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Geospatial analysis identifies critical mineral-resource potential in Alaska

Alaska consists of more than 663,000 square miles (1,717,000 square kilometers) of land—more than a sixth of the total area of the United States—and large tracts of it have not been system atically studied or sampled for mineral- resource potential. Many regions of the State are known to have significant mineral-resource potential, and there are currently six operating mines in the State along with numerous active mineral exploration projects. The U.S. Geologi cal Survey and the Alaska Division of Geological & Geophysical Surveys have developed a new geospatial tool that integrates and analyzes publicly available databases of geologic information and estimates the mineral-resource potential for criti cal minerals, which was recently used to evaluate Alaska. The results of the analyses highlight areas that have known mineral deposits and also reveal areas that were not previously considered to be prospective for these deposit types. These results will inform land manage ment decisions by Federal, State, and private landholders, and will also help guide future exploration activities and scientific investigations in Alaska.

Alaska↗

Preliminary report on the Nelson and Radovan copper prospects, Nizina district, Alaska

Renewed copper exploration by Alaska Copper Mines, Incorporated, at the Nelson and Radovan prospects, Nizina district, Alaska, led the Geological Survey in 1951 to map in detail the Nelson fault block, and to re-examine the old workings. In addition, two new prospects were studied. The Nelson fault block is cut by many dominantly strike-slip faults of small displacement, and by bedding faults. Slickensided chalcocite shows post-mineral movement, and chalcocite veinlet in a filled solution cavity indicates that some of the chalcocite is secondary, perhaps very recent. Structural relations indicate two overthrust faults cut the block. The Radovan Greenstone prospect shows massive chalcocite, up to 3 feet wide, in a silicified, epidotized fault zone in the Nikolai greenstone. Ore indicated by surface exposures may amount to 450 tons of chalcocite. The Radovan Low-Contact prospect is on a continuation of the same fault approximately 3 miles southwest of the Greenstone prospect, and 150 feet above the contact of the Nikolai greenstone and the overlying Chitistone limestone. Limonite staining is widespread in bedding planes and small faults near the fault zone; mineralization in the fault zone consists of pyrite, chalcocite, bornite, malachite, realgar, orpiment and stibnite. The sulphides in the fault zone, plus the widespread silicification and epidotization indicate a strong zone of hydrothermal activity which merits extensive prospecting.

Open-File Report↗

Gravity survey in part of the Snake River Plain, Idaho — A preliminary report

During the early summer of 1959, a total of 1,187 gravity stations were occupied on the western part of the Snake River plain in Idaho. An area of 2,000 square miles extending from Glenns Ferry, Idaho, to Caldwell, Idaho, was covered with a station density of one station per two square miles. An additional 1,200 square miles of surrounding area, mainly from Caldwell, Idaho, to the Oregon-Idaho state line, was covered with a density of one station per seven square miles. The mean reproducibility of the observed gravities of these stations was 0.05 milligal, with a maximum discrepancy of 0.2 milligal. Gravity data were reduced to simple Bouguer values using a combined free-air and Bouguer correction of 0.06 milligal per foot. The only anomalies found with closure in excess of 10 milligals are two elongated highs, orientated northwest-southeast, with the northwestern high offset to the northeast by 10 miles. The smaller of these highs extends from Meridian, Idaho, to Nyssa, Oregon, and the larger extends from Swan Falls, Idaho, to Glenns Ferry, Idaho. The maximum value recorded is a simple Bouguer value of -66.5 milligals with respect to the International Ellipsoid. Gradients on the sides of these highs are largest on the northeast sides, reaching six milligals per mile in places. Graticule interpretations of a profile across the southeastern high using a density contrast of 0.3 gm per cubic centimeter indicate an accumulation of lava reaching a thickness of at least 28,000 feet. The Snake River investigation was made for the purpose of searching out, defining, and interpreting gravity anomalies present on the western part of the Snake River lava plain in Idaho. In particular, it was desired to further define gradients associated with the gravity high shown by the regional work of Bonini and Lavin (1957). It was not planned to cover any specific area, but rather to let the observed anomalies determine the course of the field work. The study was undertaken as part of a project on Volcanism and Crustal Deformation, supervised by L. C. Pakiser of the U.S. Geological Survey. Professor Rodgers of the Geophysics Department of the Colorado School of Mines acted as an advisor.

Idaho↗

Water-quality data for two surface coal mines reclaimed with alkaline waste or urban sewage sludge, Clarion County, Pennsylvania, May 1983 through November 1989

Water-quality and other hydrologic data for two surface coal mines in Clarion County, Pa., were collected during 1983-89 as part of studies conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Resources. Water samples were collected from streams, seeps, monitor wells, and lysimeters on a monthly basis to evaluate changes in water quality resulting from the addition of alkaline waste or urban sewage sludge to the reclaimed mine-spoil surface. The mines are about 3.5 miles apart and were mined for bituminous coal of the upper and lower Clarion seams of the Allegheny Group of Pennsylvanian age. The coal had high sulfur (greater than 2 weight percent) concentrations. Acidic mine drainage is present at both mines. At one mine, about 8 years after mining was completed, large quantities (greater than 400 tons per acre) of alkaline waste consisting of limestone and lime-kiln flue dust were applied on two 2.5-acre plots within the 65-acre mine area. Water-quality data for the alkaline-addition plots and surrounding area were collected for 1 year before and 3 years after application of the alkaline additives (May 1983-July 1987). Data collected for the alkaline-addition study include ground-water level, surface-water discharge rate, temperature, specific conductance, pH, and concentrations of alkalinity, acidity, sulfate, iron (total and ferrous), manganese, aluminum, calcium, and magnesium. At the other mine, about 3.5 years after mining was completed, urban sewage sludge was applied over 60 acres within the 150-acre mine area. Waterquality data for the sludge-addition study were collected for 3.5 years after the application of the sludge (June 1986-December 1989). Data collected for the sludge-addition study include the above constituents plus dissolved oxygen, redox potential (Eh), and concentrations of dissolved solids, phosphorus, nitrogen species, sulfide, chloride, silica, sodium, potassium, cyanide, arsenic, barium, boron, cadmium, chromium, copper, lead, mercury, molybdenum, nickel, selenium, strontium, and zinc. Climatic data, including monthly average temperature and cumulative precipitation, from a nearby weather station for the period January 1983 through December 1989 also are reported.

Open-File Report↗

Geologic map of Kundelan ore deposits and prospects, Zabul Province, Afghanistan; modified from the 1971 original map compilations of K.I. Litvinenko and others

This map and cross sections are redrafted modified versions of the Geological map of the Kundelan ore deposit area, scale 1:10,000 (graphical supplement no. 18) and the Geological map of the Kundelan deposits, scale 1:2,000 (graphical supplement no. 3) both contained in an unpublished Soviet report by Litvinenko and others (1971) (report no. 0540). The unpublished Soviet report was prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan in Kabul during 1971. This redrafted map and cross sections illustrate the geology of the main Kundelan copper-gold skarn deposit, located within the Kundelan copper and gold area of interest (AOI), Zabul Province, Afghanistan. Areas of interest (AOIs) of non-fuel mineral resources within Afghanistan were first described and defined by Peters and others (2007) and later by the work of Peters and others (2011a). The location of the main Kundelan copper-gold skarn deposit (area of this map) and the Kundelan copper and gold AOI is shown on the index map provided on this map sheet. The estimated resources of the Kundelan copper-gold skarn deposit are 21,400 metric tons (t) of copper, 1.6 t of gold, and 133.4 t of molybdenum at an average grade of 1.21 weight percent (wt. %) copper (ranging from 0.66 to 4.03 wt. % copper); 0.9 grams per metric ton (g/t) gold (ranging from 0.3 to 3.1 g/t gold); 0.14 wt. % molybdenum; and as much as 10 g/t silver and 0.03 wt. % bismuth (Peters and others, 2011b). Small past production of gold and base metals is also reported by Douvgal and others (1971) from many prospects within the Kundelan copper and gold AOI. Outside the skarn areas, argillic hydrothermal alteration is present (Abdullah and others, 1977). Most copper and gold prospects in the Kundelan copper and gold AOI are reported to contain commercial-grade ores of copper and (or) gold, and many prospect areas have potential for these commodities to be discovered in commercial volumes. Future initial mine exploration and later development in many of the prospects, and specifically in the Kundelan copper-gold skarn deposit, could result in near-term small- to medium-sized gold mining operations (Peters and others, 2011b). The redrafted map and cross sections reproduce the topology of rock units, contacts, faults, and so forth, of the original Soviet map and cross sections, and they include modifications based on our examination of these documents and our observations made during a brief field visit in August of 2010. We have attempted to translate the original Russian terminology and rock classifications into modern English geologic usage as literally as possible without changing any genetic or process-oriented implications in the original descriptions. We also use the age designations from the original Soviet maps, except for the phase I and II intrusive igneous rocks. Phase I and II igneous rocks are reassigned an Early Cretaceous age (from lower Paleogene) based on a uranium-lead (U-Pb) zircon SHRIMP analysis from quartz diorite, which yielded an age of 104±1 Ma (mega-annum). The information provided in the description of map units is from both the source report by Litvinenko and others (1971) and the original 1:10,000 scale map (graphical supplement no. 18), also from Litvinenko and others (1971). Because of the poor quality of the original map, some map features could not be identified and some features may be misinterpreted. The rock unit colors used on the redrafted maps and cross sections differ from the colors shown on the original Soviet version. Colors were selected according to the color and pattern scheme of the Commission for the Geological Map of the World (CGMW) at http://www.ccgm.org. Elevations on the cross sections are derived from the original Soviet topography and may not match the Global Digital Elevation Model (GDEM) topography used on the redrafted map of this report. Most hydrography derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) has not been included on our redrafted version of the map because of a poor fit with alluvial deposits from the unmodified original Soviet map (graphical supplement no. 18; Litvinenko and others, 1971).

Zabul Province↗

Report of the committee on chemistry of natural waters, 1933–34

The personnel of this Committee during the past year, practically the same as during the previous year, has been as follows: C. S. Howard, Chairman—United States Geological Survey, Washington, D.C. L. C. Case—Gypsy Oil Company, Tulsa, Oklahoma. W. D. Collins—United States Geological Survey, Washington, D.C. H. F. Flynn—United States Engineer Office, 35 South Ninth Street, Philadelphia, Pennsylvania. W. P. Kelley—University of California, Riverside, California. Alfred C. Lane—Tufts College, Tufts College, Massachusetts. Augustus Locke—477 Mills Building, San Francisco, California. R. D. Leitch—United States Bureau of Mines, Pittsburgh, Pennsylvania. H. T. Logan—United States Bureau of Standards, Washington, D.C. Thomas S. Lovering—United States Geological Survey, Washington, D.C. Thomas E. Means—111 Sutter Street, San Francisco, California. F. B. Plummer—University of Texas, Austin, Texas. J. W. Sale—United States Food and Drug Administration, Washington, D.C. C S. Scofield—Bureau of Plant Industry, Department of Agriculture, Washington, D.C. Thomas G. Thompson—University of Washington, Seattle, Washington.

Eos, Transactions, American Geophysical Union↗

Potential sites for a spent unreprocessed fuel facility (SURFF), southwestern part of the Nevada Test Site

In the absence of specific criteria, the topography, geomorphology, and geology of Jackass Flats and vicinity in the southwestern part of the Nevada Test Site are evaluated by arbitrary guidelines for a Spent Unreprocessed Fuel Facility. The guidelines include requirements for surface slopes of less than 5 percent, 61 m of alluvium beneath the site, an area free of active erosion or deposition, lack of faults, a minimum area of 5 km2, no potential for flooding, and as many logistical support facilities as possible. The geology of the Jackass Flats area is similar to the rest of the Nevada Test Site in topographic relief (305-1,200 m), stratigraphy (complexly folded and faulted Paleozoic sediments overlain by Tertiary ash-flow tuffs and lavas overlain in turn by younger alluvium), and structure (Paleozoic thrust faults and folds, strike-slip faults, proximity to volcanic centers, and Basin and Range normal faults). Of the stratigraphic units at the potential Spent Unreprocessed Fuel Facility site in Jackass Flats, only the thickness and stability of the alluvium are of immediate importance. Basin and Range faults and a possible extension of the Mine Mountain fault need further investigation. The combination of a slope map and a simplified geologic and physiographic map into one map shows several potential sites for a Spent Unreprocessed Fuel Facility in Jackass Flats. The potential areas have slopes of less than 5 percent and contain only desert pavement or segmented desert pavement--the two physiographic categories having the greatest geomorphic and hydraulic stability. Before further work can be done, specific criteria for a Spent Unreprocessed Fuel Facility site must be defined. Following criteria definition, potential sites will require detailed topographic and geologic studies, subsurface investigations (including geophysical methods, trenching, and perhaps shallow drilling for faults in alluvium), detailed surface hydrologic studies, and possibly subsurface hydrologic studies.

Nevada↗

Groundwater quality and geochemistry of West Virginia’s southern coal fields

Coal mining has been the dominant industry and land use in West Virginia’s southern coal fields since the mid-1800s. Mortality rates for a variety of serious chronic conditions, such as diabetes, heart disease, and some forms of cancer in Appalachian coal mining regions, are higher than in areas lacking substantial coal mining activity within the Appalachian Region or elsewhere in the United States. Causes of the increased mortality and morbidity are not clear, but poor diet, high rates of smoking, socioeconomic factors, and the quality of groundwater used by area residents are all possible contributing factors. This study was conducted by the U.S. Geological Survey in cooperation with the West Virginia Department of Health and Human Resources and the West Virginia Department of Environmental Protection, with grant support from the Centers for Disease Control and Prevention (CDC) to assess the quality of groundwater in southern West Virginia. The data from this assessment of groundwater quality may be used by the CDC and other agencies to potentially investigate the role or lack thereof of groundwater quality with respect to mortality and morbidity rates in the region. The study was conducted in a region where a high density of current or past coal mining combined with a lack of advanced sewage treatment could affect concentrations of commonly occurring constituents plus contaminants, including nitrate, trace metals, major ions, indicator bacteria, radon, hydrogen sulfide, and dissolved hydrocarbons. Because rural residential wells and mine outfalls are considered private sources of water in the region, and are therefore unregulated and unmonitored, water-quality data are sparse. To fill the data gap and assess the groundwater quality in the region, water-quality samples were collected from 60 sites in a 10-county area. The 60 sites sampled included 46 rural residential homeowner wells and 14 mine outfall discharges used for residential supply. For this study, all samples were collected prior to any filtration or other treatments, typically at the pressure tank, and are indicative of total and dissolved constituents in the untreated water. Generally, data for the 60 sites indicate that most waters sampled do not exceed thresholds for most U.S. Environmental Protection Agency (EPA) drinking-water standards and U.S. Geological Survey (USGS) drinking-water screening criteria. However, there were several notable exceptions. Turbidity exceeded the 5-Nephelometric Turbidity Unit (NTU) EPA treatment technique (TT) drinking-water standard in 14 of 60 (23 percent) sites sampled and exceeded the 1-NTU TT standard in 51 of 60 (85 percent) sites sampled. Turbidity is common in many wells in southern West Virginia and may be attributed to iron oxyhydroxide precipitates, sediment carried into the aquifers from the shallow soil zone due to improperly constructed or cased wells or transported to the aquifer in shallow stress-relief fracture zones or through permeable bedding-plane partings. For the sites sampled, 31 of 60 (52 percent) had pH values at, above, or below the upper and lower range of the EPA Secondary Maximum Contaminant Level (SMCL, 6.5–8.5 standard units). Of those 31 sites, 28 (90 percent) were indicative of acidic corrosive water and 3 (10 percent) were indicative of alkaline water. The Langelier Saturation Index (LSI), which is a measure of the corrosivity of the water, was computed for all sites sampled for the study. Eighty-two percent of the sites sampled had waters that were classified as corrosive, based on a LSI less than −0.5. Corrosive water has the potential to leach lead, copper, and other metals from lead, copper, galvanized, or lead-tin soldered connections in water lines. The chloride to sulfate mass ratio also was assessed with the alkalinity to indicate the potential to promote galvanic corrosion (PPGC) of water lines and plumbing fixtures. Only one of the sites (1.7 percent) classified as a corrosive water site, had a PPGC considered high; the remaining sites were classified as having either a moderate (53.3 percent) or low (45 percent) PPGC. Therefore, the type of plumbing systems sampled for this study may be affected by corrosive water, but the potential for leaching trace metals and other constituents from residential plumbing systems containing older galvanized pipes or lead-tin soldered copper pipes is moderate to low. The indicator bacteria total coliform and Escherichia coli ( E. coli ) also were detected in groundwater samples to varying degrees. Total coliforms, which are a broad class of indicator bacteria, are common in groundwater in southern West Virginia and were detected in 39 of the 60 sites (65 percent) sampled. The presence of total coliform bacteria is a potential indicator of surface contamination, due to improperly constructed or cased wells, or infiltration of soil or other surface contaminants into the aquifer or well bore. E. coli bacteria, however, are much more indicative of fecal contamination of groundwater from either human or animal sources, and 14 of the 60 (23 percent) sites sampled had detections of E. coli . Although only a few strains of E. coli are known pathogens, their presence in groundwater may be an indicator of other related pathogens such as viruses and should be regarded as a serious potential issue. Water treatment such as chlorination, ozonation, or ultraviolet light may be appropriate to kill potential pathogenic bacteria or viruses in the source water. Manganese and iron were prevalent contaminants in the groundwater samples collected for this study, with 30 of 60 (50 percent) sites analyzed for manganese and 25 of 60 (42 percent) sites analyzed for iron exceeding the proposed 50- and 300-micrograms per liter (µg/L) SMCL drinking-water standards, respectively, for aesthetic criteria such as taste, odor, or staining of plumbing fixtures. Fourteen of the 60 sites sampled (23 percent) had concentrations of manganese that exceeded the 300-µg/L USGS health-based screening level, and 1 site exceeded the 1,600-µg/L EPA drinking-water equivalent level, which is based on a lifetime exposure level. Sodium is another common constituent in groundwater within the study area. Sodium has an EPA health-based value (HBV) of 20 milligrams per liter (mg/L) for individuals who are on a sodium-restricted diet for blood pressure or other health reasons. Sodium concentrations exceeded the 20-mg/L EPA HBV in 27 of 60 (45 percent) samples. Radon, a naturally occurring carcinogenic radioactive gas known to cause lung cancer, was detected at concentrations at or exceeding the proposed 300-picocuries per liter (pCi/L) EPA Maximum Contaminant Level (MCL) in 12 of the 60 (20 percent) sites sampled. Sites with radon gas concentrations exceeding the 300-pCi/L proposed MCL have the potential for airborne concentrations of radon to exceed the 4-pCi/L indoor air standard. Inhalation of radon can cause lung cancer, and the 4-pCi/L indoor air standard is based on an inhalation standard. Therefore, homeowners whose wells have radon gas concentrations exceeding 300 pCi/L may be advised to have their indoor air tested to determine if indoor air concentrations exceed the 4-pCi/L indoor air standard established by the EPA. Various factors were analyzed statistically and graphically to determine whether they have an influence on groundwater quality within the study area, including topographic setting, well depth, type of mining (surface or underground), type of site (well or mine outfall), and geologic formation. Only geologic formation and the type of site sampled had strong statistical correlations with one or more of the constituents of concern for this study. The overall chemistry of outfalls (mine outfalls) and wells was significantly different, with a much higher dissolved oxygen content in outfalls than in wells. The dissolved oxygen content is the primary component driving the oxidation and reduction of minerals, and the precipitation of minerals that are saturated or super saturated with respect to various cations and anions. Median dissolved oxygen concentrations for the outfalls sampled was 8.75 mg/L, and only 0.4 mg/L for the wells sampled. Median concentrations of sulfate and selenium were much higher in waters from the outfalls sampled, with median concentrations of 73.75 mg/L and 2.35 µg/L, respectively, compared to the wells sampled, which had median concentrations of 18.3 mg/L and less than (<) the 0.05-µg/L method detection limit, respectively. The maximum selenium concentration was for a well, with a concentration of 16.6 µg/L. The geochemical processes that control sulfate and selenium concentrations in groundwater are similar and are the result of the oxidation of sulfide minerals such as pyrite and ferroselite. Iron and manganese concentrations were elevated in most of the wells sampled, with median concentrations of 269.5 and 124.5 µg/L, respectively, but were rarely detected in the outfalls sampled, with median concentrations of < 4.0 and < 0.4 µg/L, respectively. The difference in iron and manganese between wells and outfalls is indicative of the role of dissolved oxygen on processes controlling groundwater chemistry in the region. Three principal geologic formations were assessed for the study, and the overall chemistry for the Pocahontas, New River, and Kanawha Formations varied substantially with respect to several constituents. Concentrations of calcium, magnesium, and total dissolved solids were highest for sites sampled in the Pocahontas Formation, with median concentrations of 41.9, 18.6, and 312 mg/L, respectively. For constituents that are commonly associated with mining activity, the highest concentrations were for sites sampled in the New River Formation, with median concentrations of iron and manganese of 2,450 µg/L and 482 µg/L, respectively, and a median pH of 6.35 standard units. Concentrations of barium also were elevated in samples collected from sites in the New River Formation, with a median barium concentration of 184 µg/L. The source of the barium is not fully known but may be associated with commingling of shallow groundwater with deeper brines or dissolution of the mineral barite. The highest median sulfate concentrations were from sites sampled in the Pocahontas Formation, with a median concentration of 64.0 mg/L. Of the 12 sites at or exceeding the 300-pCi/L proposed drinking-water standard for radon, 8 (67 percent of MCL exceedances) were for sites deriving water from the Kanawha Formation, 3 (25 percent of MCL exceedances) were for sites deriving water from the New River Formation, and only 1 site was for water from the Pocahontas Formation (8 percent of proposed MCL exceedances). Dissolved hydrocarbons, including methane, ethane, propane, propene, n - and i -butane, 1-butene, n - and i -pentane, pentane, 2- and 3-ethyl pentane, hexane, and benzene were analyzed in samples collected from 59 of the 60 sites to assess the potential occurrence and sources of these trace gases in groundwater within the study area. Results of the analysis indicate that most of the gas is of shallow biogenic origin, possibly associated with coal-bed methane, but a subset of samples has a gas signature and a chloride to bromide ratio indicative of potential mixing with deeper thermogenic gases. Only 2 of the 59 (3.3 percent) sites sampled had concentrations of methane gas, which is a highly combustible and explosive gas, exceeding the 10 milligrams per kilogram level of concern established by the U.S. Office of Surface Mining Reclamation and Enforcement. Principal components analysis was used to assess the primary geochemical processes occurring in the aquifers sampled. The first principal component had significant positive loadings for bromide, chloride, silica, ammonia, barium, iron, manganese, and arsenic, and significant negative loadings for dissolved oxygen, potassium, nitrate, and uranium, and reflects reduction and oxidation (redox) processes occurring in deeper anoxic groundwater or shallow oxic groundwater. The strong positive loadings for iron, manganese, barium, and arsenic are correlated with reducing conditions often found deeper in the aquifer. More oxic water is correlated with oxidation of nitrogen species to nitrate and environmental mobilization of uranium and sulfate in shallow wells and mine outfalls.

West Virginia↗

Geology and geochemistry of jasperoids from the Gold Bar district, Nevada

Gold Bar is one of several Carlin-type gold mining districts located in the Battle Mountain-Eureka trend, Nevada. It is composed of one main deposit, Gold Bar; five satellite deposits; and four resources that contain 1.6 Moz (50 t) of gold. All of the deposits and resources occur at the intersection of north-northwest- and northeast-trending high-angle faults in slope facies limestones of the Devonian Nevada Group exposed in windows through Ordovician basin facies siliciclastic rocks of the Roberts Mountains allochthon. Igneous intrusions and magnetic anomalies are notably absent. The Gold Bar district contains a variety of discordant and stratabound jasperoid bodies, especially along the Wall Fault zone, that were mapped and studied in some detail to identify the attributes of those most closely associated with gold ore and to constrain genetic models. Four types of jasperoids, J0, J1, J2, and J3, were distinguished on the basis of their geologic and structural settings and appearance. Field relations suggest that J0 formed during an early event. Petrographic observations, geochemistry, and ??18O values of quartz suggest it was overprinted by the hydrothermal event that produced ore-related J1, J2, and J3 jasperoids and associated gold deposits. The greater amount of siliciclastic detritus present in J0 jasperoids caused them to have higher ??18O values than J1,2,3 jasperoids hosted in underlying limestones. Ore-related jasperoids are composed of main-ore-stage replacements and late-ore-stage open-space filling quartz with variable geochemistry and an enormous range of ??18O values (24.5 and -3.7???). Jasperoids hosted in limestones with the most anomalous Au, Ag, Hg, ??(As, Sb, Tl) concentrations and the highest ??18O values are associated with the largest deposits. The 28??? range of jasperoid ??18O values is best explained by mixing between an 18O-enriched fluid and an 18O-depleted fluid. The positive correlation between the sizes of gold deposits and the ??18O composition of jasperoids indicates that gold was introduced by the 18O-enriched fluid. The lowest calculated ??18O value for water in equilibrium with late-ore-stage quartz at 200??C (-15???) and the measured ??D value of fluid inclusion water extracted from late-ore-stage orpiment and realgar (-116???) indicate that the 18O-depleted fluid was composed of relatively unexchanged meteoric water. The source of the 18O-enriched ore fluid is not constrained. The ??34S values of late-ore-stage realgar, orpiment, and stibnite (5.7-15.5???) and barite (31.5-40.9???) suggest that H2S and sulfate were derived from sedimentary sources. Likewise, the ??13C and ??18O values of late-stage calcite (-4.8 to 1.5??? and 11.5 to 17.4???, respectively) suggest that CO2 was derived from marine limestones. Based on these data and the apparent absence of any Eocene intrusions in the district, Gold Bar may be the product of a nonmagmatic hydrothermal system. ?? Springer-Verlag 2006.

Mineralium Deposita↗

Natural and mining-related sources of dissolved minerals during low flow in the Upper Animas River Basin, southwestern Colorado

As part of the Clean Water Act of 1972 (Public Law 92-500), all States are required to establish water-quality standards for every river basin in the State. During 1994, the Colorado Department of Public Health and Environment proposed to the Colorado Water Quality Control Commission (CWQCC) an aquatic-life standard of 225 µg/L (micrograms per liter) for the dissolved-zinc concentration in the Animas River downstream from Silverton (fig.1). The CWQCC delayed implementation of this water-quality standard until further information was collected and a plan for the cleanup of abandoned mines was developed. Dissolved-zinc concentrations in this section of the river ranged from about 270 µg/L during high flow, when rainfall and snowmelt runoff dilute the dissolved minerals in the river (U.S. Geological Survey, 1996, p. 431), to 960 µg/L (Colorado Department of Public Health and Environment, written commun., 1996) during low flow (such as late summer and middle winter when natural springs and drainage from mines are the main sources for the streams). Mining sites in the basin were developed between about 1872 and the 1940's, with only a few mines operated until the early 1990's. For local governments, mining sites represent part of the Nation's heritage, tourists are attracted to the historic mining sites, and governments are obligated to protect the historic mining sites according to the National Historic Preservation Act (Public Law 89-665). In the context of this fact sheet, the term "natural sources of dissolved minerals" refers to springs and streams where no effect from mining were determined. "Mining-related sources of dissolved minerals" are assumed to be: (1 ) Water draining from mines , and (2) water seeping from mine-waste dump pile where the waste piles were saturated by water draining from mines. Although rainfall and snowmelt runoff from mine-waste piles might affect water quality in streams, work described in this fact sheet was done during low-flow conditions when springs and drainage from mine were the main sources of dissolved minerals affecting the streams. Data are being collected by the U.S. Geological Survey (USGS) to determine the magnitude and sources of dissolved minerals during rainfall- and snowmelt-runoff periods. This fact sheet presents results of studies done by the USGS in collaboration with the Animas River Stakeholders Group and was prepared in cooperation with the Southwestern Colorado Water Conservation District. The studies were done at selected sites in the Upper Animas River Basin to determine natural and mining-related sources of dissolved minerals and are continuing in the basin with the Animas River Stakeholders Group and as part of the Department of the Interior Abandoned Mine Lands Initiative. The results of these studies will provide useful information for determining water-quality standards in the basin.

Colorado↗

Salinization of the upper Colorado River - Fingerprinting geologic salt sources

Salt in the upper Colorado River is of concern for a number of political and socioeconomic reasons. Salinity limits in the 1974 U.S. agreement with Mexico require the United States to deliver Colorado River water of a particular quality to the border. Irrigation of crops, protection of wildlife habitat, and treatment for municipal water along the course of the river also place restrictions on the river's salt content. Most of the salt in the upper Colorado River at Cisco, Utah, comes from interactions of water with rock formations, their derived soil, and alluvium. Half of the salt comes from the Mancos Shale and the Eagle Valley Evaporite. Anthropogenic activities in the river basin (for example, mining, farming, petroleum exploration, and urban development) can greatly accelerate the release of constituents from these geologic materials, thus increasing the salt load of nearby streams and rivers. Evaporative concentration further concentrates these salts in several watersheds where agricultural land is extensively irrigated. Sulfur and oxygen isotopes of sulfate show the greatest promise for fingerprinting the geologic sources of salts to the upper Colorado River and its major tributaries and estimating the relative contribution from each geologic formation. Knowing the salt source, its contribution, and whether the salt is released during natural weathering or during anthropogenic activities, such as irrigation and urban development, will facilitate efforts to lower the salt content of the upper Colorado River.

Colorado↗

Report on S.E.G. Symposium on the chemistry of the ore-forming fluids August-September,1964

Sessions included presentations and discussions of the following topics: mineral stability and phase assemblages at ore - forming temperatures and pressures; high-temperature solution chemistry of sulfides, carbonates, and silicates, with consideration of complexing and stability, and the generation of ore fluids ; hydrothermal fluids as deduced from wallrock alteration, from fluid inclusions and hot springs, from isotopic studies, and from mine studies, zoning, and so forth.

Economic Geology↗

Estimated water use in Ohio, 1990 -- Mining data

Our Nation's social and economic development has depended on and will continue to depend on the availability of usable water. In 1950, the U.S. Geological Survey (USGS) began publishing water-use data on a national level every 5 years to assist in the management of our Nation's water resources. The USGS currently collects and (or) estimates water-use data for the following categories: public supply, domestic, commercial, industrial, thermoelectric power, mining, livestock, animal specialties, irrigation, hydroelectric power (instream use), sewage treatment, and reservoir evaporation. In 1977, Congress authorized the National Water-Use Information Program. The program encourages the USGS and a State-level agency in each of the 50 States to cooperate in the collection and dissemination of water-use data. In Ohio, the USGS and the Ohio Department of Natural Resources, Division of Water (ODNR-DW), are cooperators in this effort. In 1990, ODNR-DW implemented the Water Withdrawal Facility Registration Program for Ohio, which requires those water consumers who have the capacity to withdraw 100,000 gallons of water daily to register with the ODNR-DW. Consumers whose daily capacity is less than 100,000 gallons are not required to register. The information collected from the registrants is maintained in computerized data bases at the ODNR-DW and the Ohio District Office of the USGS. This Fact Sheet, which summarizes Ohio's 1990 mining water-use data, is one of a series that supplements, by category, the national USGS publication on water use.

Ohio↗

Conodont color and surface textural alteration in the Muschelkalk (Triassic) of the Silesian-Cracow Zn-Pb district, Poland

Limestone and dolostone samples were collected from sites within and adjacent to ore zones in the Trzebionka mine, Silesia-Cracow zinc-lead mining district, southern Poland, to assess the level of thermal alteration of the enclosed conodonts, via the color alteration index (CAI) technique, and to study any surface alteration effects on these microfossils. Additional conodont sampling from stratigraphic levels correlative with the horizons being mined in the Trzebionka mine was accomplished at four surface and two borehole localities in the district, to compare the CAI and surface alteration effects at these, commercially non-mineralized, localities with those effects in the mine. Data show that: 1. The overall background thermal level of the Triassic strata studied, presumably due to only shallow burial, is very low: CAI = 1; in the range of 50 to 80??C. 2. CAI values in the ore zones in the Trzebionka mine are slightly higher than this regional background: 1+ to 1.5 (in the range ???50 to 90??C minimum heating over geologic time of about 0.1 to more than 1 m. y.). This implies that heating "events" of higher temperatures affecting the conodonts, including the passage of the local ore-bearing solutions, were of rather short duration(s), on the order of about 1,000 to 50,000 years. CAI data from the Trzebionka Mine is consistent with temperature data from fluid inclusions, indicating ore-bearing fluid temperatures in the 100 to 138??C range, and the scenario that these fluids were resident in these strata for a geologically short period. 3. Conodonts from both surface and subsurface samples rarely show surface corrosion effects, but tend to show apatite overgrowths. These overgrowths vary in degree of development, but are consistent for each morphological type of conodont element, and qualitatively are consistent in each sample observed. 4. Ichthyoliths (fish teeth, spines, and scales), found in most of the samples, do not exhibit either mineral overgrowths or apparent corrosion effects to the extent seen in the conodont elements. 5. Ichthyoliths show color alteration effects that are consistent within-sample but which are very different from the CAI values of conodonts in the same sample. The color alteration of the fish teeth might be of value as a thermal maturation index in the future, if and when calibrated through controlled laboratory experimental testing, but at present cannot and should not be used as equivalent to conodont CAI.

Prace - Panstwowego Instytutu Geologicznego↗

Preliminary investigation of the distribution and resources of coal in the Kaiparowits Plateau, southern Utah

This report on the coal resources of the Kaiparowits Plateau, Utah is a contribution to the U.S. Geological Survey's (USGS) 'National Coal Resource Assessment' (NCRA), a five year effort to identify and characterize the coal beds and coal zones that could potentially provide the fuel for the Nation's coal-derived energy during the first quarter of the twenty-first century. For purposes of the NCRA study, the Nation is divided into regions. Teams of geoscientists, knowledgeable about each region, are developing the data bases and assessing the coal within each region. The five major coal-producing regions of the United States under investigation are: (1) the Appalachian Basin; (2) the Illinois Basin; (3) the Gulf of Mexico Coastal Plain; (4) the Powder River Basin and the Northern Great Plains; and (5) the Rocky Mountains and the Colorado Plateau. Six areas containing coal deposits in the Rocky Mountain and Colorado Plateau Region have been designated as high priority because of their potential for development. This report on the coal resources of the Kaiparowits Plateau is the first of the six to be completed. The coal quantities reported in this study are entirely 'resources' and represent, as accurately as the data allow, all the coal in the ground in beds greater than one foot thick. These resources are qualified and subdivided by thickness of coal beds, depth to the coal, distance from known data points, and inclination (dip) of the beds. The USGS has not attempted to estimate coal 'reserves' for this region. Reserves are that subset of the resource that could be economically produced at the present time. The coal resources are differentiated into 'identified' and 'hypothetical' following the standard classification system of the USGS (Wood and others, 1983). Identified resources are those within three miles of a measured thickness value, and hypothetical resources are further than three miles from a data point. Coal beds in the Kaiparowits Plateau are laterally discontinuous relative to many other coal bearing regions of the United States. That is, they end more abruptly and are more likely to fragment or split into thinner beds. Because of these characteristics, the data from approximately 160 drill holes and 40 measured sections available for use in this study are not sufficient to determine what proportion of the resources is technologically and economically recoverable. The Kaiparowits Plateau contains an original resource of 62 billion short tons of coal in the ground. Original resource is defined to include all coal beds greater than one foot thick in the area studied. None of the resource is recoverable by surface mining. However, the total resource figure must be regarded with caution because it does not reflect geologic, technological, land-use, and environmental restrictions that may affect the availability and the recoverability of the coal. At least 32 billion tons of coal are unlikely to be mined in the foreseeable future because the coal beds are either too deep, too thin to mine, inclined at more than 12?, or in beds that are too thick to be completely recovered in underground mining. The estimated balance of 30 billion tons of coal resources does not reflect land use or environmental restrictions, does not account for coal that would be bypassed due to mining of adjacent coal beds, does not consider the amount of coal that must remain in the ground for roof support, and does not take into consideration the continuity of beds for mining. Although all of these factors will reduce the amount of coal that could be recovered, there is not sufficient data available to estimate recoverable coal resources. For purposes of comparison, studies of coal resources in the eastern United States have determined that less than 10 percent of the original coal resource, in the areas studied, could be mined economically at today's prices (Rohrbacher and others, 1994).

Open-File Report↗