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USGS2018

Preliminary groundwater salinity mapping near selected oil fields using historical water-sample data, central and southern California

The distribution of groundwater salinity was mapped for 31 oil fields and adjacent aquifers and summarized by 8 subregions across major oil-producing areas of central and southern California. The objectives of this study were to describe the distribution of groundwater near oil fields having total dissolved solids less than 10,000 milligrams per liter (mg/L) based on available data and to document where data gaps exist. Salinity was represented by the measured or calculated concentration of total dissolved solids (TDS) in samples of produced water obtained from petroleum wells and groundwater obtained from water wells. The water chemistry data were used to estimate the minimum depths of TDS greater than 3,000 mg/L and greater than 10,000 mg/L in areas near selected oil fields using historical water-chemistry data coupled with available well-location and construction information. The 10,000 mg/L threshold, representing the highest level of TDS concentration of water that could be considered as a potential source of drinking water, was present in all but 4 (Jasmin, Kern Bluff, Kern Front, and Mount Poso) of the 31 individual oil fields. Among petroleum wells, the median TDS concentration of produced water ranged from 500 mg/L for the Jasmin field to 32,636 mg/L for the Elk Hills field. Among water wells, median TDS concentrations, either reported or calculated from specific conductance, ranged from 151 mg/L for wells within 2 miles of the Ten Section field to 9,750 mg/L for wells within 2 miles of the combined North and South Belridge fields. In general, TDS across the eight geographic subregions increased with depth, but the relation of TDS with depth varied regionally. The most pronounced increases in TDS with depth were across the West Kern Valley Floor and West Kern Valley Margin subregions on the west side of the San Joaquin Valley, and in the vicinity of the Wilmington field in the Los Angeles Basin subregion; in these areas, relatively high TDS concentrations greater than 10,000 mg/L were present within the upper few hundred to several thousand feet of land surface. Total dissolved solids concentrations increased more gradually with depth in the Middle Kern Valley Floor subregion, in the South Kern Valley Margin subregion, in the vicinity of the Montebello and Santa Fe Springs fields in the Los Angeles Basin subregion, and in the Central Coast Basin subregion. The Kern Sierran Foothills and East Kern Valley Floor subregions, on the east side of the San Joaquin Valley, had the most gradual increases in TDS with depth. Fields in the East Kern Valley Floor subregion generally had groundwater and produced water with TDS less than 10,000 mg/L that extended to a large depth compared to most other subregions. Overall, the west side of the San Joaquin Valley in Kern County and the Wilmington field in Los Angeles County generally have the highest TDS values and the shallowest depths to high TDS. High TDS at relatively shallow depths on the west side of the San Joaquin Valley may be because of a combination of natural conditions and anthropogenic factors. In the vicinity of the Wilmington field in the Los Angeles Basin subregion, high TDS at relatively shallow depths is attributable at least in part to seawater intrusion. Fields on the east side of the San Joaquin Valley in Kern County have the lowest TDS and greatest depths to TDS greater than 10,000 mg/L because of their geologic setting adjacent to Sierra Nevada recharge areas. Reconnaissance salinity mapping was limited by several factors. The primary limitation was the lack of well-construction data for a significant number of water wells. Bottom perforation, well depth, or hole depth were not available for 35 percent of wells used for salinity mapping. A second limitation was variability in data quality. Total dissolved solids and specific conductance data were compiled from different data sources with varying degrees of documentation that ranged from comprehensive to very little or none. As a result, it was not always possible to assess the quality of the provided data with respect to either conditions at each well during sampling or the methodology used for sample collection and analysis. A third limitation was the lack of wells, either petroleum or water, and associated TDS data over large vertical intervals for some fields. As a result, the distribution of salinity and the depths at which TDS concentration exceeds the 3,000 and 10,000 mg/L thresholds could not always be precisely determined. This analysis highlights key gaps that need to be filled with additional analysis of other sources of information, such as borehole geophysical logs and new water sample or geophysical data collection.

California↗

USGS2007

Geological assessment of cores from the Great Bay National Wildlife Refuge, New Hampshire

Geological sources of metals (especially arsenic and zinc) in aquifer bedrock were evaluated for their potential to contribute elevated values of metals to ground and surface waters in and around Rockingham County, New Hampshire. Ayotte and others (1999, 2003) had proposed that arsenic concentrations in ground water flowing through bedrock aquifers in eastern New England were elevated as a result of interaction with rocks. Specifically in southeastern New Hampshire, Montgomery and others (2003) established that nearly one-fifth of private bedrock wells had arsenic concentrations that exceed the U.S. Environmental Protection Agency (EPA) maximum contamination level for public water supplies. Two wells drilled in coastal New Hampshire were sited to intersect metasedimentary and metavolcanic rocks in the Great Bay National Wildlife Refuge. Bulk chemistry, mineralogy, and mineral chemistry data were obtained on representative samples of cores extracted from the two boreholes in the Kittery and Eliot Formations. The results of this study have established that the primary geologic source of arsenic in ground waters sampled from the two well sites was iron-sulfide minerals, predominantly arsenic-bearing pyrite and lesser amounts of base-metal-sulfide and sulfosalt minerals that contain appreciable arsenic, including arsenopyrite, tetrahedrite, and cobaltite. Secondary minerals containing arsenic are apparently limited to iron-oxyhydroxide minerals. The geologic source of zinc was sphalerite, typically cadmium-bearing, which occurs with pyrite in core samples. Zinc also occurred as a secondary mineral in carbonate form. Oxidation of sulfides leading to the liberation of acid, iron, arsenic, zinc, and other metals was most prevalent in open fractures and vuggy zones in core intervals containing zones of high transmissivity in the two units. The presence of significant calcite and lesser amounts of other acid-neutralizing carbonate and silicate minerals, acting as a natural buffer to reduce acidity, forced precipitation of iron-oxyhydroxide minerals and the removal of trace elements, including arsenic and lead, from ground waters in the refuge. Zinc may have remained in solution to a greater extent because of complexing with carbonate and its solubility in near-neutral ground and surface waters. The regional link between anomalously high arsenic contents in ground water and a bedrock source as established by Ayotte and others (1999, 2003) and Montgomery and others (2003) was confirmed by the presence of some arsenic-bearing minerals in rocks of the Kittery and Eliot Formations. The relatively low amounts of arsenic and metals in wells in the Great Bay National Wildlife Refuge as reported by Ayotte and others (U.S. Geological Survey Water Resources Data, 2005) were likely controlled by local geochemical environments in partially filled fractures, fissures, and permeable zones within the bedrock formations. Carbonate and silicate gangue minerals that line fractures, fissures, and permeable zones likely limited the movement of arsenic from bedrock to ground water. Sources other than the two geologic formations might have been required to account for anomalously high arsenic contents measured in private bedrock aquifer wells of Rockingham County.

New Hampshire↗

USGS2013

Software for analysis of chemical mixtures--composition, occurrence, distribution, and possible toxicity

The composition, occurrence, distribution, and possible toxicity of chemical mixtures in the environment are research concerns of the U.S. Geological Survey and others. The presence of specific chemical mixtures may serve as indicators of natural phenomena or human-caused events. Chemical mixtures may also have ecological, industrial, geochemical, or toxicological effects. Chemical-mixture occurrences vary by analyte composition and concentration. Four related computer programs have been developed by the National Water-Quality Assessment Program of the U.S. Geological Survey for research of chemical-mixture compositions, occurrences, distributions, and possible toxicities. The compositions and occurrences are identified for the user-supplied data, and therefore the resultant counts are constrained by the user’s choices for the selection of chemicals, reporting limits for the analytical methods, spatial coverage, and time span for the data supplied. The distribution of chemical mixtures may be spatial, temporal, and (or) related to some other variable, such as chemical usage. Possible toxicities optionally are estimated from user-supplied benchmark data. The software for the analysis of chemical mixtures described in this report is designed to work with chemical-analysis data files retrieved from the U.S. Geological Survey National Water Information System but can also be used with appropriately formatted data from other sources. Installation and usage of the mixture software are documented. This mixture software was designed to function with minimal changes on a variety of computer-operating systems. To obtain the software described herein and other U.S. Geological Survey software, visit http://water.usgs.gov/software/.

Scientific Investigations Report↗

USGS2019

Updates to the Madison Lake (Minnesota) CE–QUAL–W2 water-quality model for assessing algal community dynamics

A previously developed CE–QUAL–W2 model for Madison Lake, Minnesota, simulated the algal community dynamics, water quality, and fish habitat suitability of Madison Lake under recent (2014) meteorological conditions. Additionally, this previously developed model simulated the complex interplay between external nutrient loading, internal nutrient loading from sediment release of phosphorus, and the organic matter decomposition of the algal biomass. However, the partitioning of Cyanophyta within the modeling framework was simplified to one group and did not account for how different Cyanophyta populations are affected by light conditions, use of nitrogen, temperature growth ranges, and differences in settling rates. Properly capturing Cyanophyta dynamics is important given the potential risks posed by potential large algal blooms. For example, when Cyanophyta form large blooms, recreational activities can become restricted in certain areas because of thick algal scums or algal mats, in addition to the possible production of a class of toxins, known as cyanotoxins, capable of threatening human health, domestic animals, and wildlife. Therefore, we updated the model to partition the Cyanophyta into a group that fixed nitrogen and a second, more buoyant Cyanophyta group that did not independently fix nitrogen. The U.S. Geological Survey, in cooperation with the St. Croix Watershed Research Station (Science Museum of Minnesota) with support from the Environmental and Natural Resources Trust Fund of Minnesota (Legislative-Citizen Commission on Minnesota Resources), updated the Madison Lake CE–QUAL–W2 model to address the shortcomings of simulating Cyanophyta in the previously developed model and better characterize Cyanophyta into two groups. In addition to updating the Cyanophyta group differentiation, the part of the model that handles the simulation of algal community dynamics was updated while preserving model predictive capabilities for nutrients, water temperature, and dissolved oxygen. The calibration and validation of the model was done under recent meteorological conditions with large and persistent Cyanophyta blooms (2014 and 2016). Overall, the model simulations predicted the persistently large total phosphorus concentrations in the hypolimnion of Madison Lake and key differences in nutrient concentrations between 2014 and 2016. The Cyanophyta bloom persistence throughout the summer was also simulated by the model in 2014 and 2016, a critical goal of the model update. Finally, monthly total phosphorus budgets were calculated for the updated Madison Lake model for 2014 and 2016.

Minnesota↗

USGS2020

Groundwater quality in relation to drinking water health standards and hydrogeologic and geochemical characteristics for 47 domestic wells in Potter County, Pennsylvania, 2017

As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, water samples from 47 domestic wells in Potter County were collected from May through September 2017. The sampled wells had depths ranging from 33 to 600 feet in sandstone, shale, or siltstone aquifers. Groundwater samples were analyzed for physicochemical properties that could be evaluated in relation to drinking-water health standards, geology, land use, and other environmental factors. Laboratory analyses included concentrations of major ions, nutrients, bacteria, trace elements, volatile organic compounds (VOCs), ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. Results of this 2017 study show that groundwater quality generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded maximum contaminant levels (MCLs) for total coliform bacteria (69.6 percent), Escherichia coli (30.4 percent), arsenic, and barium; and secondary maximum contaminant levels (SMCLs) for field pH, manganese, sodium, iron, total dissolved solids, aluminum, and chloride. All of the analyzed VOCs were below limits of detection and associated drinking water criteria. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter in 80.9 percent of the samples. The field pH of the groundwater ranged from 4.6 to 9.0. Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH values outside this range. Calcium/bicarbonate waters were the predominant hydrochemical type for the sampled aquifers, with mixed water types for many samples, including variable contributions from calcium, magnesium, and sodium combined with bicarbonate, sulfate, chloride, and nitrate. Water from 45 wells had concentrations of methane greater than the 0.0002 milligrams per liter (mg/L) detection limit. One sample had the maximum value of 11 mg/L, which exceeds the Pennsylvania action level of 7 mg/L. Additionally, three other samples had concentrations of methane greater than 4 mg/L. Outgassing of such levels of methane from the water to air within a confined space can result in a potential hazard. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH with relatively elevated concentrations of iron, manganese, ammonia, lithium, fluoride, and boron. Other constituents, including barium, sodium, chloride, and bromide, commonly were elevated, but not limited to, those well-water samples with elevated methane. Low levels of ethane (as much as 1.2 mg/L) were present in eight samples with the highest methane concentrations. Five samples were analyzed for methane isotopes. The isotopic and hydrocarbon compositions in these five samples suggest the methane may be of microbial origin or a mixture of thermogenic and microbial gas, but differed from the compositions reported for mud-gas logging samples collected during drilling of gas wells. The concentrations of sodium (median 8.2 mg/L), chloride (median 7.64 mg/L), and bromide (median 0.02 mg/L) for the 47 groundwater samples collected for this study ranged widely and were positively correlated with one another and with specific conductance and associated measures of ionic strength. Sixty percent of the Potter County well-water samples had chloride concentrations less than 10 mg/L. Samples with higher chloride concentrations had variable bromide concentrations and corresponding chloride/bromide ratios that are consistent with sources such as road-deicing salt and septic effluent (low bromide) or brine (high bromide). Brines are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. It is also possible that valley wells were drilled close to or into the brine-freshwater interface, so brine signatures do not necessarily indicate contamination due to drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. Although 1 of 8 groundwater samples with the highest methane concentrations (greater than 0.2 mg/L) had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with road-deicing salt, the other 7 of 8 samples with elevated methane had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported. Approximately 50 percent of Potter County well-water samples, including two samples with the fourth (72.9 mg/L) and fifth (47.0 mg/L) highest chloride concentrations, have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt or septic effluent.

Pennsylvania↗

USGS2006

Effects of irrigation practices on water use in the groundwater management districts within the Kansas high plains, 1991-2003

Data compiled for the High Plains region of Kansas that includes five Groundwater Management Districts (GMDs) were analyzed for trends in irrigation water use, acres irrigated, precipitation, irrigation system types, and irrigated crop types to determine the effects of irrigation practices on water use over time. For the study period 1991 through 2003, precipitation decreased significantly (with 95-percent confidence) in northwestern and west-central Kansas but not in the southwestern and south-central parts of the State. Irrigation water use had no statistically significant trend during this period. There was a good (R= -0.77) relation between average regional precipitation and total GMD irrigation water use. When irrigation water use was adjusted for this relation, there was a positive trend (90-percent confidence level) in the adjusted irrigation water use. Another adjustment to water use was made using the ratio of annual precipitation to 1991-2005 average precipitation, which resulted in a negative trend (95-percent confidence level) in irrigation water use. This demonstrated the contradictory nature of precipitation adjustments to water use, making their utility somewhat suspect. GMD 3 in southwestern Kansas used 63 percent of the total acre-feet of irrigation water within all the GMDs. When all GMDs are considered, the number of irrigated acres for flood and center pivot systems without drop nozzles decreased significantly during the study period. At the same time the number of drop nozzle irrigated acres increased significantly. The number of irrigated acres of water-intensive crops (corn, alfalfa, and soybeans) also increased significantly, whereas the number of less- or non-water-intensive crops (grain sorghum and wheat), and multiple crop type acres decreased. Drop nozzle irrigation systems used approximately 2 percent less water in a year-by-year comparison than center pivot systems and 8 to 11 percent less water than flood irrigation. The best estimator of irrigation water use incorporated total acres irrigated and annual average or March-October regional precipitation. A conclusion that can be drawn from the trend analyses described in this report is that, although irrigation water use for all GMDs showed no statistically significant trend, an apparent increased efficiency of center pivots irrigation systems with drop nozzles has allowed more water-intensive crops to be grown on more irrigated acres.

Scientific Investigations Report↗

USGS2016

Simulated effects of nitrogen saturation the global carbon budget using the IBIS model

Over the past 100 years, human activity has greatly changed the rate of atmospheric N (nitrogen) deposition in terrestrial ecosystems, resulting in N saturation in some regions of the world. The contribution of N saturation to the global carbon budget remains uncertain due to the complicated nature of C-N (carbon-nitrogen) interactions and diverse geography. Although N deposition is included in most terrestrial ecosystem models, the effect of N saturation is frequently overlooked. In this study, the IBIS (Integrated BIosphere Simulator) was used to simulate the global-scale effects of N saturation during the period 1961–2009. The results of this model indicate that N saturation reduced global NPP (Net Primary Productivity) and NEP (Net Ecosystem Productivity) by 0.26 and 0.03 Pg C yr −1 , respectively. The negative effects of N saturation on carbon sequestration occurred primarily in temperate forests and grasslands. In response to elevated CO 2 levels, global N turnover slowed due to increased biomass growth, resulting in a decline in soil mineral N. These changes in N cycling reduced the impact of N saturation on the global carbon budget. However, elevated N deposition in certain regions may further alter N saturation and C-N coupling.

Scientific Reports↗

USGS2005

Environmental setting, water budget, and stream assessment for the Broad Run watershed, Chester County, Pennsylvania

The Broad Run watershed lies almost entirely in West Bradford Township, Chester County, Pa., and drains 7.08 square miles to the West Branch Brandywine Creek. Because of the potential effect of encroaching development and other stresses on the Broad Run watershed, West Bradford Township, the Chester County Water Resources Authority, and the Chester County Health Department entered into a cooperative study with the U.S. Geological Survey to complete an annual water budget and stream assessment of overall conditions. The annual water budget quantified the basic parameters of the hydrologic cycle for the climatic conditions present from April 1, 2003, to March 31, 2004. These water-budget data identified immediate needs and (or) deficits that were present within the hydrologic cycle during that period, if present; however, an annual water budget encompassing a single year does not identify long-term trends. The stream assessment was conducted in two parts and assessed the overall condition of the watershed, an overall assessment of the fluvial-geomorphic conditions within the watershed and an overall assessment of the stream-quality conditions. The data collected will document present (2004) conditions and identify potential vulnerabilities to future disturbances. For the annual period from April 1, 2003, to March 31, 2004, determination of an annual water budget indicated that of the 67.8 inches of precipitation that fell on the Broad Run watershed, 38.8 inches drained by way of streamflow to the West Branch Brandywine Creek. Of this 38.8 inches of streamflow, local-minimum hydrograph separation techniques determined that 7.30 inches originated from direct runoff and 31.5 inches originated from base flow. The remaining precipitation went into ground-water storage (1.71 inches) and was lost to evapotranspiration (27.3 inches). Ground-water recharge for this period-35.2 inches-was based on these values and an estimated ground-water evapotranspiration rate of 2 inches. Assessment of fluvial-geomorphic conditions included large-scale mapping of stream classes within the Broad Run watershed and in-depth study of three representative stream reaches also within the Broad Run watershed. Based on the total distance of all stream reaches classified within the Broad Run watershed, 61 percent were classified as C-class, 14 percent as E-class, 13 percent as B-class, 5 percent as F-class, 4 percent as undifferentiated B- and F-class, 2 percent as G-class, and less than 1 percent as A-class. The map of stream classes indicates that the Broad Run watershed currently has no large-scale areas of stream impairment and that, generally, the stream is not entrenched and the main branch of the Broad Run has an available, functioning flood plain. Smaller tributary streams, however, showed signs of localized entrenchment due to site-specific influences such as natural stream-channel evolution, localized channelization, localized contraction due to road and driveway crossings, and (or) increased localized runoff. For example, one small reach along a tributary channel was observed to become entrenched due to runoff originating from a new housing development. Entrenched stream reaches are merely located by large-scale mapping and require individual assessment to determine potential causes of entrenchment and (or) future restorative actions. Three in-depth geomorphic study sites showed that the Broad Run can currently be considered graded or in a state of dynamic equilibrium. The sites did, however, identify certain vulnerabilities to future changes within the watershed. These vulnerabilities included disruption of the present sediment supply, including both increases and (or) reductions in the current sediment loads within the Broad Run; increases in both magnitude and duration of storm-water runoff; encroachment of development onto present flood-plain areas, and (or) alterations to riparian zones. Assessment of stream-quality conditions includ

Scientific Investigations Report↗

USGS2011

Sources, fate, and transport of nitrogen and phosphorus in the Chesapeake Bay watershed: An empirical model

Spatially Referenced Regression on Watershed Attributes (SPARROW) was used to provide empirical estimates of the sources, fate, and transport of total nitrogen (TN) and total phosphorus (TP) in the Chesapeake Bay watershed, and the mean annual TN and TP flux to the bay and in each of 80,579 nontidal tributary stream reaches. Restoration efforts in recent decades have been insufficient to meet established standards for water quality and ecological conditions in Chesapeake Bay. The bay watershed includes 166,000 square kilometers of mixed land uses, multiple nutrient sources, and variable hydrogeologic, soil, and weather conditions, and bay restoration is complicated by the multitude of nutrient sources and complex interacting factors affecting the occurrence, fate, and transport of nitrogen and phosphorus from source areas to streams and the estuary. Effective and efficient nutrient management at the regional scale in support of Chesapeake Bay restoration requires a comprehensive understanding of the sources, fate, and transport of nitrogen and phosphorus in the watershed, which is only available through regional models. The current models, Chesapeake Bay nutrient SPARROW models, version 4 (CBTN_v4 and CBTP_v4), were constructed at a finer spatial resolution than previous SPARROW models for the Chesapeake Bay watershed (versions 1, 2, and 3), and include an updated timeframe and modified sources and other explantory terms. Chesapeake Bay receives an estimated 1.32 x 10 8 kilograms (132,000 metric tons) of nitrogen and 9.74 x 10 6 kilograms (9,740 metric tons) of phosphorus annually from its watershed, mainly through its two largest tributaries, the Susquehanna and Potomac Rivers. Significant (α=0.10) sources of nutrients to streams in the watershed include fertilizer and manure applications in agricultural areas, undifferentiated urban activities, point sources, atmospheric deposition and direct fixation by crops (for nitrogen), and mineral sources (for phosphorus). Agriculture (primarily fertilizer applications and crop fixation) contributes more than half of the nitrogen delivered from the watershed to the bay; phosphorus contributions are more mixed, and fairly evenly distributed among agricultural (fertilizer and manure applications) and urban (including point) sources. Natural mineral dissolution contributes approximately 14 percent of the phosphorus flux from the watershed to the Chesapeake Bay. Empirical estimates of average yields from different source areas and of the portion of selected applications delivered to streams agree closely with previously reported values in the literature. Nutrient fate and transport through the Chesapeake Bay watershed to the bay reflect the diferent physical and chemical properties of nitrogen and phosphorus compounds. Groundwater is an important pathway for nitrogen transport (as nitrate), and TN flux is greatest in areas with greater groundwater flow and in areas of the Piedmont underlain by carbonate rocks. TN flux decreases with increasing vegetative growth (likely indicative of plant uptake) and soil available water capacity (likely indicative of reducing conditions). Phosphorus transport to streams, conversely, is greatest in areas most likely to generate overland runoff and related erosion, including those with less permeable and more erodible soils and greater precipitation. Phosphorus transport also is greater in the Coastal Plain than in other areas, possibly due to saturation of soils with historical phosphorus applications. Both nitrogen and phosphorus are lost within watershed impoundments (lakes, ponds, or reservoirs), and nitrogen is also lost significantly along flowing reaches, particularly in small streams and in larger streams in warmer areas.

Chesapeake Bay↗

USGS2004

Geologic Map of the Saint Helens Quadrangle, Columbia County, Oregon, and Clark and Cowlitz Counties, Washington

The Saint Helens 7.5' quadrangle is situated in the Puget-Willamette Lowland approximately 35 km north Portland, Oregon. The lowland, which extends from Puget Sound into west-central Oregon, is a complex structural and topographic trough that lies between the Coast Range and the Cascade Range. Since late Eocene time, Cascade Range has been the locus of a discontinuously active volcanic arc associated with underthrusting of oceanic lithosphere beneath the North American continent along the Cascadia Subduction Zone. The Coast Range occupies the forearc position within the Cascadia arc-trench system and consists of a complex assemblage of Eocene to Miocene volcanic and marine sedimentary rocks. The Saint Helens quadrangle lies in the northern part of the Portland Basin, a roughly 2000-km2 topographic and structural depression. It is the northernmost of several sediment-filled structural basins that collectively constitute the Willamette Valley segment of the Puget-Willamette Lowland (Beeson and others, 1989; Swanson and others, 1993; Yeats and others, 1996). The rhomboidal basin is approximately 70 km long and 30 km wide, with its long dimension oriented northwest. The Columbia River flows west and north through the Portland Basin at an elevation near sea level and exits through a confined bedrock valley less than 2.5 km wide about 16 km north of Saint Helens. The flanks of the basin consist of Eocene through Miocene volcanic and sedimentary rocks that rise to elevations exceeding 2000 ft (610 m). Seismic-reflection profiles (L.M. Liberty, written commun., 2003) and lithologic logs of water wells (Swanson and others, 1993; Mabey and Madin, 1995) indicate that as much as 550 m of late Miocene and younger sediments have accumulated in the deepest part of the basin near Vancouver. Most of this basin-fill material was carried in from the east by the Columbia River but contributions from streams draining the adjacent highlands are locally important. The Portland Basin has been interpreted as a pull-apart basin located in the releasing stepover between two echelon, northwest-striking, right-lateral fault zones (Beeson and others, 1985, 1989; Beeson and Tolan, 1990; Yelin and Patton, 1991; Blakely and others, 1995). These fault zones are thought to reflect regional transpression and dextral shear within the forearc in response to oblique subduction along the Cascadia Subduction Zone Pezzopane and Weldon, 1993; Wells and others, 1998). The southwestern margin of the Portland Basin is a well-defined topographic break along the base of the Tualatin Mountains, an asymmetric anticlinal ridge that is bounded its northeast flank by the Portland Hills Fault Zone (Balsillie and Benson, 1971; Beeson and others, 1989; Blakely and others, 1995), which is probably an active structure (Wong and others, 2001; Liberty and others, 2003). The nature of the corresponding northeastern margin of the basin is less clear, but a poorly defined and partially buried dextral extensional fault zone has been hypothesized from topography, microseismicity, potential fieldanomalies, and reconnaissance geologic mapping (Beeson and others, 1989; Beeson and Tolan, 1990; Yelin and Patton, 1991; Blakely and others, 1995). Another dextral structure, the Kalama Structural Zone of Evarts (2002), may underlie the north-northwest-trending reach of the Columbia River north of Woodland (Blakely and others, 1995). This map is a contribution to a U.S. Geological Survey (USGS) program designed to improve the geologic database for the Portland Basin region of the Pacific Northwest urban corridor, the populated forearc region of western Washington and Oregon. Better and more detailed information on the bedrock and surficial geology of the basin and its surrounding area is needed to refine assessments of seismic risk (Yelin and Patton, 1991; Bott and Wong, 1993), ground-failure hazards (Madin and Wang, 1999; Wegmann and Walsh, 2001) and resource availability in this rapid

Scientific Investigations Map↗

USGS2006

Cadmium risks to freshwater life: derivation and validation of low-effect criteria values using laboratory and field studies

In 2001, the U.S. Environmental Protection Agency (EPA) released updated aquatic life criteria for cadmium. Since then, additional data on the effects of cadmium to aquatic life have become available from studies supported by the EPA, Idaho Department of Environmental Quality (IDEQ), and the U.S. Geological Survey, among other sources. Updated data on the effects of cadmium to aquatic life were compiled and reviewed and low-effect concentrations were estimated. Low-effect values were calculated using EPA's guidelines for deriving numerical national water-quality criteria for the protection of aquatic organisms and their uses. Data on the short-term (acute) effects of cadmium on North American freshwater species that were suitable for criteria derivation were located for 69 species representing 57 genera and 33 families. For longer-term (chronic) effects of cadmium on North American freshwater species, suitable data were located for 28 species representing 21 genera and 17 families. Both the acute and chronic toxicity of cadmium were dependent on the hardness of the test water. Hardness-toxicity regressions were developed for both acute and chronic datasets so that effects data from different tests could be adjusted to a common water hardness. Hardness-adjusted effects values were pooled to obtain species and genus mean acute and chronic values, which then were ranked by their sensitivity to cadmium. The four most sensitive genera to acute exposures were, in order of increasing cadmium resistance, Oncorhynchus (Pacific trout and salmon), Salvelinus ('char' trout), Salmo (Atlantic trout and salmon), and Cottus (sculpin). The four most sensitive genera to chronic exposures were Hyalella (amphipod), Cottus, Gammarus (amphipod), and Salvelinus. Using the updated datasets, hardness dependent criteria equations were calculated for acute and chronic exposures to cadmium. At a hardness of 50 mg/L as calcium carbonate, the criterion maximum concentration (CMC, or 'acute' criterion) was calculated as 0.75 mug/L cadmium using the hardness-dependent equation CMC = e(0.8403 ? ln(hardness)-3.572) where the 'ln hardness' is the natural logarithm of the water hardness. Likewise, the criterion continuous concentration (CCC, or 'chronic' criterion) was calculated as 0.37 mug/L cadmium using the hardness-dependent equation CCC = (e(0.6247 ? ln(hardness)-3.384)) ? (1.101672 - ((ln hardness) ? 0.041838))). Using data that were independent of those used to derive the criteria, the criteria concentrations were evaluated to estimate whether adverse effects were expected to the biological integrity of natural waters or to selected species listed as threatened or endangered. One species was identified that would not be fully protected by the derived CCC, the amphipod Hyalella azteca. Exposure to CCC conditions likely would lead to population decreases in Hyalella azteca, the food web consequences of which probably would be slight if macroinvertebrate communities were otherwise diverse. Some data also suggested adverse behavioral changes are possible in fish following long-term exposures to low levels of cadmium, particularly in char (genus Salvelinus). Although ambiguous, these data indicate a need to periodically review the literature on behavioral changes in fish following metals exposure as more information becomes available. Most data reviewed indicated that criteria conditions were unlikely to contribute to overt adverse effects to either biological integrity or listed species. If elevated cadmium concentrations that approach the chronic criterion values occur in ambient waters, careful biological monitoring of invertebrate and fish assemblages would be prudent to validate the prediction that the assemblages would not be adversely affected by cadmium at criterion concentrations.

Scientific Investigations Report↗

USGS2011

Seasonal seepage investigation on an urbanized reach of the lower Boise River, southwestern Idaho, water year 2010

The U.S. Geological Survey in cooperation with the Idaho Department of Water Resources Treasure Valley Comprehensive Aquifer Management Planning effort investigated seasonal groundwater gains and losses on the Boise River, Idaho, starting in November 2009 through August 2010. The investigation was conducted using seepage runs in 11 subreaches over a 14-mile reach from downstream of the inactive streamgage, Boise River below Diversion Dam (U.S. Geological Survey station No. 13203510) to the active Boise River at Glenwood Bridge streamgage (U.S. Geological Survey station No. 13206000). The seepage runs measured mainstem discharge, and significant tributary contributions and diversions along the reach. In addition, an evaluation of the groundwater hydraulic gradient was simultaneously conducted through shallow groundwater mini-piezometers adjacent to the river during February (low stream discharge) and May (high stream discharge) measurement timeframes. November discharge estimates, representative of autumn, had gains and losses that varied by subreach with an overall net gain of 42 ± 8 cubic feet per second (ft 3 /s). This finding compares favorably to a previous U.S. Geological Survey seepage investigation in November 1996 that found a gaining reach with an estimated gain of 52 ft 3 /s. This finding also is supported by a U.S. Geological Survey investigation in the study reach in November 1971 that estimated a gain of 74 ft 3 /s, which largely came from groundwater. The February discharge estimates, representative of winter conditions, showed variability in the reach with a net gain of 52 ft 3 /s with an uncertainty estimate of ± 7 ft 3 /s, which is consistent with the low stream discharge findings from November 2009. This finding is further supported by the differential hydraulic head measured at transect sites that qualitatively indicated groundwater to surface-water movement with few exceptions. The May discharge estimates, representative of the spring-time conditions, were gaining or potentially gaining in all but one of the upper subreaches between Boise River below Diversion Dam and Boise River near MK Nature Center sites, with seepage run results supported by hydraulic head differentials indicating a groundwater to surface-water movement. The lower end of the study reach between Boise River near MK Nature Center and Boise River at Glenwood Bridge sites showed more variability with observed hydraulic head differentials that partially supported the potential gains or losses in the reach. Overall, the reach had a calculated net gain of 24 ± 51 ft 3 /s and, therefore, this estimate may or may not reflect the actual conditions in the reach. The groundwater gains and losses in August, representative of summer conditions, varied in both the upper and lower parts of the reach, with a net loss of -88 ± 69 ft 3 /s. Overall, the reach experienced a net gain from groundwater at low stream discharges (November and February), a net loss to groundwater at moderately high stream discharge (August), and an ambiguous finding at a higher stream discharge (May). The hydraulic head differentials measured between the groundwater and surface water largely supported the calculated gain and loss estimates in the subreaches, with a potential for groundwater to surface-water movement at low stream discharge in February, and variability during high stream discharge conditions in May.

Scientific Investigations Report↗

USGS2018

Distribution of effluent injected into the Boulder Zone of the Floridan aquifer system at the North District Wastewater Treatment Plant, southeastern Florida, 1997–2011

Nonhazardous, secondarily treated, domestic wastewater (effluent) has been injected about 1 kilometer below land surface into the Boulder Zone of the Floridan aquifer system at the North District Wastewater Treatment Plant in southeastern Florida. The Boulder Zone contains saline, nonpotable water. Effluent transport out of the injection zone is a risk of underground effluent injection. At the North District Wastewater Treatment Plant, injected effluent was detected outside the Boulder Zone. The U.S. Geological Survey, in cooperation with Miami-Dade Water and Sewer Department , investigated effluent transport from the Boulder Zone to overlying permeable zones in the Floridan aquifer system. One conceptual model is presented to explain the presence of effluent outside of the injection zone in which effluent injected into the Boulder Zone was transported to the Avon Park permeable zone, forced by buoyancy and injection pressure. In this conceptual model, effluent injected primarily into the Boulder Zone reaches a naturally occurring feature (a karst-collapse structure) near an injection well, through which the effluent is transported vertically upward to the uppermost major permeable zone of the Lower Floridan aquifer. The effluent is then transported laterally through the uppermost major permeable zone of the Lower Floridan aquifer to another naturally occurring feature northwest of the North District Wastewater Treatment Plant, through which it is then transported vertically upward into the Avon Park permeable zone. In addition, a leak within a monitoring well, between monitoring zones, allowed interflow between the Avon Park permeable zone and the Upper Floridan aquifer. A groundwater flow and effluent transport simulation of the hydrogeologic system at the North District Wastewater Treatment Plant, based on the hypothesized and non-unique conceptualization of the subsurface hydrogeology and flow system, generally replicated measured effluent constituent concentration trends. The model was calibrated to match observed concentration trends for total ammonium (NH 4 + ) and total dissolved solids. The investigation qualitatively indicates that fractures, karst-collapse structures, faults, or other hydrogeologic features may permit effluent injected into the Boulder Zone to be transported to overlying permeable zones in the Floridan aquifer system. These findings, however, are qualitative because the locations of transport pathways that might exist from the Boulder Zone to the Avon Park permeable zone are largely unknown.

Florida↗

USGS2025

Fisheries research and monitoring activities of the Lake Erie Biological Station, 2024

A comprehensive understanding of fish populations and their interactions is the cornerstone of modern fishery management and the basis for Lake Erie’s Fish Community Objectives (FCOs) developed in 2020 (Francis et al. 2020). The 2024 U.S. Geological Survey (USGS) Lake Erie Biological Station Annual Report is responsive to these FCOs and the USGS obligations via a Memorandum of Understanding (MOU 2017) with the Great Lakes Fishery Commission (GLFC) Council of Lake Committees (CLC) to provide scientific information in support of fishery management. Goals for the USGS Great Lakes Deepwater Fish Assessment and Ecological Studies were to monitor long-term changes in the fish community and track population dynamics of key fishes of interest to management agencies. Specific to Lake Erie, expectations were sustained investigations of native percids, prey fish populations, and Lake Trout. All work was conducted as part of the Deepwater Science Program under the authority of the Great Lakes Fishery Research Authorization Act of 2019 (16 USC §941h). The USGS 2024 Deepwater Science Program fieldwork began in Lake Erie in March and concluded in December, using trawl, gill net, hydroacoustic, lower trophic sampling devices, and telemetry methods. This work resulted in 44 bottom trawls covering 41 ha of lake bottom and catching 48,936 fish totaling 995 kg in the West Basin of Lake Erie, with detailed results described below. Overnight gill net sets (n=25) for coldwater species were performed in the East Basin of Lake Erie. A total of 8 km of gillnet was deployed during these surveys, which caught 106 fish, 92 of which were native coldwater species: Lake Trout, Burbot, and Lake Whitefish. Results from coldwater species assessments will be reported in the Coldwater Task Group report to the GLFC and the CLC (CTG 2025). These reports are used to inform Lake Trout stocking decisions and direct lamprey control measures (16 USC §939a). USGS hydroacoustic sampling included twenty-six 5-km transects (130 km total) in the Central Basin as part of a collaborative lake-wide survey with details and results reported by the Forage Task Group (FTG 2025). Lower trophic sampling provided data from zooplankton samples (n=12) and water quality profiles (n=12) to populate a database maintained by the Michigan Department of Natural Resources (MDNR), Ontario Ministry of Natural Resources (OMNR), Ohio Department of Natural Resources (ODNR), Pennsylvania Fish and Boat Commission (PFBC), and New York State Department of Environmental Conservation (NYSDEC). USGS also assisted CLC member agencies with deployment and maintenance of Great Lakes Acoustic Telemetry Observation System (GLATOS) infrastructure throughout all three Lake Erie basins and tributaries, supporting multiple coordinated telemetry investigations. This report presents biomass-based summaries of fish communities in western Lake Erie derived from USGS bottom trawl surveys conducted from 2013 to 2024 during June and September. The survey design compliments the August ODNR- OMNRF effort by reinforcing stock assessments with more robust data. Analyses herein evaluated trends in total biomass, abundance of dominant predator and forage species, non-native species composition, biodiversity, and community structure. Data from this effort are accessible for download (Keretz et al. 2025)

Lake Erie↗

USGS2021

Groundwater flow conceptualization of the Pahute Mesa–Oasis Valley Groundwater Basin, Nevada—A synthesis of geologic, hydrologic, hydraulic-property, and tritium data

This report provides a groundwater-flow conceptualization that integrates geologic, hydrologic, hydraulic-property, and radionuclide data in the Pahute Mesa–Oasis Valley (PMOV) groundwater basin, southern Nevada. Groundwater flow in the PMOV basin is of interest because 82 underground nuclear tests were detonated, most near or below the water table. A potentiometric map and nine sets of hydrostratigraphic and hydrologic cross sections supplement the conceptualization. Potentiometric contours indicate that groundwater in the PMOV basin generally flows south-southwest and discharges at Oasis Valley. Groundwater encounters an alternating sequence of low- and high-transmissivity rocks, referred to as dams and pools, respectively, as it moves from east to west across eastern Pahute Mesa. Flow from all Pahute Mesa nuclear tests is to Oasis Valley and is well-constrained by water-level data. Flow converges along a corridor of high transmissivity between Pahute Mesa and Oasis Valley. The location of the lateral PMOV basin boundary is well defined, and this boundary, with a few minor exceptions, represents a no-flow boundary. Some boundary uncertainty exists in the northeastern part of the basin, but potential flow-rate estimates across the northeastern boundary resulting from this uncertainty are small relative to the basin groundwater budget. Recharge in the PMOV basin is derived from episodic pulses of modern water and the diffuse percolation of old water (greater than 1,000 years). Episodic recharge is a minor recharge component observed as a rise in groundwater levels that occurs 3 months to 1 year following a wet winter. Minor amounts of episodic recharge through an unsaturated zone in excess of 1,000 feet (ft) requires preferential flow through faults and fractures. The dominant recharge component is slow, steady, diffuse percolation of old water through the unsaturated zone. A large component of old water recharging the groundwater system is consistent with observations of isotopically light deuterium and oxygen 18 compositions in water from wells on Pahute Mesa and central Oasis Valley. About half the recharge in the PMOV basin is derived from the eastern Pahute Mesa area. The remaining recharge is derived primarily from other highland areas including Timber Mountain, Belted and Kawich Ranges, and Black Mountain. The PMOV groundwater system is nearly steady state, where recharge is balanced by the 5,900 acre-feet per year of natural discharge at Oasis Valley. This assumption is reasonable because the basin is dominated by steady-state conditions, where long-term changes in groundwater storage are minimal. Total groundwater withdrawals from 1963 to 2018 have amounted to less than 10 percent of annual groundwater discharge and less than 0.2 percent of the basin’s groundwater storage. Therefore, present-day (2020) conditions are considered representative of predevelopment (pre-1950) conditions in nearly all areas of the basin. The lower PMOV basin boundary is defined at 4,000 ft below the water table to encompass all underground nuclear tests and tritium plumes. This boundary defines the lower boundary of radionuclide migration. However, nearly all flow and tritium transport occur in the upper 1,600 ft of the saturated zone because a transmissivity-with-depth relation indicates that greater than 90 percent of the transmissivity contributing to groundwater flow occurs within 1,600 ft of the water table. Rocks at deeper depths have low transmissivity because argillic and mineralized alterations plug the fractures. Volcanic rocks form the primary aquifers and confining units in the PMOV basin. Volcanic hydrogeologic units (HGUs) and hydrostratigraphic units (HSUs) have transmissivity distributions that span up to eight orders of magnitude with considerable overlap between distributions. Despite the large overlap between units, mean transmissivities of aquifers are one-to-two orders of magnitude greater than the confining units. However, all volcanic-rock HGUs and HSUs are composite units, meaning that they can function spatially as either an aquifer or confining unit .

Nevada↗

USGS2016

Climate-driven increase of natural wetland methane emissions offset by human-induced wetland reduction in China over the past three decades

Both anthropogenic activities and climate change can affect the biogeochemical processes of natural wetland methanogenesis. Quantifying possible impacts of changing climate and wetland area on wetland methane (CH 4 ) emissions in China is important for improving our knowledge on CH 4 budgets locally and globally. However, their respective and combined effects are uncertain. We incorporated changes in wetland area derived from remote sensing into a dynamic CH 4 model to quantify the human and climate change induced contributions to natural wetland CH 4 emissions in China over the past three decades. Here we found that human-induced wetland loss contributed 34.3% to the CH 4 emissions reduction (0.92 TgCH 4 ), and climate change contributed 20.4% to the CH 4 emissions increase (0.31 TgCH 4 ), suggesting that decreasing CH 4 emissions due to human-induced wetland reductions has offset the increasing climate-driven CH 4 emissions. With climate change only, temperature was a dominant controlling factor for wetland CH 4 emissions in the northeast (high latitude) and Qinghai-Tibet Plateau (high altitude) regions, whereas precipitation had a considerable influence in relative arid north China. The inevitable uncertainties caused by the asynchronous for different regions or periods due to inter-annual or seasonal variations among remote sensing images should be considered in the wetland CH 4 emissions estimation.

Scientific Reports↗

USGS2020

Geologic map of the Homestake Reservoir 7.5′ quadrangle, Lake, Pitkin, and Eagle Counties, Colorado

The Homestake Reservoir 7.5' quadrangle lies at the northwestern end of the Upper Arkansas Valley, and headwaters of the Arkansas River, and the Roaring Fork, Fryingpan, and Eagle Rivers of the Colorado River system. The quadrangle lies within tectonic provinces of the 1.4 giga-annum (Ga) Picuris orogeny and includes the late Paleozoic Ancestral Rockies, Late Cretaceous-Paleocene Laramide orogeny, Oligocene-to-Miocene and Pliocene? volcanism, and Miocene to the present Rio Grande rift extensional tectonics. In the eastern half of the quadrangle, high-angle, east-dipping, Neogene normal faults displace Proterozoic rocks, and locally Miocene-to-Pliocene? volcanic rocks. Many quartz veins and hydrothermally altered zones are exposed along the eastern flank of the quadrangle, indicative of the multiple tectonic episodes the region has experienced. The main intent of the map is to unravel the structural complexity by partitioning the structures and volcanism within the appropriate geologic interval. This ultimately permits accurate identification of geomorphic features suitable for chronologies related to landscape evolution studies, seismic and other natural hazard identification, ground and surface water modeling, and paleoclimatic studies. Within the western half of the quadrangle, Mesoproterozoic and Paleoproterozoic igneous and metamorphic rocks of 1.4 Ga St. Kevin Granite and 1.8–1.7 Ga Biotite gneiss and schist, respectively, are uplifted along the generally east-dipping, high-angle Sawatch fault system. In the northwest portion of the quadrangle, strands of the Homestake shear zone have been mapped, dated and assigned to the 1.4 Ga Picuris orogeny of northern New Mexico. 10 Be and 26 Al cosmogenic nuclide ages of the youngest glacial deposits indicate a last glacial maximum age of about 22–21 kilo-annum (ka) and complete deglaciation by about 14 kilo-annum, supported by chronologic studies in adjacent drainages. The Turquoise Lake impounding lateral and terminal moraine complex was deposited during late Pleistocene glacial maximum ~22–21 ka. No late Pleistocene tectonic activity is apparent within the quadrangle.

Colorado↗

USGS2014

Simulation of natural flows in major river basins in Alabama

The Office of Water Resources (OWR) in the Alabama Department of Economic and Community Affairs (ADECA) is charged with the assessment of the State’s water resources. This study developed a watershed model for the major river basins that are within Alabama or that cross Alabama’s borders, which serves as a planning tool for water-resource decisionmakers. The watershed model chosen to assess the natural amount of available water was the Precipitation-Runoff Modeling System (PRMS). Models were configured and calibrated for the following four river basins: Mobile, Gulf of Mexico, Middle Tennessee, and Chattahoochee. These models required calibrating unregulated U.S. Geological Survey (USGS) streamflow gaging stations to estimate natural flows, with emphases on low-flow calibration. The target calibration criteria required the errors be within the range of: (1) ±10 percent for total-streamflow volume, (2) ±10 percent for low-flow volume, (3) ±15 percent for high-flow volume, (4) ±30 percent for summer volume, and (5) above 0.5 for the correlation coefficient (R 2 ). Seventy-one of the 90 calibration stations in the watershed models for the four major river basins within Alabama met the target calibration criteria. Variability in the model performance can be attributed to limitations in correctly representing certain hydrologic conditions that are characterized by some of the ecoregions in Alabama. Ecoregions consisting of predominantly clayey soils and (or) low topographic relief yield less successful calibration results, whereas ecoregions consisting of loamy and sandy soils and (or) high topographic relief yield more successful calibration results. Results indicate that the model does well in hilly regions with sandy soils because of rapid surface runoff and more direct interaction with subsurface flow.

Alabama↗