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At least 1,243 records · Page 69Linked to original sources

USGS2016

Isotope hydrology of the Chalk River Laboratories site, Ontario, Canada

This paper presents results of hydrochemical and isotopic analyses of groundwater (fracture water) and porewater, and physical property and water content measurements of bedrock core at the Chalk River Laboratories (CRL) site in Ontario. Density and water contents were determined and water-loss porosity values were calculated for core samples. Average and standard deviations of density and water-loss porosity of 50 core samples from four boreholes are 2.73 ± 12 g/cc and 1.32 ± 1.24 percent. Respective median values are 2.68 and 0.83 indicating a positive skewness in the distributions. Groundwater samples from four deep boreholes were analyzed for strontium (87Sr/86Sr) and uranium (234U/238U) isotope ratios. Oxygen and hydrogen isotope analyses and selected solute concentrations determined by CRL are included for comparison. Groundwater from borehole CRG-1 in a zone between approximately +60 and −240 m elevation is relatively depleted in δ18O and δ2H perhaps reflecting a slug of water recharged during colder climatic conditions. Porewater was extracted from core samples by centrifugation and analyzed for major dissolved ions and for strontium and uranium isotopes. On average, the extracted water contains 15 times larger concentration of solutes than the groundwater. 234U/238U and correlation of 87Sr/86Sr with Rb/Sr values indicate that the porewater may be substantially older than the groundwater. Results of this study show that the Precambrian gneisses at Chalk River are similar in physical properties and hydrochemical aspects to crystalline rocks being considered for the construction of nuclear waste repositories in other regions.

Applied Geochemistry↗

USGS2023

High-precision ID-TIMS U-Pb geochronology of perovskite (CaTiO3) from the Ice River Complex, southeastern British Columbia

Uranium‑lead perovskite in situ geochronology has become a cornerstone technique for determining the emplacement timing of alkaline, ultrapotassic, and silica-undersaturated igneous rocks, kimberlites, and carbonatites. Accurate in situ dates are dependent on the availability of matrix matched mineral reference materials which themselves are chemically well characterized and dated accurately to the highest possible precision. When dating perovskite to high precision, such as by isotope dilution thermal ionization mass spectrometry (ID-TIMS), appropriately accounting and correcting for the quantity and isotopic composition of Pb incorporated into the crystal upon crystallization (Pb i ) is a large source of uncertainty and potential inaccuracy. Unfortunately, although ultra-high precision perovskite dates are attainable with modern mass spectrometry techniques, the accuracy of applied Pb i compositions, which can be a considerable percentage of total Pb in a crystal, has not kept pace, resulting in percent level inaccuracy on precisely measured isotopic ratios. In an effort to characterize the age and initial Pb isotopic composition of a readily available, relatively pure perovskite endmember (93–98%) which will be useful as a matrix matched age reference material for in situ U-Pb geochronology, we date crystals isolated from three samples from the Ice River Complex (samples 81IR6, I90.3, and I92.30) by ID-TIMS and evaluate their suitability as known-age reference materials. We directly determine the isotopic composition of Pb i in each sample by ID-TIMS measurement of cogenetic low 238 U/ 204 Pb (μ < 500) phlogopite, apatite, and/or clinopyroxene. Using these initial common Pb isotopic compositions, which are significantly more radiogenic than those predicted by age appropriate Pb evolution models, we obtain ultra-precise weighted-mean 206 Pb/ 238 U perovskite dates of 355.83 ± 0.14, 355.04 ± 0.15, and 357.34 ± 0.12 Ma on the three Ice River samples, respectively. These dates are consistent with the relative emplacement ages previously established for units in the Ice River layered ultramafic series based on field relationships. They also demonstrate the feasibility of attaining accurate perovskite dates in instances when maximum precision is critical by utilizing ID-TIMS analysis of cogenetic low uranium phases for direct measurement of Pb i .

British Columbia↗

USGS2025

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana↗

USGS2013

Ion-probe U–Pb dating of authigenic and detrital opal from Neogene-Quaternary alluvium

Knowing depositional ages of alluvial fans is essential for many tectonic, paleoclimatic, and geomorphic studies in arid environments. The use of U–Pb dating on secondary silica to establish the age of Neogene-Quaternary clastic sediments was tested on samples of authigenic and detrital opal and chalcedony from depths of ∼25 to 53 m in boreholes at Midway Valley, Nevada. Dating of authigenic opal present as rinds on rock clasts and in calcite/silica cements establishes minimum ages of alluvium deposition; dating of detrital opal or chalcedony derived from the source volcanic rocks gives the maximum age of sediment deposition. Materials analyzed included 12 samples of authigenic opal, one sample of fracture-coating opal from bedrock, one sample of detrital opal, and two samples of detrital chalcedony. Uranium–lead isotope data were obtained by both thermal ionization mass spectrometry and ion-microprobe. Uranium concentrations ranged from tens to hundreds of μg/g. Relatively large U/Pb allowed calculation of 206 Pb/ 238 U ages that ranged from 1.64±0.36 (2 σ ) to 6.16±0.50 Ma for authigenic opal and from 8.34±0.28 to 11.2±1.3 Ma for detrital opal/chalcedony. Three samples with the most radiogenic Pb isotope compositions also allowed calculation of 207 Pb/ 235 U ages, which were concordant with 206 Pb/ 238 U ages from the same samples. These results indicate that basin development at Midway Valley was initiated between about 8 and 6 Ma, and that the basin was filled at long-term average deposition rates of less than 1 cm/ka. Because alluvium in Midway Valley was derived from adjacent highlands at Yucca Mountain, the low rates of deposition determined in this study may imply a slow rate of erosion of Yucca Mountain. Volcanic strata underlying the basin are offset by a number of buried faults to a greater degree than the relatively smooth-sloping bedrock/alluvium contact. These geologic relations indicate that movement on most faults ceased prior to erosional planation and burial. Therefore, ages of the authigenic opal from basal alluvium indicate that the last movement on buried faults was older than about 6 Ma.

Earth and Planetary Science Letters↗

USGS2016

Quantifying chemical weathering rates along a precipitation gradient on Basse-Terre Island, French Guadeloupe: new insight from U-series isotopes in weathering rinds

Inside soil and saprolite, rock fragments can form weathering clasts (alteration rinds surrounding an unweathered core) and these weathering rinds provide an excellent field system for investigating the initiation of weathering and long term weathering rates. Recently, uranium-series (U-series) disequilibria have shown great potential for determining rind formation rates and quantifying factors controlling weathering advance rates in weathering rinds. To further investigate whether the U-series isotope technique can document differences in long term weathering rates as a function of precipitation, we conducted a new weathering rind study on tropical volcanic Basse-Terre Island in the Lesser Antilles Archipelago. In this study, for the first time we characterized weathering reactions and quantified weathering advance rates in multiple weathering rinds across a steep precipitation gradient. Electron microprobe (EMP) point measurements, bulk major element contents, and U-series isotope compositions were determined in two weathering clasts from the Deshaies watershed with mean annual precipitation (MAP) = 1800 mm and temperature (MAT) = 23 °C. On these clasts, five core-rind transects were measured for locations with different curvature (high, medium, and low) of the rind-core boundary. Results reveal that during rind formation the fraction of elemental loss decreases in the order: Ca ≈ Na > K ≈ Mg > Si ≈ Al > Zr ≈ Ti ≈ Fe. Such observations are consistent with the sequence of reactions after the initiation of weathering: specifically, glass matrix and primary minerals (plagioclase, pyroxene) weather to produce Fe oxyhydroxides, gibbsite and minor kaolinite. Uranium shows addition profiles in the rind due to the infiltration of U-containing soil pore water into the rind as dissolved U phases. U is then incorporated into the rind as Fe-Al oxides precipitate. Such processes lead to significant U-series isotope disequilibria in the rinds. This is the first time that multiple weathering clasts from the same watershed were analyzed for U-series isotope disequlibrian and show consistent results. The U-series disequilibria allowed for the determination of rind formation ages and weathering advance rates with a U-series mass balance model. The weathering advance rates generally decreased with decreasing curvature: ∼0.17 ± 0.10 mm/kyr for high curvature, ∼0.12 ± 0.05 mm/kyr for medium curvature, and ∼0.11 ± 0.04, 0.08 ± 0.03, 0.06 ± 0.03 mm/kyr for low curvature locations. The observed positive correlation between the curvature and the weathering rates is well supported by predictions of weathering models, i.e., that the curvature of the rind-core boundary controls the porosity creation and weathering advance rates at the clast scale. At the watershed scale, the new weathering advance rates derived on the low curvature transects for the relatively dry Deshaies watershed (average rate of 0.08 mm/kyr; MAP = 1800 mm and MAT = 23 °C) are ∼60% slower than the rind formation rates previously determined in the much wetter Bras David watershed (∼0.18 mm/kyr, low curvature transect; MAP = 3400 mm and MAT = 23 °C) also on Basse-Terre Island. Thus, a doubling of MAP roughly correlates with a doubling of weathering advance rate. The new rind study highlights the effect of precipitation on weathering rates over a time scale of ∼100 kyr. Weathering rinds are thus a suitable system for investigating long-term chemical weathering across environmental gradients, complementing short-term riverine solute fluxes.

Basse-Terre Island↗

USGS2017

Oxygen and U-Th isotopes and the timescales of hydrothermal exchange and melting in granitoid wall rocks at Mount Mazama, Crater Lake, Oregon

We report new whole rock U-Th and in-situ oxygen isotope compositions for partially melted (0–50 vol% melt), low-δ 18 O Pleistocene granitoid blocks ejected during the ∼7.7 ka caldera-forming eruption of Mt. Mazama (Crater Lake, Oregon). The blocks are interpreted to represent wall rocks of the climactic magma chamber that, prior to eruption, experienced variable amounts of exchange with meteoric hydrothermal fluids and subsequent partial melting. U-Th and oxygen isotope results allow us to examine the timescales of hydrothermal circulation and partial melting, and provide an “outside in” perspective on the buildup to the climactic eruption of Mt. Mazama. Oxygen isotope compositions measured in the cores and rims of individual quartz ( n = 126) and plagioclase ( n = 91) crystals, and for transects across ten quartz crystals, document zonation in quartz (Δ 18 O Core-Rim ≤ 0.1–5.5‰), but show homogeneity in plagioclase (Δ 18 O Core-Rim ≤ ±0.8‰). We propose that oxygen isotope zonation in quartz records hydrothermal exchange followed by high-temperature exchange in response to partial melting caused by injection of basaltic to andesitic recharge magma into the deeper portions of the chamber. Results of modeling of oxygen diffusion in quartz indicates that hydrothermal exchange in quartz occurred over a period of ∼1000–63,000 years. Models also suggest that the onset of melting of the granitoids occurred a minimum of ∼10–200 years prior to the Mazama climactic eruption, an inference which is broadly consistent with results for magnetite homogenization and for Zr diffusion in melt previously reported by others. Uranium-thorium isotope compositions of most granitoid blocks are in 238 U excess, and are in agreement with a 238 U enriched array previously measured for volcanic rocks at Mt. Mazama. Uranium excess in the granitoids is likely due to enrichment via hydrothermal circulation, given their low δ 18 O values. The sample with the highest U excess (≥5.8%) also has the most 18 O isotope depletion (average δ 18 O plag = −4.0‰). The granitoids are a probable assimilant and source of U excess in volcanic rocks from Mt. Mazama. Two granitoids have Th excess and low δ 18 O values, interpreted to record leaching of U during hydrothermal alteration. A U-Th isochron based on the U excess array of the granitoids and volcanic rocks indicates that hydrothermal circulation initiated ∼40–75 kyrs before the climactic eruption, potentially marking the initiation of a persistent upper-crustal magma chamber. The U-Th ages are consistent with the maximum timescales inferred for hydrothermal alteration based on oxygen isotope zoning in quartz.

Oregon↗

USGS2011

U-Pb (zircon) and geochemical constraints on the age, origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu-Au district, southern Mongolia

Uranium–Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu–Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt , the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions ( ε Nd(t) range from + 3.1 to + 7.5 and 206 Pb/ 204 Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have < 1.5% TiO 2 ) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu–Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism . Uranium–Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu–Au deposits are ~ 372 Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu–Au mineralization are ~ 366 Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu–Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu–Au deposits from younger magmatic suites in the district.

Southern Mongolia↗

USGS2015

Maximum likelihood Bayesian model averaging and its predictive analysis for groundwater reactive transport models

While Bayesian model averaging (BMA) has been widely used in groundwater modeling, it is infrequently applied to groundwater reactive transport modeling because of multiple sources of uncertainty in the coupled hydrogeochemical processes and because of the long execution time of each model run. To resolve these problems, this study analyzed different levels of uncertainty in a hierarchical way, and used the maximum likelihood version of BMA, i.e., MLBMA, to improve the computational efficiency. This study demonstrates the applicability of MLBMA to groundwater reactive transport modeling in a synthetic case in which twenty-seven reactive transport models were designed to predict the reactive transport of hexavalent uranium (U(VI)) based on observations at a former uranium mill site near Naturita, CO. These reactive transport models contain three uncertain model components, i.e., parameterization of hydraulic conductivity, configuration of model boundary, and surface complexation reactions that simulate U(VI) adsorption. These uncertain model components were aggregated into the alternative models by integrating a hierarchical structure into MLBMA. The modeling results of the individual models and MLBMA were analyzed to investigate their predictive performance. The predictive logscore results show that MLBMA generally outperforms the best model, suggesting that using MLBMA is a sound strategy to achieve more robust model predictions relative to a single model. MLBMA works best when the alternative models are structurally distinct and have diverse model predictions. When correlation in model structure exists, two strategies were used to improve predictive performance by retaining structurally distinct models or assigning smaller prior model probabilities to correlated models. Since the synthetic models were designed using data from the Naturita site, the results of this study are expected to provide guidance for real-world modeling. Limitations of applying MLBMA to the synthetic study and future real-world modeling are discussed.

California↗

USGS2017

A geochronologic framework for the Ziegler Reservoir fossil site, Snowmass Village, Colorado

The Ziegler Reservoir fossil site near Snowmass Village, Colorado, provides a unique opportunity to reconstruct high-altitude paleoenvironmental conditions in the Rocky Mountains during the last interglacial period. We used four different techniques to establish a chronological framework for the site. Radiocarbon dating of lake organics, bone collagen, and shell carbonate, and in situ cosmogenic 10 Be and 26 Al ages on a boulder on the crest of a moraine that impounded the lake suggest that the ages of the sediments that hosted the fossils are between ~ 140 ka and > 45 ka. Uranium-series ages of vertebrate remains generally fall within these bounds, but extremely low uranium concentrations and evidence of open-system behavior limit their utility. Optically stimulated luminescence (OSL) ages (n = 18) obtained from fine-grained quartz maintain stratigraphic order, were replicable, and provide reliable ages for the lake sediments. Analysis of the equivalent dose (D E ) dispersion of the OSL samples showed that the sediments were fully bleached prior to deposition and low scatter suggests that eolian processes were likely the dominant transport mechanism for fine-grained sediments into the lake. The resulting ages show that the fossil-bearing sediments span the latest part of marine isotope stage (MIS) 6, all of MIS 5 and MIS 4, and the earliest part of MIS 3.

Colorado↗

USGS1997

238U-234U-230Th disequilibrium in hydrogenous oceanic Fe-Mn crusts: Palaeoceanographic record or diagenetic alteration?

A detailed TIMS study of ( 234 U exc / 238 U), ( 230 Th/ 232 Th), and Th/U ratios have been performed on the outermost margin of ten hydrogenous Fe Mn crusts from the equatorial Pacific Ocean and west-central Indian Ocean.Th/U concentration ratios generally decrease from the crust's surface down to 0.5-1 mm depth and growth rates estimated by uranium and thorium isotope ratios are significantly different in Fe Mn crusts from the Peru Basin and the west-central Indian Ocean. Fe Mn crusts from the same geographical area define a single trend in plots of Ln( 234 U exc / 238 U) vs. Ln( 230 Th/ 232 Th) and Th/U ratios vs. age of the analysed fractions. Results suggest that (l) hydrogenous Fe Mn crusts remain closed-systems after formation, and consequently (2) the discrepancy observed between the 230 Th and 234U chronometers in Fe Mn crusts, and the variations of the Th/U ratios through the margin of FeMn crusts, are not due to redistribution of uranium and thorium isotopes after oxyhydroxide precipitation, but rather to temporal variations of both Th/U and initial thorium activity ratios recorded by the Fe Mn layers. Implications of these observations for determination of Fe Mn crust growth-rates are discussed. Variations of both Th/U and initial Th activity ratios in Fe Mn crusts might be related to changes in particle input to seawater and/or changes in ocean circulation during the last 150 ka.

Geochimica et Cosmochimica Acta↗

USGS1997

222Rn transport in a fractured crystalline rock aquifer: Results from numerical simulations

Dissolved 222Rn concentrations in ground water from a small wellfield underlain by fractured Middle Proterozoic Pikes Peak Granite southwest of Denver, Colorado range from 124 to 840 kBq m-3 (3360-22700 pCi L-1). Numerical simulations of flow and transport between two wells show that differences in equivalent hydraulic aperture of transmissive fractures, assuming a simplified two-fracture system and the parallel-plate model, can account for the different 222Rn concentrations in each well under steady-state conditions. Transient flow and transport simulations show that 222Rn concentrations along the fracture profile are influenced by 222Rn concentrations in the adjoining fracture and depend on boundary conditions, proximity of the pumping well to the fracture intersection, transmissivity of the conductive fractures, and pumping rate. Non-homogeneous distribution (point sources) of 222Rn parent radionuclides, uranium and 226Ra, can strongly perturb the dissolved 222Rn concentrations in a fracture system. Without detailed information on the geometry and hydraulic properties of the connected fracture system, it may be impossible to distinguish the influence of factors controlling 222Rn distribution or to determine location of 222Rn point sources in the field in areas where ground water exhibits moderate 222Rn concentrations. Flow and transport simulations of a hypothetical multifracture system consisting of ten connected fractures, each 10 m in length with fracture apertures ranging from 0.1 to 1.0 mm, show that 222Rn concentrations at the pumping well can vary significantly over time. Assuming parallel-plate flow, transmissivities of the hypothetical system vary over four orders of magnitude because transmissivity varies with the cube of fracture aperture. The extreme hydraulic heterogeneity of the simple hypothetical system leads to widely ranging 222Rn values, even assuming homogeneous distribution of uranium and 226Ra along fracture walls. Consequently, it is concluded that 222Rn concentrations vary, not only with the geometric and stress factors noted above, but also according to local fracture aperture distribution, local groundwater residence time, and flux of 222Rn from parent radionuclides along fracture walls.

Journal of Hydrology↗

USGS2003

Optical dating of tufa via in situ aeolian sand grains: A case example from the Southern High Plains, USA

Precipitated carbonates (commonly termed tufas or travertines) maybe of considerable utility for palaeoenvironmental reconstruction. Their potential, however, for such reconstruction is commonly limited by difficulties associated with their absolute age control. Attempts to date such deposits via uranium series techniques have been complicated by their chemically open behaviour. Here we describe an alternative approach to date tufa deposits associated with ephemeral saline lake basins from the Southern High Plains, USA. We have optically dated sand grains of a mixed aeolian/fluvial (spring fed) origin as the integrating dosimeter. We assume that the grains are fully resetting prior to their incorporation into the tufa deposits and employ a time-dependent disequilibrium dosimetric model to account for the build-up of uranium series daughter products. The approach was applied to a set of four samples with known stratigraphic association. We obtained stratigraphically sensible optical ages ranging from 78??8 to 56??4ka. These data are consistent with existing palaeoenvironmental models of regional recharge. ?? 2003 Elsevier Science Ltd. All rights reserved.

Conference Paper↗

USGS2002

Quantitative radiochemical method for determination of major sources of natural radioactivity in ores and minerals

When an ore sample contains radioactivity other than that attributable to the uranium series in equilibrium, a quantitative analysis of the other emitters must be made in order to determine the source of this activity. Thorium-232, radon-222, and lead-210 have been determined by isolation and subsequent activity analysis of some of their short-lived daughter products. The sulfides of bismuth and polonium are precipitated out of solutions of thorium or uranium ores, and the α -particle activity of polonium-214, polonium-212, and polonium-210 is determined by scintillation-counting techniques. Polonium-214 activity is used to determine radon-222, polonium-212 activity for thorium-232, and polonium-210 for lead-210. The development of these methods of radiochemical analysis will facilitate the rapid determination of some of the major sources of natural radioactivity.

Analytical Chemistry↗

USGS2026

Decadal trends and occurrence of geogenic constituents and mixtures in groundwater across the continental United States

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent concentrations in groundwater across the continental United States using 3 decades of data from the U.S. Geological Survey’s National Water Quality Network. Thousands of groundwater wells were grouped into agricultural, urban, or domestic supply network types. Although most networks and constituents had no statistically significant change in concentration, many had increasing concentration trends, elevated concentrations, or both. Lithium, sodium, radium, sulfate, and uranium had increasing trends in more than 10% of the study networks. Urban and domestic well networks had increasing lithium and sodium trends more often than agricultural networks. Manganese most commonly increased in domestic well networks; uranium more commonly increased in agricultural and urban networks. Elevated concentration mixtures were widespread, and mixture complexities appeared to increase over time. Our results indicate that more than 2.3 million domestic-well users may be affected by elevated concentrations of one or more geogenic constituents.

continental United States↗

USGS2009

Surface complexation modeling of U(VI) adsorption by aquifer sediments from a former mill tailings site at Rifle, Colorado

A study of U(VI) adsorption by aquifer sediment samples from a former uranium mill tailings site at Rifle, Colorado, was conducted under oxic conditions as a function of pH, U(VI), Ca, and dissolved carbonate concentration. Batch adsorption experiments were performed using <2mm size sediment fractions, a sand-sized fraction, and artificial groundwater solutions prepared to simulate the field groundwater composition. To encompass the geochemical conditions of the alluvial aquifer at the site, the experimental conditions ranged from 6.8 ?? 10 -8 to 10 -5 M in [U(VI)]tot, 7.2 to 8.0 in pH, 3.0 ?? 10 -3 to 6.0 ?? 10 -3 M in [Ca 2+ ], and 0.05 to 2.6% in partial pressure of carbon dioxide. Surface area normalized U(VI) adsorption Kd values for the sand and <2 mm sediment fraction were similar, suggesting a similar reactive surface coating on both fractions. A two-site two-reaction, nonelectrostatic generalized composite surface complexation model was developed and successfully simulated the U(VI) adsorption data. The model successfully predicted U(VI) adsorption observed from a multilevel sampling well installed at the site. A comparison of the model with the one developed previously for a uranium mill tailings site at Naturita, Colorado, indicated that possible calcite nonequilibrium of dissolved calcium concentration should be evaluated. The modeling results also illustrate the importance of the range of data used in deriving the best fit model parameters. ?? 2009 American Chemical Society.

Environmental Science & Technology↗

USGS1999

Evaluation of weights of evidence to predict epithermal-gold deposits in the Great Basin of the western United States

The weights-of-evidence method provides a simple approach to the integration of diverse geologic information. The application addressed is to construct a model that predicts the locations of epithermal-gold mineral deposits in the Great Basin of the western United States. Weights of evidence is a data-driven method requiring known deposits and occurrences that are used as training sites in the evaluated area. Four hundred and fifteen known hot spring gold–silver, Comstock vein, hot spring mercury, epithermal manganese, and volcanogenic uranium deposits and occurrences in Nevada were used to define an area of 327.4 km 2 as training sites to develop the model. The model consists of nine weighted-map patterns that are combined to produce a favorability map predicting the distribution of epithermal-gold deposits. Using a measure of the association of training sites with predictor features (or patterns), the patterns can be ranked from best to worst predictors. Based on proximity analysis, the strongest predictor is the area within 8 km of volcanic rocks younger than 43 Ma. Being close to volcanic rocks is not highly weighted, but being far from volcanic rocks causes a strong negative weight. These weights suggest that proximity to volcanic rocks define where deposits do not occur. The second best pattern is the area within 1 km of hydrothermally altered areas. The next best pattern is the area within 1 km of known placer-gold sites. The proximity analysis for gold placers weights this pattern as useful when close to known placer sites, but unimportant where placers do not exist. The remaining patterns are significantly weaker predictors. In order of decreasing correlation, they are: proximity to volcanic vents, proximity to east-west to northwest faults, elevated airborne radiometric uranium, proximity to northwest to west and north-northwest linear features, elevated aeromagnetics, and anomalous geochemistry. This ordering of the patterns is a function of the quality, applicability, and use of the data. The nine-pattern favorability map can be evaluated by comparison with the USGS National Assessment for hot spring gold–silver deposits. The Spearman's ranked correlation coefficient between the favorability and the National Assessment permissive tracts is 0.5. Tabulations of the areas of agreement and disagreement between the two maps show 74% agreement for the Great Basin. The posterior probabilities for 51 significant deposits in the Great Basin, both used and not used in the model, show the following: 26 classified as favorable; 25 classified as permissive; and 1, Florida Canyon, classified as nonpermissive.The Florida Canyon deposit has a low favorability because there are no volcanic rocks near the deposit on the Nevada geologic map used. The largest areas of disagreement are caused by the USGS National Assessment team concluding that volcanic rocks older than 27 Ma in Nevada are not permissive, which was not assumed in this model. The weights-of-evidence model is evaluated as reasonable and delineates permissive areas for epithermal deposits comparable to expert's delineation. The weights-of-evidence model has the additional characteristics that it is well defined, reproducible, objective, and provides a quantitative measure of confidence.

California, Nevada↗

USGS2012

Pedologic and climatic controls on Rn-222 concentrations in soil gas, Denver, Colorado

Soil-gas radon concentrations are controlled seasonally by factors of climate and pedology. In a swelling soil of the semiarid Western United States, soil-gas radon concentrations at 100 cm depth increase in winter and spring due to increased emanation with higher soil moisture and the capping effect of surface water or ice. Increased soil moisture results from a combination of higher winter and spring precipitation and decreased insolation in fall and winter, lowering soil temperatures so that water infiltrates deeper and evaporates more slowly. Radon concentrations in soil drop markedly through the summer and fall. The increased insolation of spring and summer warms and dries the soil, limiting the amount of water that reaches 100 cm. As the soil dries, radon emanation decreases, and deep soil cracks develop. These cracks aid convective transport of soil gas, increase radon's flux into the atmosphere, and lower its concentration in soil gas. Probable controls on the distribution of uranium within the soil column include its downward leaching, its precipitation or adsorption onto B-horizon clays, concretions, or cement, and the uranium content and mineralogy of the soil's granitic and gneissic precursors.

Geophysical Research Letters↗

USGS2012

Age estimates and uplift rates for late Pleistocene marine terraces: Southern Oregon portion of the Cascadia forearc

Interest in the Cascadia subduction zone has increased because recent investigations have suggested that slip along plates at certain types of convergent margins is characteristically accompanied by large earthquakes. In addition, other investigations have suggested that convergent margins can be broadly classified by the magnitude of their uplift rates. The authors generated new uranium series, amino acid, and stable isotope data for southern Oregon marine terrace fossils. These data, along with terrace elevations and two alternative estimates of sea level at the time of terrace formation, allow one to determine terrace ages and uplift rates. Uranium series analysis of fossil coral yields an age of 83 {plus minus} 5 ka for the Whisky Run terrace at Coquille Point in Bandon, Oregon. A combination of amino acid and oxygen isotope data suggest ages of about 80 and 105 ka for the lowest two terraces at Cape Blanco. These ages indicate uplift rates of 0.45-1.05 and 0.81-1.49 m/kyr for Coquille Point and Cape Blanco, respectively. In order to assess the utility of the southern Oregon uplift rates for predicting the behavior of the Cascadia subduction zone, the authors compared late Quaternary uplift rates derived from terrace data from subduction zones around the world. On the basis of this comparison the southern Oregon rates of vertical deformation are not usually high or low. Furthermore, late Quaternary uplift rates show little relationship to the type of convergent margin. In the case of the southern Oregon coast, variability in uplift rate probably reflects local structures in the overriding plate, and the rate of uplift cannot be used as a simple index of the potential for great earthquakes along the southern Cascadia subduction zone.

California, Oregon↗