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Detecting changes in riparian habitat conditions based on patterns of greenness change: A case study from the Upper San Pedro River Basin, USA

Healthy riparian ecosystems in arid and semi-arid regions exhibit shifting patterns of vegetation in response to periodic flooding. Their conditions also depend upon the amount of grazing and other human uses. Taking advantage of these system properties, we developed and tested an approach that utilizes historical Landsat data to track changes in the patterns of greenness (Normalized Difference Vegetation Index) within riparian zones. We tested the approach in the Upper San Pedro River of southeastern Arizona of the US, an unimpounded river system that flows north into the US from northern Mexico. We evaluated changes in the pattern of greenness in the San Pedro River National Conservation Area (SPRNCA), an area protected from grazing and development since 1988, and in a relatively unprotected area north of the SPRNCA (NA). The SPRNCA exhibited greater positive changes in greenness than did the NA. The SPRNCA also exhibited larger, more continuous patches of positive change than did the NA. These pattern differences may reflect greater pressures from grazing and urban sprawl in the NA than in the SPRNCA, as well as differences in floodplain width, depth to ground water, and base geology. The SPRNCA has greater amounts of ground and surface water available to support a riparian gallery forest than does the NA, and this may have influenced changes during the study period. Estimates of the direction of greenness change (positive or negative) from satellite imagery were similar to estimates derived from aerial photography , except in areas where changes were from one type of shrub community to another, and in areas with agriculture. Change estimates in these areas may be more difficult because of relatively low greenness values, and because of differences in soil moisture, sun-angle, and crop rotations among the dates of data collection. The potential for applying a satellite-based, greenness change approach to evaluate riparian ecosystem condition over broad geographic areas is also discussed.

Arizona↗

Range-wide phylogeographic analysis of the spotted frog complex (Rana luteiventris and Rana pretiosa) in northwestern North America

The dynamic geological and climatic history of northwestern North America has made it a focal region for phylogeography. We conducted a range-wide phylogeographic analysis of the spotted frog complex (Rana luteiventris and Rana pretiosa) across its range in northwestern North America to understand its evolutionary history and the distribution of clades to inform conservation of R. pretiosa and Great Basin R. luteiventris, candidates for listing under the US Endangered Species Act. Mitochondrial DNA sequence data from a segment of the cytochrome b gene were obtained from 308 R. luteiventris and R. pretiosa from 96 sites. Phylogenetic analysis revealed one main R. pretiosa clade and three main R. luteiventris clades, two of which overlapped in southeastern Oregon. The three R. luteiventris clades were separated from each other by high levels of sequence divergence (average of 4.75-4.97%). Two divergent clades were also uncovered within the Great Basin. Low genetic variation in R. pretiosa and the southeastern Oregon clade of R. luteiventris suggests concern about their vulnerability to extinction. ?? 2008 Elsevier Inc.

Molecular Phylogenetics and Evolution↗

Mapping structural control through analysis of land-surface deformation for the Rialto-Colton groundwater subbasin, San Bernardino County, California, 1992–2010

The locations of many faults in and near the Rialto-Colton groundwater subbasin are not precisely known because the spatial density of existing lithologic and hydrologic data used to infer the locations of faults can be sparse. The U.S. Geological Survey, in cooperation with the San Bernardino Valley Municipal Water District, analyzed structural control of groundwater flow in and near the Rialto-Colton groundwater subbasin using Interferometric Synthetic Aperture Radar (InSAR) methods. Faults commonly are barriers to groundwater flow, and the high spatial resolution of InSAR imagery can be used to infer the locations of buried faults where groundwater pumping occurs. InSAR results have revealed three areas in and near the Rialto-Colton groundwater subbasin where buried faults are interpreted as groundwater-flow barriers: the northwestern area about 3 miles northwest of the City of Rialto, the San Jacinto fault area west of the City of San Bernardino, and the southeastern area about 2 miles southeast of the City of Colton. The InSAR results were combined with knowledge gained from previous studies to better define the location and extent of faults acting as groundwater-flow barriers. New data about faults acting as groundwater-flow barriers can be incorporated into future conceptual and hydrologic models of the Rialto-Colton groundwater subbasin and provide water managers information to help effectively manage groundwater resources.

California↗

Value-aligned planning objectives for restoring North Carolina aquatic resources

Rapid population growth and development in the southeastern United States have resulted in substantial impairment to freshwater aquatic ecosystems. National or regional restoration policies strive to address impaired ecosystems but can suffer from inconsistent and opaque processes. The Clean Water Act, for example, establishes reallocation mechanisms to transfer ecosystem services from sites of disturbance to compensation sites to offset aquatic resource functions that are unavoidably lost through land development. However, planning for the prioritization of compensatory mitigation areas is often hampered by unstructured decision-making processes that are narrowly framed because they are not co-produced with stakeholders affected by, or having an interest in, the impacts and mitigation. This summary report represents the collaborative efforts of the U.S. Geological Survey and the North Carolina Department of Environmental Quality, Division of Mitigation Services, to co-develop an applied decision framework following the principles of structured decision-making for prioritizing watershed catchments by their potential for realizing a range of beneficial outcomes from future mitigation projects. The framework focuses on supporting the State’s nationally recognized stream and wetlands compensatory mitigation program by clarifying a discrete decision problem and specifying agency and stakeholder values to formulate fundamental and means objectives for prioritizing restoration sites. The co-development of this decision framework resulted in a number of useful insights from the perspective of the decision maker, including recognition (1) that the problem is a multi-objective decision driven by values beyond restoring lost functionality of ecosystems (that is, biogeophysical goals), (2) that the decision comprises a linked and sequential planning-to-implementation process, and (3) that future risk associated with land-use and climate change must be considered. The outcomes of this collaboration can serve as a systematic and transparent framework to prioritize a wide range of restoration, conservation, and resource-allocation activities in similar environmental contexts across the Nation.

North Carolina↗

Planning report for the southeastern limestone regional aquifer system analysis

The southeastern limestone aquifer system is one of the major sources of ground water in the United States. Over 3 billion gallons of water are pumped daily making the aquifer the principal source of municipal, industrial, and agricultural water supply in large parts of Florida and Georgia and to a lesser extent in South Carolina, and Alabama. Another important use is the disposal of industrial wastes and treated sewage into parts of the limestone system containing saline water. A variety of problems have developed in the aquifer in recent years, principally declining water levels, saltwater intrusion in coastal areas, water-quality degradation, and inadequate supplies of fresh ground water locally. In 1978 the U.S. Geological Survey began a study whose goal is to provide a complete description of the hydrogeologic framework, geochemistry, and regional flow system of the limestone aquifer. A 4-year effort is planned that will include: (1) synthesis of all existing data and presentation on a series of regional hydrogeological and geochemical maps; (2) obtaining new hydrogeological information to fill data voids -- particularly where ongoing State and Federal programs are not likely to generate such data; and (3) design and calibration of a regional digital model of the aquifer system and detailed models of problem areas. Computer simulation will be used extensively to assess the effects of large withdrawals of ground water and waste injection into the aquifer.

Alabama, Florida, Georgia, South Carolina↗

Geologic interpretation of gravity data from the Date Creek basin and adjacent areas, west-central Arizona

A gravity survey of the Date Creek Basin and adjacent areas was conducted in June 1977 to provide information for the interpretation of basin geology. A comparison of facies relations in the locally uraniferous Chapin Wash Formation and the position of the Anderson mine gravity anomaly in the Date Creek Basin suggested that a relationship between gravity lows and the development of thick lacustrine sections in the region might exist. A second-order residual gravity map derived from the complete Bouguer gravity map for the survey area (derived from survey data and pre-existing U.S. Department of Defense data) shows an excellent correspondence between gravity lows and sediment-filled basins and suggests considerable variation in basin-fill thickness. Using the Anderson mine anomaly as a model, gravity data and facies relations suggest that the southeastern flank of the Aguila Valley gravity low and the gravity low at the western end of the Hassayampa Plain are likely areas for finding thick sections of tuffaceous lacustrine rocks.

Arizona↗

Geology and ground-water resources of Camden County, New Jersey

The major fresh water aquifers in Camden County, N. J., are in the unconsolidated sediments of Cretaceous and Tertiary age. The major aquifers are the sand and gravel units in the Potomac Group and the Raritan and Magothy Formations, the Cohansey Sand, the Wenonah Formation-Mount Laurel Sand, and the Englishtown Formation. The average ground-water use for Camden County was 68 million gallons per day for 1966. All of the major artesian aquifers have had potentiometric head declines due to ground-water withdrawals. The largest water-level decline occurred in the aquifer system in the Potomac Group and the Raritan and Magothy Formations. At Haddon Heights the potentiometric head declined over 110 feet from 1900 to 1968. In the aquifer in the Wenonah Formation-Mount Laurel Sand the potentiometric head declined 43 feet in about 60 years. The quality of ground water is generally good. In the southeastern portion of the county chloride concentrations in excess of 250 mg/liter occur in the Potomac-Raritan-Magothy aquifer system. The high chloride water has remained in the aquifer system from the time of deposition or has re-entered the system from the ocean after the changes in sea level. The greatest potential of future ground-water development is from the Cohansey Sand which is under water table conditions. It also may have the greatest possibility of local ground-water contamination. (Woodard-USGS)

Water-Resources Investigations Report↗

Great Basin geoscience data base

This CD-ROM serves as the archive for 73 digital GIS data set for the Great Basin. The data sets cover Nevada, eastern California, southeastern Oregon, southern Idaho, and western Utah. Some of the data sets are incomplete for the total area. On the CD-ROM, the data are provided in three formats, a prototype Federal Data Exchange standard format, the ESRI PC ARCVIEW1 format for viewing the data, and the ESRI ARC/INFO export format. Extensive documentation is provided to describe the data, the sources, and data enhancements. The following data are provided. One group of coverages comes primarily from 1:2,000,000-scale National Atlas data and can be assembled for use as base maps. These various forms of topographic information. In addition, public land system data sets are provided from the 1:2,500,000-scale Geologic Map of the United States and 1:500,000-scale geologic maps of Nevada, Oregon, and Utah. Geochemical data from the National Uranium Resource Evaluation (NURE) program are provided for most of the Great Basin. Geophysical data are provided for most of the Great Basin, typically gridded data with a spacing of 1 km. The geophysical data sets include aeromagnetics, gravity, radiometric data, and several derivative products. The thematic data sets include geochronology, calderas, pluvial lakes, tectonic extension domains, distribution of pre-Cenozoic terranes, limonite anomalies, Landsat linear features, mineral sites, and Bureau of Land Management exploration and mining permits.

Data Series↗

Imperiled mammalian fauna of aquatic ecosystems in the Southeast: A management perspective

Management of imperiled mammals associated with aquatic ecosystems in the southeastern United States ranges from almost no management for some species to intensive, high-profile programs for others. Aquatic mammals are notoriously difficult to census because they are often secretive, trap-wary, relatively rare, or have extensive movement patterns. As a result, conservation efforts aimed at these animals often have been greatly hampered by a general lack of comprehensive population data. Historically, certain high-profile, "flagship" species have been the primary beneficiaries of management efforts. One of the earliest examples involves beaver, Castor canadensis , which had been reduced to a low ebb due to unregulated harvest and were subsequently live-trapped by state game officials in the 1940s and repatriated throughout the southeastern states. The success of this restocking program has exceeded expectations, and today beaver numbers have reached what many consider to be nuisance proportions in most states. Similar restocking stories can be told for muskrats ( Ondatra zibethicus ) and, to a limited extent, for river otters ( Lutra canadensis ). Unfortunately, other imperiled species of lesser economic or recreational value have not been as fortunate. Efforts to conserve these lower-profile species have been minimal or conservation problems so immense that their complete recovery has been unsuccessful. Wilson (1992) suggested that 20 percent of all species on earth may be lost to extinction in the next four decades. If this disaster should occur, it would rival the greatest geological extinction episodes. Certainly, conservationists need to explore new methods for preserving mammalian diversity. In this chapter we will discuss the resource management history of aquatic mammals which are imperiled in the Southeast. In doing so we define an aquatic mammal as any mammal that is directly or indirectly associated with aquatic ecosystems. Imperiled mammals are any mammalian species, subspecies, or population listed as endangered, threatened, or of special concern on any state or federal list, and also includes mammals experiencing long-term population declines or significant range contractions.

Book chapter↗

ASTER-Derived 30-Meter-Resolution Digital Elevation Models of Afghanistan

INTRODUCTION The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) is an imaging instrument aboard the Terra satellite, launched on December 19, 1999, as part of the National Aeronautics and Space Administration's (NASA) Earth Observing System (EOS). The ASTER sensor consists of three subsystems: the visible and near infrared (VNIR), the shortwave infrared (SWIR), and the thermal infrared (TIR), each with a different spatial resolution (VNIR, 15 meters; SWIR, 30 meters, TIR 90 meters). The VNIR system has the capability to generate along-track stereo images that can be used to create digital elevation models (DEMs) at 30-meter resolution. Currently, the only available DEM dataset for Afghanistan is the 90-meter-resolution Shuttle Radar Topography Mission (SRTM) data. This dataset is appropriate for macroscale DEM analysis and mapping. However, ASTER provides a low cost opportunity to generate higher resolution data. For this publication, study areas were identified around populated areas and areas where higher resolution elevation data were desired to assist in natural resource assessments. The higher resolution fidelity of these DEMs can also be used for other terrain analysis including landform classification and geologic structure analysis. For this publication, ASTER scenes were processed and mosaicked to generate 36 DEMs which were created and extracted using PCI Geomatics' OrthoEngine 3D Stereo software. The ASTER images were geographically registered to Landsat data with at least 15 accurate and well distributed ground control points with a root mean square error (RMSE) of less that one pixel (15 meters). An elevation value was then assigned to each ground control point by extracting the elevation from the 90-meter SRTM data. The 36 derived DEMs demonstrate that the software correlated on nearly flat surfaces and smooth slopes accurately. Larger errors occur in cloudy and snow-covered areas, lakes, areas with steep slopes, and southeastern-facing slopes. In these areas, holes, large pits, and spikes were generated by the software during the correlation process and the automatic interpolation method. To eliminate these problems, overlapping DEMs were generated and filtered using a progressive morphologic filter. The quadrangles used to delineate the DEMs in the publication were derived from the Afghan Geodesy and Cartography Head Office's (AGCHO) 1:100,000-scale maps series quadrangles. Each DEM was clipped and assigned a name according to the associated AGCHO quadrangle name. The geospatial data included in this publication are intended to be used with any GIS software packages including, but not limited to, ESRI's ArcGIS and ERDAS IMAGINE.

Data Series↗

Correlations along a 140 km transect in the westernmost Peach Spring Tuff, and tracing changing facies through depositional environments

Tephrochronology is the correlation of tephra beds and tuffs by various means, and it is an important tool in refining stratigraphic and structural interpretations. The 18.78 Ma Peach Spring Tuff (PST) is a large-volume ignimbrite that was deposited across a ~200 km x 360 km area of southeastern California, northwestern Arizona, and southern Nevada. The PST is a valuable stratigraphic marker in several stratigraphic sequences in this area. In this study, the field characteristics, mineral abundance, and feldspar composition of eight ignimbrite locations are examined along a 140 km swath across the northwestern extent of the PST in the Mojave Desert. Based on geochronologic or paleomagnetic data, five of the ignimbrites are PST, and three are possible PST ignimbrites do not have supporting geochronologic or paleomagnetic data. In 53 regionally dispersed locations of the PST, including the three possible PST ignimbrites in this study, the overlying and underlying sedimentary deposits are described in order to determine the depositional changes, if any, resulting from the geologically instantaneous deposition of the ignimbrite. Of the 53 locations, 37 locations allow interpretation of the pre- and post-PST depositional environments. Of the 37, 25 have an upward fining-thinning trend indicating that the deposition of the ignimbrite resulted in (1) disruption and change in local stream gradients and sediment supply, (2) a long period of time for depositional systems to propagate to and regenerate at a location, or (3) a lack of re-establishment of the pre-PST environments. However, 12 have no significant change, so there was minimal disruption to the depositional system.

Arizona, California, Nevada↗

Relation of urbanization to stream habitat and geomorphic characteristics in nine metropolitan areas of the United States

The relation of urbanization to stream habitat and geomorphic characteristics was examined collectively and individually for nine metropolitan areas of the United States?Portland, Oregon; Salt Lake City, Utah; Denver, Colorado; Dallas?Forth Worth, Texas; Milwaukee?Green Bay, Wisconsin; Birmingham, Alabama; Atlanta, Georgia; Raleigh, North Carolina; and Boston, Massachusetts. The study was part of a larger study conducted by the U.S. Geological Survey from 1999 to 2004 to examine the effects of urbanization on the physical, chemical, and biological components of stream ecosystems. The objectives of the current study were to determine how stream habitat and geomorphic characteristics relate to different aspects of urbanization across a variety of diverse environmental settings and spatial scales. A space-for-time rural-to-urban land-cover gradient approach was used. Reach-scale habitat data and geomorphic characteristic data were collected once during low flow and included indicators of potential habitat degradation such as measures of channel geometry and hydraulics, streambed substrate, low-flow reach volume (an estimate of base-flow conditions), habitat complexity, and riparian/bank conditions. Hydrologic metrics included in the analyses were those expected to be altered by increases in impervious surfaces, such as high-flow frequency and duration, flashiness, and low-flow duration. Other natural and human features, such as reach-scale channel engineering, geologic setting, and slope, were quantified to identify their possible confounding influences on habitat relations with watershed-scale urbanization indicators. Habitat and geomorphic characteristics were compared to several watershed-scale indicators of urbanization, natural landscape characteristics, and hydrologic metrics by use of correlation analyses and stepwise linear regression. Habitat and geomorphic characteristics were related to percentages of impervious surfaces only in some metropolitan areas and environmental settings. The relations between watershed-scale indicators of urbanization and stream habitat depended on physiography and climate, hydrology, pre-urban channel alterations, reach-scale slope and presence of bedrock, and amount of bank stabilization and grade control. Channels increased in size with increasing percentages of impervious surfaces in southeastern and midwestern metropolitan areas regardless of whether the pre-existing land use was forest or agriculture. The amount of enlargement depended on annual precipitation and frequency of high-flow events. The lack of a relation between channel enlargement and increasing impervious surfaces in other metropolitan areas was thought to be confounded by pre-urbanization hydrologic and channel alterations. Direct relations of channel shape and streambed substrate to urbanization were variable or lacking, probably because the type, amount, and source of sediment are dependent on the phase of urbanization. Reach-scale slope also was important for determining variations in streambed substrate and habitat complexity (percentage of riffles and runs). Urbanization-associated changes in reach-scale riparian vegetation varied geographically, partially depending on pre-existing riparian vegetation characteristics. Bank erosion increased in Milwaukee?Green Bay and Boston urban streams, and bank erosion also increased with an increase in a streamflow flashiness index. However, potential relations likely were confounded by the frequent use of channel stabilization and bank protection in urban settings. Low-flow reach volume did not decrease with increasing urbanization, but instead was related to natural landscape characteristics and possibly other unmeasured factors. The presence of intermittent bedrock in some sampled reaches likely limited some geomorphic responses to urbanization, such as channel bed erosion. Results from this study emphasize the importance of including a wide range of landscape variables at m

Scientific Investigations Report↗

Titanium mineral resources in heavy-mineral sands in the Atlantic coastal plain of the southeastern United States

This study examined titanium distribution in the Atlantic Coastal Plain of the southeastern United States; the titanium is found in heavy-mineral sands that include the minerals ilmenite (Fe 2+ TiO 3 ), rutile (TiO 2 ), or leucoxene (an alteration product of ilmenite). Deposits of heavy-mineral sands in ancient and modern coastal plains are a significant feedstock source for the titanium dioxide pigments industry. Currently, two heavy-mineral sands mining and processing operations are active in the southeast United States producing concentrates of ilmenite-leucoxene, rutile, and zircon. The results of this study indicate the potential for similar deposits in many areas of the Atlantic Coastal Plain. This study used the titanium analyses of 3,457 stream sediment samples that were analyzed as part of the U.S. Geological Survey’s National Geochemical Survey program. This data set was analyzed by an integrated spatial modeling technique known as Bayesian hierarchical modeling to map the regional-scale, spatial distribution of titanium concentrations. In particular, clusters of anomalous concentrations of titanium occur: (1) along the Fall Zone, from Virginia to Alabama, where metamorphic and igneous rocks of the Piedmont region contact younger sediments of the Coastal Plain; (2) a paleovalley near the South Carolina and North Carolina border; (3) the upper and middle Atlantic Coastal Plain of North Carolina; (4) the majority of the Atlantic Coastal Plain of Virginia; and (5) barrier islands and stretches of the modern shoreline from South Carolina to northeast Florida. The areas mapped by this study could help mining companies delimit areas for exploration.

Scientific Investigations Report↗

Bathymetry of the continental margin off Liberia, West Africa

A bathymetric map based on new data allows examination of geomorphic features on the narrow continental margin off Liberia. The continental shelf in this region is relatively flat and featureless. The northwestern part of the continental slope, off Monrovia and Cape Mount, shows complex slump features and two submarine valleys. The central part of the slope is smoother, apparently as a result of progradation. The southeastern part of the slope, near Cape Palmas, is crossed oblique to the shoreline by a structural valley that has been modified by large slumps or landslides. This valley may be the termination, at the continental margin, of an oceanic fracture zone. The major slumplike features of the Liberian continental margin appear to be surface manifestations of deep faulting which has been partially masked by sedimentation.

Journal of Research of the U.S. Geological Survey↗

Areas contributing recharge to priority wells in valley-fill aquifers in the Neversink River and Rondout Creek drainage basins, New York

In southeastern New York, the villages of Ellenville, Wurtsboro, Woodridge, the hamlet of Mountain Dale, and surrounding communities in the Neversink River and Rondout Creek drainage basins rely on wells that pump groundwater from valley-fill glacial aquifers for public water supply. Glacial aquifers are vulnerable to contamination because they are highly permeable and have a shallow depth to water table. To protect the quality of these water resources, water managers need accurate information about the areas that contribute recharge to production wells that pump from these aquifers. The New York State Department of Environmental Conservation and the New York State Department of Health designated eight priority wells in this region for which water supply protection is of primary concern. The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation and the New York State Department of Health, began an investigation in 2019 with the general objectives of (1) improving understanding of regional groundwater-flow system, (2) delineating areas contributing recharge to eight priority production wells, and (3) quantifying the uncertainty of these contributing areas in a probabilistic way that can be used to inform decision-making related to priority well source-water protection. To complete these objectives, a MODFLOW 6 groundwater model was created encompassing the eight priority wells and the surrounding flow system, which includes parts of the Neversink River and Rondout Creek Basins in Sullivan County and Ulster County, New York. The model was built using Python tools (such as flopy , modflow-setup , and sfrmaker ) that facilitate transparent and repeatable model development using existing datasets. The model parameters were estimated with a stepwise approach using an iterative ensemble smoother implementation of the Parameter ESTimation software PEST++ (version 5.0.0). We evaluated initial “best guess” parameter bounds with a prior Monte Carlo analysis. Results of the first prior Monte Carlo analysis were used to make informed adjustments to model parameter bounds (typically resulting in expanded bounds), and a second prior Monte Carlo analysis was run to identify improved ranges for model parameters during history matching. The history matching effort produced an ensemble of parameter values for the groundwater-flow model that spans the range of values within prior uncertainty bounds. The ensemble is informed by the historical observation data, within a reasonable range of uncertainty on those observations. This history-matched ensemble was used in a particle tracking Monte Carlo analysis to delineate the areas contributing recharge to priority wells. The groundwater-flow and particle tracking (MODPATH7) models were run once for each ensemble member. Deterministic contributing areas computed for each ensemble member were aggregated to produce maps showing the probability that a location contributes recharge to priority wells. Finally, the particle tracking Monte Carlo analysis was repeated for six pumping scenarios, representing a wide range of possible pumping levels, to incorporate uncertainty in future pumping rates related to population growth or other management decisions. Increasing pumping rates generally led to larger contributing recharge areas and larger areas of high probability that a location contributes recharge to priority wells. These maps show the overall uncertainty of the areas contributing recharge to priority wells in the study area and provide a tool for risk-based decision making for protection of well source water.

New York↗

Nomenclature of regional hydrogeologic units of the Southeastern Coastal Plain aquifer system

Clastic sediments of the Southeastern Coastal Plain aquifer system can be divided into four regional aquifers separated by three regional confining units. The four regional aquifers have been named for major rivers that cut across their outcrop areas and expose the aquifer materials. From youngest to oldest, the aquifers are called the Chickasawhay River, Pearl River, Chattahoochee River, and Black Warrior River aquifers, and the regional confining units separating them are given the same name as the aquifer they overlie. Most of the regional hydrogeologic units are subdivided within each of the four States that comprise the study area. Correlation of regional units is good with hydrogeologic units delineated by a similar regional study to the west and southwest. Because of complexity created by a major geologic structure to the northeast of the study area and dramatic facies change from clastic to carbonate strata to the southeast, correlation of regional hydrogeologic units is poor in these directions. (Author 's abstract)

Water-Resources Investigations Report↗

Suspended sediment and trace element transport in the Big River downstream from the Old Lead Belt in southeastern Missouri, 2018–21

Lead Belt, an area of major lead mining from the 1860s until 1972 where more than 8.5 million tons of lead were mined. After active mining ceased, the effects of mining activities persisted in the Big River system because of large mine waste pile erosion, and floodplain sediment and streambank contamination along several tributaries and the main stem of the Big River. Lead-contaminated streambed and floodplain sediments extend more than 90 miles from the Old Lead Belt to the confluence of the Big River with the Meramec River. The waste piles and mine-waste contaminated streambed and floodplain sediments have been sources of high concentrations of several trace elements, primarily cadmium, lead, and zinc. The U.S. Environmental Protection Agency Region 7 has made several efforts to prevent further erosion of contaminated sediments into the Big River including the capping of major mine waste piles, reclaiming sediment deposits along the floodplains, and monitoring soil conditions of croplands and residential properties. A cooperative effort began in 2011 between the U.S. Geological Survey and the U.S. Environmental Protection Agency Region 7 to characterize suspended sediment quantity and quality in the Big River downstream from the Old Lead Belt as reclamation activities in the drainage basin progressed. The study was completed in two phases, and each phase included continuous stage, turbidity, and water temperature monitoring at the Big River below Bonne Terre, Missouri, streamgage and sampling station. Periodic suspended sediment samples also were collected manually (discrete samples) during base flow and selected stormflow events. Continuous streamflow, turbidity, and discrete suspended sediment data were used to develop regression models to compute daily suspended sediment concentrations and loads. During both phases, the discrete stormflow event samples were also evaluated to determine particle size distribution and concentrations of select trace elements. Phase one was completed from October 2011 through September 2013, and phase two, which is the primary focus of this report, was completed from October 2018 through September 2021. Phase two also included time-integrated suspended sediment samples collected using passive samplers. Discrete samples (collected during stormflow events) and passive samples were analyzed for concentrations of barium, cadmium, lead, and zinc in two sediment size fractions (when possible) to estimate trace element loads. Suspended sediment concentrations and loads and select trace element concentration results computed during phase one were compared to those computed during phase two to identify trends in the Big River Basin during the full study period. The concentrations of cadmium, lead, and zinc in nearly all discrete stormflow event suspended sediment samples and passive suspended sediment samples exceeded the threshold effect concentrations and the probable effect concentrations, which are two sediment quality guidelines. Most samples also exceeded the toxic effect threshold, the level at which sediment is considered to be heavily contaminated and problematic for sediment-dwelling organisms. Bulk cadmium concentrations (median of 7.90 milligrams per kilogram [mg/kg]) exceeded the toxic effect threshold (3.0 mg/kg) in 17 discrete stormflow event samples, and bulk lead concentrations (median of 1,070 mg/kg) exceeded the toxic effect threshold (170 mg/kg) in all 18 discrete stormflow event samples. Bulk zinc concentrations (median of 500 mg/kg) exceeded the toxic effect threshold (540 mg/kg) in eight discrete stormflow event samples. Bulk concentrations of these trace elements in passive suspended sediment samples were slightly greater, with concentrations of cadmium (median of 14.0 mg/kg) and lead (median of 1,860 mg/kg) exceeding the toxic effect threshold in all 18 samples. Bulk concentrations of zinc (median of 733 mg/kg) exceeded the toxic effect threshold in 15 passive samples. Compared to phase one (water years 2012–13), phase two (water years 2019–21) concentrations of lead and cadmium in the fine fraction of discrete suspended sediment samples collected at Big River below Bonne Terre were statistically similar; concentrations of barium and zinc were statistically smaller in samples collected during phase two (water years 2018–21). Sediment quality data from passive samples and daily mean suspended sediment loads from the regression model were used to calculate annual oads of barium, cadmium, lead, and zinc at the Bonne Terre streamgage. Water year 2019 had the largest loads of barium, cadmium, lead, and zinc (58.6, 1.43, 194, and 76.5 tons, respectively). The total loads of barium, cadmium, lead, and zinc for phase two (water years 2019–21) were 149, 4.00, 520, and 213 tons, respectively. Less than 5 percent of the total lead load calculated for the study period was transported when daily mean streamflow was less than 455 cubic feet per second, which is the approximate flow at which the passive samplers were inundated and began sampling. This highlights that most of the lead load is transported during stormflow events and the effectiveness of using passive samplers for ongoing monitoring of the Big River. Annual suspended sediment loads at the Bonne Terre streamgage computed using the regression model were 113,000 tons in water year 2019, 83,400 tons in water year 2020, and 96,500 tons in water year 2021. The event-based suspended sediment loads for the eight sampled stormflow events ranged from 45.3 to 32,500 tons. Although only a portion of all stormflow events during phase two were sampled, the loads accounted for during these eight stormflow events represented approximately 30.9 percent of the total suspended sediment load calculated for the study period, confirming that a large part of suspended sediments continue to be transported in the Big River during stormflow events. Event-based loads of barium, cadmium, lead, and zinc were greatest during the stormflow events sampled in January 2020 (event 4) and March 2021 (event 8). Event-based loads calculated for event 4 for barium, cadmium, lead, and zinc were 17.1, 0.206, 27.2, and 14.5 tons, respectively. During event 8, an estimated 15.6 tons of barium, 0.239 tons of cadmium, 34.0 tons of lead, and 13.6 tons of zinc were transported in suspended sediments. The continued high concentrations of lead in suspended sediments in the Big River, despite reclamation activities, is likely because of the continual transport from streambed and stream banks of lead-enriched sediment, which remain in the system from historical mining activities.

Missouri↗

Assessment of the petroleum, coal, and geothermal resources of the Economic Community of West African States (ECOWAS) region

Approximately 85 percent of the land area of the ECOWAS (Economic Community of West African States) region is covered by basement rocks (igneous and highly metamorphosed rocks) or relatively thin layers of Paleozoic, Upper Precambrian, and 'Continental Intercalaire? sedimentary rocks. These areas have little or no petroleum potential. Areas of the ECOWAS region that have potential for petroleum production or potential for increased petroleum production include the narrow belt of sedimentary rocks that stretches along the continental margin from Mauritania to Nigeria and the Niger Delta and the Benue depression. The Senegal Basin, located on the continental margin of Mauritania, Senegal, Gambia, Guinea Bissau, and Guinea, has been intensely explored by the oil industry and most of the larger structures onshore and on the shelf probably have been tested by drilling with little or no resulting commercial production. Unless basic ideas pertaining to the petroleum geology of the Senegal Basin are revised, future discoveries are expected to be limited to small fields overlooked by industry at a time when petroleum prices were low. On the continental shelf of Sierra Leone and the continental shelf of northeast and central Liberia, the sedimentary rocks are relatively thin, and industry has shown little interest in the area. On the continental rise of these countries, however, the sedimentary section, deposited in a complex fault-block system, increases in thickness. A renewal of industry interest in this deep-water area will probably follow further development of deep-water production technology. A recent oil discovery on the continental slope off the Ivory Coast is expected to spur further exploration offshore of southeastern Liberia, Ivory Coast, Ghana, Togo, and Benin. This relatively unexplored area in the Gulf of Guinea has good possibilities .for the discovery of giant oil fields. Nigeria's oil development from the Niger Delta may have peaked, as 13 of 14 giant oil fields were discovered prior to 1969 and the greatest number of fields were discovered in the period 1965 through 1967. Like delta regions in other parts of the world, individual oil fields of the Niger Delta are small to medium by world standards and future discoveries, therefore, are likely to reflect this reality. The natural gas resources of the Niger Delta, unlike its oil resources, are comparatively underdeveloped. Parts of the Benue depression in Nigeria and Niger could contain significant deposits of petroleum. The lower Benue depression, immediately north of the Niger Delta, has been extensively explored by drilling. Except for noncommercial discoveries of oil and gas and traces of oil and gas on the ground surface, the results of exploration in the lower Benue depression were negative. However, in the Lake Chad area of Chad and in southern Chad near the Central African Republic boundary, oil and gas discoveries were made just prior to the cessation of all drilling and exploration activity in early 1979. It is rumored that these discoveries may be large although little information is available. The relation between the two areas in Chad and their overall relation to the Benue depression is poorly understood; however, the possibility of thick sedimentary sections containing Cretaceous marine source rock and Tertiary reservoir beds-all contained within grabens in a highly faulted failed-arm system subjected to high heat flow--is attractive. Of the ECOWAS countries, only Nigeria and Niger produce coal commercially. Nigeria produces subbituminous coal from Paleocene-Maestrichtian and Maestrichtian (Late Cretaceous) age rocks of the Niger Delta region; reserves are estimated, on the basis of extensive drilling, to be 350 million tons (standard coal equivalent). In addition, lignite deposits of the Niger Delta appear to be large but have not been developed. Niger produces small amounts of coal used locally by uranium mine and mill operations from C

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