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Magnetic storms and geoelectric hazards

Magnetic storms induce geoelectric fields at Earth's surface that can interfere with grounded long-line systems. The September 1859 storm disrupted global telegraph operations, the March 1989 storm caused a blackout in Canada and interfered with electric-power-transmission systems in the United States, and other storms have had related impacts. The geographic and temporal dependence of geoelectric fields are functions of both geomagnetic variation and local surface impedance, which differ considerably across different geological regions. These dependencies can be mapped across the contiguous United States by combining magnetotelluric impedance tensors with ground magnetometer time series. This review illustrates such mapping for the 1989 storm and shows that power-system interference was experienced where surface impedance is high, and when and where geoelectric fields were intense. Statistical analyses indicate that storms comparable to that of March 1989 occur roughly once every four solar cycles. Ongoing developments in numerical modeling and real-time monitoring are anticipated to enable prediction of geoelectric hazards. ▪ Magnetic storms can induced electric fields in the solid Earth that interfere with electric-power-transmission systems. ▪ Geoelectric hazards depend on the storm-time geomagnetic disturbance and the electrical conductivity structure of Earth. ▪ Historically, impacts on telecommunication and power-transmission systems in the United States have been concentrated in the East and Midwest. ▪ The future occurrence of a magnetic superstorm could cause widespread disruption of electric-power-transmission systems.

Annual Review of Earth and Planetary Sciences↗

Editorial: Synthetic Aperture Radar and natural hazards: Applications and outlooks

The ability of Synthetic Aperture Radar (SAR) to image the Earth’s surface, even through dense cloud cover and in night-and-day conditions, can facilitate the evaluation and monitoring of natural hazards and the management of natural disasters. The family of SAR satellite sensors orbits the Earth at an altitude ranging from 500 to 800 km, following sun-synchronous, near-polar orbits, slightly inclined with respect to Earth meridians. The most commonly used bands in SAR applications are the C-band (5–6 GHz, ~5,6 cm wavelength), the X-band (8–12 GHz, ~3,1 cm wavelength) and the L-band (1–2 GHz ~23 cm wavelength) with a temporal resolution depending on the satellite revisiting time. The availability of SAR has made a new spectrum of measurements possible on a global and spatial scale not attainable by ground-based studies, revealing critical insights into remote or poorly understood areas (e.g., Biggs et al., 2014). This Research Topics presents a review of articles on the state-of-art in the application of SAR sensors to study surface deformation in different geologic environments and triggered by a variety of processes. The topics discussed range from the analysis of co-seismic deformation (Marryman Boncori) to studies of volcanic unrest (Dzurisin et al., Garthwaite et al.), monitoring of landslides (Bianchini et al.) and ground subsidence in urban areas (Solari et al.).

Frontiers in Earth Science↗

Synoptic analysis of a decade of daily measurements of SO2 emission in the troposphere from volcanoes of the global ground-based Network for Observation of Volcanic and Atmospheric Change

Volcanic plumes are common and far-reaching manifestations of volcanic activity during and between eruptions. Observations of the rate of emission and composition of volcanic plumes are essential to recognize and, in some cases, predict the state of volcanic activity. Measurements of the size and location of the plumes are important to assess the impact of the emission from sporadic or localized events to persistent or widespread processes of climatic and environmental importance. These observations provide information on volatile budgets on Earth, chemical evolution of magmas, and atmospheric circulation and dynamics. Space-based observations during the last decades have given us a global view of Earth's volcanic emission, particularly of sulfur dioxide ( SO 2 ). Although none of the satellite missions were intended to be used for measurement of volcanic gas emission, specially adapted algorithms have produced time-averaged global emission budgets. These have confirmed that tropospheric plumes, produced from persistent degassing of weak sources, dominate the total emission of volcanic SO 2 . Although space-based observations have provided this global insight into some aspects of Earth's volcanism, it still has important limitations. The magnitude and short-term variability of lower-atmosphere emissions, historically less accessible from space, remain largely uncertain. Operational monitoring of volcanic plumes, at scales relevant for adequate surveillance, has been facilitated through the use of ground-based scanning differential optical absorption spectrometer (ScanDOAS) instruments since the beginning of this century, largely due to the coordinated effort of the Network for Observation of Volcanic and Atmospheric Change (NOVAC). In this study, we present a compilation of results of homogenized post-analysis of measurements of SO 2 flux and plume parameters obtained during the period March 2005 to January 2017 of 32 volcanoes in NOVAC. This inventory opens a window into the short-term emission patterns of a diverse set of volcanoes in terms of magma composition, geographical location, magnitude of emission, and style of eruptive activity. We find that passive volcanic degassing is by no means a stationary process in time and that large sub-daily variability is observed in the flux of volcanic gases, which has implications for emission budgets produced using short-term, sporadic observations. The use of a standard evaluation method allows for intercomparison between different volcanoes and between ground- and space-based measurements of the same volcanoes. The emission of several weakly degassing volcanoes, undetected by satellites, is presented for the first time. We also compare our results with those reported in the literature, providing ranges of variability in emission not accessible in the past. The open-access data repository introduced in this article will enable further exploitation of this unique dataset, with a focus on volcanological research, risk assessment, satellite-sensor validation, and improved quantification of the prevalent tropospheric component of global volcanic emission.

Earth System Science Data↗

Mapping geoelectric fields during magnetic storms: Synthetic analysis of empirical United States impedances

Empirical impedance tensors obtained from EarthScope magnetotelluric data at sites distributed across the midwestern United States are used to examine the feasibility of mapping magnetic storm induction of geoelectric fields. With these tensors, in order to isolate the effects of Earth conductivity structure, we perform a synthetic analysis—calculating geoelectric field variations induced by a geomagnetic field that is geographically uniform but varying sinusoidally with a chosen set of oscillation frequencies that are characteristic of magnetic storm variations. For north-south oriented geomagnetic oscillations at a period of T 0 =100 s, induced geoelectric field vectors show substantial geographically distributed differences in amplitude (approximately a factor of 100), direction (up to 130 ∘ ), and phase (over a quarter wavelength). These differences are the result of three-dimensional Earth conductivity structure, and they highlight a shortcoming of one-dimensional conductivity models (and other synthetic models not derived from direct geophysical measurement) that are used in the evaluation of storm time geoelectric hazards for the electric power grid industry. A hypothetical extremely intense magnetic storm having 500 nT amplitude at T 0 =100 s would induce geoelectric fields with an average amplitude across the midwestern United States of about 2.71 V/km, but with a representative site-to-site range of 0.15 V/km to 16.77 V/km. Significant improvement in the evaluation of such hazards will require detailed knowledge of the Earth's interior three-dimensional conductivity structure.

Geophysical Research Letters↗

Multiple resource limitation of dryland soil microbial carbon cycling on the Colorado Plateau

Understanding interactions among biogeochemical cycles is increasingly important as anthropogenic alterations of global climate and of carbon (C), nitrogen (N), and phosphorus (P) cycles interactively affect the Earth system. Ecosystem processes in the dryland biome, which makes up over 40% of Earth's terrestrial surface, are often distinctively sensitive to small changes in resource availability, likely because levels of many resources are low. However, data also suggest that simultaneous changes in the availability of multiple resources may be necessary to affect a response in these low-resource systems, offering an opportunity to test patterns and controls of co-limitation, serial limitation, and individual limitation in soil environments. While drylands may play a governing role in key aspects of Earth's C cycle, and while an improved understanding of resource limitation could substantially improve our forecasts of dryland responses to change, our understanding of interacting controls on soil C cycle processes remains notably poor in these dry systems. Here, we address multiple fundamental hypotheses of resource controls over ecosystem function to test how water, C, N, and P regulate soil C cycling individually and interactively in a dryland ecosystem on the Colorado Plateau. Using a series of laboratory incubations, we found that, while water, C, and N limited C cycling through serial limitation, water alone resulted in an extremely small respiratory response from target organisms, whereas water + C resulted in a dramatic increase in soil C cycling, suggesting a degree of functional co-limitation. Nitrogen additions alone resulted in no changes to soil C cycling, but when N was added in concert with water and C, N greatly increased soil C cycling rates relative to additions of water and C without N. Phosphorus additions had no effect on the C cycle either alone or synergistically. These patterns were consistent with the stoichiometry of the system and interactions among resources were surprising in ways that inform our understanding of critical theories in ecology, such as the Transient Maxima Hypothesis, supporting the suggestion that multiple resource limitation explains pulse-dynamic C cycling in drylands better than water limitation alone.

Utah↗

Galileo Photometry of Asteroid 951 Gaspra

Galileo images of Gaspra make it possible for the first time to determine a main-belt asteroid's photometric properties accurately by providing surface-resolved coverage over a wide range of incidence and emission angles and by extending the phase angle coverage to phases not observable from Earth. We combine Earth-based telescopic photometry over phase angles 2° ≤ α ≤ 25° with Galileo whole-disk and disk-resolved data at 33° ≤ α ≤ 51° to derive average global photometric properties in terms of Hapke's photometric model. The microscopic texture and particle phase-function behavior of Gaspra's surface are remarkably like those of other airless rocky bodies such as the Moon. The macroscopic surface roughness parameter, θ̄ = 29°, is slightly larger than that reported for typical lunar materials. The particle single scattering albedo, ώ 0 = 0.36 ± 0.07, is significantly larger than for lunar materials, and the opposition surge amplitude, B 0 = 1.63 ± 0.07, is correspondingly smaller. We determine a visual geometric albedo p v = 0.22 ± 0.06 for Gaspra, in close agreement with p v = 0.22 ± 0.03 estimated from Earth-based observations. Gaspra's phase integral is 0.47, and the bolometric Bond albedo is estimated to be 0.12 ± 0.03. An albedo map derived by correcting Galileo images with our average global photometric function reveals subdued albedo contrasts of ±10% or less over Gaspra's northern hemisphere. Several independent classification algorithms confirm the subtle spectral heterogeneity reported earlier (S. Mottola, M. DiMartino, M. Gonano-Beurer, H. Hoffman, and G. Neukum, 1993, Asteroids, Comets, Meteors, pp. 421-424; M. J. S. Belton et al ., 1992, Science 257, 1647-1652). Whole-disk colors (0.41 ≤ λ ≤ 0.99 μm) vary systematically with longitude by about ±5%, but color differences as large as 30% occur locally. Colors vary continuously between end-member materials whose areal distribution correlates with regional topography. Infrared: violet (0.99:0.41-μm) color ratios on Gaspra are strongly correlated with local elevation, being largest at lower elevations and smaller at higher elevations. No correlation was detected between elevation and the green:violet (0.56:0.41-μm) color ratio. Bright materials with a strong 1-μm absorption occur primarily in association with craters along ridges, while darker materials with 30% weaker 1-μm signatures occur downslope. The variations of color and albedo cannot be easily explained by grain-size effects alone or by differences in photometric geometry. The trends observed are consistent with those revealed by laboratory studies of the effects of comminution, glass formation, and segregation of metal from silicate components in chondritic meteorites and also in some silicate mixtures. The relative importance of these various processes on Gaspra remains to be determined.

Icarus↗

Quantitative approaches to characterizing natural chemical weathering rates

Silicate minerals, constituting more than 90% of the rocks exposed at the earth’s surface, are commonly formed under temperature and pressure conditions that make them inherently unstable in surficial environments. Undoubtedly, the most significant aspect of chemical weathering resulting from this instability is the formation of soils which makes life possible on the surface of the earth. Many soil macronutrients in this “critical zone” are directly related to the rate at which primary minerals weather (Huntington, 1995; Chadwick et al., 2003). Chemical weathering also creates economically significant ore deposits, such as those for Al and U (Samma, 1986; Misra, 2000), as well as potentially releasing high concentrations of toxic trace elements such as Se and As (Frankenberger and Benson, 1994). Silicate weathering is a significant buffer to acidification caused by atmospheric deposition (Driscoll et al., 1989) and from land use practices (Farley and Werritty, 1989). Atmospheric CO 2 levels have been primarily controlled by the balance between silicate weathering and the rate of volcanic inputs from the Earth’s interior, a relationship which may explain long-term climate stability (Ruddiman, 1997)

Book chapter↗

Magnetic indices

Magnetic indices are simple measures of magnetic activity that occurs, typically, over periods of time of less than a few hours and which is recorded by magnetometers at ground‐based observatories (Mayaud, 1980 ; Rangarajan, 1989 ; McPherron, 1995 ). The variations that indices measure have their origin in the Earth's ionosphere and magnetosphere. Some indices having been designed specifically to quantify idealized physical processes, while others function as more generic measures of magnetic activity. Indices are routinely used across the many subdisciplines in geomagnetism, including direct studies of the physics of the upper atmosphere and space, for induction studies of the Earth's crust and mantle, and for removal of disturbed‐time magnetic data in studies of the Earth's deep interior and core. Here we summarize the most commonly used magnetic indices, using data from a worldwide distribution of observatories, those shown in Figure M31 and whose sponsoring agencies are given in Table M1 .

Book chapter↗

The ASTER data system: An overview of the data products in Japan and in the United States

The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data system is a cooperative system, which is operated jointly by Japan’s Ministry of Economy, Trade, and Industry (METI) through its Earth Remote Sensing Data Analysis Center (ERSDAC), and by the National Aeronautics and Space Administration (NASA) primarily through its Goddard Space Flight Center (GSFC) and Land Processes (LP) Distributed Active Archive Center (DAAC). ASTER is a moderate-resolution land remote sensing system onboard the Earth Observing System (EOS) Terra spacecraft. ASTER-acquired data are received at the White Sands, New Mexico, ground receiving station, and then transmitted via land network to the EOS Data and Operations System (EDOS) within the Goddard DAAC, located at the GSFC. EDOS pre-processes raw ASTER data to Level-0 (L0) data, and sends them via the high-speed Asia-Pacific Advanced Network (APAN) to the ASTER Ground Data System (GDS) in Japan. ASTER GDS processes the L0 data to level-1 (L1) datasets; they distribute these data to users, and also use them to generate higher-level products for their user community. ASTER GDS sends a copy of all L1A data they produce to NASA’s LP DAAC, located at the U.S. Geological Survey’s Center for Earth Resources Observation and Science (EROS) near Sioux Falls, South Dakota. All L1 data received from Japan are ingested, archived, and available for users at LP DAAC. The LP DAAC also generates and distributes higher-level products from L1 data based on requests from users. To meet time-critical needs related to sensor health and performance, natural disasters, national emergencies, and certain field campaigns, the ASTER Expedited Data System (EDS) was developed, and is operated jointly by U.S. and Japanese partners.

Book chapter↗

Geochemical investigations by the U.S. Geological Survey on uranium mining, milling, and environmental restoration

Recent research by the U.S. Geological Survey has characterized contaminant sources and identified important geochemical processes that influence transport of radionuclides from uranium mining and milling wastes. 1) Selective extraction studies indicated that alkaline earth sulfates and hydrous ferric oxides are important hosts of 226 Ra in uranium mill tailings. The action of sulfate-reducing and ironreducing bacteria on these phases was shown to enhance release of radium, and this adverse result may temper decisions to dispose of uranium mill tailings in anaerobic environments. 2) Field studies have shown that although surface-applied sewage sludge/wood chip amendments aid in revegetating pyritic spoil, the nitrogen in sludge leachate can enhance pyrite oxidation, acidification of groundwater, and the consequent mobilization of metals and radionuclides. 3) In a U.S. Environmental Protection Agencyfunded study, three permeable reactive barriers consisting of phosphate-rich material, zero-valent iron, or amorphous ferric oxyhydroxide have been installed at an abandoned uranium upgrader facility near Fry Canyon, UT. Preliminary results indicate that each of the permeable reactive barriers is removing the majority of the uranium from the groundwater. 4) Studies on the geochemistry of rare earth elements as analogues for actinides such as uranium and thorium in acid mine drainage environments indicate high mobility under acid-weathering conditions but measurable attenuation associated with iron and aluminum colloid formation. Mass balances from field and laboratory studies are being used to quantify the amount of attenuation. 5) A field study in Colorado demonstrated the use of 234 U/ 238 U isotopic ratio measurements to evaluate contamination of shallow groundwater with uranium mill effluent.

Utah↗

Finite-difference modeling and dispersion analysis of high-frequency love waves for near-surface applications

Love-wave propagation has been a topic of interest to crustal, earthquake, and engineering seismologists for many years because it is independent of Poisson's ratio and more sensitive to shear (S)-wave velocity changes and layer thickness changes than are Rayleigh waves. It is well known that Love-wave generation requires the existence of a low S-wave velocity layer in a multilayered earth model. In order to study numerically the propagation of Love waves in a layered earth model and dispersion characteristics for near-surface applications, we simulate high-frequency (>5 Hz) Love waves by the staggered-grid finite-difference (FD) method. The air-earth boundary (the shear stress above the free surface) is treated using the stress-imaging technique. We use a two-layer model to demonstrate the accuracy of the staggered-grid modeling scheme. We also simulate four-layer models including a low-velocity layer (LVL) or a high-velocity layer (HVL) to analyze dispersive energy characteristics for near-surface applications. Results demonstrate that: (1) the staggered-grid FD code and stress-imaging technique are suitable for treating the free-surface boundary conditions for Love-wave modeling, (2) Love-wave inversion should be treated with extra care when a LVL exists because of a lack of LVL information in dispersions aggravating uncertainties in the inversion procedure, and (3) energy of high modes in a low-frequency range is very weak, so that it is difficult to estimate the cutoff frequency accurately, and "mode-crossing" occurs between the second higher and third higher modes when a HVL exists. ?? 2010 Birkh??user / Springer Basel AG.

Pure and Applied Geophysics↗

The use of fluorite geochemistry and machine learning to identify critical mineral systems

Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.

Mineralium Deposita↗

Near-solidus melts of MORB + 4 wt% H2O at 0.8 – 2.8 GPa applied to issues of subduction magmatism and continent formation

Experiments on MORB + 4 wt% H 2 O at 0.8–2.8 GPa and 700–950 °C (Liu in High pressure phase equilibria involving the amphibolite–eclogite transformation. PhD dissertation, Stanford University, Stanford, California, 1997; Liu et al. in Earth Planet Sci Lett 143:161–171, 1996) were reexamined for their major and trace element melt compositions and melting relations. Degree of melting diminishes at greater pressures, with corresponding evolution of melt from andesitic at the lowest pressures and hottest temperatures to high-silica rhyolitic at the greatest pressure and coolest temperature. Quartz contributes greatly to the production of near-solidus melts of basaltic eclogite, with the result that melt productivity falls markedly following quartz exhaustion. This limits the extent of melting attainable in the basaltic eclogite portions of sub-arc subducting plates to no more than ~ 2 × the modal wt% quartz in the mafic eclogite protolith. Synthesized residual mineral assemblages lack an epidote-series mineral at temperatures > 750 °C, and as a result, melts from the rutile eclogite and rutile-amphibole eclogite facies have elevated concentrations of light rare earth elements, U, Th, have elevated Ba, K, and Sr, high Sr/Y, and are strongly depleted in Nb, Y, and the heavy rare earth elements. Models of eclogite partial melt reacting with peridotite of the mantle wedge reproduce major and trace element characteristics of parental arc magmas so long as the proportions of infiltrating melt to peridotite are relatively high, consistent with channelized ascent. Melt mass is estimated to increase roughly three- to ten-fold, consistent with H 2 O concentrations of 3–7 wt% in the magmas produced by reaction. Partial melts of subducting basaltic eclogite are predicted to have positive Sr concentration anomalies, relative to Ce and Nd, that persist through melt-peridotite reactions. Primitive arc magmas commonly have positive Sr anomalies, whereas such anomalies are smaller in estimates of the bulk continental crust. Overall, Sr anomalies diminish passing from primitive to more evolved arc volcanic rocks, consistent with extensive mineral-melt differentiation (crystallization, partial remelting) involving plagioclase. On the order of 50 wt% differentiation would be necessary to eliminate Sr positive anomalies, based on geochemical variations in the Cascade and western Aleutian magmatic arcs. Loss to the mantle of cumulates and restites with high Sr anomalies, in abundances broadly equal to the mass of the preserved crust, would be required to form the continents via processes similar to present-day subduction magmatism.

Contributions to Mineralogy and Petrology↗

Estimation of elastic moduli in a compressible Gibson half-space by inverting Rayleigh-wave phase velocity

A Gibson half-space model (a non-layered Earth model) has the shear modulus varying linearly with depth in an inhomogeneous elastic half-space. In a half-space of sedimentary granular soil under a geostatic state of initial stress, the density and the Poisson's ratio do not vary considerably with depth. In such an Earth body, the dynamic shear modulus is the parameter that mainly affects the dispersion of propagating waves. We have estimated shear-wave velocities in the compressible Gibson half-space by inverting Rayleigh-wave phase velocities. An analytical dispersion law of Rayleigh-type waves in a compressible Gibson half-space is given in an algebraic form, which makes our inversion process extremely simple and fast. The convergence of the weighted damping solution is guaranteed through selection of the damping factor using the Levenberg-Marquardt method. Calculation efficiency is achieved by reconstructing a weighted damping solution using singular value decomposition techniques. The main advantage of this algorithm is that only three parameters define the compressible Gibson half-space model. Theoretically, to determine the model by the inversion, only three Rayleigh-wave phase velocities at different frequencies are required. This is useful in practice where Rayleigh-wave energy is only developed in a limited frequency range or at certain frequencies as data acquired at manmade structures such as dams and levees. Two real examples are presented and verified by borehole S-wave velocity measurements. The results of these real examples are also compared with the results of the layered-Earth model. ?? Springer 2006.

Surveys in Geophysics↗

Preface—Evaluating the response of critical zone processes to human impacts with sediment source fingerprinting

1) Background: Critical Zone Processes in the Anthropocene The Earth’s Critical Zone encompasses a suite of interconnected processes in the near-surface lithosphere, pedosphere, biosphere, atmosphere, and hydrosphere (Brantley et al., 2007; Lin, 2010) (Fig. 1). Processes and interactions both within and between these various Critical Zone components supports life-sustaining ecosystem services and resources that establish the foundation for humanity (NRC, 2001). This includes the formation production of fertile soils, flourishing vegetation, productive rivers, lakes and oceans, and our life-sustaining atmosphere (Gaillardet, 2014; Guo and Lin, 2016). Rapid population growth, land use intensification, and global environmental change are disturbing many of these fundamental Critical Zone processes. More than half of the Earth’s terrestrial surface is now impacted by anthropogenic activities (e.g., clearing, grazing, plowing, mining, and logging) (Hooke et al., 2012; Richter and Mobley, 2009). These changes are so widespread and pervasive that the great acceleration of socioeconomic development that occurred around 1950 (Fig. 2) has been recommended to delineate the dawn of the Anthropocene (Waters et al., 2016). Although the utility of adopting and delineating the Anthropocene as the current epoch is subject to debate (Crutzen, 2002; Ruddiman et al., 2015; Smith and Zeder, 2013), the concept effectively highlights both the nature and the extent of our global impact on Earth’s Critical Zone. Soil forming processes and ecosystem services provided by the pedosphere are central to the Critical Zone (Banwart et al., 2011; Lin, 2010). Many of these processes have been disturbed by the agricultural intensification that coincided with the great acceleration resulting in unsustainable land use practices now outpacing soil formation processes (Brantley et al., 2007). As agricultural landscapes now cover an area equivalent to what was scoured during the last glacial maximum (Amundson et al., 2007), the broad-scale intensification of anthropogenic activities has resulted in significant on- and off-site impacts. On-site, soil loss has resulted in decreases in soil fertility and agricultural yields (Ladha et al., 2009) threatening the ability to feed the world’s growing population (Brantley et al., 2007). Off-site, the excess delivery of particulate matter downstream is degrading riverine, lacustrine, and estuarine ecosystems (Bilotta and Brazier, 2008; Clark, 1985; Owens et al., 2005). The challenge, as noted by Brantley et al., (2007), is that despite our society having over 10,000 years of experience working with soils, our conceptual and quantitative models remain inadequate at predicting Critical Zone dynamics under current conditions. Notwithstanding growing pressure for improved environmental management, we still have a limited capacity to predict changes in the Critical Zone in response to anthropogenic activities owing to the multiple spatial and temporal scales at which these complex processes and feedbacks are manifest. As river basin systems are impacted by many of these processes, a deep understanding of soil-sediment continuum dynamics may provide a valuable framework for evaluating the disturbance response of Critical Zone processes. Understanding these processes may also provide land and resource managers with the information necessary to manage both the on-site and off-site effects of accelerated soil erosion.

Journal of Soils and Sediments↗

The development of China’s monopoly over cobalt battery materials

While previous resource conflicts have often been linked to fuel minerals such as oil, future resource conflict may revolve around nonfuel minerals that enable strategic emerging technologies. During a 2010 diplomatic dispute, China reportedly blocked exports of rare earth elements to Japan, thereby leveraging China’s near-monopoly to threaten Japanese manufacturers of advanced technologies including batteries and permanent magnets. Although this caused significant concern for manufacturers outside China, China’s control over other critical minerals has yet to be studied comprehensively. Besides rare earth elements, perhaps no mineral has received more attention for its supply risks than cobalt. Here Chinese control is estimated for each cobalt material at each stage of the cobalt supply chain from 2000 through 2022. The results show that from mining, to refining, consumption, recycling, stocks, and trade, China dominates the cobalt materials that feed lithium-ion battery cathode production. Specifically, the results show that in 2022 Chinese firms had control over 62% of cobalt mine materials primarily used for cobalt chemical refining, 95% control of refined commercial-grade cobalt chemicals, 92% control of battery-grade tricobalt tetroxide, 85% control of battery-grade cobalt sulfate, and 91% control of nickel–cobalt-manganese cathode precursor materials. China’s monopoly over cobalt battery materials may imply a serious supply risk to non-Chinese battery producing and consuming industries—especially given rising geopolitical tensions and the reemergence of critical mineral export restrictions including gallium for semiconductors, germanium for solar panels, graphite for lithium-ion batteries, and (again) rare earth elements.

Mineral Economics↗

The Cretaceous-Tertiary extinction: A lethal mechanism involving anhydrite target rocks

The Chicxulub Crater, Yucatan, Mexico, is a leading contender as the site for the impact event that caused the Cretaceous-Tertiary (K-T) extinctions. A considerable thickness of anhydrite (CaSO 4 ) forms part of the target rock. High temperatures resulting from impact would drive SO 2 off from the anhydrite. Hundreds of billions of tonnes of sulfuric acid aerosol would thus enter the stratosphere and cause considerable cooling of the Earth's surface, decrease photosynthesis by orders of magnitude, deplete the ozone layer, and permit increased UV radiation to reach the Earth's surface. Finally, the aerosol would fall back to Earth as acid rain and devastate land and some lacustrine biota and near-surface marine creatures. The presence of anhydrite in the Chicxulub target rock may thus help explain the many extinctions observed at the K-T boundary.

Geochimica et Cosmochimica Acta↗

Pre-gilbertian conceptions of terrestrial magnetism

It is now well known that William Gilbert, in his De Magnete of 1600, first suggested that the earth behaves as a great magnet. By their very nature, however, such explicit statements tend, in retrospect, to be emphasised at the expense of less explicit antecedent ideas and experiments, with the result that, in the example under consideration here, the impression has sometimes been given that before Gilbert there was not the slightest suspicion that the earth exerts influence on the magnetic needle. In fact, Gilbert's conclusion represented the culmination of many centuries of thought and experimentation on the subject. This essay traces the main steps in the evolutionary process from the idea that magnetic ‘virtue’ derived from the heave, through the gradual realisation that magnetism is closely associated with the earth, up to the time of Gilbert's definite statement.

Tectonophysics↗