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At least 127 records · Page 7Linked to original sources

Preliminary evaluation of effects of best management practices in the Black Earth Creek, Wisconsin, priority watershed

Nonpoint-source contamination accounts for a substantial part of the water quality problems in many watersheds. The Wisconsin Nonpoint Source Water Pollution Abatement Program provides matching money for voluntary implementation of various best management practices (BMPs). The effectiveness of BMPs on a drainage-basin scale has not been adequately assessed in Wisconsin by use of data collected before and after BMP implementation. The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources, monitored water quality in the Black Earth Creek watershed in southern Wisconsin from October 1984 through September 1986 (pre-BMP conditions). BMP implementation began during the summer of 1989 and is planned to continue through 1993. Data collection resumed in fall 1989 and is intended to provide information during the transitional period of BMP implementation (1990-93) and 2 years of post-BMP conditions (1994-95). Preliminary results presented for two subbasins in toe Black Earth Creek watershed (Brewery and Garfoot Creeks) are based on data collected during pre-BMP conditions and the first 3 years of the transitional period. The analysis includes the use of regressions to control for natural variability in the data and, hence, enhance the ability to detect changes. Data collected to date (1992) indicate statistically significant differences in storm mass transport of suspended sediment and ammonia nitrogen at Brewery Creek. The central tendency of the regression residuals has decreased with the implementation of BMPs; hence, the improvement in water quality in the Brewery Creek watershed is likely a result of BMP implementation. Differences in storm mass transport at Garfoot Creek were not detected, primarily because of an insufficient number of storms in the transitional period. As practice implementation continues, the additional data will be used to determine the level of management which results in significant improvements in water quality in the two watersheds. Future research will address techniques for including snowmelt runoff and early spring storms.Nonpoint-source contamination accounts for a substantial part of the water quality problems in many watersheds. The Wisconsin Nonpoint Source Water Pollution Abatement Program provides matching money for voluntary implementation of various best management practices (BMPs). The effectiveness of BMP s on a drainage-basin scale has not been adequately assessed in Wisconsin by use of data collected before and after BMP implementation. The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources, monitored water quality in the Black Earth Creek watershed in southern Wisconsin from October 1984 through September 1986 (pre-BMP conditions). BMP implementation began during the summer of 1989 and is planned to continue through 1993. Data collection resumed in fall 1989 and is intended to provide information during the transitional period of BMP implementation (1990-93) and 2 years of post-BMP conditions (1994-95). Preliminary results presented for two subbasins in the Black Earth Creek watershed (Brewery and Garfoot Creeks) are based on data collected during pre-BMP conditions and the first 3 years of the transitional period. The analysis includes the use of regressions to control for natural variability in the data and, hence, enhance the ability to detect changes. Data collected to date (1992) indicate statistically significant differences in storm mass transport of suspended sediment and ammonia nitrogen at Brewery Creek. The central tendency of the regression residuals has decreased with the implementation of BMPs; hence, the improvement in water quality in the Brewery Creek watershed is likely a result of BMP implementation. Differences in storm mass transport at Garfoot Creek were not detected, primarily because of an insufficient number of storms in the transitional period. As practice implementation continues, the addit

Conference Paper

Incorporation of rare earth elements in titanite: Stabilization of the A2/a dimorph by creation of antiphase boundaries

The atomic arrangement of a natural rare-earth-rich titanite and two synthetic rare-earth-doped titanites have been refined in space group A2/a, and the atomic arrangement of an undoped P21/a synthetic titanite was also refined for comparison. Previous work has shown that titanite possesses a domain structure, with domains formed of like-displaced Ti atoms in the [100] octahedral chains. P21/a titanite results when the crystal is formed of a single domain, but as Ti-reversal sites occur in the octahedral chain the apparent A2/a structure results from the average of antiphase domains. Antiphase boundaries occur at O1, which is alternately overbonded or underbonded at the boundaries, depending on the displacement of the neighboring Ti atoms. Type 2 antiphase boundaries exist where two Ti atoms are displaced away from the intervening O1 atom and are energetically unfavorable because of underbonding of that O1 atom. However, substitution of a trivalent rare earth element in the adjacent Ca2+ site relieves that underbonding, favoring the creation of type 2 antiphase boundaries and stabilization of the A2/a dimorph. The results of high-precision crystal structure analyses demonstrate that rare earth substituents for Ca stabilize the A2/a dimorph at lower substitution levels than required for octahedral substitutions.

American Mineralogist

Mineral resource of the month: rare earths

As if classified as a top-secret project, the rare earths have been shrouded in secrecy. The principal ore mineral of the group, bastnäsite, rarely appears in the leading mineralogy texts. The long names of the rare-earth elements and some unusual arrangements of letters, many Scandinavian in origin, may have intimidated even those skilled in phonics. Somewhat obscurely labeled, the rare earths are neither rare nor earths (the historical term for oxides). They are a relatively abundant group of metallic elements that occur in nature as nonmetallic compounds and have hundreds of commercial applications.

Geotimes

Availability of Earth observations data from the U.S. Geological Survey's EROS data center

For decades federal and state agencies have been collecting regional, continental, and global Earth observations data acquired by satellites, aircraft, and other information-gathering systems. These data include photographic and digital remotely sensed images of the Earth's surface, as well as earth science, cartographic, and geographic data. Since 1973, the U.S. Geological Survey's Earth Resources Observation Systems (EROS) Data Center (EDC) in Sioux Falls, South Dakota, has been a data management, production, dissemination, and research center for these data. Currently, the Data Center holds over 10 million satellite images and aerial photographs, in photographic and digital formats. Users are able to place inquiries and orders for these holdings via a nationwide computer network. In addition to cataloging the data stored in its archives, the Data Center provides users with rapid access to information on many data collections held by other facilities.

Pecora 12 Symposium

Foreign literature and translations in earth science

More than 50 percent of the total abstracted geologic literature is in Russian, followed by English at about 30 percent, and French, German, and Japanese from about 8 to 2 percent. Communist Chinese publications ceased as a result of the Cultural Revolution and have not resumed. Less than 2 percent of American earth scientists read and use Russian literature in the original to any significant extent. About 30 percent know some French, German, and Spanish, but only a much smaller proportion uses these languages in practice. The most important sources of knowledge about foreign work are translation journals, almost exclusively from Russian, and foreign scientists who write in American and international journals. Less than 0.5 percent of Russian earth science books are translated or known in the United States. Scientific provincialism is strong and increasing in the United States, owing to or demonstrated by the publications explosion and squeeze on libraries and scientists, weakening or abandonment of language requirements in universities, and cessation of all broad earth science abstracting services in English. Suggestions for improving communication of foreign literature include earlier exposure to languages in schools and stress on critical use rather than perfunctory examinations. A "critical mass" of linguistically competent and active scientists is necessary to find the important, not merely important-sounding, titles in the literature morass and introduce them into widely read earth science media.

Conference Paper

California community Earth Models for Seismic Hazard Assessments workshop report

The California Community Earth Models for Seismic Hazard Assessments Workshop (https://www.scec.org/workshops/2024/california-community-models) was held online March 4–5, 2024, with more than 200 participants over the two days. In this report, we provide a summary of the key points from the presentations and discussions. We highlight three use cases that drive the development of community Earth models, present an inventory of existing community Earth models in California, summarize a few techniques for integrating and merging models, discuss potential connections with the Cascadia Region Earthquake Science Center, and discuss what “community” means in community Earth models.

California

Triggering and modulation of geyser eruptions in Yellowstone National Park by earthquakes, earth tides, and weather

We analyze intervals between eruptions (IBEs) data acquired between 2001 and 2011 at Daisy and Old Faithful geysers in Yellowstone National Park. We focus our statistical analysis on the response of these geysers to stress perturbations from within the solid earth (earthquakes and earth tides) and from weather (air pressure and temperature, precipitation, and wind). We conclude that (1) the IBEs of these geysers are insensitive to periodic stresses induced by solid earth tides and barometric pressure variations; (2) Daisy (pool geyser) IBEs lengthen by evaporation and heat loss in response to large wind storms and cold air; and (3) Old Faithful (cone geyser) IBEs are not modulated by air temperature and pressure variations, wind, and precipitation, suggesting that the subsurface water column is decoupled from the atmosphere. Dynamic stress changes of 0.1−0.2 MPa resulting from the 2002 M-7.9 Denali, Alaska, earthquake surface waves caused a statistically significant shortening of Daisy geyser's IBEs. Stresses induced by other large global earthquakes during the study period were at least an order of magnitude smaller. In contrast, dynamic stresses of >0.5 MPa from three large regional earthquakes in 1959, 1975, and 1983 caused lengthening of Old Faithful's IBEs. We infer that most subannual geyser IBE variability is dominated by internal processes and interaction with other geysers. The results of this study provide quantitative bounds on the sensitivity of hydrothermal systems to external stress perturbations and have implications for studying the triggering and modulation of volcanic eruptions by external forces.

Wyoming

On developing thermal cave detection techniques for earth, the moon and mars

The purpose of this study is to (1) demonstrate the viability of detecting terrestrial caves at thermal-infrared wavelengths, (2) improve our understanding of terrestrial cave thermal behavior, (3) identify times of day when cave openings have the maximum thermal contrast with the surrounding surface regolith, and (4) further our understanding of how to detect caves on Earth, the Moon and Mars. We monitored the thermal behavior of two caves in the Atacama Desert of northern Chile. Through this work, we identified times when temperature contrasts between entrance and surface were greatest, thus enabling us to suggest optimal overflight times. The largest thermal contrast for both caves occurred during mid-day. One cave demonstrated thermal behavior at the entrance suggestive of cold-trapping, while the second cave demonstrated temperature shifts suggestive of airflow. We also collected thermograms without knowing optimal detection times; these images suggest both caves may also be detectable during off-peak times. We suggest cave detection using thermal remote sensing on Earth and other planetary objects will be limited by (1) capturing imagery in the appropriate thermal wavelength, (2) the size of cave entrance vs. the sensor's spatial resolution, (3) the viewing angle of the platform in relation to the slope trajectory of the cave entrance, (4) the strength of the thermal signal associated with the cave entrance, and (5) the time of day and season of thermal image capture. Through this and other studies, we will begin to identify the range of conditions under which caves are detectable in the thermal infrared and thus improve our detection capabilities of these features on Earth, the Moon and Mars.

Earth and Planetary Science Letters

Down to Earth with nuclear electromagnetic pulse: Realistic surface impedance affects mapping of the E3 geoelectric hazard

An analysis is made of Earth-surface geoelectric fields and voltages on electricity transmission power-grids induced by a late-phase E3 nuclear electromagnetic pulse (EMP). A hypothetical scenario is considered of an explosion of several hundred kilotons set several hundred kilometers above the eastern-midcontinental United States. Ground-level E3 geoelectric fields are estimated by convolving a standard parameterization of E3 geomagnetic field variation with magnetotelluric Earth-surface impedance tensors derived from wideband measurements acquired across the study region during a recent survey. These impedance tensors are a function of subsurface three-dimensional electrical conductivity structure. Results, presented as a movie-map, demonstrate that localized differences in surface impedance strongly distort the amplitude, polarization, and variational phase of induced E3 geoelectric fields. Locations with a high degree of E3 geoelectric polarization tend to have high geoelectric amplitude. Uniform half-space models and one-dimensional, depth-dependent models of Earth-surface impedance, such as those widely used in government and industry reports informing power-grid vulnerability assessment projects, do not provide accurate estimates of the E3 geoelectric hazard in complex geological settings. In particular, for the Eastern-Midcontinent, half-space models can lead to (order-one) overestimates/underestimates of EMP-induced geovoltages on parts of the power grid by as much as 1,000 volts (a range of 2,000 volts)—comparable to the amplitudes of the geovoltages themselves.

Earth and Space Sciences

Harnessing big data to rethink land heterogeneity in Earth system models

The continual growth in the availability, detail, and wealth of environmental data provides an invaluable asset to improve the characterization of land heterogeneity in Earth system models – a persistent challenge in macroscale models. However, due to the nature of these data (volume and complexity) and computational constraints, these data are underused for global applications. As a proof of concept, this study explores how to effectively and efficiently harness these data in Earth system models over a 1/4° ( ∼ 25 km) grid cell in the western foothills of the Sierra Nevada in central California. First, a novel hierarchical multivariate clustering approach (HMC) is introduced that summarizes the high-dimensional environmental data space into hydrologically interconnected representative clusters (i.e., tiles). These tiles and their associated properties are then used to parameterize the sub-grid heterogeneity of the Geophysical Fluid Dynamics Laboratory (GFDL) LM4-HB land model. To assess how this clustering approach impacts the simulated water, energy, and carbon cycles, model experiments are run using a series of different tile configurations assembled using HMC. The results over the test domain show that (1) the observed similarity over the landscape makes it possible to converge on the macroscale response of the fully distributed model with around 300 sub-grid land model tiles; (2) assembling the sub-grid tile configuration from available environmental data can have a large impact on the macroscale states and fluxes of the water, energy, and carbon cycles; for example, the defined subsurface connections between the tiles lead to a dampening of macroscale extremes; (3) connecting the fine-scale grid to the model tiles via HMC enables circumvention of the classic scale discrepancies between the macroscale and field-scale estimates; this has potentially significant implications for the evaluation and application of Earth system models.

Hydrology and Earth System Sciences

Volcanogenic Sulfur on Earth and Io: Composition and Spectroscopy

The causes of Io's variegated surface, especially the roles of sulfur, and the geochemical history of sulfur compounds on Io are not well understood. Suspecting that minor impurities in sulfur might be important, we have investigated the major and trace element chemistry and spectroscopic reflectance of natural sulfur from a variety of terrestrial volcanic-hydrothermal environments. Evidence suggests that Io may be substantially coated with impure sulfur. On Earth, a few tenths of a percent to a few percent of chalcophile trace elements (e.g., As and Se) comonly occur in sulfur and appear to stabilize material of yellow, brown, orange, and red hues, which may persist even at low temperatures. Percentage levels of chalcophile impurities are reasonably expected to occur on Io in vapor sublimate deposits and flows derived from such deposits. Such impurities join a host of other mechanisms that might explain Io's reds and yellows. Two-tenths to two percent opaque crystalline impurities, particularly pyrite (FeS2), commonly produces green, gray, and black volcanic sulfur on Earth and might explain areas of Io having deposits of these colors. Pyrite produces a broad absorption near 1 ??m that gradually diminishes out to 1.6 ??m - similar but not identical to the spectrum of Io seen in Galileo NIMS data. Percentage amounts of carbonaceous impurities and tens of percent SiO2 (as silicates) also strongly affect the spectral properties of Earth's sulfur. Io's broad absorption between 0.52 and 0.64 ??m remains unexplained by these data but could be due to sodium sulfides, as suggested previously by others, or to As, Se, or other impurities. These impurities and others, such as P and Cl (which could exist on Io's surface in amounts over 1% that of sulfur), greatly alter the molecular structure of molten and solid sulfur. Minor impurities could impact Io's geology, such as the morphology of sulfur lava flows and the ability of sulfur to sustain high relief. We have not found any natural sulfur containing significant Na beyond that attributable to silicate inclusions. In sum, the unique physical-chemical properties of S-rich systems and the strong affinity of certain elements for S may have broad implications for the appearance, spectroscopic interpretation, and geologic processes of Io. Identification of impurities in sulfur may be helpful in tracing the geochemical evolution of surface deposits on Io. Perhaps foretelling of new areas of investigation, Cl has recently been reported in the Io torus (M. Kueppers and N. M. Schneider 1999, Eos Trans.80, 5207), suggesting the presence on Io of either salts, such as halite, or sulfur chlorides. Further evidence of minor iogenic impurities should be sought in Io's neutral cloud and plasma torus as well as in further scrutiny of Io's reflectance spectra. ?? 1999 Academic Press.

Icarus

The concept of evanescent microbial ecosystems in Earth's atmosphere

This essay presents the hypothesis that short-lived or evanescent microbial ecosystems exist in Earth’s lower troposphere (~ < 4 km). This hypothesis is supported by culture- and molecular-based studies that have shown diverse, viable, and metabolically active microbial communities within Earth’s atmospheric boundary layer. Surprisingly, microorganisms are routinely recovered in samples collected at extreme altitudes including those within the stratosphere (> 18 km). Volcanic eruptions, dust storms, fires, and sea spray are known to seed the atmosphere with microorganisms and to serve as potential nutrient sources while in the atmosphere and upon deposition. Recent research has demonstrated that microorganisms are metabolically active in clouds; for example, archaea capable of utilizing gases such as methane and hydrogen-nitrogen have been identified in clouds and in the atmosphere over natural and anthropogenic gas seeps. The only difference between this hypothesized ecosystem to more traditionally defined ecosystems is its evanescent characteristics where clouds or gas plumes eventually dissipate as they reside over and traverse Earth’s terrestrial and/or aquatic environments. The life cycle of these hypothesized evanescent airborne ecosystems would be short-lived relative to the classically defined biomes or ecosystems.

Book chapter

Structural evolution of iron coordination in proteins across Earth’s oxygenation history

Protein metal-binding sites support essential biological functions shaped by protein fold, subunit interactions, and cofactor chemistry. Because these sites encode both biochemical function and environmental constraint, they offer a route to connect protein evolution with changes in Earth’s surface environment through time. Of particular interest is iron (Fe), the most widely used metal in biology and a cofactor central to both anaerobic and aerobic metabolism. Here, we systematically compare the immediate chemical environments of functionally essential Fe-binding sites in three-dimensional protein structures to test whether Fe coordination spheres differ across oxygen contexts. Using a curated dataset of experimentally determined structures, we identify a clear shift in the local chemistry of Fe-binding environments from anaerobic to aerobic proteins. Aerobic Fe sites are significantly more hydrophilic than anaerobic ones, and amino-acid composition analyses show reduced cysteine use in aerobic Fe-binding neighborhoods. These patterns suggest that as Earth’s surface environments became more oxygenated, proteins retained Fe as a core redox metal while reconfiguring local coordination chemistry in ways less vulnerable to oxidative damage. More broadly, this study introduces and applies the Coordination Sphere Analysis and Comparison (CSAC) workflow, an open and archived Python workflow for extracting local metal-binding environments from structure datasets, providing a framework for linking metalloprotein structure to evolutionary and geobiological transitions across Earth history.

Discover Life

A chemical-spectrochemical method for the determination of rare earth elements and thorium in cerium minerals

In a combined chemical-spectrochemical procedure for quantitatively determining rare earth elements in cerium minerals, cerium is determined volumetrically, a total rare earths plus thoria precipitate is separated chemically, the ceria content of the precipitate is raised to 80·0 percent by adding pure ceria, and the resulting mixture is analyzed for lanthanum, praseodymium, neodymium, samarium, gadolinium, yttrium, and thorium spectrochemically by means of the d.c. carbon arc. Spectral lines of singly ionized cerium are used as internal standard lines in the spectrochemical determination which is patterned after Fassel's procedure [1]. Results of testing the method with synthetic mixtures of rare earths and with samples of chemically analyzed cerium minerals show that the coefficient of variation for a quadruplicate determination of any element does not exceed 5·0 (excepting yttrium at concentrations less than 1 percent) and that the method is free of serious systematic error.

Spectrochimica Acta

Trace and rare earth elements determination in milk whey from the Veneto region, Italy

Multi-element analyses determine the content of 17 trace elements (Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Cd, Cs, Ba, Pb, U) and 14 rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu, Y) in whey samples from cow and goat milk by inductively coupled plasma mass spectrometry and inductively coupled plasma-sector field mass spectrometry. A total of 261 milk whey samples were collected from four locations in the Veneto region of northeastern (NE) Italy. These samples contain a wide range concentration of 17 trace elements (0.06–1530 μg kg −1 ) and 14 rare earth elements (0.16–28.2 ng kg −1 ) in whey samples, but do not reach toxic concentrations. Elemental fingerprinting of trace and rare earth elements in cow and goat milk whey provide information on the dairy quality and, as they reflect the local environmental conditions, result in an excellent indicator of their geographical origin.

Veneto region

Historical background and current developments for mapping burned area from satellite Earth observation

Fire has a diverse range of impacts on Earth's physical and social systems. Accurate and up to date information on areas affected by fire is critical to better understand drivers of fire activity, as well as its relevance for biogeochemical cycles , climate, air quality, and to aid fire management. Mapping burned areas was traditionally done from field sketches. With the launch of the first Earth observation satellites, remote sensing quickly became a more practical alternative to detect burned areas, as they provide timely regional and global coverage of fire occurrence. This review paper explores the physical basis to detect burned area from satellite observations, describes the historical trends of using satellite sensors to monitor burned areas, summarizes the most recent approaches to map burned areas and evaluates the existing burned area products (both at global and regional scales). Finally, it identifies potential future opportunities to further improve burned area detection from Earth observation satellites.

Remote Sensing of Environment

Planning for the Global Earth Observation System of Systems (GEOSS)

The Group on Earth Observations was established to promote comprehensive, coordinated, and sustained Earth observations. Its mandate is to implement the Global Earth Observation System of Systems (GEOSS) in accord with the GEOSS 10-Year Implementation Plan and Reference Document. During the months over which the GEOSS Implementation Plan was developed, many issues surfaced and were addressed. This article discusses several of the more interesting or challenging of those issues-e.g. fitting in with existing organizations and securing stable funding - some of which have yet to be resolved fully as of this writing. Despite the relatively short period over which the Implementation Plan had to be developed, there is a good chance that the work undertaken will be influential for decades to come. ?? 2005 Elsevier Ltd. All rights reserved.

Space Policy

Integrating Earth–life systems: A geogenomic approach

For centuries, scientists have recognized and worked to understand how Earth’s mutable landscape and climate shape the distribution and evolution of species. Here, we describe the emerging field of geogenomics, which uses the reciprocal and deep integration of geologic, climatic, and population genomic data to define and test cause–effect relationships between Earth and life at intermediate spatial and temporal scales (i.e., the mesoscale). Technological advances now power the detailed reconstruction of landscape and evolutionary histories, but transdisciplinary collaborations and new quantitative tools are needed to better integrate Earth–life data. Geogenomics can help build a more unified theory and characterize the boundary conditions under which geologic and climatic processes generate new biodiversity, how species’ responses differ, and why.

Trends in Ecology & Evolution