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Uranium provinces of North America — Their definition, distribution, and models

Uranium resources in North America are principally in unconformity-related, quartz-pebble conglomerate, sandstone, volcanic, and phosphorite types of uranium deposits. Most are concentrated in separate, well-defined metallogenic provinces. Proterozoic quartz-pebble conglomerate and unconformity-related deposits are, respectively, in the Blind River–Elliot Lake (BRELUP) and the Athabasca Basin (ABUP) Uranium Provinces in Canada. Sandstone uranium deposits are of two principal subtypes, tabular and roll-front. Tabular sandstone uranium deposits are mainly in upper Paleozoic and Mesozoic rocks in the Colorado Plateau Uranium Province (CPUP). Roll-front sandstone uranium deposits are in Tertiary rocks of the Rocky Mountain and Intermontane Basins Uranium Province (RMIBUP), and in a narrow belt of Tertiary rocks that form the Gulf Coastal Uranium Province (GCUP) in south Texas and adjacent Mexico. Volcanic uranium deposits are concentrated in the Basin and Range Uranium Province (BRUP) stretching from the McDermitt caldera at the Oregon-Nevada border through the Marysvale district of Utah and Date Creek Basin in Arizona and south into the Sierra de Peña Blanca District, Chihuahua, Mexico. Uraniferous phosphorite occurs in Tertiary sediments in Florida, Georgia, and North and South Carolina and in the Lower Permian Phosphoria Formation in Idaho and adjacent States, but only in Florida has economic recovery been successful. The Florida Phosphorite Uranium Province (FPUP) has yielded large quantities of uranium as a byproduct of the production of phosphoric acid fertilizer. Economically recoverable quantities of copper, gold, molybdenum, nickel, silver, thorium, and vanadium occur with the uranium deposits in some provinces. Many major epochs of uranium mineralization occurred in North America. In the BRELUP, uranium minerals were concentrated in placers during the Early Proterozoic (2,500–2,250 Ma). In the ABUP, the unconformity-related deposits were most likely formed initially by hot saline formational water related to diagenesis (»1,400 to 1,330 Ma) and later reconcentrated by hydrothermal events at »1,280–»1,000, »575, and »225 Ma. Subsequently in North America, only minor uranium mineralization occurred until after continental collision in Permian time (255 Ma). Three principal epochs of uranium mineralization occurred in the CPUP: (1) » 210–200 Ma, shortly after Late Triassic sedimentation; (2) »155–150 Ma, in Late Jurassic time; and (3) » 135 Ma, after sedimentation of the Upper Jurassic Morrison Formation. The most likely source of the uranium was silicic volcaniclastics for the three epochs derived from a volcanic island arc at the west edge of the North American continent. Uranium mineralization occurred during Eocene, Miocene, and Pliocene times in the RMIBUP, GCUP, and BRUP. Volcanic activity took place near the west edge of the continent during and shortly after sedimentation of the host rocks in these three provinces. Some volcanic centers in the Sierra de Peña Blanca district within the BRUP may have provided uranium-rich ash to host rocks in the GCUP. Most of the uranium provinces in North America appear to have a common theme of close associations to volcanic activity related to the development of the western margin of the North American plate. The south and west margin of the Canadian Shield formed the leading edge of the progress of uranium source development and mineralization from the Proterozoic to the present. The development of favorable hosts and sources of uranium is related to various tectonic elements developed over time. Periods of major uranium mineralization in North America were Early Proterozoic, Middle Proterozoic, Late Triassic–Early Jurassic, Early Cretaceous, Oligocene, and Miocene. Tertiary mineralization was the most pervasive, covering most of Western and Southern North America.

Bulletin↗

Geologic evolution of Hess Rise, central North Pacific Ocean

Cores from four Deep Sea Drilling Project (DSDP) sites (310, 464, 465, and 466) and seismic-reflection profiles provide data that are used to interpret the geological evolution and paleoenvironments of Hess Rise, a prominent oceanic plateau in the central North Pacific Ocean. Hess Rise apparently formed in the Southern Hemisphere along the western flank of the Pacific-Farallon Ridge 110 to 100 m.y. B.P. Core stratigraphies and lithologies show the response of sedimentation to subsidence and northward movement of Hess Rise on the Pacific plate. Oceanic islands, which crowned Hess Rise during its early evolution, were eroded and subsequently subsided below sea level. Major structural trends include three northwest-trending (∼327°) arms, or ridges, and an east-northeast-trending southern Hess Rise that parallels the Mendocino Fracture Zone (060°). Normal faults offset basement as much as 3,000 m along the southern edge and 1,500 m on the western flank of Hess Rise. Many faults were active during sedimentation. Tholeiitic basalt from the base of Hole 464, trachyte from the base of Hole 465A, and alkalic basalt clasts within sediment of Hole 466 show the diversity of rock types that constitute the igneous basement. A major rock unit is middle Cretaceous limestone, chalk, and minor chert that form the basal sedimentary unit. Some limestone samples, rich in organic carbon, reflect accumulation above the carbonate compensation depth (CCD) within a mid-water oxygen minimum zone. The organic-carbon-rich sediments probably were deposited on the submarine slopes of islands and banks that were at upper bathyal depths as Hess Rise crossed the wide equatorial divergence where increased upwelling and biogenic productivity contributed to high accumulation rates. The source of organic matter was mostly lipid-rich, autochthonous, marine organic matter. Analyses of sediment samples from across the Cretaceous-Tertiary boundary at Site 465 show that there was a significant decrease in surface water temperature and biological productivity. An abrupt increase in transition metals and iridium suggests that an outside source, perhaps extraterrestrial, was the cause for many of the sudden oceanographic, geochemical, and biological changes at the boundary.

GSA Bulletin↗

New measurements indicate that natural geologic methane emissions from microseepage in the Michigan Basin are likely negligible

The magnitude of natural geologic methane (CH 4 ) emissions to the atmosphere (including emissions of fossil CH 4 from offshore and onshore gas and oil seeps, diffuse microseepage, mud volcanoes, volcanic vents, and geothermal areas) is highly uncertain. The largest component of geologic emissions is thought to be microseepage, which is the diffuse flux of CH 4 from soils across large areas of productive hydrocarbon basins. The accuracy of existing bottom-up estimates of microseepage is limited by low spatial coverage of published microseepage measurements. We present the first soil—atmosphere CH 4 flux measurements from Michigan Basin, USA. Results from 335 measurements taken during summer and winter seasons across a large portion of the basin suggest microseepage is nonexistent in the sampled region. Even areas with predictive features for microseepage (e.g., underlying mature, organically rich source rocks, proven gas accumulations, faults, and lineaments) yield null or negative fluxes, suggesting that CH 4 emissions from microseepage are negligible throughout our study region. A Monte Carlo method was used to place an upper limit on the regional-mean microseepage flux, in which synthetic patchy microseepage distributions were generated and tested against our observations to assess the impact of possible emission hot spots that were missed by our sampling strategy. Our analysis finds it is very unlikely that regional-mean emissions are as high as assumed in a previous global microseepage study. The observed lack of seepage may be explained by groundwater flow, active methanotrophy, glacial sediments, and bedded salt deposits, which could inhibit vertical gas migration and release to atmosphere.

Michigan↗

Database for the geologic map of Newberry Volcano, Deschutes, Klamath, and Lake Counties, Oregon

Newberry Volcano, one of the largest Quaternary volcanoes in the conterminous United States, is a broad shield-shaped volcano measuring 60 km north-south by 30 km east-west with a maximum elevation of more than 2 km. Newberry Volcano is the product of deposits from thousands of eruptions, including at least 25 in the past approximately 12,000 years (Holocene Epoch). Newberry Volcano has erupted as recently as 1,300 years ago, but isotopic ages indicate that the volcano began its growth as early as 0.6 million years ago. Such a long eruptive history and recent activity suggest that Newberry Volcano is likely to erupt in the future. This geologic map database of Newberry Volcano distinguishes rocks and deposits based on their composition, age, and lithology.

Oregon↗

Geologic map and digital database of the Conejo Well 7.5 minute quadrangle, Riverside County, southern California

This data set maps and describes the geology of the Conejo Well 7.5 minute quadrangle, Riverside County, southern California. The quadrangle, situated in Joshua Tree National Park in the eastern Transverse Ranges physiographic and structural province, encompasses part of the northern Eagle Mountains and part of the south flank of Pinto Basin. It is underlain by a basement terrane comprising Proterozoic metamorphic rocks, Mesozoic plutonic rocks, and Mesozoic and Mesozoic or Cenozoic hypabyssal dikes. The basement terrane is capped by a widespread Tertiary erosion surface preserved in remnants in the Eagle Mountains and buried beneath Cenozoic deposits in Pinto Basin. Locally, Miocene basalt overlies the erosion surface. A sequence of at least three Quaternary pediments is planed into the north piedmont of the Eagle Mountains, each in turn overlain by successively younger residual and alluvial deposits. The Tertiary erosion surface is deformed and broken by north-northwest-trending, high-angle, dip-slip faults in the Eagle Mountains and an east-west trending system of high-angle dip- and left-slip faults. In and adjacent to the Conejo Well quadrangle, faults of the northwest-trending set displace Miocene sedimentary rocks and basalt deposited on the Tertiary erosion surface and Pliocene and (or) Pleistocene deposits that accumulated on the oldest pediment. Faults of this system appear to be overlain by Pleistocene deposits that accumulated on younger pediments. East-west trending faults are younger than and perhaps in part coeval with faults of the northwest-trending set. The Conejo Well database was created using ARCVIEW and ARC/INFO, which are geographical information system (GIS) software products of Envronmental Systems Research Institute (ESRI). The database consists of the following items: (1) a map coverage showing faults and geologic contacts and units, (2) a separate coverage showing dikes, (3) a coverage showing structural data, (4) a point coverage containing line ornamentation, and (5) a scanned topographic base at a scale of 1:24,000. The coverages include attribute tables for geologic units (polygons and regions), contacts (arcs), and site-specific data (points). The database, accompanied by a pamphlet file and this metadata file, also includes the following graphic and text products: (1) A portable document file (.pdf) containing a navigable graphic of the geologic map on a 1:24,000 topographic base. The map is accompanied by a marginal explanation consisting of a Description of Map and Database Units (DMU), a Correlation of Map and Database Units (CMU), and a key to point-and line-symbols. (2) Separate .pdf files of the DMU and CMU, individually. (3) A PostScript graphic-file containing the geologic map on a 1:24,000 topographic base accompanied by the marginal explanation. (4) A pamphlet that describes the database and how to access it. Within the database, geologic contacts , faults, and dikes are represented as lines (arcs), geologic units as polygons and regions, and site-specific data as points. Polygon, arc, and point attribute tables (.pat, .aat, and .pat, respectively) uniquely identify each geologic datum and link it to other tables (.rel) that provide more detailed geologic information.

California↗

Geology of the Alaska-Juneau lode system, Alaska

The Alaska-Juneau lode system for many years was one of the worlds leading gold-producing areas. Total production from the years 1893 to 1946 has amounted to about 94 million dollars, with principal values in contained gold but with some silver and lead values. The principal mine is the Alaska-Juneau mine, from which the lode system takes its name. The lode system is a part of a larger gold-bearing belt, generally referred to as the Juneau gold belt, along the western border of the Coast Range batholith. The rocks of the Alaska-Juneau lode system consist of a monoclinal sequence of steeply northeasterly dipping volcanic, state, and schist rocks, all of which have been metamorphosed by dynamic and thermal processes attendant with the intrusion of the Coast Range batholith. The rocks form a series of belts that trend northwest parallel to the Coast Range. In addition to the Coast Range batholith lying a mile to the east of the lode system, there are numerous smaller intrusives, all of which are sill-like in form and are thus conformable to the regional structure. The bedded rocks are Mesozoic in age; the Coast Range batholith is Upper Jurassic and Lower Cretaceous in age. Some of the smaller intrusives pre-date the batholith, others post-date it. All of the rocks are cut by steeply dipping faults. The Alaska-Juneau lode system is confined exclusively to the footwall portion of the Perseverance slate band. The slate band is composed of black slate and black phyllite with lesser amounts of thin-bedded quartzite. Intrusive into the slate band are many sill-like bodies of rocks generally referred to as meta-gabbro. The gold deposits of the lode system are found both within the slate rocks and the meta-gabbro rocks, and particularly in those places where meta-gabbro bodies interfinger with slate. Thus the ore bodies are found in and near the terminations of meta-gabbro bodies. The ore bodies are quartz stringer-lodes composed of a great number of quartz veins from 6 inches to 3 feet wide and extending along their strike and dip for several tens to hundreds of feet. In addition to quartz, the only other vein gangue mineral is ankerite. It occurs in small amounts along the borders of the quartz veins. Metallic vein minerals, in addition to native gold, are, in order of decreasing abundance, pyrrhotite, galena, sphalerite, and arsenopyrite. In the aggregate the metallic minerals comprise only 1 to 2 percent of the total amount of vein material. The wall rock, particularly the meta-gabbro, was profoundly altered by the vein-forming processes. The principal effects on the meta-gabbro were the addition of large amounts of soda, potash, titanium, carbon dioxide, and phosphorous, and the removal of considerable quantities of iron, magnesia, lime, and combined water. Silica also may have been decreased. The mineralogical changes involved in the alteration were the development of biotite and ankerite at the expense of original hornblende and feldspar, resulting in a brown-colored biotite- and ankerite-rich rock. The slates are relatively unaffected by the vein-forming processes. Because of their small size, relatively low grade, and discontinuity, no attempt has been made to mine any individual vein. The prevailing practice has been to mine large blocks of ground by a system of modified block-caving, followed by hand sorting to remove the barren country rock from the gold-bearing quartz prior to milling.

Open-File Report↗

A regional assessment of potential environmental hazards to and limitations on petroleum development of the Southeastern United States Atlantic continental shelf, slope, and rise, offshore North Carolina

More than 11,000 km of high-resolution seismic-reflection data, 325 km of mid-range sidescan-sonar data, and 500 km of long-range sidescan-sonar data were examined and used to construct an environmental geology map of the Continental Shelf, Slope, and Rise for the area of the U.S. Atlantic margin between lats. 32?N. and 37?N. Hardgrounds and two faults described in previous literature also are shown on the map. On the Continental Shelf, at least two faults, the Helena Banks fault and the White Oak lineament, appear to be tectonic in origin. However, a lack of historical seismicity associated with these faults indicates that they are probably not active at the present time. Hardgrounds are widely scattered but are most abundant in Onslow Bay. Although paleostream channels are common nearshore, they do not appear to be common on the central and outer shelf except off Albemarle Sound where extensive Pleistocene, Pliocene, and late Miocene channels extend across the shelf. Mobile bottom sediments are confined mainly to the shoals off Cape Romain, Cape Fear, Cape Lookout, and Cape Hatteras. Elsewhere the sand cover is thin, and older more indurated rocks are present in subcrop. No slope-instability features were noted on the Florida-Hatteras slope off North Carolina. The lack of features indicates that this slope is relatively stable. Evidence for scour by strong currents is ubiquitous on the northern Blake Plateau although deep-water reefs are sparse. The outer edge of the plateau is dominated by a major growth fault and numerous splay and antithetic faults. These faults are the product of salt tectonism in the Carolina trough and thus are not associated with seismicity. Displacements observed near the sea floor and breached diapirs offshore indicate that the main fault is still moving. Associated with the faults are collapse features that are interpreted to be caused by karst solution and cavernous porosity in Eocene and Oligocene limestones at depth. Major slumps have taken place in two large areas of the Continental Slope. Seismic-reflection profiles of the southern area, centered on the lower slope at 1at. 33?N., long. 76?W., show a 80-m-hlgh scarp in which bedding has been truncated. Rotational slump faults are present in this area on the middle and upper slope. Sidescan images show that large blocks have slid downslope from the scarp face, furrowing the bottom. High-resolution (3.5-kHz) records show that the rotational slump faults upslope are active. The association of these slumps and the scarps with salt diapirs suggests subsidence accompanying salt tectonism as the cause. Seismic-reflection records over the northern area, at about fat. 36?20'N., long. 74?40'W., show two steep scarps, each about 225 m high on the upper and middle-slope. These slump scars and an absence of Pleistocene sediments indicate that large blocks of the slope have been removed by slumping. The slope north of fat. 35?N. is highly dissected by canyons. Mid-range sidescan-sonar records suggest that the canyons are the product of mass wasting and have probably formed largely by slumping. Sediments in a wide zone on the upper rise are highly disturbed and faulted owing to salt tectonism. Twenty-six salt diapirs are mapped, as is a zone of disturbed bottom related to salt tectonism. An area of frozen bottom (clathrate) under which shallow free gas is trapped underlies the outer Blake Plateau, the slope, and the upper rise. Although the hazards of drilling into or through clathrates have not been tested, the release of gas from beneath this frozen layer may prove to be a primary hazard to exploration.

Open-File Report↗

California State Waters Map Series — Offshore of Bodega Head, California

Introduction In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow subsurface geology. The Offshore of Bodega Head map area is located in northern California, about 70 km north of San Francisco and about 80 km south of Point Arena. The onshore part of the map area is largely undeveloped, used primarily for recreation, farms and ranches, and a few wineries. The small town of Bodega Bay, located on the east side of Bodega Harbor, is the largest cultural center. Bodega Harbor is an important commercial fishing base and, in season, an active sport fishing and recreation harbor. Much of the coastline from Bodega Head north to about 6 km north of the Russian River is part of Sonoma Coast State Park. The Offshore of Bodega Head map area includes two California Marine Protected Areas, the Bodega Head State Marine Reserve and the northern part of the Bodega Head State Marine Conservation Area. Additionally, the inland parts of two large estuaries in the map area, Estero Americano and Estero de San Antonio, have been designated as State Marine Recreational Management Areas. The map area is cut by the northwest-striking San Andreas Fault, the right-lateral transform boundary between the North American and Pacific plates. This fault juxtaposes rocks of the Jurassic and Cretaceous Franciscan Complex on the northeast with Cretaceous granitic rocks on the southwest, and it has an estimated slip rate of about 17 to 25 mm/yr in this area. The devastating great 1906 California earthquake (M7.8) is thought to have nucleated on the San Andreas Fault offshore of San Francisco, about 80 km south of Bodega Head, with the rupture extending northward through the Offshore of Bodega Head map area and an additional 220 km to the south flank of Cape Mendocino. North of the mouth of Salmon Creek, the coast and shoreline are rugged and scenic, characterized by flights of uplifted marine terraces, rocky promontories, nearshore sea stacks, kelp-rich coves, and both pocket beaches and longer beach strands, the latter of which include Wrights Beach and Portuguese Beach. The coast has lower relief between the mouth of Salmon Creek and Mussel Point, where South Salmon Creek Beach is backed by a large (about 4 km 2 ) complex of coastal sand dunes. The enormous volume of sand on the beach and in the dune field is derived by southward littoral drift from the Russian River, Salmon Creek, and smaller coastal watersheds. The sediment is trapped by protruding bedrock at Mussel Point, which represents the south end of the Russian River littoral cell. Bodega Head is underlain by Cretaceous granitic rocks, and its shoreline is variously characterized by relatively low-lying terraces, steep and high bluffs, and a few pocket beaches. East of Bodega Head, Doran Beach (part of Doran Regional Park) is a 1.7-km-long sand spit that forms the north boundary of Bodega Bay and the south boundary of Bodega Harbor. The coast south of Doran Beach on the east flank of Bodega Bay is composed of rocky bluffs, hummocky marine terraces, and a few small pocket beaches. The bluffs are underlain by sheared rocks of the Franciscan Complex and are highly susceptible to landslides. This section of coast includes two prominent watersheds, Estero Americano and Estero de San Antonio, which drain westward into Bodega Bay. The offshore part of the Offshore of Bodega Head map area is characterized by an extensive, rugged and rocky shelf underlain by Cretaceous granitic rocks. This rocky terrain, centered offshore of Bodega Head, extends northwestward for about 15 km, from the south edge of the map area (where it forms the west boundary of Bodega Bay) to the northern-central part of the map area offshore of the mouth of Salmon Creek. This rocky seafloor reaches water depths of 40 to 80 m and is overlain by young sediment. Circulation over the shelf and seafloor in the map area (and in the broader central California region) is dominated by the southward-flowing California Current, the eastern boundary current of the North Pacific Gyre. Associated upwelling brings cool, nutrient-rich waters to the surface, resulting in high biological productivity. Persistent northwest winds are sometimes weak or absent during the fall and winter, causing the California Current to move farther offshore so that the shelf is affected by the Davidson Current, a weaker northward-flowing countercurrent. As a result, net flow over the continental shelf is commonly southeastward during the spring and summer and northwestward during the fall and winter. Throughout the year, this part of the northern California coast is exposed to four wave climate regimes: the north Pacific swell, the southern swell, northwest wind waves, and local wind waves. The north Pacific swell dominates in winter months (typically November through March). During summer months, the largest waves come from the southern swell, generated by storms in the south Pacific and offshore of Central America. Northwest wind waves affect the coast throughout the year, whereas local wind waves are most common from October to April. Potential marine benthic habitats in the Offshore of Bodega Head map area include unconsolidated continental-shelf sediments, mixed continental-shelf substrate, and hard continental-shelf substrate. Rocky-shelf outcrops and rubble are considered to be promising potential habitats for rockfish and lingcod, both of which are recreationally and commercially important species.

California↗

Regional and economic geology of Pennsylvanian age coal beds of West Virginia

West Virginia is the only place in the United States where an entire section of Pennsylvanian age (Upper Carboniferous) strata can be seen. These strata occur within a wedge of rock that thins to the north and west from the southeastern part of the State. The progressive north-northwesterly termination of older Pennsylvanian geologic units beneath younger ones prominently outlines the center of the Appalachian basin of West Virginia. Over most of West Virginia, Lower and/or Middle Pennsylvanian strata unconformably overly Upper Mississippian (Lower Carboniferous) strata. Sediment deposition was accomplished by a complex system of deltas prograding north and west from an eastern and southeastern source area. More than 100 named coal beds occur within the Lower, Middle, and Upper Pennsylvanian rocks of West Virginia and at least 60 of these have been or are currently being mined commercially. Collectively, these coal beds account for original in-ground coal resources of almost 106.1×10 9 t (117×10 9 tons). West Virginia ranks fourth in the United States in demonstrated coal reserves. In 1988, West Virginia produced 131.4×10 6 t (144.9×10 6 T) of coal, third highest in the United States. Of this annual production, 75% was from underground mines. In 1988, West Virginia led the nation in the number of longwall mining sections currently in place. West Virginia's low-volatile coal beds are known worldwide as important metallurgical-grade coals, while the higher-volatile coal beds are utilized primarily for steam production.

International Journal of Coal Geology↗

Cadmium isotope fractionation during coal combustion: Insights from two U.S. coal-fired power plants

Coal combustion, one of the principal energy sources of electricity in the United States, produces over 100 million tons of coal combustion products (CCPs) per year in the U.S. The reuse and disposal of CCPs has the potential to release toxic trace elements, including cadmium (Cd), into the environment. In this study, we investigated CCPs, including bottom ash (BA), economizer fly ash (EFA), and fly ash (FA), as well as feed coal (FC) and pulverized coal (PC) collected from two U.S. coal-fired power plants in New Mexico and Ohio with different coal supplies. The New Mexico plant uses high volatile C bituminous, low-sulfur coals mined from the San Juan Basin (Cretaceous Fruitland Formation) and the Ohio plant uses high volatile A bituminous, high-sulfur central Appalachian Basin coals (Upper Pennsylvanian Monongahela Formation). Mineralogical and elemental analysis showed that these CCP samples consist of ∼70% amorphous Al-Si-rich glasses and ∼30% mineral phases of quartz (SiO 2 ) and mullite (Ai 6 Si 2 O 13 ). The Cd isotope compositions (δ 114 Cd, normalized to NIST Cd standard 3108) of FA and EFA samples (ranging from −0.51 to +0.47‰) are distinctively heavier than those of BA samples (−0.75 to −0.52‰) in both power plants. We interpret this Cd isotope difference as a result of Cd condensation from the gas phase during flue gas cooling, instead of evaporation of Cd phase during coal combustion. Cd condensation is the main process to generate the isotopically heavy Cd signatures that preferentially partition on the fine FA particles. We also investigated Cd isotope compositions in different leachate products from a series of batch-leaching experiments with these CCPs, using diluted acetic acid, hydroxyl ammonium chloride, hydrogen peroxide followed by ammonium acetate, and 5% nitric acid, as a possible means to identify CCP-released Cd in the environment. Unusually and significantly heavier Cd isotope compositions were observed in each leachate of FA samples (+1.10 to +7.09‰), which fall far outside from the range of Cd isotope ratios observed in natural soils and rocks, but less so for the EFA samples (−0.43 to +1.18‰). Such an observation is consistent with the interpretation that isotopically heavy Cd preferentially partitions on the fine FA particles after coal combustion and is readily to be released during these leaching experiments. This study demonstrates that high-temperature coal combustion can lead to a very large degree of fractionation of Cd isotopes that can be used as a unique tracer for identifying anthropogenic metal inputs in the environment. The major Cd isotope fractionation process occurs as the Cd gas phase condenses on fine FA particles during the flue gas cooling stage after coal combustion.

New Mexico, Ohio↗

Subduction erosion of the Jurassic Talkeetna-Bonanza arc and the Mesozoic accretionary tectonics of western North America

The Jurassic Talkeetna volcanic arc of south-central Alaska is an oceanic island arc that formed far from the North American margin. Geochronological, geochemical, and structural data indicate that the arc formed above a north-dipping subduction zone after ca. 201 Ma. Magmatism migrated northward into the region of the Talkeetna Mountains ca. 180 Ma. We interpret this magmatism as the product of removal of the original forearc while the arc was active, mainly by tectonic erosion. Rapid exhumation of the arc after ca. 160 Ma coincided with the sedimentation of the coarse clastic Naknek Formation. This exhumation event is interpreted to reffect collision of the Talkeetna arc with either the active margin of North America or the Wrangellia composite terrane to the north along a second north-dipping subduction zone. The juxtaposition of accreted trench sedimentary rocks (Chugach terrane) against the base of the Talkeetna arc sequence requires a change from a state of tectonic erosion to accretion, probably during the Late Jurassic (before 150 Ma), and definitely before the Early Cretaceous (ca. 125 Ma). The change from erosion to accretion probably reflects increasing sediment flux to the trench due to collision ca. 160 Ma. ?? 2005 Geological Society of America.

Geology↗

Fluorspar deposits of Utah

The studies of fluorspar localities in Utah made by the U. S. Geological Survey during and since the recent war are summarized. The fluorspar at the Cougar Spar and Blue Bell mines in the Indian Peak Range of western Beaver County occurs as fissure veins in fault and breccia zones in volcanic and intrusive rocks. At the Monarch (Staats) claims in west-central Beaver County fluorspar was mined chiefly from a fault between limestone and rhyolite porphyry. The Thomas Range district in Juab County has yielded sizeable tonnages of fluorspar from pipes in faulted dolomite and rhyolite porphyry. From 1918 to 1924 the Silver Queen mine in Tooele County produced fluorspar from flssure veins in faulted limestone. The report describes the geology of producing mines and the various prospects examined. Production and reserves of fluorspar for Utah are summarized.

Utah↗

Geochemical evidence of drawdown in the Cerro Prieto geothermal field

Some wells of the Cerro Prieto geothermal field have undergone changes in the chemistry of fluids produced which reflect reservoir processes. Pressure decreases due to production in the southeastern part of the field have produced both drawdown of lower chloride fluids from an overlying aquifer and boiling in the aquifer with excess steam reaching the wells. These reservoir changes are indicated by changes in fluid chloride concentrations, Na/K ratios and measured enthalpies and by comparisons of aquifer fluid temperatures and chloride concentrations calculated from enthalpy and chemical measurements. Fluid temperatures have not been greatly affected by this drawdown because heat contained in the rock was transferred to the fluid. When this heat is exhausted, fluid temperatures may drop rapidly. ?? 1979.

Geothermics↗

Mud fossils

At the close of the 18th century, the haze of fantasy and mysticism that tended to obscure the true nature of the Earth was being swept away. Careful studies by scientists showed that rocks had diverse origins. Some rock layers, containing clearly identifiable fossil remains of fish and other forms of aquatic animal and plant life, originally formed in the ocean. Other layers, consisting of sand grains winnowed clean by the pounding surf, obviously formed as beach deposits that marked the shorelines of ancient seas.

General Information Product↗

Summary of ground-water hydrology of the Cambrian-Ordovician aquifer system in the northern Midwest, United States

The Cambrian-Ordovician aquifer system contains very productive aquifers throughout an area of about 161,000 square miles in the northern Midwest. The aquifer system is used extensively for industrial and rural water supplies and is the primary source of water for many municipalities in most of its area of occurrence, except in Indiana, central and southern Illinois, and western Iowa, where the aquifer system contains saline water. About 680 million gallons per day was withdrawn from drilled wells in the aquifer system in 1980. Rocks of Cambrian and Ordovician age, mainly marine sandstones and carbonate rocks, constitute most of the bedrock and subcrop beneath glacial drift in southeastern Minnesota, northeastern Iowa, Wisconsin, northern Illinois, and extreme northwestern Indiana. These strata dip generally to the south and east off the Transcontinental arch in Minnesota and the Wisconsin arch, which are structurally high areas of the Precambrian basement, into the structural lows of the Forest City basin of southwestern Iowa, the Illinois basin, and the Michigan basin. The Cambrian and Ordovician rocks are buried by younger rocks in the remainder of Iowa, Illinois, and Indiana and in most of northern Missouri. Silurian and Devonian carbonate rocks immediately overlie the Cambrian and Ordovician rocks in those areas and are termed the "Silurian-Devonian aquifer" in this study. The balance of the Devonian rocks and the overlying Mississippian and Pennsylvanian rocks generally are fine-grained sediment or dense carbonate rocks and collectively are considered to be a regional confining unit. Most of the area is covered by a veneer of glacial drift, which, along with Cretaceous sandstone in northwestern Iowa, is treated as a regional water-table aquifer. The Cambrian-Ordovician aquifer system is composed of six hydrogeologic units, which are, in descending order, the Maquoketa confining unit, St. Peter-Prairie du Chien-Jordan aquifer, St. Lawrence- Franconia confining unit, Ironton-Galesville aquifer, Eau Claire confining unit, and Mount Simon aquifer. The uppermost confining unit is the least permeable; it consists primarily of the Maquoketa Shale but includes the dense carbonate rocks of the Galena Dolomite and the Decorah, Platteville, and Glenwood Formations where they are overlain by the Maquoketa Shale. The presence of the Maquoketa in Iowa, eastern Wisconsin, northeastern Illinois, and Indiana effectively confines the entire aquifer system below. The aquifer system is a leaky-artesian system in which movement of ground water is controlled partly by the internal confining units. In the northern outcrop area, unconfined conditions prevail in shallow parts of the aquifer system and where the system is thin. Much of the recharge in upland areas discharges to streams through local flow systems, which are no more than a few miles in length. The remainder of the recharge moves slowly downward to deeper formations and downgradient to form or join the regional flow system. Computer simulations of regional ground-water flow improve understanding of the regional character of the Cambrian-Ordovician aquifer system. Ground-water flow in the confined part of the aquifer system is mainly horizontal, away from the structural highs in the north, toward the structural basins in the south and east. The rate of ground-water movement is very slow, and the flux along flow paths into the basins decreases because of a progressive loss of head and small but widespread upward leakage. Saline water in the basins restricts movement of freshwater into the deeper parts of the basins, thereby forcing flow upward through confining units. Principal regional discharge areas are the Mississippi and Missouri Rivers, the Illinois and Michigan structural basins, and Lake Michigan. However, the lake is not in direct hydraulic connection with the Cambrian-Ordovician aquifer system and receives flow primarily from the Silurian-Devonian aquifer, which it directly overlies. The longest regional flow paths originate in recharge areas in northwestern Iowa and extend southeastward as much as 400 miles toward the Illinois basin. Simulated predevelopment recharge and discharge for the Cambrian- Ordovician aquifer system balance at 351 million gallons per day. Development of the aquifer system began in various parts of the northern Midwest in the 1860's and 1870's with the drilling of deep, generally flowing artesian wells near Lake Michigan in eastern Wisconsin and northeastern Illinois and along the valleys of the Mississippi River and its tributaries. Initial heads of 186 and 130 feet above Lake Michigan at Milwaukee and Chicago, respectively, have been reported. Large-scale pumping has produced cones of depression in these two areas, with respective head declines of as much as 375 and 900 feet. Other major pumping centers generally have had much smaller declines. The largest withdrawals from the aquifer system were about 180 million gallons per day in each of the major metropolitan areas of Chicago and Minneapolis-St. Paul (Twin Cities). However, the total decline in head in the St. Peter-Prairie du Chien-Jordan aquifer in the Twin Cities by 1980 was only 90 feet because the aquifer is unconfined. Most of the eastern two-thirds of Iowa, where the aquifer system is tightly confined, is characterized by more than 50 feet of head decline, with 200 feet or more at Mason City and the Quad Cities. Pumpage from the Cambrian-Ordovician aquifer system throughout the study area averaged 683 million gallons per day for the period 1976-80. Results of a transient-model simulation show that recharge increased over predevelopment recharge by 447 million gallons per day. Natural discharge decreased by 99 million gallons per day, and 137 million gallons per day was released from aquifer storage. Mineralization of ground water in the aquifer system increases from slightly mineralized calcium magnesium bicarbonate water in the northern recharge areas, through more mineralized, mixed water types with increased sodium and sulfate, to highly mineralized sodium chloride brines in the deeper parts of the structural basins.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Geologic history of the Yosemite Valley

The problem of the origin of the Yosemite Valley inherently demands a solution in quantitative terms. Its essence is, To what extent is the valley a product of glacial action, to what extent a product of stream erosion? The principal result of the investigations upon which this report is based is the determination within narrow limits of the preglacial depth of the Yosemite Valley and of other facts concerning its preglacial development which permit fairly definite estimates of the proportionate shares of work performed by stream and by glacier. The investigations comprise a detailed survey of the glacial and geomorphologic features of the Yosemite region and an equally intensive study of its rock formations, supplemented by reconnaissance work of both kinds in adjoining parts of the Sierra Nevada. The petrologic studies were made by Frank C. Calkins; the glacial and geomorphologic survey by Francois E. Matthes. Detailed mapping of the morainal system of the ancient Yosemite Glacier has served not only to determine the farthest limits reached by that glacier but to throw new light on the significance of the hanging valleys of the Yosemite region. It is reasonably certain that the glacier never extended more than about a mile beyond the site of El Portal. The hanging side valleys of the Merced Canyon below El Portal, therefore, hang not because of any glacial deepening suffered by that canyon. The explanation is offered that they hang because their streamlets have been unable to trench as rapidly as the Merced River since the rejuvenation of the Merced by the last uptilting of the Sierra Nevada. The streamlets were handicapped not only by their comparatively small volume but also by the fact that their courses trend northwestward and southeastward, substantially at right angles to the direction of the tilting, and therefore have remained essentially unsteepened, whereas the Merced's course trends southwestward, directly down the slope of the Sierra block, and therefore has been appreciably steepened. Projection of the longitudinal profiles of these hanging valleys forward to the axis of the Merced Canyon shows that they are closely accordant in height. Their profiles indicate a series of points on a former profile of the Merced with respect to which the side streams had graded their courses prior to the last uplift. This old profile can be extended upward into the glaciated part of the Merced Canyon above El Portal and even into the profoundly glaciated Yosemite Valley, accordant points being furnished by a number of hanging side valleys (due allowance being made for glacial erosion suffered by those valleys). However, not all the hanging valleys of the Yosemite region are accordant with this set. Several of them, including the upland valley of Yosemite Creek, constitute a separate set indicating another old profile of the Merced at a level 600 to 1,000 feet higher than the first. Others, including the hanging gulch of lower Bridalveil Creek, point to an old profile of the Merced about 1,200 feet lower than the first. There are thus three distinct sets of hanging valleys produced in three cycles of stream erosion. The valleys of the upper set, like those of the middle set, were left hanging as a result of rapid trenching by the Merced induced by an uplift of the range, there having been two such uplifts. Only the valleys of the lower set hang because of glacial deepening and widening of the Yosemite Valley, the cycle in which they were cut having been interrupted by the advent of the Pleistocene glaciers. They consequently indicate the preglacial depth of the Yosemite Valley. That depth, measured from the brow of El Capitan, was about 2,400 feet; measured from the rim at Glacier Point it was about 2,000 feet.

California↗

Graphite

Graphite is a form of pure carbon that normally occurs as black crystal flakes and masses. It has important properties, such as chemical inertness, thermal stability, high electrical conductivity, and lubricity (slipperiness) that make it suitable for many industrial applications, including electronics, lubricants, metallurgy, and steelmaking. For some of these uses, no suitable substitutes are available. Steelmaking and refractory applications in metallurgy use the largest amount of produced graphite; however, emerging technology uses in large-scale fuel cell, battery, and lightweight high-strength composite applications could substantially increase world demand for graphite. Graphite ores are classified as “amorphous” (microcrystalline), and “crystalline” (“flake” or “lump or chip”) based on the ore’s crystallinity, grain-size, and morphology. All graphite deposits mined today formed from metamorphism of carbonaceous sedimentary rocks, and the ore type is determined by the geologic setting. Thermally metamorphosed coal is the usual source of amorphous graphite. Disseminated crystalline flake graphite is mined from carbonaceous metamorphic rocks, and lump or chip graphite is mined from veins in high-grade metamorphic regions. Because graphite is chemically inert and nontoxic, the main environmental concerns associated with graphite mining are inhalation of fine-grained dusts, including silicate and sulfide mineral particles, and hydrocarbon vapors produced during the mining and processing of ore. Synthetic graphite is manufactured from hydrocarbon sources using high-temperature heat treatment, and it is more expensive to produce than natural graphite. Production of natural graphite is dominated by China, India, and Brazil, which export graphite worldwide. China provides approximately 67 percent of worldwide output of natural graphite, and, as the dominant exporter, has the ability to set world prices. China has significant graphite reserves, and China’s graphite production is expected to increase, although rising labor costs and some mine production problems are developing. China is expected to continue to be the dominant exporter for the near future. Mexico and Canada export graphite mainly to the United States, which has not had domestic production of natural graphite since the 1950s. Most graphite deposits in the United States are too small, low-grade, or remote to be of commercial value in the near future, and the likelihood of discovering larger, higher-grade, or favorably located domestic deposits is unlikely. The United States is a major producer of synthetic graphite.

Professional Paper↗

Enhanced bioremediation of RDX and co-contaminants perchlorate and nitrate using an anaerobic dehalogenating consortium in a fractured rock aquifer

The potential neurotoxic and carcinogenic effects of the explosives compound RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) on human health requires groundwater remediation strategies to meet low cleanup goals. Bioremediation of RDX is feasible through biostimulation of native microbes with an organic carbon donor but may be less efficient, or not occur at all, in the presence of the common co-contaminants perchlorate and nitrate. Laboratory tests compared biostimulation with bioaugmentation to achieve anaerobic degradation of RDX, perchlorate, and nitrate; a field pilot test was then conducted in a fractured rock aquifer with the selected bioaugmentation approach. Insignificant reduction of RDX, perchlorate, or nitrate was observed by the native microbes in microcosms, with or without biostimulation by addition of lactate. Tests of the RDX-degrading ability of the microbial consortium WBC-2, originally developed for dehalogenation of chlorinated volatile organic compounds, showed first-order biodegradation rate constants ranging from 0.57 to 0.90 per day (half-lives 1.2 to 0.80 days). WBC-2 sustained degradation without daughter product accumulation when repeatedly amended with RDX and lactate for a year. In microcosms with groundwater containing perchlorate and nitrate, RDX degradation began without delay when bioaugmented with 10% WBC-2. Slower RDX degradation occurred with 3% or 5% WBC-2 amendment, indicating a direct relation with cell density. Transient RDX daughter compounds included methylene dinitramine, MNX, and DNX. With WBC-2 amendment, nitrate concentrations immediately decreased to near or below detection, and perchlorate degradation occurred with half-lives of 25 to 34 days. Single-well injection tests with WBC-2 and lactate showed that the onset of RDX degradation coincided with the onset of sulfide production, which was affected by the initial perchlorate concentration. Bioegradation rates in the pilot injection tests agreed well with those measured in the microcosms. These results support bioaugmentation with an anaerobic culture as a remedial strategy for sites contaminated with RDX, nitrate, and perchlorate.

New Mexico↗