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Cenozoic tectonic evolution of the basin and range province in northwestern Nevada

A regional synthesis of new and existing geologic and thermochronologic data document late Cretaceous - early Cenozoic regional erosion, Oligocene - Miocene volcanism, and subsequent late Miocene extension of the Basin and Range Province in northwestern Nevada and northeastern California. Across an ???220-km-wide region between the Santa Rosa and Warner Ranges, conformable sequences of 35 to 15 Ma volcanic rocks are cut by only a single generation of high-angle normal faults that accommodated ???23 km of total east-west extension (???12%). Fission-track, (U-Th)/He, geologic, and structural data from the Pine Forest Range show that faulting there began at 11 to 12 Ma, progressed at a relatively constant rate until at least 3 Ma, and has continued until near the present time. Extension in the Santa Rosa Range to the east took place during the same interval, although the post-6 Ma part of this history is less well constrained. Less complete constraints from adjacent ranges permit a similar timing for faulting, and we infer that extensional faulting in northwestern Nevada began everywhere at 12 Ma and has continued up to the present. Faulting in the Warner Range in northeastern California can only be constrained to have begun between 14 and 3 Ma, but may represent westward migration of Basin and Range extension during the Pliocene. Compared to the many parts of the Basin and Range in central and southern Nevada, extension in northwestern Nevada began more recently, is of lesser total magnitude, and was accommodated entirely by high-angle normal faults. Fission-track data document Late Cretaceous unroofing of Cretaceous (115 - 100 Ma) granitic basement rocks in northwestern Nevada, followed by a long period of relative tectonic quiescence that persisted through Oligocene and Miocene volcanism until the onset of Basin and Range extension at ???12 Ma. The low magnitude of extension (12%) and early Tertiary stability suggest that the modern ???31 km thick crust in northwestern Nevada was only slightly thicker (???35 km) prior to extension at 12 Ma, and was no thicker than ???38 km in the Late Cretaceous. This stands in contrast to other parts of the Basin and Range, where the crust was thickened to at least 45 to 50 km by Cretaceous thrusting and subsequently thinned to ???30 km by large magnitude (>50%) extension.

American Journal of Science↗

Status and understanding of groundwater quality in the Cascade Range and Modoc Plateau study unit, 2010: California GAMA Priority Basin Project

Groundwater quality in the Cascade Range and Modoc Plateau study unit was investigated as part of the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The study was designed to provide a statistically unbiased assessment of untreated groundwater quality in the primary aquifer system. The depth of the primary aquifer system for the Cascade Range and Modoc Plateau study unit was delineated by the depths of the screened or open intervals of wells in the State of California’s database of public-supply wells. Two types of assessments were made: a status assessment that described the current quality of the groundwater resource, and an understanding assessment that made evaluations of relations between groundwater quality and potential explanatory factors representing characteristics of the primary aquifer system. The assessments characterize the quality of untreated groundwater, not the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on water-quality data collected in 2010 by the U.S. Geological Survey from 90 wells and springs (USGS-grid wells) and on water-quality data compiled from the State of California’s regulatory compliance database for samples collected from 240 public-supply wells between September 2007 and September 2010. To provide context, the water-quality data discussed in this report were compared to California and Federal drinking-water regulatory and non-regulatory benchmarks for treated drinking water. Groundwater quality is defined in terms of relative concentrations (RCs), which are calculated by dividing the concentration of a constituent in groundwater by the concentration of the benchmark for that constituent. The RCs for inorganic constituents (major ions, trace elements, nutrients, and radioactive constituents) were classified as “high” (the RC is greater than 1.0, indicating that the concentration is above the benchmark), “moderate” (the RC is from 1.0 to greater than 0.5), or “low” (the RC is less than or equal to 0.5). For organic constituents (volatile organic compounds and pesticides) and special-interest constituents (perchlorate), the boundary between moderate and low RCs was set at 0.1. All benchmarks used for organic constituents were health-based. For inorganic constituents, health-based and aesthetic-based benchmarks were used. Constituents without benchmarks were not considered in the status assessment . The primary metric used for quantifying regional-scale groundwater quality was the aquifer-scale proportion—the areal percentages of the primary aquifer system with high, moderate, and low RCs for a given constituent or class of constituents. The study unit was divided into six study areas on the basis of geologic differences (Eastside Sacramento Valley, Honey Lake Valley groundwater basin, Cascade Range and Modoc Plateau Low Use Basins, Quaternary Volcanic Areas, Shasta Valley and Mount Shasta Volcanic Area, and Tertiary Volcanic Areas), and each study area was divided into equal-area grid cells. Aquifer-scale proportions were calculated for individual constituents and constituent classes for each of the six study areas and for the study unit as a whole by using grid-based (one well per cell) and spatially weighted (many wells per cell) statistical methods. The status assessment showed that inorganic constituents were present at high and moderate RCs in greater proportions of the Cascade Range and Modoc Plateau study unit than were organic constituents. One or more inorganic constituents with health-based benchmarks were present at high RCs in 9.4 percent, and at moderate RCs in 14.7 percent of the primary aquifer system. Arsenic was present at high RCs in approximately 3 percent of the primary aquifer system; boron, molybdenum, uranium, and vanadium each were present at high RCs in approximately 2 percent of the primary aquifer system. One or more inorganic constituents with aesthetic-based benchmarks were present at high RCs in 15.1 percent of the primary aquifer system and at moderate RCs in 4.9 percent. Manganese, iron, and total dissolved solids were present at high RCs in approximately 12 percent, 5 percent, and 2 percent, respectively, of the primary aquifer system. Organic constituents were not detected at high or moderate RCs in the primary aquifer system, and one or more organic constituents were detected at low RCs in approximately 40 percent of the primary aquifer system. Two classes of organic constituents were detected in more than 10 percent of the primary aquifer system: trihalomethanes (chloroform only) and herbicides. The special interest constituent perchlorate was not detected at high RCs, but was detected at moderate RCs in approximately 2 percent of the primary aquifer system. The understanding assessment relied on statistical tests to evaluate relations between concentrations of constituents and values of potential explanatory factors representing geology, land use, well construction, hydrologic conditions, groundwater age, and geochemical conditions. The majority of the high and moderate RCs of arsenic, boron, molybdenum, uranium, and total dissolved solids were in samples from the Honey Lake Valley groundwater basin study area. Groundwater mixing with hydrothermal fluids present in the study area, evaporative concentration of groundwater in the Honey Lake playa, presence of uranium-bearing sediment derived from the adjacent Sierra Nevada, and release of arsenic and other trace elements from sediments under high pH and low dissolved oxygen conditions all appeared to contribute to these elevated concentrations. Thermal springs are in many parts of the Cascade Range and Modoc Plateau study unit and could account for locally elevated concentrations of arsenic, boron, molybdenum, and total dissolved solids in samples from the other study areas. Vanadium concentrations were greater in oxic samples than in anoxic samples, but were not correlated with pH, contrary to expectations from previous studies. Organic constituents were not detected at high or moderate RCs, and the occurrence of low organic constituents at low RCs ranged from 27 percent to 73 percent of the primary aquifers system in the six study areas. The Shasta Valley and Mount Shasta Volcanic study area had significantly greater occurrence of low RCs of herbicides compared to all of the other study areas, which could reflect the greater prevalence of modern groundwater in the Shasta Valley and Mount Shasta Volcanic study area and the presence of potential sources of herbicides, including applications to timberlands and roadside rights-of-way. The Eastside Sacramento Valley study area had the greatest occurrence of low concentrations of chloroform, and chloroform occurrence was most strongly associated with the combination of septic-tank density greater than two tanks per square kilometer and urban land use greater than 10 percent within a radius of 500 meters of the well. These conditions were most prevalent in the Eastside Sacramento Valley study area. The detection frequency of low concentrations of perchlorate was consistent with the probability of occurrence expected under natural conditions, except in the Eastside Sacramento Valley study area, where detection frequencies were much higher than expected and could not be explained by known anthropogenic sources of perchlorate.

California↗

Floods in Arkansas, magnitude and frequency characteristics through 1968

Techniques are presented for estimating the magnitude and frequency of floods on Arkansas streams. Modern topographic maps now available and computer techniques facilitate in making a comprehensive analysis in which physical and climactic characteristics of river basins are related to flood characteristics at gaging stations. Equations derived from the analysis make it possible to estimate the magnitude of future floods with recurrence intervals of as much as 50 years on gaged and ungaged streams that have drainage areas of 0.1-3,000 square miles. An estimate of the future flood potential can be used to locate and design flood-control structures, establish flood-insurance rates, and devise flood-zoning plans. Appendixes in the report contain data on flood characteristics of gaged drainage basins, a summary of climatic and topographic characteristics of drainage basins, peak stages and discharges for gaging stations that have 5 or more years of record, and peak-flow data for outstanding floods at miscellaneous sites.

Arkansas↗

Geology and ground-water resources of southeastern New Hampshire

The continued growth and development of southeastern New Hampshire, an area of about 390 square miles adjacent to the Atlantic Ocean, will depend partly on effectively satisfying the demand for water, which has increased rapidly since World War II. The report identifies and describes the principal geologic units with respect to the occurrence of ground water. These units include bedrock and the various unconsolidated deposits that mantle the bedrock surface discontinuously throughout the area. The bedrock formations, consisting of igneous and metamorphic rocks, chiefly of Paleozoic age, form a single water-bearing unit. Ground water is in joints and fractures. The fractures are small and scattered and therefore impart only a low permeability to the rocks. Wells in the bedrock commonly produce small but reliable supplies of ground water at depths of less than 150 feet. The yields of about 80 wells inventoried for this report ranged from 1? to 100 gpm (gallons per minute) and the median was 912 gpm. Depths ranged from 45 to 600 feet. The unconsolidated deposits consist of glacial drift of Pleistocene age; swamp deposits, alluvium, and beach deposits of Recent age; and eolian deposits of Pleistocene -and Recent age. For this report the glacial drift is divided into till, ice-contact deposits, marine deposits, and outwash and shore deposits. Glacial till forms a discontinuous blanket, commonly less than 15 but in some hills (drumlins) as much as about 200 feet thick. It has a low permeability but, because of its widespread outcrop area, it has been utilized as a source of water for numerous domestic supplies. Because most wells in till are shallow, many fail to meet modern demands during dry summers. Ice-contact deposits locally form kames, kame terraces, kame plains, and ice-channel fillings throughout the area. They overlie bedrock and till and range in thickness from less than 1 foot to as much as 190 feet. In general, the ice-contact deposits are coarse textured and permeable, but variations in- the physical and hydrologic properties of a single deposit and from deposit to deposit are common. Ice-contact deposits are the source of the larger ground-water supplies in southeastern New Hampshire. Marine deposits underlie lowlands and valleys to a distance of about 20 miles inland from the present coastline. They commonly overlie bedrock and till and at places overlie or are interbedded with ice-contact deposits. Marine deposits range in thickness from less than 1 foot to possibly 75 feet. They are fine textured and impermeable; they do not yield water to wells in southeastern New Hampshire but generally act as a barrier to ground-water movement. Outwash and shore deposits form broad sand plains or gently sloping terraces of small extent. At most places the outwash and shore deposits, which range in thickness from less than 1 foot to about 50 feet, overlie marine deposits, but at some places they overlie bedrock, till, or ice-contact deposits. The outwash and shore deposits are fine textured and moderately permeable. They commonly yield enough ground water to meet the needs of farms, homes, and small industries. Alluvium underlies the flood plains and channels of the principal streams and overlies bedrock and older unconsolidated deposits wherever streams cross the older units. The alluvium generally is not tapped by wells. Beach deposits occupy areas along the Atlantic Ocean between promontories of bedrock or till. In general beach deposits are permeable and are a source of water supplies for domestic use. Yields of wells are limited, however, by the danger of drawing in salty water. Recharge in southeastern New Hampshire is derived principally from precipitation on outcrop areas of ice-contact deposits and outwash and shore deposits during the nongrowing season. Ground water is discharged naturally by springs, by effluent seepage to streams and other bodies of surface water, and by evapotranspiration. It

Water Supply Paper↗

Preliminary Earthquake Hazard Map of Afghanistan

Introduction Earthquakes represent a serious threat to the people and institutions of Afghanistan. As part of a United States Agency for International Development (USAID) effort to assess the resource potential and seismic hazards of Afghanistan, the Seismic Hazard Mapping group of the United States Geological Survey (USGS) has prepared a series of probabilistic seismic hazard maps that help quantify the expected frequency and strength of ground shaking nationwide. To construct the maps, we do a complete hazard analysis for each of ~35,000 sites in the study area. We use a probabilistic methodology that accounts for all potential seismic sources and their rates of earthquake activity, and we incorporate modeling uncertainty by using logic trees for source and ground-motion parameters. See the Appendix for an explanation of probabilistic seismic hazard analysis and discussion of seismic risk. Afghanistan occupies a southward-projecting, relatively stable promontory of the Eurasian tectonic plate (Ambraseys and Bilham, 2003; Wheeler and others, 2005). Active plate boundaries, however, surround Afghanistan on the west, south, and east. To the west, the Arabian plate moves northward relative to Eurasia at about 3 cm/yr. The active plate boundary trends northwestward through the Zagros region of southwestern Iran. Deformation is accommodated throughout the territory of Iran; major structures include several north-south-trending, right-lateral strike-slip fault systems in the east and, farther to the north, a series of east-west-trending reverse- and strike-slip faults. This deformation apparently does not cross the border into relatively stable western Afghanistan. In the east, the Indian plate moves northward relative to Eurasia at a rate of about 4 cm/yr. A broad, transpressional plate-boundary zone extends into eastern Afghanistan, trending southwestward from the Hindu Kush in northeast Afghanistan, through Kabul, and along the Afghanistan-Pakistan border. Deformation here is expressed as a belt of major, north-northeast-trending, left-lateral strike-slip faults and abundant seismicity. The seismicity intensifies farther to the northeast and includes a prominent zone of deep earthquakes associated with northward subduction of the Indian plate beneath Eurasia that extends beneath the Hindu Kush and Pamirs Mountains. Production of the seismic hazard maps is challenging because the geological and seismological data required to produce a seismic hazard model are limited. The data that are available for this project include historical seismicity and poorly constrained slip rates on only a few of the many active faults in the country. Much of the hazard is derived from a new catalog of historical earthquakes: from 1964 to the present, with magnitude equal to or greater than about 4.5, and with depth between 0 and 250 kilometers. We also include four specific faults in the model: the Chaman fault with an assigned slip rate of 10 mm/yr, the Central Badakhshan fault with an assigned slip rate of 12 mm/yr, the Darvaz fault with an assigned slip rate of 7 mm/yr, and the Hari Rud fault with an assigned slip rate of 2 mm/yr. For these faults and for shallow seismicity less than 50 km deep, we incorporate published ground-motion estimates from tectonically active regions of western North America, Europe, and the Middle East. Ground-motion estimates for deeper seismicity are derived from data in subduction environments. We apply estimates derived for tectonic regions where subduction is the main tectonic process for intermediate-depth seismicity between 50- and 250-km depth. Within the framework of these limitations, we have developed a preliminary probabilistic seismic-hazard assessment of Afghanistan, the type of analysis that underpins the seismic components of modern building codes in the United States. The assessment includes maps of estimated peak ground-acceleration (PGA), 0.2-second spectral acceleration (SA), and 1.0-secon

Open-File Report↗

Peralkaline- and calc-alkaline-hosted volcanogenic massive sulfide deposits of the Bonnifield District, East-Central Alaska

Volcanogenic massive sulfide (VMS) Zn-Pb-Cu-Ag-Au deposits of the Bonnifield mining district formed during Late Devonian-Early Mississippian magmatism along the western edge of Laurentia. The largest deposits, Dry Creek and WTF, have a combined resource of 5.7 million tonnes at 10% Zn, 4% Pb, 0.3% Cu, 300 grams per tonne (g/t) Ag, and 1.6 g/t Au. These polymetallic deposits are hosted in high field strength element (HFSE)- and rare-earth element (REE)-rich peralkaline (pantelleritic) metarhyolite, and interlayered pyritic argillite and mudstone of the Mystic Creek Member of the Totatlanika Schist Formation. Mystic Creek metarhyolite and alkali basalt (Chute Creek Member) constitute a bimodal pair that formed in an extensional environment. A synvolcanic peralkaline quartz porphyry containing veins of fluorite, sphalerite, pyrite, and quartz intrudes the central footwall at Dry Creek. The Anderson Mountain deposit, located ~32 km to the southwest, occurs within calc-alkaline felsic to intermediate-composition metavolcanic rocks and associated graphitic argillite of the Wood River assemblage. Felsic metavolcanic rocks there have only slightly elevated HFSEs and REEs. The association of abundant graphitic and siliceous argillite with the felsic volcanic rocks together with low Cu contents in the Bonnifield deposits suggests classification as a siliciclastic-felsic type of VMS deposit. Bonnifield massive sulfides and host rocks were metamorphosed and deformed under greenschist-facies conditions in the Mesozoic. Primary depositional textures, generally uncommon, consist of framboids, framboidal aggregates, and spongy masses of pyrite. Sphalerite, the predominant base metal sulfide, encloses early pyrite framboids. Galena and chalcopyrite accompanied early pyrite formation but primarily formed late in the paragenetic sequence. Silver-rich tetrahedrite is a minor late phase at the Dry Creek deposit. Gold and Ag are present in low to moderate amounts in pyrite from all of the deposits; electrum inclusions occur in Dry Creek sphalerite. Contents and ratios of trace elements in graphitic argillite that serve as proxies for the redox state of the bottom waters in the basin indicate that Dry Creek mineralization took place in suboxic to periodically anoxic bottom waters. Trace element data show higher contents of Tl-Mn-As in pyrite from the Anderson Mountain deposit compared to the Dry Creek or WTF deposits and thus suggest that Anderson Mountain may have formed at lower temperatures or under slightly more oxidizing conditions. No exact modern analogue for the tectonic setting of the Bonnifield VMS deposits is known, although the back-arc regions of the Okinawa Trough and Woodlark Basin satisfy the requirement for a submarine, extensional setting adjacent to a continental margin. Limited occurrences of peralkaline volcanic rocks occur in these two potential analogues, but the peralkalinity of those rocks is much less than that of the Mystic Creek Member metarhyolites in the Bonnifield district. The highly elevated trace element (e.g., Zr, Nb) contents of Mystic Creek metarhyolites suggest that a better analogue may be a submarine rifted continental margin. The calc-alkaline composition of the host rocks to the Anderson Mountain deposit suggests that mineralization there formed in a continental margin arc, outboard of the extended continental margin setting of the peralkaline-hosted Dry Creek and WTF deposits.

Alaska↗

Recent trends in the nonfuel minerals industry of Iran

Summary In response to the recent removal of international sanctions on Iran, including the lifting of “secondary” sanctions by the United States on investment into and trade with Iran, the U.S. Geological Survey National Minerals Information Center compiled and analyzed available information on the current state of Iran’s nonfuel minerals industry. This Circular features a new map and table that identify existing mines and mineral-processing facilities and provide information on location, ownership, and capacity for metals and industrial minerals whose output levels may substantially change in the near future. Additionally, the report covers Iran’s mineral resources and reserves, official mineral production targets for 2025, and current output and share of global mineral production. Recent trends and developments in individual mineral commodities are discussed, including mineral exploration and partnerships with foreign investors. The U.S. Geological Survey estimated that Iran held globally significant reserves of feldspar (2d largest in the world), barite (5th largest), gypsum (5th largest), fluorspar (8th largest), and iron ore (10th largest). The Government of Iran claimed to also have significant reserves of chromium, copper, gold, manganese, phosphate rock, and zinc. In 2014, Iran was the second-leading producer of gypsum and the sixth-leading producer of barite, with 6.1 percent and 3.6 percent of world output, respectively. Iran was also the world’s 7th-leading producer of cement, feldspar, and fluorspar; 8th-leading producer of bentonite; 9th-leading producer of molybdenum; 11th-leading producer of iron ore; and 14th-leading producer of crude steel. The Government of Iran plans to quadruple the output of aluminum, copper cathode, direct-reduced iron, and iron ore pellets; triple that of crude steel and gold; and double that of cement, pig iron, and zinc by 2025. It also plans to double the contribution of mining and to quadruple that of mineral processing to the national economy in the next decade. In order to achieve these major goals, the construction and expansion of several mines and mineral facilities are planned or under development. Whether Iran’s annual mineral production increases as rapidly as envisioned by the Government will depend largely on the amount of foreign investment into the minerals industry; integration of modern technology into mineral facilities; and availability of energy to aluminum, copper, and steel plants at competitive prices to international investors.

Circular↗

Hydrogeology and water quality of the upper Floridan aquifer, western Albany area, Georgia

Geologic, hydrologic, and water-quality data were collected to refine the hydrogeologic framework conceptual model of the Upper Floridan aquifer, and to qualitatively evaluate the potential of human activities to impact water quality in the Upper Floridan aquifer in the western Albany area, Georgia. Ground-water age dating was conducted by using chlorofluorocarbons (CFC) and tritium concentrations in water from the Upper Floridan aquifer to determine if recharge and possible contaminant migration to the aquifer is recent or occurred prior to the introduction of CFCs and tritium in the early 1950's into the global natural water system. Data were collected from core holes and wells installed during this study and previously existing wells in the Albany area. Hydrogeologic data collected during this study compare well to the regional hydrogeologic conceptual model developed during previous studies. However, the greater data density available from this study shows the dynamic and local variability in the hydrologic character of the Upper Floridan aquifer in more detail. The occurrence of sediment sizes from clay to gravel in the overburden, the absence of overburden because of erosion or sinkhole collapse, and large areas lacking surface drainage west of the Flint River provide potential areas for recharge and contaminant migration from the surface to the Upper Floridan aquifer throughout the study area. Ground-water ages generally range from 9 to 34 years, indicating that recharge consisting of 'modern' water (post early-1950's) is present in the aquifer. Ground-water ages and hydraulic heads in the Upper Floridan aquifer have an irregular distribution, indicating that localized areas of recharge to the aquifer are present in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area.

Georgia↗

Seismic evidence of glacial-age river incision into the Tahaa barrier reef, French Polynesia

Rivers have long been recognized for their ability to shape reef-bound volcanic islands. On the time-scale of glacial–interglacial sea-level cycles, fluvial incision of exposed barrier reef lagoons may compete with constructional coral growth to shape the coastal geomorphology of ocean islands. However, overprinting of Pleistocene landscapes by Holocene erosion or sedimentation has largely obscured the role lowstand river incision may have played in developing the deep lagoons typical of modern barrier reefs. Here we use high-resolution seismic imagery and core stratigraphy to examine how erosion and/or deposition by upland drainage networks has shaped coastal morphology on Tahaa, a barrier reef-bound island located along the Society Islands hotspot chain in French Polynesia. At Tahaa, we find that many channels, incised into the lagoon floor during Pleistocene sea-level lowstands, are located near the mouths of upstream terrestrial drainages. Steeper antecedent topography appears to have enhanced lowstand fluvial erosion along Tahaa's southwestern coast and maintained a deep pass. During highstands, upland drainages appear to contribute little sediment to refilling accommodation space in the lagoon. Rather, the flushing of fine carbonate sediment out of incised fluvial channels by storms and currents appears to have limited lagoonal infilling and further reinforced development of deep barrier reef lagoons during periods of highstand submersion.

Tahaa barrier reef↗

Geochemistry and jasper beds from the Ordovician Løkken ophiolite, Norway: origin of proximal and distal siliceous exhalites

Stratiform beds of jasper (hematitic chert), composed essentially of SiO 2 (69–95 wt %) and Fe 2 O 3 (3–25 wt %), can be traced several kilometers along strike in the Ordovician Løkken ophiolite, Norway. These siliceous beds are closely associated with volcanogenic massive sulfide (VMS) deposits and are interpreted as sea-floor gels that were deposited by fallout from hydrothermal plumes in silica-rich seawater, in which plume-derived Fe oxyhydroxide particles promoted flocculation and rapid settling of large (~200 μm) colloidal particles of silica-iron oxyhydroxide. Concentrations of chalcophile elements in the jasper beds are at the parts per million level implying that sulfide particle fallout was insignificant and that the Si-Fe gel-forming plumes were mainly derived from intermediate- (100°–250°C) to high-temperature (>250°C) white smoker-type vents with high Fe/S ratios. The interpreted setting is similar to that of the Lau basin, where high-temperature (280°–334°C) white smoker venting alternates or overlaps with sulfide mound-forming black smoker venting. Ratios of Al, Sc, Th, Hf, and REE to iron are very low and show that the detrital input was <0.1 percent of the bulk jasper. Most jasper beds are enriched in U, V, P, and Mo relative to the North American Shale Composite, reflecting a predominantly seawater source, whereas REE distribution patterns (positive Eu and negative Ce anomalies) reflect variable mixing of hydrothermal solutions with oxic seawater at dilution ratios of ~10 2 to 10 4 . Trace element variations in the gel precursor to the jasper are thought to have been controlled by coprecipitation and/or adsorption by Fe oxyhydroxide particles that formed by the oxidation of hydrothermal Fe 2+ within the variably seawater-diluted hydrothermal plume(s). Thick jasper layers near the Høydal VMS orebody show distinct positive As/Fe and Sb/Fe anomalies that are attributed to near-vent rapid settling of Si-Fe particles derived from As- and Sb-rich hydrothermal fluids prior to extensive mixing with seawater in the buoyant plume. Particles that formed later in the highly diluted nonbuoyant plume formed relatively As and Sb poor distal jasper. The large particle sizes and accordingly high settling rates of the particles, together with mass-balance calculations based on modern vent field data, suggest that individual meter-thick jasper beds formed within a plume lifetime of 200 years or less. The lack of thick jasper beds near the Løkken VMS orebody, which is larger than the Høydal orebody by more than two orders of magnitude, probably reflects a shift to anoxic conditions during Løkken mineralization. This environment limited oxidation of iron in the hydrothermal plume and formation of the ferric oxyhydroxides necessary for the flocculation of silica and sea-floor deposition of the gel precursor of the jasper beds. Distal pyritic and iron-poor cherts are more common than jasper in ancient VMS-hosting sequences. The origin of these other types of siliceous exhalite is enigmatic but at least in some cases involved sulfidation, reduction to magnetite, or dissolution of the original ferric iron in precursor Si-rich gels, either by hydrothermal or diagenetic processes.

Economic Geology↗

Deformational and erosional history for the Abiquiu and contiguous area, north-central New Mexico: Implications for formation of the Abiquiu embayment and a discussion of new geochronological and geochemical analysis

Geologic mapping, age determinations, and geochemistry of rocks exposed in the Abiquiu area of the Abiquiu embayment of the Rio Grande rift, north-central New Mexico, provide data to determine fault-slip and incision rates. Vertical-slip rates for faults in the area range from 16 m/m.y. to 42 m/m.y., and generally appear to decrease from the eastern edge of the Colorado Plateau to the Abiquiu embayment. Incision rates calculated for the period ca. 10 to ca. 3 Ma indicate rapid incision with rates that range from 139 m/m.y. on the eastern edge of the Colorado Plateau to 41 m/m.y. on the western part of the Abiquiu embayment. The Abiquiu area is located along the margin of the Colorado Plateau–Rio Grande rift and lies within the Abiquiu embayment, a shallow, early extensional basin of the Rio Grande rift. Cenozoic rocks include the Eocene El Rito Formation, Oligocene Ritito Conglomerate, Oligocene–Miocene Abiquiu Formation, and Miocene Chama–El Rito and Ojo Caliente Sandstone Members of the Tesuque Formation (Santa Fe Group). Volcanic rocks include the Lobato Basalt (Miocene; ca. 15–8 Ma), El Alto Basalt (Pliocene; ca. 3 Ma), and dacite of the Tschicoma Formation (Pliocene; ca. 2 Ma). Quaternary deposits consist of inset axial and side-stream deposits of the ancestral Rio Chama (Pleistocene in age), landslide and pediment alluvium and colluvium, and Holocene main and side-stream channel and floodplain deposits of the modern Rio Chama. The predominant faults are Tertiary normal high-angle faults that displace rocks basinward. A low-angle fault, referred to as the Abiquiu fault, locally separates an upper plate composed of the transitional zone of the Ojo Caliente Sandstone and Chama–El Rito Members from a lower plate consisting of the Abiquiu Formation or the Ritito Conglomerate. The upper plate is distended into blocks that range from about 0.1 km to 3.5 km long that may represent a larger sheet that has been broken up and partly eroded. Geochronology ( 40 Ar/ 39 Ar) from fifteen volcanic and intrusive rocks resolves discrete volcanic episodes in the Abiquiu area: (1) emplacement of Early and Late Miocene basaltic dikes at 20 Ma and ca. 10 Ma; (2) extensive Late Miocene–age lava flows at 9.5 Ma, 7.9 Ma, and 5.6 Ma; and (3) extensive basaltic eruptions during the early Pliocene at 2.9 Ma and 2.4 Ma. Clasts of biotite- and hornblende-rich trachyandesites and trachydacites from the base of the Abiquiu Formation are dated at ca. 27 Ma, possibly derived from the Latir volcanic field. The most-mafic magmas are interpreted to be generated from a similar lithospheric mantle during rifting, but variations in composition are correlated with partial melting at different depths, which is correlated with thinning of the crust due to extensional processes.

GSA Special Papers↗

Preliminary assessment of recent deposition related to a crevasse splay on the Mississippi River delta: Implications for coastal restoration

Historically, the Mississippi River has replenished sediment across the lower deltaic plain, abating land loss. However, flood-control structures along the river now restrict this natural process and divert sediment from the modern delta offshore to the shelf break, thereby removing it from the coastal system. Localized crevasse splays, however, can deposit significant amounts of sediment in a short span of time. Satellite imagery and field investigations, including eight sediment vibracores, have identified a recent crevasse splay originating from Brant Bayou within the Delta National Wildlife Refuge on the lower Mississippi River delta. The splay deposits are estimated to be as much as 3 m thick and are located stratigraphically above shallow interdistributary-bay deposits. In addition, the deposits exhibit physical characteristics similar to those of large scale prograded deltas. The Bayou Brant crevasse splay began forming in 1978 and has built approximately 3.7 km 2 of land. Coastal planners hope to utilize on this natural process of sediment dispersion to create new land within the deltaic plain.

Mississippi River delta↗

Revision of Fontes & Garnier's model for the initial 14 C content of dissolved inorganic carbon used in groundwater dating

The widely applied model for groundwater dating using 14 C proposed by Fontes and Garnier (F&G) (Fontes and Garnier, 1979) estimates the initial 14 C content in waters from carbonate-rock aquifers affected by isotopic exchange. Usually, the model of F&G is applied in one of two ways: (1) using a single 13 C fractionation factor of gaseous CO 2 with respect to a solid carbonate mineral, εg/s, regardless of whether the carbon isotopic exchange is controlled by soil CO 2 in the unsaturated zone, or by solid carbonate mineral in the saturated zone; or (2) using different fractionation factors if the exchange process is dominated by soil CO 2 gas as opposed to solid carbonate mineral (typically calcite). An analysis of the F&G model shows an inadequate conceptualization, resulting in underestimation of the initial 14 C values ( 14 C 0 ) for groundwater systems that have undergone isotopic exchange. The degree to which the 14 C 0 is underestimated increases with the extent of isotopic exchange. Examples show that in extreme cases, the error in calculated adjusted initial 14 C values can be more than 20% modern carbon (pmc). A model is derived that revises the mass balance method of F&G by using a modified model conceptualization. The derivation yields a “global” model both for carbon isotopic exchange dominated by gaseous CO 2 in the unsaturated zone, and for carbon isotopic exchange dominated by solid carbonate mineral in the saturated zone. However, the revised model requires different parameters for exchange dominated by gaseous CO 2 as opposed to exchange dominated by solid carbonate minerals. The revised model for exchange dominated by gaseous CO 2 is shown to be identical to the model of Mook (Mook, 1976). For groundwater systems where exchange occurs both in the unsaturated zone and saturated zone, the revised model can still be used; however, 14 C 0 will be slightly underestimated. Finally, in carbonate systems undergoing complex geochemical reactions, such as oxidation of organic carbon, radiocarbon ages are best estimated by inverse geochemical modeling techniques.

Chemical Geology↗

Glaciotectonic origin of the Massachusetts coastal end moraines and a fluctuating late Wisconsinan ice margin

Late Wisconsinan end moraines on Cape Cod and islands south and west of Cape Cod are believed to be glaciotectonic features formed by advancing ice fronts. Evidence of a glaciotectonic origin includes the stratified drift composition of the moraines, dislocated preglacial and glaciolacustrine deposits, tilted preglacial and glacial beds, folding and thrust faulting, and morphologic similarity to ancient and modern glaciotectonic moraines. Evidence for major ice readvances during over-all general recession includes the moraines themselves, till atop stratified drift, and the numerous basal tills that are inferred to exist beneath Cape Cod Bay. The Thompson Glacier end moraine in the Canadian Arctic Archipelago is considered to be a modern example of how late Wisconsinan end moraines on Cape Cod and the islands were formed. The Thompson Glacier is overriding its outwash plain, displacing outwash deposits forward and upward beyond the ice front. New sheets are added to the base of the moraine, and till is deposited atop the moraine as the ice overrides it. Evidence from Cape Cod and the nearby islands indicates that over-all recession of late Wisconsinan ice was characterized by alternating episodes of ice-front retreat, during which the outwash plains were formed, and of ice-front advance, during which the moraines were built. Retreat of the ice from Cape Cod and the islands may have been similar to the retreat of the Lake Michigan lobe, deposits of which contain evidence of at least 12 moraine-building episodes caused by readvancing ice during the over-all retreat of the late Wisconsinan ice sheet.

Geological Society of America Bulletin↗

Status and understanding of groundwater quality in the North San Francisco Bay Shallow Aquifer study unit, 2012; California GAMA Priority Basin Project (ver. 1.1, February 2018)

Groundwater quality in the North San Francisco Bay Shallow Aquifer study unit (NSF-SA) was investigated as part of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in Marin, Mendocino, Napa, Solano, and Sonoma Counties and included two physiographic study areas: the Valleys and Plains area and the surrounding Highlands area. The NSF-SA focused on groundwater resources used for domestic drinking water supply, which generally correspond to shallower parts of aquifer systems than that of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included three components: (1) a status assessment , which characterized the status of the quality of the groundwater resources used for domestic supply for 2012; (2) an understanding assessment , which evaluated the natural and human factors potentially affecting water quality in those resources; and (3) a comparison between the groundwater resources used for domestic supply and those used for public supply. The status assessment was based on data collected from 71 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2012. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that has concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. In the NSF-SA study unit as a whole, inorganic constituents with human-health benchmarks were detected at high relative concentrations (RCs) in 27 percent of the shallow aquifer system, and inorganic constituents with secondary maximum contaminant levels (SMCL) were detected at high RCs in 24 percent of the system. The inorganic constituents detected at high RCs were arsenic, boron, fluoride, manganese, nitrate, iron, sulfate, and total dissolved solids (TDS). Organic constituents with human-health benchmarks were detected at high RCs in 1 percent of the shallow aquifer system. Of the 148 organic constituents analyzed, 30 constituents were detected, although only 1, chloroform, had a detection frequency greater than 10 percent. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors. Groundwater age class (modern, mixed, or pre-modern), redox class (oxic or anoxic), aquifer lithology class (metamorphic, sedimentary, or volcanic), and dissolved oxygen concentrations were the explanatory factors that explained distribution patterns of most of the inorganic constituents best. Groundwater classified primarily as pre-modern or mixed in age was associated with higher concentrations of arsenic and fluoride than waters classified as modern. Anoxic or mixed redox conditions were associated with higher concentrations of boron, fluoride, and manganese. Similar patterns of association with explanatory variables were seen for inorganic constituents with aesthetic-based benchmarks detected at high concentrations. Nitrate and perchlorate had higher concentrations in oxic than in the anoxic redox class and were positively correlated with urban land use. The NSF-SA water-quality results were compared to those of the GAMA North San Francisco Bay Public-Supply Aquifer study unit (NSF-PA). The NSF-PA was sampled in 2004 and covers much of the same area as the NSF-SA, but focused on the deeper public-supply aquifer system. The comparison of the NSF-PA to the NSF-SA showed that there were more differences between the Valleys and Plains study areas of the two study units than between the Highlands study areas of the two study units. As expected from the shallower depth of wells, the NSF-SA Valleys and Plains study area had a lesser proportion of pre-modern age groundwater and greater proportion of modern age groundwater than the NSF-PA Valleys and Plains study area. In contrast, well depths and groundwater ages were not significantly different between the two Highlands study areas. Arsenic, manganese, and nitrate were present at high RCs, and perchlorate was detected in greater proportions of the NSF-SA Valleys and Plains study area than the NSF-PA Valleys and Plains study area.

California↗

Progress report on sediment analyses at selected faunal monitoring sites in north-central and northeastern Florida Bay

Florida Bay is a shallow, subtropical lagoon at the southern tip of the Florida peninsula. The 2200 square kilometer, triangular-shaped area is the site of modern carbonate sediment formation and deposition. The intricate ecosystem of the bay has undergone significant changes as the result of natural influences and human intervention. The purpose of this study is to investigate carbonate sediment characteristics and distribution in conjunction with faunal and floral to determine the substrate preferences of associated fauna and flora. The modern data provide the proxy data for down-core analyses of sediments, fauna and flora in order to document ecosystem changes in the bay. Selected sediment samples collected during 1996 from 18 sites in the northeastern and central bay were analyzed for insoluble residues, organic content, total carbonate, and percent of silt and clay sized particles. Insoluble residues range from 0.8% of the sediment in a shell lag to 11.5% with an average of 5.1%. Organic content ranged from a minimum of 1.43% of the sediment to 18.05% with an average of 7.6%. The total carbonate content ranged from 72.56% to 97.81%, averaging 87.98%. The percent silt and clay sized particles ranged from 13.75% to 63.62% for the samples analyzed. The insoluble residue content shows a general trend of decreasing insoluble residues from the northeastern bay toward the southwest. Organic content is variable throughout the bay and does not show a regional trend. Several sites show a trend of higher organic content in the samples collected in February as compared to those collected in July. Lithologic examination indicated that, in addition to the carbonate mud (less than 63mm), sample components included whole and fragmented mollusks, foraminifers, bryozoans, ostracods, and organic matter. The insoluble residues consisted of quartz sand and silt, clays and siliceous fossils. A component of the insoluble residues may be dust derived from Africa and transported to southern Florida by the prevailing winds. This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards or with the North American Stratigraphic Code. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Open-File Report↗

Hydrothermal, biogenic, and seawater components in metalliferous black shales of the Brooks Range, Alaska: Synsedimentary metal enrichment in a carbonate ramp setting

Trace element and Os isotope data for Lisburne Group metalliferous black shales of Middle Mississippian (early Chesterian) age in the Brooks Range of northern Alaska suggest that metals were sourced chiefly from local seawater (including biogenic detritus) but also from externally derived hydrothermal fluids. These black shales are interbedded with phosphorites and limestones in sequences 3 to 35 m thick; deposition occurred mainly on a carbonate ramp during intermittent upwelling under varying redox conditions, from suboxic to anoxic to sulfidic. Deposition of the black shales at ~335 Ma was broadly contemporaneous with sulfide mineralization in the Red Dog and Drenchwater Zn-Pb-Ag deposits, which formed in a distal marginal basin. Relative to the composition of average black shale, the metalliferous black shales ( n = 29) display large average enrichment factors (>10) for Zn (10.1), Cd (11.0), and Ag (20.1). Small enrichments (>2–<10) are shown by V, Cr, Ni, Cu, Mo, Pd, Pt, U, Se, Y, and all rare earth elements except Ce, Nd, and Sm. A detailed stratigraphic profile over 23 m in the Skimo Creek area (central Brooks Range) indicates that samples from at and near the top of the section, which accumulated during a period of major upwelling and is broadly correlative with the stratigraphic levels of the Red Dog and Drenchwater Zn-Pb-Ag deposits, have the highest Zn/TOC (total organic carbon), Cu/TOC, and Tl/TOC ratios for calculated marine fractions (no detrital component) of these three metals. Average authigenic (detrital-free) contents of Mo, V, U, Ni, Cu, Cd, Pb, Ge, Re, Se, As, Sb, Tl, Pd, and Au show enrichment factors of 4.3 × 10 3 to 1.2 × 10 6 relative to modern seawater. Such moderate enrichments, which are common in other metalliferous black shales, suggest wholly marine sources (seawater and biogenic material) for these metals, given similar trends for enrichment factors in organic-rich sediments of modern upwelling zones on the Namibian, Peruvian, and Chilean shelves. The largest enrichment factors for Zn and Ag are much higher (1.4 × 10 7 and 2.9 × 10 7 , respectively), consistent with an appreciable hydrothermal component. Other metals such as Cu, Pb, and Tl that are concentrated in several black shale samples, and are locally abundant in the Red Dog and Drenchwater Zn-Pb-Ag deposits, may have a partly hydrothermal origin but this cannot be fully established with the available data. Enrichments in Cr (up to 7.8 × 10 6 ) are attributed to marine and not hydrothermal processes. The presence in some samples of large enrichments in Eu (up to 6.1 × 10 7 ) relative to modern seawater and of small positive Eu anomalies (Eu/Eu* up to 1.12) are considered unrelated to hydrothermal activity, instead being linked to early diagenetic processes within sulfidic pore fluids. Initial Os isotope ratios ( 187 Os/ 188 Os) calculated for a paleontologically based depositional age of 335 Ma reveal moderately unradiogenic values of 0.24 to 0.88 for four samples of metalliferous black shale. A proxy for the ratio of coeval early Chesterian seawater is provided by initial ( 187 Os/ 188 Os) 335 Ma ratios of four unaltered black shales of the coeval Kuna Formation that average 1.08, nearly identical to the initial ratio of 1.06 for modern seawater. Evaluation of possible sources of unradiogenic Os in the metalliferous black shales suggests that the most likely source was mafic igneous rocks that were leached by externally derived hydrothermal fluids. This unradiogenic Os is interpreted to have been leached by deeply circulating hydrothermal fluids in the Kuna basin, followed by venting of the fluids into overlying seawater. We propose that metal-bearing hydrothermal fluids that formed Zn-Pb-Ag deposits such as Red Dog or Drenchwater vented into seawater in a marginal basin, were carried by upwelling currents onto the margins of a shallow-water carbonate platform, and were then deposited in organic-rich muds, together with seawater- and biogenically derived components, by syngenetic sedimentary processes. Metal concentration in the black shales was promoted by high biologic productivity, sorption onto organic matter, diffusion across redox boundaries, a low sedimentation rate, and availability of H 2 S in bottom waters and pore fluids.

Alaska↗

Timescales of water-quality change in a karst aquifer, south-central Texas

Understanding the drivers and timescales over which groundwater quality changes informs groundwater management, use, and protection. To better understand timescales of water-quality change over short (daily to monthly) and long (seasonal to decadal) timescales, the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Enhanced Trends Network (ETN) program instrumented and sampled three wells in the Edwards aquifer in south-central Texas. The wells were instrumented to provide high-frequency continuous (subhourly) water-quality data (temperature, pH, specific conductance, and dissolved oxygen), which were augmented by the collection of discrete samples (about 6 per year) for a range of geochemical constituents (including selected isotopes and age tracers). ETN data (2013–2017) are considered with data from additional sites for the same time period, and also historical records (over more than 80 years) of climatic and hydrologic conditions. During the four-year study, hydrologic conditions transitioned from very dry to very wet. Sites in the updip/unconfined part of the aquifer showed notable changes in water level and geochemistry (1) in response to rainfall/recharge events, and (2) over the multiyear dry/wet cycle. Sites in the downdip/confined part of the aquifer showed changes in water level/spring discharge over similar timescales, although the response is more muted. Geochemistry at the downdip/confined sites, however, varied slowly and minimally, indicating that the geochemical response of the deeper aquifer is decoupled from recent hydrologic responses. Changes at the updip/unconfined sites reflect mixing with recent recharge, whereas the downdip/confined sites were dominated by mineral-solution reactions resulting from longer (decadal) residence times. Mean groundwater ages interpreted from measured age tracers and lumped parameter models range from 7 to >700 years (where mixed with premodern downdip water) but were mostly modern. The aquifer is characterized by updip-to-downdip trends in geochemistry with respect to water-rock interaction and groundwater age. Fourier spectral analysis of historical records indicate hydrologic variability has occurred at dominant periods of 30 and 15 years; in conjunction with age tracers, these results provide insight into timescales at which the aquifer’s public supply is vulnerable to changes in the water quality of recharge.

Texas↗