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101 records · Page 6Linked to original sources

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Airborne geophysics for geologic mapping of critical mineral systems in the United States southern midcontinent

The increased demand for clean energy technology and a significant reliance on foreign supply chains have given impetus to understanding critical mineral systems and locating potential resources within the United States. At least thirteen critical mineral-bearing systems have been identified throughout the U.S. southern Midcontinent (Hofstra and Kreiner, 2020) but much of the region’s geologic framework is concealed by vegetation and sedimentary cover that hinder traditional geologic mapping efforts. Airborne geophysical data provide an effective way to overcome these obstacles and to provide additional insight into the deeper structures that underlie shallow mineralization. However, legacy airborne magnetic and radiometric data were collected using now-outdated instruments and methods, inconsistent survey parameters, and large flight-line spacings resulting in low-resolution data that present challenges to regional-scale study and interpretation. Over the last decade, the U.S. Geological Survey Earth Mapping Resources Initiative (EMRI) and National Cooperative Geologic Mapping Program have conducted a series of high-resolution airborne magnetic and radiometric surveys across the southern Midcontinent (Fig. 1) as part of an effort to improve understanding of the geophysical framework and natural resource potential in the region. These surveys are designed using modern survey methods and instruments with consistent parameters for flight-line spacing and flight height relative to magnetic sources. The EMRI airborne surveys are planned in collaboration with State geological surveys based on focus areas (Dicken et al., 2022) according to the presence of or potential for critical mineral deposits. High-resolution airborne magnetic and radiometric data cover focus areas such as the southeast Missouri iron metallogenic province and South-Central iron-oxide-apatite (IOA) – iron-oxide-copper-gold (IOCG) province, the Magnet Cove alkaline-carbonatite complex, the Midwest Permian ultramafic dike district, the Illinois-Kentucky fluorspar district, and several Mississippi Valley-type lead-zinc deposits and districts (Fig. 1). These focus areas represent known deposits or prospective host systems of critical minerals including rare earth elements (REEs), platinum-group elements (PGEs), cobalt, lithium, fluorspar, niobium, titanium, vanadium, lead, zinc, gallium, germanium, and many more. Other significant geologic and geophysical features covered include the Reelfoot rift, the New Madrid seismic zone, the Illinois basin, the Arkoma basin, the South-Central magnetic lineament, and the Kentucky-Tennessee magnetic anomaly (Fig. 1). This presentation focuses on new airborne magnetic and radiometric data with continuous coverage across parts of six states, preliminary interpretations, examples of geologic mapping applications, and discussion of newly discovered magnetic anomalies and follow-up investigations.

Conference Paper

Variable partitioning of lithium in rhyolitic melt during decompression and ascent

The partitioning behavior of Li in magmatic systems is increasingly being investigated due to the economic importance of Li in the transition to sustainable energy resources (e.g., batteries). However, at upper crustal pressures, it remains uncertain whether Li preferentially partitions into the vapor or liquid (brine) phase or remains in the silicate melt. This complicates our ability to determine where Li resides—silicate melt, minerals, or fluid phase—upon eruption, a crucial factor for understanding its postdepositional movement and concentration into a brine or volcano-sedimentary deposit. Here, we present a novel investigation into the behavior of Li within natural evolved melts during continuous magma decompression and ascent using melt embayments (open melt inclusions). Mineral-hosted melt embayments preserve records of the evolving composition of the exterior melt, including degassing pathways and ascent timescales, when paired with appropriate diffusion coefficients. Lithium concentration profiles were measured in quartz-hosted melt embayments from the rapidly quenched eruptive phases of five rhyolitic, caldera-forming eruptions to investigate the behavior of Li during magma decompression and ascent, where vapor partitioning and ascent dynamics were previously established by investigating H 2 O and CO 2 profiles. We find that in four systems, embayments contain lower interior Li concentrations than the coerupted melt inclusions; the fifth system contains the same Li concentrations in embayments and melt inclusions. However, many of these embayments contain gradients, with 84 % preserving Li enrichment near the melt-bubble interface, as compared to their interior concentration. We interpret these characteristics to represent two distinct stages of Li partitioning during magma decompression and ascent, in contrast to existing literature that proposes only one type of partitioning behavior. The first stage is interpreted as melt depletion of Li, likely driven by partitioning into an exsolved supercritical fluid phase, supported by the strong correlation between the extent of Li depletion and Cl concentration in the melt, as well as the decompression rate. This behavior then fundamentally shifts, where Li reenriches in the melt, postulated to be driven by the unmixing of the supercritical fluid phase at shallow pressures. For the one system that did not develop Li gradients through decompression, we attribute this to the lower values of Na and Cl in the melt, potentially inhibiting the partitioning of Li into a fluid phase. Importantly, the behavior of Li during decompression is not consistent within or between volcanic centers, highlighting the need for systematic experimental investigation in variable composition melts at pressures relevant to conduit dynamics. This knowledge would improve our ability to model Li profiles to understand magma decompression, and predict where Li resides (e.g., stored in volcanic glass, gas, or crystals) upon eruption prior to any later extraction.

Economic Geology

Effects of a low-lipid diet on the gut microbiome and head kidney transcriptome of juvenile Chinook Salmon

Objective Pacific salmon Oncorhynchus spp. reared in production hatcheries are typically fed high-lipid, energy-dense diets to achieve large size and high body condition prior to release. In contrast, juveniles in natural environments tend to consume low-lipid, high-protein diets, and fish reared for research or conservation purposes are sometimes fed diets that are formulated to mimic natural diets and promote wild-like phenotypes. Understanding how these alternative diets affect fish health beyond growth and body condition could ultimately contribute to improving hatchery fish fitness. Methods In this work, we evaluated changes in the fecal microbiome and gene expression of juvenile Chinook Salmon O. tshawytscha on a standard high-lipid hatchery diet versus a low-lipid diet formulated to mimic the nutrition profile of natural-origin fish. To evaluate the time scale at which diet alters the fecal microbiome, we collected longitudinal samples over a 12-week period and switched the diets of a subset of fish twice during the experiment. We used 16S ribosomal RNA gene amplicon sequencing to characterize fecal microbiome differences between fish on the two diets as well as hatchery-reared fish at a production hatchery, hatchery fish that had been captured after release into a stream, and natural-origin, stream-reared fish of similar ages. Additionally, we conducted RNA sequencing on head kidney samples from laboratory-reared fish to evaluate changes in gene expression in this important immune organ. Results We found that the low-lipid diet and the hatchery diet resulted in microbiomes that differed from the microbiome of natural-origin fish and from each other and that diet-driven changes to the microbiome could occur in under 14 d. The low-lipid diet did not result in a microbiome that resembled the microbiome of naturally produced fish. Instead, the low-lipid diet resulted in a microbiome community that was distinct from those of fish reared on the hatchery diet and fish sampled from the wild. The RNA sequencing results indicated differential enrichment of pathways related to immunity, metabolism, and hormone synthesis between fish that were fed the two experimental diets. Conclusions The results suggest that additional environmental factors influence the microbiome more strongly than diet formulation or that the low-lipid diet has a smaller effect on the microbiome than a natural, ­invertebrate-based diet. Given that the gut microbiome and systemic immune function contribute significantly to disease resistance, our findings highlight the importance of understanding how diets fed to fish in captivity may affect fish health beyond growth and body condition metrics.

Journal of Aquatic Animal Health

The Great Lakes Geologic Mapping Coalition—Working collaboratively to understand the geology of the Great Lakes Region

Introduction The Great Lakes Geologic Mapping Coalition (GLGMC), commonly referred to as the “Coalition,” is a partnership between the U.S. Geological Survey (USGS), the U.S. States of Illinois, Indiana, Michigan, Minnesota, New York, Ohio, Pennsylvania, and Wisconsin and the Canadian province of Ontario. The member States receive funding for geologic mapping work from the USGS National Cooperative Geologic Mapping Program (NCGMP), whereas Ontario participates as a nonfunded partner. The mission of the GLGMC is to produce three-dimensional (3D) geologic maps that depict unconsolidated sediments and near-surface bedrock in the Great Lakes region of North America. Geologic maps are the basis of most earth science investigations and help support resource exploration (energy, minerals, groundwater), natural hazard mitigation, infrastructure development, and land-use planning, all of which can be used to advance economic development and strengthen national security in the Great Lakes region. During the last few million years, the Great Lakes region has experienced repeated glacial advances and retreats, leaving behind extensive sediments, abundant natural resources, and widespread effects on the underlying bedrock geology (Swezey and others, 2022). Linked by shared histories of past glaciations, industrial agriculture, and legacy automotive, coal, steel, and manufacturing industries, the GLGMC member States collaborate to improve the understanding of the 3D distribution of the sediments overlying the region’s bedrock (fig. 1). Developing a comprehensive subsurface 3D framework of this glaciated terrain can provide earth science data to policymakers at all levels. These insights facilitate informed decisions on the exploration, use, and protection of vital resources, such as critical minerals, industrial materials, and aquifers, thereby supporting economic prosperity and the well-being of the citizens of this region. Since its inception in 1998, the Coalition has completed more than 100 geologic mapping projects across the Great Lakes region. Each project aims to deliver geologic maps, 3D datasets, and other information that improves understanding of the geology of the Great Lakes region, with an emphasis on economic and water resources. Key deliverables include 3D geologic maps and models typically portraying sediment thickness, often derived from top-of-bedrock and borehole data. These products are developed through a combination of fieldwork, subsurface modeling, and the collection and analysis of rock and sediment cores. To support Coalition goals, member States collaborate with scientists working on related STATEMAP, EDMAP, and FEDMAP projects. Coalition scientists also engage with Tribal Nations in the Great Lakes region to ensure that Tribal interests pertaining to Coalition work are addressed. Through this collaboration, the Coalition unites the efforts of State, Federal, and Tribal Nation stakeholders to advance geologic data production and enhance understanding of the geologic resources of the Great Lakes region.

Illinois, Indiana, Michigan, Minnesota, New York,

Conventional hydrothermal power-producing systems of the Great Basin, USA

As part of the update to the electric-grade conventional hydrothermal assessment of the Great Basin, USA, Monte Carlo analyses of identified resources within explored regions will be performed to make estimates of discovered resources and associated uncertainty. Analyses use conditional statistics where estimates are conditioned upon a hydrothermal favorability map, allowing for the likelihood that more resources exist in regions of higher hydrothermal favorability. For these analyses, a dataset of identified hydrothermal systems is compiled, and the new compilation is described herein. Recognizing that a single hydrothermal system may be developed with multiple power plants, and that the hydrothermal upflow zone may be several kilometers across with many measurements characterizing a single hydrothermal system, a procedure was developed and employed to create clusters of points (power plants, measurements, etc.) that are associated with a single system, and a new central point was defined as the best estimator of the center of the hydrothermal system. Hydrothermal systems were uniquely identified by grouping electric-grade hydrothermal measurements and operating power plants within a distance of 10 km. Groups that are >10 km apart are assumed to be different electric-grade hydrothermal systems. While 10 km was used as the threshold, most systems were significantly further apart, and most points within groups were typically within 5 km of each other. A well measurement was considered an electric-grade measurement of a hydrothermal system if it had two properties: a measured temperature of >85 °C and evidence of hydrothermal convection. Other points that were added to the dataset are locations of operating powerplants or locations that have been classified as an electric-grade hydrothermal resource by either the U.S Geological Survey (USGS) or the Great Basin Center for Geothermal Energy. After all points are assigned to systems, new points were computed with the goal of identifying the center of the throat of the hydrothermal upflow zone. If operating powerplants exist for a system, then the arithmetic average of all power plant locations is used. Otherwise, if USGS made an estimate, that location is used. In the absence of both powerplants or USGS estimates, the arithmetic average of all electric-grade measurement locations is used. An example is shown of how these newly compiled locations might be ranked for uncertainty analyses, where higher confidence is assumed if measured temperature is higher and there are many supporting measurements indicating an electric-grade resource. In summary, 28 systems have operating power plants, an additional 78 systems are known identified electric-grade hydrothermal resources, and 99 new systems were identified as probable electric-grade systems with varying levels of confidence. These 205 locations are shown as a function of a recent hydrothermal favorability map, conceptually illustrating the conditional statistics that can be used to make estimates of the undiscovered resources of the Great Basin. An accompanying data release provides summaries of developed capacity by system and USGS estimates of likely total capacity and associated uncertainty.

Arizona, California, Idaho, Nevada, Oregon, Utah

Methodology and technical input for the 2025 U.S. List of Critical Minerals—Assessing the potential effects of mineral commodity supply chain disruptions on the U.S. economy

The Secretary of the Interior, acting through the Director of the U.S. Geological Survey, is tasked by section 7002 (“Mineral Security”) of title VII (“Critical Minerals”) of the Energy Act of 2020 (Public Law 116–260, December 27, 2020, 116th Congress) with reviewing and revising the methodology used to evaluate mineral commodity supply risk and the U.S. List of Critical Minerals (LCM) no less than every 3 years. Following two previous LCM assessments, this analysis represents the latest technical input for evaluating each mineral commodity’s supply risk and determining their recommended status on the LCM. We evaluated mineral commodity supply risk using two criteria: (1) an economic effects assessment that quantified the potential effects of various trade disruption scenarios on the U.S. economy, and (2) an examination of whether the mineral commodity’s U.S. supply chain relied on a sole domestic producer that represented a single point of failure. For the first criterion, postdisruption equilibrium quantities and prices for each mineral commodity were calculated based on their price elasticities of supply and demand and the availability of excess production capacity for each yearlong foreign trade disruption scenario. Subsequently, a nonlinear optimization routine was used with detailed economic input-output tables to estimate the potential economic effects on the U.S. economy of over 1,200 scenarios for 84 mineral commodities. After accounting for the probability of each scenario’s occurrence, the overall results are presented in terms of changes in U.S. gross domestic product (GDP) by individual industry and the economy overall. The results, which ranged from a net decrease in U.S. GDP of nearly $4.5 billion to a net increase of $33 million, largely reflect U.S. import dependency and world production concentration. Using the Jenks natural breaks optimization method, a statistical classification technique, we categorized the mineral commodities into several classes based on this overall risk quantification. Mineral commodities with annualized probability-weighted net decreases in U.S. GDP greater than $2 million were recommended for inclusion on the LCM. If a mineral commodity did not meet the threshold for inclusion on the LCM under the first criterion, its domestic supply chain was examined under the second criterion, which recommended a mineral commodity for inclusion on the LCM if there was only a single domestic producer. Ultimately, the two criteria resulted in the recommendation of the addition of six mineral commodities (in descending risk order, potash, silicon, copper, silver, rhenium, and lead) to and the removal of two mineral commodities (arsenic and tellurium) from the LCM. By using an economic effects assessment, the results of this analysis provide a prioritization that can also be compared directly against other risk analyses and the cost of various risk mitigation strategies.

Open-File Report

Multiple-well monitoring site adjacent to the Midway- Sunset and Buena Vista Oil Fields, Kern County, California

Groundwater quality in and around oil fields in the Southern San Joaquin Valley is of interest to many California residents that rely heavily on groundwater for domestic, commercial, and agricultural use. To help assess the effects of historical oil-field activities and natural geologic sources on groundwater near the southwest margins of the Kern County Groundwater Subbasin, a multiple-well monitoring site was installed near the administrative boundary between the Midway-Sunset and Buena Vista Oil Fields in Kern County, California. The installation of the Midway-Sunset Buena Vista multiple-well monitoring site (MSBV) supports regional analysis of the relations of oil and gas sources to groundwater quality by providing information about the geology, hydrology, geophysical properties, and water quality of the alluvial and upper Tulare aquifers in areas where groundwater data were limited. Data collected from the site included drill cuttings, whole core samples, sidewall core samples, mud-gas analysis, borehole geophysical logs, depth to water measurements, and water quality samples. Whole cores were scanned using dual energy computed tomography. Subsamples of selected cores were analyzed for density, porosity, specific retention, and bulk minerology. Thin sections of the subsamples were prepared, photographed, and examined. Two samples were analyzed using scanning electron microscope technology to examine the microporosity of diatomite laden sediment. Instrumentation installed in the wells collect hourly depth to water measurements. Analysis of the data show there is 355 feet of alluvium overlying the Tulare Formation at the well site. The contact between the two formations is an aquitard resulting in a perched aquifer in the alluvium and unconfined aquifer in the Tulare Formation. The alluvium is more heterogenous and finer grained than the Tulare Formation resulting in markedly higher porosity in the alluvium compared to the Tulare Formation. Higher specific retention observed in the alluvium is attributed to the finer grained sediment and greater abundance of reworked diatomite (as represented by opal-CT [cristobalite-tridymite]) compared to the Tulare Formation. Total dissolved solids (TDS) approached or exceeded 10,000 milligrams per liter (mg/L) in the alluvium from approximately 176 to 242 feet below land surface and at the top of the Amnicola clay at approximately 670 feet below land surface within the Tulare Formation. Elevated TDS, chloride, and boron concentrations in the alluvium and on top of the Amnicola clay likely reflect groundwater that is mixed with oil-field water. Water chemistry and modern-aged groundwater in the alluvial monitoring well (MSBV #3) are consistent with the oil-field water in the alluvium being derived from documented historical surface disposal of oil-field water upslope (northwest) of the site. Water chemistry and pre-modern groundwater age in the deeper Tulare monitoring well (MSBV #1) on top of the Amnicola clay are consistent with oil-field fluids derived from upslope natural geologic sources or old oil wells that leak in the subsurface. Shallow groundwater in the Tulare (MSBV #2) is not affected by mixing with oil-field sources.

EarthArXiv

Three-dimensional temperature maps of the Williston Basin, USA: Implications for deep hot sedimentary and enhanced geothermal resources

As part of U.S. Geological Survey's (USGS) efforts to identify and assess geothermal energy resources of the US, a three-dimensional (3D) geologic and thermal model has been constructed for the Williston Basin, USA. The geologic model consists of all sedimentary units above the Proterozoic and Archean crystalline rock (called basement herein), with a total sedimentary thickness of up to 5 km near the basin center. Twenty-nine geologic units were mapped from interpreted formation tops from 16,465 wells. A 3D temperature model was constructed to a depth of 7 km by constructing a 3D heat flow model for the sedimentary units, followed by estimating underlying temperature using a one-dimensional (1D) analytic solution for heat flow within the underlying crystalline basement. Using the sedimentary basin model, heat flow was simulated in 3D and was calibrated using three temperature datasets: 1) 24 high-confidence static temperature logs (equilibrium thermal profiles), 2) more than15,000 drill stem test (DST) measurements from >7,000 wells, and 3) more than 45,000 bottomhole temperature (BHT) measurements from >14,000 wells. The DST and BHT datasets provide broad spatial coverage, but are lower confidence, primarily because measurements were made prior to attaining thermal equilibrium. DST and BHT measurements were binned regionally to develop representative thermal profiles that generally agree with these lower quality data (hereafter called pseudowell temperature profiles). Layer properties (primarily thermal conductivity and compaction curves) were set to best estimate values, then the heat flow model was calibrated to fit pseudowell and static temperature logs primarily by adjusting basal heat flow to approximate the overall temperature profile. Minor adjustments to thermal conductivity allowed adjusting changes in slope at lithologic contacts. Resulting maps include 3D temperature and basal (bottom of sedimentary units) heat flow estimates, which are used as input for the temperature model of the basement. The crystalline basement temperature model uses an analytic 1D solution to the heat flow equation that requires estimates of heat flow and temperature at the upper boundary (i.e., the sediment/basement contact), radiogenic heat production within the crystalline basement, and reference thermal conductivity (i.e., uncorrected for temperature). Two regions of high heat flow are identified: 1) in western North Dakota along the North American Central Plains Conductivity Anomaly and 2) in eastern Montana near the Poplar dome. Within the sedimentary column in the center of the basin of the basin, an area of approximately 100,000 km2 is predicted to have moderate- to high-temperature geothermal resources (>90 °C) under the thickest sequences of sediments. Where thick insulation and high heat flow coincide, electric-grade resources can be less than 4 km deep. Assuming a maximum feasible drilling depth of 7 km, temperatures are predicted to be as high as 175 °C. The geologic model may be used to identify strata at sufficient temperatures that may have natural permeability or that may have conditions that favor development of enhanced/engineered geothermal systems resources.

Montana, North Dakota, South Dakota

Completion summary for monitor wells NRF-17 and NRF-18 at the Naval Reactors Facility, Idaho National Laboratory, Idaho

The U.S. Geological Survey (USGS)—in cooperation with the U.S. Department of Energy (DOE) for the Naval Reactors Laboratory Field Office that supports operations for the Naval Reactors Facility (NRF) located at the Idaho National Laboratory (INL)—drilled and constructed well NRF-17 (formerly borehole USGS 151) and well NRF-18 (formerly borehole USGS 152) for stratigraphic framework analyses and water-quality monitoring at the Idaho National Laboratory (INL) near the NRF, in southeastern Idaho. Borehole USGS 151 was continuously cored from about 48 to 1,070 feet (ft) below land surface (BLS); rotary drilled from approximately 1,070 to 1,720 ft BLS; and re-drilled to complete construction as a monitor well NRF-17, completed to 461 ft BLS. Borehole USGS 152 was continuously cored from approximately 19 to 1,259 ft BLS; rotary drilled from approximately 1,259 to 1,630 ft BLS; and re-drilled to complete construction as a monitor well NRF-18, completed to 450 ft BLS. Geophysical data were examined with photographed core material to record lithologic descriptions and to suggest zones where groundwater flow was anticipated. Basalt flows varied from highly fractured to dense, with high-to-low vesiculation. Well NRF-17 generally was constructed in mostly dense basalt (greater than 75 percent), and well NRF-18 was constructed in primarily fractured and (or) vesicular basalt. In well NRF-17, the well capacity is directly affected by the limited amount of fractured basalt, which serves as the primary pathway for groundwater. This effect was observed during the pumping test conducted after the well's final construction. Single-well aquifer tests were done at wells NRF-17 and NRF-18 to provide estimates of transmissivity and hydraulic conductivity after final well construction and initial well development. Estimated values of transmissivity and hydraulic conductivity for well NRF-17 were 8.81 feet squared per day (ft 2 /d) and 1.04×10 -2 feet per day (ft/d), respectively. Estimated values of transmissivity and hydraulic conductivity for well NRF-18 were 4.77×10 3 ft 2 /d and 5.61 ft/d, respectively. The NRF-17 pump test resulted in 19.41 ft of measured drawdown at a sustained average pumping rate of 3.3 gallons per minute (gal/min). The NRF-18 pump test resulted in 0.55 ft of measured drawdown at a sustained average pumping rate of 31.0 gal/min. Water-quality samples collected from the two wells were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for select inorganic constituents showed concentrations consistent with signatures from tributary valley groundwater with influences from ephemeral surface-water recharge from the Big Lost River. Water-quality samples analyzed for stable isotopes of oxygen and hydrogen are consistent with signatures from tributary valley groundwater and surface-water recharge inputs to the aquifer. No measured water-quality results were greater than their respective maximum contaminant levels for public drinking-water supplies. Inorganic and nutrient water-quality results for well NRF-17 and well NRF-18 suggest the groundwater in this area is potentially affected by industrial wastewater disposal.

Idaho

Origin and evolution of mafic volcanism associated with 3 m.y. of andesite production at the Goat Rocks volcanic cluster, southern Washington Cascade Range

More than 3 m.y. of mafic volcanism near the Goat Rocks volcanic cluster in the southern Washington Cascade Range, USA, lends insight into the evolution of basalts and the subarc mantle at a long-lived, major arc volcanic locus. We contribute field observations, 40 Ar/ 39 Ar dates, paleomagnetic directions, and bulk rock and mineral compositions to characterize nine mafic units that erupted in association with the Goat Rocks volcanic cluster. The time frame of mafic volcanism, ca. 3.6 Ma to 60 ka, encompasses the lifespan of the central volcanic cluster (3.1 Ma to 115 ka), with a lull from ca. 2.7 Ma to 1.4 Ma. A climactic period of voluminous mafic activity and far-traveled lava flows, including construction of the Hogback Mountain shield volcano, coincided with voluminous andesite eruptions from the central volcanic cluster. The basaltic rocks in the Goat Rocks area are calc-alkaline to barely tholeiitic and have high field strength element depletion relative to large-ion lithophile elements characteristic of calc-alkaline basalts (CAB) of the Cascade volcanic arc. Unlike at neighboring andesitic volcanic centers (Mounts Adams, St. Helens, and Rainier), no other mafic end members such as high-aluminum olivine tholeiite (HAOT) or intraplate-type basalt (IPB) are present at or near the Goat Rocks volcanic cluster, although some of the calc-alkaline basalts in this study have IPB-like affinities. The Goat Rocks mafic units exhibit two main temporal trends in composition: (1) the most primitive basalts erupted earlier, compared to less primitive and more evolved compositions later, and (2) high field strength element concentrations are higher in the younger basalt units relative to the oldest two. In contrast to these temporal trends, the mafic units define two compositional groups that recur through time, a low-Sr and a high-Sr group, each with distinct trace element and Sr and Nd isotope ratios. Although radiogenic isotope ratios are generally aligned with High Cascades CAB and HAOT, some extend toward IPB of Mount Adams and Simcoe Mountains volcanic field. Olivine-dominated crystal fractionation at shallow pressure from a small range of parent magma compositions accounts for much of the variation among the basalts and basaltic andesites. A high-pressure fractionation model is plausible for only one of the youngest basalt units (basalt of Walupt Lake volcano). Mafic recharge and crustal assimilation accounts for the incompatible-element enriched composition of basaltic andesites erupted during construction of the largest andesitic centers, further supporting sustained basalt mass flux and thermal energy driving andesite genesis. We model the most primitive members of the Goat Rocks mafic units as partial melts of successively less depleted mantle in time. Variable degrees of fluxing with fluids and melts from subduction explain the distinction between high-Sr and low-Sr groups. We propose that mantle metasomatism by ancestral subduction and fluid-flux melting is heterogeneously distributed through the local subarc mantle and played a greater role in the genesis of the high-Sr basalt group. The limited range of primitive basalt types around the Goat Rocks volcanic cluster contrasts with the much greater diversity of basalts throughout the southern Washington to northern Oregon Cascade arc. On the other hand, the central volcanic cluster encompasses nearly the entire diversity observed at neighboring composite volcanoes. In the case of the Goat Rocks area at least, and perhaps attributable to the entire region, this means that the genesis of diverse intermediate magmas is independent from and does not require vastly different parental basalt compositions.

California, Oregon, Washington