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At least 91 records · Page 5Linked to original sources

VegET evapotranspiration for Africa: Continental-scale simulation, multi-product evaluation, and drought assessment

Study region Continental Africa, encompassing diverse climatic zones—tropical, arid, and temperate—and spanning major transboundary river basins such as the Nile, Niger, Congo, Volta, and Zambezi River Basins. The region exhibits pronounced hydroclimatic gradients and heterogeneous land use systems ranging from rainfed croplands and rangelands to dense tropical forests and irrigated schemes. Study focus Actual evapotranspiration (ETa) is a central component of the terrestrial water balance, governing the redistribution of water and energy between the land surface and the atmosphere. Accurate estimation of ETa at continental scale is critical for hydrological monitoring, water resource management, and climate adaptation, as well as for quantifying water, energy, and carbon fluxes that underpin sustainable development. In this study, we applied the agro-hydrologic VegET v2 model to simulate a new, high-resolution, continental-scale ETa dataset for Africa (2000–2021). The model results were benchmarked against four widely used remote sensing-based products—MODIS16 v6.1, SSEBop v6.1, WaPOR v3, and GLEAM v4.1a—across major climate zones, land use types, and River Basins, providing a comprehensive multi-product evaluation of evapotranspiration dynamics across the continent. New hydrological insights for the region Validation against eddy covariance flux tower observations at eight representative sites confirmed that VegET v2 accurately reproduces the seasonal dynamics of observed ETa, achieving a correlation (r) of 0.8 and an RMSE of 25 mm month⁻¹ —accuracy that is comparable to or higher than accuracies of satellite-based products MODIS16, SSEBop, and GLEAM. This study represents one of the first Africa-wide hydrological simulations of ETa, extending the VegET model beyond basin-scale applications. Intercomparisons reveal that VegET aligns closely with MODIS16, SSEBop, and GLEAM in humid and tropical regions (r = 0.80–0.90; RMSE < 20 mm month⁻¹), while greater discrepancies appear in arid and semi-arid zones, where WaPOR tends to overestimate ETa (RMSE ≥ 28 mm month⁻¹). Despite these differences, VegET effectively captures spatial and temporal ETa variability across rainfed croplands, forests, and savannas, supporting its utility in regional water balance assessments, water accounting, and drought monitoring. A key application of VegET v2 is the Evapotranspiration Deficit Index (ETDI), derived by integrating VegET-based ETa with potential evapotranspiration (PET) to quantify water stress. ETDI successfully captured major drought episodes across Africa, including persistent Sahelian and southern African dry spells, the 2020–2021 winter drought in the Maghreb, and the 2018–2019 austral summer drought in southern Africa, while identifying positive anomalies over central Africa indicative of recurrent wetness. These results underscore VegET’s capability as a hydrologically consistent, operational tool for continental ETa monitoring and drought assessment, offering support for basin-scale water balance studies, food security planning, and climate resilience across Africa’s diverse hydrological environments.

Journal of Hydrology: Regional Studies↗

Computational electromagnetic geophysics for groundwater system studies: A review on established practices and recent advances

Identifying effective solutions for locating groundwater resources and ensuring the quality of drinking water is increasingly urgent, given the challenges posed by climate change and population growth. This review investigates electromagnetic geophysical imaging techniques, in both time- and frequency-domain, that can provide valuable insights for groundwater assessment. We explore computational electromagnetic methods used to evaluate electromagnetic data and several recent hydrogeophysical case studies. As open-source frameworks for modeling electromagnetic geophysical problems become available, a broader range of researchers can interpret their data with computationally advanced software. We provide an overview of documented open-source codes for evaluating electromagnetic data and analyze various hydrological targets in relation to their electromagnetic surveying technique and the computational method applied. Furthermore, we evaluate the potential of advanced computational techniques, including three-dimensional modeling, non-deterministic inversion and machine learning, to couple geophysical with numerical groundwater modeling and apply it in groundwater system studies. Despite obstacles such as complexity and resource demands, our findings indicate that the quantification and integration of predictive uncertainties from both electromagnetic and hydrological data and simulations would significantly improve the reliability of hydrogeophysical models. This can lead to a deeper understanding of groundwater systems and improved management practices.

Journal of Hydrology↗

Modelling streamwater chemistry as a mixture of soilwater end-members - An application to the Panola Mountain catchment, Georgia, U.S.A.

Streamwater chemistry at Panola Mountain research catchment, Georgia, U.S.A., is explained as a mixture of representative soilwater solutions that are considered to be temporally invariant to a first approximation. The selection of three end-members from all sampled soil waters is evaluated by comparing the observed and predicted streamwater concentration of six solutes (alkalinity, sulfate, sodium, magnesium, calcium and dissolved silica), which are assumed to mix conservatively, and by assessing the consistency of the implied hydrograph separation with the hydrological mechanisms that are believed to be operating in this catchment. The percentage of variation in the streamwater solute concentrations explained by the end-member mixing analysis (EMMA) ranges from 82 to >97%, and the hydrograph separation is, intuitively, physically reasonable. If the correct end-members have been identified, the streamwater chemical response to different levels of acidic deposition can be predicted by examining the change in each end-member under different loads; no hydrological model is required. If a traditional hydrochemical model, which is driven by rainfall quantity and quality, is desired, this analysis provides an indication of the model structure that would be necessary to reproduce both streamwater and soilwater chemistry.

Georgia↗

Effects of climate and land management change on streamflow in the driftless area of Wisconsin

Baseflow and precipitation in the Kickapoo River Watershed, located in the Driftless Area of Wisconsin, exhibit a step increase around 1970, similar to minimum and median flows in many other central and eastern USA streams. Potential effects on streamflow due to climatic and land management changes were evaluated by comparing volumetric changes in the hydrologic budget before and after 1970. Increases in precipitation do not fully account for the increase in baseflow, which appears to be offset by a volumetric decrease in stormflow. This suggests that factors that influence the partitioning of precipitation into overland runoff or infiltration have changed. A transition from relatively more intensive to relatively less intensive agricultural land use is generally associated with higher infiltration rates, and likely influences partitioning of flow. Changes in agricultural land management practices in the Driftless Area, which began in the mid-1930s, do not coincide with the abrupt increase in baseflow around 1970. Instead, the timing of hydrologic change appears to coincide with changes in precipitation, whereas the magnitude of the change in baseflow and stormflow was likely amplified by changes in agricultural land management. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

Hydrologic modeling in a marsh-mangrove ecotone: Predicting wetland surface water and salinity response to restoration in the Ten Thousand Islands region of Florida, USA

At the fringe of Everglades National Park in southwest Florida, United States, the Ten Thousand Islands National Wildlife Refuge (TTINWR) habitat has been heavily affected by the disruption of natural freshwater flow across the Tamiami Trail (U.S. Highway 41). As the Comprehensive Everglades Restoration Plan (CERP) proposes to restore the natural sheet flow from the Picayune Strand Restoration Project area north of the highway, the impact of planned measures on the hydrology in the refuge needs to be taken into account. The objective of this study was to develop a simple, computationally efficient mass balance model to simulate the spatial and temporal patterns of water level and salinity within the area of interest. This model could be used to assess the effects of the proposed management decisions on the surface water hydrological characteristics of the refuge. Surface water variations are critical to the maintenance of wetland processes. The model domain is divided into 10 compartments on the basis of their shared topography, vegetation, and hydrologic characteristics. A diversion of + 10 % of the discharge recorded during the modeling period was simulated in the primary canal draining the Picayune Strand forest north of the Tamiami Trail (Faka Union Canal) and this discharge was distributed as overland flow through the refuge area. Water depths were affected only modestly. However, in the northern part of the refuge, the hydroperiod, i.e., the duration of seasonal flooding, was increased by 21 days (from 115 to 136 days) for the simulation during the 2008 wet season, with an average water level rise of 0.06 m. The average salinity over a two-year period in the model area just south of Tamiami Trail was reduced by approximately 8 practical salinity units (psu) (from 18 to 10 psu), whereas the peak dry season average was reduced from 35 to 29 psu (by 17%). These salinity reductions were even larger with greater flow diversions ( + 20 % ). Naturally, the reduction in salinity diminished toward the open water areas where the daily flood tides mix in saline bay water. Partially restoring hydrologic flows to TTINWR will affect hydroperiod and salinity regimes within downslope wetlands, and perhaps serve as a management tool to reduce the speed of future encroachment of mangroves into marsh as sea levels rise.

Journal of Hydrologic Engineering↗

Collaborative modelling and integrated decision support system analysis of a developed terminal lake basin

A terminal lake basin in west-central Nevada, Walker Lake, has undergone drastic change over the past 90 yrs due to upstream water use for agriculture. Decreased inflows to the lake have resulted in 100 km 2 decrease in lake surface area and a total loss of fisheries due to salinization. The ecologic health of Walker Lake is of great concern as the lake is a stopover point on the Pacific route for migratory birds from within and outside the United States. Stakeholders, water institutions, and scientists have engaged in collaborative modeling and the development of a decision support system that is being used to develop and analyze management change options to restore the lake. Here we use an integrated management and hydrologic model that relies on state-of-the-art simulation capabilities to evaluate the benefits of using integrated hydrologic models as components of a decision support system. Nonlinear feedbacks among climate, surface-water and groundwater exchanges, and water use present challenges for simulating realistic outcomes associated with management change. Integrated management and hydrologic modeling provides a means of simulating benefits associated with management change in the Walker River basin where drastic changes in the hydrologic landscape have taken place over the last century. Through the collaborative modeling process, stakeholder support is increasing and possibly leading to management change options that result in reductions in Walker Lake salt concentrations, as simulated by the decision support system.

Nevada↗

Timescales of water-quality change in a karst aquifer, south-central Texas

Understanding the drivers and timescales over which groundwater quality changes informs groundwater management, use, and protection. To better understand timescales of water-quality change over short (daily to monthly) and long (seasonal to decadal) timescales, the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Enhanced Trends Network (ETN) program instrumented and sampled three wells in the Edwards aquifer in south-central Texas. The wells were instrumented to provide high-frequency continuous (subhourly) water-quality data (temperature, pH, specific conductance, and dissolved oxygen), which were augmented by the collection of discrete samples (about 6 per year) for a range of geochemical constituents (including selected isotopes and age tracers). ETN data (2013–2017) are considered with data from additional sites for the same time period, and also historical records (over more than 80 years) of climatic and hydrologic conditions. During the four-year study, hydrologic conditions transitioned from very dry to very wet. Sites in the updip/unconfined part of the aquifer showed notable changes in water level and geochemistry (1) in response to rainfall/recharge events, and (2) over the multiyear dry/wet cycle. Sites in the downdip/confined part of the aquifer showed changes in water level/spring discharge over similar timescales, although the response is more muted. Geochemistry at the downdip/confined sites, however, varied slowly and minimally, indicating that the geochemical response of the deeper aquifer is decoupled from recent hydrologic responses. Changes at the updip/unconfined sites reflect mixing with recent recharge, whereas the downdip/confined sites were dominated by mineral-solution reactions resulting from longer (decadal) residence times. Mean groundwater ages interpreted from measured age tracers and lumped parameter models range from 7 to >700 years (where mixed with premodern downdip water) but were mostly modern. The aquifer is characterized by updip-to-downdip trends in geochemistry with respect to water-rock interaction and groundwater age. Fourier spectral analysis of historical records indicate hydrologic variability has occurred at dominant periods of 30 and 15 years; in conjunction with age tracers, these results provide insight into timescales at which the aquifer’s public supply is vulnerable to changes in the water quality of recharge.

Texas↗

Evolution of the conceptual model of unsaturated zone hydrology at Yucca Mountain, Nevada

Yucca Mountain is an arid site proposed for consideration as the United States’ first underground high-level radioactive waste repository. Low rainfall (approximately 170 mm/yr) and a thick unsaturated zone (500–1000 m) are important physical attributes of the site because the quantity of water likely to reach the waste and the paths and rates of movement of the water to the saturated zone under future climates would be major factors in controlling the concentrations and times of arrival of radionuclides at the surrounding accessible environment. The framework for understanding the hydrologic processes that occur at this site and that control how quickly water will penetrate through the unsaturated zone to the water table has evolved during the past 15 yr. Early conceptual models assumed that very small volumes of water infiltrated into the bedrock (0.5–4.5 mm/yr, or 2–3 percent of rainfall), that much of the infiltrated water flowed laterally within the upper nonwelded units because of capillary barrier effects, and that the remaining water flowed down faults with a small amount flowing through the matrix of the lower welded, fractured rocks. It was believed that the matrix had to be saturated for fractures to flow. However, accumulating evidence indicated that infiltration rates were higher than initially estimated, such as infiltration modeling based on neutron borehole data, bomb-pulse isotopes deep in the mountain, perched water analyses and thermal analyses. Mechanisms supporting lateral diversion did not apply at these higher fluxes, and the flux calculated in the lower welded unit exceeded the conductivity of the matrix, implying vertical flow of water in the high permeability fractures of the potential repository host rock, and disequilibrium between matrix and fracture water potentials. The development of numerical modeling methods and parameter values evolved concurrently with the conceptual model in order to account for the observed field data, particularly fracture flow deep in the unsaturated zone. This paper presents the history of the evolution of conceptual models of hydrology and numerical models of unsaturated zone flow at Yucca Mountain, Nevada (Flint, A.L., Flint, L.E., Kwicklis, E.M., Bodvarsson, G.S., Fabryka-Martin, J.M., 2001. Hydrology of Yucca Mountain. Reviews of Geophysics in press). This retrospective is the basis for recommendations for optimizing the efficiency with which a viable and robust conceptual model can be developed for a complex site.

Nevada↗

Calibrated models as management tools for stream-aquifer systems: The case of central Kansas, USA

We address the problem of declining streamflows in interconnected stream-aquifer systems and explore possible management options to address the problem for two areas of central Kansas: the Arkansas River valley from Kinsley to Great Bend and the lower Rattlesnake Creek-Quivira National Wildlife Refuge area. The approach we followed implements, calibrates, and partially validates for the study areas a stream-aquifer numerical model combined with a parameter estimation package and sensitivity analysis. Hydrologic budgets for both predevelopment and developed conditions indicate significant differences in the hydrologic components of the study areas resulting from development. The predevelopment water budgets give an estimate of natural ground-water recharge, whereas the budgets for developed conditions give an estimate of induced recharge, indicating that major ground-water development changes the recharge-discharge regime of the model areas with time. Such stream-aquifer models serve to link proposed actions to hydrologic effects, as is clearly demonstrated by the effects of various management alternatives on the streamflows of the Arkansas River and Rattlesnake Creek. Thus we show that a possible means of restoring specified streamflows in the area is to implement protective stream corridors with restricted ground-water extraction.

Journal of Hydrology↗

Use of Doppler velocity radars to monitor and predict debris and flood wave velocities and travel times in post-wildfire basins

The magnitude and timing of extreme events such as debris and floodflows (collectively referred to as floodflows) in post-wildfire basins are difficult to measure and are even more difficult to predict. To address this challenge, a sensor ensemble consisting of noncontact, ground-based (near-field), Doppler velocity (velocity) and pulsed (stage or gage height) radars, rain gages, and a redundant radio communication network was leveraged to monitor flood wave velocities, to validate travel times, and to compliment observations from NEXRAD weather radar. The sensor ensemble (DEbris and Floodflow Early warNing System, DEFENS) was deployed in Waldo Canyon, Pike National Forest, Colorado, USA, which was burned entirely (100 percent burned) by the Waldo Canyon fire during the summer of 2012 ( MTBS, 2020 ). Surface velocity, stage, and precipitation time series collected during the DEFENS deployment on 10 August 2015 were used to monitor and predict flood wave velocities and travel times as a function of stream discharge (discharge; streamflow). The 10 August 2015 event exhibited spatial and temporal variations in rainfall intensity and duration that resulted in a discharge equal to 5.01 cubic meters per second (m 3 /s). Discharge was estimated post-event using a slope-conveyance indirect discharge method and was verified using velocity radars and the probability concept algorithm. Mean flood wave velocities – represented by the kinematic celerity ( c k = 2.619 m e t e r s p e r s e c o n d , m / s &#xB1; 0.556 p e r c e n t "> 𝑐 𝑘 = 2.619 𝑚𝑒𝑡𝑒𝑟𝑠 𝑝𝑒𝑟 𝑠𝑒𝑐𝑜𝑛𝑑, m/s ± 0.556 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and dynamic celerity ( c d = 3.533 m / s &#xB1; 0.181 p e r c e n t a n d t h e i r u n c e r t a i n t i e s "> 𝑐 𝑑 = 3.533 m/s ± 0.181 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and their uncertainties were computed. L-moments were computed to establish probability density functions (PDFs) and associated statistics for each of the at-a-section hydraulic parameters to serve as a workflow for implementing alert networks in hydrologically similar basins that lack data. Measured flood wave velocities and travel times agreed well with predicted values. Absolute percent differences between predicted and measured flood wave velocities ranged from 1.6 percent to 49 percent and varied with water slope, hydraulic radius, and depth. The kinematic celerity was a better predictor for steep slopes and wide flood plains associated with the Upper Waldo and Middle Waldo radar streamgages; whereas, the dynamic celerity was a better surrogate for shallow slopes and incised channels such as the Lower Waldo radar streamgage. The method demonstrates the potential extensibility of a post-wildfire warning system by (1) leveraging multiple systems (i.e., weather radar, near-field velocity and stage radars, and rain gages) for accurate and timely warnings of debris and floodflows, (2) establishing an order of operations to site, install, and operate near-field radars and conventional rain gages to record floodflows, forecast travel times, and document geomorphic change in this basin and hydrologically similar basins that lack data, and (3) communicating data operationally with the Colorado Department of Transportation engineering staff, National Weather Service forecasters, and emergency managers.

Colorado↗

Measurement of fluid velocity using temperature profiles: Experimental verification

Temperature profiling has been used to predict the rate and direction of groundwater movement. A controlled field experiment was conducted to ascertain the validity of the rate calculations made using this method. The vertical velocity, or leakage, of groundwater between two aquifers was calculated utilizing both hydrologic and temperature measurements in a well drilled into the Paw Paw buried bedrock valley in northern Illinois. The experiment showed that accurate estimates of leakage can be made in stable boreholes where there are no geologic complications. Estimates utilizing temperature and hydrologic methods produced similar results for one of two aquicludes. However, the methods produced dissimilar results for the second aquiclude. It is speculated that the presence of a thin organic silt caused most of the problem; other complicating factors were lithologic variation and a very low hydraulic gradient. Nevertheless, the method appears to have great promise in many geologic environments.

Illinois↗

Groundwater-derived nutrient and trace element transport to a nearshore Kona coral ecosystem: Experimental mixing model results

Study region The groundwater influenced coastal waters along the arid Kona coast of the Big Island, Hawai’i. Study focus A salinity-and phase partitioning-based mixing experiment was constructed using contrasting groundwater endmembers along the arid Konacoast of the Big Island, Hawai’i and local open seawater to better understand biogeochemical and physicochemical processes that influence the fate of submarine groundwater discharge (SGD)-derived nutrients and trace elements. New Hydrological Insights for the Region Treated wastewater effluent was the main source for nutrient enrichment downstream at the Honokōhau Harbor site. Conservative mixing for some constituents, such as nitrate + nitrite, illustrate the effectiveness of physical mixing to maintain oceanic concentrations in the colloid (0.02–0.45 μm) and truly dissolved (

Hawaii↗

An overview of current applications, challenges, and future trends in distributed process-based models in hydrology

Process-based hydrological models have a long history dating back to the 1960s. Criticized by some as over-parameterized, overly complex, and difficult to use, a more nuanced view is that these tools are necessary in many situations and, in a certain class of problems, they are the most appropriate type of hydrological model. This is especially the case in situations where knowledge of flow paths or distributed state variables and/or preservation of physical constraints is important. Examples of this include: spatiotemporal variability of soil moisture, groundwater flow and runoff generation, sediment and contaminant transport, or when feedbacks among various Earth&rsquo;s system processes or understanding the impacts of climate non-stationarity are of primary concern. These are situations where process-based models excel and other models are unverifiable. This article presents this pragmatic view in the context of existing literature to justify the approach where applicable and necessary. We review how improvements in data availability, computational resources and algorithms have made detailed hydrological simulations a reality. Avenues for the future of process-based hydrological models are presented suggesting their use as virtual laboratories, for design purposes, and with a powerful treatment of uncertainty.

Journal of Hydrology↗

An operational GLS model for hydrologic regression

Recent Monte Carlo studies have documented the value of generalized least squares (GLS) procedures to estimate empirical relationships between streamflow statistics and physiographic basin characteristics. This paper presents a number of extensions of the GLS method that deal with realities and complexities of regional hydrologic data sets that were not addressed in the simulation studies. These extensions include: (1) a more realistic model of the underlying model errors; (2) smoothed estimates of cross correlation of flows; (3) procedures for including historical flow data; (4) diagnostic statistics describing leverage and influence for GLS regression; and (5) the formulation of a mathematical program for evaluating future gaging activities.

Journal of Hydrology↗

Comparison of chemical hydrogeology of the carbonate peninsulas of Florida and Yucatan

Aquifers of the peninsulas of Florida and northern Yucatan are Tertiary marine carbonate formations showing many lithologic and faunal similarities. In addition, the tropical to subtropical climates of the two areas are similar, each having annual rainfall of about 1000 to 1500 mm. Despite similarities in these fundamental controls, contrasts in the hydrologic and geochemical systems are numerous and striking. For example, Florida has many rivers; Yucatan has none. Maximum thickness of fresh ground water in Florida is about 700 meters; in the Yucatan it is less than 70 meters. In Florida the gradient of the potentiometric surface averages about 1 meter per kilometer; in the Yucatan it is exceedingly low, averaging about 0.02 meter per kilometer. In Florida the chemical character of water changes systematically downgradient, owing to solution of minerals of the aquifer and corresponding increases in total dissolved solids, sulfate, calcium, and Mg-Ca ratio; in the Yucatan no downgradient change exists, and dominant processes controlling the chemical character of the water are solution of minerals and simple mixing of the fresh water and the body of salt water that underlies the peninsula at shallow depth. Hydrologic and chemical differences are caused in part by the lower altitude of the Yucatan plain. More important, however, these differences are due to the lack of an upper confining bed in Yucatan that is hydrologically equivalent to the Hawthorn Formation of Florida. The Hawthorn cover prevents recharge and confines the artesian water except where it is punctured by sinkholes, but sands and other unconsolidated sediments fill sinkholes and cavities and impede circulation. In the Yucatan the permeability of the entire section is so enormous that rainfall immediately infiltrates to the water table and then moves laterally to discharge areas along the coasts.

Florida Peninsula, Yucatan Peninsula↗

Regional patterns in hydrologic response, a new three-component metric for hydrograph analysis and implications for ecohydrology, Northwest Volcanic Aquifer Study Area, USA

Study Region Oregon, California, Idaho, Nevada and Utah Study Focus Spatial patterns of hydrologic response were examined for the Northwest Volcanic Aquifer Study Area (NVASA). The utility of established hydrograph-separation methods for assessing hydrologic response in permeable volcanic terranes was assessed and a new three-component metric for hydrograph analysis was developed. The new metric, which partitions streamflow into subcomponents defined by the timescales of hydrologic response (e.g., fast-runoff, intermediate-interflow and slow-baseflow), was used to gain a fundamental understanding of the regional hydrology, investigate sub-regional differences, influencing factors, and ecohydrological implications. New Hydrological Insights The combined effects of NVASA’s physiography, climate and geology create a strongly coupled surface-groundwater system that produces copious baseflow and limited quantities of runoff and interflow. Patterns of hydrologic response are influenced by the type and rate of precipitation and permeability of the underlying geology. Under variable precipitation conditions the hydrologic response of volcanic terranes with similar permeability and subsurface-storage capacity can be significantly different. From a water management and ecohydrology perspective, understanding regional patterns of hydrologic response and sub-regional differences is fundamental. Results indicate that minimum-flow methods provide the most conservative estimate of baseflow and may be the most robust for filtering out snowmelt bias in baseflow estimates. Baseflow contributes ∼75% of the perennial streamflow across the NVASA and represents a critical component of the regional water supply that provides critical cold-water habitat.

California, Idaho, Nevada, Oregon, Utah↗

Temporal and spatial variability of shallow soil moisture across four planar hillslopes on a tropical ocean island, San Cristóbal, Galápagos

Study Region: This paper provides a summary of findings from temporal and spatial studies of soil water content on planar hillslopes across the equatorial island of San Cristóbal, Galápagos (Ecuador). Study Focus: Soil water content (SWC) was measured to generate temporal and spatial records to determine seasonal variation and to investigate how the behavior of surface and near-surface root-zone soil water may support island-wide hydrogeology models. SWC probes were installed at four weather stations in a climosequence to generate a temporal record and spatial surveys of shallow SWC across the selected sites were completed during wet and dry seasons. Temporal differences in SWC were driven by seasonal variations in rainfall and evapotranspiration, while spatial variability remained high during both wet and dry seasons. Unsaturated hydraulic conductivity determined by mini-disk infiltrometers was highly variable across the slopes, as were other hydrologic variables. New Hydrological Insights for the Region: The high heterogeneity of soil water and hydrologic characteristics provides a means to explain why little runoff is observed at the study sites: soils do not saturate uniformly across hillslopes, allowing for runoff generated in one part of the hillslope to be conducted into the soil in adjacent parts of the hillslope. The lack of connected surface runoff helps explain how water enters the groundwater system of the island.

Journal of Hydrology: Regional Studies↗

Multivariate statistical approach to estimate mixing proportions for unknown end members

A multivariate statistical method is presented, which includes principal components analysis (PCA) and an end-member mixing model to estimate unknown end-member hydrochemical compositions and the relative mixing proportions of those end members in mixed waters. PCA, together with the Hotelling T 2 statistic and a conceptual model of groundwater flow and mixing, was used in selecting samples that best approximate end members, which then were used as initial values in optimization of the end-member mixing model. This method was tested on controlled datasets (i.e., true values of estimates were known a priori) and found effective in estimating these end members and mixing proportions. The controlled datasets included synthetically generated hydrochemical data, synthetically generated mixing proportions, and laboratory analyses of sample mixtures, which were used in an evaluation of the effectiveness of this method for potential use in actual hydrological settings. For three different scenarios tested, correlation coefficients ( R 2 ) for linear regression between the estimated and known values ranged from 0.968 to 0.993 for mixing proportions and from 0.839 to 0.998 for end-member compositions. The method also was applied to field data from a study of end-member mixing in groundwater as a field example and partial method validation.

Journal of Hydrology↗