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Intrusions and intrusive complexes in an ophiolite near San Luis Obispo; a chemical and petrologic study

The San Luis Obispo ophiolite is a sequence of mafic and ultramafic rocks that lie as a thrust-like slice on top of Franciscan melange in the southern California Coast Range. The ophiolite comprises the classic Steinmann Trinity of basal serpentinized ultramafic rocks overlain sequentially by spilitized pillow lavas and cherts. The ophiolite is intruded by numerous diabasic dikes and several large intrusive complexes that contain peridotite, gabbro, diabase and felsic rocks. Field relations indicate that this ophiolite originated as a sequence of submarine volcanic flows and breccia units extruded onto an ultramafic basement. Later the volcanic and ultramafic rocks were intruded along their contact by mafic magma that crystallized as a stratiform complex of cumulate peridotite and gabbro. Next, this stratiform complex was intruded by diorite and albite-granite (trondhjemite) sills, which may have been produced by partial melting of gabbros in the upper levels of the stratiform complex. Finally all earlier units were intruded by diabasic sills and dikes that probably were late feeders for the pre-existing volcanic unit. All the ophiolite rocks underwent subsequent highly localized brecciation, under greenschist-facies conditions, in which felsic rocks were incipiently melted by frictional heating. The host rocks and intrusions were metamorphosed at low temperature and the mafic rocks were altered by Na- and Si-metasomatism. Despite this pervasive alteration, evidences of the formational stages of the ophiolite are preserved in disequilibrium mineral assemblages, primarily within mafic and ultramafic rocks of the intrusive complexes. Whole-rock analyses of the ophiolite suite indicate that alteration has obscured but not obliterated the original chemical character of the mafic rocks. The ophiolite diabases and basalts contain up to 6 weight percent Na 2 0 and 58 percent Si0 2 , in contrast to normal Si0 2 contents of 50 percent or less and Na 2 0 contents of less than 3 percent for unaltered oceanic and continental tholeiite basalts. However, the low K 2 0 contents (less than 0.8 percent) of all units in the ophiolite suite indicate that these rocks are not part of an alkalic kindred, but rather are altered tholeiites. Compositions of relict amphibole and plagioclase in the mafic rocks indicate that the ophiolite formed in a high-temperature environment and the deep seated rocks were metamorphosed under amphibolite-facies conditions. A later change in the environmental conditions allowed subsequent low-temperature (greenschist facies) metamorphism and metasomatism. The structure and chemistry of the San Luis Obispo ophiolite support the hypothesis that this body may represent a fragment of oceanic crust and mantle. The volcanic rocks and the intrusive complexes probably formed at a mid-ocean ridge, where conditions of high heat-flow provided the requisite high-temperature environment and promoted the production of mafic magmas. The change to low-temperature conditions probably was due to inception or acceleration of crustal spreading at that portion of the ridge where this ophiolite formed. The nature of brecciation in the ophiolite indicates that the low-temperature environment also was one of greater tectonic disturbance, relative to conditions at the ridge. This tectonically active environment probably corresponds to an island arc where the ophiolite-bearing plate was subducted in an adjacent trench. The absence of a high-pressure mineral assemblage in the San Luis Obispo ophiolite suggests that this segment of ocean-crust and upper mantle was not buried in a subduction zone, but rather was rafted on top of subduction melange (Franciscan Formation) into its present position.

California↗

Sandstone-hosted uranium deposits of the Colorado Plateau, USA

More than 4,000 sandstone-hosted uranium occurrences host over 1.2 billion pounds of mined and in situ U 3 O 8 throughout the Colorado Plateau. Most of the resources are in two distinct mineral systems with deposits hosted in the Triassic Chinle and Jurassic Morrison Formations. In the Chinle mineral system, base metal sulfides typically accompany mineralization. The Morrison mineral system is characterized by V/U ratios up to 20. The uranium source was likely volcanic ash preserved as bentonitic mudstones in the Brushy Basin Member of the Morrison Formation, and lithic volcanic clasts, ash shards, and bentonitic clay in the lower part of the Chinle Formation. Vanadium originated from two possible sources: iron–titanium oxides that are extensively altered in bleached rock near deposits or from similar minerals in variably bleached red beds interbedded with and beneath the Morrison. In Chinle-hosted deposits, in addition to volcanic ash, a contributing source of both vanadium and uranium is proposed here for the first time to be underlying red beds in the Moenkopi and Cutler Formations that have undergone a cycle of reddening-bleaching-reoxidation. Transport in both systems was likely in groundwater through the more permeable sandstones and conglomerate units. The association of uranium minerals with carbonate and more rarely apatite, suggests that transport of uranium was as a carbonate or phosphate complex. The first comprehensive examination of paleoclimate, paleotopography, and subsurface structure of aquifers coupled with analysis of the geochronology of deposits suggests that that there were distinct pulses of uranium mineralization/redistribution during the period from about 259 Ma to 12 Ma when oxidized mineralizing fluids were intermittently rejuvenated in the Plateau in response to changes in tectonic regime and climate. Multiple lines of evidence indicate that deposits formed at ambient temperatures of about 25 °C to no greater than about 140 °C. In both systems, deposits formed where groundwater flow slowed and was subject to evaporative concentration. Stagnant conditions allowed for prolonged interaction of U- and V-enriched groundwater with ferrous iron-bearing reductants, such as illite and iron–titanium oxides, and more rarely organic material such as plant debris. Paragenetically late in the sequence, reducing fluids introduced additional organic matter to some deposits. Reducing fluids and introduced organic matter (now amorphous and altered by radiolysis) may originate from regional petroleum systems where peak oil and gas generation was from ∼ 82 to ∼ 5 Ma. Our novel analysis indicates that these reducing fluids bleached rock and protected affected deposits from remobilization during exposure and weathering that followed uplift of the Plateau (∼80 to 40 Ma).

Arizona, Colorado, Nevada, New Mexico, Utah↗

Geochronology of Precambrian granites and associated U-Ti-Th mineralization, northern Olary province, South Australia

Proterozoic granitoids and metamorphic rocks in the Olary province of the Willyama block of South Australia host ore-grade amounts of U-Th-Ti and U-Fe-Ti-Th minerals. U-Pb-Th isotope analyses on zircons from all granitoids associated with the Crocker Well brannerite deposit indicate that these granitoids were intruded within a short time span, close to the 1579.2??1.5 m.y. age of the brannerite-bearing host-rock. Though the early Paleozoic Delamerian orogeny was intense in this region, the zircon isotopic systems remained unaffected; rather, the best-defined zircon chords on concordia plots show a welldefined lower intercept of 43.8??6.5 Ma, which can only be associated with early Tertiary block faulting. Pb-U-Th isotope analyses on brannerite from the Crocker Well deposit and davidite from the Mt. Victoria deposit and the Radium Hill deposit yield badly scattered and discordant apparent ages that suggest a primary age at least as old as the age of the Crocker Well granitoids, followed by a severe disturbance in the early Paleozoic. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Uranium deposits of the northern part of the Boulder Batholith, Montana

Uranium minerals and radioactivity anomalies occur in many silver-lead veins and chalcedony veins and vein zones in the Boulder batholith of southwestern Montanao Pitchblende has been identified in a few silver-lead veins. These veins occupy shear zones along which there is no evidence of large-scale lateral displacement. The wall rock adjacent to the veins is intensely silicified and sencitized quartz monzonite and granodiortte. The veins have yielded substantial quantities of lead, silver, zinc, and gold. The silver-lead veins consist principal1y of galena, spha1erite, tetrahedrite, cha1copyrite and pyrite in a gangue of light to dark gray quartz, altered rock, gouge, and subordinate chalcedony and carbonate minerals. No anomalous radioactivity nor uranium minerals have been found in similar veins in pre-batholithic rocks of the area. Chalcedony veins and vein zones, some of which are ttraniferous, are distinctly different from the silver-lead veins and, with a single except1on, are known only in the batholith. The chalcedony vein zones consist of one or more discontinuous stringers or veins of cha1cedony and microcrystalline quartz in silicified and sericitized quartz monzonite and granodiorite, and in less strongly altered alaskite. On1y small amounts of silver ore have been produced from these chalcedony veins and vein zones. All of the veins are ear1y Tertiary in age, but the silver-lead veins probably are older than the chalcedony veins. Uranium is closely associated with chalcedory and microcrystalline quartz in both types of veins. This association suggests that all of the uranium in the area is of the same age. If so, some of the silver-lead veins must have been reopened during the period of chalcedony vein formation.

Trace Elements Memorandum↗

Major- and trace-element concentrations in rock samples collected in 2004 from the Taylor Mountains 1:250,000-scale quadrangle, Alaska

The Kuskokwim mineral belt of Bundtzen and Miller (1997) forms an important metallogenic region in southwestern Alaska that has yielded more than 3.22 million ounces of gold and 400,000 ounces of silver. Precious-metal and related deposits in this region associated with Late Cretaceous to early Tertiary igneous complexes extend into the Taylor Mountains 1:250,000-scale quadrangle. The U.S. Geological Survey is conducting geologic mapping and a mineral resource assessment of this area that will provide a better understanding of the geologic framework, regional geochemistry, and may provide targets for mineral exploration and development. During the 2004 field season 137 rock samples were collected for a variety of purposes. The 4 digital files accompanying this report reflect the type of analysis performed and its intended purpose and are available for download as an Excel workbook, comma delimited format (*.csv), dBase 4 files (*.dbf) or as point coverages in ArcInfo interchange format (*.e00). Data values are provided in percent, pct (1gram per 100grams), or parts per million, ppm (1gram per 1,000,000grams) per the column heading in the table. All samples were analyzed for a suite of 42 trace-elements (icp42.*) to provide data for use in geochemical exploration as well as some baseline data. Selected samples were analyzed by additional methods; 104 targeted geochemical exploration samples were analyzed for gold, arsenic, and mercury (auashg.*); 21 of these samples were also analyzed to obtain concentrations of 10 loosely bound metals (icp10.*); 33 rock samples were analyzed for major element oxides to support the regional mapping program (reg.*), of which 28 sedimentary rock samples were also analyzed for total carbon, and carbonate carbon.

Open-File Report↗

Microbial reduction of structural iron in interstratified illite-smectite minerals by a sulfate-reducing bacterium

Clay minerals are ubiquitous in soils, sediments, and sedimentary rocks and could coexist with sulfate‐reducing bacteria (SRB) in anoxic environments, however, the interactions of clay minerals and SRB are not well understood. The objective of this study was to understand the reduction rate and capacity of structural Fe(III) in dioctahedral clay minerals by a mesophilic SRB, Desulfovibrio vulgaris and the potential role in catalyzing smectite illitization. Bioreduction experiments were performed in batch systems, where four different clay minerals (nontronite NAu‐2, mixed‐layer illite‐smectite RAr‐1 and ISCz‐1, and illite IMt‐1) were exposed to D. vulgaris in a non‐growth medium with and without anthraquinone‐2,6‐disulfonate (AQDS) and sulfate. Our results demonstrated that D. vulgaris was able to reduce structural Fe(III) in these clay minerals, and AQDS enhanced the reduction rate and extent. In the presence of AQDS, sulfate had little effect on Fe(III) bioreduction. In the absence of AQDS, sulfate increased the reduction rate and capacity, suggesting that sulfide produced during sulfate reduction reacted with the phyllosilicate Fe(III). The extent of bioreduction of structural Fe(III) in the clay minerals was positively correlated with the percentage of smectite and mineral surface area of these minerals. X‐ray diffraction, and scanning and transmission electron microscopy results confirmed formation of illite after bioreduction. These data collectively showed that D. vulgaris could promote smectite illitization through reduction of structural Fe(III) in clay minerals.

Geobiology↗

Geology and mineralization at the Ishmas Kabir gold prospect, Ishmas gold district, Kingdom of Saudi Arabia

Ishmas Kabir ancient gold mine is located approximately 60 km southeast of the city of Ranyah and 9 km northwest of Jabal Ishmas in the southwestern part of the Ishmas gold district. The mine workings are located near the eastern edge of a flat plain covered by eolian sand and drained by Wadi Bishah. Two elongate dumps, 75 m wide and 530 m long (combined length), comprise the workings. Rising 4 m above the plain, they are prominent features in this area of low relief. Core drilling (1,023 m total depth drilled) was conducted to define the extent of potential gold occurrences at the prospect. The two northeasternmost of the four holes drilled unequivocally intersected the gold-bearing main vein zone. Drill hole 1, the northeasternmost hole drilled, passed through significant lengths of altered wall rocks + quartz veins containing > 100 ppb Au (threshold value). The average gold concentration of all intercepts in drill holes 1 through 4 is 278 ppb; the total length of drill core that assayed above the gold threshold value is 13.46 m. The highest gold concentration (1,620 ppb) reported in geochemical assay results was obtained from a 0.33 m length of core in drill hole 1. Gold-intercept occurrences are not economic in the rocks drilled; no further deep drilling is recommended at this time. Gold concentrations in samples obtained from mine dumps are much higher than in drill-core samples. Samples collected by earlier workers assayed 3-7 g/t, and tonnage estimates of mine spoil have been estimated to be as high as 120,000 tons. A possible sampling bias in earlier studies may favor larger gold-enriched, samples relative to samples from quartz tailings. Further work at Ishmas Kabir should be limited to defining gold resource potential in the dumps and in the oxidized, near-surface quartz-vein system. Primary gold at the Ishmas Kabir gold prospect occurs with quartz veins and associated sericite + pyrite alteration hosted by quartz diorite and mafic dikes. The highest gold concentrations both in dumps (earlier studies) and drill core (this investigation) are found with limonite + hematite in breccia zones, in stringer veins, and in sericitic alteration envelopes surrounding quartz veins. Secondary gold is significant in this system and attests to the importance of oxidizing, acidic solutions. Quartz veins intersected by drill holes are surrounded by mylonite schist. Quartz and carbonate veins less than 5 mm thick are boudined, whereas thick quartz veins (£ 1.2 m) have disrupted and brecciated margins; mylonitized country rock envelops quartz-vein fragments. Sulfide mineralization associated with vein formation predates this rock-deformation event. Contemporaneous brittle and ductile deformation of quartz veins and country rocks occurred during the Nabitah orogeny. Supergene gold enrichment took place much later.

Open-File Report↗

Regional study of mineral resources in Nevada: Insights from three-dimensional analysis of gravity and magnetic anomalies

A three-dimensional interpretation of the basins of Nevada was developed based on statewide data bases of digital-gravity, magnetic, geologic, well, and topographic information. An iterative technique was applied to isostatic residual gravity anomalies in Nevada in order to define the location and shape of pre-Tertiary basement and to produce a gravity map that reflects variations of density within the pre-Tertiary basement. The dominant feature of the basement gravity of Nevada is an enormous area of low gravity that spans the entire state between latitudes 37°N and 40.5°N. This regional low strongly correlates with the distribution of middle and late Tertiary volcanic rocks and may reflect silicic intrusions within the mid-crust and upper crust that are the counterparts of volcanic rocks at the surface. Although 80% of Nevada is covered by Cenozoic deposits, these deposits are thicker than 1 km over only about 20% of the state. The remaining 60% of Nevada may have pre-Tertiary basement rocks within reach of current mineral-exploration techniques. Aeromagnetic profiles from the National Uranium Resource Evaluation (NURE) were analyzed in order to produce a map showing the location of shallow magnetic sources in Nevada. This analysis shows that 46% of the state has magnetic sources, generally Mesozoic and Cenozoic igneous rocks, within 1 km of the surface. A linear magnetic anomaly in north-central Nevada has been interpreted by others as a rift zone active during middle Miocene time. The rift also is evident in NURE magnetic profiles, but our interpretation suggests that the magnetic expression of the rift continues south-southeast with similar strike to at least 38°N and perhaps to the amagmatic zone (lat. 37°N). The survival since the middle Miocene of this narrow crustal feature, essentially linear over a distance of 500 km, is difficult to interpret in light of later Basin and Range deformation. Our analysis of gravity anomalies shows that many deep Cenozoic basins are located near the rift, yet only two basins cut across it, and at least five others change strike near the rift, as if to avoid it. The rift may have remained linear because it is associated with crustal structures that acted to resist subsequent deformation.

Nevada↗

Ore deposits on northwestern Chichagof Island, Alaska

The area mapped includes most of northwestern Chichagof Island. The work, started in 1946, is a continuation of the geologic mapping done in the adjoining Chichagof mining district by Reed and Coats. The gold-bearing zone recognized by these writers continues through the area mapped by the writer to the northern shore of Chichagof Island. Stratified rocks ranging in age from Paleozoic through Early Cretaceous were intruded by gabbro, quartz diorite, norite-gabbro, and by younger quartz diorite. The igneous rocks from oldest to youngest are: gabbro, diorite, quartz diorite, the rocks associated with the nickel deposits, which include gabbro-norite and quartz diorite, and basalt. The diorite is believed to have been formed during Early Cretaceous time, and the gabbro is older by an unknown amount. The gabbro and diorite are believed to be, over large areas, recrystallized older rock. The oldest group of quartz diorite intrusives in places cuts the diorite and is therefore younger. The quartz diorite is minerally somewhat foliated and slightly metamorphosed. The igneous rocks associated with the nickel deposits are the youngest of the major igneous rock groups. They intruded the Cretaceous graywacke after it had been folded to essentially its present position. Gold is the most economically important mineral commodity mined to date. The Apex and El Nido are the two largest mines in the area, but some gold has been recovered from the Goldwin and Cobol properties and small amounts from some other small prospects. In addition to gold the area includes nickel-bearing deposits at Mirror Harbor on Chichagof Island and at Bohemia Basin on Yakobi Island. Copper mineralization occurs in the area north of Goulding Harbor. An attempt has been made to outline areas favorable for prospecting based on the regional geology and, on the number and kind of quartz veins found. In general the best area for prospecting appears to be on a northwest-trending zone which extends from the head Pinta Bay to the northern end of Althorp Peninsula.

Alaska↗

Geochemical survey of Shining Rock Wilderness, Heywood County, North Carolina

The U.S. Geological Survey (USGS) made a reconnaissance geochemical survey of the Shining Rock Wilderness (fig. 1) to test for unidentified or unexposed mineral deposits that might be recognized by their geochemical halos. Similar geochemical survey based on trace-element analyses have been credited with the discovery of many types of mineral deposits (Hawkes and Webb, 1962). Although no metallic mineral deposits are known in the study area, the same sequence of rocks that is exposed there contains small deposits of copper-bearing sulfides 10-18 mi (16-28 km) west and southwest of the wilderness (Gair and Slack, 1979). Keith (1907, p. 8) reports minor amounts of copper sulfides and iron sulfides in schist and in quartz veins cutting schist near Retreat, 4 mi (6.5 km) northwest of the wilderness. An old gold mine, the Boylston mine, on Forge Mountain 10 mi (16 km) east of the wilderness (Nitze and Hanna, 1896, p. 181-191) is in metasedimentary rocks of the Great Smoky Group (Hadley and Nelson, 1971) which are probably younger than the rocks exposed in the wilderness.

North Carolina↗

Summaries of data on and lists of references to metallic and selected nonmetallic mineral deposits in the McCarthy Quadrangle, Alaska

These summaries of data on metallic and selected nonmetallic mineral occurrences and lists of selected references to .them in Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys (and predecessor State and Territorial agencies) reports and maps and a very.few journal articles are designed to aid in library research on the mineral resources of the McCarthy quadrangle, Alaska. The references listed are selected in the sense that mainly statistical reports such as the annual Minerals Yearbook of the U.S. Bureau of Mines and many annual and biennial reports of the Alaska Division of Geological and Geophysical Surveys and its predecessor agencies are not included. Also not included are data on claims about which little more than their locations is known (for example, localities 126- 130 in MacKevett and Holloway, 1977 (OF 77-169A). These omissions should not be interpreted as a judgement that the claims are not on valid mineral occurrences, but only chat there are insufficient data to describe any mineral deposits that might be present. Geochemical anomalies determined by analyses of rock and stream-sediment samples in which no metallic mineral was indentified are also omitted.

Alaska↗

Mapping the mineral resource base for mineral carbon-dioxide sequestration in the conterminous United States

This database provides information on the occurrence of ultramafic rocks in the conterminous United States that are suitable for sequestering captured carbon dioxide in mineral form, also known as mineral carbon-dioxide sequestration. Mineral carbon-dioxide sequestration is a proposed greenhouse gas mitigation technology whereby carbon dioxide (CO 2 ) is disposed of by reacting it with calcium or magnesium silicate minerals to form a solid magnesium or calcium carbonate product. The technology offers a large capacity to permanently store CO 2 in an environmentally benign form via a process that takes little effort to verify or monitor after disposal. These characteristics are unique among its peers in greenhouse gas disposal technologies. The 2005 Intergovernmental Panel on Climate Change report on Carbon Dioxide Capture and Storage suggested that a major gap in mineral CO 2 sequestration is locating the magnesium-silicate bedrock available to sequester the carbon dioxide. It is generally known that silicate minerals with high concentrations of magnesium are suitable for mineral carbonation. However, no assessment has been made in the United States that details their geographical distribution and extent, nor has anyone evaluated their potential for use in mineral carbonation. Researchers at Columbia University and the U.S. Geological Survey have developed a digital geologic database of ultramafic rocks in the conterminous United States. Data were compiled from varied-scale geologic maps of magnesium-silicate ultramafic rocks. The focus of our national-scale map is entirely on ultramafic rock types, which typically consist primarily of olivine- and serpentine-rich rocks. These rock types are potentially suitable as source material for mineral CO 2 sequestration.

Conterminous United States↗

Mineral resource potential map of the Savannah Roadless Area, Liberty County, Florida

The Savannah Roadless Area is underlain by sedimentary rocks having low potential for oil and gas and minerals. The low potential for oil or gas notwithstanding, the possibilities for discovery cannot be ruled out because the area and nearby lands have not been thoroughly explored. No minerals have been mined within the Savannah Roadless Area, and the only production nearby has been the digging of clayey sand used in stabilizing U.S. Forest Service roads. Fuller's earth, quartz sand and gravel, clayey sand, and common clay presently are produced elsewhere in the region, and limestone and peat have been produced in the past. No clay suitable for structural clay products or fuller's earth is present in the roadless area; however, a bed of quartz sand and gravel of excellent quality was penetrated at a depth interval of 37-50 ft by one drill hole. Although this bed is coarser grained-and therefore is more suitable for many uses-than the sand deposits worked elsewhere in the Big Bend region, its mineral resource potential is reduced by the thickness of overburden above it and by its distance from markets in population centers. The Apalachicola National Forest has been explored for phosphate and reconnoitered for heavy minerals, but no valuable deposits of either have been found.

Florida↗

Water quality in the Appalachian Valley and Ridge, the Blue Ridge, and the Piedmont Physiographic Provinces, eastern United States

Chemical quality of ground water, spring water, and surface water differs substantially among the three physiographic provinces. Maps showing regional variations for 18 water properties and constituents are included in this Regional Aquifer System Analysis study report. Systematic variations in water quality are due to differences in geologic and hydrologic factors that include the dominant lithology, the availability of soluble minerals, and the degree of exposure of water to rock. Most ground water in the study area is low in concentrations of dissolved minerals, is moderately hard, and is slightly acidic. Spring water is generally harder than ground water and is slightly alkaline; whereas, surface water is softer than the ground water and is also slightly alkaline.

Alabama, Delaware, Georgia, Maryland, New Jersey, ↗

Re-Os systematics and geochemistry of cobaltite (CoAsS) in the Idaho cobalt belt, Belt-Purcell Basin, USA: Evidence for middle Mesoproterozoic sediment-hosted Co-Cu sulfide mineralization with Grenvillian and Cretaceous remobilization

We report the first study of the Re-Os systematics of cobaltite (CoAsS) using disseminated grains and massive sulfides from samples of two breccia-type and two stratabound deposits in the Co-Cu-Au Idaho cobalt belt (ICB), Lemhi subbasin to the Belt-Purcell Basin, Idaho, USA. Using a 185 Re + 190 Os spike solution, magnetic and non-magnetic fractions of cobaltite mineral separates give reproducible Re-Os analytical data for aliquot sizes of 150 to 200 mg. Cobaltite from the ICB has highly radiogenic 187 Os/ 188 Os ratios (17–45) and high 187 Re/ 188 Os ratios (600–1800) but low Re and total Os contents (ca. 0.4–4 ppb and 14–64 ppt, respectively). Containing 30 to 74% radiogenic 187 Os, cobaltite from the ICB is amenable to Re-Os age determination using the isochron regression approach. Re-Os data for disseminated cobaltite mineralization in a quartz-tourmaline breccia from the Haynes-Stellite deposit yield a Model 1 isochron age of 1349 ± 76 Ma (2σ, n = 4, mean squared weighted deviation MSWD = 2.1, initial 187 Os/ 188 Os ratio = 4.7 ± 2.2). This middle Mesoproterozoic age is preserved despite a possible metamorphic overprint or a pulse of metamorphic-hydrothermal remobilization of pre-existing cobaltite that formed along fold cleavages during the ca. 1190–1006 Ma Grenvillian orogeny. This phase of remobilization is tentatively identified by a Model 3 isochron age of 1132 ± 240 Ma (2σ, n = 7, MSWD = 9.3, initial 187 Os/ 188 Os ratio of 9.0 ± 2.9) for cobaltite in the quartz-tourmaline breccia from the Idaho zone in the Blackbird mine. All Mesoproterozoic cobaltite mineralization in the district was affected by greenschist- to lower amphibolite-facies (garnet zone) metamorphism during the Late Jurassic to Late Cretaceous Cordilleran orogeny. However, the fine- to coarse-grained massive cobaltite mineralization from the shear zone-hosted Chicago zone, Blackbird mine, is the only studied deposit that has severely disturbed Re-Os systematics with evidence for a linear trend of mixing with (metamorphic?) fluids. The new Re-Os ages and extremely high initial 187 Os/ 188 Os ratios of cobaltite reported here favor a magmatic-hydrothermal genetic model for a multi-stage REE-Y-Co-Cu-Au mineralization occurring at ca. 1370 to 1349 Ma, and related to the emplacement of the Big Deer Creek granite pluton at ca. 1377 Ma. In our model, deposition of paragenetically early xenotime and gadolinite was followed by an influx of Mesoproterozoic evaporitic brines and magmatic-hydrothermal fluids containing metals and reduced sulfur derived from mafic and oceanic island-arc Archean to Paleoproterozoic rocks in the Laurentian basement. Cobaltite mineralization occurred upon cooling of these fluids at an inferred temperature of 300 °C or below.

Idaho↗

Geologic map and structure sections of the Clear Lake Volcanics, Northern California

The Clear Lake Volcanics are located in the California Coast Ranges about 150 km north of San Francisco. This Quaternary volcanic field has erupted intermittently since 2.1 million years ago. This volcanic field is considered a high-threat volcanic system (Ewert and others, 2005) The adjacent Geysers geothermal field, largest power-producing geothermal field in the world, is powered by the magmatic heat source for the volcanic field. This report consists of three sheets that include the geologic map, one table, two figures, three cross sections, description of map units, charts of standard and diagrammatic correlation of map units, and references. This map supersedes U.S. Geological Survey Open-File Report 76-751. Descriptions of map units are grouped by geographic area. Summaries of the evolution, chemistry, structure, and tectonic setting of the Clear Lake Volcanics are given in Hearn and others (1981) and Donnelly-Nolan and others (1981). The geology of parts of the area underlain by the Cache Formation is based on mapping by Rymer (1981); the geology of parts of the areas underlain by the Sonoma Volcanics, Franciscan assemblage, and Great Valley sequence is based on mapping by McLaughlin (1978). Volcanic compositional map units are basalt, basaltic andesite, andesite, dacite, rhyodacite, and rhyolite, based on SiO2 content. Included in this report are maps showing the distribution of volcanic rocks through time and a chart showing erupted volumes of different lava types through time. A table gives petrographic data for each map unit by mineral type, abundance, and size. Most ages are potassium-argon (K/Ar) ages determined for whole-rock samples and mineral separates by Donnelly-Nolan and others (1981), unless otherwise noted. A few ages are carbon-14 ages or were estimated from geologic relationships. Magnetic polarities are from Mankinen and others (1978; 1981) or were determined in the field by B.C. Hearn, Jr., using a portable fluxgate magnetometer. Thickness for most units is estimated from topographic relief except where drill-hole data were available.

California↗

Ages, rare-earth element enrichment, and petrogenesis of tholeiitic and alkalic basalts from Kahoolawe Island, Hawaii

Kahoolawe Island, Hawaii (18×11 km), is a basaltic shield volcano with caldera-filling lavas, seven identified postshield vents, and at least two occurrences of apparent rejuvenated-stage eruptive. We examined 42 samples that represent all stages of Kahoolawe volcano stratigraphy for their petrography, whole-rock major-and trace-element contents, mineral compositions, and K−Ar ages. The two oldest shield samples have an average age of 1.34±0.08 Ma, and four postshield samples (3 are alkalic) average 1.15±0.03 Ma; ages of 1.08 and 0.99 Ma for two additional tholeiitic samples probably are minimum ages. Whole-rock major- and trace-element and mineral compositions of Kahoolawe shield and caldera-fill laves are generally similar to the lavas forming Kilauea and Mauna Loa tholeiitic shields, but in detail, Kahoolawe shield lavas have distinctive compositions. An unusual aspect of many postshield Ka-hoolawe lavas is anomalously high REE and Y abundances (up to 200 ppm La and 175 ppm Y) and negative Ce anomalies. These enrichments reflect surficial processes, where weathering and soil development promoted REE-Y transport at the weathering front. Major element abundances (MgO, 10–6 wt.%) for shield and caldera-fill basalts are consistent with fractionation of ol+px+pl in frequently replenished magma reservoirs. In general, tholeiitic basalts erupted from late vents are higher in SiO 2 than the shield lavas, and temporal differences in parental magma compositions are the likely explanation. Alkalic basalts that erupted from vents are comparable in composition to those at other Hawaiian volcanoes. Trace-element abundance ratios indicate that alkalic basalts represent either relatively lower degrees of melting of the shield source or a distinct source. Apparent rejuvenated-stage basalts (i.e., emplaced after substantial Kahoolawe erosion) are tholeiitic, unlike the rejuvenated-stages at other Hawaiian volcanoes (alkalic). Kahoolawe, like several other Hawaiian volcanoes, has intercalated tholeiitic and alkalic basalts in the postshield stage, but it is the only volcano that appears to have produced tholeiitic rejuvenated-stage lavas.

Hawaii↗

Preliminary geologic and geophysical data of the UE25a-3 exploratory drill hole, Nevada Test Site, Nevada

The UE25a-3 drill hole, located in the Calico Hills area, southwestern part of the Nevada Test Site, was drilled as part of an effort to evaluate the Calico Hills area as a possible nuclear waste repository site. The purpose of the drill hole was to verify the existence of an intrusive crystalline body in the subsurface and to determine the stratigraphy, structure, and nature of fractures of the cored rocks. Cored samples were obtained for mineral, chemical, and material property analyses. Continuous cores were taken from 30.5 m (100ft) to total depth of 771.2 m (2,530.1 ft) of units J and I{?) (Late Mississippian age) of the Eleana Formation. The drill hole penetrated 416.1 m (1 ,365ft) of argillite, and 304.5 m (999ft) of thermally altered argillite of unit J, and 50.6 m (166ft) of marble of unit I(?). No crystalline rocks were intersected by the drill hole. Numerous high-angle faults and brecciated zones were intersected by the drill hole. The units cored were intensely fractured with fracture analysis of the core consisting of frequency of fractures, dips of fractures, open and closed (sealed) fractures and types of fracture sealing or coating material. Twenty-four hundred and thirty fractures, representing approximately 30 percent of the fractures present, indicate an average fracture frequency of 13.2 fractures per meter, predominantly high-angle dips with 66 percent of the fractures closed. Fractures in the argillite interval are sealed or coated predominantly with kaolinite, nacrite, and dickite. Calcite, chlorite, and magnetite are present in fractures in the altered argillite interval. Fractures in the marble interval are sealed or coated with calcite, dolomite, and ferruginous clay. The core index indicates that the lower half of the drilled interval is more competent than the upper half. Borehole geophysical logs were run by the Birdwell Division of Seismograph Service Corporation for geologic correlations and lithologic characterizations. The logs include: caliper, density, resistivity, spontaneous potential, Vibroseis, 3-D velocity, neutron, and gamma-ray logs. Lithologic boundaries and structures correlate to responses in the logs.

Nevada↗