and sphalerite, high levels of acidity may be present if sulfide dissolution is not balanced by the presence of acid-neutralizing carbonate minerals. Some of the vanadium-bearing deposit types, particularly some SSV and black-shale deposits, contain appreciable amounts of carbonate minerals, which lowers the acid-generation potential. Vanadium is a micronutrient with a postulated requirement for humans of less than 10 micrograms per day, which can be met through dietary intake. Primary and secondary drinking water regulations for vanadium are not currently in place in the United States. Vanadium toxicity is thought to result from an intake of more than 10 to 20 milligrams per day. Vanadium is essential for some biological processes and organisms. For example, some nitrogen-fixing bacteria require vanadium for producing enzymes necessary to convert nitrogen from the atmosphere into ammonia, which is a more biologically accessible form of nitrogen.

Professional Paper↗

Ground-water quality and its relation to hydrogeology, land use, and surface-water quality in the Red Clay Creek basin, Piedmont Physiographic Province, Pennsylvania and Delaware

The Red Clay Creek Basin in the Piedmont Physiographic Province of Pennsylvania and Delaware is a 54-square-mile area underlain by a structurally complex assemblage of fractured metamorphosed sedimentary and igneous rocks that form a water-table aquifer. Ground-water-flow systems generally are local, and ground water discharges to streams. Both ground water and surface water in the basin are used for drinking-water supply. Ground-water quality and the relation between ground-water quality and hydrogeologic and land-use factors were assessed in 1993 in bedrock aquifers of the basin. A total of 82 wells were sampled from July to November 1993 using a stratified random sampling scheme that included 8 hydrogeologic and 4 land-use categories to distribute the samples evenly over the area of the basin. The eight hydrogeologic units were determined by formation or lithology. The land-use categories were (1) forested, open, and undeveloped; (2) agricultural; (3) residential; and (4) industrial and commercial. Well-water samples were analyzed for major and minor ions, nutrients, volatile organic compounds (VOC's), pesticides, polychlorinated biphenyl compounds (PCB's), and radon-222. Concentrations of some constituents exceeded maximum contaminant levels (MCL) or secondary maximum contaminant levels (SMCL) established by the U.S. Environmental Protection Agency for drinking water. Concentrations of nitrate were greater than the MCL of 10 mg/L (milligrams per liter) as nitrogen (N) in water from 11 (13 percent) of 82 wells sampled; the maximum concentration was 38 mg/L as N. Water from only 1 of 82 wells sampled contained VOC's or pesticides that exceeded a MCL; water from that well contained 3 mg/L chlordane and 1 mg/L of PCB's. Constituents or properties of well-water samples that exceeded SMCL's included iron, manganese, dissolved solids, pH, and corrosivity. Water from 70 (85 percent) of the 82 wells sampled contained radon-222 activities greater than the proposed MCL of 300 pCi/L (picoCuries per liter). Differences in selected major and minor ion concentrations and radon-222 activities were statistically significant between some lithologies and are related to differences in mineralogy. Ground water from felsic gneiss and schist generally contained higher radon-222 activities than the other lithologies; activities as high as 10,000 pCi/L were measured in a water sample from the felsic gneiss. Differences in the concentrations of nitrate, sodium, and chloride, and the frequency of pesticide detections in ground water were statistically significant between samples from wells in some land-use categories. Concentrations of nitrate generally were greatest in agricultural and in industrial and commercial areas and can be attributed to the use of fertilizers on the land surface and other agricultural activities. Much of the industrial and commercial land use is in areas previously used for or related to mushroom production. Concentrations of chloride and sodium also were greatest in water from wells in agricultural and industrial and commercial areas, probably because of the use of fertilizer and road salt. Concentrations of nitrate, chloride, and sodium in water samples from wells in forested and residential land use did not differ statistically significantly from each other. The herbicides metolachlor and atrazine were the most frequently detected pesticides and were detected more frequently in agricultural areas than in areas with other land uses; their presence is related to their use in crop production. VOC's were detected infrequently and only in residential and industrial and commercial areas. The relation between ground-water quality and surface-water quality is assessed by comparing nitrate and chloride concentrations in the 1993 ground-water samples and 1993-94 base-flow samples. Base-flow samples were collected at eight stream sites in the headwaters of the West Branch of Red Clay Creek in 1994 and at two long-term stream-monitoing sites on the East and West Branches of the Red Clay Creek in 1993-94. The average concentrations of chloride and nitrate in ground-water samples from wells in areas above the headwater stream sites and two long-term stream-monitoring sites were similar to the concentrations of chloride and nitrate in base flow at those sites. An observed increase in nitrate concentration in base flow at the long-term monitoring site on the West Branch of Red Clay Creek from 1970 to 1995 may be related to an increase in nitrate concentrations in ground water in that area of the basin.

Water-Resources Investigations Report↗

Timing of rhyolite intrusion and Carlin-type gold mineralization at the Cortez Hills Carlin-type deposit, Nevada, USA

Carlin-type gold deposits (CTDs) of Nevada are the largest producers of gold in the United States, a leader in world gold production. Although much has been resolved about the characteristics and origin of CTDs in Nevada, major questions remain, especially about (1) the role of magmatism, whether only a source of heat or also metals, (2) whether CTDs only formed in the Eocene, and (3) whether pre-Eocene metal concentrations contributed to Eocene deposits. These issues are exemplified by the CTDs of the Cortez region, the second largest concentration of these deposits after the Carlin trend. Carlin-type deposits are notoriously difficult to date because they rarely generate dateable minerals. An age can be inferred from crosscutting relationships with dated dikes and other intrusions, which we have done for the giant Cortez Hills CTD. What we term “Cortez rhyolites” consist of two petrographic-geochemical groups of siliceous dikes: (1) quartz-sanidine-plagioclase-biotite-phyric, high-SiO 2 rhyolites emplaced at 35.7 Ma based on numerous 40 Ar/ 39 Ar dates and (2) plagioclase-biotite-quartz ± hornblende-phyric, low-SiO 2 rhyolites, which probably were emplaced at the same time but possibly as early as ~36.2 Ma. The dikes form a NNW-trending belt that is ~6 to 10 km wide × 40 km long and centered on the Cortez Hills deposit, and they require an underlying felsic pluton that fed the dikes. Whether these dikes pre- or postdated mineralization has been long debated. We show that dike emplacement spanned the time of mineralization. Many of both high- and low-SiO 2 dikes are altered and mineralized, although none constitute ore. In altered-mineralized dikes, plagioclase has been replaced by kaolinite and calcite, and biotite by smectite, calcite, and marcasite. Sanidine is unaltered except in a few samples that are completely altered to quartz and kaolinite. Sulfides present in mineralized dikes are marcasite, pyrite, arsenopyrite, and As-Sb–bearing pyrite. Mineralized dikes are moderately enriched in characteristic Carlin-type elements (Au, Hg, Sb, Tl, As, and S), as well as elements found in some CTDs (Ag, Bi, Cu, Mo), and variably depleted in MgO, CaO, Na 2 O, K 2 O, MnO, Rb, Sr, and Ba. In contrast, some high-SiO 2 rhyolites are unaltered and cut high-grade ore, which shows that they are post-ore. Both mineralized and post-ore dikes have indistinguishable sanidine 40 Ar/ 39 Ar dates. These characteristics, along with published interpretations that other giant CTDs formed in a few tens of thousands of years, indicate the Cortez Hills CTD formed at 35.7 Ma. All Cortez-area CTDs are in or adjacent to the Cortez rhyolite dike swarm, which suggests that the felsic pluton that fed the dikes was the hydrothermal heat source. Minor differences in alteration and geochemistry between dikes and typical Paleozoic sedimentary rock-hosted ore probably reflect low permeability and low reactivity of the predominantly quartzofeldspathic dikes. Despite widespread pre-35.7 Ma mineralization in the Cortez region, including deposits near several CTDs, we find no evidence that older deposits or Paleozoic basinal rocks contributed metals to Cortez-area CTDs. Combining our new information about the age of Cortez Hills with published and our dates on other CTDs demonstrates that CTD formation coincided with the southwestern migration of magmatism across Nevada, supporting a genetic relationship to Eocene magmatism. CTDs are best developed where deep-seated (~6–8 km), probably granitic plutons, expressed in deposits only as dikes, established large, convective hydrothermal systems.

Nevada↗