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Multi-scale geophysical imaging of a hydrothermal system in Yellowstone National Park, USA

Little is known about the local plumbing systems that fuel Yellowstone’s famous hot springs, geysers and mud pots. A multi-method, multi-scale geophysical investigation was carried out in the Obsidian Pool Thermal Area (OPTA) to: (i) delineate the lateral extent of the hydrothermal area and associated surface features; (ii) estimate the dimensions of the upflow zone and identify its main controlling structures; (iii) assess fluids circulation pathways from depth to surface. Ground and airborne geophysical data were acquired to connect local and regional scales, from shallow to large depths. Maps of surface electrical resistivity show a strong correlation with hydrothermal features. At in-termediate depths, electrical resistivity permits delineating the upper limit of the upflow zone, while Poisson’s ratio highlights differences in subsurface fluid content. Combining these results with surface observations and topographic information, we speculate that differential mixing of hydrothermal and fresh water could explain the wide diversity of features observed at OPTA. Low electrical resistivity observed at large depths also suggest that a vast upflow zone, controlled by rhyolite flows and conjugate faults, underlies the OPTA. We speculate that hydrothermal fluids rise along fractures and reach the surface in topographic lows to form hydrothermal features. Our results show that synoptic, multi-scale geophysical measurements provide a roadmap for understanding where and how geologic heterogeneity, topography, fluid-gas separation, and the mixing of thermal and meteoric waters conspire to produce the wide variety of Yellowstone’s renowned hydrothermal features.

Wyoming

Site-specific, extended ShakeMaps for earthquake engineering applications

The U.S. Geological Survey (USGS) routinely produces ShakeMaps of shaking intensity across the globe. Due to practical constraints, the number of response spectral periods was limited to three standard periods (0.3, 1.0, and 3.0 sec). We have recently developed the tools that are necessary to expand this functionality to include 22 periods (matching the current U.S. National Seismic Hazard Model periods) as well as the orientation-independent components (e.g., “RotD50”). We refer to ShakeMap products that include these extensions as “extended ShakeMaps.” The added level of complexity motivated us to also develop a user-friendly tool called the “ShakeMap Sampling Tool” (SST) that gives all the estimated shaking metrics for a specific location (or list of locations). Additionally, we develop a web application where users can input locations of interest and view/download the SST results. We further familiarize users with the concept of “Composite ShakeMaps.” For earthquakes sequences such as a mainshock and larger foreshocks and aftershocks, this provides a map of the maximum value of each shaking metric, which is useful for overall loss estimates, the full extent of ground failure triggering potential, and a better portrayal of the repeated shaking levels at a given point for a series of earthquakes. Such a site-specific shaking history facilitates earthquake forensics at building or infrastructure sites for which damage may be of concern, as described in the Disproportionate Damage Earthquake trigger specified in the IEBC (2018, Section 405.2.2) and in developing ATC-145 guidelines (Guidelines for Post-Earthquake Assessment, Repair, and Retrofit of Buildings). The composite ShakeMap can be combined with the SST for a variety of earthquake-hazard applications, such as systematically inferring triggering shaking estimates at specific sites of geotechnical interest for landsliding, liquefaction, and lateral-spreading hazards.

Kahramanmaraş

How do hydrological variability and human activities control the spatiotemporal changes of riverine nitrogen export in the Upper Mississippi River Basin?

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO 3 – + NO 2 – -N) export across the UMRB at high spatial resolution (12-digit Hydrologic Unit Codes or HUC12 subwatershed scale) during 2001–2020 and quantifies the effects of anthropogenic activities and hydrological variability on riverine NO 3 – + NO 2 – -N export changes in the region between 2001–2005 and 2016–2020. Our results revealed hotspots of substantial increases in NO 3 – + NO 2 – -N yields across the UMRB, with distinct regional patterns in driving factors. Over the entire UMRB, NO 3 – + NO 2 – -N yields increased by 9.7 kg/ha/yr on average from 2001–2005 to 2016–2020, with anthropogenic activities contributing 4.8 kg/ha/yr and hydrological variability contributing 4.9 kg/ha/yr. The northern and western UMRB had combined influences from both anthropogenic activities and hydrological variability, while the east-central regions had predominantly hydrologically driven changes. Agricultural sources, including fertilizer, manure, and biological nitrogen fixation, collectively contributed over 80% of NO 3 – + NO 2 – -N loading throughout the basin. This framework for disentangling human and hydrological impacts provides critical insights for developing effective and targeted watershed management strategies to reduce nutrient losses and improve water quality.

Upper Mississippi River Basin

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan

2025 USGS National Seismic Hazard Model for Puerto Rico and the U.S. Virgin Islands: Overview of model and hazard results

The U.S. Geological Survey recently updated the National Seismic Hazard Model (NSHM) for Puerto Rico and the U.S. Virgin Islands (PRVI). The first version of the PRVI NSHM was released in 2003, and therefore this 2025 update includes over 20 years of new geologic, geophysical, and engineering data, methods, and models. Updates follow similar efforts performed in the recent 2023 50-state NSHM. However, this is the first NSHM in which we: (1) apply an inversion methodology to subduction interface fault sources in the earthquake rupture forecast (ERF) model; (2) develop scaled backbone median ground-motion models and independent aleatory variability models that are applied in the ground-motion characterization (GMC) model; and (3) calculate epistemic uncertainty related to alternative scenarios in the ERF and GMC models for all grid points in the study region. Long-term time-independent mean hazard calculations were performed for peak ground acceleration and 5%-damped pseudospectral acceleration at 21 spectral periods from 0.01- to 10.0-s, for eight National Earthquake Hazards Reduction Program site conditions ranging from V S30 = 150 to 1500 m/s, and for 2%, 5%, and 10% in 50-year probabilities of exceedance (return periods of 2475, 975, and 475 years, respectively). Epistemic uncertainty, in the form of selected percentiles, is also provided for a suite of test sites and all grid points in the study region for limited periods, site conditions, and probabilities of exceedance. Selected results, including comparisons with the 2003 PRVI NSHM, are shown and discussed for selected periods, site conditions, and probabilities of exceedance. When comparing the 2025 PRVI NSHM with the 2003 PRVI NSHM, hazard is generally higher at shorter periods and lower at longer periods, as a result of updates in both ERF and GMC models. The 2025 PRVI NSHM is applicable for return periods greater than ∼475 or less than ∼10,000 years.

Puerto Rico, U.S. Virgin Islands

Multiple-well monitoring site adjacent to the Midway- Sunset and Buena Vista Oil Fields, Kern County, California

Groundwater quality in and around oil fields in the Southern San Joaquin Valley is of interest to many California residents that rely heavily on groundwater for domestic, commercial, and agricultural use. To help assess the effects of historical oil-field activities and natural geologic sources on groundwater near the southwest margins of the Kern County Groundwater Subbasin, a multiple-well monitoring site was installed near the administrative boundary between the Midway-Sunset and Buena Vista Oil Fields in Kern County, California. The installation of the Midway-Sunset Buena Vista multiple-well monitoring site (MSBV) supports regional analysis of the relations of oil and gas sources to groundwater quality by providing information about the geology, hydrology, geophysical properties, and water quality of the alluvial and upper Tulare aquifers in areas where groundwater data were limited. Data collected from the site included drill cuttings, whole core samples, sidewall core samples, mud-gas analysis, borehole geophysical logs, depth to water measurements, and water quality samples. Whole cores were scanned using dual energy computed tomography. Subsamples of selected cores were analyzed for density, porosity, specific retention, and bulk minerology. Thin sections of the subsamples were prepared, photographed, and examined. Two samples were analyzed using scanning electron microscope technology to examine the microporosity of diatomite laden sediment. Instrumentation installed in the wells collect hourly depth to water measurements. Analysis of the data show there is 355 feet of alluvium overlying the Tulare Formation at the well site. The contact between the two formations is an aquitard resulting in a perched aquifer in the alluvium and unconfined aquifer in the Tulare Formation. The alluvium is more heterogenous and finer grained than the Tulare Formation resulting in markedly higher porosity in the alluvium compared to the Tulare Formation. Higher specific retention observed in the alluvium is attributed to the finer grained sediment and greater abundance of reworked diatomite (as represented by opal-CT [cristobalite-tridymite]) compared to the Tulare Formation. Total dissolved solids (TDS) approached or exceeded 10,000 milligrams per liter (mg/L) in the alluvium from approximately 176 to 242 feet below land surface and at the top of the Amnicola clay at approximately 670 feet below land surface within the Tulare Formation. Elevated TDS, chloride, and boron concentrations in the alluvium and on top of the Amnicola clay likely reflect groundwater that is mixed with oil-field water. Water chemistry and modern-aged groundwater in the alluvial monitoring well (MSBV #3) are consistent with the oil-field water in the alluvium being derived from documented historical surface disposal of oil-field water upslope (northwest) of the site. Water chemistry and pre-modern groundwater age in the deeper Tulare monitoring well (MSBV #1) on top of the Amnicola clay are consistent with oil-field fluids derived from upslope natural geologic sources or old oil wells that leak in the subsurface. Shallow groundwater in the Tulare (MSBV #2) is not affected by mixing with oil-field sources.

EarthArXiv

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

Event classification, seismicity, and eruption forecasting at Great Sitkin Volcano, Alaska: 1999–2023

The frequency content of volcanogenic seismicity is often used to classify events and their spatial and temporal progression is then used to map subsurface volcanic processes. The progression of volcano-seismic events and associated source processes also plays a critical role in eruption forecasting. Here we develop and evaluate a computerized methodology for characterizing volcano-seismic event types using Frequency Index and Average Peak Frequency. We apply and test this technique at Great Sitkin Volcano, Alaska, classifying over 9000 hypocenters between 1999 and 2023. This 24-year time span covers periods of seismic quiescence, earthquake activity on nearby tectonic (bookshelf) faults, precursory unrest from 2016 to 2021, and the explosive onset in May 2021 of the ongoing effusive eruption. We use the spatial and temporal evolution of classified event types to map the active volcanic and tectonic processes, develop a conceptual model of the subsurface magmatic system, and perform a retrospective analysis of eruption forecasts at Great Sitkin Volcano between 2016 and the present. The classification and progression of hypocenters suggests the subsurface Great Sitkin Volcano magmatic system consists of a mid- to lower- crustal source zone between 10 and 40 km depth and an upper crustal magma storage area between −1 and 10 km depth (hypocenter depth is referenced to sea level and negative depths reflect height above sea level). The earliest precursors occurred in July 2016 and consisted of deep long-period and volcano-tectonic earthquakes at mid-crustal depths suggesting the subsequent unrest and eruption were triggered by a deeper intrusion of magma. This mid-crustal seismic activity was immediately followed by the onset upper-crustal long-period events and volcano-tectonic earthquakes VTs suggesting a strong linkage between the shallow and deeper portions of the magmatic system. The upper crustal area was likely capped by the 1974 lava dome until the magmatic explosion on May 26, 2021.

Alaska

Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin

Techniques for management of drainage basins that use water budgets to balance available water resources with actual or anticipated water use require accurate and precise estimates of basin withdrawals, interbasin transfers of freshwater, unaccounted-for use, water use, consumptive use, inflow and infiltration, basin return flow, and interbasin transfers of wastewater. Frequently, interbasin transfers of freshwater and wastewater are not included in basin water budgets because they occur within public water-delivery and wastewater-collection systems. A new 10-step method was developed to improve estimates of inflow and infiltration and interbasin transfers using readily available statewide data. The accuracy and precision of water-use estimates determined by this method are improved through careful application of coefficients for small users and the use of metered values for large users. The method was developed and tested with data for the Ten Mile River Basin in southeastern Massachusetts. This report uses examples from the basin to illustrate each step of the method.

Massachusetts

Airborne geophysics for geologic mapping of critical mineral systems in the United States southern midcontinent

The increased demand for clean energy technology and a significant reliance on foreign supply chains have given impetus to understanding critical mineral systems and locating potential resources within the United States. At least thirteen critical mineral-bearing systems have been identified throughout the U.S. southern Midcontinent (Hofstra and Kreiner, 2020) but much of the region’s geologic framework is concealed by vegetation and sedimentary cover that hinder traditional geologic mapping efforts. Airborne geophysical data provide an effective way to overcome these obstacles and to provide additional insight into the deeper structures that underlie shallow mineralization. However, legacy airborne magnetic and radiometric data were collected using now-outdated instruments and methods, inconsistent survey parameters, and large flight-line spacings resulting in low-resolution data that present challenges to regional-scale study and interpretation. Over the last decade, the U.S. Geological Survey Earth Mapping Resources Initiative (EMRI) and National Cooperative Geologic Mapping Program have conducted a series of high-resolution airborne magnetic and radiometric surveys across the southern Midcontinent (Fig. 1) as part of an effort to improve understanding of the geophysical framework and natural resource potential in the region. These surveys are designed using modern survey methods and instruments with consistent parameters for flight-line spacing and flight height relative to magnetic sources. The EMRI airborne surveys are planned in collaboration with State geological surveys based on focus areas (Dicken et al., 2022) according to the presence of or potential for critical mineral deposits. High-resolution airborne magnetic and radiometric data cover focus areas such as the southeast Missouri iron metallogenic province and South-Central iron-oxide-apatite (IOA) – iron-oxide-copper-gold (IOCG) province, the Magnet Cove alkaline-carbonatite complex, the Midwest Permian ultramafic dike district, the Illinois-Kentucky fluorspar district, and several Mississippi Valley-type lead-zinc deposits and districts (Fig. 1). These focus areas represent known deposits or prospective host systems of critical minerals including rare earth elements (REEs), platinum-group elements (PGEs), cobalt, lithium, fluorspar, niobium, titanium, vanadium, lead, zinc, gallium, germanium, and many more. Other significant geologic and geophysical features covered include the Reelfoot rift, the New Madrid seismic zone, the Illinois basin, the Arkoma basin, the South-Central magnetic lineament, and the Kentucky-Tennessee magnetic anomaly (Fig. 1). This presentation focuses on new airborne magnetic and radiometric data with continuous coverage across parts of six states, preliminary interpretations, examples of geologic mapping applications, and discussion of newly discovered magnetic anomalies and follow-up investigations.

Conference Paper

Groundwater age estimates for the Mississippi River Valley alluvial aquifer based on tracer data collected during 2018–20

This study characterized groundwater age across the Mississippi River Valley alluvial aquifer (MRVA). Groundwater samples from 69 MRVA wells and 19 wells in Tertiary units of the Mississippi embayment aquifer system (MEAS) were analyzed for sulfur hexafluoride (SF 6 ), tritium ( 3 H), helium (He), and (or) carbon-14 of dissolved inorganic carbon ( 14 C). The age distributions of 89 samples were estimated by fitting lumped parameter models to processed tracer concentrations with the U.S. Geological Survey software TracerLPM. Mean ages of MRVA groundwater samples ranged from 12 to 22,000 years, with a median of 140 years. Mean ages of MEAS groundwater samples ranged from 230 to 52,000 or more years, with a median of 13,500 years. The spatial distribution of MRVA groundwater ages was found to be influenced by depth, inflow of groundwater from deeper units, and soil saturated hydraulic conductivity. In parts of the MRVA, the spatial distribution of MRVA groundwater ages was found to be influenced by annual recharge and (or) annual groundwater pumpage.

Alabama, Arkansas, Illinois, Kentucky, Louisiana,

Slow slip detectability in seafloor pressure records offshore Alaska

In subduction zones worldwide, seafloor pressure data are used to observe tectonic deformation, particularly from megathrust earthquakes and slow slip events (SSEs). However, such measurements are also sensitive to oceanographic circulation-generated pressures over a range of frequencies that conflate with tectonic signals of interest. Using seafloor pressure and temperature data from the Alaska Amphibious Community Seismic Experiment, and sea surface height data from satellite altimetry, we evaluate the efficacy of various seasonal and oceanographic pressure signal proxy corrections and conduct synthetic tests to determine their impact on the timing and amplitude prediction of ramp-like signals typical of SSEs. We find that subtracting out the first mode of the complex empirical orthogonal functions of the pressure records on either the shelf or slope yields signal root-mean-square error (RMS) reductions up to 73% or 80%, respectively. Additional correction with proxies that exploit the depth-dependent spatial coherence of pressure records provides cumulative variance reductions up to 83% and 93%, respectively. Our detectability tests show that the timing and amplitude of synthetic SSE-like ramps can be well constrained for ramp amplitudes ≥4 cm on the shelf and ≥2 cm on the slope, using a fully automated detector. The principal limits on detectability are residual abrupt changes in pressure that occur as part of the transition to and from summer to winter conditions but are not adequately characterized by our seasonal corrections, as well as the inability to properly account for instrumental drift, which is not readily separated from the seasonal signal.

Alaska

Modeling seawater intrusion along the Alabama coastline using physical and machine learning models to evaluate the effects of multiscale natural and anthropogenic stresses

Seawater intrusion threatens groundwater resources in coastal regions, including southern Baldwin County, Alabama, where the freshwater-saltwater interface dynamics remain poorly understood. To address this gap, this study uses combined physics-based and machine-learning models to quantify seawater intrusion caused by natural (storm surges) and anthropogenic (human activities) perturbations. The long short-term memory network and wavelet analysis were used to assess vertical aquifer vulnerabilities, revealing that the shallow part of the Coastal lowlands aquifer system (CL1) in the southern Baldwin County region is more susceptible to sea level rise and groundwater extraction than deeper aquifers. Based on these findings, a cross-sectional numerical model (physics approach) for the CL1 aquifer was developed to evaluate tidal and storm surge effects, using Tropical Storm Claudette (June 2021) as a case study. Results showed that tidal fluctuations had a minimal impact on the saltwater-freshwater interface location, whereas storm surges caused substantial inland movement, with effects lasting for nine months. The steady-state version of the three-dimensional (3D) physical model predicted seawater intrusion across the entire area, and convolutional neural network-based modeling further validated the model results. The 3D physical model was also applied to a smaller area to assess human impact on the saltwater interface due to two groundwater pumping scenarios (± 50% of the baseline pumping rate). Results revealed that a 50% increase in groundwater withdrawals caused seawater to advance ~ 320 m inland, whereas a 50% reduction led to a ~ 270-meter retreat. This study highlights the vulnerability of Alabama’s shallow coastal aquifers to seawater intrusion due to storm surges and human activities, and demonstrates that combining physics-based models with machine learning approaches can improve groundwater predictions, though its accuracy depends on the availability of site-specific data.

Alabama

Analyzing spatial distributions and alignments of pitted cone features in Utopia Planitia on Mars

Martian geomorphology and surface features provide links to understanding past geologic processes such as fluid movement, local and regional tectonics, and feature formation mechanisms. Pitted cones are common features in the northern plains basins of Mars. They have been proposed to have formed from upwelling volatile-rich fluids, such as magma or water-sediment slurries. In this study, we map the spatial distributions of pitted cone features across the Utopia Planitia (UP) basin. Using the Average Nearest Neighbor technique, we find that pitted cone features appear to be clustered across the basin, occurring in a narrow band around the circumferential rim of UP. Additionally, we find that pitted cone features also appear to be aligned in chains that are sub-parallel with the basin margin. Parallel bands of cones generally follow elevation contours of the UP basin, which suggests elevation or a correlated factor plays a major role in pitted cone and cone chain formation. We propose that pitted cones and cone chains may be related to vertical fractures formed around the UP basin rim from subsidence of infilling basin material.

Icarus

Sedimentary exhalative (sedex) zinc-lead-silver deposit model

This report draws on previous syntheses and basic research studies of sedimentary exhalative (sedex) deposits to arrive at the defining criteria, both descriptive and genetic, for sedex-type deposits. Studies of the tectonic, sedimentary, and fluid evolution of modern and ancient sedimentary basins have also been used to select defining criteria. The focus here is on the geologic characteristics of sedex deposit-hosting basins that contain greater than 10 million metric tons of zinc and lead. The enormous size of sedex deposits strongly suggests that basin-scale geologic processes are involved in their formation. It follows that mass balance constraints of basinal processes can provide a conceptual underpinning for the evaluation of potential ore-forming mechanisms and the identification of geologic indicators for ore potential in specific sedimentary basins. Empirical data and a genetic understanding of the physicochemical, geologic, and mass balance conditions required for each of these elements are used to establish a hierarchy of quantifiable geologic criteria that can be used in U.S. Geological Survey national assessments. In addition, this report also provides a comprehensive evaluation of environmental considerations associated with the mining of sedex deposits.

Scientific Investigations Report

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States

Tracing fluid evolution during batholith and deposit formation: In-situ and bulk rock Mo isotopes from the Questa porphyry Mo deposit, New Mexico, USA

The Oligocene Questa porphyry Mo deposit, located in New Mexico, USA, is a well-characterized system that formed over 400 kyr, punctuating the 8 Myr formation of the Questa-Latir batholith. Detailed sampling of the intrusions and minerals associated with magmatichydrothermal mineralization, as well as bookending barren intrusions, allows for examination of the Mo isotope record of the deposit and its host batholith. Through this established chronologic framework, such data can yield insights into the metallogenesis of deposit formation and long-term magma genesis evolution for upper crustal magmatism. The Mo isotopic compositions of barren intrusions yield a younging trend towards lighter δ 98 Mo. However, intrusions associated with Mo deposit formation yield heavier δ 98 Mo relative to barren magmatism, by up to 2.0‰. This indicates that they were affected by an isotopically heavy and Mo-rich fluid. The in-situ data from molybdenite covers the range observed in mineralized bulk rocks. However, individual samples consistently yield Mo isotopic variations of 0.4‰ to 0.5‰. The consistency of the δ 98 Mo variation in in-situ analyses of molybdenite within hand samples and individual mineral grains is likely the result of MoS 2 crystallization in a closed system and reflects an almost complete precipitation of Mo.

New Mexico

Using a temporary emigration model to estimate abundance of stream fishes from hybrid removal surveys with and without block nets

Monitoring programs are often faced with a decision to allocate resources into either robust spatiotemporal coverage to estimate a population index (e.g., not true abundance) or confirming closed sampling conditions (e.g., with block nets) for an unbiased population estimate at the cost of spatiotemporal coverage. However, making accurate and precise abundance estimates at robust spatiotemporal scales is possible when combining open and closed sampling designs with integrated modeling techniques. We used simulations and a case study of backpack electrofishing surveys in the Santa Ana River, California to test the efficacy of an integrated abundance model (temporary emigration model, TE) to estimate abundance of fishes using removal sampling methods with a hybrid sampling design (sampling with and without block nets during removal sampling). We found that the TE model performed well under most modeling scenarios (sample size, amount of closure violation, number of samples collected during closure), although at least a few samples with block nets were necessary for all parameters to be estimable. When applied to fish surveys in the Santa Ana River, we found that catch of the fishes fit to the TE model (Santa Ana Sucker, Arroyo Chub, Channel Catfish, Largemouth Bass, Yellow Bullhead) showed little evidence that the closure assumption was violated when block nets were not used. Additionally, we found that the abundance of non-native fishes negatively affected the abundance of the native Santa Ana Sucker, which was also found to adversely affect the native fish’s access to critical habitat consisting of gravel and cobble substrate. Our results indicate that the TE model presents a viable solution to common sampling problems that impact many monitoring programs, where precise and accurate population estimates can be made at large spatiotemporal scales even when most samples violate the closure assumption.

California