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At least 1,351 records · Page 75Linked to original sources

Geophysical expression of a buried niobium and rare earth element deposit: the Elk Creek carbonatite, Nebraska, USA

The lower Paleozoic Elk Creek carbonatite is a 6–8-km-diameter intrusive complex buried under 200 m of sedimentary rocks in southeastern Nebraska. It hosts the largest known niobium deposit in the U.S. and a rare earth element (REE) deposit. The carbonatite is composed of several lithologies, the relations of which are poorly understood. Niobium mineralization is most enriched within a magnetite beforsite (MB) unit, and REE oxides are most concentrated in a barite beforsite unit. The carbonatite intrudes Proterozoic country rocks. Efforts to explore the carbonatite have used geophysical data and drilling. A high-resolution airborne gravity gradient and magnetic survey was flown over the carbonatite in 2012. The carbonatite is associated with a roughly annular vertical gravity gradient high and a subdued central low and a central magnetic high surrounded by magnetic field values lower than those over the country rocks. Geophysical, borehole, and physical property data are combined for an interpretation of these signatures. The carbonatite is denser than the country rocks, explaining the gravity gradient high. Most carbonatite lithologies have weaker magnetic susceptibilities than those of the country rocks, explaining why the carbonatite does not produce a magnetic high at its margin. The primary source of the central magnetic high is interpreted to be mafic rocks that are strongly magnetized and are present in large volumes. MB is very dense (mean density 3200 kg/m 3 ) and strongly magnetized (median 0.073 magnetic susceptibility), producing a gravity gradient high and contributing to the aeromagnetic high. Barite beforsite has physical properties similar to most of the carbonatite volume, making it a poor geophysical target. Geophysical anomalies indicate the presence of dense and strongly magnetized rocks at depths below existing boreholes, either a large volume of MB or another unknown lithology.

Nebraska↗

Characterization of gas hydrate distribution using conventional 3D seismic data in the Pearl River Mouth Basin, South China Sea

A new 3D seismic reflection data volume acquired in 2012 has allowed for the detailed mapping and characterization of gas hydrate distribution in the Pearl River Mouth Basin in the South China Sea. Previous studies of core and logging data showed that gas hydrate occurrence at high concentrations is controlled by the presence of relatively coarse-grained sediment and the upward migration of thermogenic gas from the deeper sediment section into the overlying gas hydrate stability zone (BGHSZ); however, the spatial distribution of the gas hydrate remains poorly defined. We used a constrained sparse spike inversion technique to generate acoustic-impedance images of the hydrate-bearing sedimentary section from the newly acquired 3D seismic data volume. High-amplitude reflections just above the bottom-simulating reflectors (BSRs) were interpreted to be associated with the accumulation of gas hydrate with elevated saturations. Enhanced seismic reflections below the BSRs were interpreted to indicate the presence of free gas. The base of the BGHSZ was established using the occurrence of BSRs. In areas absent of well-developed BSRs, the BGHSZ was calculated from a model using the inverted P-wave velocity and subsurface temperature data. Seismic attributes were also extracted along the BGHSZ that indicate variations reservoir properties and inferred hydrocarbon accumulations at each site. Gas hydrate saturations estimated from the inversion of acoustic impedance of conventional 3D seismic data, along with well-log-derived rock-physics models were also used to estimate gas hydrate saturations. Our analysis determined that the gas hydrate petroleum system varies significantly across the Pearl River Mouth Basin and that variability in sedimentary properties as a product of depositional processes and the upward migration of gas from deeper thermogenic sources control the distribution of gas hydrates in this basin.

Pearl River Mouth Basin, South China Sea↗

Nonmarine facies in the Late Triassic(?) to Early Jurassic Horn Mountain Tuff member of the Talkeetna Formation, Horn Mountain, lower Cook Inlet basin, Alaska

The Talkeetna Formation is a prominent lithostratigraphic unit in south-central Alaska. In the Iniskin–Tuxedni area, Detterman and Hartsock (1966) divided the formation into three mappable units including, from oldest to youngest, the Marsh Creek Breccia, the Portage Creek Agglomerate, and the Horn Mountain Tuff Members. The Horn Mountain Tuff Member was thought to include rocks deposited in a nonmarine setting based on the presence of “tree stumps in an upright position” (Detterman and Hartsock, 1966, p. 19) near the top of the type section at Horn Mountain. Bull (2015) recognized possible nonmarine volcaniclastic rocks in the member during the 2014 field season in a saddle on the north side of Horn Mountain (figs. 2-1 and 2-2). The authors visited this location in 2015 and measured a short stratigraphic section to document facies, interpret depositional setting, and constrain age. This report summarizes our field observations and presents preliminary interpretations.

Alaska↗

Preliminary stratigraphy and facies analysis of the Upper Cretaceous Kaguyak Formation, including a brief summary of newly discovered oil stain, upper Alaska Peninsula

The Alaska Division of Geological and Geophysical Surveys has an ongoing program aimed at evaluating the Mesozoic forearc stratigraphy, structure, and petroleum systems of lower Cook Inlet. Most of our field studies have focused on the Jurassic component of the petroleum system[this report.] However, in late July and early August of 2012, we initiated a study of the stratigraphy and reservoir potential of the Upper Cretaceous Kaguyak Formation. The Kaguyak Formation is locally well exposed on the upper Alaska Peninsula (fig. 25) and was named by Keller and Reiser (1959) for a sequence of interbedded siltstone and sandstone of upper Campanian to Maastrichtian age that they estimated to be 1,450 m thick.Subsequent work by Detterman and Miller (1985) examined 900 m of section and interpreted the unit as the record of a prograding submarine fan.This interpretation of deep-water deposition contrasts with other Upper Cretaceous rocks exposed along the Alaska Peninsula and lower Cook Inlet that are generally described as nonmarine to shallow marine (Detterman and others, 1996; LePain and others, 2012).Based on foraminifera and palynomorphs from the COST No. 1 well, Magoon (1986) concluded that the Upper Cretaceous rocks were deposited in a variety of water depths and environments ranging from upper bathyal to nonmarine. During our recent fieldwork west and south of Fourpeaked Mountain, we similarly encountered markedly varying lithofacies in the Kaguyak Formation (fig. 25), and we also found oil-stained rocks that are consistent with the existence of an active petroleum system in Upper Cretaceous rocks on the upper Alaska Peninsula and in lower Cook Inlet. These field observations are summarized below.

Alaska↗

Classification of river regimes: A context for hydroecology

Over the past 30 years, ecologists have demostrated the importance of flow and temperature as primary variables in driving running water, riparian and floodplain ecosystems. As it is important to assess the size and timing of discharge variations in relation to those in temperature, a method is proposed that uses multivariate techniques to separately classify annual discharge and temperature regimes according to their 'shape' and 'magnitude', and which then combines the classifications. This paper: (i) describes a generally applicable method; (ii) tests the method by applying it to riparian systems on four British rivers using a 20-year record (1977-97) of flow and air temperature: (iii) proposes a hydroecological interpretation of the classification; (iv) considers the degree to which the methodology might provide information to support the design of ecologically acceptable flow regimes. 'Regimes' are defined for discharge and air temperature using monthly mean data. The results of applying the classification procedure to four British rivers indicates that the 'typical' regimes for each of the four catchments are composite features produced by a small number of clearly defined annual types that reflect interannual variability in hydroclimatological conditions. Annual discharge patterns are dominated by three 'shape' classes (accounting for 94% of the station years: class A, early (November) peak; class B, intermediate (December-January) peak; and class C, late (March) peak) and one 'magnitude' class (70% of the station years fall into class 3, intermediate), with two subordinate 'magnitude' classes: low-flow years (18%) and high flow years (12%). For air temperature, annual patterns are classified evenly into three 'shape' and four 'magnitude' classes. It is argued that this variety of flow-temperature patterns is important for sustaining ecosystem integrity and for establishing benchmark flow regimes and associated frequencies to aid river management. Copyright ?? 2000 John Wiley & Sons, Ltd.Over the past 30 years, ecologists have demonstrated the importance of flow and temperature as primary variables in driving running water, riparian and floodplain ecosystems. As it is important to assess the size and timing of discharge variations in relation to those in temperature, a method is proposed that uses multivariate techniques to separately classify annual discharge and temperature regimes according to their `shape' and `magnitude', and which then combines the classifications. This paper: (i) describes a generally applicable method; (ii) tests the method by applying it to riparian systems on four British rivers using a 20-year record (1977-97) of flow and air temperature; (iii) proposes a hydroecological interpretation of the classification; (iv) considers the degree to which the methodology might provide information to support the design of ecologically acceptable flow regimes. `Regimes' are defined for discharge and air temperature using monthly mean data. The results of applying the classification procedure to four British rivers indicates that the `typical' regimes for each of the four catchments are composite features produced by a small number of clearly defined annual types that reflect interannual variability in hydroclimatological conditions. Annual discharge patterns are dominated by three `shape' classes (accounting for 94% of the station years: class A, early (November) peak; class B, intermediate (December-January) peak; and class C, late (March) peak) and one `magnitude' class (70% of the station years fall into class 3, intermediate), with two subordinate `magnitude' classes: low-flow years (18%) and high flow years (12%). For air temperature, annual patterns are classified evenly into three `shape' and four `magnitude' classes. It is argued that this variety of flow-temperature patterns is important for sustaining ecosystem integrity and for establishing benchmark flow regimes and associated frequencies to aid

Hydrological Processes↗

Species-specific demographic and behavioral responses to food availability during migratory stopover

Understanding the effects of migratory stopover site conditions on both demographic rates and migratory behaviors is critical for interpreting changes in passage population sizes at stopover sites and predicting responses to future changes and conservation actions. We used a Bayesian formulation of the open robust design model to analyze mark-resight observations of three migratory shorebird species using Delaware Bay, USA during spring stopover from 2005 to 2018. We tested for an effect of stopover food availability and weather conditions on survival probability and the probability of returning to this site in the next year and found species differences in these relationships. After years with greater food availability, red knot Calidris canutus rufa had higher survival probability but ruddy turnstone Arenaria interpres were more likely to return to the site. Estimates of within-year probabilities of arrival and persistence at the stopover site showed relatively consistent migration schedules for ruddy turnstone, but more interannual variation for red knot and sanderling Calidris alba . Shorebird use of this site typically peaked during May 26–28, but the estimated proportion of the population present during this period varied dramatically among years for red knot (range: 0.07–0.59) but less so for ruddy turnstone and sanderling. This demonstrates that both the proportion of the flyway population using this stopover site and the proportion present during a given sampling period vary among years, and both should be considered in analyzing and interpreting monitoring data. Stopover conditions can influence both migratory behavior and demographics, underscoring the importance of flyway-wide monitoring.

Delaware, New Jersey↗

Segmentation of plate coupling, fate of subduction fluids, and modes of arc magmatism in Cascadia, inferred from magnetotelluric resistivity

Five magnetotelluric (MT) profiles have been acquired across the Cascadia subduction system and transformed using 2-D and 3-D nonlinear inversion to yield electrical resistivity cross sections to depths of ∼200 km. Distinct changes in plate coupling, subduction fluid evolution, and modes of arc magmatism along the length of Cascadia are clearly expressed in the resistivity structure. Relatively high resistivities under the coasts of northern and southern Cascadia correlate with elevated degrees of inferred plate locking, and suggest fluid- and sediment-deficient conditions. In contrast, the north-central Oregon coastal structure is quite conductive from the plate interface to shallow depths offshore, correlating with poor plate locking and the possible presence of subducted sediments. Low-resistivity fluidized zones develop at slab depths of 35–40 km starting ∼100 km west of the arc on all profiles, and are interpreted to represent prograde metamorphic fluid release from the subducting slab. The fluids rise to forearc Moho levels, and sometimes shallower, as the arc is approached. The zones begin close to clusters of low-frequency earthquakes, suggesting fluid controls on the transition to steady sliding. Under the northern and southern Cascadia arc segments, low upper mantle resistivities are consistent with flux melting above the slab plus possible deep convective backarc upwelling toward the arc. In central Cascadia, extensional deformation is interpreted to segregate upper mantle melts leading to underplating and low resistivities at Moho to lower crustal levels below the arc and nearby backarc. The low- to high-temperature mantle wedge transition lies slightly trenchward of the arc.

Geochemistry, Geophysics, Geosystems↗

Mars Reconnaissance Orbiter and Opportunity observations of the Burns formation: crater hopping at Meridiani Planum

Compact Reconnaissance Imaging Spectrometer for Mars hyperspectral (1.0–2.65 µm) along-track oversampled observations covering Victoria, Santa Maria, Endeavour, and Ada craters were processed to 6 m/pixel and used in combination with Opportunity observations to detect and map hydrated Mg and Ca sulfate minerals in the Burns formation. The strongest spectral absorption features were found to be associated with outcrops that are relatively young and fresh (Ada) or preferentially scoured of dust, soil, and coatings by prevailing winds. At Victoria and Santa Maria, the scoured areas are on the southeastern rims and walls, opposite to the sides where wind-blown sands extend out of the craters. At Endeavour, the deepest absorptions are in Botany Bay, a subdued and buried rim segment that exhibits high thermal inertias, extensive outcrops, and is interpreted to be a region of enhanced wind scour extending up and out of the crater. Ada, Victoria, and Santa Maria outcrops expose the upper portion of the preserved Burns formation and show spectral evidence for the presence of kieserite. In contrast, gypsum is pervasive spectrally in the Botany Bay exposures. Gypsum, a relatively insoluble evaporative mineral, is interpreted to have formed close to the contact with the Noachian crust as rising groundwaters brought brines close to and onto the surface, either as a direct precipitate or during later diagenesis. The presence of kieserite at the top of the section is hypothesized to reflect precipitation from evaporatively concentrated brines or dehydration of polyhydrated sulfates.

Journal of Geophysical Research E: Planets↗

Hydrothermal response to a volcano-tectonic earthquake swarm, Lassen, California

The increasing capability of seismic, geodetic, and hydrothermal observation networks allows recognition of volcanic unrest that could previously have gone undetected, creating an imperative to diagnose and interpret unrest episodes. A November 2014 earthquake swarm near Lassen Volcanic National Park, California, which included the largest earthquake in the area in more than 60 years, was accompanied by a rarely observed outburst of hydrothermal fluids. Although the earthquake swarm likely reflects upward migration of endogenous H 2 O-CO 2 fluids in the source region, there is no evidence that such fluids emerged at the surface. Instead, shaking from the modest sized (moment magnitude 3.85) but proximal earthquake caused near-vent permeability increases that triggered increased outflow of hydrothermal fluids already present and equilibrated in a local hydrothermal aquifer. Long-term, multiparametric monitoring at Lassen and other well-instrumented volcanoes enhances interpretation of unrest and can provide a basis for detailed physical modeling.

California↗

Subsea ice-bearing permafrost on the U.S. Beaufort Margin: 1. Minimum seaward extent defined from multichannel seismic reflection data

Subsea ice-bearing permafrost (IBPF) and associated gas hydrate in the Arctic have been subject to a warming climate and saline intrusion since the last transgression at the end of the Pleistocene. The consequent degradation of IBPF is potentially associated with significant degassing of dissociating gas hydrate deposits. Previous studies interpreted the distribution of subsea permafrost on the U.S. Beaufort continental shelf based on geographically sparse data sets and modeling of expected thermal history. The most cited work projects subsea permafrost to the shelf edge (∼100 m isobath). This study uses a compilation of stacking velocity analyses from ∼100,000 line-km of industry-collected multichannel seismic reflection data acquired over 57,000 km 2 of the U.S. Beaufort shelf to delineate continuous subsea IBPF. Gridded average velocities of the uppermost 750 ms two-way travel time range from 1475 to 3110 m s −1 . The monotonic, cross-shore pattern in velocity distribution suggests that the seaward extent of continuous IBPF is within 37 km of the modern shoreline at water depths < 25 m. These interpretations corroborate recent Beaufort seismic refraction studies and provide the best, margin-scale evidence that continuous subsea IBPF does not currently extend to the northern limits of the continental shelf.

Geochemistry, Geophysics, Geosystems↗

Reconsidering earthquake scaling

The relationship (scaling) between scalar moment, M 0 , and duration, T , potentially provides key constraints on the physics governing fault slip. The prevailing interpretation of M 0 - T observations proposes different scaling for fast (earthquakes) and slow (mostly aseismic) slip populations and thus fundamentally different driving mechanisms. We show that a single model of slip events within bounded slip zones may explain nearly all fast and slow slip M 0 - T observations, and both slip populations have a change in scaling, where the slip area growth changes from 2-D when too small to sense the boundaries to 1-D when large enough to be bounded. We present new fast and slow slip M 0 - T observations that sample the change in scaling in each population, which are consistent with our interpretation. We suggest that a continuous but bimodal distribution of slip modes exists and M 0 - T observations alone may not imply a fundamental difference between fast and slow slip.

Geophysical Research Letters↗

Comment on "Next-Generation Ice Core Technology Reveals True Minimum Natural Levels of lead (Pb) in the atmosphere: Insights from the Black Death" by More et al.

Results and interpretation of the subject article are surprising and conflict with expectations about atmospheric deposition of lead (Pb) Before interpretation of subject article is accepted a body of information about natural deposition of lead (Pb) must be considered This body of information includes knowledge of volcano emissions, chemistry of natural dusts, and isotopes of lead (Pb)

Geohealth News↗

Seismicity and anisotropic imaging reveal an active detachment beneath the northern Alaska Range foothills

North of the Denali Fault, the collision between the Yakutat block with North America is accommodated by a fold-thrust belt giving rise to the northern Alaska Range foothills. At the western end, the Kantishna Hills anticline hosts prominent microseismicity and surface deformation, interpreted as active folding of the Kantishna Hills anticline above a midcrustal detachment. We test for this detachment by using anisotropy-aware receiver functions to image fabric contrasts within the crust in context with seismicity. Seismic stations near the crest of the Kantishna Hills anticline and near its southern flank show a single strong contrast in dipping fabric at depths of 12–13 km near microseismicity clustering depths, consistent with a detachment plane beneath the fold. A minimum b -value at 10–13 km depth is consistent with seismicity on the detachment, compatible with the imaged anisotropic contrast, while off-fault seismicity is shallower and deeper with smaller magnitudes. South-dipping imbricate thrusts in schist characterize the northern Alaska Range foothills structure. This supports our interpretation of the observed anisotropy as reflecting SSW–SSE-dipping foliation above a detachment at ∼10–13 km depth that exploits existing crustal weaknesses along subtle fabric contrasts observed in the seismically quiescent region north of the actively deforming belt.

Alaska↗

Clarifying the trophic state concept to advance macroscale freshwater science and management

For over a century, ecologists have used the concept of trophic state (TS) to characterize an aquatic ecosystem's biological productivity. However, multiple TS classification schemes, each relying on a variety of measurable parameters as proxies for productivity, have emerged to meet use-specific needs. Frequently, chlorophyll a, phosphorus, and Secchi depth are used to classify TS based on autotrophic production, whereas phosphorus, dissolved organic carbon, and true color are used to classify TS based on both autotrophic and heterotrophic production. Both classification approaches aim to characterize an ecosystem's function broadly, but with varying degrees of autotrophic and heterotrophic processes considered in those characterizations. Moreover, differing classification schemes can create inconsistent interpretations of ecosystem integrity. For example, the US Clean Water Act focuses exclusively on algal threats to water quality, framed in terms of eutrophication in response to nutrient loading. This usage lacks information about non-algal threats to water quality, such as dystrophication in response to dissolved organic carbon loading. Consequently, the TS classification schemes used to identify eutrophication and dystrophication may refer to ecosystems similarly (e.g., oligotrophic and eutrophic), yet these categories are derived from different proxies. These inconsistencies in TS classification schemes may be compounded when interdisciplinary projects employ varied TS frameworks. Even with these shortcomings, TS can still be used to distill information on complex aquatic ecosystem function into a set of generalizable expectations. The usefulness of distilling complex information into a TS index is substantial such that usage inconsistencies should be explicitly addressed and resolved. To emphasize the consequences of diverging TS classification schemes, we present three case studies for which an improved understanding of the TS concept advances freshwater research, management efforts, and interdisciplinary collaboration. To increase clarity in TS, the aquatic sciences could benefit from including information about the proxy variables, ecosystem type, as well as the spatiotemporal domains used to classify TS. As the field of aquatic sciences expands and climatic irregularity increases, we highlight the importance of re-evaluating fundamental concepts, such as TS, to ensure their compatibility with evolving science.

Ecosphere↗

Holistic understanding of uncertainty for collaborative and proactive global change decision making

Global change is accelerating and pushing the planet's ecosystems beyond the range of historical observations, creating increasing uncertainty in future system conditions. Despite general agreement that proactive environmental action is warranted, environmental decision conversations often end by identifying additional data needed to reduce uncertainty before taking novel action. Given the inherent uncertainty in complex issues such as global change, quantitative data alone are likely insufficient to support proactive environmental action. Holistic understanding of uncertainty includes scientific quantification of uncertainty paired with emotional responses and transcendental grounding to help people work together toward proactive action in uncertain decision contexts. Holistic understanding arises from the four ways in which humans perceive the world, termed the Four Realms: Physical (e.g., how I observe), Mental (e.g., how I think), Emotional (e.g., how I feel), and Transcendental (e.g., how I connect to greater meaning or purpose). Environmental scientists and decision makers are generally trained in Physical and Mental Realm observation and analysis, but not in how to apply Emotional and Transcendental Realm understanding. Emotional and Transcendental processing occurs in scientists and decision makers whether it is acknowledged or not and contributes to different people interpreting the same information in different ways. Thus, when the role of Emotional and Transcendental Realms in an individual's interpretation process is not understood, it can derail conversations and perpetuate the status quo. Explicitly recognizing all Four Realms can bring people together across differences and inspire shared, novel decision making even in increasing uncertainty. To illustrate the benefits of holistic understanding, we share stories from our experiences in environmental decision contexts. Because accessing the Four Realms requires experiential and embodied techniques, while still relying on core scientific tenets of observation and analysis, we also present techniques for readers to learn to feel their own emotional understanding and connect to their own transcendental understanding. Holistic understanding can enhance data-driven decisions by recognizing that human responses to uncertainty inherently include interactions between emotions, thoughts, transcendental connections, and behavior. Ultimately, holistic understanding can help anchor data-driven decisions in intra- and interpersonal connections, inspiring action in the face of uncertainty.

Ecosphere↗

Environmental DNA dynamics of three species of unionid freshwater mussels

North American freshwater mussels are of special conservation concern due to their high endemism and the multiple anthropogenic stressors affecting them. Of the over 300 species in North America, nearly one third of these species are federally listed as threatened or endangered. Environmental DNA (eDNA) analysis has been successful in detecting freshwater mussels and could aid in monitoring their populations. Production and degradation rates of eDNA for the species of interest are needed to inform interpretation of eDNA detections, allow possible modeling of relative abundance and population location, and aid in mussel conservation through population identification. Here, we designed and tested qPCR assays for three freshwater mussel species, mucket ( Ortmanniana ligamentina ), fatmucket ( Lampsilis siliquoidea ), and the federally endangered spectaclecase ( Cumberlandia monodonta ). We performed laboratory experiments under controlled conditions to measure eDNA shedding and degradation rates for each species. Different biomasses, temperatures, and food regimens were tested independently to determine if these factors influence the amount of DNA produced by the mussels. Degradation rates of eDNA were measured from experimental tank water after mussels were removed. Overall, we observed low eDNA shedding rates for freshwater mussels compared to previous studies of fish eDNA shedding rates. Furthermore, temperature and feeding showed limited or no significant effects in the species studied. Environmental DNA degradation rates were consistent with those reported in the literature for other taxa. Collectively, our results will be useful for designing eDNA monitoring studies, modeling eDNA dispersal, and interpreting eDNA results to help inform freshwater mussel conservation efforts.

Environmental DNA↗

Process convolution approaches for modeling interacting trajectories

Gaussian processes are a fundamental statistical tool used in a wide range of applications. In the spatiotemporal setting, several families of covariance functions exist to accommodate a wide variety of dependence structures arising in different applications. These parametric families can be restrictive and are insufficient in some situations. In contrast, process convolutions represent a flexible, interpretable approach to defining the covariance of a Gaussian process and have modest requirements to ensure validity. We introduce a generalization of the process convolution approach that employs multiple convolutions sequentially to form a “process convolution chain”. In our proposed multistage framework, complex dependencies that arise from a combination of different interacting mechanisms are decomposed into a series of interpretable kernel smoothers. We demonstrate an application of process convolution chains to model killer whale movement, in which the paths taken by multiple individuals are not independent but reflect dynamic social interactions within the population. Our proposed model for dependent movement provides inference for the latent dynamic social structure in the study population. Additionally, by leveraging the positive dependence among individual paths, we achieve a reduction in uncertainty for the estimated locations of the killer whales, compared with a model that treats paths as independent.

Environmetrics↗

Larval aquatic insect responses to cadmium and zinc in experimental streams

To evaluate the risks of metal mixture effects to natural stream communities under ecologically relevant conditions, the authors conducted 30-d tests with benthic macroinvertebrates exposed to cadmium (Cd) and zinc (Zn) in experimental streams. The simultaneous exposures were with Cd and Zn singly and with Cd+Zn mixtures at environmentally relevant ratios. The tests produced concentration–response patterns that for individual taxa were interpreted in the same manner as classic single-species toxicity tests and for community metrics such as taxa richness and mayfly (Ephemeroptera) abundance were interpreted in the same manner as with stream survey data. Effect concentrations from the experimental stream exposures were usually 2 to 3 orders of magnitude lower than those from classic single-species tests. Relative to a response addition model, which assumes that the joint toxicity of the mixtures can be predicted from the product of their responses to individual toxicants, the Cd+Zn mixtures generally showed slightly less than additive toxicity. The authors applied a modeling approach called Tox to explore the mixture toxicity results and to relate the experimental stream results to field data. The approach predicts the accumulation of toxicants (hydrogen, Cd, and Zn) on organisms using a 2-p K a bidentate model that defines interactions between dissolved cations and biological receptors (biotic ligands) and relates that accumulation through a logistic equation to biological response. The Tox modeling was able to predict Cd+Zn mixture responses from the single-metal exposures as well as responses from field data. The similarity of response patterns between the 30-d experimental stream tests and field data supports the environmental relevance of testing aquatic insects in experimental streams.

Environmental Toxicology and Chemistry↗