Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “Contribution”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,387 records · Page 77Linked to original sources

Etiology of a fish kill, Including the endangered Tidewater Goby (Eucyclogobius newberryi), in a northeastern pacific coastal lagoon

Ecological disturbances such as fish kills can negatively impact ecosystem processes in coastal lagoons. To gain an understanding of factors causing fish kills, we examined conditions associated with a summertime fish kill in a northeastern Pacific coastal lagoon (Rodeo Lagoon, CA, USA). Examination of available data indicated the fish kill was likely caused by hypoxia involving the following etiology: (1) strong onshore winds (up to 12 m/s) mixed a stratified water column, (2) water column mixing transported nutrients from near the bed into the photic zone, (3) increased nutrient concentrations in the photic zone (> 200%) together with high solar irradiance fueled a phytoplankton bloom, (4) death and decomposition of phytoplankton (72% decrease in abundance) contributed to biological oxygen demand that led to (5) hypoxic conditions (as low as 0.6 mg/L) that caused the fish kill. The event resulted in the death of an estimated 3677 Tidewater Goby ( Eucyclogobius newberryi ), a species listed as endangered under the US Endangered Species Act, and numerous (but not enumerated) Threespine Stickleback ( Gasterosteus aculeatus ), unidentified sculpins (Cottidae), and macroinvertebrates (primarily Amphipoda). The processes contributing to the event are likely re-occurring phenomena responsible for observed periodic fish kills. Coastal lagoons with limited freshwater inflows and connection to the Pacific Ocean may retain nutrients and be susceptible to similar events.

California↗

Accelerating elevation gain indicates land loss associated with erosion in Mississippi River Deltaic Plain tidal wetlands

In recent years, the Mississippi River Deltaic Plain (MRDP) has experienced the highest rates of wetland loss in the USA. Although the process of vertical drowning has been heavily studied in coastal wetlands, less is known about the relationship between elevation change and land loss in wetlands that are experiencing lateral erosion and the contribution of erosion to land loss in the MRDP. We quantified relationships of elevation change and land change in ten submerging tidal wetlands and found that, despite significant land loss, elevation trajectories in seven of the land loss study sites were positive. Furthermore, we observed an acceleration in elevation gain preceding the conversion from vegetated marsh to open water. To identify regional contributions of lateral erosion to land loss, we quantified the relationship of elevation change and land change in 159 tidal marsh sites in the MRDP. Approximately half the sites were persistently losing land, and 82% of these sites were vulnerable to erosion, identifying erosion as a dominant mechanism of coastal wetland loss in this region. Notably, the sites that were vulnerable to erosion were experiencing land loss while also gaining elevation, and sites with the highest land loss exhibited accelerating elevation gain. Together, these data illustrate that (1) erosion is a dominant mechanism of wetland loss in the MRDP, (2) accelerated elevation gain is an indicator of erosion, and (3) consideration of elevation change trajectories within the context of land change is critical for providing accurate coastal wetland vulnerability assessments.

Louisiana↗

Spring distribution in Winona County, Minnesota, USA and the relationship with geologic strata in a karst landscape

Karst aquifers are important groundwater resources, but are vulnerable to contamination due to relatively rapid subsurface transport. Springs, points where the landscape and water table intersect and cold groundwater discharges, link aquifer systems with land surfaces and water bodies. As such, in many regions, they are critical to the viability of lakes, streams and cold-water fish communities. An understanding of where springs are located is important to watershed, fishery and environmental management efforts in karst regions. To better understand spatial distribution of springs and as a potential method for identifying variables that characterize locations of springs for improved land and watershed management, a nearest-neighbor analysis and a discriminant function analysis (DFA) of springs were conducted in Winona County, Minnesota, USA, a karst landscape. Nearest-neighbor analysis examined the spatial spring distribution. Twenty-two variables describing the locations of springs were analyzed to ascertain their ability to discriminate correct aquifer unit or bedrock unit classification for each spring. Springs were clumped with the highest densities in the lowest elevations. Springs were correctly assigned to aquifer units and bedrock units with eight and 11 landscape variables, respectively. Forest land cover was the only land cover type contributing to spring discrimination. Consideration of upland human activities, particularly in forested areas, on spring discharge along with a better understanding of characteristics describing spring locations could lead to better management activities that locate and protect springs and their important contributions to regional ecohydrology.

Minnesota↗

A 3-year in-situ measurement of CO2 efflux in coastal wetlands: Understanding carbon loss through ecosystem respiration and its partitioning

Understanding the link between ecosystem respiration (Reco) and its influential factors is necessary to evaluate the sources of gaseous carbon loss in coastal wetlands. Seablite (Suaeda salsa Pall.) is the main vegetation type pioneering temperate coastal wetlands in northeast China, and is generally an understudied wetland type. To evaluate the influence of environmental factors on Reco, a multi-year in-situ experiment was carried out during the growing seasons of 2012 to 2014. Total CO2 efflux was measured and separated further into soil microbial and belowground root respiration (Rs + r) and plant respiration (Rplant). Reco displayed strong seasonal variation, with effluxes as high as 845 to 1150 mg CO2 m−2 h−1 during summer months and as low as 32 to 111 mg CO2 m−2 h−1 during spring (when new shoots are sprouting) and fall (when plants are senescing) months. Aboveground plant structures contributed on average 79% to total plant biomass, and accounted for most of the Reco measured; i.e., 62–96% was associated as Rplant. Plant activity was strongly seasonal, accordingly driving Reco, with 1 g of soil-emergent S. salsa biomass (dry weight) producing approximately 1.58 mg CO2 per hour toward Reco during mid-summer. When water level was below the soil surface, Rs + r was exponentially correlated to air temperature. Because Reco for S. salsa marsh in the Liaohe Delta is controlled by plant growth cycles, inundation regime, and air temperature, this finding may be applied for national carbon budget estimation purposes from S. salsa wetlands throughout Northeast China and potentially close a key gap in understanding the role of this large wetland area in contributing to respiratory CO2 emissions globally.

Wetlands↗

Doing the same thing over and over again and getting the same result: Assessing variance in wetland invertebrate assemblages

Past efforts to explain variation of invertebrate assemblages in freshwater wetlands have been less productive than anticipated. To explore why efforts are disappointing, we assembled large invertebrate data sets from North Dakota prairie potholes, California rock pools, and Georgia Carolina bay wetlands that addressed spatial (among wetlands) and temporal (among seasons and years) variation. We anticipated that these large data-set sizes would enable robust conclusions to be drawn, and each place had unique environmental conditions that might contribute to greater explanatory power. We used statistical techniques that partitioned variation in invertebrate assemblages into spatial and/or temporal components, and that also yielded a measure of the amount of unexplained variation; Permutational Multivariate Analysis of Variation and Principal Coordinates Analysis assessed whole assemblage variation, and Analysis of Variance or Analysis of Covariance assessed variation in taxon richness, total abundances, and abundances of wide-spread individual taxa. Across all locations, variation explained by spatial and temporal factors, and unexplained variation were of comparable magnitudes (i.e., similar R 2 values of ~ 50%). Review of other published studies indicate that this pattern is widespread. The 50% or more unexplained variation is typically ignored by researchers, who instead focus on explained fractions. We argue that, besides addressing explained spatial and temporal variation in invertebrate assemblages (e.g., control by hydrology, resources, predation), efforts to understand what contributes to currently unexplained variation, that is unrelated to local spatial or temporal controls (e.g., broad climatic and biogeographic patterns, organism physiology and behavior), will lead to a fuller comprehension of how invertebrates in freshwater wetlands are controlled.

Wetlands↗

Re-evaluating invasive species in degraded ecosystems: A case study of red-eared slider turtles as partial ecological analogs

Exotic species are often vilified as "bad" without consideration of the potential they have for contributing to ecological functions in degraded ecosystems. The red-eared slider turtle (RES) has been disparaged as one of the worst invasive species. Based on this review, we suggest that RES contribute some ecosystem functions in urban wetlands comparable to those provided by the native turtles they sometimes dominate or replace. While we do not advocate for releases outside their native range, or into natural environments, in this review, we examine the case for the RES to be considered potentially beneficial in heavily human-altered and degraded ecosystems where native turtles struggle or fail to persist. After reviewing the ecosystem functions RESs are known to provide, we conclude that in many modified environments the RES is a partial ecological analog to native turtles and removing them may obviate the ecological benefits they provide. We also suggest research avenues to better understand the role of RESs in heavily modified wetlands.

Discover Sustainability↗

Alteration of basalt hyaloclastite at the off-axis Sea Cliff hydrothermal field, Gorda Ridge

The Sea Cliff hydrothermal field on the northern segment of the Gorda Ridge is situated along a rift-bounding normal fault about 2.6 km east of the neovolcanic zone and approximately 300 m above the spreading axis. The structural setting of this hydrothermal field differs from that of most other active seafloor hydrothermal sites investigated to date, which are typically situated in the neovolcanic zone. Mineralization occurs in basaltic talus covering a large normal-fault scarp. Hydrothermal crusts cover much of the seafloor in the area of the active hydrothermal field. These crusts form by extensive alteration of basaltic hyaloclastite in a zone of mixing between ascending hydrothermal fluid and entrained seawater. The initial stage of alteration is magnesian metasomatism of both crystalline basalt and basaltic glass, converting the rock to Mg-rich smectite and smectite/chlorite. Further alteration removes nearly all cations and ultimately leads to silicification. Preservation of basaltic texture in the silicified rocks provides evidence that even such sparingly soluble elements as A1 and Ti have been removed. Oxygen-isotopic ratios of the altered rocks constrain initial alteration to temperatures near 220°C, close to the maximum measured vent temperatures of 247°C. Silicification proceeded to much lower temperatures, and most amorphous silica deposition occurred at temperatures below 100°C. Sulfur-, strontium-, and lead-isotopic data all indicate a predominantly basaltic source, with important contributions from seawater but no significant contribution from sedimentary sources. Comparison with ophiolite-hosted massive sulfide deposits shows that the structural setting, alteration sequence, and depositional environment are all similar and suggests that mineralization and replacement of basaltic breccia in the Sea Cliff hydrothermal field likely occur in the subsurface beneath a capping layer of silicified hyaloclastite.

California, Oregon↗

Isotope geochemistry of recent magmatism in the Aegean arc: Sr, Nd, Hf, and O isotopic ratios in the lavas of Milos and Santorini-geodynamic implications

In this comparative study of variations in the isotopic compositions (Sr, Nd, O and Hf) of the calc-alkaline magmas of the largest two volcanoes, Milos and Santorini, of the Aegean arc (eastern Mediterranean) we demonstrate the complexity of the processes governing the evolution of the magmas on the scale both of the arc and of each volcano. On Santorini, the crustal contamination processes have been limited, effecting the magma gradually during its differentiation. The most differentiated lavas (rhyodacite and pumice) are also the most contaminated. On Milos, by contrast, these processes are very extensive. They are expressed in the 143 Nd/ 144 Nd vs. 87 Sr/ 86 Sr diagram as a continuous mixing curve between a mantle and a crustal end member pole defined by schists and metavolcanic rocks outcropping on these volcanoes. In contrast with Santorini, the least differentiated lavas on Milos are the most contaminated. These isotopic singularities can be correlated with the geodynamic evolution of the Aegean subduction zone, consisting of alternating tectonic phases of distension and compression. The genesis of rhyolitic magmas can be linked to the two phases of distension, and the contamination of the calc-alkaline mantle-derived magmas with the intermediate compressive phase. The isotopic characteristics of uncontaminated calc-alkaline primitive magmas of Milos and Santorini are directly comparable to those of magmas generated in subduction zones for which a contribution of subducted sediments to partial melts from the mantle is suggested, such as in the Aleutian, Sunda, and lesser Antilles island arcs. However, in spite of the importance of the sediment pile in the eastern Mediterranen oceanic crust (6–10 km), the contribution of the subducted terrigenous materials remains of limited amplitude.

Earth and Planetary Science Letters↗

Mechanical and hydraulic properties of rocks related to induced seismicity

Witherspoon, P.A. and Gale, J.E., 1977. Mechanical and hydraulic properties of rocks related to induced seismicity. Eng. Geol., 11(1): 23-55. The mechanical and hydraulic properties of fractured rocks are considered with regard to the role they play in induced seismicity. In many cases, the mechanical properties of fractures determine the stability of a rock mass. The problems of sampling and testing these rock discontinuities and interpreting their non-linear behavior are reviewed. Stick slip has been proposed as the failure mechanism in earthquake events. Because of the complex interactions that are inherent in the mechanical behavior of fractured rocks, there seems to be no simple way to combine the deformation characteristics of several sets of fractures when there are significant perturbations of existing conditions. Thus, the more important fractures must be treated as individual components in the rock mass. In considering the hydraulic properties, it has been customary to treat a fracture as a parallel-plate conduit and a number of mathematical models of fracture systems have adopted this approach. Non-steady flow in fractured systems has usually been based on a two-porosity model, which assumes the primary (intergranular) porosity contributes only to storage and the secondary (fracture) porosity contributes only to the overall conductivity. Using such a model, it has been found that the time required to achieve quasi-steady state flow in a fractured reservoir is one or two orders of magnitude greater than it is in a homogeneous system. In essentially all of this work, the assumption has generally been made that the fractures are rigid. However, it is clear from a review of the mechanical and hydraulic properties that not only are fractures easily deformed but they constitute the main flow paths in many rock masses. This means that one must consider the interaction of mechanical and hydraulic effects. A considerable amount of laboratory and field data is now available that clearly demonstrates this stress-flow behavior. Two approaches have been used in attempting to numerically model such behavior: (1) continuum models, and (2) discrete models. The continuum approach only needs information as to average values of fracture spacing and material properties. But because of the inherent complexity of fractured rock masses and the corresponding decrease in symmetry, it is difficult to develop an equivalent continuum that will simulate the behavior of the entire system. The discrete approach, on the other hand, requires details of the fracture geometry and material properties of both fractures and rock matrix. The difficulty in obtaining such information has been considered a serious limitation of discrete models, but improved borehole techniques can enable one to obtain the necessary data, at least in shallow systems. The possibility of extending these methods to deeper fracture systems needs more investigation. Such data must be considered when deciding whether to use a continuum or discrete model to represent the interaction of rock and fluid forces in a fractured rock system, especially with regard to the problem of induced seismicity. When one is attempting to alter the pressure distribution in a fault zone by injection or withdrawal of fluids, the extent to which this can be achieved will be controlled in large measure by the behavior of the fractures that communicate with the borehole. Since this is essentially a point phenomenon, i.e., the changes will propagate from a relatively small region around the borehole, the use of a discrete model would appear to be preferable.

Engineering Geology↗

Ferromanganese nodules from MANOP Sites H, S, and R-Control of mineralogical and chemical composition by multiple accretionary processes

The chemical composition of ferromanganese nodules from the three nodule-bearing MANOP sites in the Pacific can be accounted for in a qualitative way by variable contributions of distinct accretionary processes. These accretionary modes are: 1. (1) hydrogenous, i.e ., direct precipitation or accumulation of colloidal metal oxides in seawater, 2. (2) oxic diagenesis which refers to a variety of ferromanganese accretion processes occurring in oxic sediments; and 3. (3) suboxic diagenesis which results from reduction of Mn +4 by oxidation of organic matter in the sediments. Geochemical evidence suggests processes (1) and (2) occur at all three MANOP nodule-bearing sites, and process (3) occurs only at the hemipelagic site, H, which underlies the relatively productive waters of the eastern tropical Pacific. A normative model quantitatively accounts for the variability observed in nearly all elements. Zn and Na, however, are not well explained by the three end-member model, and we suggest that an additional accretionary process results in greater variability in the abundances of these elements. Variable contributions from the three accretionary processes result in distinct top-bottom compositional differences at the three sites. Nodule tops from H are enriched in Ni, Cu, and Zn, instead of the more typical enrichments of these elements in nodule bottoms. In addition, elemental correlations typical of most pelagic nodules are reversed at site H. The three accretionary processes result in distinct mineralogies. Hydrogenous precipitation produces δMnO 2 . Oxic diagenesis, however, produces Cu-Ni-rich todorokite, and suboxic diagenesis results in an unstable todorokite which transforms to a 7 Å phase (“birnessite”) upon dehydration. The presence of Cu and Ni as charge-balancing cations influence the stability of the todorokite structure. In the bottoms of H nodules, which accrete dominantly by suboxic diagenesis, Na + and possibly Mn +2 provide much of the charge balance for the todorokite structure. Limited growth rate data for H nodules suggest suboxic accretion is the fastest of the three processes, with rates at least 200 mm/10 6 yr. Oxic accretion is probably 10 times slower and hydrogenous 100 times slower. Since these rates predict more suboxic component in bulk nodules than is calculated by the normative analysis, we propose that suboxic accretion is a non-steady-state process. Variations in surface water productivity cause pulses of particulate flux to the sea floor which result in transient Mn reduction in the surface sediments and reprecipitation on nodule surfaces.

Geochimica et Cosmochimica Acta↗

Stable isotope geochemistry of acid mine drainage: Experimental oxidation of pyrite

Sulfate and water from experiments in which pyrite was oxidized at a pH of 2.0 were analyzed for sulfur and oxygen stable isotopes. Experiments were conducted under both aerobic and anaerobic sterile conditions, as well as under aerobic conditions in the presence of Thiobacillus ferrooxidans, to elucidate the pathways of oxidation. Oxygen isotope fractionation between SO2-4 and H2O varied from +4.0 %. (anaerobic, sterile) to + 18.0 %. (aerobic, with T. ferrooxidans.). The oxygen isotope composition of dissolved oxygen utilized in both chemical and microbially-mediated oxidation was also determined (+11.4 %., by T. ferrooxidans; +18.4 %., chemical). Contributions of water-derived oxygen and dissolved oxygen to the sulfate produced in the oxidation of pyrite could thus be estimated. Water-derived oxygen constituted from 23 to ~ 100 percent of the oxygen in the sulfate produced in the experiments, and this closely approximates the range of contribution in natural acid mine drainage. Oxidation of sulfides in anaerobic, water-saturated environments occurs primarily by chemical oxidation pathways, whereas oxidation of sulfides in well-aerated, unsaturated zone environments occurs dominantly by microbially mediated pathways.

Geochimica et Cosmochimica Acta↗

Variations in the chemical and stable isotope composition of carbon and sulfur species during organic-rich sediment alteration: An experimental and theoretical study of hydrothermal activity at Guaymas Basin, Gulf of California

Organic-rich diatomaceous ooze was reacted with seawater and a Na-Ca-K-Cl fluid of seawater chlorinity at 325–400°C, 400–500 bars, and fluid/sediment mass ratios of 1.56–2.35 to constrain factors regulating the abundance and stable isotope composition of C and S species during hydrothermal alteration of sediment from Guaymas Basin, Gulf of California. Alteration of inorganic and organic sedimentary components resulted in extensive exchange reactions, the release of abundant H 2 S, CO 2 , CH 4 , and C organic , to solution, and recrystallization of the sediment to an assemblage containing albitic plagioclase, quartz, pyrrhotite, and calcite. The δ 34 S cdt "> δ 34 S cdt values of dissolved H 2 S varied from −10.9 to +4.3‰ during seawater-sediment interaction at 325 and 400°C and from −16.5 to −9.0‰ during Na-Ca-K-Cl fluid-sediment interaction at 325 and 375°C. In the absence of seawater SO 4 , H 2 S is derived from both the transformation of pyrite to pyrrhotite and S released during the degradation of organic matter. In the presence of seawater SO 4 , reduction of SO 4 contributes directly to H 2 S production. Sedimentary organic matter acts as the reducing agent during pyrite and SO 4 reduction. Requisite acidity for the reduction of SO 4 is provided by Mg fixation during early-stage sediment alteration and by albite and calcite formation in Mg-free solutions. Organically derived CH 4 was characterized by δ 13 C pdb "> δ13Cpdb values ranging between −20.8 and −23.1‰, whereas δ 13 C pdb "> δ 13 C pdb values for dissolved C organic ranged between −14.8 and −17.7%. Mass balance calculations indicate that δ 13 C values for organically derived CO 2 were ≥ − 14.8%. Residual solid sedimentary organic C showed small (≤ 0.7‰) depletions in 13 C relative to the starting sediment. The experimental results are consistent with the isotopic and chemical composition of natural hydrothermal fluids and minerals at Guaymas Basin and permit us to better constrain sources and sinks for C and S species in subseafloor hydrothermal systems at sediment-covered spreading centers. Our data show that the sulfur isotope composition of hydrothermal Sulfide minerals in Guaymas Basin can be explained by derivation of S from diagenetic sulfide and seawater sulfate. Basaltic S may also contribute to hydrothermal sulfide precipitates but is not required to explain their isotopic composition. Estimates of seawater/ sediment mass ratios based on sulfur isotopic composition of sulfide minerals and the abundance of dissolved NH 3 in vent fluids range from 3–29 during hydrothermal circulation. Sources of C in Guaymas Basin hydrothermal fluids include thermal degradation of organic matter, bacteriogenic methane production, and dissolution of diagenetic carbonate.

Baja California Sur↗

Annual and semiannual variations of the geomagnetic field at equatorial locations

For a year of quiet solar-activity level, geomagnetic records from American hemisphere observatories located between about 0?? and 30?? north geomagnetic latitude were used to compare the annual and semiannual variations of the geomagnetic field associated with three separate contributions: (a) the quiet-day midnight level, MDT; (b) the solar-quiet daily variation, Sq; (c) the quiet-time lunar semidiurnal tidal variation, L(12). Four Fourier spectral constituents (24, 12, 8, 6 h periods) of Sq were individually treated. All three orthogonal elements (H, D and Z) were included in the study. The MDT changes show a dominant semiannual variation having a range of about 7 gammas in H and a dominant annual variation in Z having a range of over 8 gammas. These changes seem to be a seasonal response to the nightside distortions by magnetospheric currents. There is a slow decrease in MDT amplitudes with increasing latitude. The Sq changes follow the patterns expected from an equatorial ionospheric dynamo electrojet current system. The dominant seasonal variations occur in H having a range of over 21 gammas for the 24 h period and over 12 gammas for the 12 h period spectral components. The higher-order components are relatively smaller in size. The Sq(H) amplitudes decrease rapidly with increasing latitude. Magnetospheric contributions to the equatorial Sq must be less than a few per cent of the observed magnitude. The L(12) variation shows the ionospheric electrojet features by the dominance of H and the rapid decrease in amplitude with latitude away from the equator. However, the seasonal variation range of over 7 gammas has a maximum in early February and minimum in late June that is not presently explainable by the known ionospheric conductivity and tidal behavior. ?? 1981.

Journal of Atmospheric and Terrestrial Physics↗

Determination of the components of stormflow using water chemistry and environmental isotopes, Mattole River basin, California

The chemical and isotopic composition of rainfall and stream water was monitored during a storm in the Mattole River basin of northwestern California. About 250 mm of rain fell during 6 days (∼80% within a 42 h period) in late January, 1972, following 24 days of little or no precipitation. River discharge near Petrolia increased from 22 m 3 s −1 to a maximum of 1300 m 3 s −1 while chloride and silica concentrations decreased only from 3.2 to 2.1 and 11.5 to 8.6 mgl −1 , respectively. Meanwhile, the isotopic composition of the river changed from δD = -42%, δ 18 O = -6.8% and 40 tritium units (T.U.) to extreme values at highest flow of δD = -35%, δ 18 O = -5.9% and 25 T.U. in response to volume-weighted rainfall averaging δD = -19.5%, δ 18 O = -3.1% and 18 T.U. Despite much rainfall of a composition quite different from that of the prestorm river water, “buffering” processes in the watershed greatly restricted changes in the chemical and isotopic content of the river during storm runoff. Because of the physical and hydrologic characteristics of the watershed, major contributions of groundwater to stormflow are very unlikely. The large increase in dissolved chemical load observed at maximum river discharge required that extensive interaction with, and presumably penetration of, soils occurred within a few hours time. Such a large increase in chemical load also required subsurface stormflow throughout a high proportion of the watershed. Chemical and isotopic stabilization of stormflow is believed to be due mainly to displacement of prestorm soil water, with some effects on river chemistry due to rapid rain-soil interactions. The isotopic and chemical composition of prestorm soil moisture cannot readily be predicted a priori because of possible variability in rainfall composition, evaporation, and exchange with atmospheric moisture, nor can it be assumed that baseflow has a predictable relation to the chemical or isotopic composition of water displaced from soils during storms. Therefore, it seems inappropriate to draw conclusions as to the relative proportions of groundwater and rainfall in runoff from a particular storm based only on the average compositions of rainfall, stormflow, and prestorm river water, as has been done in most previous isotope hydrograph studies. Given the great variation in hydrology, topography, soil characteristics, rainfall intensity and quantity, etc. from place to place, the relative amount of overland flow, subsurface flow from the unsaturated zone and of groundwater in stormflow can vary greatly in time and space.

California↗

Effect of atrazine on potential denitrification in aquifer sediments

Agriculturaf use of fertilizers and herbicides has often resulted in nitrate and atrazine contamination of the shallow aquifers that underlay cultivated fields. In several cases, the concentrations of atrazine and nitrate dissolved in ground water are positively correlated (Spalding ef al., 1979; Chen and Druliner, 1987; Spalding et al., 1989). Because simultaneous application of nitrate fertilizers and the herbicide, atrazine, is common, the co-occurrence of these contaminants in ground water is not entirely unexpected. However, the possibility also exists that this co-occurrence may ret&t interactions of atrazine with nitrate in the subsurface environment. R&ton and Cervelh (1980), McElhannon ei al. (1984) and Mills (1984) have reported that atrazine inhibits denitrification in‘soil’lf this i‘s indeed the case, atrazine contamination may contribute to nitrate preservation and accumulation in anaerobic aquifers by inhibiting denitrification, the principal mechanism for nitrate removal in anaerobic systems. Huwever, the effect of atrazine on the rate of denit~ficat~on in soils remains controversial, because atrazine has been reported variously to enhance denitrification (Cervelli and Ralston, 1983) or to have no effect on denitrification in soils (Bollag and Henninger, 1976; Yeomans and Bremner, IQ85, 1987). Moreover, the effect of dissolved atrazine concentrations on the rate of denitrification in aquifer sediments has not been reported. Our purpose was to determine the elects of dissolved atrazine concentrations on potential rates ofdenitri~~t~on in aquifer sediments from two different agricultural areas to evaluate the hypothesis that, by inhibiting denitrification, atrazine contributes to nitrate preservation in anaerobic aquifer systems.

Soil Biology and Biochemistry↗

Surface faults in the gulf coastal plain between Victoria and Beaumont, Texas

Displacement of the land surface by faulting is widespread in the Houston-Galveston region, an area which has undergone moderate to severe land subsidence associated with fluid withdrawal (principally water, and to a lesser extent, oil and gas). A causative link between subsidence and fluid extraction has been convincingly reported in the published literature. However, the degree to which fluid withdrawal affects fault movement in the Texas Gulf Coast, and the mechanism(s) by which this occurs are as yet unclear. Faults that offset the ground surface are not confined to the large (>6000-km 2 ) subsidence “bowl” centered on Houston, but rather are common and characteristic features of Gulf Coast geology. Current observations and conclusions concerning surface faults mapped in a 35,000-km 2 area between Victoria and Beaumont, Texas (which area includes the Houston subsidence bowl) may be summarized as follows: (1) Hundreds of faults cutting the Pleistocene and Holocene sediments exposed in the coastal plain have been mapped. Many faults lie well outside the Houston-Galveston region; of these, more than 10% are active, as shown by such features as displaced, fractured, and patched road surfaces, structural failure of buildings astride faults, and deformed railroad tracks. (2) Complex patterns of surface faults are common above salt domes. Both radial patterns (for example, in High Island, Blue Ridge, Clam Lake, and Clinton domes) and crestal grabens (for example, in the South Houston and Friendswood-Webster domes) have been recognized. Elongate grabens connecting several known and suspected salt domes, such as the fault zone connecting Mykawa, Friendswood-Webster, and Clear Lake domes, suggest fault development above rising salt ridges. (3) Surface faults associated with salt domes tend to be short (<5 km in length), numerous, curved in map view, and of diverse trend. Intersecting faults are common. In contrast, surface faults in areas unaffected by salt diapirism are frequently mappable for appreciable distances (>10 km), occur singly or in simple grabens, have gently sinuous traces, and tend to lie roughly parallel to the ENE-NE “coastwise” trend common to regional growth faults identified in subsurface Tertiary sediments. (4) Evidence to support the thesis that surface scarps are the shallow expression of faults extending downward into the Tertiary section is mostly indirect, but nonetheless reasonably convincing. Certainly the patterns of crestal grabens and radiating faults mapped on the surface above salt domes are more than happenstance; analogous fault patterns have been documented around these structures at depth. Similarly, some of the long surface faults not associated with salt domes seem to have subsurface counterparts among known regional growth faults documented through well logs and seismic data. Correlations between surface scarps and faults offsetting subsurface data are not conclusive because of the large vertical distances (1900- 3800 m) involved in making the most of the inferred connections. Nevertheless, the large number of successful correlations - in trend, movement sense, and position - suggests that many surface scarps represent merely the most recent displacements on faults formed during the Tertiary. (5) Upstream-facing fault scarps in this region of low relief can be significant impediments to streams. Locally, both abandoned, mud-filled Pleistocene distributary channels and, more commonly, Holocene drainage lines still occupied by perennial streams reflect the influence of faulting on their development. Some bend sharply near faults and have tended to flow along or pond against the base of scarps; others meander within topographically expressed grabens. Such evidence for Quaternary displacement of the ground surface is widespread in the Texas Gulf coast. In the general, however, streams in areas now offset by faulting show no disruption of their courses where they cross fault scarps. Such scarps are probably very young, and where they can be demonstrated to partly or wholly predate fluid withdrawal, very recent natural fault activity is indicated. (6) Early aerial photographs (1930) of the entire region and topographic maps (1915-16 surveys) of Harris County (Houston and vicinity) show that many faults had already displaced the land surface at a time when appreciable pressure declines in subjacent strata were localized to relatively few areas of large-scale pumping. Prehistoric faulting of the land surface, as noted above, appears to have affected much of the Texas Gulf Coast. (7) A relation between groundwater extraction and current motion on active faults is suspected because of the increased incidence of ground failure in the Houston-Galveston subsidence bowl. This argument is weakened somewhat by recognition of numerous surface faults, some of them active today, far beyond the periphery of the strongly subsiding area. Moreover, tilt beam records from two monitored faults in northwest Houston and accounts of fault damage from local residents demonstrate a complex, episodic nature of fault creep which can only partially be correlated with groundwater production. Nevertheless, although specific mechanisms are in doubt, the extraction of groundwater from shallow (<800-m) sands is probably a major factor in contributing to current displacement of the ground surface in the Houston-Galveston region. Within this large area, the number of faults recognizable from aerial photographs has increased at least tenfold between 1930 and 1970. Elsewhere in the Texas Gulf Coast only a moderate increase has been noted, some of which is possibly attributable to oil and gas production. Surface fault density in the Houston-Galveston region is far greater than in any other area of the Texas Gulf Coast investigated to date. A plausible explanation for these differences is that large overdrafts of groundwater over an extended period of time in the Houston-Galveston region have stimulated fault activity there. Throughout the Texas Gulf Coast, however, a natural contribution to fault motion remains a distinct possibility.

Texas↗

Arsenopyrite in the bank deposits of the Whitewood Creek-Belle Fourche-Cheyenne River-Lake Oahe system, South Dakota, U.S.A.

Mining, milling, and processing wastes containing quantities of arsenopyrite were produced around Lead, South Dokata, from 1875 to 1977. Much of this material was discharged into Whitewood Creek, and from there portions of the waste were transported to the Belle Fourche River, thence to the Cheyenne River, and finally to the Missouri River. In 1958, the Missouri River was dammed at Pierre, forming Lake Oahe. Analyses of cores collected from the lake bottom showed the presence of arsenic-rich layers in the bed sediments; substantial portions of the arsenic are due to arsenopyrite in the 8-16 and 16-32 ??m size fractions of the sediments. In addition, suspended-sediment samples collected from the Cheyenne River above Lake Oahe contain detectable quantities of arsenopyrite in the 8-16 and 16-32 ??m fractions. Solid material collected from the banks and floodplains of the Belle Fourche River and Whitewood Creek contains reduced and oxidized phases. The reduced phases have arsenic maxima in the 16-32 and 32-63 ??m size ranges. These fractions also contribute the most arsenic to the samples; the major source being arsenopyrite. The oxidized segments have arsenic maxima in the < 2 and > 63 ??m size ranges. The < 2 ??m maxima are associated with widely disseminated, arsenic-bearing iron oxide coatings. However, the > 63 ??m fractions contribute the most arsenic to the oxidized samples. This arsenic, despite the oxidized nature of the samples, is associated with arsenopyrite coated with thin iron oxide rinds. It has been calculated that 80% of the arsenic in these deposits is associated with sulfides (in the form of arsenopyrite), while 20% is associated with iron oxides. The arsenopyrite found in the banks and floodplains of Whitewood Creek and the Belle Fourche River are the likely source of the arsenopyrite found in the suspended sediments of the Cheyenne River and in the bed sediment of Lake Oahe.

Conference Paper↗

Response of a 42-storey steel-frame building to the Ms = 7.1 Loma Prieta earthquake

A set of 14 acceleration records was obtained from a 42-storey steel-frame building, the Chevron Building, in San Francisco during the M s = 7.1 "> M s = 7.1 Loma Prieta earthquake of 17 October 1989. Data were analysed using a system identification method based on the discretetime linear filtering, and the least-squares estimation techniques. The results show that the response of the building is dominated by two modes: a translational mode in the weaker (southwest-northeast) principal direction of the building at 0.16 Hz with 5% damping, and a translational-torsional mode along the east-west diagonal of the building's cross-section at 0.20 Hz with 7% damping. There are significant contributions from higher modes at 0.54 Hz, 0.62 Hz, 1.02 Hz and 1.09 Hz. All the modes incorporate some torsion, but the amplitudes of torsional components are small, about 10% of translational amplitudes. Soil-structure interaction influences the vibrations near 1.0 Hz. The contribution of soil-structure interaction to the peak displacements of the building is significant, particularly at lower floors.

California↗