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USGS2011

Effects of acid deposition on ecosystems: Advances in the state of the science

Chapter 2 focused on the environmental results of the ARP, presenting data from national monitoring networks on SO2 and NOx emissions, air quality, atmospheric deposition, surface water chemistry, and visibility. This chapter expands on this information by examining the most recent research into how ecosystems respond to acid deposition, especially the processes that control the recovery of ecosystems as acid deposition decreases. In Chapter 2, two general trends were discussed regarding the current recovery status of affected ecosystems: (1) these ecosystems are trending generally towards recovery, but improvements in ecosystem condition shown by surface water chemistry monitoring data thus far have been less than the improvements in deposition; and (2) ecosystem impacts and trends vary widely by geographic region, but the evidence of improvement is strongest and most evident in the Northeast. These trends are not uniform across the United States, however, and in some regions (e.g., central Appalachian Mountain region), trends in improved water quality are generally not evident. Despite the strong link in many areas between reduced emissions and reduced acidity of atmospheric deposition, the link is less clear between reduced acidity and recovery of the biological communities that live in aquatic and terrestrial ecosystems that have experienced deleterious effects from acid deposition. The recovery of these communities is proceeding at a slower pace than, for example, the improvements in stream and lake ANC would indicate. The goal of this chapter is to synthesize the science in a weightof-evidence manner to provide policy makers with tangible evidence and likely causative factors regarding ecosystem status and recovery patterns to date. This chapter serves as an update to the 2005 NAPAP RTC (NSTC, 2005), with an emphasis on scientific studies and monitoring since 2003, which was the last year for consideration of research results in the 2005 report. Several issues pertinent to ecosystem response to emission controls and acid deposition are receiving increasing attention in the scientific literature and will be discussed in this chapter, including the (1) observed delay in ecosystem recovery in the eastern United States, even with decreases in emissions and deposition over the past 30 years; (2) emerging ecosystem impacts of nitrogen deposition in the western United States; (3) the application of critical deposition loads as a tool for scientists to better inform air quality policies; (4) the role of changes in climate and the carbon cycle as factors that affect the response of ecosystems to acid deposition; and (5) the interaction of multiple pollutants in ecosystems. Throughout this chapter, the value of long-term environmental monitoring data in informing air quality policy will be highlighted, including the limitations of assessing the current status of some ecosystem indicators for which continuous, long-term data are lacking.

Report↗

USGS2019

Sources, timing, and fate of sediment and contaminants in the nearshore: insights from geochemistry

Rivers in Cascade watersheds carry sediment with a volcanic composition that is distinct from the plutonic composition of the Puget lowlands. Compositional properties (signatures) allow discrimination of river-sourced Cascade from lowland sediment, and inferences about transport pathways. Surface sediment on land contains atmospheric radionuclides whose known decay rates define monthly (7Be) and decadal (210Pb) timescales of sediment inputs from land to nearshore regions. We used geochemical signatures to source river-borne sediment in two urban embayments in Cascade watersheds: Commencement Bay (CB) and Bellingham Bay (BB). We concurrently determined sediment contaminant levels and, in CB, used geochemical aging to distinguish contaminants in recent winter outflow from those that were pre-existing. Methods are described in Takesue et al. (2017). Geochemical signatures showed that Puyallup River (PU)-sourced fine sediment (<63 µm) accumulated more along the northeast (NE) shore of CB than the southwest: median 91% and 69%, respectively. River-sourced sediment from recent winter storms, containing higher 7Be activities (open circles, Fig. 1A), also accumulated on the NE shore and had lower contents of PAHs, fecal sterols, PCBs, and potentially toxic metals (TM) compared to the south shore; only PBDEs were higher (column graphs, Fig. 1A). Lower 7Be and 210Pb activities in south shore sediment indicated that contaminants there were associated with older sediment. Existing sediment in CB contained higher levels of urban contaminants than new PU material. No PAH, PCB, or TM levels in CB exceeded Washington State marine sediment quality standards (WAMSQS). Geochemical signatures were not distinct in the Nooksack River watershed and lowlands, precluding sediment sourcing in BB. PAH ratios in BB sediments were ubiquitous (open circles, Fig. 1B), suggesting atmospheric rather than riverine transport, and had values indicating biomass/coal combustion sources, except for three sites along the urban waterfront that had values indicative of vehicle emissions (closed circles, Fig. 1B). Elevated TM occurred offshore of Fairhaven (cadmium, Cd; copper, Cu; lead, Pb; zinc, Zn), Whatcom Creek Waterway (Pb, Zn), and the marina (Cu, Zn). No PAH or TM concentrations in BB exceeded WAMSQS. Insights gained from sediment geochemistry about the sources, timing, transport, and fate of riverborne fine sediment and contaminants in nearshore regions are valuable components of monitoring programs that can help guide habitat restoration and resource management decisions toward effective and sustainable outcomes.

Washington↗

USGS2019

Managed aquifer recharge in snow-fed river basins: What, why and how?

What does climate change mean for snow-fed river basins? Climate change poses unique challenges in snow-fed river basins across the western United States because the majority of water supply originates as snow (Dettinger, Udall, & Georgakakos, 2015). In the Sierra Nevada, recent observations include changes in snow accumulation and snowmelt, and shifts in peak streamflow timing (Barnhart et al., 2016; Hatchett et al., 2017; Kim & Jain, 2010; McCabe, Wolock, & Valentin, 2018; Mote, Li, Lettenmaier, Xiao, & Engel, 2018). Such changes upstream alter surface water deliveries downstream, as well as groundwater recharge utilized as both primary and supplemental water supply (Godsey et al., 2014; Harpold, 2016; Jasechko et al., 2014). basin where snowmelt runoff produces substantial water supply to meet diverse agricultural, environmental and urban water demand (Figure 1). The East and West Forks join at the confluence of the Carson River near the north end of the Carson Valley, a rich agricultural region (40,000 acres) that grows primarily alfalfa hay. The majority of irrigators rely on surface water delivered through a network of earthen ditches constructed in the mid-19th and early 20th centuries. Flow through these earthen networks and the practice of flood irrigation contribute significantly to groundwater recharge. Because no upstream surface water reservoirs exist, snowpack that accumulates through winter and melts slowly through spring has acted as a “natural” reservoir, providing ample supply through the summer irrigati agricultural, environmental and urban water demand (Figure 1). The East and West Forks join at the confluence of the Carson River near the north end of the season. Some irrigators have permitted access to supplemental groundwater that is useful during periods of drought for augmenting shortfalls in surface water delivery. Groundwater is the primary source of municipal and industrial water supply for surrounding communities (e.g., Carson City, Minden, Gardnerville, Dayton). Across the basin, water use is highly regulated through federal, tribal, state and local water-sharing agreements based on prior appropriation doctrine (Wilds, 2014). Carson River surface water allocations follow the Alpine Decree, initiated by the United States Department of Interior in 1925 and signed into law in 1980, following 55 years of litigation, to adjudicate surface water rights to individual parties (NDWP, 1999). The Alpine Decree acknowledges return flows to lower river segments, and thus each river segment is distributed autonomously. This means that the most junior water right on an upper segment can be fulfilled before considering the most senior water right on a lower segment. Ultimately, the ruling is at the discretion of the Federal Water Master to satisfy the needs of each water right Downstream of Carson Valley, surface water flows are stored in Lahontan Reservoir, the nation’s first desert reclamation project (est. 1906), where releases are managed to meet the Newland’s Project irrigation water demand and for environmental use on the Stillwater National Wildlife Refuge. Flows from the Carson River are supplemented through diversions from the Truckee River via the Truckee Canal, resulting in a trans-basin water supply system. How is the Water for the Seasons research program informing snow-fed river basin communities? In the Truckee-Carson River System, researchers and local water managers are working together to assess climate change impacts to water supply and explore how model simulations can produce useful information to support local climate adaptation. Twelve key water managers represent agricultural, environmental, urban and regulatory water-use communities, and bring to the table diverse input and perspectives on how to adapt to climate change. Hydrologists use this input to craft scenarios and simulations that meet the information needs of local water managers. Biannual workshops provide an opportunity for information exchange, where researchers and key water managers generate new knowledge of river system function. That is, researchers share results of models that examine the physical potential, and managers validate the on-the-ground potential, further informing the research process. Coincident to this research program, the region faced a prolonged drought period (2012-2016) with historically low snowpack, followed by a historic wet year (2017) that brought winter and spring flooding as a result of atmospheric river storm events (Sterle et al., 2019). For the Carson River, an important observation made by managers was that peak streamflow that had traditionally coincided with peak irrigation demands, had shifted to earlier in the spring, with summer baseflow also decreasing (Sterle & Singletary, 2017). Managers shared with researchers concerns over potential future impacts that changing snowpack will have on surface water deliveries and reliance on groundwater, as the region’s population and economy continue to grow. During workshops that occurred over this period, local water managers and researchers discussed ways to evaluate water distribution and use that honors the existing legal framework and accounts for changing snowpack regimes (amount, rain versus snow, timing). In response to managers growing interest, researchers introduced the concept of managed aquifer recharge as one potential strategy to adapt and enhance regional water sustainability. What is managed aquifer recharge? Simply stated, managed aquifer recharge is the intentional recharge of structures to spread water over agricultural lands, allowing water to naturally infiltrate into the groundwater system (Bouwer, 1999; Niswonger et al., 2017). The latter may occur during the irrigation season by applying excess water, or during the nonirrigation season when evapotranspiration losses are low. Figure 2 illustrates managed aquifer recharge in a snow-fed river basin, where streamflow generated from snowmelt runoff is diverted to agricultural lands to recharge the aquifer. Such flood irrigation practices, including water delivery through earthen ditch networks, provide incidental but significant aquifer recharge through seepage and deep drainage beneath fields (Niswonger, Allander, & Jeton, 2014). The effects of managed aquifer recharge can vary depending on the location and intensity of practice. For example, implementing managed aquifer recharge water into the groundwater system (Dillon, 2009). This differs from the incidental recharge that may occur as part of normal irrigation practices. Managed recharge may occur by injection into the aquifer through existingwells, or by using existing conveyance adjacent to/along the river’s floodplain has the potential to enhance late-season instream flows due to increased return flows, resulting in greater downstream deliveries as well as improving ecological conditions (Niswonger et al., 2017). Implementing managed aquifer recharge away from the river’s floodplain has the potential to enhance groundwater supply which is increasingly relied upon during surface water shortage (Green et al., 2011), by storing water in available aquifer space in the deep aquifer. At the basin scale, managed aquifer recharge may lead to regional groundwater sustainability. Is the Carson River Basin a candidate for managed aquifer recharge? The physical limitations to implementing managed aquifer recharge in the Carson River Basin hinges on three key factors. The first factor relates to the physical connectivity between rivers and streams, and the irrigation delivery network of canals and ditches that divert water to agricultural lands (Niswonger et al., 2017). In the Carson River Basin the mechanisms for getting water to fields is already in place. Thus, intentionally routing high flows that occur in wet years through this system during the nonirrigation season would mimic what occurs naturally during the irrigation season. The second factor relates to the occurrence of atmospheric river storm events that deliver large amounts of precipitation to the region, much greater than average (Dettinger et al., 2015). With increased frequency and intensity projected under a warmer climate, such events have the potential to produce excess water over short periods of time that could be stored through mechanisms such as managed aquifer recharge (Niswonger et al., 2017). The third factor relates to the change in snowpack accumulation and shifts in snowmelt timing observed elsewhere in the Sierra Nevada (e.g., Godsey et al., 2014; Mote et al., 2018). Having a mechanism in place to maximize use of earlier snowmelt and shifts in streamflow timing could be advantageous and enhance regional groundwater sustainability. As part of the Water for the Seasons study, a hypothetical scenario was developed to determine the feasibility of managed aquifer recharge in the Carson River Basin, assuming no legal constraints. During “wet” or above-average water years, irrigators in the Upper Carson Valley would divert high flows and spread water over agricultural lands during the nonirrigation season. Assuming flows are abundant and “early,” diversions would begin prior to the growing season, when water would otherwise flow downstream to the Lahontan Reservoir. During “dry” years or drought periods, when surface water availability is less, irrigators in the Upper Carson Valley could augment surface water shortages with groundwater, allowing available surface water flows to flow downstream. Researchers hypothesize the amount of water has the potential to boost baseflow to support environmental instream flows, for example. What concerns have local water managers expressed? The hypothetical managed aquifer recharge scenario was presented to water managers in a workshop setting. Presentations included an overview of the hydrologic and operations modeling tools used to evaluate managed aquifer recharge by simulating the timing and distribution of water in the upper watershed. Specifically, in the Upper Carson Valley, a hydrologic model (GSFLOW) simulates streamflow driven by snowmelt, and surface and groundwater interactions, while a river basin operations model (MODSIM) allocates water according to the prior appropriation doctrine in the basin (see Figure 1) (Morway, Niswonger, & Triana, 2016; Niswonger et al., 2017). Integrating these two modeling tools advances the evaluation of climate impacts on water availability in agricultural communities and the resulting impacts of alternative management strategies (Morway et al., 2016). When asked about the viability of managed aquifer recharge, the perspectives of 11 managers varied (Figure 3). Regardless of rating, all managers questioned, “How would thisreally work?” Several managers questioned whether models could simulate the connectivity between surface and groundwater to accurately quantify changes to instream flow. Others raised concerns that managed aquifer recharge violates the Alpine Decree and Nevada Water Law. Still others requested researchers consider alternatives that could work within the confines of current (2019) water law. Managers posed specific questions that should be considered when evaluating the potential for managed aquifer recharge. For example: What triggers implementation of managed aquifer recharge?How “high” or “low” must annual flows be to initiate managed aquifer recharge? When in the water year is this determined? Where exactly in the Carson Valley is managed aquiferre charge possible? For example, what areas away from the floodplain could ensure long-term storage? Can model simulations quantify potential benefits and consequences system-wide?Would this information support decision-making, such as permitting of additional supplemental groundwater rights? How are researchers going to address managers’ research questions? Managers’ perspectives help to validate the on-the-ground potential of particular strategies and further refine alternative management scenarios. For example, understanding that managers are concerned with oversaturated fields helps researchers to define conditions in the model, such as what defines a wet versus “too” wet type of year and where to focus irrigation for managed aquifer recharge. Incorporating these nuances provides more accurate quantification of the potential benefits and consequences for users across the basin. Modeling is underway to simulate managed aquifer recharge scenarios and explore basin-wide implications. Researchers and local water managers will convene to collaboratively review results and further assess whether this or other strategies could work under the confines of existing water law. Subsequent fact sheets will present these findings.

Nevada↗

USGS2021

Appendix E. Water quality and hydrology of Green Lake, Wisconsin, and the response in its near-surface water-quality and metalimnetic dissolved oxygen minima to changes in phosphorus loading

Green Lake is the deepest natural inland lake in Wisconsin, USA, with a maximum depth of about 72 meters (m). In the early 1900’s, the lake was believed to have very good water quality (low nutrient concentrations and good water clarity), with low dissolved oxygen (DO) concentrations only in the deepest part of the lake. Because of increased phosphorus (P) inputs from anthropogenic activities in its watershed, total phosphorus (TP) concentrations in the lake increased, which led to increased algal production and low DO concentrations not only occurring in its deepest areas but also in the middle of the water column (metalimnion). Routine monitoring of the lake and its tributaries has been conducted by the U.S. Geological Survey since 2004 and 1988, respectively. Results from this monitoring led to the Wisconsin Department of Natural Resources (WDNR) listing the lake as impaired because of low DO concentrations in the metalimnion, with elevated TP concentrations identified as the cause of impairment. As part of this study, comprehensive sampling of the lake and its tributaries was conducted in 2017–2018 to augment ongoing monitoring and further describe the low DO concentrations in the lake (especially in the metalimnion). Empirical and process-driven water quality models were then used to determine the causes of the low DO concentrations and the magnitude of P load reductions needed to improve the water quality of the lake to meet multiple water-quality goals, including the WDNR criteria for TP and DO. Data from previous studies showed that DO concentrations in the metalimnion decreased slightly as summer progressed in the early 1900’s, but since the late 1970s have typically dropped below 5 milligrams per liter (mg/L), which is the WDNR criterion for impairment. During 2014–2018 (baseline period for this study), the near-surface geometric-mean TP concentration during June–September in the east side of the lake was 0.020 mg/L and in the west side was 0.016 mg/L (both were below the 0.015 mg/L WDNR criterion for the lake), and the minimum metalimnetic DO concentrations measured in August ranged from 1.0 to 4.7 mg/L. It was believed that the degradation in water quality was caused by excessive P inputs to the lake; therefore, the total P inputs to the lake were estimated. The mean annual external P load during 2014–2018 was estimated to be 8,980 kilograms per year (kg/yr), of which monitored and unmonitored tributary inputs contributed 84 percent, atmospheric inputs contributed 8 percent, waterfowl contributed 7 percent, and septic systems contributed 1 percent. At fall turnover, internal sediment recycling contributed an additional 7,040 kg that increased TP concentrations in shallow areas of the lake by about 0.020 mg/L. The elevated TP concentrations then persisted until the following spring. On an annual basis, however, there is a net deposition of P to the bottom sediments. Empirical models were used to describe how the near-surface water quality of Green Lake would be expected to respond to changes in external P loading. Predictions from the models showed a relatively linear response between P loading and TP and chlorophyll-a (Chl-a) concentrations in the lake, with the changes in TP and Chl-a concentrations being less on a percentage basis (50–60 percent for TP and 30–70 percent for Chl-a) than the changes in P loading. Mean summer water clarity, indicated by Secchi disk depths, had a larger response to decreases in P loading than to increases in loading. Based on these relations, external P loading to the lake would need to be decreased from 8,980 kg/yr to about 5,460 kg/yr for the geometric mean June–September TP concentration on the east side of the lake, with higher TP concentrations than the west side, to reach the WDNR criterion of 0.015 mg/L. This reduction of 3,520 kg/yr equates to a 46-percent reduction in the potentially controllable external P sources (all external sources except precipitation, atmospheric deposition, and waterfowl) from that measured during water years (WYs) 2014–2018. The total external P loading would need to be decreased to 7,680 kg/yr (17-percent reduction in potentially controllable external P sources) for near-surface June–September TP concentrations in the west side of the lake to reach 0.015 mg/L. Total external P loading would need to be decreased to 3,870–5,320 kg/yr for the lake to be classified as oligotrophic, with a near-surface June-September TP concentration of 0.012 mg/L. Results from the hydrodynamic water-quality model GLM-AED (General Lake Model coupled to the Aquatic Ecodynamics modeling library) indicated that metalimnetic DO minima are driven by external P loading and internal sediment recycling that lead to high TP concentrations during spring and early summer, which in turn lead to high phytoplankton production, high metabolism and respiration, and ultimately DO consumption in the upper, warmer areas of the metalimnion. GLM-AED results indicated that settling of organic material during summer may be slowed by the colder, denser, and more viscous water in the metalimnion and increase DO consumption. Based on empirical evidence comparing minimum metalimnetic DO concentrations with various meteorological, hydrologic, water quality, and in-lake physical factors, lower metalimnetic DO concentrations occurred when there was warmer metalimnetic water temperatures, higher near-surface Chl-a and TP concentrations, and lower Secchi depths during summer. GLM-AED results indicated that the external P load would need to be reduced to about 4,010 kg/yr, a 57-percent reduction from that measured in 2014–2018, to eliminate the occurrence of metalimnetic DO minima of less than 5 mg/L in over 75 percent of the years (the target provided by the WDNR). Large reductions in external P loading are expected to have an immediate effect on the near-surface TP concentrations and metalimnetic DO concentrations in Green Lake. However, it may take several years for the full effects of the external load reduction to be observed because internal sediment recycling is an important source of P for the following spring.

Wisconsin↗

USGS2022

Response in the water level of Anvil Lake, Wisconsin, to changes in meteorological and climatic changes, Wisconsin

Anvil Lake, a relatively shallow seepage lake in northern Wisconsin, USA, has experienced dramatic changes in water level since elevation records began in 1938 in response to changes in meteorological and climatic conditions (Figure 1. Robertson et al., 2018). Anvil Lake’s water level record shows a pronounced 10–15-yr cycle, with recurring highs and lows with a typical swing of over 1 m. Although experiencing large cycles in water levels, the long-term average levels were relatively stable until about 1987, when water level dropped dramatically by an additional 1 m (in 2016). Water levels then rebounded dramatically, reaching near “normal” water levels in 2020. At its lowest level, the lake had a maximum depth of 8.2 m (mean depth of 4.7 m) and an area of 128 ha. Like most long-term records, Anvil Lake’s water level record has been measured by several observers using various techniques. To verify the consistency of the various datums used throughout this period, historical photographs with the water’s edge identified were obtained, tied to NAVD 1988 using a Real Time Kinematic satellite global positioning system, and compared with the measured water levels (See Figure 1). To determine the causes of the changes in water level, a complete water budget was estimated for Anvil Lake from 1980 to 2014. Water levels in Anvil Lake were simulated (Figure 1) using a hydrodynamic model (General Lake Model, GLM), with daily lake evaporation estimated by GLM, monthly lake/groundwater exchange estimated with a groundwater model (MODFLOW), daily precipitation from the North American Land Data Assimilation System (NLDAS), and stream inflow and outflow were set as zero because the lake has no inlets or outlet. Atmospheric fluxes (precipitation minus evaporation) primarily drove the lake-level fluctuations and trends, but sub-decadal fluctuations in net groundwater exchange (groundwater inflow minus lake seepage) either enhanced or reduced the lake level response to the atmospheric drivers. The changes in water levels were shown to affect the extent of stratification and water quality in the lake (Robertson et al., 2018). During periods of lower precipitation and lower water levels, Anvil Lake was a polymictic lake, whereas during periods of higher precipitation and higher water levels the lake was a dimictic lake with stratification lasting throughout summer. During periods with higher water levels, the water quality in the lake was shown to improve slightly as a result of the nutrients being diluted in a larger volume of water. If precipitation increases in the future, as results from many General Circulation Models (GCMs) suggest (Robertson et al., 2016), and if that outweighs the effects of increased evaporation caused by increased air temperatures, water levels in Anvil Lake may be expected to fluctuate at a higher level. Higher water levels in Anvil Lake are expected to result in the lake becoming more strongly stratified and have slightly improved water quality (lower nutrient and algal concentrations and increased water clarity) (Robertson et al., 2018).

Wisconsin↗

USGS2020

He-CO2-N2 isotope and relative abundance characterization of geothermal fluids from the Ethiopian Rift

We report He-CO 2 -N 2 isotopic and relative abundances in free gases and dissolved gas phase of geothermal fluids from the Ethiopian Rift. Fluid samples were collected from ~30 geothermal localities from three key regions throughout rifted and non-rifted areas of Ethiopia. The majority of samples, including off-rift samples, indicate a strong contribution of mantle-derived He-C-N to the fluid samples. Helium ( 3 He/ 4 He) and δ15N-(N 2 ) isotope anomalies are highest (> 15.9RA and > +5.0‰, respectively) at a single locality in south Afar (Sodere), but the maximum δ13C-(CO 2 ) (-0.78‰) is found east of Lake Shalla in the Lake District of the Main Ethiopian Rift. High 3 He/ 4 He values, consistent with mantle plume contributions, are also evident in fluids from the Lake District, where fluids from the Lake Shalla site extend up to 15.5RA. CO 2 / 3 He values span over four orders of magnitude while δ13C-(CO 2 ) values cluster mostly between mantle-like values of -4 and -7‰; only samples east of Lake Shalla display more positive values. Atmospheric-derived nitrogen has likely influenced a number of measured δ15N-(N 2 ) values but following a correction for atmospheric-contamination, the majority of samples reveal positive values (up to 6.5‰) which appear to be coupled to high 3 He/ 4 He values. In regions affected by upwelling mantle plumes, such high values have been interpreted to reflect deep mantle inputs of recycled nitrogen.

Ethiopian Rift↗

USGS2011

Land cover change, biogeochemical modelling of carbon stocks, and climate change in West Africa

The carbon in ecosystems exists in dynamic soil and vegetation pools which vary in amounts and cycle with the global atmosphere at varying rates. These stocks and fluxes play important roles in global carbon regulation and in the maintenance of goods and services. Changes in land cover or ecosystems result in increased or decreased fluxes to the atmosphere and play a major role in climate regulation. Carbon in soil is closely coupled to soil nitrogen and the continued mining of soil for crops or fuel without replenishment of nutrients results in decreased productivity and impacts food security. The assessment of these processes across large areas, although difficult, is aided by the integration of simulation modelling (biogeochemical and ecosystem) and remote sensing. We acquired satellite imagery for four periods from the 1960s to 2000s, trained environmental scientists from 14 countries on image analysis and interpretation, and now report systematic analyses of land cover changes in select countries of West Africa and quantify potential impacts of climate change and management at specific sites. Statistical changes and maps of land cover are documented for most countries. Senegal, for example, illustrates a 57 percent loss in dense forests between 1975 and 2000 with an even greater loss rate in the preceding 10 years. Bare soil increased 16.6 percent, often related to unproductive “badland” formation. Settlements increased 45.6 percent, and reforestation replaced bare sandy areas for sand dune stabilization. In some countries (Senegal and Ghana), the impact of these conversions and changes in land management and future projections has been incorporated into biogeochemical models to quantify carbon changes and project future carbon and crop scenarios. We present current assessments of carbon fluxes and the availability of data for these West African countries.

Conference Paper↗

USGS2007

Optimization of an ecosystem model through the assimilation of eddy flux observations using a smoothed ensemble Kalman filter

The parameters of ecosystem models are conventionally optimized through nonsequential inversion methods, which treat observations as a whole and lack the flexibility to investigate possible temporal evolution of the model parameters. This research developed a smoothed ensemble Kalman filter (SEnKF) to assess to what extent the parameters and state variables of an ecosystem model can be simultaneously optimized through the assimilation of eddy flux observations. The performance of the SEnKF was demonstrated in one case study: the assimilation of measurements of carbon exchange between a mixed forest and the atmosphere at Niwot Ridge Forest (Colorado, USA) from 2000 to 2004 into a carbon flux partition model. Our analyses demonstrated that some model parameters, such as light use efficiency and respiration coefficients, were highly constrained by eddy flux data at daily to seasonal time scales. Light use efficiency was strongly seasonal. Model predictions based on parameters modified by the SEnKF were much improved, compared to predictions made without progressive data assimilation. The SEnKF reduced the variance of state variables that is caused by uncertainties of parameters and driving variables. The analysis of net ecosystem exchange of carbon between the forest and the atmosphere was improved.

Conference Paper↗

USGS2004

Global environmental databases from CEOS agencies

The Committee on Earth Observation Satellites (CEOS) is an international organization charged with coordinating international civil spaceborne missions designed to observe and study planet Earth. Comprising 44 space agencies and other national and international organizations, CEOS is recognized as the major international forum for the coordination of Earth observation satellite programs and for the interaction of these programs with users of satellite data worldwide. CEOS was created in 1984 in response to a recommendation from the Economic Summit of Industrialized Nations Working Group on Growth, Technology, and Employment’s Panel of Experts on Satellite Remote Sensing. This group recognized the multidisciplinary nature of satellite Earth observation and the value of coordination across all proposed missions. The CEOS members collect, maintain, apply, and make available data from space missions that encompass the atmospheric, terrestrial, and oceanographic fields. Collectively, these members possess petabytes of Earth observation data critical to understanding the Earth environment. Uses include monitoring oil slicks, evaluating human-induced changes to the atmosphere, determining mineral exploration areas, assessing the environmental effects of volcanic eruptions, measuring the growth of urban areas, determining where landscapes have changed because of urban growth trends, improving the efficiency of fishing as a world food stock, monitoring pest infestation, managing crop production, predicting climate and weather, and numerous other applications vital to industry, national infrastructures, and the world as a whole. The vast amount of satellite obtained, environmental data the CEOS members possess represents a fertile resource for researchers worldwide to exploit.

Conference Paper↗

USGS1987

Variation of wet deposition chemistry in Sequoia National Park, California

Sequoia National Park has monitored wet deposition chemistry in conjunction with the National Atmospheric Deposition Program and National Trends Network (NADP/NTN), on a weekly basis since July, 1980. Annual deposition of H, NO 3 and SO 4 (0.045, 3.6, and 3.9 kg ha −1 a −1 , respectively) is relatively low compared to that measured in the eastern United States, or in the urban Los Angeles and San Francisco areas. Weekly ion concentrations are highly variable. Maximum concentrations of 324,162, and 156 μeq ol −1 of H, NO 3 and SO 4 have been recorded for one low volume summer storm (1.4 mm). Summer concentrations of NO 3 and SO 4 average two and five times higher, respectively, than concentrations reported for remote areas in the world. There is considerable variability in the ionic concentration of low volume samples, and much less variability in moderate and high volume samples.

California↗

USGS1988

Short-term trends in sulfate deposition at selected bulk precipitation stations in New York

Trends in rainfall-adjusted sulfate concentration were assessed for 5-yr subrecords of the 14.5–17 yr of monthly bulk-deposition data from five stations in New York by using the seasonal Kendall test. For the 5-yr subrecord from 1978 to 1982, the trends for the bulk deposition were similar to those for weekly wet-only deposition for adjacent stations of the National Atmospheric Deposition Program (NADP). The long-term trend at each of the bulk-precipitation sites was downward and statistically significant at P < 0.02, whereas 26% of the 69 subrecords had trends that were statistically significant only at P < 0.2. Of these statistically significant subrecord trends, 10% were positive (opposite to the long-term trend). Furthermore, the slopes of the subrecord trends tended to be much steeper than those of the whole record. These 5-yr trends, consequently, are poor indicators of the trends that occur over much longer periods in the same record.

New York↗

USGS1995

A possible deficiency in estimates of wet deposition obtained from data generated by the NADP/NTN network

A conventional precipitation scavenging model is used to evaluate the effect of the performance of a wet-deposition collector on the reported deposition amounts. Three National Atmospheric Deposition Program/National Trends Network sites in semi arid western Colorado were chosen to evaluate chloride and sulfate wet deposition. Observations of the performance of a wet-deposition collector have demonstrated a delay in opening and cycling during a precipitation event. A significant fraction of wet deposition may be excluded when small amounts of initial precipitation are not sampled and a potentially large fraction of annual wet deposition may be excluded if a majority of precipitation events are small. The actual amount missed depends on the precipitation intensity, variability of intensity with time, raindrop or snowflake size and the individual performance characteristics of the collector. Detailed performance data are needed for individual wet-deposition collectors before accurate estimates of wet deposition can be expected.

Atmospheric Environment↗

USGS2007

Feasibility of a simple laboratory approach for determining temperature influence on SPMD–air partition coefficients of selected compounds

Semipermeable membrane devices (SPMDs) are a widely used passive sampling methodology for both waterborne and airborne hydrophobic organic contaminants. The exchange kinetics and partition coefficients of an analyte in a SPMD are mediated by its physicochemical properties and certain environmental conditions. Controlled laboratory experiments are used for determining the SPMD–air ( K sa 's) partition coefficients and the exchange kinetics of organic vapors. This study focused on determining a simple approach for measuring equilibrium K sa 's for naphthalene (Naph), o -chlorophenol ( o -CPh) and p -dichlorobenzene ( p -DCB) over a wide range of temperatures. SPMDs were exposed to test chemical vapors in small, gas-tight chambers at four different temperatures (−16, −4, 22 and 40 °C). The exposure times ranged from 6 h to 28 d depending on test temperature. K sa 's or non-equilibrium concentrations in SPMDs were determined for all compounds, temperatures and exposure periods with the exception of Naph, which could not be quantified in SPMDs until 4 weeks at the −16 °C temperature. To perform this study the assumption of constant and saturated atmospheric concentrations in test chambers was made. It could influence the results, which suggest that flow through experimental system and performance reference compounds should be used for SPMD calibration.

Atmospheric Environment↗

USGS2011

Short-term nitrogen additions can shift a coastal wetland from a sink to a source of N 2 O

Coastal salt marshes sequester carbon at high rates relative to other ecosystems and emit relatively little methane particularly compared to freshwater wetlands. However, fluxes of all major greenhouse gases (N 2 O, CH 4 , and CO 2 ) need to be quantified for accurate assessment of the climatic roles of these ecosystems. Anthropogenic nitrogen inputs (via run-off, atmospheric deposition, and wastewater) impact coastal marshes. To test the hypothesis that a pulse of nitrogen loading may increase greenhouse gas emissions from salt marsh sediments, we compared N 2 O, CH 4 and respiratory CO 2 fluxes from nitrate-enriched plots in a Spartina patens marsh (receiving single additions of NaNO 3 equivalent to 1.4 g N m −2 ) to those from control plots (receiving only artificial seawater solutions) in three short-term experiments (July 2009, April 2010, and June 2010). In July 2009, we also compared N 2 O and CH 4 fluxes in both opaque and transparent chambers to test the influence of light on gas flux measurements. Background fluxes of N 2 O in July 2009 averaged −33 μmol N 2 O m −2 day −1 . However, within 1 h of nutrient additions, N 2 O fluxes were significantly greater in plots receiving nitrate additions relative to controls in July 2009. Respiratory rates and CH 4 fluxes were not significantly affected. N 2 O fluxes were significantly higher in dark than in transparent chambers, averaging 108 and 42 μmol N 2 O m −2 day −1 respectively. After 2 days, when nutrient concentrations returned to background levels, none of the greenhouse gas fluxes differed from controls. In April 2010, N 2 O and CH 4 fluxes were not significantly affected by nitrate, possibly due to higher nitrogen demands by growing S. patens plants, but in June 2010 trends of higher N 2 O fluxes were again found among nitrate-enriched plots, indicating that responses to nutrient pulses may be strongest during the summer. In terms of carbon equivalents, the highest average N 2 O and CH 4 fluxes observed, exceeded half the magnitude of typical daily net carbon sequestration rates by salt marshes. Thus, anthropogenic additions of nitrate to coasts can substantially alter N 2 O fluxes from marshes, although substantial temporal variation in these fluxes was observed. To better assess the climatic roles of salt marshes, greenhouse gas emissions need to be studied in the context of chronic nitrogen loads that impact many coastal ecosystems.

Atmospheric Environment↗

USGS2021

Biological and chemical recovery of acidified Catskill Mountain streams in response to the Clean Air Act Amendments of 1990

Decades of acidic deposition have adversely affected aquatic and terrestrial ecosystems in acid-sensitive watersheds in parts of the eastern United States. The national Acid Rain Program (Title IV of the 1990 Clean Air Act Amendments - CAAA) helped reduce emissions of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ) and resulted in sharp decreases in the acidity of atmospheric deposition. The decrease in acidic deposition produced a steady decline in the acidity of streams in many poorly buffered waters across the western Adirondacks and parts of the Catskill Mountains of New York. Until recently, however, there has been little evidence of biological recovery in most acid-sensitive streams in both regions. Long-term deposition and stream-chemistry records and fish-community data from quantitative surveys done during 1991–93 and again during 2012–19 at 13 sites in the upper Neversink River and its tributaries were evaluated to determine if chemical and biological recovery were evident in this Catskill Mountain watershed and if they could be linked to regional declines in acidic deposition. Between 1991 and 2019, large decreases in sulfate and nitrate deposition in the basin mirrored declines in total nationwide SO 2 and NO x emissions. There were corresponding decreases in sulfate and nitrate concentrations in deposition at a National Trends Network station at Frost Valley (NY68) and coincident declines in sulfate concentrations at four long-term monitoring sites in the Neversink River watershed. Mean acid neutralizing capacity and pH increased and inorganic aluminum (Al i ) concentrations from routine summertime samples decreased significantly at most moderately to severely acidified sites between the two study periods. Richness, density, and biomass of fish communities increased at most sites, while the density and biomass of brook trout Salvelinus fontinalis populations increased at fewer sites that were undergoing chemical recovery. Although recovery is far from complete, trends in deposition chemistry, water quality, and fish assemblages in streams of the upper Neversink watershed indicate that the 1990 CAAA is having positive impacts on aquatic ecosystems in the Catskill Mountain region, New York.

New York↗

USGS2001

Use of stable sulfur isotopes to identify sources of sulfate in Rocky Mountain snowpacks

Stable sulfur isotope ratios and major ions in bulk snowpack samples were monitored at a network of 52 high-elevation sites along and near the Continental Divide from 1993 to 1999. This information was collected to better define atmospheric deposition to remote areas of the Rocky Mountains and to help identify the major source regions of sulfate in winter deposition. Average annual ??34S values at individual sites ranged from + 4.0 to + 8.2??? and standard deviations ranged from 0.4 to 1.6???. The chemical composition of all samples was extremely dilute and slightly acidic; average sulfate concentrations ranged from 2.4 to 12.2 ??eql-1 and pH ranged from 4.82 to 5.70. The range of ??34S values measured in this study indicated that snowpack sulfur in the Rocky Mountains is primarily derived from anthropogenic sources. A nearly linear relation between ??34S and latitude was observed for sites in New Mexico, Colorado, and southern Wyoming, which indicates that snowpack sulfate in the southern part of the network was derived from two isotopically distinct source regions. Because the major point sources of SO2 in the region are coal-fired powerplants, this pattern may reflect variations in the isotopic composition of coals burned by the plants. The geographic pattern in ??34S for sites farther to the north in Wyoming and Montana was much less distinct, perhaps rflecting the paucity of major point sources of SO2 in the northern part of the network.

Atmospheric Environment↗

USGS2000

Comparison of precipitation chemistry in the Central Rocky Mountains, Colorado, USA

Volume-weighted mean concentrations of nitrate (NO3-), ammonium (NH4+), and sulfate (SO42-) in precipitation were compared at high-elevation sites in Colorado from 1992 to 1997 to evaluate emission source areas to the east and west of the Rocky Mountains. Precipitation chemistry was measured by two sampling methods, the National Atmospheric Deposition Program/National Trends Network (NADP/NTN) and snowpack surveys at maximum accumulation. Concentrations of NO3- and SO42- in winter precipitation were greater on the western slope of the Rockies, and concentrations of NO3- and NH4+ in summer precipitation were greater on the eastern slope. Summer concentrations in general were almost twice as high as winter concentrations. Seasonal weather patterns in combination with emission source areas help to explain these differences. This comparison shows that high-elevation ecosystems in Colorado are influenced by air pollution emission sources located on both sides of the Continental Divide. It also suggests that sources of nitrogen and sulfur located east of the Divide have a greater influence on precipitation chemistry in the Colorado Rockies. Copyright (C) 2000.

Atmospheric Environment↗

USGS1999

Early evolution of a stratospheric volcanic eruption cloud as observed with TOMS and AVHRR

This paper is a detailed study of remote sensing data from the total ozone mapping spectrometer (TOMS) and the advanced very high resolution radiometer (AVHRR) satellite detectors, of the 1982 eruption of El Chichón, Mexico. The volcanic cloud/atmosphere interactions in the first four days of this eruption were investigated by combining ultraviolet retrievals to estimate the mass of sulfur dioxide in the volcanic cloud [ Krueger et al. , 1995] with thermal infrared retrievals of the size, optical depth, and mass of fine-grained (1–10 μm radius) volcanic ash [ Wen and Rose , 1994]. Our study provides the first direct evidence of gravitational separation of ash from a stratospheric, gas-rich, plinian eruption column and documents the marked differences in residence times of volcanic ash and sulfur dioxide in volcanic clouds. The eruption column reached as high as 32 km [ Carey and Sigurdsson , 1986] and was injected into an atmosphere with a strong wind shear, which allowed for an observation of the separation of sulfur dioxide and volcanic ash. The upper, more sulfur dioxide-rich part of the cloud was transported to the west in the stratosphere, while the fine-grained ash traveled to the south in the troposphere. The mass of sulfur dioxide released was estimated at 7.1 × 10 9 kg with the mass decreasing by approximately 4% 1 day after the peak. The mass of fine-grained volcanic ash detected was estimated at 6.5 × 10 9 kg, amounting to about 0.7% of the estimated mass of the ash which fell out in the mapped ash blanket close to the volcano. Over the following days, 98% of this remaining fine ash was removed from the volcanic cloud, and the effective radius of ash in the volcanic cloud decreased from about 8 μm to about 4 μm.

Journal of Geophysical Research D: Atmospheres↗