Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “Rock Products”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,009 records · Page 56Linked to original sources

A unique approach to estimating lateral anisotropy in complex geohydrologic environments

Aquifers in fractured rock or karstic settings are likely to have anisotropic transmissivity distributions. Aquifer tests that are performed in these settings also are frequently affected by leakage from adjacent confining units. Finite-difference models such as MODFLOW are convenient tools for estimating the hydraulic characteristics of the stressed aquifer and adjacent confining units but are poor tools for the estimation of lateral anisotropy. This limitation of finite-difference methods can be overcome by application of the spin method, a technique whereby the positions of the observation wells are rotated about the production well to estimate anisotropy and orientation. Formal parameter estimation is necessary to analyze aquifer tests because of the number of parameters that are estimated. As a test, transmissivity, anisotropy, and orientation were successfully estimated for a simple hypothetical problem with known properties. The technique also was applied to estimate hydraulic properties of the Santee Limestone/Black Mingo (SL/BM) aquifer and a leaky confining unit beneath Charleston, South Carolina. A 9-day aquifer test with an average discharge of 6441/min was analyzed numerically. Drawdowns in the SL/BM aquifer and confining unit were simulated with a 12-layer MODFLOW model that was discretized into 81 rows of 81 columns. Simulated drawdowns at seven observation wells that ranged from 23 to 2700 m from the production well were matched to measured drawdowns. Transmissivity estimated along the minor axis ranged from 10 to 15 m 2 /day and along the major axis ranged from 80 to 10Om 2 /day. The major axis of transmissivity was oriented along compass heading 116° (degrees clockwise from north), which agrees with geologic interpretations. Vertical hydraulic conductivity and specific storage estimates for the overlying confining unit were 4 x 10 -5 m/day and 2 x 10 -4 1/m, respectively.

South Carolina↗

Recent surface movements in the Baldwin Hills, Los Angeles County, California

The Baldwin Hills are located in the northwest part of the densely populated Los Angeles basin. They comprise one of several groups of isolated hills that extend along the northwest-trending Newport-Inglewood zone of folds and faults, a structural lineament identified with a series of very productive oil fields. In addition to being the site of the Inglewood oil field, these hills are the site of surface deformation that has been monitored for over 35 years. This record of deformation, which includes differential subsidence, horizontal displacements, and surface rupturing, forms one of the best documented examples of oilfield-associated surface deformation yet recognized. The deformation is described in detail, analyzed as to cause(s), and finally attributed largely or essentially entirely to the exploitation of the spatially-associated Inglewood oil field. The Baldwin Hills are underlain by gently to moderately arched and conspicuously faulted Cenozoic sedimentary and volcanic rocks that overlie crystalline basement rocks at a depth of more than 10,000 feet. The Inglewood fault, a part of the northwest-trending Newport-Inglewood zone, diagonally transects the hills. Right-lateral displacements of 3,000-4,000 feet since middle or late Pliocene time and 1,500-2,000 feet during Quaternary time are indicated by offset structural and physio-graphic features; indications of vertical separations of up to about 200 feet during late Quaternary time occur locally. Evidence of continuing deformation includes recognized seismicity and regional elevation changes. The M5-5 1/2 Inglewood earthquake of 1920, the largest local earthquake of record, is believed to have originated immediately southeast of the Baldwin Hills; it was apparently unassociated with surficial fault displacements. Leveling in and around the west and central Los Angeles basin has shown that lowland stations have been consistently subsiding, whereas foothill stations commonly have been rising. Several seemingly persistent basins of differential subsidence and a zone of positive movement, roughly coincident with the Newport-Inglewood zone, have also been identified in the northwest part of the basin. A prominent, elliptically-shaped, northwest-trending subsidence bowl encompassing the northwest part of the Baldwin Hills, has been defined by repeated level circuits. Partial reconstruction of selected level circuits with respect to a common, relatively stable control point (Hollywood E-11), located on the edge of the subsidence bowl, has permitted evaluation of the subsidence since 1910 and 1911 at two points near the center of the bowl. Thus bench mark PBM 67 is estimated to have subsided approximately 4.324 feet between June 1910 and February 1963; and bench mark PBM 68 (the only bench mark within the subsidence bowl that was leveled prior to 1926 and has been repeatedly leveled since) subsided 3.846 feet between November 1911 and June 1962. Analysis of the available data indicates little if any elevation change at PBM 68 (or elsewhere throughout the Baldwin Hills-Inglewood area) associated with the Inglewood earthquake of 1920. Maximum subsidence of PBM 122 (which has remained very close to the center of subsidence since at . least 1950) between 1911 and 1963 is calculated to have been 5.67 feet. Horizontal displacements (with respect to a north-south base line about 3 miles east of the hills) of six triangulation points within the subsidence bowl have been measured for various periods between 1934 and 1963. Displacements have been generally toward the center of subsidence and almost precisely perpendicular to the immediately adjacent isobases of equal elevation change. Maximum movement has been recorded at triangulation point Baldwin Aux, which was displaced 2.21 feet between 1934 and 1961; horizontal displacements of three additional points ranged from 0.95 foot to 1.85 feet between 1936 and 1961. Displacements of 0.10-0.29 foot were recorded at all six monuments during the period 1961-1963. "Earth cracks" and surficial fault displacements were recognized in the Baldwin Hills at least as early as 1957. The cracks are relatively straight, generally continuous fractures confined to the structural block east of the Inglewood fault; they are concentrated in two areas centering on (1) the Baldwin Hills Reservoir and (2) the Stocker Street-LaBrea Avenue-Overhill Drive intersection. The cracks trend north to north-northeast and are nearly everywhere parallel to or coincident with minor faults and joints, and are generally orthogonal to radii emanating from the center of subsidence. Differential movement along the cracks has been almost entirely dip slip along steep to nearly vertical surfaces, and generally down-dropped toward the center of subsidence. Cumulative displacements have been as much as 6 or 7 inches. Rates of displacement have ranged widely, and the movement has generally occurred as creep or very small discrete jumps. A probable exception is the several inches of differential movement that is believed to have occurred along a crack through the floor of the Baldwin Hills Reservoir on or about December 14, 1963. The contemporary surface movements are attributable to one or more of the following phenomena: (1). exploitation of the Inglewood oil field; (2) changes in the ground-water regimen; (3) compaction of sedimentary materials in response to surface loading; (4) tectonic activity. The following considerations indicate that the differential subsidence is attributable largely or entirely to exploitation of the underlying Inglewood oil field: (1) the coincidence of the centers of the oil field, the producing structure, and the subsidence bowl; (2) the general correspondence between the pattern of subsidence and the outlines of the oil field; (3) the approximate coincidence between the initiation of production and the initiation of subsidence; (4) the generally linear relations between various measures of subsidence and liquid production from both the field as a whole and the exceptionally prolific Vickers zone in particular; (5) the sharp deceleration of subsidence in the eastern block of the field coincident with the initiation of full-scale water flooding there; (6) the many examples of oil fields In which both spatial and temporal associations between production and subsidence are recognized; (7) the many similarities of the subsidence-production relations in the Inglewood field to those in the Wilmington field, where the subsidence has been authoritatively attributed to oilfield operations; (8) the theoretical relation between subsidence or a tendency toward subsidence and increased effective pressure associated with underground fluid extraction. Consideration of six possible explanations for the increasing rather than decreasing or constant rate of subsidence with respect to reservoir fluid pressure decline suggests that measured or calculated down-hole reservoir fluid pressure decline is non-representative of average or real fluid pressure decline away from producing wells. The near-linear relations between net-liquid production and subsidence are explained through analogy with a tightly confined artesian system of infinite areal extent, where production must derive from liquid expansion and/or reservoir compaction. Test data from compaction studies in two other oil fields yield estimates of ultimate compaction of the Vickers zone resulting from a total loss of fluid pressure; these estimates range over an order of magnitude. The best estimate, based on these data and considerations of late Cenozoic history in the Baldwin Hills area, is about 10 feet. The centripetally-directed horizontal movements are considered attributable to exploitation of the Inglewood oil field on the basis of: (1) their well-defined symmetrical and geometrical association with the differential subsidence; (2) the similarities between these associations and those developed in and around other subsiding oil fields; and (3) the mechanical compatibility of these movements with subsidence induced by the extraction of subsurface materials. The earth cracks and surficial fault displacements are considered largely or entirely attributable to the exploitation of the Inglewood oil field on the basis of: (1) their spatial and temporal relations to both oil-field operations and the differential subsidence; (2) the similarities of these cracks and displacements to those generated in and around other oil fields and areas of subsurface materials extraction; and (3) surface strain patterns predicted from the measured vertical and horizontal surface movements. The cracks and displacements can i)e explained by an exploitation-based, elastic-rebound model which requires elastic compression of the sedimentary section in response to compaction-induced downdrag within those blocks around the periphery of the subsidence bowl. The measured displacements have been about one-quarter to one-half those predicted for a purely elastic system. Analysis of: (1) the history of ground-water extraction within and around the Baldwin Hills; and (2) subsidence associated with water-level declines in sediments comparable with those in the Baldwin Hills, indicate that the surface movements can be no more than incidentally attributed to changes in ground-water conditions. Similarly, analysis of the history of natural and artificial changes in surface loading indicate that these movements are generally unassociated with changes in surface loading conditions. Considerations of local geologic history and various tectonic associations indicate that it is very unlikely that the differential subsidence and horizontal movements are due to tectonic downwarping. There exists a far stronger prima facie argument for tectonic involvement in the earth cracking and associated fault displacements. This argument is disputed by; (1) the spatial and temporal relations of the earth cracks to, and their mechanical compatibility with, the nontectonic differential subsidence; (2) the absence of displacements on the Inglewood fault in conjunction with those along the conjugate earth cracks; (3) the probability that purely tectonic displaceMents would be characterized by oblique or strike slip; and (4) the absence of any clear temporal relation between crack growth and local seismicity, However, because as much as 10 percent of the local isobase gradient may be unexplained' by oil-field exploitation, a small fraction of this gradient, and thus the displacements among the southern group of cracks, may be attributable to tectonic activity. This fraction should have been insignificant in the presence of the strain pattern produced by nontectonic compaction of the underlying oil measures. Because nearly all of the observed and measured surface movements can be fully explained as the products of oil-field operations, yet can be no more than incidentally attributed to changes in ground-water conditions, surface loading, or tectonic activity, we conclude that these movements are attributable largely or essentially entirely to the exploitation of the Inglewood oil field.

California↗

California State Waters Map Series — Offshore of Pacifica, California

In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow (to about 100 m) subsurface geology. The Offshore of Pacifica map area is located in northern California, on the Pacific coast of the San Francisco Peninsula about 10 kilometers south of the Golden Gate. The map area extends from Daly City, through Pacifica, to the small coastal community of Montara. Much of the coastal zone is managed by either the State of California or local governments, including Thornton Beach State Park, Mussel Rock Park, Pacifica State Beach, Gray Whale Cove State Beach, and Montara State Beach. The major structure in the transform boundary between the Pacific and North American tectonic plates, the northwest-striking San Andreas Fault, cuts through the map area, crossing the shoreline near Mussel Rock before continuing offshore. The epicenter of the great 1906 California earthquake is located on the offshore part of the San Andreas Fault Zone a few kilometers north of the map area. The map area is located at the northwest end of the Santa Cruz Mountains, much of which has been uplifted in the last 400,000 years. Southwest of the San Andreas Fault Zone, this uplift has resulted in a highly variable coastal morphology characterized by long, narrow beaches bounded by steep cliffs or marine terraces, small pocket beaches surrounded by rocky promontories, and steep, narrow coastal watersheds. Geologic units mapped along the coast include sedimentary, volcanic, and metamorphic rocks of the Franciscan Complex; Cretaceous granitic rocks; Tertiary sedimentary rocks; and Quaternary coastal marine terraces, deep-seated and shallow landslides, and beach and sand dune deposits, all of which contribute sediment to the coastal zone. In contrast to the more rural coastal zone to the south, the highly urbanized coastal zone north of Mussel Rock and the San Andreas Fault Zone is characterized by a narrow beach bounded by steep, 50- to 120-m-high cliffs made up of sand, silt, and clay of the Pliocene and Pleistocene Merced Formation, the source of numerous landslides. Two large landslides along “Northridge bluff” in 2003 and 2007 had estimated volumes of 305,800 to 382,300 m 3 and 120,800 m 3 , respectively. Coastal landslides also are an issue to the south between Mussel Rock and Mori Point, even as bluffs diminish in height and pocket beaches transition to a more continuous strand bounded by Quaternary-age dunes and low-lying marine terraces. Mori Point, a coastal promontory in Pacifica underlain by rocks of the Franciscan Complex, rises abruptly to a height of 90 m from the shoreline. Pocket beaches characterize the shoreline from Mori Point south to Shelter Cove, the largest of which, Pacifica State Beach, is at the mouth of San Pedro Creek. The coastal zone south of Pacifica, which stretches from Shelter Cove to Montara and includes Point San Pedro and Devils Slide, lies at the northwest end of San Pedro Mountain (underlain largely by early Tertiary sedimentary rocks) and Montara Mountain (underlain by Cretaceous granitic rocks). Elevations at Montara Mountain exceed 500 m just 4 km from the shoreline, and steep cliffs along the coast are as high as 275 m. This rugged terrain results in numerous rocky promontories, small pocket beaches, and large coastal landslides. Slope failures along Devils Slide are notorious for closing California Highway 1, creating such a large and persistent problem that the California Department of Transportation has bypassed this coastal section by tunneling through San Pedro Mountain; the tunnel was completed and the new section of highway opened in 2013. Coastal relief diminishes at Montara in the southernmost part of the map area, where the shoreline is bounded by 10- to 20-m-high marine terraces. Throughout the year, this part of the coast is exposed to the north Pacific swell, the southern swell, northwest wind waves, and local wind waves. The north Pacific swell dominates in winter months, having wave heights that range from 2 to 10 m at offshore buoys and wave periods that range from 10 to 25 s. During summer months, the largest waves come from the southern swell, generated by storms in the south Pacific and offshore of Central America. Characteristically, these swells have smaller wave heights (0.3–3 m) but similarly long wave periods (10–25 s). Local wind waves are most common from October to April, whereas northwest wind waves affect the coast throughout the year. These two wind-wave regimes typically have wave heights of 1 to 4 m and short wave periods (3–10 s). Unlike many other parts of the California coast where sediment is supplied primarily from river and (or) stream runoff, sediment supply to the offshore along this part of northern California is a complex mixture of (1) sand transported from the coast north of the Golden Gate, (2) sediment transported to the coast through the San Francisco Bay via the Golden Gate and then dispersed over the adjacent ebb-tide delta, and (3) varying volumes of sediment eroded from adjacent steep coastal bluffs caused by wave-induced landslides and other erosional events. Additionally, since the 1980s, coastal erosion south of the Golden Gate has increased substantially between Ocean Beach (on the west coast of San Francisco, about 5 km north of the map area) and Point San Pedro. The combined sediment load is transported southward along the coast by the generally north-to-south alongshore current, which develops in response to the energetic winter-wave climate associated with the north Pacific swell. Overall, beaches in the map area have a long-term erosional trend, except near Mussel Rock where a long-term accretionary trend may reflect increased sediment supply from landslides. Beach-front riprap armoring and retaining walls are used locally to protect the shoreline from seasonal storm waves, most notably between Mussel Rock and Mori Point. The continental shelf in the map area is about 40 km wide, with water depths at the shelf break that range from about 80 to 120 m. Within California’s State Waters, the midshelf to inner shelf areas are characterized by a relatively flat, shallow (water depths of as much as 44 m) seafloor that dips gently (about 0.2° to 0.3°) westward. The seafloor is composed primarily of unconsolidated Holocene sediment (marine deposits), as well as some nearshore bedrock outcrops that consist primarily of rocks of the Tertiary Purisima Formation and also Cretaceous plutonic rocks (granite or granodiorite).

California↗

Hydrogeology, Aquifer Geochemistry, and Ground-Water Quality in Morgan County, West Virginia

Private and public wells throughout Morgan County, W. Va., were tested to determine aquifer hydraulic, geochemical, and water-quality characteristics. The entire study area is located in the Valley and Ridge Physiographic Province, a region of complex geologic structure and lithology. Aquifers in the study area are characterized by thin to thick bedded formations with interbedding among the various limestones, shales, sandstones, and siltstones that are folded into a series of steeply dipping north-south trending anticlines and synclines. Zones of ground-water production typically consist of one to two fracture sets, with little to no production from unfractured bedrock matrix. Measurements of transmissivity range from 2 to 1,490 feet squared per day, with the larger transmissivities occurring near bedding contacts and in zones with cross-faulting or jointing. Ground water flows from recharge areas in the uplands to local drainages and to deeper flow systems that appear to be controlled by regional geologic structure. The overall flow direction is from south to north within the study area. Ground water within the study area is predominantly a calcium-bicarbonate type water reflecting contact with carbonate rocks. Sodium-bicarbonate and calcium-magnesium-sulfate end-members also exist, with many samples exhibiting mixing, which may be the result of flow between the differing rock types or within units containing both carbonate rocks and shales. Values of water-quality characteristics that were greater than U.S. Environmental Protection Agency drinking-water standards included radon-222, pH, turbidity, iron, manganese, aluminum, and total- and fecal-coliform and Escherichia coli (E. coli) bacteria. Concentrations of radon-222 were detected in all samples from all units, with the largest concentrations (1,330 and 2,170 picocuries per liter) from the Clinton Formation.

Scientific Investigations Report↗

Carnotite resources of Outlaw Mesa, Mesa County, Colorado

The U.S. Geological Survey explored Outlaw Mesa for carnotite deposits from 1949 through 1951 with 1,302 diamond-drill holes that totaled 222,150 feet. Total production from Outlaw Mesa from 1914 through 1951 was about 30,000 short tons of carnotite ore, having an estimated grade of about 0.40 percent U3O8 and 1.7 percent V205. The known carnotite deposits are in a number of sandstone lenses in the upper part of the Salt Wash sandstone member of the Jurassic Morrison formation. The deposits are mainly impregnations of sandstone by carnotite and vanadium-bearing clay minerals. Commonly, the deposits are irregular tabular layers or pod-like or crescentic masses ("rolls") connected by thin layers of mineralized rock. The deposits and rolls have a dominant northeasterly trend. Useful criteria for recognizing-sandstone that might contain mineralized rock are: (1) thick, light-brown sandstone, (2) gray mudstone at the base of and in this sandstone, and (3) abundant carbonaceous material. The indicated and inferred reserves of carnotite-bearing material, and the pounds of contained U308 and V205 are summarized in table 1. Potential reserves, whose existence is based on geologic evidence alone, are estimated to total about 80,000 short tones, averaging about 0.35 percent U308 and 1.5percent V205. No further exploration by the Geological Survey is planned; however, additional drilling by private operators is recommended, particularly in ground underlain by mineralized rock.

Colorado↗

Geology and ground water of the Savannah River Plant and vicinity, South Carolina

The area described in this report covers approximately 2,600 square miles in west-central South Carolina and includes the site of the Savannah River Plant, a major production facility of the U.S. Atomic Energy Commission. The climate, surface drainage, and land forms of the study area are typical of the southern part of the Atlantic Coastal Plain. Precipitation is normally abundant and fairly evenly distributed throughout the year, and the mean annual temperature is moderately warm (64?F). The major streams that drain the area (the Savannah, Salkehatchie, and Edisto Rivers) have low gradients and flow in a southeasterly direction toward the Atlantic Ocean. Surface features of the area include narrow, flat-bottomed, steep-sided valleys and broad gently rolling interfluvial areas. Those parts of the Coastal Plain included within the report area can be subdivided into the Aiken Plateau, the Congaree Sandhills, and the Coastal Terraces. The area is underlain by a sequence of unconsolidated and partly consolidated sediments of Late Cretaceous, Tertiary, and Quaternary age. The unconsolidated sediments were deposited unconformably on a basement of igneous and metamorphic rocks of Precambrian and Paleozoic age and sedimentary rocks of Triassic age. The basement rocks are similar to the granite-diorite complex of the Charlotte Belt, the metamorphosed rocks of the Carolina Slate Belt, and the consolidated sediments of the Newark Group. The unconsolidated sediments strike about N. 60 ? E. and dip 6-20 feet per mile to the southeast. They form a wedge-shaped mass that increases in thickness toward the southeast to slightly more than 1,200 feet in the vicinity of Allendale, S.C., on the southeast or downdip side of the study area. The oldest or lowermost unconsolidated sedimentary unit, the Tuscaloosa Formation of Late Cretaceous age, is overlain in the subsurface by beds that are also probably Late Cretaceous in age and that herein are named the Ellenton Formation. The Upper Cretaceous deposits are, in turn, overlain by the, McBean Formation and the Congaree(?) Formation of middle Eocene age, the Barnwell Formation of late Eocene age, the Hawthorn Formation of early and middle Miocene age, and by fluvial and marine(?) terrace deposits of Pliocene(?), Pleistocene, and Recent age. In the mapped area, the Congaree(?) Formation includes undifferentiated rocks (mostly Congaree and Barnwell Formations and some Mcbean outliers). (See map explanation.) Structurally, the Upper Cretaceous sediments are overlapped to the northwest by Tertiary deposits. A preliminary geologic map of the general area is included in the report. The principal aquifer in the area is composed of the beds of medium to coarse sand and gravel contained in the Tuscaloosa and Ellenton Formations. Subordinate aquifers include deposits of sand and limestone of Tertiary and Quaternary age. The ground water in the principal aquifer occurs under water-table conditions in the outcrop area of the Tuscaloosa Formation in the northern and western parts of the study area, but it is under artesian pressure downdip in the southern and eastern parts of the study area. Contours drawn on the piezometric surface of the water in the principal aquifer indicate that water is recharged to the aquifer mainly by leakage through the overlying Tertiary formations. Likewise, the piezometric contours show that the outcrop area of the Tuscaloosa Formation functions chiefly as an area of discharge. Doubtless, water is also discharged from the aquifer by moving downdip to areas near the coast where the prevailing hydraulic gradient may favor the upward leakage of water through the upper confining beds. The hydraulic properties of the principal aquifer were determined by a series of pumping tests. The results indicate that the aquifer is highly productive and could supply 15 million gallons per day in the vicinity of the Savannah River Plant without exceeding the available drawdown.

South Carolina↗

Composition and origin of Early Cambrian Tiantaishan phosphorite-Mn carbonate ores, Shaanxi Province, China

The Tiantaishan phosphorite-Mn carbonate ores occur in the Early Cambrian Tananpo Formation in complexly folded and faulted rocks located in southern Shaanxi Province. About 65 x 106 tonnes of 17% P2O5 ore reserves exist and Mn-ore reserves are about 8.3 x 106 tonnes of +18% Mn. The stratigraphic sequence in ascending order consists of black phyllite, black to gray phosphorite ore, black phyllite, rhodochrostone ore, Mn mixed-carbonates, and dolostone. Data are presented from microprobe mineral chemistry, whole-rock chemistry, stable isotopes of carbonates, X-ray mineralogy, petrographic and SEM observations, and statistical analysis of chemical data. The dominant ore-forming minerals are hydroxy- and carbonate fluorapatite and Ca rhodochrosite, with Mg kutnahorite and dolomite comprising the Mn mixed-carbonate section. Pyrite occurs in all rock types and alabandite (MnS) occurs throughout the rhodochrostone section. The mean P2O5 content of phosphorite is 31% and argillaceous phosphorite is 16%, while the mean MnO content of rhodochrostone ore is 37%. Phosphorite ores are massive, spheroidal, laminated, and banded, while rhodochrostone ores have oolitic, spheroidal, and granular fabrics. The most distinguishing characteristics of the ores are high total organic carbon (TOC) contents (mean 8.4%) in the phosphorite and high P2O5 contents (mean 2.7%) in the rhodochrostone ore. The atypically high TOC contents in the Tiantaishan phosphorite probably result from very strong productivity leading to high sedimentation rates accompanied by weak reworking of sediments; poor utilization of the organic matter by bacteria; and/or partial replacement of bacterial or algal mats by the apatite. The depositional setting of the ores was the margin of an epicontinental seaway created as a direct consequence of global processes that included break-up of a supercontinent, formation of narrow seaways, creation of extensive continental shelves, overturn of stagnant, metal-rich deep-ocean waters, and marine transgression. Water depth increased from deposition of the black phyllite sequence through deposition of the Mn mixed-carbonate sequence, then shallowed again during deposition of the overlying dolostone sequence. Bottom waters were mostly dysoxic to suboxic, but fluctuated from oxic to anoxic. Productivity was high during deposition of the black phyllite sequence, increased during precipitation of phosphorite, and then decreased to moderate levels during precipitation of rhodochrostone ores. Biosilica contributions occur in each lithology, but are greatest in rhodochrostone. Changes in sedimentation were determined by changes in water depth, productivity, upwelling, sea-level change, and ventilation of the depositional basin. The source of the phosphorus was organic matter produced in great quantities during deposition of the black phyllite and phosphorite sequences in a zone of coastal upwelling. Organic matter accumulation was rapid. Globally, Mn was supplied by overturn of stagnant, metal-rich deep-ocean waters, which were redistributed to areas of coastal upwelling and seaways; that process may have been initiated by latest Proterozoic glaciations which would have promoted density stratification and accumulation and storage of metals. Regionally, Mn was supplied by terrigenous input into the shallow seaway and hydrothermal input into the deeper water parts of that seaway. Locally, Mn sources included leaching and transport of metals from the sediment column. Manganese was stored locally in low-oxygen (not anoxic) seawater prior to Mn-ore formation. The source of the carbon in the Mn carbonates and dolostones was predominantly seawater bicarbonate and secondarily CO2 derived from the oxidation of organic matter in the bacterially mediated diagenetic zone of sulfate reduction.

Ore Geology Reviews↗

Occurrence and geochemistry of natural gases, Piceance Basin, northwest Colorado

The Piceance basin is a hydrocarbon-rich province that has natural gas production from reservoirs ranging in age from Late Jurassic to Eocene and large undeveloped resources of natural gas in coal beds and tight sandstone reservoirs of Cretaceous age. Gases from all producing intervals are of predominantly thermal origin and become isotopically heavier (delta isotope{13}C[1]: -51.3 to -29.1 o/oo) and chemically drier (C[1]/C[1-5]: 0.26 to 1.00) with increasing thermal maturity of reservoirs (R[o]: 0.45 to 2.40%) over a depth range of 1100 to 11,702 ft (335-3567 m). Scatter in trend is attributed to source rock differences and considerable vertical and lateral migration. Based on chemical and isotopic composition, three major types of gases can be distinguished: those generated from mixed type II and III kerogens, those from dispersed type III kerogen, and those from coal. Gases generated from mixed type II and III kerogens are produced from the Upper Jurassic Morrison Formation, the Lower Cretaceous Cedar Mountain Formation, the Upper Cretaceous Dakota Sandstone, the Upper Cretaceous Mancos "B" producing interval, and marginal marine sandstones of the Upper Cretaceous Iles producing interval. These gases are associated with minor amounts of oil and probably were generated from kerogen in the marine Mancos Shale. Gases generated from dispersed type III kerogen are produced from nonmarine sandstones of the Upper Cretaceous Williams Fork producing inter al and from thermally immature reservoirs in the overlying Paleocene and Eocene Fort Union and Wasatch Formations. These nonassociated gases contain large amounts of CO[2] and probably were generated from carbonaceous shales in the Williams Fork producing interval. Their presence in immature Fort Union and Wasatch reservoirs implies considerable vertical migration. The third type of gas is methane rich, is produced by devolatilization of humic coal, and is generally in coal beds of the Cameo-Fairfield zone of the Williams Fork producing interval. These gases are not the major source for adjacent sandstone reservoirs. A fourth, distinct type of isotopically light thermogenic gas occurs in immature reservoirs of the Eocene Green River Formation. This gas is inferred to have migrated from u identified deeper, more mature source rocks.

Colorado↗

Petroleum geology and resources of northeastern Mexico

Petroleum deposits (primarily gas) in northeastern Mexico occur in two main basins, the Tertiary Burgos basin and the Mesozoic Sabinas basin. About 90 gas fields are present in the Burgos basin, which has undergone active exploration for the past 30-40 years. Production in this basin is from Oligocene and Eocene nearshore marine and deltaic sandstone reservoirs. Most of the fields are small to medium in size on faulted anticlinal or domal structures, some of which may be related to deep-seated salt intrusion. Cumulative production from these fields is about 4 trillion cubic feet gas and 100 million barrels condensate and oil. Since 1975, about 10 gas fields, some with large production rates, have been discovered in Cretaceous carbonate and Jurassic sandstone reservoirs in the Sabinas basin and adjacent Burro-Picachos platform areas. The Sabinas basin, which is in the early stages of exploration and development, may have potential for very large gas reserves. The Sabinas basin is oriented northwesterly with a large number of elongate northwest- or west-trending asymmetric and overturned Laramide anticlines, most of which-are faulted. Some of the structures may be related to movement of Jurassic salt or gypsum. Lower Cretaceous and in some cases Jurassic rocks are exposed in the centers of the larger anticlines, and Upper Cretaceous rocks are exposed in much of the remainder of the basin. A thick section of Upper Cretaceous clastic rocks is partly exposed in tightly folded and thrust-faulted structures of the west-east oriented, deeply subsided Parras basin, which lies south of the Sabinas basin and north of the Sierra Madre Oriental fold and thrust belt south and west of Monterrey. The sedimentary cover of Cretaceous and Jurassic rocks in the Sabinas and Parras basins ranges from about 1,550 m (5,000 ft) to 9,000 m (30,000 ft) in thickness. Upper Jurassic rocks are composed of carbonate and dark organic shaly or sandy beds underlain by an unknown thickness of Late Jurassic and older redbed clastics and evaporites, including halite. Lower Cretaceous rocks are mainly platform carbonate and fine clastic beds with some evaporites (gypsum or anhydrite) deposited in two main rudist reef-bearing carbonate cycles. Upper Cretaceous rocks are mainly continental and marine clastic beds related to early development of the Laramide orogeny. This Upper Cretaceous sequence contains a marine shale and deltaic clastic complex as much as 6,000 m (20,000 ft) or more thick in the Parras basin, which grades northward and eastward to open marine, fine clastic beds. The Burgos basin, which is an extension of the Rio Grande embayment of the western Gulf of Mexico basin province, contains an eastward-thickening wedge of Tertiary continental and marine clastics. These beds are about 1,550 to 3,000 m (5,000-10,000 ft) thick in the outcrop belt on the west side of the basin and thicken to more than 16,000 m (50,000 ft) near the Gulf Coast.

Circular↗

Tests and researches on building stones

In 1941, the "Association Francaise de Normalisation" (French Association of Standardization) decided to create a Commission for the purpose of writing out a standard for building stones. When this Commission met under the chairmanship of Mr. Pol Abraham, Architect, they realized how far behind was our precise technical knowledge of this kind of material, and found the necessity of determining exactly the testing and acceptance methods. They expressed the wish that a careful study of the subject be entrusted to a specialized laboratory. This wish was received by the Ministry of Production, which, after an agreement with the competent organizing committees, entrusted our laboratory with this work. The main object was to establish the difficulty of stone-cutting in order to permit a classification of the stones according to the difficulty met when working them up into shape, to refer the other technical properties of the stones to this property, and finally to see what relation exists between the figures obtained. To this end nine stones were chosen by the Commission, from the hardest to the softest: Hauteville, Comblanchien, spotted Larrys, yellow Massangis rock, Euville rock, fine-grained Lavoux, soft Maximin rock, "banc royal" Mery, and "bane royal" Billy. Each type of stone included three large blocks of 0.75 by 0.75 by 0.5 meters to be dressed by hand by specialized workmen, the difficulty of stone-cutting being determined by the time spent for the dressing and preparation of the surfaces. After this operation, detail of which will be given later, we had an important quantity of material which we were to use to the best advantage. I thought that it would be interesting to determine on each one the maximum of physical, chemical and mechanical tests in order not only to be able to compare them in precise conditions, but also to set up each sample as a standard intended for future studies. In other words, each element in the mentioned list must, in my mind, be able to serve in the future as reference to which we will compare the other kinds of calcareous stones used for building. As all the available material was not used, we were able to keep some as a reserve in case later comparisons would be necessary.

Open-File Report↗

Aeromagnetic map of northwest Utah and adjacent parts of Nevada and Idaho

Two aeromagnetic surveys were flown to promote further understanding of the geology and structure in northwest Utah and adjacent parts of Nevada and Idaho by serving as a basis for geophysical interpretations and by supporting geological mapping, water and mineral resource investigations, and other topical studies. Although this area is in general sparsely populated, (except for cities and towns along the Wasatch Front such as Ogden and Brigham City), it encompasses metamorphic core complexes in the Grouse Creek and Raft River Mountains (figure 1) of interest to earth scientists studying Cenozoic extension. The region was shaken in 1909 and 1934 by M6+ earthquakes east of the Hansel Mountains (Doser, 1989; Arabasz and others, 1994); damage from the 1934 earthquake occurred as far east as Logan, Utah (http:// www.seis.utah.edu/lqthreat/nehrp_htm/1934hans/n1934ha1. shtml#urbse). The presence of Quaternary shield volcanoes and bimodal Pleistocene volcanism in Curlew Valley (Miller and others, 1995; Felger and others, 2016) as well as relatively high temperature gradients encountered in the Indian Cove drillhole in the north arm of Great Salt Lake (Blackett and others, 2014) may indicate some potential for geothermal energy development in the area (Miller and others, 1995). The area also hosts four significant mining districts, in the northern Pilot Range, the Goose Creek Mountains in the northwest corner of the map, the southern end of the Promontory Mountains, and the southwest part of the Raft River Mountains, although production notably waned after World War II (Doelling, 1980). Other prospects of interest include those in the southern Grouse Creek Mountains, Silver Island, and the northern Newfoundland Mountains. Large areas of northwest Utah are covered by young, surficial deposits or by Great Salt Lake or are down-dropped into deep Cenozoic basins, making extrapolation of bedrock geology from widely spaced exposures difficult or tenuous (figure 1). Local spatial variations in the Earth's magnetic field (evident as anomalies on aeromagnetic maps) reflect the distribution of magnetic minerals, primarily magnetite, in the underlying rocks. In many cases the volume content of magnetic minerals can be related to rock type, and abrupt spatial changes in the amount of magnetic minerals commonly mark lithologic or structural boundaries. Magnetic data reflect magnetization variations within the crust and are well suited for mapping the distribution of mafic igneous rocks, although felsic igneous rocks, some mineralized zones, and other rock types also can produce measurable magnetic anomalies. For these reasons, the U.S. Geological Survey (USGS) and Utah Geological Survey (UGS) contracted for the collection of aeromagnetic data in this area.

Idaho, Nevada, Utah↗

Geology of El Chichon volcano, Chiapas, Mexico

The (pre-1982) 850-m-high andesitic stratovolcano El Chicho??n, active during Pleistocene and Holocene time, is located in rugged, densely forested terrain in northcentral Chiapas, Me??xico. The nearest neighboring Holocene volcanoes are 275 km and 200 km to the southeast and northwest, respectively. El Chicho??n is built on Tertiary siltstone and sandstone, underlain by Cretaceous dolomitic limestone; a 4-km-deep bore hole near the east base of the volcano penetrated this limestone and continued 770 m into a sequence of Jurassic or Cretaceous evaporitic anhydrite and halite. The basement rocks are folded into generally northwest-trending anticlines and synclines. El Chicho??n is built over a small dome-like structure superposed on a syncline, and this structure may reflect cumulative deformation related to growth of a crustal magma reservoir beneath the volcano. The cone of El Chicho??n consists almost entirely of pyroclastic rocks. The pre-1982 cone is marked by a 1200-m-diameter (explosion?) crater on the southwest flank and a 1600-m-diameter crater apparently of similar origin at the summit, a lava dome partly fills each crater. The timing of cone and dome growth is poorly known. Field evidence indicates that the flank dome is older than the summit dome, and K-Ar ages from samples high on the cone suggest that the flank dome is older than about 276,000 years. At least three pyroclastic eruptions have occurred during the past 1250 radiocarbon years. Nearly all of the pyroclastic and dome rocks are moderately to highly porphyritic andesite, with plagioclase, hornblende and clinopyroxene the most common phenocrysts. Geologists who mapped El Chicho??n in 1980 and 1981 warned that the volcano posed a substantial hazard to the surrounding region. This warning was proven to be prophetic by violent eruptions that occurred in March and April of 1982. These eruptions blasted away nearly all of the summit dome, blanketed the surrounding region with tephra, and sent pyroclastic flows down radial drainages on the flanks of the cone; about 0.3 km3 of material (density of all products normalized to 2.6 g cm-3) was erupted. More debris entered the stratosphere than from any other volcanic eruption within at least the past two decades. Halite and a calcium sulfate mineral (anhydrite?) recovered from the stratospheric cloud, and anhydrite as a common accessory mineral in 1982 juvenile erupted products may reflect contamination of El Chicho??n magma by the evaporite sequence revealed by drilling. ?? 1984.

Journal of Volcanology and Geothermal Research↗

A far-traveled basalt lava flow in north-central Oregon, USA

Widely separated basalt lava-flow outcrops in north-central Oregon, USA, expose products of a single eruptive episode. A Pliocene lava flow, here informally termed the Tetherow basalt, issued from vents near Redmond, in the Deschutes basin of Oregon, as a plains-forming basalt now exposed in continuous outcrops northward for 60 km. A similar basalt crops out 47 km farther north, near Maupin, within what was then a slightly incised ancestral Deschutes River canyon. The northernmost outcrops of this lava flow lie on Fulton Ridge, in the Dalles basin, near the confluence of the Deschutes and Columbia Rivers. Complementary lines of evidence confirm these rocks are all from the same volcanic eruption. Outcrops in the Deschutes and Dalles basins are chemically similar high-titanium basalts, petrographically similar to each other and distinct from other lava flows in the area. Paleomagnetic directions from 11 scattered sites are similar and indistinguishable by various tests for a common mean. Three new 40 Ar/ 39 Ar ages indicate the Tetherow basalt eruption occurred between 5.5 Ma and 5.0 Ma, likely at ca. 5.2 Ma. The widely separated outcrops of this lava flow span 160–180 km along the ancestral Deschutes River and downstream Columbia River. The lava flow’s length and erupted volume of 15–20 km 3 are extraordinarily large in a non-flood-basalt setting. This lava flow provides a datum with which to describe regional physiographic history, assess incision rates, and infer tectonic history. Spanning different depositional basins, the Tetherow basalt is a useful chronologic and stratigraphic marker bed.

Oregon↗

Preliminary publications book 2 from project on mineral resources, metallogenesis, and tectonics of northeast Asia

This is the Web version of a CD-ROM publication. This report consists of summary major compilations and syntheses accomplished in the six-year project through April 2003 for the study on the Mineral Resources, Metallogenesis, and Tectonics of Northeast Asia (Eastern and Southern Siberia, Mongolia, Northeastern China, South Korea, and Japan). The major scientific goals and benefits of the project are to: (1) provide a comprehensive international data base on the mineral resources of the region that is the first, extensive knowledge available in English; (2) provide major new interpretations of the origin and crustal evolution of mineralizing systems and their host rocks, thereby enabling enhanced, broad-scale tectonic reconstructions and interpretations; and (3) promote trade and scientific and technical exchanges between the North America and Northeast Asia. Data from the project are providing sound scientific data and interpretations for commercial firms, governmental agencies, universities, and individuals that are developing new ventures and studies in the project area, and for land-use planning studies that deal with both mineral potential issues. Northeast Asia has vast potential for known and undiscovered mineral deposits; however, little information existed in English in the West until publication of products from this project. Consequently, data and interpretations from the project are providing basic knowledge for major scientific, commercial, national, and international endeavors by other interested individuals and groups.

Siberia↗

Deposit model for heavy-mineral sands in coastal environments

This report provides a descriptive model of heavy-mineral sands, which are sedimentary deposits of dense minerals that accumulate with sand, silt, and clay in coastal environments, locally forming economic concentrations of the heavy minerals. This deposit type is the main source of titanium feedstock for the titanium dioxide (TiO 2 ) pigments industry, through recovery of the minerals ilmenite (Fe 2+ TiO 3 ), rutile (TiO 2 ), and leucoxene (an alteration product of ilmenite). Heavy-mineral sands are also the principal source of zircon (ZrSiO 4 ) and its zirconium oxide; zircon is often recovered as a coproduct. Other heavy minerals produced as coproducts from some deposits are sillimanite/kyanite, staurolite, monazite, and garnet. Monazite [(Ce,La,Nd,Th)PO 4 ] is a source of rare earth elements as well as thorium, which is used in thorium-based nuclear power under development in India and elsewhere. The processes that form coastal deposits of heavy-mineral sands begin inland. High-grade metamorphic and igneous rocks that contain heavy minerals weather and erode, contributing detritus composed of sand, silt, clay, and heavy minerals to fluvial systems. Streams and rivers carry the detritus to the coast, where they are deposited in a variety of coastal environments, such as deltas, the beach face (foreshore), the nearshore, barrier islands or dunes, and tidal lagoons, as well as the channels and floodplains of streams and rivers in the coastal plain. The sediments are reworked by waves, tides, longshore currents, and wind, which are effective mechanisms for sorting the mineral grains on the basis of differences in their size and density. The finest-grained, most dense heavy minerals are the most effectively sorted. The result is that heavy minerals accumulate together, forming laminated or lens-shaped, heavy-mineral-rich sedimentary packages that can be several meters and even as much as tens of meters thick. Most economic deposits of heavy-mineral sands are Paleogene, Neogene, and Quaternary in age; some are modern coastal deposits. Superimposed on these basic processes of ore formation are a multitude of contributing and modifying factors, such as the following: Strong, sustained wave action moves sand from offshore to the shore, where the sand and heavy minerals are sorted by size and density. Mineral sorting occurs mainly on the upper part of the hightide swash (wave) zone. Fine-grained sands and heavy minerals on the foreshore can be remobilized by winds, forming heavy mineral-rich sand dunes behind the beach. Longshore drift combined with the geomorphology of the coast exert strong influence on the location of the heavy-mineral sands deposits. Sea level changes are a function of climatic changes, such as ice ages. Rises in regional sea level (transgression) and lowering of sea level (regression) strongly influence the deposition and preservation of heavy-mineral sands. The majority of heavy-mineral sands accumulation appears related to seaward progradation of the shore during regression events. Local faulting may affect the geomorphology of the coast, which controls the distribution of heavy mineral deposition in a coastal basin. Heavy mineral grains appear to weather primarily after their deposition in the coastal plain; this weathering is caused by groundwaters, humic acids, and other intrabasinal fluids. This weathering can enhance the TiO 2 content of ilmenite. Iron is leached from ilmenite during weathering, which thereby upgrades the TiO 2 content of the ilmenite, forming leucoxene. The resulting deposits of heavy-mineral sands can be voluminous. Individual bodies of heavy mineral-rich sands are typically about 1 kilometer wide and more than 5 kilometers long. Many heavy-mineral sands districts extend for more than 10 kilometers and contain several individual deposits that are spread along an ancient or modern strandline. Reported thicknesses of economic deposits range from 3 to 45 meters. Individual ore deposits typically comprise at least 10 megatonnes of ore (the total size of the individual sand-silt body), whose overall heavy-mineral content is 2 to greater than 10 percent. Heavy-mineral sands deposits are relatively easy to mine because they are weakly to poorly consolidated, and they are relatively easy to process. From a geoenvironmental standpoint, mining of heavy mineral-sands generates little or no acid or solubilized metals. However, environmental and human health concerns related to such mining include potential effects on indigenous flora and fauna, effects on local hydrology, and issues related to processing and storing thorium-bearing monazite, owing to its radioactivity. Regional exploration for deposits of heavy-mineral sands can utilize the analyses of stream sediment samples for Ti, Hf, the rare earth elements, Th, and U, and geophysical surveys, particularly radiometric (gamma-ray spectrometry for K, U, and Th) and magnetic methods. Geophysical anomalies may be small, and surveys are generally more successful when conducted close to sources of interest.

Scientific Investigations Report↗

Surface monitoring of microseismicity at the Decatur, Illinois, CO2 sequestration demonstration site

Sequestration of CO2 into subsurface reservoirs can play an important role in limiting future emission of CO2 into the atmosphere (e.g., Benson and Cole, 2008). For geologic sequestration to become a viable option to reduce greenhouse gas emissions, large-volume injection of supercritical CO2 into deep sedimentary formations is required. These formations offer large pore volumes and good pore connectivity and are abundant (Bachu, 2003; U.S. Geological Survey Geologic Carbon Dioxide Storage Resources Assessment Team, 2013). However, hazards associated with injection of CO2 into deep formations require evaluation before widespread sequestration can be adopted safely (Zoback and Gorelick, 2012). One of these hazards is the potential to induce seismicity on pre-existing faults or fractures. If these faults or fractures are large and critically stressed, seismic events can occur with magnitudes large enough to pose a hazard to surface installations and, possibly more critical, the seal integrity of the cap rock. The Decatur, Illinois, carbon capture and storage (CCS) demonstration site is the first, and to date, only CCS project in the United States that injects a large volume of supercritical CO2 into a regionally extensive, undisturbed saline formation. The first phase of the Decatur CCS project was completed in November 2014 after injecting a million metric tons of supercritical CO2 over three years. This phase was led by the Illinois State Geological Survey (ISGS) and included seismic monitoring using deep borehole sensors, with a few sensors installed within the injection horizon. Although the deep borehole network provides a more comprehensive seismic catalog than is presented in this paper, these deep data are not publicly available. We contend that for monitoring induced microseismicity as a possible seismic hazard and to elucidate the general patterns of microseismicity, the U.S. Geological Survey (USGS) surface and shallow borehole network described below provides an adequate event detection threshold. The formation targeted for injection is the Mount Simon Sandstone, which is laterally extensive, has high porosity and permeability and has the potential to host future CCS projects due to its favorable hydrologic characteristics and proximity to industrial sources of CO2 (Birkholzer and Zhou, 2009). At Decatur, CO2, a byproduct of ethanol production at the Archer Daniels Midland (ADM) facility, is compressed to supercritical state and injected at 2.1 km depth into the 460 m thick Mount Simon Sandstone. This sandstone has varying properties, ranging from the lower, fine- to coarse-grained sandstone with high permeability and porosity, to the middle and upper Mount Simon, which consist of planar, cross-bedded layers of varied permeability and porosity (Leetaru and Freiburg, 2014). The changes in permeability and porosity within the Mount Simon Sandstone, due to depositional and diagenetic differences, create horizontal baffles, which inhibit vertical flow and restrict the injected CO2 to remain near the injection horizon (Bowen et al., 2011). The lowest portion of the Mount Simon Sandstone overlying the Precambrian rhyolite basement is the Pre-Mount Simon interval, generally < 15 m in thickness and composed of fine- to medium-grain size sandstone that is highly deformed (Leetaru and Freiburg, 2014). The basement rhyolite has a clayrich matrix and is fractured, with significant alterations within the fractures. The primary sealing cap rock is the Eau Claire Formation, a 100–150 m thick unit at a depth of roughly 1.69 km (Leetaru and Freiburg, 2014). The Maquoketa Shale Group and the New Albany Shale serve as secondary and tertiary seals at shallower depths of ∼820 and ∼650 m, respectively. The ISGS managed the Illinois Basin–Decatur Project (IBDP), a three-year project beginning in November 2011, during which carbon dioxide was injected at a rate of ∼1000 metric tons per day until November 2014 (Finley et al., 2011, 2013). ADM manages the Illinois Industrial CCS (ICCS) project, which will inject ∼3000 metric tons/day into a second injection well starting in the summer of 2015. The USGS began monitoring microseismicity with a 13- station seismic network at Decatur in July 2013 (Fig. 1). This network provides good detection capabilities and azimuthal (focal sphere) coverage for microseismicity with moment magnitudes (Mw) above about −0:5. Here, we report on 19 months of microseismicity monitoring at the Decatur CO2 sequestration site, which permits a detailed look at the evolution and character of injection-induced seismicity.

Illinois↗

Carbonatite and alkaline intrusion-related rare earth element deposits&ndash;A deposit model

The rare earth elements are not as rare in nature as their name implies, but economic deposits with these elements are not common and few deposits have been large producers. In the past 25 years, demand for rare earth elements has increased dramatically because of their wide and diverse use in high-technology applications. Yet, presently the global production and supply of rare earth elements come from only a few sources. China produces more than 95 percent of the world's supply of rare earth elements. Because of China's decision to restrict exports of these elements, the price of rare earth elements has increased and industrial countries are concerned about supply shortages. As a result, understanding the distribution and origin of rare earth elements deposits, and identifying and quantifying our nation's rare earth elements resources have become priorities. Carbonatite and alkaline intrusive complexes, as well as their weathering products, are the primary sources of rare earth elements. The general mineral deposit model summarized here is part of an effort by the U.S. Geological Survey's Mineral Resources Program to update existing models and develop new descriptive mineral deposit models to supplement previously published models for use in mineral-resource and mineral-environmental assessments. Carbonatite and alkaline intrusion-related REE deposits are discussed together because of their spatial association, common enrichment in incompatible elements, and similarities in genesis. A wide variety of commodities have been exploited from carbonatites and alkaline igneous rocks, such as rare earth elements, niobium, phosphate, titanium, vermiculite, barite, fluorite, copper, calcite, and zirconium. Other enrichments include manganese, strontium, tantalum, thorium, vanadium, and uranium.

Open-File Report↗

Pesticide Occurrence and Distribution in the Lower Clackamas River Basin, Oregon, 2000-2005

Pesticide occurrence and distribution in the lower Clackamas River basin was evaluated in 2000?2005, when 119 water samples were analyzed for a suite of 86?198 dissolved pesticides. Sampling included the lower-basin tributaries and the Clackamas River mainstem, along with paired samples of pre- and post-treatment drinking water (source and finished water) from one of four drinking water-treatment plants that draw water from the lower river. Most of the sampling in the tributaries occurred during storms, whereas most of the source and finished water samples from the study drinking-water treatment plant were obtained at regular intervals, and targeted one storm event in 2005. In all, 63 pesticide compounds were detected, including 33 herbicides, 15 insecticides, 6 fungicides, and 9 pesticide degradation products. Atrazine and simazine were detected in about half of samples, and atrazine and one of its degradates (deethylatrazine) were detected together in 30 percent of samples. Other high-use herbicides such as glyphosate, triclopyr, 2,4-D, and metolachlor also were frequently detected, particularly in the lower-basin tributaries. Pesticides were detected in all eight of the lower-basin tributaries sampled, and were also frequently detected in the lower Clackamas River. Although pesticides were detected in all of the lower basin tributaries, the highest pesticide loads (amounts) were found in Deep and Rock Creeks. These medium-sized streams drain a mix of agricultural land (row crops and nurseries), pastureland, and rural residential areas. The highest pesticide loads were found in Rock Creek at 172nd Avenue and in two Deep Creek tributaries, North Fork Deep and Noyer Creeks, where 15?18 pesticides were detected. Pesticide yields (loads per unit area) were highest in Cow and Carli Creeks, two small streams that drain the highly urban and industrial northwestern part of the lower basin. Other sites having relatively high pesticide yields included middle Rock Creek and upper Noyer Creek, which drain basins having nurseries, pasture, and rural residential land. Some concentrations of insecticides (diazinon, chlorpyrifos, azinphos-methyl, and p,p?-DDE) exceeded U.S. Environmental Protection Agency (USEPA) aquatic-life benchmarks in Carli, Sieben, Rock, Noyer, Doane, and North Fork Deep Creeks. One azinphos-methyl concentration in Doane Creek (0.21 micrograms per liter [?g/L]) exceeded Federal and State of Oregon benchmarks for the protection of fish and benthic invertebrates. Concentrations of several other pesticide compounds exceeded non-USEPA benchmarks. Twenty-six pesticides or degradates were detected in the Clackamas River mainstem, typically at much lower concentrations than those detected in the lower-basin tributaries. At least 1 pesticide was detected in 65 percent of 34 samples collected from the Clackamas River, with an average of 2?3 pesticides per sample. Pesticides were detected in 9 (or 60 percent) of the 15 finished water samples collected from the study water-treatment plant during 2003?2005. These included 10 herbicides, 1 insecticide, 1 fungicide, 1 insect repellent, and 2 pesticide degradates. The herbicides diuron and simazine were the most frequently detected (four times each during the study), at concentrations far below human-health benchmarks?USEPA Maximum Contaminant Levels or U.S. Geological Survey human Health-Based Screening Levels (HBSLs). The highest pesticide concentration in finished drinking water was 0.18 ?g/L of diuron, which was 11 times lower than its low HBSL benchmark. Although 0?2 pesticides were detected in most finished water samples, 9 and 6 pesticides were detected in 2 storm-associated samples from May and September 2005, respectively. Three of the unregulated compounds detected in finished drinking water (diazinon-oxon, deethylatrazine [CIAT], and N, N-diethyl-m-toluamide [DEET]) do not have human-health benchmarks available for comparison. Although most of the 51 curren

Scientific Investigations Report↗