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At least 775 records · Page 43Linked to original sources

Geochemical characterization of groundwater evolution south of Grand Canyon, Arizona (USA)

Better characterization of the geochemical evolution of groundwater south of Grand Canyon, Arizona (USA), is needed to understand natural conditions and assess potential effects from breccia-pipe uranium mining in the region. Geochemical signatures of groundwater at 28 sampling locations were evaluated; baseline concentrations for select trace elements (As, B, Ba, Cr, Li, Mo, Rb, Se, Sr, Th, Tl, U, V) were established, and anomalous chemistry characteristics were identified. Concentrations at some groundwater sites exceeded the USEPA drinking water standard for As of 10 μg/L (Red Canyon, Miners, JT, Havasu, and Warm Springs) and U of 30 μg/L (Salt Creek Spring). Four springs from the study area (Blue, Havasu, Fern, and Warm Springs) had unique chemistry, which may indicate a deep flow path or potential contribution of fluids from lower in the crust. Other springs in the study area were distinguished by major anion water type: sulfate, bicarbonate, and a mixture of the two. Water type distinctions were somewhat spatially segregated, with sulfate type present on the western side of the study area, bicarbonate type on the eastern side, and a mixture of the two interspersed between the endmember sites. Sulfate-type water from this study area had low strontium isotopic ratio (87Sr/86Sr) values. The location of spring discharge within single drainages of the Grand Canyon may influence chemistry, as groundwater discharging from bedrock was altered after flowing through alluvial material. Geochemical analysis of groundwater in Grand Canyon indicates the importance of continued monitoring and better understanding of short-term chemical fluctuations.

Arizona↗

Aftershocks of the western Argentina (Caucete) earthquake of 23 November 1977: Some tectonic implications

An aftershock survey, using a network of eight portable and two permanent seismographs, was conducted for the western Argentina (Caucete) earthquake ( M S 7.3) of November 23, 1977. Monitoring began December 6, almost 2 weeks after the main shock and continued for 11 days. The data set includes 185 aftershock hypocenters that range in the depth from near surface to more than 30 km. The spatial distribution of those events occupied a volume of about 100 km long ×50 km wide ×30 km thick. The volumnar nature of the aftershock distribution is interpreted to be a result of a bimodal distribution of foci that define east- and west-dipping planar zones. Efforts to select which of those zones was associated with the causal faulting include special attention to the determination of the mainshock focal depth and dislocation theory modeling of the coseismic surface deformation in the epicentral region. Our focal depth (25–35 km) and modeling studies lead us to prefer an east-dipping plane as causal. A previous interpretation by other investigators used a shallower focal depth (17 km) and similar modeling calculations in choosing a west-dipping plane. Our selection of the east-dipping plane is physically more appealing because it places fault initiation at the base of the crustal seismogenic layer (rather than in the middle of that layer) which requires fault propagation to be updip (rather than downdip).

Tectonophysics↗

Using generalized linear models to estimate selectivity from short-term recoveries of tagged red drum Sciaenops ocellatus: Effects of gear, fate, and regulation period

Estimating the selectivity patterns of various fishing gears is a critical component of fisheries stock assessment due to the difficulty in obtaining representative samples from most gears. We used short-term recoveries ( n = 3587) of tagged red drum Sciaenops ocellatus to directly estimate age- and length-based selectivity patterns using generalized linear models. The most parsimonious models were selected using AIC, and standard deviations were estimated using simulations. Selectivity of red drum was dependent upon the regulation period in which the fish was caught, the gear used to catch the fish (i.e., hook-and-line, gill nets, pound nets), and the fate of the fish upon recovery (i.e., harvested or released); models including all first-order interactions between main effects outperformed models without interactions. Selectivity of harvested fish was generally dome-shaped and shifted toward larger, older fish in response to regulation changes. Selectivity of caught-and-released red drum was highest on the youngest and smallest fish in the early and middle regulation periods, but increased on larger, legal-sized fish in the late regulation period. These results suggest that catch-and-release mortality has consistently been high for small, young red drum, but has recently become more common in larger, older fish. This method of estimating selectivity from short-term tag recoveries is valuable because it is simpler than full tag-return models, and may be more robust because yearly fishing and natural mortality rates do not need to be modeled and estimated.

North Carolina↗

Plant diversity shifts with drying and wetting cycles following removal of poplar plantations in Dongting Lake, China

Dongting Lake, the second largest lake in China, plays a crucial role in maintaining regional ecological security by providing key habitats for waterbirds. This study examined how hydrology and topography (ditches and mounds) together generate fine-scale wet–dry gradients that shape species establishment and successional trajectories. Over the past decade, vegetation restoration has been implemented through the removal of poplar plantations. We selected sites in West Dongting Lake representing different stages following poplar removal, including active plantations (Poplar), one-year (1Yr) and five-year (5Yr) restored sites, and natural floodplain reference sites. Analyses of seasonal water-level dynamics over several years revealed distinct hydrological regimes among restoration stages, with differences in inundation duration and amplitude corresponding to ditch–mound topography. Species diversity indicators showed that species richness was highest in Poplar (37 species) and lowest in Reference sites (14 species), with exotic species richness following the same trend. The lowest Cody index occurred between 1Yr and Reference sites, while the Jaccard similarity differed significantly among site pairs, with lower similarity observed in comparisons with the Reference site. Non-metric Multidimensional Scaling (NMDS) analysis indicated minimal overlap between Poplar and Reference sites, with 1Yr and 5Yr sites clustering together but remaining distinct from the Reference site. These results suggest that poplar cultivation and its associated mound-ditch topography have altered hydrological and community structure of the wetland, facilitating the persistence of exotic species. Natural recolonization is driven by the interaction between seasonal water-level dynamics and topography, which regulate inundation duration and wet–dry cycles. Effective restoration may require removal of poplar plantations and regrading of artificial ditches and mounds to restore natural hydrological connectivity to support vegetation recovery in these subtropical monsoonal wetlands.

Dongting Lake↗

A comparison of methods for streamflow uncertainty estimation

Streamflow time series are commonly derived from stage‐discharge rating curves, but the uncertainty of the rating curve and resulting streamflow series are poorly understood. While different methods to quantify uncertainty in the stage‐discharge relationship exist, there is limited understanding of how uncertainty estimates differ between methods due to different assumptions and methodological choices. We compared uncertainty estimates and stage‐discharge rating curves from seven methods at three river locations of varying hydraulic complexity. Comparison of the estimated uncertainties revealed a wide range of estimates, particularly for high and low flows. At the simplest site on the Isère River (France), full width 95% uncertainties for the different methods ranged from 3 to 17% for median flows. In contrast, uncertainties were much higher and ranged from 41 to 200% for high flows in an extrapolated section of the rating curve at the Mahurangi River (New Zealand) and 28 to 101% for low flows at the Taf River (United Kingdom), where the hydraulic control is unstable at low flows. Differences between methods result from differences in the sources of uncertainty considered, differences in the handling of the time‐varying nature of rating curves, differences in the extent of hydraulic knowledge assumed, and differences in assumptions when extrapolating rating curves above or below the observed gaugings. Ultimately, the selection of an uncertainty method requires a match between user requirements and the assumptions made by the uncertainty method. Given the significant differences in uncertainty estimates between methods, we suggest that a clear statement of uncertainty assumptions be presented alongside streamflow uncertainty estimates.

Water Resources Research↗

Genomic data characterize reproductive ecology patterns in Michigan invasive Red Swamp Crayfish (Procambarus clarkii)

The establishment and spread of invasive species are directly related to intersexual interactions as dispersal and reproductive success are related to distribution, effective population size, and population growth. Accordingly, populations established by r-selected species are particularly difficult to suppress or eradicate. One such species, the red swamp crayfish ( Procambarus clarkii ) is established globally at considerable ecological and financial costs to natural and human communities. Here, we develop a single nucleotide polymorphism (SNP) loci panel for P. clarkii using restriction-associated DNA-sequencing data. We use the SNP panel to successfully genotype 1800 individuals at 930 SNPs in southeastern Michigan, USA. Genotypic data were used to reconstruct pedigrees, which enabled the characterization of P. clarkii's mating system and statistical tests for associations among environmental, demographic, and phenotypic predictors and adult reproductive success estimates. We identified juvenile cohorts using genotype-based pedigrees, body size, and sampling timing, which elucidated the breeding phenology of multiple introduced populations. We report a high prevalence of multiple paternity in each surveyed waterbody, indicating polyandry in this species. We highlight the use of newly developed rapid genomic assessment tools for monitoring population reproductive responses, effective population sizes, and dispersal during ongoing control efforts.

Evolutionary Applications↗

Tag return models allowing for harvest and catch and release: Evidence of environmental and management impacts on striped bass fishing and natural mortality rates

Catch-and-release fisheries have become very important in the management of overexploited recreational fish stocks. Tag return studies, where the tag is removed regardless of fish disposition, have been used to assess the effectiveness of restoration efforts for these fisheries. We extend the instantaneous rate formulation of tag return models to allow for catch and release as well as harvest. The key point of our methods is that, given an estimate of the tag reporting rate, the fishing mortality rate (F) is separated into two components: the mortality on harvested fish and the "mortality" on tags (because the lags are removed) of fish released alive. The total fishing mortality rate for untagged fish is the sum of the Fs due to harvest and hooking mortality suffered by fish released alive. Natural mortality rates can also be estimated. Both age-independent models and age-dependent models are constructed, and the age-dependent models are illustrated by application to data from a study of striped bass Morone saxatilis in Chesapeake Bay from 1991 to 2003 by the Maryland Department of Natural Resources. By fitting models of the natural mortality rate with limited age and year dependence, we demonstrate an overall decrease in natural mortality rates as fish age and provide evidence of an increase in natural mortality beginning in the late 1990s, when an outbreak of the disease mycobacteriosis is thought to have begun. Our results indicate that fishing mortality is age dependent; selectivity increases up to age 6, when fish appear to be fully recruited to the fishery. There is also evidence of an increase in fishing mortality since 1995, when regulations were relaxed. ?? Copyright by the American Fisheries Society 2007.

North American Journal of Fisheries Management↗

Concentrations and loads of cadmium, lead, and zinc measured on the ascending and descending limbs of the 1999 snowmelt-runoff hydrographs for nine water-quality stations, Coeur d'Alene River basin, Idaho

The Remedial Investigation/Feasibility Study conducted by the U.S. Environmental Protection Agency within the Spokane River Basin of northern Idaho and eastern Washington included extensive data-collection activities to determine the nature and extent of trace-element contamination within the basin. The U.S. Geological Survey designed and implemented synoptic sampling of a high-flow runoff event at selected water-quality stations during the 1999 water year. The objective was to quantify spatial and temporal differences in constituent concentrations and loads over the ascending and descending limbs of a hydrograph depicting a high-flow runoff event. Discharge and water-quality data were collected during spring 1999 snowmelt runoff (May through early June) at nine water-quality stations, one on the North Fork Coeur d’Alene River and eight on the South Fork Coeur d’Alene River. The nine stations were sam- pled for whole-water recoverable and dissolved concentrations and loads of cadmium, lead, and zinc. The concentrations and loads sampled during the 1999 snowmelt-runoff event represented near-normal conditions, not flood conditions, in that the recurrence interval for discharge near the hydrograph peak was about 2 years. The general trend among the nine stations was an inverse relation between discharge and dissolved concentrations of cadmium, lead, and zinc, and a direct relation between discharge and whole-water recoverable concentrations of these constituents. The smallest loads of dissolved and whole-water recoverable cadmium, lead, and zinc were measured at South Fork Coeur d’Alene River above Deadman Gulch; constituent concentrations at this site were some of the smallest among those sampled, and discharge was also relatively small. The largest loads of dissolved and whole-water recoverable cadmium, lead, and zinc were measured at South Fork Coeur d’Alene River at Pinehurst; constituent concentrations at this site were large and discharge was the second-largest of all the discharge measurements. Hysteresis effects on concentrations and loads over the ascending and descending limbs of the snowmelt-runoff hydrograph were quite apparent, especially for whole-water recoverable constituents. Hysteresis is present when a property, such as constituent concentration or load, has different values for a given discharge over the ascending and descending limbs of a hydrograph. During this study, loads of whole-water recoverable constituents on the ascending limb were between 1.5 and 3.6 times larger than those mea- sured on the descending limb at nearly equal discharge. In contrast, dissolved constituents showed minimal hysteresis effects.

Idaho↗

Water quality at a biosolids-application area near Deer Trail, Colorado, 1993-1999

The Metro Wastewater Reclamation District (Metro District) in Denver, Colo., applied biosolids resulting from municipal sewage treatment to farmland in eastern Colorado beginning in December 1993. In mid-1993, the U.S. Geological Survey in cooperation with the Metro District began monitoring water quality at the biosolids-application area about 10 miles east of Deer Trail, Colo., to evaluate baseline water quality and the combined effects of natural processes, land uses, and biosolids applications on water quality of the biosolids application area. Water quality was characterized by baseline and post-biosolids-application sampling for selected inorganic and bacteriological constituents during 1993 through 1998, with some additional specialized sampling in 1999. The study included limited sampling of surface water and the unsaturated zone, but primarily focused on groundwater. See report for complete abstract.

Colorado↗

Groundwater quality and age of secondary bedrock aquifers in the glaciated portion of eastern Nebraska, 2016–18

The Eastern Nebraska Water Resources Assessment (ENWRA) project was initiated in 2006 to assist water managers by developing a hydrogeologic framework and water budget for the glaciated portion of eastern Nebraska. Within the ENWRA area, the primary groundwater sources for municipal, domestic, and irrigation water needs are provided by withdrawals from alluvial, buried paleovalley, and the High Plains aquifer (where present). Generally, other bedrock aquifers are considered a secondary water source. However, in some areas, such as parts of Sarpy and Nemaha Counties, these secondary bedrock aquifers are the only source of water within glaciated upland areas. To improve the understanding of the quality, geochemistry, and age of groundwater from bedrock aquifers, the U.S. Geological Survey (USGS), in cooperation with the ENWRA group, which includes the Lewis and Clark, Lower Elkhorn, Lower Platte North, Lower Platte South, Nemaha, and Papio-Missouri River Natural Resources Districts, designed a study to sample 31 wells completed in the secondary bedrock aquifers and analyze samples for major ions, physical properties, nutrients, stable isotopes, and selected age tracers. Of the 31 samples collected for this report, 22 samples were collected from the Dakota aquifer contained in the Dakota Sandstone, 3 from the Niobrara aquifer contained in the Niobrara Formation of Colorado Group, and 6 from Paleozoic aquifers contained in undifferentiated Paleozoic-age units. The results of this study indicate that major ion data collected from the Dakota aquifer can be used for assessing the quality, recharge source, and age of groundwater. Calcium bicarbonate dominant samples were characterized as modern or mixed, indicating that, in these areas, groundwater is unconfined and is recharged by precipitation and (or) surface water. If groundwater extraction rates exceed recharge rates, total dissolved solid concentrations may increase as a result of upwelling of groundwater from deeper units or formations, which can adversely affect groundwater quality. Sampling results presented in this report indicate water quality is good, but that groundwater in the Dakota aquifer with calcium bicarbonate water type may be vulnerable to surface contamination. In contrast, groundwater sampled from the Dakota aquifer, having a dominant water type other than calcium bicarbonate, generally has low dissolved oxygen and nitrate concentrations, and higher concentrations of total dissolved solids and trace elements, including iron and strontium. The geochemical characteristics of noncalcium bicarbonate samples from the Dakota aquifer indicated confining conditions and limited groundwater recharge from local precipitation. Apparent groundwater ages estimated from radiocarbon (carbon-14) sampling of noncalcium bicarbonate samples from the Dakota aquifer indicated that the time of groundwater recharge to the Dakota aquifer occurred during Pleistocene time. Depleted stable isotopes results indicate recharge during a colder climate. Groundwater under confined conditions is not easily recharged from precipitation or surface water. Future groundwater-level monitoring in locations where the Dakota aquifer appears to be confined could provide information to evaluate whether groundwater supplies remain sufficient to meet future municipal, domestic, and irrigation needs. For the Niobrara aquifer and Paleozoic aquifers, the dominant water type was not a diagnostic indicator of recharge source, age, and groundwater quality as with the Dakota aquifer. Most likely this is because the host formation was dominated by calcium-carbonate-rich rocks; however, few samples were collected from these aquifers to be able to confirm this interpretation. Samples collected from wells completed in the Niobrara aquifer and Paleozoic aquifers and characterized as calcium sulfate water type have statistically significantly higher concentrations of total dissolved solids compared to other samples from the Niobrara aquifer and Paleozoic aquifers characterized as calcium bicarbonate. Given that six of the nine of samples collected from the Niobrara and Paleozoic aquifers indicated modern recharge, these secondary bedrock aquifers are reliant on precipitation to sustain groundwater levels and may be vulnerable to a multiyear drought. Well yields of the Niobrara and Paleozoic aquifers are dependent on the presence of secondary porosity and these units offer little storage. Samples collected from wells completed in Paleozoic aquifers were the most isotopically enriched and similar to modern precipitation and had the highest concentrations of nitrate, indicating that groundwater is affected by agricultural activities. Future groundwater sampling would be beneficial to characterize groundwater-quality changes within the Niobrara and Paleozoic aquifers over time.

Nebraska↗

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas: Shallow ground-water quality of a land-use area in the San Luis Valley, south-central Colorado, 1993

This report describes the quality of shallow ground water in an agricultural area in the San Luis Valley, Colorado, and discusses how natural and human factors affect the quality of shallow ground water. Thirty-five wells were installed, and water samples were collected from these wells and analyzed for selected dissolved common constituents, nutrients, trace elements, radionuclides, and synthetic organic compounds. The San Luis Valley is a high intermontane valley that is partially drained by the Rio Grande. The San Luis Valley land-use study area was limited to a part of the valley where the depth to water is generally less than 25 feet. The area where the 35 monitor wells were installed was further limited to the part of the study area where center-pivot overhead sprinklers are used to irrigate crops. Precipitation, runoff from adjacent mountainous areas, and ground-water inflow from the adjacent mountainous areas are the main sources of water to the aquifers in the San Luis Valley. Discharge of water from the shallow, unconfined aquifer in the valley is mainly from evapotranspiration. The dominant land use in the San Luis Valley is agriculture, although nonirrigated land and residential land are interspersed with agricultural land. Alfalfa, native hay, barley, wheat, potatoes, and other vegetables are the main crops. Dissolved-solids concentrations in shallow ground water sampled ranged from 75 to 1,960 milligrams per liter. The largest median concentration of cations was for calcium, and the largest median concentration of anions was for bicarbonate in shallow ground water in the San Luis Valley. Calcium concentrations ranged from 7.5 to 300 milligrams per liter, and bicarbonate concentrations ranged from 28 to 451 milligrams per liter. Nitrite plus nitrate concentrations ranged from less than 0.1 to 58 milligrams per liter as N; water from 11 wells had nitrite plus nitrate concentrations greater than 10 milligrams per liter as N. With the exception of the following trace elements--aluminum, barium, iron, manganese, molybdenum, and uranium--the concentrations of trace elements were less than 10 micrograms per liter in 90 percent of the samples. All trace-element concentrations measured were below the maximum contaminant levels set by the U.S. Environmental Protection Agency. Five samples exceeded the proposed maximum contaminant level of 0.02 milligram per liter for uranium. All samples collected exceeded the proposed maximum contaminant level for radon-222. The volatile organic compound methyltertbutylether was detected in one sample at a concentration of 0.6 microgram per liter. Of the pesticides analyzed for, one or more were detected in water from 5 of the 35 wells sampled. Metribuzin was the most commonly detected pesticide and was detected in water from three wells at concentrations ranging from an estimated 0.005 to 0.017 microgram per liter. Metolachlor (detected in one sample at a concentration of 0.072 microgram per liter), prometon (detected in one sample at a concentration of 0.01 microgram per liter), and p,p'-DDE (detected in one sample at an estimated concentration of 0.002 microgram per liter) were the other pesticides detected. The U.S. Environmental Protection Agency lifetime health advisory for metolachlor, metribuzin, and prometon is 100 micrograms per liter, which is much larger than the concentrations measured in the shallow ground water sampled for this study. The elevated nitrite plus nitrate concentrations in shallow ground water are indicative of leaching of fertilizers from the land surface. This conclusion is consistent with conclusions made in other investigations of the San Luis Valley.

Colorado↗

Surface-water-quality assessment of the lower Kansas River basin, Kansas and Nebraska– Analysis of available data through 1986

Available surface water-quality data were used to provide an initial assessment of current water-quality conditions for 1978-86, define long-term trends in constituent concentrations, and relate current water-quality conditions and trends to human and natural factors in the lower Kansas River basin, Kansas and Nebraska. This basin drains 15,300 square miles of predominantly agricultural land and is one of seven areas selected for study as part of the National Water-Quality Assessment Program.

Kansas, Nebraska↗

Growth and mortality of invasive Flathead Catfish in the tidal James River, Virginia

Invasive species are a major threat to biodiversity of native fishes in North America. In Atlantic coastal rivers of the United States, large catfishes introduced from the Gulf of Mexico drainages have become established and contributed to native species declines. Flathead Catfish Pylodictis olivaris were introduced to the Chesapeake Bay drainage in the 1960s and 1970s in the James and Potomac river systems in the eastern United States. Diet studies have found James River Flathead Catfish function as apex predators and are known to consume at-risk Alosa spp. To limit further range expansion and impacts to native species, resource management agencies need information on population characteristics to support population assessments and management plan development. Thus, we examined temporal trends in growth rates and estimated total instantaneous mortality for tidal James River Flathead Catfish collected by Virginia Department of Game and Inland Fisheries from 1997 to 2015. Parameters of the von Bertalanffy growth model with length-at-age observations pooled across sampling years were estimated as L ∞ = 1,059 mm, k = 0.231/y, and t 0 = 0.55 y. Flathead Catfish growth differed among sampling years, especially for the years 2007 and 2014, which had the largest sample sizes. However, there were no obvious temporal trends in growth trajectories. James River Flathead Catfish tend to grow much faster than most populations used in development of the relative growth index, but the species is known to grow faster in its nonnative range. Consequently, scientists and managers should use caution when applying growth indices if native and nonnative populations are not expressly considered in development of the index. We estimated total instantaneous mortality as Z = 0.50 and mean natural mortality from six estimators as M = 0.30. A lack of older individuals in the population means that mortality rates may be overestimated as a result of gear selectivity or ongoing maturation of the population. These data provide information to support future work examining the species in the James River and development of population models to evaluate management strategies and management plans.

Virginia↗

Selected hydrologic data for Cache Valley, Utah and Idaho, 1969-91

This report contains hydrologic data collected in Cache Valley from 1969 to 1991. The report area is in north-central Utah and southeast Idaho, within the Basin and Range physiographic province described by Fenneman (1931), and includes about 660 square miles. Most of the data in this report were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Resources and Water Rights. Some of the data collected before 1969 were previously published by McGreevy and Bjorklund (1970). The purpose of this report is to provide hydrologic data for use by the general public and by officials managing the area's water resources, and to supplement interpretive reports for the area. Tables 1 to 7 contain selected well, spring, and surface-water data. The numbering systems used in this report for hydrologic-data sites are illustrated in figure 1. Hydrologic-data sites are shown on plate 1. These data could not have been collected without the cooperation of local residents and officials of irrigation companies and municipalities, that permitted access to their wells, springs, and canals to measure water levels in wells and flow in springs and canals. The Idaho Department of Water Resources also provided valuable assistance and data.

Idaho, Utah↗

Characterization of water quality, biology, and habitat of the Pearl River and selected tributaries contiguous to and within Tribal lands of the Pearl River Community of the Mississippi Band of Choctaw Indians, 2017–18

The U.S. Geological Survey, in cooperation with the Mississippi Band of Choctaw Indians (MBCI), conducted a baseline assessment of the physical, chemical, and biological quality of selected streams and rivers within and contiguous to the Pearl River Community (PRC) in 2017 and 2018. The MBCI is a federally recognized tribe with territories in Mississippi and Tennessee. MBCI Tribal government and communities have sovereign authority over their natural resources and are responsible for protecting the quality of waters within the Tribal lands from sources of pollution and restoring impaired waters. The quality of these surface waters has a profound effect upon the health and welfare of MBCI Tribal members. Data generated from this study may be used with other relevant water-quality data for comparison and development of Tribal water-quality standards. The PRC territory is drained by the Pearl River and associated tributaries. Water-quality and biological samples were collected and habitat surveys were conducted at sites on the mainstem of the Pearl River and major tributaries of the Pearl River—Wolf Creek, Beasha Creek, Jones Creek, and Kentawka Creek. The selected stream sites represent a range of land use/land cover and potential sources of alteration and contamination from within their respective drainage areas. In particular, Wolf Creek watershed has the highest relative percentage of developed land. Ambient physicochemical properties, major ions, nutrients, and organic wastewater compounds (OWCs) were analyzed quarterly from surface-water samples from October 2017 through August 2018. Physicochemical properties were also measured in June 2018 over a continuous 48-hour period. Trace elements and polycyclic aromatic hydrocarbons were analyzed from streambed sediments in August 2018. Biological samples included the collection of periphyton algae (August 2018), benthic macroinvertebrate (March 2017 and March 2018), and fish communities (April 2018). Physical stream habitat characteristics were assessed using qualitative (March 2017 and March 2018) and quantitative surveys (August 2018). While not directly applicable, the State of Mississippi Water Quality Standards were used as reference to evaluate Tribal water quality. Physicochemical water-quality constituents—water temperature, specific conductance (SC), pH, and dissolved oxygen (DO)—were generally within natural ranges among sites and samples, with a few exceptions that exceeded existing Mississippi water-quality standards. pH and DO periodically were below the minimum State standards at some sampled sites. Specific conductance was also relatively high at both Wolf Creek sites but did not exceed the existing maximum standard for recreational waters. The surface water among stream sites was predominantly calcium bicarbonate type, with a shift toward sodium-bicarbonate water type at the downstream Wolf Creek (Wolf DS) site. Major ion concentrations were generally highest at the Wolf Creek sites. Nutrient concentrations were also often highest at Wolf DS, but total nitrogen and total phosphorus periodically exceeded recommended State and Federal nutrient criteria thresholds among most sampled sites. Twenty-nine OWCs, including 10 known or suspected endocrine disruptors, were detected among sites. Concentrations of OWCs were relatively low, and only 19 percent of all detections were above the reporting level. Concentrations of copper and nickel in streambed sediments were detected above consensus-based threshold-effect concentrations (TECs) at one site each, and arsenic and chromium exceeded TECs at most sites. Concentrations of all polycyclic aromatic hydrocarbons in streambed sediments were low and well below TECs at all sites. The periphyton, macroinvertebrate, and fish communities at most sampled sites appear typical of central Mississippi streams; however, the diversity, composition, and abundance of taxa sampled from Wolf DS were particularly distinctive compared to other sampled stream sites. Periphyton taxa richness was low at both Wolf Creek sites, and both sites had greater abundances of diatom taxa, which are indicative of high nutrient concentrations, than of soft-algae taxa. Similarly, Wolf DS had relatively low macroinvertebrate diversity, the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa, a high abundance of Tubificid taxa, and the lowest overall Mississippi-Benthic Index of Stream Quality score. Fish species richness was also relatively low at Wolf DS compared to some other sampled sites. Habitat characteristics also appeared to be generally typical of most central Mississippi streams. Qualitative habitat assessment scores were at or above the regional least disturbed streams for Wolf DS, the upstream Wolf Creek (Wolf US) site, and Jones Creek. Habitat scores among the remaining sites indicate fair conditions. Quantitative and qualitative habitat characteristics indicate relatively lower habitat quality at the two Beasha Creek sites.

Mississippi↗

Chemical analysis of water samples and geophysical logs from cored test holes drilled in the central Oklahoma Aquifer, Oklahoma

Chemical analyses of water from eight test holes and geophysical logs for nine test holes drilled in the Central Oklahoma aquifer are presented. The test holes were drilled to investigate local occurrences of potentially toxic, naturally occurring trace substances in ground water. These trace substances include arsenic, chromium, selenium, residual alpha-particle activities, and uranium. Eight of the nine test holes were drilled near wells known to contain large concentrations of one or more of the naturally occurring trace substances. One test hole was drilled in an area known to have only small concentrations of any of the naturally occurring trace substances. Water samples were collected from one to eight individual sandstone layers within each test hole. A total of 28 water samples, including four duplicate samples, were collected. The temperature, pH, specific conductance, alkalinity, and dissolved-oxygen concentrations were measured at the sample site. Laboratory determinations included major ions, nutrients, dissolved organic carbon, and trace elements (aluminum, arsenic, barium, beryllium, boron, cadmium, chromium, hexavalent chromium, cobalt, copper, iron, lead, lithium, manganese, mercury, molybdenum, nickel, selenium, silver, strontium, vanadium and zinc). Radionuclide activities and stable isotope (5 values also were determined, including: gross-alpha-particle activity, gross-beta-particle activity, radium-226, radium-228, radon-222, uranium-234, uranium-235, uranium-238, total uranium, carbon-13/carbon-12, deuterium/hydrogen-1, oxygen-18/oxygen-16, and sulfur-34/sulfur-32. Additional analyses of arsenic and selenium species are presented for selected samples as well as analyses of density and iodine for two samples, tritium for three samples, and carbon-14 for one sample. Geophysical logs for most test holes include caliper, neutron, gamma-gamma, natural-gamma logs, spontaneous potential, long- and short-normal resistivity, and single-point resistance. Logs for test-hole NOTS 7 do not include long- and short-normal resistivity, spontaneous-potential, or single-point resistivity. Logs for test-hole NOTS 7A include only caliper and natural-gamma logs.

Oklahoma↗

A study of the temporal variability of atrazine in private well water. Part I: Study design, implementation, and database development

In 1988, the Iowa Department of Natural Resources, along with the University of Iowa conducted the Statewide Rural Well Water Survey, commonly known as SWRL. A total of 686 private rural drinking water wells was selected by use of a probability sample and tested for pesticides and nitrates. Sixty-eight of these wells, the '10% repeat' wells, were additionally sampled in October, 1990 and June, 1991. Starting in November, 1991, the University of Iowa, with sponsorship from the United States Environmental Protection Agency, revisited these wells to begin a study of the temporal variability of atrazine and nitrates in wells. Other wells, which had originally tested positive for atrazine in SWRL but were not in the 10% repeat population, were added to the study population. Temporal sampling for a year-long period began in February of 1992 and concluded in January of 1993. All wells were sampled monthly, one subset was sampled weekly, and a second subset was sampled for 14-day consecutive periods. Two unique aspects of this study were the use of an immunoassay technique to screen for triazines before gas chromatography/mass spectrometry (GC/MS) analysis and quantification of atrazine, and the use of well owners to sample the wells. A total of 1771 samples from 83 wells are in the final data base for this study. This paper reviews the study design, the analytical methodologies, and development of the data base. A companion paper discusses the analysis of the data from this survey.

Environmental Monitoring and Assessment↗

Preliminary results on photometric properties of materials at the Sagan Memorial Station, Mars

Reflectance measurements of selected rocks and soils over a wide range of illumination geometries obtained by the Imager for Mars Pathfinder (IMP) camera provide constraints on interpretations of the physical and mineralogical nature of geologic materials at the landing site. The data sets consist of (1) three small “photometric spot” subframed scenes, covering phase angles from 20° to 150°; (2) two image strips composed of three subframed images each, located along the antisunrise and antisunset lines (photometric equator), covering phase angles from ∼0° to 155°; and (3) full‐image scenes of the rock “Yogi,” covering phase angles from 48° to 100°. Phase functions extracted from calibrated data exhibit a dominantly backscattering photometric function, consistent with the results from the Viking lander cameras. However, forward scattering behavior does appear at phase angles >140°, particularly for the darker gray rock surfaces. Preliminary efforts using a Hapke scattering model are useful in comparing surface properties of different rock and soil types but are not well constrained, possibly due to the incomplete phase angle availability, uncertainties related to the photometric function of the calibration targets, and/or the competing effects of diffuse and direct lighting. Preliminary interpretations of the derived Hapke parameters suggest that (1) red rocks can be modeled as a mixture of gray rocks with a coating of bright and dark soil or dust, and (2) gray rocks have macroscopically smoother surfaces composed of microscopically homogeneous, clear materials with little internal scattering, which may imply a glass‐like or varnished surface.

Journal of Geophysical Research E: Planets↗