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Diagenesis of hydrocarbon-bearing rocks in the Middle Ordovician Simpson Group, southeastern Anadarko Basin, Oklahoma

Quartzarenites and subarkoses in the Middle Ordovician Simpson Group in the Gulf Costello No. 1 and Sunray-DX Parker No. 1 Mazur wells, southeastern Anadarko basin, have undergone a complex diagenetic and petroleum-migration history. During early burial, petroleum migrated locally through sandstones; patches of bitumen in calcite and bitumen-lined quartz overgrowths containing oil-bearing inclusions reflect the introduction of petroleum-bearing fluids at shallow depths. Stable-isotope data reveal that early calcite precipitated at near-surface temperatures from fluids dominated by marine carbon. At moderate to deep burial, calcite dissolution, followed by ferroan-dolomite and clay-mineral precipitation, occurred at about the same time as the rocks reached levels of thermal maturity sufficient for the generation of hydrocarbons. Maximum paleotemperatures during deep burial are estimated from maturation models to have reached 250°F in the Costello well and 300°F in the Mazur well. Maturation-derived temperatures in the Costello well are consistent with preliminary homogenization temperatures (210-250°F) for oil inclusions along microscopic healed fractures that formed during deep burial, thus supporting an Early to Middle Pennsylvanian timing for the generation and migration of late-stage hydrocarbons. The early petroleum phase, emplaced while the rocks were at shallow burial depths, migrated from mature source rocks deeper in the basin.

Oklahoma↗

Reduction of red bed sedimentary rocks in connection with energy metal ore formation: A case study from the Sinbad seep, Mesa County, Colorado

The Paradox Basin’s Sinbad seep is a modern analog for ancient bleaching of red bed sediments by introduced alkaline, reducing brines. This bleaching, involving reductive alteration of former red beds, is essential ground preparation that enables the altered rocks to trap Cu, U, and V from later oxidized fluids, forming ore deposits. Study of Sinbad thus offers insights into these metallic mineralization processes in the Paradox and other sedimentary basins. The Sinbad seep occurs where shallow groundwater interacts with organic-rich petroleum source rocks, flows up a fault, and discharges into Salt Creek. Ratios of Na/Cl, Na/Br, and Cl/Br, plus high sulfate concentrations, indicate that the salinity of the seep water originated from dissolution of halite and gypsum during topographically driven flow of meteoric water across a diapir of the Pennsylvanian Paradox Formation, rather than from deep basinal brines. In contact with the organic-rich shales of the Paradox, these SO 4 -rich waters become reduced through bacterial reduction, producing H 2 S. The waters react with red beds of the Permian Cutler Formation, causing pervasive bleaching. The bleaching at Sinbad is characterized by iron-conservative reduction of ferric iron in diagenetic hematite and detrital ilmenite and magnetite to Fe sulfides. The ferrous iron is retained in these sulfides likely as sorbed Fe. Associated alteration includes precipitation of quartz and feldspar overgrowths, partial dissolution of detrital quartz and feldspar caused by pressure solution, formation of clay and authigenic rutile, and precipitation of carbonate and gypsum. The Fe sulfides rapidly degenerate to a mixture of jarosite and iron oxides on weathering at the surface. Among the major-oxide elements and most trace elements, there is no statistical difference between unbleached and bleached samples. The exceptions are uranium and sulfur, which are somewhat greater in bleached samples. Fission track radiography illuminates that uranium is preferentially concentrated in iron oxide cements, iron sorbed into detrital clasts, and finely disseminated iron oxide in illite cement in bleached samples. A leaching experiment suggests that uranium may be more easily available for mobilization from rocks that have undergone bleaching alteration, making them potential U sources. In addition, bleached rocks form effective traps for U, V, and some Cu mineralization.

Colorado↗

Composition of dust deposited to snow cover in the Wasatch Range (Utah, USA): Controls on radiative properties of snow cover and comparison to some dust-source sediments

Dust layers deposited to snow cover of the Wasatch Range (northern Utah) in 2009 and 2010 provide rare samples to determine the relations between their compositions and radiative properties. These studies are required to comprehend and model how such dust-on-snow (DOS) layers affect rates of snow melt through changes in the albedo of snow surfaces. We evaluated several constituents as potential contributors to the absorption of solar radiation indicated by values of absolute reflectance determined from bi-conical reflectance spectroscopy. Ferric oxide minerals and carbonaceous matter appear to be the primary influences on lowering snow-cover albedo. Techniques of reflectance and Mössbauer spectroscopy as well as rock magnetism provide information about the types, amounts, and grain sizes of ferric oxide minerals. Relatively high amounts of ferric oxide, indicated by hard isothermal remanent magnetization (HIRM), are associated with relatively low average reflectance (<0.25) across the visible wavelengths of the electromagnetic spectrum. Mössbauer spectroscopy indicates roughly equal amounts of hematite and goethite, representing about 35% of the total Fe-bearing phases. Nevertheless, goethite (α-FeOOH) is the dominant ferric oxide found by reflectance spectroscopy and thus appears to be the main iron oxide control on absorption of solar radiation. At least some goethite occurs as nano-phase grain coatings less than about 50 nm thick. Relatively high amounts of organic carbon, indicating as much as about 10% organic matter, are also associated with lower reflectance values. The organic matter, although not fully characterized by type, correlates strongly with metals (e.g., Cu, Pb, As, Cd, Mo, Zn) derived from distal urban and industrial settings, probably including mining and smelting sites. This relation suggests anthropogenic sources for at least some of the carbonaceous matter, such as emissions from transportation and industrial activities. The composition of the DOS samples can be compared with sediments in a likely dust-source setting at the Milford Flat Fire (MFF) area about 225 km southwest of Salt Lake City. The MFF area represents geologically and physiographically similar and widespread dust sources west-southwest of the Wasatch Range and heavily populated Wasatch Front. The DOS layers and MFF sediments are similar in some textural, chemical, and magnetic properties, as well as in the common presence of goethite, hematite, magnetite-bearing basalt fragments, quartz, plagioclase, illite, and kaolinite. Textural and some chemical differences among these deposits can be explained by atmospheric sorting as well as by inputs from other settings, such as salt-crusted playas and contaminant sources.

Utah↗

Influence of rock composition on the geochemistry of stream and spring waters from mountainous watersheds in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado

The ranges of geochemical baselines for stream and spring waters were determined and maps were constructed showing acid-neutralizing capacity and potential release of total dissolved solids for streams and spring waters for watersheds underlain by each of ten different rock composition types in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado (GMUG). Water samples were collected in mountainous headwater watersheds that have comparatively high precipitation and low evapotranspiration rates and that generally lack extensive ground-water reservoirs. Mountainous headwaters react quickly to changes in input of water from rain and melting snow and they are vulnerable to anthropogenic impact. Processes responsible for the control and mobility of elements in the watersheds were investigated. The geochemistry of water from the sampled watersheds in the GMUG, which are underlain by rocks that are relatively unmineralized, is compared to the geochemistry of water from the mineralized Redcloud Peak area. The water with the highest potential for release of total dissolved solids is from watersheds that are underlain by Paleozoic sedimentary rocks; that high potential is caused primarily by gypsum in those rocks. Water that has the highest acid-neutralizing capacity is from watersheds that are underlain by Paleozoic sedimentary rocks. The water from watersheds underlain by the Mancos Shale has the next highest acid-neutralizing capacity. Water that has the lowest acid-neutralizing capacity is from watersheds that are underlain by Tertiary ash-flow tuff. Tertiary sedimentary rocks containing oil shale, the Mesavede Formation containing coal, and the Mancos Shale all contain pyrite with elevated metal contents. In these mountainous head-water areas, water from watersheds underlain by these rock types is only slightly impacted by oxidation of pyrite, and over-all it is of good chemical quality. These geochemical baselines demonstrate the importance of rock composition in determining the types of waters that are in the headwater areas. The comparison of these geochemical baselines to later geochemical base-lines will allow recognition of any significant changes in water quality that may occur in the future.

Colorado↗

Origin and significance of high nickel and chromium concentrations in pliocene lignite of the Kosovo Basin, Serbia

Trace element data from 59 Pliocene lignite cores from the lignite field in the Kosovo Basin, southern Serbia, show localized enrichment of Ni and Cr (33-304 ppm and 8-176 ppm, respectively, whole-coal basis). Concentrations of both elements decrease from the western and southern boundaries of the lignite field. Low-temperature ash and polished coal pellets of selected bench and whole-coal samples were analyzed by X-ray diffraction and scanning electron microscopy with energy-dispersive X-ray analyses. These analyses show that most of the Ni and Cr are incorporated in detrital and, to a lesser degree, in authigenic minerals. The Ni- and Cr-bearing detrital minerals include oxides, chromites, serpentine-group minerals and rare mixed-layer clays. Possible authigenic minerals include Ni-Fe sulfates and sulfides. Analyses of three lignite samples by a supercritical fluid extraction technique indicate that some (1-11%) of the Ni is organically bound. Ni- and Cr-bearing oxides, mixed-layer clays, chromites and serpentine-group minerals were also identified in weathered and fresh samples of laterite developed on serpentinized Paleozoic peridotite at the nearby Glavica and C??ikatovo Ni mines. These mines are located along the western and northwestern rim, respectively, of the Kosovo Basin, where Ni contents are highest. The detrital Ni- and Cr-bearing minerals identified in lignite samples from the western part of the Kosovo Basin may have been transported into the paleoswamp by rivers that drained the two Paleocene laterites. Some Ni may have been transported directly into the paleoswamp in solution or, alternatively, Ni may have been leached from detrital minerals by acidic peat water and adsorbed onto organic matter and included into authigenic mineral phases. No minable source of Ni and Cr is known in the southern part of the lignite field; however, the mineral and chemical data from the lignite and associated rocks suggest that such a source area may exist.

International Journal of Coal Geology↗

Soil geochemistry of Mother Lode-type gold deposits in the Hodson mining district, central California, U.S.A.

The Hodson mining district is in the westernmost foothills of the Sierra Nevada in California, about 17 km west of the town of Angels Camp. This district is part of the West Gold Belt, which lies about 12-16 km west of, and generally parallel to, the better known Mother Lode Gold Belt in central California. The district produced several million dollars worth of Au between about 1890 and 1940. The geologic setting and mineral deposits in the West Gold Belt are generally similar to those in the Mother Lode Gold Belt. Rocks in the study area are of Jurassic age and consist of a mixture of (1) fine-grained, generally thin-bedded, clastic sedimentary rocks that have been metamorphosed to slates, schists, and phyllites, and (2) massive volcanic flows and welded tuffs that have been metamorphosed to metabasalts and metatuffs. All rocks were intensely faulted and folded during the Late Cretaceous Nevadan orogeny; northnorthwest- and northwest-trending faults dominate. Mining in the area was of low-grade gold-pyrite ores occurring principally in the carbonatized wall rocks adjacent to the major northwest-trending Hodson fault and its splays. Minor amounts of other sulfide minerals (principally chalcopyrite, arsenopyrite, sphalerite, and galena) are locally associated with the Au deposits.

California↗

Vadose zone controls on weathering intensity and depth: Observations from grussic saprolites

An investigation of vadose zone weathering processes has been undertaken on grussic saprolites developed on Californian granitoids. Preliminary results indicate strong climatic control, through infiltration, on the depth and intensity of weathering. At sites with higher infiltration, the vadose zone is comprehensively altered to grussic saprolite and saprock. Conversely, lower infiltration sites display only thin grussic saprolites, strongly influenced by rock texture. Both vadose zone and weathering depth appear to be governed by local base level, and vadose zone hydrology exerts a fundamental control on the effective operation and relative dominance of the key weathering reactions. In zones of matrix permeability, oxidation of biotite comprehensively disaggregates the rock but results in little mass loss and clay mineral formation. Conversely, the higher transient flow rates that characterize zones of fracture permeability result in plagioclase hydrolysis, significant mass losses and accompanying clay mineral formation. A variable hydrological regime may also contribute to high partial pressures of O 2 in vadose zone pore waters and pore spaces, thereby enhancing the oxidative environment and further predisposing grussic saprolite formation.

Applied Geochemistry↗

Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars

The feldspar and pyroxene mineralogies on Mars revealed by the Thermal Emission Spectrometer (TES) on Mars Global Surveyor likely record a variety of shock effects, as suggested by petrologic analyses of the Martian meteorites and the abundance of impact craters on the planet's surface. To study the effects of shock pressures on thermal infrared spectra of these minerals, we performed shock recovery experiments on orthopyroxenite and anorthosite samples from the Stillwater Complex (Montana) over peak pressures from 17 to 63 GPa. We acquired emissivity and hemispherical reflectance spectra (350–1400 cm −1 ; ∼7–29 μm) of both coherent chips and fine-grained powders of shocked and unshocked samples. These spectra are more directly comparable to remotely sensed data of Mars (e.g., TES) than previously acquired absorption or transmission spectra of shocked minerals. The spectra of experimentally shocked feldspar show systematic changes with increasing pressure due to depolymerization of the silica tetrahedra. For the spectra of chips, this includes the disappearance of small bands in the 500–650 cm −1 region and a strong band at 1115 cm −1 , and changes in positions of a strong band near 940 cm −1 and the Christiansen feature near 1250 cm −1 . Spectra of the shocked powders show the gradual disappearance of a transparency feature near 830 cm −1 . Fewer changes are observed in the pyroxene spectra at pressures as high as 63 GPa. Spectra of experimentally shocked minerals will help identify more precisely the mineralogy of rocks and soils not only from TES but also from Mars instruments such as miniTES and THEMIS.

Journal of Geophysical Research E: Planets↗

Corundum discovered by SuperCam and the Perseverance rover at Jezero crater, Mars

Mars is primarily composed of mafic mineral assemblages and their alteration products, but small, scattered rocks strewn across the landscape offer clues to greater petrological diversity. While traversing the Jezero crater rim, the Perseverance rover encountered several plagioclase-rich light-toned float rocks. SuperCam identified the distinctive signature of corundum (α-Al 2 O 3 ) in these rocks using time-resolved luminescence spectroscopy. Two strong peaks (692.7 and 694.1 nm) with millisecond lifetimes, and additional supporting lines, are consistent with Cr 3+ substitution for Al 3+ in corundum. Corundum forms in Al-rich, Si-depleted environments through magmatic or metamorphic processes. Given the rocks' small size, association with plagioclase, and location on the crater rim, we interpret the most plausible formation scenario to be impact induced metamorphism at the interface of a felsic and a mafic/ultramafic member with the likely action of fluids at some stage, although other possibilities are not excluded.

Geophysical Research Letters↗

Conodont color and textural alteration: An index to regional metamorphism, contact metamorphism, and hydrothermal alteration

Experimental and field data are used to extend the utility of conodonts as semi-quantitative thermal indices into the regimes of regional and contact metamorphism, as well as hydrothermal alteration. An Arrhenius plot of data from induced conodont color alteration by pyrolysis in air at 1 atm was used to generate the geologic temperatures for conodont color-alteration indices (CAI) above 300 °C, that is, for CAI values of 5½ through 8. Such CAI values occur in very low- to medium-grade, regionally metamorphosed, contact-metamorphosed, and hydrothermally altered rocks. The uniformity or variability of CAI values within a sample, together with conodont texture, can help to distinguish grades and environments of metamorphism, particularly in metacarbonate sequences. Induced CAI by pyrolysis in a water-methane mixture at ½ kbar results in retardation of CAI and in a disparate mixture of both low and high CAI values within each experimental sample. In this system, color-alteration processes, above a CAI of 2 to 3, seem to change from predominantly carbonization to predominantly loss of organic matter, presumably by oxidation and volatilization of oxides. These experiments approximate the type of CAI mixture characteristically found in conodonts recovered from hydrothermally altered rocks. These data indicate that CAI values of 6 to 8 cannot be used to assess precise temperatures of hydrothermally altered rocks but may serve as useful indicators of potential mineralization.

Geological Society of America Bulletin↗

Geochemical evidence for airborne dust additions to soils in Channel Islands National Park, California

There is an increasing awareness that dust plays important roles in climate change, biogeochemical cycles, nutrient supply to ecosystems, and soil formation. In Channel Islands National Park, California, soils are clay-rich Vertisols or Alfisols and Mollisols with vertic properties. The soils are overlain by silt-rich mantles that contrast sharply with the underlying clay-rich horizons. Silt mantles contain minerals that are rare or absent in the volcanic rocks that dominate these islands. Immobile trace elements (Sc-Th-La and Ta-Nd-Cr) and rare-earth elements show that the basalt and andesite on the islands have a composition intermediate between upper-continental crust and oceanic crust. In contrast, the silt fractions and, to a lesser extent, clay fractions of the silt mantle have compositions closer to average upper-continental crust and very similar to Mojave Desert dust. Island shelves, exposed during the last glacial period, could have provided a source of eolian sediment for the silt mantles, but this is not supported by mineralogical data. We hypothesize that a more likely source for the silt-rich mantles is airborne dust from mainland California and Baja California, either from the Mojave Desert or from the continental shelf during glacial low stands of sea. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. The eolian silt mantles constitute an important medium of plant growth and provide evidence that abundant eolian silt and clay may be delivered to the eastern Pacific Ocean from inland desert sources. ?? 2007 Geological Society of America.

Geological Society of America Bulletin↗

Preliminary report on the stratigraphy and structure of the area of the Utukok River with notes on the Corwin-Cape Beaufort region, Alaska

U.S. Geological Survey Party 3 studied the geology of the Utukok River area and conducted a short reconnaissance of the Corwin-Cape Beaufort Region during the period May 12 to August 31, 1947. The upper part of the Utukok River was examined for several miles on either side while the lower, or Coastal Plain-portion, was necessarily limited to the few outcrops along the river. During this study, the major emphasis was placed upon rocks of Upper Cretaceous age and their relationships to the underlying Lower Cretaceous rocks. All macrofossils, and numerous samples for porosity, heavy mineral, and microfossil determinations were collected. A triangulation net was established by theodolite from Camp. 1 near the headwaters of the river to the mouth of Carbon Creek. The survey started and ended on measured base lines, and stations were determined by intersection and resection. Stations were selected, insofar as possible, on points that could be pin pricked on aerial photographs where adequate coverage was available, Horizontal control was computed for cartographic purposes. Vertical differences were computed from an elevation at Camp 1 assumed at 2,000 feet above sea level based upon two different airplane altimeter readings. Most of the country is too rough for wheel landings with the exception of several gravel bars in the river between Camp 6 and the coast. Pontoon landings with a Cub plane can be made at most places on the river. Driftwood, Adventure, Disappointment, Carbon, and Elusive Creeks are the main tributaries to the Utukok. At various localities, terrace gravels are common on divides of these streams. A terrace north of Driftwood Creek and about ten miles east of Camp 2 is covered with a deposit of gravel which is apparently, thick and is spread over an irregular area about two miles long and a half mile wide. A thin tundra cover obscures what is probably a much larger continuation of the gravel deposit. With favorable conditions plane landings could be made, but with a little construction work a commercial size airfield could be made.

Alaska↗

Preliminary geologic map of the Cherry Hill quadrangle, Dinwiddie, Sussex, and Greensville Counties, Virginia

The Cherry Hill 7.5-minute quadrangle straddles the Coastal Plain and Piedmont Provinces along the Tidewater Fall Line. Rocks of the eastern Piedmont Roanoke Rapids terrane crop out in the western part of the quadrangle and consist of greenschist- to amphibolite-facies Neoproterozoic felsic to intermediate metavolcanic rocks, some of which contain flattened quartz phenocrysts and are locally isoclinally folded; greenstone that locally preserves primary layering; and intrusive metadiorite and metagabbro, much of which has been altered to amphibolite. Most of these rocks are strongly foliated and jointed. Greenschist-facies metasiltstone that preserves primary bedding also occurs locally in the Roanoke Rapids terrane. Neoproterozoic mica schist, middle Paleozoic foliated metagranite, and late Paleozoic massive and porphyritic granite crop out in the eastern part of the quadrangle and are part of the Dinwiddie terrane and the late Paleozoic De Witt pluton. Upper greenschist- to lower amphibolite-facies mica schist consists of stringers and boudins of vein quartz and contains porphyroclasts of staurolite that preserve an earlier foliation as inclusion trails. Porphyroblasts of garnet, staurolite, and kyanite also occur locally. Foliation in granites of the De Witt pluton may be magmatic. Separating the Dinwiddie terrane from the Roanoke Rapids terrane are greenschist-facies, highly strained granitic mylonite and bodies of less deformed granite within the Nottoway River fault zone, which is a strand of the eastern Piedmont fault system. Paleozoic pegmatite dikes and quartz veins cross-cut rocks of the Dinwiddie terrane, and quartz veins and Jurassic diabase dikes cross-cut rocks of the Roanoke Rapids terrane. Sand and gravel deposits of the Atlantic Coastal Plain overlie Piedmont rocks. Two units assigned to the upper part of the Neogene Chesapeake Group occur at elevations up to 295 feet (90 meters) above sea level atop the Richmond plain in the central part of the quadrangle. Two units of the Quaternary Bacons Castle Formation occupy the Essex plain and Norge uplands at elevations up to 180 feet (55 meters) above sea level in the eastern part of the quadrangle. In the western part of the quadrangle, multiple levels of terrace deposits are the fluvial equivalent of estuarine to marine units of the Atlantic Coastal Plain to the east. Holocene alluvium occurs along creeks and the Nottoway River. Quaternary colluvial deposits occur locally. Numerous Carolina bays pock the landscape of the Richmond and Essex plains, and three abandoned channelways represent former locations of Sappony Creek, one of the major drainages of the quadrangle. Brittle faults juxtapose Piedmont basement rocks against Neogene sediments of the upper part of the Chesapeake Group. These Cenozoic faults were first uncovered in mine excavations in the late 1990s; new mapping indicates that many of these faults are reactivated silicified cataclasite zones that occur throughout the Piedmont basement rocks. Silicified cataclasites and associated quartz veins are typically mineralized with iron and iron sulfide minerals. The quadrangle was the focus of extensive mining for heavy minerals, including ilmenite and zircon, in upland Atlantic Coastal Plain deposits beginning in the mid-1990s. Other mineral resources, including precious metals, clay for structural brick, crushed stone, and building stone for millstones, have also been prospected or quarried in the quadrangle.

Virginia↗

Geology of the Olds Mountain-Clark Peak area, Juneau and vicinity, Alaska

The area under study lies about ten miles east of Juneau, Alaska, and includes the bedded rocks adjacent to the Coast Range batholith, and intrusive rocks related to the batholith. Deep glaciated valleys and glacially scoured rocks are the major topographic features. The relief is about 3,500 feet, and the highest mountain reaches an altitude of 4,453 feet. Remnants of larger glaciers and perennial snow fields cover many of the higher summits, and glacial erratics at elevations above 3,100 feet attest to a former thick ice cover. The bedded rocks are crystalline schists that locally reach katozonal metamorphic rank as indicated by biotite-garnet-kyanite-sillimanite mineral assemblages. The schists are believed to be dominantly a product of regional metamorphism predating the intrusion of rocks related to the Coast Range batholith. It appears, however, that stresses continued to be active during igneous and granitizing activity accompanying the Coast Range orogeny. The major intrusive bodies are a composite quartz-dioritic batholith and quartz-diorite sills that locally reach a thickness of more than two thousand feet. The sills usually are notably gneissic, and appear to have formed by intrusion rather than replacement. The batholith is a composite body formed by migmatization, replacement, and local fusion. A stressed environment during formation is suggested by a primary gneissic structure. A high quartz content and a paucity of potash feldspars is diagnostic of the intrusive bodies. In addition to the bodies of quartz-diorite, small sills and dikes of gabbro, quartz-pegmatite, and unmetamorphosed diabase intrude the schists. Overturned folds in the schists are nearly isoclinal, and some of the folds are large enough to cause repetition of beds in the Clark Peak schists. Two persistent northwest-trending strike faults of small displacement cut the schists. Two east-trending faults of larger displacement are marked by thick gouge zones locally containing graphite. The rocks near the faults are hydrothermally altered and pyritized, and at least two of the diabase dikes are crushed and hydrothermally altered near one of the northwest-trending faults. Faulting and hydrothermal activity probably continued at least into the early Tertiary.

Open-File Report↗

Physical exploration for uranium during 1951 in the Silver Reef district, Washington County, Utah

During 1951 a joint exploration program of the most promising uraniferous areas in the Silver Reef district was made by the U.S. Geological Survey and the U.S. atomic Energy Commission. A U.S. Bureau of Mines drill crew, on contract to the Atomic Energy Commission, did 2,450 feet of diamond drilling under the geological supervision of the U.S. Geological Survey. The purpose of the drilling was to delineate broadly the favorable ground for commercial development of the uranium deposits. Ten drill holes were located around Pumpkin Point, which is the northeastern end of Buckeye Reef, to probe for extensions of small ore sheets mined on the Point in fine-grained sandstones of the Chinle formation. Three additional holes were located around Tecumseh Hill to probe for extensions of the small showings of uranium-bearing rocks of Buckeye Reef. Only one trace of uranium mineral was detected in the 13 drill holes by logging of drill cores, gamma-ray logging of the holes, and analysis of many core splits from favorable lithology. Extensive traversing with Geiger counters throughout the district and detailed geologic mapping of areas on Buckeye Reef and on East Reef indicate that the chances of discovering significant uranium deposits in the Silver Reef district are very poor, because of: highly variable lithology, closely faulted structure, and obliteration of the shallow uranium-bearing lenses by silver mining. Most of the available ore in the district was in the Pumpkin Point area and has been mined during 1950 to 1953. No ore reserves can be computed for the district before further development work. The most favorable remaining area in the district is now being explored by the operators with Atomic Energy Commission supervision.

Open-File Report↗

Questa baseline and pre-mining ground-water quality investigation. 20. Water chemistry of the Red River and selected seeps, tributaries, and precipitation, Taos County, New Mexico, 2000-2004

As part of a multi-year project to infer the pre-mining ground-water quality at Molycorp's Questa mine site, surface-water samples of the Red River, some of its tributaries, seeps, and snow samples were collected for analysis of inorganic solutes and of water and sulfate stable isotopes in selected samples. The primary aim of this study was to document diel, storm event, and seasonal variations in water chemistry for the Red River and similar variations in water chemistry for Straight Creek, a natural analog site similar in topography, hydrology, and geology to the mine site for inferring pre-mining water-quality conditions. Red River water samples collected between 2000 and 2004 show that the largest variations in water chemistry occur during late summer rainstorms, often monsoonal in nature. Within hours, discharge of the Red River increased from 8 to 102 cubic feet per second and pH decreased from 7.80 to 4.83. The highest concentrations of metals (iron, aluminum, zinc, manganese) and sulfate also occur during such events. Low-pH and high-solute concentrations during rainstorm runoff are derived primarily from alteration 'scar' areas of naturally high mineralization combined with steep topography that exposes continually altered rock because erosion is too rapid for vegetative growth. The year 2002 was one of the driest on record, and Red River discharge reflected the low seasonal snow pack. No snowmelt peak appeared in the hydrograph record, and a late summer storm produced the highest flow for the year. Snowmelt was closer to normal during 2003 and demonstrated the dilution effect of snowmelt on water chemistry. Two diel sampling events were conducted for the Red River, one during low flow and the other during high flow, at two locations, at the Red River gaging station and just upstream from Molycorp's mill site. No discernible diel trends were observed except for dissolved zinc and manganese at the upstream site during low flow. Straight Creek drainage water was sampled periodically from 2001 to 2004 at the down stream end of surface drainage near the point at which it disappeared into the debris fan. This water has a minimal range in pH (2.7 to 3.2) but a substantial concentration range in many solutes; for example, sulfate concentrations varied from 525 to 2,660 mg/L. Many elements covary with sulfate suggesting that dilution is the primary control of the range in solute concentrations. A transect of water samples higher in the scar area were collected in October of 2003. They had a lower range in pH (2.44 to 3.05) and higher solute concentrations than those collected periodically from lower in the catchment. Water isotopes for the upper transect samples indicated slight evaporation, and in part, may account for the higher solute concentrations. Drainage waters also were collected from Hottentot, Junebug, Hansen, Little Hansen, and Goat Hill Gulch drainages. Most constituents from other scar drainage waters showed ranges of concentration similar to those of the Straight Creek waters. An exception was water collected from Goat Hill Gulch, which has some of the highest concentrations of any surface-water sample collected but also contained waste-rock leachates.

New Mexico↗

Water-quality data analysis of the upper Gunnison River watershed, Colorado, 1989-99

Water-quality data from October 1969 to December 1999 for both surface water and ground water in the upper Gunnison River watershed were retrieved and compiled from the U.S. Geological Survey National Water Information System and the U.S. Environmental Protection Agency Storage and Retrieval databases. Analyses focused primarily on a subset of these data from October 1989 to December 1999. The upper Gunnison River watershed is located west of the Continental Divide in the Southern Rocky Mountains physiographic province. Surface-water-quality data were compiled for 482 sites in the upper Gunnison River watershed. Most values of surface-water temperature, dissolved oxygen, and pH were within Colorado Department of Public Health and Environment (CDPHE) in-stream standards. Calcium bicarbonate type water was the most spatially dominant water type in the basin. Nutrients were most commonly sampled along the Slate River and East River near Crested Butte and along the Gunnison River from the confluence of the East and Taylor Rivers to the western edge of the watershed. Median ammonia concentrations were low, with many concentrations less than laboratory reporting levels. All nitrate concentrations met the CDPHE in-stream standard of 10 milligrams per liter. More than 30 percent of stream sites with total phosphorus data (23 of 61 sites) had concentrations greater than the U.S. Environmental Protection Agency (USEPA) recommendation for controlling eutrophication. Ammonia concentrations at a site on the Slate River near Crested Butte had a statistically significant upward trend for the 1995–99 period. The Slate River near Crested Butte site is located immediately downstream from the towns of Crested Butte and Mount Crested Butte and may reflect recent population growth or other land-use changes. However, the rate of change of the trend is small (0.017 milligram per liter per year). Although a multiple comparison test showed nitrate concentrations were statistically different between agriculture and forest sites and between agriculture and urban land-use classified sites, median concentrations were low among all land-use settings. Median concentrations of total phosphorus were greatest in rangeland areas and least in urban areas. No significant differences were identified for median concentrations of total phosphorus in agriculture and forest land-use areas. Median concentrations of arsenic, lead, mercury, selenium, and silver were low or below reporting levels throughout the watershed. Aluminum, cadmium, copper, lead, manganese, and zinc concentrations were elevated near the town of Crested Butte and on Henson Creek upstream from Lake City, which may be explained by upstream areas of historical mining. Samples for six trace elements exceeded standards: cadmium, copper, lead, manganese, silver, and zinc. A downward trend (3 micrograms per liter per year) was identified for the dissolved iron concentration at a site on the Gunnison River at County Road 32 downstream from the city of Gunnison. Streambed-sediment samples from areas affected by historical mining also had elevated concentrations of some trace elements. Chlorophyll- a concentrations in samples from Blue Mesa Reservoir and streams in the Crested Butte and Gunnison areas were typical of unenriched to moderately enriched conditions. Median concentrations of 5-day biochemical oxygen demand concentrations for sites between Crested Butte and Blue Mesa Reservoir were less than 2 milligrams per liter. Occasional high (greater than 200 counts per 100 milliliters) concentrations for fecal coliform were determined at selected sites within the study area. However, median concentrations were less than 100 counts per 100 milliliters except for the Squaw Creek and Cimarron River areas in the western part of the watershed. Ground-water-quality data have been collected by the U.S. Geological Survey from 99 wells. Many wells were completed in aquifers composed of Holocene-age valley fill and alluvium. Most field properties were within the USEPA Secondary Drinking Water Regulations (SDWR) range for treated drinking water, except for 2 (of 40) pH samples. Calcium bicarbonate was the predominant water type in nearly all aquifers except for the aquifers composed of volcanic rock, which had more sodium and sulfate mixed water types. Wells with sulfate concentrations exceeding the SDWR of 250 milligrams per liter were completed in aquifers composed of volcanic rock near Lake City. Dissolution and oxidation of sulfide minerals in these aquifers may explain the elevated sulfate concentrations in ground water at these locations. Nutrient concentrations in ground water were generally low, and median concentrations for ammonia, nitrite, and dissolved phosphorus were below reporting levels. All nitrate concentrations in the samples were below the USEPA drinking-water maximum contaminant level of 10 mg/L. No statistical difference was found in nitrate concentrations among the four land-use classifications (agriculture, forest, rangeland, and urban). Trace elements in ground water were generally below the USEPA SDWR. Three iron samples exceeded the USEPA SDWR of 300 micrograms per liter at two wells located near the city of Gunnison and at a well south of the town of Powderhorn near the Cebolla River. Nine of 39 manganese samples exceeded the USEPA SDWR of 50 micrograms per liter and were collected from aquifers composed of Holocene-age valley fill and alluvium near Gunnison and Crested Butte and in one well near the Cebolla River. Radon gas is a natural radioactive decay product of uranium. All 39 radon samples collected from ground water in the watershed exceeded the proposed USEPA drinking-water maximum contaminant level of 300 picocuries per liter and ranged from 426 to 3,830 picocuries per liter.

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