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Assessment of bridge scour countermeasures at selected bridges in the United States, 2014–18

Erosion of the streambed, known also as scour, around pier 3 of the New York State Thruway bridge over Schoharie Creek caused the pier to fail, which ultimately resulted in bridge failure during the flooding event of April 5, 1987. The Federal Highway Administration (FHWA) responded to the need for better guidance on the evaluation of bridge scour and the selection and installation of scour countermeasures with the release of several Hydraulic Engineering Circulars. Although this information has been available, used, and updated over the years, an evaluation of the current conditions of scour countermeasures has not been performed. Therefore, the U.S. Geological Survey, in cooperation with the FHWA, began a study in 2013 to assess the current conditions of bridge scour countermeasures at selected sites around the country. The bridge scour countermeasure site assessments included reviewing countermeasure design plans, field inspections, traditional surveys, motion-compensated terrestrial light detection and ranging technology (lidar), high-resolution multi-beam bathymetry scanning, underwater video imaging, and a review of the peak and daily streamflow history for the associated river or stream. A total of 34 bridge scour countermeasure sites were selected in 11 states for this study. The types of countermeasures installed at the bridge scour study sites ranged from riprap, the most common countermeasure in the study, to A-Jacks and cabled-concrete mattresses. The installed countermeasures were generally exposed to hydraulic forces from floods that equaled or exceeded the 1-percent, and even the 0.2-percent, annual exceedance probability at some of the study sites, but not all. The field inspections and countermeasure evaluations identified areas of shifting, slumping, and some scour holes and damage or washouts to the countermeasures, but generally most remained in place. The high-resolution laser scanner data, photo imaging and traditional survey data, and field notes were provided to the FHWA for expert evaluation of the bridge scour countermeasure performance.

Alabama, Florida, Idaho, Illinois, Indiana, Iowa, ↗

Statewide assessment of karst aquifers in New York with an inventory of closed-depression and focused-recharge features

Karst is a landscape formed from the dissolution of soluble rock or rock containing minerals that are easily dissolved from within the rock. The landscape is characterized by sinkholes, caves, losing streams, springs, and underground drainage systems, which rapidly move water through the karst. The two forms of karst in New York State include carbonate karst, which forms in carbonate rock (limestone, marble, and dolostone), and evaporite karst, which forms in rock that contains the evaporite minerals gypsum and halite. Past and recent studies of karst across the State have shown that areas of focused recharge in karstic carbonate rock allow contaminants to enter aquifer systems with little attenuation. Focused areas of recharge need to be identified to help prevent such contamination from sources on or adjacent to the karst. The New York State Departments of Environmental Conservation and Health are collaborating with the agricultural community to make farmers and farm-planning advisors more aware of karst and how to manage daily farming activities to reduce their impact on surface water and groundwater resources, especially in karst areas. There is also a need to make regulators, planners, and the general public aware of New York’s karst resources and to properly protect and manage these resources to protect the quality of groundwater and surface water that can flow into, through, and from karst bedrock. Using publicly available geospatial data, karst bedrock and closed depressions over or near karst rock were identified across New York. Carbonate, evaporite, and marble geologic units were selected from a statewide 1:250,000-scale bedrock geology dataset. The selected geologic units were intersected with 7.5-minute quadrangle maps to define the study area. The U.S. Geological Survey has compiled an inventory of closed depressions from statewide digital contour data, scanned 7.5-minute topographic maps known as a digital raster graphics, and light detection and ranging (lidar) digital elevation models. Analysis of the data resulted in the identification of 5,023 closed depressions statewide. The inventory was conducted to eliminate duplication of results from analysis of the three data sources. A series of overlay analyses was conducted using the closed depressions and thematic data known to be key factors in determining the probability of a closed depression contributing to focused groundwater recharge; the thematic data include bedrock geology, soil type, soil infiltration rate, and land cover. Though the extent of karst development is important in understanding the interaction between surface water and groundwater in karst terrains, some of the worst cases of groundwater contamination in karst can occur where only minor karst features might be present. The presence of karst—be it a short section of a solutioned fracture or an extensive cave system—requires careful consideration, forward-looking environmental planning, and consistent water-quality protection to preserve New York State’s water resources.

New York↗

Storage capacity and sedimentation characteristics of Loch Lomond Reservoir, California, 2019

In May of 2019, Loch Lomond Reservoir was surveyed by the U.S. Geological Survey (USGS) in cooperation with the city of Santa Cruz to assess the current storage capacity and sedimentation rates in the reservoir. Survey methods combined sonar soundings to measure bathymetry and lidar scans with GPS data to measure near-shore topography and sediment bed samples to understand reservoir bed-material size. The survey data produced a bare-earth digital elevation model (DEM) of the reservoir at a resolution of 1 square meter or better to elevations at or above the reservoir spillway elevation, providing the coverage needed to estimate storage capacity. Additionally, the USGS compared the current survey to storage estimates from historical surveys—particularly the most recent survey in 2009—to evaluate storage capacity trends. Lastly, a hindcast estimate of scaled sediment yield using sediment yields from the San Lorenzo River (USGS station 11160500)—where the San Lorenzo River watershed encompasses the Loch Lomond Reservoir watershed—were used to compare indirect estimates of storage loss to direct storage loss. The 2019 survey resulted in a measured storage capacity of 8,770±50 acre-feet. The differences in storage between 2009 and 2019 varied substantially by depth. In shallow areas with depths less than 30 ft (at full reservoir), such as the very upstream end of the reservoir, storage loss (sediment deposition) dominated with a loss of about 68 acre-feet from 2009 to 2019. In areas deeper than 30 ft, persistent small storage gains over a wide range of depths totaled 82 acre-feet from 2009 to 2019. Storage loss estimates derived from estimated watershed sediment yields and reservoir characteristics were similar to storage losses computed from past surveys. This hindcasting produced an estimate of about 500 acre-feet of total storage loss for the history of the reservoir, or an average of about 8–9 acre-feet/year during the 60-year period. For the period 2009–2019, the hindcast produced an estimated total storage loss of 42 acre-feet, which is broadly consistent with the 68 acre-feet of storage loss computed for shallow areas based on the repeat surveys.

California↗

Analysis of high-resolution single channel seismic data for use in sediment resource evaluation, eastern Texas and western Louisiana Continental Shelf, Gulf of Mexico

Shallow subsurface geologic data recorded as high-resolution seismic profiles are used to interpret the geology of coastal and marine systems. These data were originally recorded on paper rolls that are stored in geophysical archives. Data collection has since converted to entirely digital formats, yet the analog data are still useful for geologic interpretation. This report describes the process of recovering analog copies of seismic profiles from physical archives, electronically scanning, and converting them to industry-standard digital format. The recovered data are also reviewed and assessed for potential sediment resources. The data recovered in this study were collected from the Gulf of Mexico continental shelf offshore of East Texas and West Louisiana. The project is a collaborative study between the U.S. Geological Survey and the Bureau of Ocean Energy Management.

Louisiana, Texas↗

Streamflow characterization and effects of Interstate 26 highway construction on water-quality and channel morphology conditions of the French Broad River in Buncombe and Henderson Counties, North Carolina, 2019–22

The North Carolina Department of Transportation began a series of highway construction projects to upgrade Interstate 26 (I–26) in Buncombe and Henderson Counties, North Carolina, starting in early 2020. The North Carolina Department of Transportation and the U.S. Geological Survey partnered in 2019 to monitor and assess water-quality and geomorphic conditions throughout the French Broad River corridor in areas near Interstate 26 highway construction activities. This report summarizes findings from multi-year water-quality and channel morphology monitoring from 2019 through 2022 in the French Broad River corridor near ongoing highway construction activities. Dissolved oxygen, pH, specific conductance, turbidity, and water temperature were monitored at six gaging locations, three of which were near highway sections undergoing construction during the study period from June 1, 2019, through December 31, 2022. Water quality was compared across three monitoring locations before and during construction using Brunner-Dette-Munk statistical tests, a nonparametric form of analysis of variance used for unbalanced datasets. Most Brunner-Dette-Munk test results detected insignificant effects of highway construction on water-quality conditions when controlling for monitoring location, except for the test of daily maximum specific conductance values. However, the effects of highway construction could not be isolated from other external factors that may have affected specific conductance, including an extended period of low streamflow and possible road salt application after winter storms. Additional Brunner-Dette-Munk tests, controlling for flow magnitude (streamflow quantiles) or hydrograph position (“rising limb,” “falling limb,” or “base flow”), did not suggest that highway construction affected water-quality conditions in the study area. Geomorphic surveys of the streambed and streambanks were performed in a 1-kilometer reach from 2019 through 2022 to assess geomorphic changes during the reconstruction of a bridge spanning the French Broad River. Bathymetric surveys of the streambed and light detection and ranging (lidar) scans of the streambanks were collected from a canoe using motion-compensated, real-time positioning solutions. Initial geomorphic surveys were used as a baseline to which subsequent repeat surveys were compared using geomorphic change detection analysis. Detectable elevation changes were determined using statistically robust thresholds, ensuring only changes exceeding measurement uncertainty were considered for interpretive analyses. Change detection results identified that 16.4 percent of the reach experienced detectable geomorphic change during the study period, with inter-survey changes ranging from 3.5 to 12.4 percent of the total reach. Most detectable change is attributed to the installation and reconfiguration of temporary construction pads; other changes are attributed to enlargement of a scour hole and upstream deposition near the bridge. Although anthropogenic activities and changes in streamflow regime contributed to these observations, the approach used in this study provides confidence that reported values reflect real geomorphic changes and not noise.

North Carolina↗

Radioactive source materials in Los Estados Unidos de Venezuela

This report summarizes the data available on radioactive source materials in Los Estados Unidos de Venezuela accumulated by geologists of the Direccions Tecnica de Geolgia and antecedent agencies prior to June 1951, and the writers from June to November 1951. The investigation comprised preliminary study, field examination, office studies, and the preparation of this report, in which the areas and localities examined are described in detail, the uranium potentialities of Venezuela are summarized, and recommendations are made. Preliminary study was made to select areas and rock types that were known or reported to be radioactive or that geologic experience suggests would be favorable host for uranium deposits, In the office, a study of gamma-ray well logs was started as one means of amassing general radiometric data and of rapidly scanning many of ye rocks in northern Venezuela; gamma-ray logs from about 140 representative wells were examined and their peaks of gamma intensity evaluated; in addition samples were analyzed radiometrically, and petrographically. Radiometic reconnaissance was made in the field during about 3 months of 1951, or about 12 areas, including over 100 localities in the State of Miranda, Carabobo, Yaracuy, Falcon, Lara, Trujillo, Zulia, Merida, Tachira, Bolivar, and Territory Delta Amacuro. During the course of the investigation, both in the filed and office, information was given about geology of uranium deposits, and in techniques used in prospecting and analysis. All studies and this report are designed to supplement and to strengthen the Direccion Tecnica de Geologias's program of investigation of radioactive source in Venezuela now in progress. The uranium potentialities of Los Estados de Venezuela are excellent for large, low-grade deposits of uraniferous phospahtic shales containing from 0.002 to 0.027 percent uranium; fair, for small or moderate-sized, low-grade placer deposits of thorium, rare-earth, and uranium minerals; poor, for high-grade hydrothermal pitchblende deposits; and highly possible for small, medium- to high-grade despots of carnotite-or copper-uranium bearing sandstone. Recommendations for the Venezuelan uranium program include 1) the systematic collection of a mass general radiometric data by examining sample collections, expanding the gamma-ray program, encouraging the use of Geiger counter by field geologists, and by enlisting the aid of the general public; 2) , the examination of specific areas or localities, chosen on the basis of geologic favorability from the results of the amassing of data, or obtained by hints and rumors; 3), the organization of a unit within the Direccion Tecnica de Geologica to direct, collection, and collate metric data. It is emphasized that to be most fruitful the program requires the application of sounds and imaginative geologic theory.

Trace Elements Investigations↗

Compilation of data on the uranium and equivalent uranium content of samples analyzed by U.S. Geological Survey during a program of sampling mine, mill, and smelter products

In 1942 the Geological Survey began to collect, in response to a request made by the War Production Board, samples of mine, mill, and smelter products. About 1,400 such samples were collected and analyzed spectrographically for about 20 elements that were of strategic importance, in order to determine whether any of the products analyzed might be possible sources of some of the needed elements. When attention was directed to radioactive elements in 1943, most of the samples were scanned for radioactivity. Part of the work was done on behalf of the Division of Raw Materials of the Atomic Energy Commission. The sources, mine mill, smelter, or prospect, from which these samples were collected, the kind of material sampled, i.e. ores, concentrates, middlings, tailings, flue dusts, and so forth, and the radioactivity of the samples are listed in this report. Samples of the materials collected in the course of the Geological Survey’s investigations for uranium are excluded, but about 500 such samples were analyzed spectrographically for some or all of the same 20 elements sought in the samples that are the subject of this report. Most of the samples were tested only for their radioactivity, but a few were analyzed chemically for uranium. The radioactivity of many of the samples tested in the early screening was determined only qualitatively. Several samples were tested at one time, and if the count obtained did not exceed a predetermined minimum above background, the samples were not tested individually. If the count was more than this minimum, the samples were tested individually to identify the radioactive sample or samples and to obtain a quantitative value for the radioactivity. In general, the rough screening served as a basis for separating samples in which the radioactivity amount to less than 0.003 percent equivalent uranium from those in which it exceeded that amount. Some aspects of various phases of the investigation of radioactivity in these samples have been reported in various other reports, as follows.

Trace Elements Investigations↗

Trace elements investigations in the Sweepstakes Creek area, Koyuk district, Seward Peninsula, Alaska

A significant content of radioactive material was recognized in a few placer concentrates from Sweepstakes and Rube Creeks in the Koyuk district of eastern Seward Peninsula, Alaska, when old collections were scanned for radioactivity in the spring of 1945. Subsequent field investigations with a Geiger-Mueller counter were made of the creek gravels and the placer-gold paystreak on the bench ground of Sweepstakes Creek and its tributaries, the syenite stock of Granite Mountain to the north, of Sweepstakes Creek, and the creek gravels of Rube and Anzac Creeks which are tributaries of the Peace River east of the syenite stock. The content of radioactive minerals in the gravels and in the placer-gold paystreak was found to be disappointingly low. There concentration ratios were between 45 and 169 to 1, the content of concentrates from the creek gravels is only .001 to .016 percent equivalent uranium the average content of the creek gravels in place is computed as .0001 percent equivalent uranium. The placer-gold paystreak was not accessible in place, but the content was computed as .0003 percent equivalent uranium from the sluice-box concentrates and tailings at Winder's open-cut,the only active placer mine in the area in 1945. The radioactive minerals are relatively abundant in such gravity concentrates as the sluice-box concentrates, and are particularly abundant in certain size fractions of these sluice concentrates Thus the concentrates from the aluiee-fcex, after screening through 20-mesh, showed 0.04 percent equivalent uranium. An even greater concentration of radioactive minerals is obtained in the "blowings," which represent a further cleaning of the sluice-box concontrates, one saample showing 14.20 percent equivalent uranium.

Alaska↗

Comparison of thickness, grade, and depth of radioactive layers as determined by gamma-ray logging and by core sampling

Thickness, grade, and depth data were obtained by analyzing gamma-ray logs and core samples from 56 diamond drill holes penetrating uranium deposits in the Colorado Plateau. The data from the two methods were compared to determine variations found in gamma-ray log interpretation and chemical and radiometric analyses of the drill core. Correlations within each parameter varied among the drilling areas analyzed. Gamma-ray interpretations of grade compared to chemical analyses were within the range of -10 to +25 percent. Most depth measurements determined by gamma-ray log interpretation compared to drill core measurement were within 0.5 percent. Results of the study indicate a need for better thickness definition in both gamma-ray logging and core scanning equipment.

Trace Elements Investigations↗

Standard for the U.S. Geological Survey Historical Topographic Map Collection

This document defines the digital map product of the U.S. Geological Survey (USGS) Historical Topographic Map Collection (HTMC). The HTMC is a digital archive of about 190,000 printed topographic quadrangle maps published by the USGS from the inception of the topographic mapping program in 1884 until the last paper topographic map using lithographic printing technology was published in 2006. The HTMC provides a comprehensive digital repository of all scales and all editions of USGS printed topographic maps that is easily discovered, browsed, and downloaded by the public at no cost. Each printed topographic map is scanned “as is” and captures the content and condition of each map. The HTMC provides ready access to maps that are no longer available for distribution in print. A new generation of topographic maps called “US Topo” was defined in 2009. US Topo maps, though modeled on the legacy 7.5-minute topographic maps, conform to different standards. For more information on the HTMC, see the project Web site at: http://nationalmap.gov/historical/ .

Techniques and Methods↗

Creating 3D point clouds, digital elevation models, and orthomosaics from historical aerial imagery through structure from motion aided photogrammetry

Detailed and accurate historical data are crucial to characterizing landscape change, whether it is caused by natural phenomena or of anthropogenic origin. Aerial imagery has been periodically collected by government and nongovernment agencies, for a broad range of purposes, since the early 20th century. The acquisition of aerial images involves using standardized equipment with large-format, carefully calibrated cameras and lens assemblies. Historical archives of aerial images preserve a record of the landscape and are invaluable sources of information that predate satellite and lidar. Structure from motion (SfM) aided photogrammetry provides an efficient means for creating digital three-dimensional data from the vast archives of historical aerial imagery. This report presents techniques, methods, best practices, and a standard workflow for creating point clouds, digital elevation models, and orthomosaic digital scans of overlapping (stereographic) vertical aerial photographs using photogrammetry software. A list of critical issues relevant to SfM-aided photogrammetry of historical aerial imagery is provided, along with potential contingencies and solutions. The workflow was tested in many geographic study areas and with historical imagery datasets of different scales and sources. Three case studies are included. By integrating known SfM methods, these procedures enable the consistent and optimal extraction of historical quantitative data from archives like the U.S. Geological Survey (USGS) Aerial Photo Single Frame archive in the USGS EarthExplorer data portal.

Techniques and Methods↗

Determination of heat purgeable and ambient purgeable volatile organic compounds in water by gas chromatography/mass spectrometry

Two new analytical methods have been developed by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) that allow the determination of 37 heat purgeable volatile organic compounds (VOCs) (USGS Method O-4437-16 [NWQL Laboratory Schedule (LS) 4437]) and 49 ambient purgeable VOCs (USGS Method O-4436-16 [NWQL LS 4436]) in unfiltered water. This report documents the procedures and initial performance of both methods. The compounds chosen for inclusion in the methods were determined as having high priority by the USGS National Water-Quality Assessment (NAWQA) Program. Both methods use a purge-and-trap technique with gas chromatography/mass spectrometry. The compounds are extracted from the sample by bubbling helium through a 25-milliliter sample. For the polar and less volatile compounds, the sample is heated at 60 degrees Celsius, whereas the less polar and more volatile compounds are purged using a separate analytical procedure at ambient temperature. The compounds are trapped on a sorbent trap, desorbed into a gas chromatograph/mass spectrometer for separation, and then identified and quantified. Sample preservation is recommended for both methods by adding a 1:1 solution of hydrochloric acid (HCl [1:1]) to water samples to adjust the pH to 2. Analysis within 14 days from sampling is recommended. The heat purgeable method (USGS Method O-4437-16) operates with the mass spectrometer in the simultaneous full scan/selected ion monitoring mode. This method supersedes USGS Method O-4024-03 (NWQL LS 4024). Method detection limits (MDLs) for fumigant compounds 1,2-dibromoethane, 1,2-dichloropropane, 1,2,3-trichloropropane, chloropicrin, and 1,2-dibromo-3-chloropropane range from 0.002 to 0.010 microgram per liter (µg/L). The MDLs for all remaining heat purgeable VOCs range from 0.006 µg/L for tert -butyl methyl ether to 3 µg/L for alpha -terpineol. Calculated holding times indicate that 36 of the 37 heat purgeable VOCs are stable for a minimum of 14 days preserved with HCl (1:1) to pH 2, and many are stable longer. Acrolein was retained in the method validation and initial method implementation and subsequently deleted because of instability and inconsistent performance. 2-Chloromethyl oxirane, methyl oxirane, and oxirane were tested using this method, but the compounds degraded quickly with the HCl (1:1) used for microbial preservation. The ambient purgeable method, USGS Method O-4436-16, operates with the mass spectrometer in the full scan mode. This method is a modification of USGS Method O-4127-96 (NWQL LS 2020). Several compounds were retained from Method O-4127-96 and will continue to be determined in Method O-4436-16. Eleven high priority compounds were added. MDLs for the high priority compounds range from 0.007 µg/L for 2,2-dichloro-1,1,1-trifluoroethane to 0.04 µg/L for 1,2,3,4-tetrahydronaphthalene and 1,3-butadiene. Historical MDLs for the compounds retained from Method O-4127-96 range from 0.009 µg/L for trans -1,2-dichloroethene to 0.1 µg/L for bromomethane. The calculated holding times for the compounds indicate the majority of the compounds are stable for a minimum of 14 days, or longer, at pH 2 with HCl (1:1) preservation. Four semivolatile compounds, 1,2-dimethylnaphthalene, 1,6-dimethylnaphthalene, 2,6-di- tert -butyl phenol, and 2-chloronapthalene, were tested and deleted from the method due to poor performance. Benzyl chloride was tested and deleted due to instability.

Techniques and Methods↗

Creating oriented and precisely sectioned mineral mounts for in situ chemical analyses—An example using olivine for diffusion chronometry studies

Diffusion chronometry is now a widely applied methodology for determining the rates and timescales of geologic processes from the chemical zoning observed in minerals. Despite the popularity of the method, several challenges still remain during its application, including: (1) the random sectioning of minerals either in thin sections or grain mounts in which both off-center and oblique sections contribute substantial uncertainty to modeled timescales and (2) diffusion anisotropy needs to be accounted for in models, which generally requires determining the principal crystallographic axes of the mineral using electron backscatter diffraction, a technique that is both challenging and limiting because few scanning electron microscopes have an electron backscatter detector. This guide developed by the U.S. Geological Survey focuses on a step-by-step methodology for mounting individually oriented minerals that are sectioned through their cores prior to polishing for analytical work. Using this technique, one can significantly reduce the uncertainties associated with off-center sections and minimize or completely remove the need for determining crystallographic orientation via electron backscatter diffraction analyses. This report is presented as a guide for using the technique on olivine crystals but can be applied to any minerals that can be extracted for analysis. Two variations of the methodology are included here: (1) The individual crystal method that entails mounting individually sectioned single crystals and crystal groups and (2) the whole mount method in which multiple single crystals or crystal clusters are mounted and sectioned at the same time.

Techniques and Methods↗

Quality of water and bed material in streams of Logan Township, Gloucester County, New Jersey, 1984

The surface water and surficial-bed material at seven stations on three streams in Logan Township, Gloucester County, New Jersey, were sampled in the fall of 1984. Samples of water were analyzed for volatile organic compounds, trace metals, and organochlorine and organophosphorous compounds. Surficial-bed material was analyzed for extractable trace metals and organochlorine compounds. Water samples from two closely spaced sampling locations along Raccoon Creek contained elevated concentrations of methylene chloride (455 and 1800 micrograms/L, respectively), a volatile organic solvent. Bed-material samples taken from Little Timber and Birch Creeks contained elevated levels of trace metals and organochlorine compounds, including polychlorinated biphenyls (PCB's). Contaminant concentrations in bed-material samples taken from Raccoon Creek were much lower than those found previously by the U.S. Geological Survey in 1980. Only a trace of PCB 's was detected in any bed material sample taken from Racoon Creek. Gas chromatographic flame-ionization detector scans, performed on solvent extracts of all water and sediment samples, were useful in characterizing the presence or absence of organic contaminants in those samples. Changes in the character of organic contamination along the reaches of two streams were apparent when the fingerprints of chromatograms representing upstream sites were compared to those representing downstream sites. (Author 's abstract)

Water-Resources Investigations Report↗

Geohydrology and ground-water quality at selected sites in Meade County, Kentucky, 1987-88

Meade County in north-central Kentucky is about 305 sq mi in size, and is underlain by thick beds of limestone and dolomite which are the principal sources of drinking water for about 8 ,500 residents. About half the area contains mature, karst terrain with abundant sinkholes, springs, and caves. Because of this karst terrain, groundwater is susceptible to rapid changes in water quality and contamination from human sources. Thirty-seven wells and 12 springs were selected as sampling points to characterize groundwater quality in the area. Water was analyzed for major anions and cations, nitrates, trace elements, and organic compounds. Water from selected sites was also analyzed for fecal species of coliform streptococci bacteria and total coliform content. Except for fluoride and lead, the water quality was within the range expected for carbonate aquifers.The fluoride content was significantly higher in water from wells than in water from springs. Concentrations of detectable lead ranged from 10 to 50 micrograms/L and had a median value of 7.5 microg/L. Dissolved solids ranged from 100 to 2,200 mg/L and the median value was 512 mg/L. Hardness ranged from 20 to 1,100 mg/L and the median value was 290 mg/L. Organic compounds detected by the gas chromatographic/flame ionization detection scans, did not indicate evidence of concentrations in excess of the current Federal drinking water standards. Analysis for specific organic compounds indicated that the presence of these compounds was associated with agricultural chemicals, usually pesticides. Total coliform content exceeded drinking water standards in water from all 12 springs and in 18 wells. Statistical analysis of the groundwater quality data indicates that the variance of the concentrations of fluoride and chloride may be attributed to the site type. There was strong correlation between hardness and dissolved solids, hardness and sulfate, and sulfate and dissolved solids. No apparent relations were detected between water quality and the geographic location of sampling sites. However, seasonal variations were detected in the concentrations of dissolved solids, hardness, and iron. (Lantz-PTT)

Water-Resources Investigations Report↗

Pesticides in soils and ground water in selected irrigated agricultural areas near Havre, Ronan, and Huntley, Montana

Three areas in Montana representing a range of agricultural practices and applied pesticides, were studied to document whether agricultural pesticides are being transported into the soil and shallow groundwater in irrigated areas. Analytical scans for triazine herbicides, organic-acid herbicides, and carbamate insecticides were performed on soil and shallow groundwater samples. The results indicate pesticide residue in both types of samples. The concentrations of pesticides in the groundwater were less than Federal health-advisory limits. At the Havre Agricultural Experiment Station, eight wells were installed at two sites. All four soil samples and two of four water samples collected after application of pesticides contained detectable concentrations of atrazine or dicamba. In an area where seed potatoes are grown near Ronan, eight wells were installed at two sites. Pesticides were not detected after initial application of pesticides and irrigation water. The site was resampled after irrigation water was reapplied, and aldicarb metabolities were detected in four of five soil samples and one of five water samples. At the Huntley Agricultural Experiment Station, five wells were installed in a no-tillage corn field where atrazine was applied in 1987. Soil and water samples were collected in June and July 1988; pesticides were not detected in any samples. Results indicate residue of two pesticides in soil samples and three soluble pesticides in groundwater samples. Therefore, irrigated agricultural areas in Montana might be susceptible to transport of soluble pesticides through permeable soil to the shallow groundwater system. (USGS)

Water-Resources Investigations Report↗

Lithology and fracture characterization from drilling investigations in the Mirror Lake area, Grafton County, New Hampshire

The lithology and fracture network of the bedrock aquifer in the Mirror Lake area were characterized from hydrogeologic data collected from 1979-95 in Grafton County, N.H. The collection of these data is an integral part of an ongoing multidisciplinary study by the U.S. Geological Survey to characterize groundwater flow and solute transport in fractured rock. The data provide a physical framework and enable the characterization of the fractures and the rock types in the bedrock aquifer in the Mirror Lake study area. In addition, these data provide a detailed description of the subsurface intersected by boreholes that can be used to compare the results of other borehole testing. The Mirror Lake area is characterized by steep bedrock uplands that are mostly covered by colluvium, discontinuous stratified-drift deposits, and glacial till that varies locally in thickness from less than 10 meters to as much as 50 meters. The land-surface altitude ranges from 180 meters near the Pemigewasset River to 720 meters on the mountain top on the northwestern side of the study area. The bedrock in the area is predominantly sillimanite-grade pelitic schists that have been complexly folded and intruded by granitoids, pegmatites, and diabase dikes. The bedrock has been fractured in response to local and tectonic stress. The resulting interconnected network of fractures forms the bedrock aquifer. This report describes the lithologic units in the study area and provides a characterization of the lithology and fractures found in 40 boreholes, which range in depth from 60 to 305 meters, that were drilled for this study. Drilling logs and color video surveys were used to locate and characterize the fractures and rock types in the subsurface. Solid bedrock core was obtained from three of the boreholes. Petrographic thin-section, x-ray diffraction and scanning electron microscope with energy dispersive x-ray fluorescence spectrometry analyses were done on selected samples from boreholes and outcrops. Observations recorded at the time of drilling, descriptions of rock samples collected from the boreholes, interpretation of rock type and fractures based on boreholeimaging surveys, descriptions of rock core and petrographic analyses of selected rock samples are in tables and figures. Analysis of the data provided information on the distribution of fractures and lithology in the boreholes at Mirror Lake. The relative abundances of the rock types were computed for three groups of boreholes, including (1) the Forest Service Experimental (FSE) well field, (2) the Camp Osceola (CO) well field, and (3) the index boreholes, which are 15 boreholes distributed areally throughout the study area including the deepest borehole from each of the two well fields. The index boreholes are separated by hundreds of meters and are typically 100 meters deep. The FSE well field includes 13 boreholes that are separated by 10 to 40 meters. These 13 boreholes are approximately 100 meters deep, except for one borehole that is 230 meters deep. The rocks penetrated by the FSE wells are predominantly igneous. Approximately 70 percent of the rocks encountered in the boreholes in the FSE well field were granite, pegmatite, and aplite. The CO well field includes 9 boreholes that range from 60-70 meters deep and one borehole that is 175 meters deep. The rocks encountered in these boreholes were predominantly metamorphic. The distribution of rock types in the CO well field is similar to the distribution of rocks in highway roadcuts, that are approximately 90 to 150 meters east of the well field. Seventy percent of the roadcut exposures are schist. Collectively, in the 15 index boreholes, the metamorphic and igneous rocks are equally distributed. Analysis of the rock types in these boreholes indicates that the rock types tend to "change" every 5 to 9 meters. Although the metamorphic and igneous rocks each comprise approximately 50 percent of the rock types observed in the 15 index boreholes, 73 percent of the fractures were in the igneous rocks. This indicates that the granitoids tend to be more fractured than the metamorphic rocks. Pegmatite, diabase, quartzite, and gneissic rocks are relatively unfractured. Boreholes completed in bedrock generally have one or two water-bearing zones, which were identified during the drilling process. At the completion of drilling a borehole, the driller estimated the yield of the borehole with an air-lift test. Yields estimated by drillers ranged from less than 3 to 378 liters per minute. These yields are typical of the yields measured for domestic wells in Grafton County. Water levels measured in the open boreholes after the boreholes recovered from the hydraulic stresses of drilling were usually in the steel casing and were within 10 meters of the land surface. Water levels in eight of the boreholes were above the top of casing or above land surface.

New Hampshire↗

Mineralogy and lithology of the Upper Cretaceous Niobrara Formation determined by hyperspectral core imaging

Sections of the Upper Cretaceous (Coniacian to Campanian) Niobrara Formation in two cores from Kansas and Colorado, the Amoco Rebecca Bounds and USGS Portland 1, respectively, were examined by hyperspectral core imaging and analysis. A spectral imaging system combining high-resolution photography (50 μm), 3D laser profiling (20 μm), and near-visible + short-wave infrared reflectance spectroscopy (wavelengths from 450 to 2500 nm, 500 μm pixel size) was applied to these cores to provide spectral and textural data facilitating creation of continuous mineral and lithology class maps. In addition, compositing of pixel-based results to group pixels to create mineralogical and lithological logs (0.5 ft resolution) was performed to facilitate comparisons to other geochemical datasets. The results show general correspondence in trends identified by previous geochemistry studies, with some exceptions due to instrumental limitations related to low reflectance of some rock intervals and the limited range of infrared wavelengths examined. This study provides a cursory overview of an extensive dataset meant to demonstrate the utility of hyperspectral core scanning to studies of mudrocks in petroleum systems as well as the kinds of information this technique can provide for detailed examination of stratigraphic features in sedimentary systems more generally.

Mountain Geologist↗