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USGS2026

Roadway runoff induced acute mortality in juvenile coho salmon during spring storm events

Extensive mortalities of adult coho salmon ( Oncorhynchus kisutch ), often called “Urban Runoff Mortality Syndrome” (URMS), have been documented during the fall in creeks where water quality has been degraded by roadway runoff. The primary cause of mortality is 6PPD-quinone (6PPDQ; N -(1,3-dimethylbutyl)- N ′-phenyl- p -phenylenediamine quinone)–an ozone transformation product that forms on all vehicle tires. Laboratory studies have shown that juvenile coho salmon are highly sensitive to 6PPDQ exposure. Unlike adults, juveniles reside in impacted watersheds year-round, including during the spring when 6PPDQ concentrations can frequently exceed lethal thresholds during storms. To assess the potential incidence of URMS in springtime rearing habitats for juvenile coho salmon, we conducted a paired water quality and toxicology study at Miller Creek, a runoff-impacted watershed in Normandy Park, WA, USA. Using a small field facility, three naïve groups of juvenile coho salmon ( N = 720) were exposed to either creek water or groundwater ( N = 120 per treatment per storm), across three spring storms while comparing water quality and mortality end points. In creek water during exposures, peak 6PPDQ concentrations reached 73–110 ng/L, exceeding reported median lethal concentrations (LC 50 ) for coho salmon. Over each 24–73 h storm exposure period, ∼80% of Miller Creek-exposed juvenile salmon died. No mortality occurred among control fish exposed to groundwater. These results indicate previously unidentified mortality risks for juvenile life stages of coho salmon during spring storms, suggesting substantial and year-round water quality impediments to coho salmon health and recovery across roadway runoff-impacted spawning, rearing, and migratory habitats.

Washington↗

USGS2024

Analysis of factors affecting plume remediation in a sole-source aquifer system, southeastern Nassau County, New York

Several plumes of dissolved, chlorinated solvents, including trichloroethylene, have been identified in a sole-source aquifer near the former Northrop Grumman Bethpage Facility and Naval Weapons Industrial Reserve Plant sites in southeastern Nassau County, New York. Past investigations have documented that the groundwater contamination originated from this industrial area and now extends to the south, in the direction of groundwater flow. The intermixed plumes are commonly referred to as the “Navy Grumman groundwater plume.” Detailed groundwater-flow modeling was needed for the New York State Department of Environmental Conservation (NYSDEC) to evaluate design options necessary for the construction, operation, optimization, maintenance, and monitoring of a groundwater extraction and treatment cleanup plan selected in a December 2019 Amended Record of Decision by the NYSDEC to comprehensively address these plumes. Consequently, the NYSDEC began a cooperative study with the U.S. Geological Survey in 2020 to better understand the local hydrogeologic framework using two independent approaches to characterize aquifer heterogeneity and update an existing regional groundwater-flow model to provide transient boundary conditions for new inset groundwater-flow models of the plume area. We developed these detailed inset models for the two independent aquifer characterizations using history-matching techniques coupled with a novel approach to risk-based management optimization of the remedial design. We also used the updated regional model to assess this optimized groundwater extraction and treatment design for potential saltwater intrusion. The ensembles of parameters resulting from history matching provided a platform with which to evaluate capture by water-supply and remedial wells using particle-tracking techniques. Using the ensemble to select a risk stance, we performed multiobjective optimization to identify various configurations of remedial pumping that are consistent with external constraints and that favor potentially competing objectives. Multiple solutions provide tradeoffs that NYSDEC can consider. In general, pumping redistribution may help to prevent further contamination migration downgradient. These and other study results are intended to support decisions for the remedial design focused on the local area encompassing the full extent of the Navy Grumman groundwater plume.

New York↗

USGS2026

Distributed faulting of the northern West Napa Fault Zone in Napa Valley, California

Mapped surface ruptures from the 24 August 2014 M w 6.0 South Napa earthquake in the Napa Valley, California, show a 2‐km‐wide zone of distributed faulting in the southern and central West Napa fault zone (WNFZ). In the northern WNFZ at Hendry Winery (HW), however, the mapped 2014 surface ruptures encompass an ∼100‐m‐wide zone, implying significant narrowing of the near‐surface fault zone to the north. We present a tomographic shear‐wave velocity ( ⁠⁠ V S ) model and guided‐wave data that indicate the northern WNFZ is at least 400‐m wide, with multiple near‐surface fault traces. Our V S model shows that the 2014 surface ruptures are underlain by discrete low‐velocity zones (LVZs), and coincident guided‐wave data show that the LVZs carry fault‐zone guided waves. If nearby (<500 m) mapped faults to the east of HW are part of the WNFZ, the entire WNFZ is more than 1 km wide in the northern Napa Valley. WNFZ guided waves travel up to 38% slower than S body waves, and low‐strain guided‐wave shaking is up to five times stronger than the associated body‐wave shaking. Our data suggest that guided waves, traveling along distributed faults, may result in an increased shaking hazard over a 1‐km‐wide area of the northern Napa Valley during future significant earthquakes. In places, the 2014 surface ruptures were difficult to find one year after the earthquake, and paleoseismic trenching showed only weak evidence for faulting, which may not have been identified in trenches if the locations of the 2014 surface ruptures had not been previously mapped ( Prentice et al. , 2015 ). Guided‐wave and V S tomography data, however, show strong evidence for faulting beneath the 2014 surface ruptures and at locations to the east. Although paleoseismic trenching is the gold standard for identifying near‐surface faulting, methods such as peak ground velocities of guided waves may better identify immature near‐surface fault traces.

California↗

USGS1999

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado↗

USGS1989

An investigation of shallow ground-water quality near East Fork Poplar Creek, Oak Ridge, Tennessee

Alluvial soils and fill materials in and near the floodplain of East Fork Poplar Creek in Oak Ridge, Tennessee, are contaminated with various trace metals (primarily mercury), organic compounds, and radionuclides that were lost to the stream as a result of past operations at the Y-12 Plant, a nuclear-processing facility located within the U.S. Department of Energy’s Oak Ridge Reservation. Observation wells were installed in the shallow (above bedrock) aquifer in and near the floodplain of East Fork Poplar Creek and water-quality samples were collected to determine if contaminants found in the soils and fill are also present in the shallow ground water. The shallow aquifer in the East Fork Poplar Creek flood plain consists primarily of alluvial silt and clay with lesser amounts of sand and gravel. Thickness of the shallow aquifer ranges from essentially zero to as much as 20 feet. A silty-clay glei horizon is present between the base of the alluvium and the top of bedrock at most flood-plain locations and, where present, likely impedes downward ground-water movement. Water in the shallow aquifer near East Fork Poplar Creek occurs under water-table conditions. Recharge to the shallow aquifer is principally from precipitation, and discharge is through springs and seeps to East Fork Poplar Creek and its tributaries. During spring, summer; and fall, evapotranspiration also accounts for the removal of water in storage in the shallow aquifer. Water levels in the shallow aquifer fluctuate seasonally in response to variations in recharge and evapotranspiration. Generally, the depth to water in the observation wells ranged from about 1 to 4 feet below land surface in late winter, and from about 2 to 7 feet below land surface in late fall. During extremely dry periods, the water table recedes below the top of bedrock in some flood-plain areas, possibly causing East Fork Poplar Creek to lose water to the shallow aquifer along some reaches. Contaminants found in water samples collected from several of the observation wells in concentrations (total and (or) total-recoverable) which equaled or exceeded drinking-water standards established by the U.S. Environmental Protection Agency are antimony, chromium, lead, mercury, selenium, total phenols, and strontium-90. Total and dissolved uranium concentrations exceeded 1.0 microgram per liter in samples from nearly 70 percent of the wells in the East Fork Poplar Creek flood plain. Organic compounds that were identified in low concentrations in samples from a few wells in the flood plain are: Arochlor 1260, benzo(a)anthracene, benzo(b)fluoranthene, chrysene, 3,3-dichlorobenzidine, di-n-butylphthalate, N-nitrosodiphenylamine, and pyrene. Water from one well in the East Fork Poplar Creek flood plain at a contaminated fill site contained 37and 8 micrograms per liter of trichloroethene and trans-1,2-dichloroethene, respectively. Comparison of the results of total and (or) total-recoverable trace-metal determinations with those from dissolved determinations demonstrates that elevated concentrations of these substances in water collected from several of the wells in the East Fork Poplar Creek flood plain resulted from sorption of trace metals (and possibly organic compounds and radionuclides) by fine sediment suspended in the samples. The occurrence of contaminated sediment in these samples is suspected to be the result of borehole contamination during well installation.

Tennessee↗

USGS2024

Uncertainty in ground-motion-to-intensity conversions significantly affects earthquake early warning alert regions

We examine how the choice of ground‐motion‐to‐intensity conversion equations (GMICEs) in earthquake early warning (EEW) systems affects resulting alert regions. We find that existing GMICEs can underestimate observed shaking at short rupture distances or overestimate the extent of low‐intensity shaking. Updated GMICEs that remove these biases would improve the accuracy of alert regions for the ShakeAlert EEW system for the West Coast of the United States. ShakeAlert uses ground‐motion prediction equations (GMPEs), which calculate spatial distributions of peak ground acceleration (PGA) and peak ground velocity (PGV) from earthquake source estimates, combined with GMICEs to translate GMPE output into modified Mercalli intensity (MMI). We find significant epistemic uncertainty in alert distances; near‐source MMI estimates from different GMICEs can differ by over 1 MMI unit, and MMI extents used for public EEW alerts can differ by hundreds of kilometers for larger magnitude earthquakes ( M ∼6.5+). We use a catalog of “Did You Feel It?” shaking reports to evaluate how well GMICEs predict observed shaking. Our preferred GMICE is the one that computes MMI using PGV for high intensities and transitions to using PGA for nondamaging intensities. These results motivate updating GMICE relationships more generally, including in ShakeMap applications.

The Seismic Record↗

USGS2026

Forecasting volcanic activity in Germany—A multi-criteria approach

Igneous activity, including shallow intrusions and volcanism, has the potential to disrupt underground critical infrastructure. Notably, future underground infrastructure projects like high-level radioactive waste repositories must be sited in areas of extremely low disruption probability by igneous activity. In Germany, according to the Repository Site Selection Act of 2017 (Standortauswahlgesetz, or StandAG), areas in which Quaternary volcanism is either present or future volcanic activity is expected within the next 1 million years (m.y.) must be excluded from the site selection process. Although the locations of regions with Quaternary volcanism are reasonably well known in Germany, forecasting potential igneous activity at intraplate volcanic fields is challenging, as many processes and their interactions control the spatial distribution of volcanic centers. Here, a semi-quantitative, multi-criteria approach is proposed for a regional evaluation of the relative potential of future igneous activity in Germany. A variety of geoscientific indicators are used, including seismic anomalies in Earth’s mantle, gravity data, tectonic activity, sutures, ground motion, earthquakes, mantle degassing centers, and geochronological data of volcanic rocks. The indicators describe the sequence of processes from potential melt generation in Earth’s mantle, through ascent and accumulation of melt within the lithosphere, to eruption at Earth’s surface. In total, 15 out of 30 proposed geoscientific indicators are selected and quantified using 20 total assigned parameters. Defined threshold values are used to spatially delimit relevant parameter properties to focus on areas with higher potential of future magmatic activity. To consider uncertainties of parameters and their underlying processes, which are usually more spatially extensive below ground, buffer zones are defined in which values of relevance decrease with increasing distance from the initial lateral shape of a parameter. Normalized parameters are combined into an index, whose spatial value distribution is used to differentiate the relative potential of future igneous activity (within the next 1 m.y.). The sensitivity of the results is shown by varying the weighting factors for the relevant parameters in country-wide index maps. Thereby, profiles illustrate the distribution of the resulting index values and respective index fractions of various parameters. Different index maps for the relative potential of future igneous activity are presented and can be used for hazard assessments.

Professional Paper↗

USGS2026

Re-examining the growing degree day minimum for grass carp spawning initiation in Lake Erie: Have we missed the mark?

Understanding the timing of life history processes of invasive fish species, such as adult aggregations during spawning, allows natural resource managers to optimize targeted population control efforts. Temperature-based estimates of the timing of spawning initiation for grass carp ( Ctenopharyngodon idella ) exist from its native range, but have not previously been developed for grass carp reproduction in its invaded range in the Laurentian Great Lakes of North America. We accounted for differences among methods across studies and calculated cumulative growing degree days (GDD) for the dates of grass carp egg capture in Lake Erie tributaries (Sandusky, Maumee, and Huron rivers) during 2015–2024 and compared these values to the existing GDD base 15°C requirement estimate from the native range (633 GDD–15°C). The earliest egg detection in Lake Erie (Sandusky River) was 19 GDD–15°C or 361 GDD–5°C (latest egg detection was 2285 GDD–5°C from the Sandusky River), indicating that spawning was initiated up to 25 days earlier than would be predicted by the native range GDD. Moreover, spawning in Lake Erie tributaries occurred earlier than predicted for 58% of spawning events examined based on the native range GDD. The GDD values for spawning initiation in Lake Erie tributaries can be used to refine the timing of control efforts targeting pre-spawn and spawning adult fish, inform the timing of egg sampling, and provide linkages to existing early life stage models to infer the length of the growing season available for age-0 fish to reassess tributary suitability.

Lake Erie, Maumee, River, Sandusky river↗

USGS2025

Base-flow sampling to enhance understanding of the groundwater flow component of nitrogen loading in small watersheds draining into Long Island Sound

Excessive nitrogen discharge is a major concern for the Long Island Sound. Programs have been implemented to reduce point sources of nitrogen to the sound, but little is known about the nonpoint sources. This study aims to better understand the current groundwater contributions of nitrogen from nonpoint sources in the Long Island Sound watershed. During the spring and summer of 2022, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, collected water-quality samples to analyze nutrients (nitrogen and phosphorus), chloride, and bromide at 45 stations in the Long Island Sound watershed in Connecticut, New York, and Rhode Island. The stations were in small drainage watersheds (5 to 30 square kilometers) in the southern part of the Long Island Sound watershed. During two separate synoptic sampling events, water-quality samples and instantaneous streamflow measurements were collected under base-flow conditions (where the streamflow is dominated by groundwater inputs rather than overland flow or runoff flow). One sampling event was in the nongrowing season (April 24–25, 2022), and the other was in the growing season (June 30–July 1, 2022). To calculate instantaneous nitrogen loads and yields, streamflow was measured at the time of sample collection. Nitrogen concentrations, loads, and yields varied among sampling stations and by season. Total filtered nitrogen concentrations were generally lower in the nongrowing season (from less than 0.14 to 1.9 milligrams per liter) than in the growing season (from less than 0.23 to 3.0 milligrams per liter). Nitrate plus nitrite concentrations showed little variation between the nongrowing and growing seasons. Unfiltered ammonia plus organic nitrogen concentrations were generally lower in the nongrowing season (from less than 0.07 to 0.83 milligram per liter) than in the growing season (from 0.11 to 0.98 milligram per liter). In contrast, total filtered and unfiltered nitrogen loads and yields were higher in the nongrowing season than during the growing season, likely because streamflows were higher during the nongrowing season. Total unfiltered nitrogen yields during the nongrowing season ranged from less than 0.15 to 5.0 kilograms per square kilometer per day. Total unfiltered nitrogen yields during the growing season ranged from less than 0.12 to 2.5 kilograms per square kilometer per day. Total filtered nitrogen yields during the nongrowing season ranged from less than 0.13 to 5.2 kilograms per square kilometer per day. Total filtered nitrogen yields during the growing season ranged from less than 0.06 to 2.5 kilograms per square kilometer per day.

Connecticut, New York, Rhode Island↗

USGS2025

An exploration of the relative influence of physical models for Omori’s law

Omori’s law states that the rate of aftershocks decays as a function of inverse time. There are multiple physical explanations that we reduce into a nonlinear mixed effects relation of three terms: (1) a Rate/State expression that can account for static/dynamic and viscoelastic triggering caused directly by the mainshock, (2) a fluid diffusion triggering term, and (3) a randomized secondary triggering (cascade) term. We fit free physical-model parameters to an observed aftershock sequence through two nonlinear regression methods to find the relative contributions of physics-based models in an observed aftershock sequence. Results from both methods show that Rate/State models overpredict aftershock rates by ∼0–30%. Secondary aftershocks cause a net negative contribution (seismicity rate reduction that corrects overprediction by other terms) ranging between ∼0 and 30%. All regression solutions yield negative secondary triggering contributions without being guided to do so. A physical explanation for this is that aftershock occurrence relieves stress from the crust, ultimately causing the sequence to extinguish itself. Fluid diffusion triggering contributions range from ∼0 to 20%. Diffusion processes are observed to be shorter in time than the full duration of an aftershock sequence and they are also spatially limited, diminishing their influence. Our results apply to an aftershock decay curve from the 2016 Central Apennines earthquake sequence, meaning that our specific results may not be general. Our primary conclusion is that any one physical model cannot alone fit the observed sequence as well as the combination of three we investigated.

Frontiers in Earth Science↗

USGS2000

Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington

Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.

Washington↗

USGS2021

Geology, mineralogy, and cassiterite geochronology of the Ayawilca Zn-Pb-Ag-In-Sn-Cu deposit, Pasco, Peru

The Ayawilca deposit in Pasco, Peru, represents the most significant recent base-metal discovery in the central Andes and one of the largest undeveloped In resources globally. As of 2018, it hosts an 11.7 Mt indicated resource grading 6.9% Zn, 0.16% Pb, 15 g/t Ag, and 84 g/t In, an additional 45.0 Mt inferred resource grading 5.6% Zn, 0.23% Pb, 17 g/t Ag, and 67 g/t In, and a separate Sn-Cu-Ag inferred resource of 14.5 Mt grading 0.63% Sn, 0.21% Cu, and 18 g/t Ag. Newly obtained U–Pb dates for cassiterite by LA-ICP-MS (22.77 ± 0.41 and 23.05 ± 2.06 Ma) assign the Ayawilca deposit to the Miocene polymetallic belt of central Peru. The polymetallic mineralization occurs as up to 70-m-thick mantos hosted by carbonate rocks of the Late Triassic to Early Jurassic Pucará Group, and subordinately, as steeply dipping veins hosted by rocks of the Pucará Group and overlying Cretaceous sandstones-siltstones of the Goyllarisquizga Group. Relicts of a distal retrograde magnesian skarn and cassiterite (stage pre-A) were identified in the deepest mantos. The volumetrically most important mineralization at Ayawilca comprises a low-sulfidation assemblage (stage A) with quartz, pyrrhotite, arsenopyrite, chalcopyrite, Fe-rich sphalerite, and traces of stannite and herzenbergite. Stage A sphalerite records progressive Fe depletion, from 33 to 10 mol% FeS, which is compatible with the observed transition from low- to a subsequent intermediate-sulfidation stage (B) marked by the crystallization of abundant pyrite and marcasite. Finally, during a later intermediate-sulfidation stage (C) sphalerite (up to 11 mol% FeS), galena, native bismuth, Cu-Pb-Ag sulfosalts, siderite, Mn-Fe carbonates, kaolinite, dickite, and sericite were deposited. This paragenetic evolution shows striking similarities with that at the Cerro de Pasco Cordilleran-type polymetallic deposit, even if at Ayawilca stage C did not reach high-sulfidation conditions. The occurrence of an early retrograde skarn assemblage suggests that the manto bodies at Ayawilca formed at the transition between distal skarn and skarn-free (Cordilleran-type) carbonate-replacement mineralization. Mineral assemblages define a T- f S 2 evolutionary path close to the pyrrhotite-pyrite boundary. Buffering of hydrothermal fluids by underlying Devonian carbonaceous phyllites of the Excelsior Group imposed highly reduced conditions during stage A mineralization (log f O 2 < − 30 atm). The low f O 2 favored efficient Sn mobility during stages pre-A and A, in contrast to other known ore deposits in the polymetallic belt of central Peru, in which the occurrence of Sn minerals is minor. Subsequent cooling, progressive sealing of vein walls, and decreasing buffering potential of the host rocks promoted the shift from low- (stage A) to intermediate-sulfidation (stages B and C) states. LA-ICP-MS analyses reveal significant In contents in Fe-rich sphalerite (up to 1.7 wt%), stannite (up to 1908 ppm), and chalcopyrite (up to 1185 ppm). The highest In content was found in stage A sphalerite that precipitated along with chalcopyrite and stannite, thus pointing to the early, low-sulfidation assemblage as prospective for this high-tech metal in similar mineral systems. Indium was likely incorporated into the sphalerite crystal lattice via Cu + + In 3+ ↔ 2 Zn 2+ and (Sn, Ge) 4+ + (Ga, In) 3+ + (Cu + Ag) + ↔ 4 Zn 2+ coupled substitutions. Indium incorporation mechanisms into the stannite and chalcopyrite crystal lattices remain unclear.

Pasco↗

USGS2025

Update of the 2008 provisional Enhanced Geothermal Systems (EGS) assessment for the Great Basin, USA

In response to the Energy Act of 2020, the U.S. Geological Survey (USGS) is updating the Enhanced Geothermal Systems (EGS) resource assessment for the Great Basin, USA. The previous 2008 provisional assessment estimated how much electricity could be generated from EGS resources of the western United States using models of electric-grade heat, models of heat extraction over time, and estimates of how much rock might be stimulated to produce viable amounts of heat. Herein, a similar conceptual strategy is applied, using updated models of heat extraction as a function of fracture spacing and well distance. Previously used reservoir heat delivery models are updated to have a dependence on fracture and well spacing, potentially improving future estimates of EGS resources as ongoing research provides a better understanding about the success of reservoir stimulation as a function of geology and location. For a range of well distances (250-1000 m) and fracture spacings (1-50 m), heat extraction efficiency ranges from 25-62%, demonstrating the importance of accounting for the most likely results of proven viable fracturing technologies. Although fracturing is important, the biggest uncertainty by far in estimating the EGS resource for the Great Basin is estimating which geologic units at what depths can be stimulated sufficiently to produce geothermal energy economically and efficiently. Uncertainties in these factors yield estimates that range over two orders of magnitude with an upper limit of ~174 terawatts-thermal (TWth) produced for 30 years from the upper 7 km of the crust. This upper limit would require significant technological advances to access most of the electric-grade resource across the Great Basin. Assuming that 1% of this estimate will be accessible in the next few decades gives a resource estimate similar to that made in the 2008 provisional assessment. These estimated EGS heat extraction rates far exceed ( greater than 100x) the natural geothermal heat production rate, thus geothermal electricity production at these rates might not be sustainable unless heat is also recharged from other sources (e.g., excess solar energy when supply exceeds demand). In addition to assessment maps and cumulative estimates, the new models of fractured reservoirs developed herein can be used to estimate steady power production given a set of fractures and well spacing, and estimates can be made for setback distances to ensure no thermal interference with nearby powerplants.

Arizona, California, Idaho, Nevada, Oregon, Utah↗

USGS2026

Groundwater source water assessment area delineation of public supply wells in the Treasure Valley, western Idaho

The Idaho Department of Environmental Quality (IDEQ) is responsible for assessing the source water for public water supply systems including the delineation of source water assessment areas for wells, which are defined as the subsurface areas contributing water to a well during a period of time. Part of the IDEQ assessment plan is to update source water assessments over time. The U.S. Geological Survey (USGS) developed a new groundwater-flow model for part of the western Snake River Plain aquifer in southwestern Idaho. This groundwater- flow model provided a new opportunity for IDEQ to update source water assessment for public water supply wells within the model boundary. The USGS, in cooperation with IDEQ, used the USGS Treasure Valley Groundwater Flow Model along with a MODPATH particle tracking post-processing program to reassess public-water supply source water assessment areas. The USGS created an automated script that requests a well location, depth, and pumpage rate, and then incorporates that information into the Treasure Valley Groundwater Flow Model combined with the MODPATH model to create 3-, 6-, and 10-year time of travel zones that are output to a geographic information system shapefile. The TVSWA_Delineator script provides a fast, transparent tool for IDEQ to reassess or create new public-water supply source water assessment area delineations based on new and updated information and is available as a Python script and a Windows executable with the compiled script and all necessary components. TVSWA_Delineator utilizes a quadtree approach to rediscretize the Treasure Valley Groundwater Flow Model grid around the pumping well location from 1-mile cell lengths telescoped down to 1/16 mile. This rediscretization increases the source water assessment area delineation resolution near the pumping well and minimizes the effect of weak sinks in the MODPATH model. The stress inputs for each month of the final 10 years (2006 to 2015) of the Treasure Valley Groundwater Flow model historical simulation were averaged for the particle tracking analysis. The MODPATH model used backwards tracking of particles released at each stress period to create the source water assessment area delineations. This report documents the creation of the TVSWA_Delineator Python script, including adaptations made to the Treasure Valley Groundwater Flow Model, creation of a companion MODPATH model, and post-processing results to provide source water assessment areas.

Idaho↗

USGS2026

Relating glassy rind thicknesses to ambient air temperatures at the Lost Jim flow field in the Imuruk Lake volcanic field, Alaska

The Lost Jim flow field, in the Imuruk Lake volcanic field, Alaska, extends west ~34 km from a single vent, crossing subarctic tundra and currently touches several lakes and streams. The weighted mean of five 36Cl cosmogenic exposure ages from the Lost Jim pāhoehoe flow is 7.73 ± 0.37 ka, indicating this eruption occurred substantially after the eruption of the underlying Camille flow, which was emplaced at 39.7 ± 1.3 ka. Paleoclimate records indicate the period when the Lost Jim flow field was emplaced was after deglaciation, and the climate was similar to today. We propose that the emplacement of lava in these cold subarctic conditions can lead to faster cooling of the lava surface compared to lava emplaced in warmer locations such as mid- latitude cold deserts. Glass abundance in the outermost rinds at the Lost Jim flow field was on average 74 % with 6.4 mm thick rims, compared to 60 % with 2.9 mm rims for cold mid-latitude desert samples. We interpret increased glass content as a proxy for rapid cooling likely occurring partly during winter. Glassiness values varied less across vent, margin, and mid-flow locations when compared to the mid-latitude flows suggesting the Lost Jim flow field was broadly impacted by the subarctic climate as opposed to responding to local microclimates. Our results indicate that lava glassiness may be a useful environmental indicator of cooler (in this case subarctic) conditions.

Alaska↗

USGS2025

Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho

The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.

Idaho↗

USGS2024

The advantages of electric-grade heat storage in long closed-loop wells

Though long (e.g., tens of kilometers) closed-loop geothermal wells are under consideration for the extraction of subsurface heat, these wells might also serve as an efficient energy storage mechanism for electricity generation. Using a semi-analytic model solution, the potential for electric-grade heat storage as a function of ambient temperature (e.g., corresponds to depth of loop), well length, well diameter, and flow rate is evaluated. The following simplified cases for comparison of standard closed loop operation with energy storage operation were considered: [1] constant flow rate and constant temperature (90 °C) injection to represent the standard closed-loop base-case; and [2] constant flow rate and annual cycle sinusoidal temperature (90-150 °C) to represent seasonal (summer) charging while solar resources are peak. Initial temperatures for all scenarios considered herein are a uniform 175 °C. Electric-grade heat is assumed to be delivered whenever temperatures at the extraction point exceed 90 °C. For calculation purposes only, if temperature falls below 100 °C, it is assumed that heat delivered is sub-economic, so no electricity would be produced. For all scenarios, temperatures at the extraction well asymptotically approach the flow-weighted average injection temperature, but energy storage scenarios exhibited a damped time-varying signal that diminishes in magnitude with length of the loop. The asymptotic approach depends on initial temperatures in the rock and the heat extraction rate (a function of well diameter and flowrate). This analysis demonstrates that shorter closed loops can produce more electricity over time than longer closed-loops previously proposed for electricity production over typical engineering design lifetimes (e.g., 30 years). Although only a high-temperature scenario is considered herein, rock that is initially below boiling temperature would not host a standard closed-loop resource, but injection of hot water seasonally would asymptotically heat this low-temperature system to temperatures capable of electricity production. In other words, regardless of initial temperatures, closed loops could be used to store electricity with no critical minerals in the geothermal battery.

Conference Paper↗

USGS2024

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine↗