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At least 757 records · Page 42Linked to original sources

Simulation of Streamflow and Water Quality to Determine Fecal Coliform and Nitrate Concentrations and Loads in the Mad River Basin, Ohio

The Hydrological Simulation Program Fortran (HSPF) was used to simulate the concentrations and loads of fecal coliform and nitrate for streams in the Mad River Basin in west-central Ohio during the period 1999 through 2003. The Mad River Basin was divided into subbasins that were defined either by the 14-digit Hydrologic Unit (HU) boundaries or by streamflow-gaging-station locations used in the model. Model calibration and simulation processes required the formation of nine meteorologic zones to input meteorologic time-series data and water-quality data. Sources of fecal coliform and nitrate from wastewater-treatment discharges and combined sewer overflow discharges (CSOs) within the City of Springfield were point sources simulated in the model. Failing septic systems and cattle with direct access to streams were nonpoint sources included in the study but treated in the model as point sources. Other nonpoint sources were addressed by adjusting interflow and ground-water concentrations in the subsurface and maximum storage capacities and accumulation rates of the simulated constituents on the land surface for each meteorologic zone. Simulation results from the calibrated model show that several HUs exceeded the water-quality standard of 1,000 colony-forming units per 100 mL for fecal coliform based on the maximum 30-day geometric mean. Most HUs with high fecal coliform counts were within or downstream from the City of Springfield. No water-quality standard has been set for instream nitrate concentrations; however, the Ohio Environmental Protection Agency (Ohio EPA) considered a concentration of 5 mg/L or greater to be of concern. Simulation results indicate that several HUs in the agricultural areas of the basin exceeded this level. The calibrated model was modified to create scenarios that simulated loads of fecal coliform and nitrate that were either reduced or eliminated from selected sources. The revised models included the elimination of failing septic systems, elimination of direct access of cattle to streams, decrease in fecal coliform loads from the CSOs and selected wastewater-treatment facilities, and decrease in nitrate loads from land surfaces. The fecal coliform source-reduction model decreased the fecal coliform concentrations below a target concentration of 1,000 colonies per 100 milliliters for all HU outlets and decreased the load at the mouth of the Mad River by 73 percent. The nitrate source-reduction model decreased some HU mean concentrations to 5 milligrams per liter or less and decreased the load at the mouth of the Mad River by 52 percent. Other reduction scenarios may be run by Ohio EPA with the intent of identifying a management strategy that will attain a target concentration for the Mad River Basin.

Scientific Investigations Report↗

Distillation irrigation: A low-energy process for coupling water purification and drip irrigation

A method is proposed for combining solar distillation and drip irrigation to simultaneously desalinize water and apply this water to row crops. In this paper, the basic method is illustrated by a simple device constructed primarily of sheets of plastic, which uses solar energy to distill impaired water and apply the distillate to a widely spaced row crop. To predict the performance of the proposed device, an empirical equation for distillate production, dp , is developed from reported solar still production rates, and a modified Jensen-Haise equation is used to calculate the potential evapotranspiration, et , for a row crop. Monthly values for et and dp are calculated by using a generalized row crop at five locations in the Western United States. Calculated et values range from 1 to 22 cm month −1 and calculated dp values range from 2 to 11 cm month −1 , depending on the location, the month, and the crop average. When the sum of dp plus precipitation, dp + P , is compared to et for the case of 50% distillation irrigation system coverage, the results indicate that the crop's et is matched by dp + P , at the cooler locations only. However, when the system coverage is increased to 66%, the crop's et is matched by dp + P even at the hottest location. Potential advantages of distillation irrigation include the ability: (a) to convert impaired water resources to water containing no salts or sediments; and (b) to efficiently and automatically irrigate crops at a rate that is controlled primarily by radiation intensities. The anticipated disadvantages of distillation irrigation include: (a) the high costs of a system, due to the large amounts of sheeting required, the short lifetime of the sheeting, and the physically cumbersome nature of a system; (b) the need for a widely spaced crop to reduce shading of the system by the crop; and (c) the production of a concentrated brine or precipitate, requiring proper off-site disposal.

Agricultural Water Management↗

Vadose water

Vadose water is subsurface water between the land surface and the saturated zone below the water table. The vadose (or unsaturated) zone includes soil water, which is immediately available to the biosphere. It acts as a controlling agent in the transmission of water and other substances between various components of the earth system: aquifers, land surface, bodies of water, atmosphere, and so on. As an accessible body of material near the earth's surface, the vadose zone is a focus of much human activity, including agriculture, mining, construction, and waste disposal. Thus, it is affected by anthropogenic modifications of its chemical and physical components. Modern hydrology must consider interactions not only among the natural constituents, but also with a wide variety of contaminants, including pesticides, fertilizers, irrigation wastewater, sewage, toxic chemicals, radioactive substances, bacteria, mine wastes, and organic liquids.

Book chapter↗

Local environment and individuals’ beliefs: The dynamics shaping public support for sustainability policy in an agricultural landscape

Agricultural landscapes are the bleeding-edge in the advancement of sustainability and climate change adaptation. Our study focuses on how individual support for sustainability policy is shaped in coupled natural and human systems. We present an agent-based model in which a cultural decision-rule quantifies the probability that a stakeholder decides to support an easement policy for a region in the Central Great Plains, USA. Our model defines a cultural threshold used to assess how culturally meaningful the policy is for each stakeholder. The individual cultural threshold is estimated using the value-belief-norm framework and is modified by perceived changes in the environment. Results demonstrated that few stakeholders support the policy in the average cultural setting (8.9%). However, enough stakeholders would support the policy under a lower cultural threshold (40.7%). Our results indicate that sustainability policies do not need to be cheap if they are culturally meaningful.

Kansas↗

Potential climatic impacts of vegetation change: A regional modeling study

The human species has been modifying the landscape long before the development of modern agrarian techniques. Much of the land area of the conterminous United States is currently used for agricultural production. In certain regions this change in vegetative cover from its natural state may have led to local climatic change. A regional climate version of the Colorado State University Regional Atmospheric Modeling System was used to assess the impact of a natural versus current vegetation distribution on the weather and climate of July 1989. The results indicate that coherent regions of substantial changes, of both positive and negative sign, in screen height temperature, humidity, wind speed, and precipitation are a possible consequence of land use change throughout the United States. The simulated changes in the screen height quantities were closely related to changes in the vegetation parameters of albedo, roughness length, leaf area index, and fractional coverage.

Journal of Geophysical Research D: Atmospheres↗

The human footprint in the west: a large-scale analysis of anthropogenic impacts.

Anthropogenic features such as urbanization, roads, and power lines, are increasing in western United States landscapes in response to rapidly growing human populations. However, their spatial effects have not been evaluated. Our goal was to model the human footprint across the western United States. We first delineated the actual area occupied by anthropogenic features, the physical effect area. Next, we developed the human footprint model based on the ecological effect area, the zone influenced by features beyond their physical presence, by combining seven input models: three models quantified top-down anthropogenic influences of synanthropic predators (avian predators, domestic dog and cat presence risk), and four models quantified bottom-up anthropogenic influences on habitat (invasion of exotic plants, human-caused fires, energy extraction, and anthropogenic wildland fragmentation). Using independent bird population data, we found bird abundance of four synanthropic species to correlate positively with human footprint intensity and negatively for three of the six species influenced by habitat fragmentation. We then evaluated the extent of the human footprint in relation to terrestrial (ecoregions) and aquatic systems (major rivers and lakes), regional management and conservation status, physical environment, and temporal changes in human actions. The physical effect area of anthropogenic features covered 13% of the western United States with agricultural land (9.8%) being most dominant. High-intensity human footprint areas (class 8 – 10) overlapped highly productive low-elevation private landholdings and covered 7% of the western United States compared to 48% for low-intensity areas (class 1 – 3), which were confined to low-productivity high-elevation federal landholdings. Areas within 1 km of rivers were more affected by the human footprint compared to lakes. Percentage human population growth was higher in low-intensity human footprint areas. The disproportional regional effects of the human footprint on landscapes in the western United States create a challenge to management of ecosystems and wildlife populations. Using footprint models, managers can plan land use actions, develop restoration scenarios, and identify areas of high conservation value at local landscapes within a regional context. Moreover, human footprint models serve as a tool to stratify landscapes for studies investigating floral and faunal response to human disturbance intensity gradients.

Ecological Applications↗

Groundwater quality in the San Diego Drainages Hydrogeologic Province, California

More than 40 percent of California's drinking water is from groundwater. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The San Diego Drainages Hydrogeologic Province (hereinafter referred to as San Diego) is one of the study units being evaluated. The San Diego study unit is approximately 3,900 square miles and consists of the Temecula Valley, Warner Valley, and 12 other alluvial basins (California Department of Water Resources, 2003). The study unit also consists of all areas outside defined groundwater basins that are within 3 kilometers of a public-supply well. The study unit was separated, based primarily on hydrogeologic settings, into four study areas: Temecula Valley, Warner Valley, Alluvial Basins, and Hard Rock (Wright and others, 2005). The sampling density for the Hard Rock study area, which consists of areas outside of groundwater basins, was much lower than for the other study areas. Consequently, aquifer proportions for the Hard Rock study area are not used to calculate the aquifer proportions shown by the pie charts. An assessment of groundwater quality for the Hard Rock study area can be found in Wright and Belitz, 2011. The temperatures in the coastal part of the study unit are mild with dry summers, moist winters, and an average annual rainfall of about 10 inches. The temperatures in the mountainous eastern part of the study unit are cooler than in the coastal part, with an annual precipitation of about 45 inches that occurs mostly in the winter. The primary aquifers consist of Quaternary-age alluvium and weathered bedrock in the Temecula Valley, Warner Valley, and Alluvial Basins study areas, whereas in the Hard Rock study area the primary aquifers consist mainly of fractured and decomposed granite of Mesozoic age. The primary aquifers are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. Public-supply wells typically are drilled to depths between 200 and 700 feet, consist of solid casing from the land surface to a depth of about 60 to 170 feet, and are perforated, or consist of an open hole, below the solid casing. Water quality in the shallow and deep parts of the aquifer system may differ from water quality in the primary aquifers. Municipal water use accounts for approximately 70 percent of water used in the study unit; the majority of the remainder is used for agriculture, industry, and commerce. Groundwater accounts for approximately 8 percent of the municipal supply, and surface water, the majority of which is imported, accounts for the rest. Recharge to groundwater occurs through stream-channel infiltration from rivers and their tributaries, infiltration in engineered recharge basins, and infiltration of water from precipitation and irrigation. The primary source of discharge is water pumped from wells.

California↗

Organic compounds in Elm Fork Trinity River water used for public supply near Carrollton, Texas, 2002–05

Organic compounds studied in this U.S. Geological Survey (USGS) assessment generally are man-made, including pesticides, solvents, gasoline hydrocarbons, personal-care and domestic-use products, refrigerants, and propellants. A total of 103 of 277 compounds were detected at least once among the 30 samples of source water for a community water system on the Elm Fork Trinity River near Carrollton, Texas, collected approximately monthly during 2002-05. The diversity of compounds detected indicates a variety of different sources and uses (including wastewater discharge, industrial, agricultural, domestic, and others) and different pathways (including overland runoff and groundwater discharge) to drinking-water supplies. Nine compounds were detected year-round in source-water samples, including chloroform, methyl tert-butyl ether (MTBE), and selected herbicide compounds commonly used in the Trinity River Basin and in other urban areas across the United States. About 90 percent of the 42 compounds detected most frequently in source water (in at least 20 percent of the samples) also were detected most frequently in finished water (after treatment but before distribution). Concentrations for all detected compounds in source and finished water generally were less than 0.1 microgram per liter and always less than human-health benchmarks, which are available for about one-half of the detected compounds.

Texas↗

Quaternary stratigraphy and tectonics, and late prehistoric agriculture of the Safford Basin (Gila and San Simon river valleys), Graham County, Arizona

This guidebook accompanied the 46th annual meeting of the Rocky Mountain Cell of the Friends of the Pleistocene (FOP) and the 2002 Fall Field Trip of the Arizona Geological Society. The meeting and field trip were held in the Safford Basin, southeastern Arizona. The Friends of the Pleistocene is an informal gathering of Quaternary geologists, geomorphologists, and pedologists who meet annually for a field conference. The first part of the guidebook consists of road logs with descriptions of stops covering the three days of the field trip. An overview of the geology of the Safford Basin is given in Stop 1-1. The second part of the guidebook consists of four short papers that discuss adjacent areas or that expand upon the road log descriptions of the field trip stops. The first paper by Reid and Buffler is a summary of upper Cenozoic depositional facies in the Duncan Basin, the first basin to the east of the Safford Basin. The next three papers expand upon (1) the soil study of the gridded field agricultural complex (Stop 2-3, Homburg and Sandor), (2) the vertebrate fossils of the San Simon Valley in the southeastern part of the Safford Basin (Stop 3-1, Thrasher), and (3) paleoIndian irrigation systems and settlements in Lefthand Canyon at the foot of the Pinaleno Mountains (Stop 3-2, Neely and Homburg).

Open-File Report↗

Effects of two contrasting agricultural land uses on shallow groundwater quality in the San Joaquin Valley, California; design and preliminary interpretation

From 1992 through 1994, the San Joaquin-Tulare Basins Study team of the USGS National Water Quality Assessment program investigated the occurrence and distribution of water quality constituents in shallow groundwater underlying two areas of different agricultural land uses: almond orchards and vineyards. The study was restricted to the alluvial fans of the eastern San Joaquin Valley, the area of most groundwater use in the valley. A geographic information system (GIS) was used to delineate the distribution of the two target land uses, to evaluate ancillary data, and to select candidate wells that fit prescribed criteria. Twenty domestic water supply wells were sampled in each of the two areas. In addition, pairs of observation wells were installed and sampled at five of the sites in each area to evaluate whether the water quality in the domestic wells reflects that of the shallow groundwater underlying the target land use. A preliminary evaluation of the results shows that nitrate concentrations in the shallow groundwater are significantly higher in the almond orchard areas than in the vineyard area (p=0.005). In contrast, concentrations of 1,2-dibromo-3-chloropropane (DBCP) were higher in the vineyard area than in the almond orchard area (p=0.032). The most frequently detected pesticides in groundwater underlying both areas were simazine, atrazine, and desethylatrazine (an atrazine degradation product). These observations are explained, in part, by differences in chemical application and hydrogeologic factors.

California↗

Bathymetry and capacity of Blackfoot Reservoir, Caribou County, Idaho, 2011

The U.S. Geological Survey (USGS), in cooperation with the Shoshone-Bannock Tribes, surveyed the bathymetry and selected above-water sections of Blackfoot Reservoir, Caribou County, Idaho, in 2011. Reservoir operators manage releases from Government Dam on Blackfoot Reservoir based on a stage-capacity relation developed about the time of dam construction in the early 1900s. Reservoir operation directly affects the amount of water that is available for irrigation of agricultural land on the Fort Hall Indian Reservation and surrounding areas. The USGS surveyed the below-water sections of the reservoir using a multibeam echosounder and real-time kinematic global positioning system (RTK-GPS) equipment at full reservoir pool in June 2011, covering elevations from 6,090 to 6,119 feet (ft) above the North American Vertical Datum of 1988 (NAVD 88). The USGS used data from a light detection and ranging (LiDAR) survey performed in 2000 to map reservoir bathymetry from 6,116 to 6,124 ft NAVD 88, which were mostly in depths too shallow to measure with the multibeam echosounder, and most of the above-water section of the reservoir (above 6,124 ft NAVD 88). Selected points and bank erosional features were surveyed by the USGS using RTK-GPS and a total station at low reservoir pool in September 2011 to supplement and verify the LiDAR data. The stage-capacity relation was revised and presented in a tabular format. The datasets show a 2.0-percent decrease in capacity from the original survey, due to sedimentation or differences in accuracy between surveys. A 1.3-percent error also was detected in the previously used capacity table and measured water-level elevation because of questionable reference elevation at monitoring stations near Government Dam. Reservoir capacity in 2011 at design maximum pool of 6,124 ft above NAVD 88 was 333,500 acre-ft.

Idaho↗

Groundwater-level elevations in the Denver Basin bedrock aquifers and Upper Black Squirrel Creek alluvial aquifer, El Paso County, Colorado, 2021–24

El Paso County is the second-most populous county in Colorado and is projected to grow another 15 percent by 2030. Within El Paso County is the Upper Black Squirrel Creek Designated Groundwater Basin (Black Squirrel Basin), an area where surface water is scarce and water users rely primarily on groundwater from five different aquifers (the Upper Black Squirrel Creek alluvial aquifer and four bedrock aquifers within the Denver Basin aquifer system: the lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) to meet their needs. Currently (2024), land within the Upper Black Squirrel Creek Basin is primarily used for rural grazing and agriculture; however, municipal development is ongoing. In 2021, the U.S. Geological Survey, in cooperation with the Upper Black Squirrel Creek Ground Water Management District, began a study to establish a baseline dataset and assess the groundwater resources of the aquifers within the Black Squirrel Basin. A network of 39 wells was established in 2021; discrete groundwater-level measurements were made bimonthly. Nine of the 39 wells were equipped with pressure transducers to record hourly groundwater-level data. Seven wells had statistically significant seasonal trends, and trends at 3 wells were negative. For the discrete data, 16 wells had a significant trend for the study period, and 4 wells had negative trends. For the time-series data, 8 wells had significant trends, and 3 wells had negative trends. Potentiometric surface maps were created for this study using discrete, static groundwater levels measured in April 2023. These maps showed the estimated groundwater flow direction from the north-northwest to the south-southeast in the alluvial aquifer and from the northwest to the east-southeast for the lower Dawson and Denver aquifer wells. This study indicates the potential benefit of monitoring wells in the areas near municipal pumping. Additional monitoring could lead to a better understanding of connectivity between aquifers and be an important tool for assessing long-term sustainability of groundwater use.

Colorado↗

Soil moisture product validation good practices protocol, version 1.0

The Global Climate Observing System (GCOS) included soil moisture in the list of Essential Climate Variables (ECVs) to express its important role in Earth’s water, energy and carbon cycle. Soil moisture has a major impact on agriculture, land surface hydrology, weather, and climate forecasting. This document is a community-based effort to provide recommendations on good practices for the validation of global to regional soil moisture products. Definitions are given and metrics to adequately describe the quality of soil moisture products are presented. Spaceborne active and passive microwave sensors are listed with their characteristics, and the typical soil moisture retrieval methods are explained, including dielectric mixing models and optical methods. Spatial scaling, root zone soil moisture estimation, and operational implementations are addressed, as these issues continue to gain more and more importance. Standard and advanced in situ measurement techniques are described as well as sensor calibration, spatial representativity, sampling strategies, and the benefit of airborne campaigns.The community has agreed upon the utilization of the International Soil Moisture Network (ISMN) as the main online repository for in situ soil moisture measurements. Different validation methods such as ground-based validation, satellite product intercomparison, and time series analyses are presented. We provide strategies to evaluate the long-term quality of soil moisture products, and give advice on how to handle typical temporal and spatial-scale mismatches and how to effectively report validation results. Moreover, the benefit of blind tests is discussed to gain objective validation results. We encourage data providers, scientists and practitioners to use this Soil Moisture Product Validation Good Practices Protocol to provide, analyze, and improve high quality Earth Observation results.

Report↗

Incorporating uncertainty into high-resolution groundwater supply models

Groundwater modeling is a useful tool for evaluating whether an acquifer system is capable of supporting groundwater withdrawals over long periods of time and what effect, if any, such activity will have on the regional flow dynamics as well as on specific public water, agricultural and industrial supplies. An overview is given of an ongoing groundwater modeling study of the Chicot Aquifer in southwestern Louisiana where a low-resolution groundwater model is being used to study the regional flow in the Chicot acquifer and to provide boundary conditions for higher-resolution inset models created using telescopic mesh refinement (TMR).

Conference Paper↗

Central Valley Hydrologic Model version 2 (CVHM2): Decision support tool for groundwater and land subsidence management

The San Joaquin Valley (SJV) of California is one of the world’s most productive agricultural regions. Reliance on groundwater has led to some of the greatest rates of human-induced land subsidence in the world in the 20th century, as well as more recently. The United States Geological Survey (USGS) has recently developed an integrated surface–subsurface hydrologic model, the Central Valley Hydrologic Model 2 (CVHM2), that represents the major components of the hydrologic system of California’s Central Valley. In this study, CVHM2 was applied as a decision support tool while simulating various management strategies to mitigate the land subsidence caused by the extraction of groundwater. CVHM2 was extended through to 2073 and applied to simulate management scenarios in terms of three primary drivers and their impact on subsidence along the Delta–Mendota Canal (DMC), a critical piece of infrastructure in the western SJV. The drivers considered were agricultural water demands, managed aquifer recharge (MAR), and changes in future climate. The results show that future subsidence is most sensitive to water demands, second most sensitive to future changes in climate, and relatively insensitive to MAR when it is applied as a surface application in the western SJV. However, we demonstrate via proof-of-concept scenarios that the MAR is capable of arresting subsidence when implemented via injection below the Corcoran Clay Member of the Tulare Formation instead of as a surface application. We also examine the uncertainty that is the result of climate variability and how to use the tool to identify the most appropriate strategies to constrain future subsidence to acceptable levels.

California↗

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States↗

Calculating crop water requirement satisfaction in the West Africa Sahel with remotely sensed soil moisture

The Soil Moisture Active Passive (SMAP) mission will provide soil moisture data with unprecedented accuracy, resolution, and coverage, enabling models to better track agricultural drought and estimate yields. In turn, this information can be used to shape policy related to food and water from commodity markets to humanitarian relief efforts. New data alone, however, do not translate to improvements in drought and yield forecasts. New tools will be needed to transform SMAP data into agriculturally meaningful products. The objective of this study is to evaluate the possibility and efficiency of replacing the rainfall-derived soil moisture component of a crop water stress index with SMAP data. The approach is demonstrated with 0.1°-resolution, ~10-day microwave soil moisture from the European Space Agency and simulated soil moisture from the Famine Early Warning Systems Network Land Data Assimilation System. Over a West Africa domain, the approach is evaluated by comparing the different soil moisture estimates and their resulting Water Requirement Satisfaction Index values from 2000 to 2010. This study highlights how the ensemble of indices performs during wet versus dry years, over different land-cover types, and the correlation with national-level millet yields. The new approach is a feasible and useful way to quantitatively assess how satellite-derived rainfall and soil moisture track agricultural water deficits. Given the importance of soil moisture in many applications, ranging from agriculture to public health to fire, this study should inspire other modeling communities to reformulate existing tools to take advantage of SMAP data.

Journal of Hydrometeorology↗

Ground-water quality and vulnerability to contamination in selected agricultural areas of southeastern Michigan, northwestern Ohio, and northeastern Indiana

Ground-water quality was assessed in the northeastern part of the Corn Belt, where tile-drained row crops are underlain by fractured glacial till. Data were collected from 30 shallow monitor wells and 18 co-located domestic wells as part of the U.S. Geological Survey’s National Water- Quality Assessment in the Lake Erie-Lake St. Clair Basin. Pesticides or pesticide degradates were detected in 41 percent of the monitor wells and 6 percent of the domestic wells. The pesticides detected closely correspond to those most heavily applied—herbicides used on corn and soybeans. Pesticide degradates were detected three times more frequently, and at higher concentrations, than were parent compounds. No pesticide concentration exceeded a USEPA Maximum Contaminant Level (MCL), but MCL’s have not been established for 9 of the 11 compounds detected. Thirty-seven percent of monitor-well samples had nitrate concentrations indicative of human influences such as fertilizer, manure or septic systems. Nitrate was the only chemical constituent detected at a concentration greater than an MCL. The MCL was exceeded in 7 percent of samples from monitor wells which were too shallow to be used as a source of drinking water. Pesticide and nitrate concentrations in the study area are low relative to other agricultural areas of the Nation. Several authors have suggested that ground water in parts of the Upper Midwest is minimally contaminated because it is protected by the surficial glacial till or tile drains. These ideas are examined in light of the relations between concentration, well depth, and groundwater age in the study area. Most of the shallow ground water is hydraulically connected to the land surface, based on the observations that 83 percent of waters from monitor wells were recharged after 1953, and 57 percent contained a pesticide or an elevated nitrate concentration. Fractures or sand-and-gravel stringers within the till are the probable pathways. In some areas, deeper parts of the groundwater- flow system are also hydraulically connected to the land surface. Almost half the waters from wells 50 to 100 feet deep were recharged after 1953. Anthropogenic constituents were detected in samples from three domestic wells 60 to 121 feet deep, in areas where the till is relatively coarse-grained. The hydrogeologic system has several geochemical characteristics conducive to transformations or sorption of nitrate or pesticides: (1) the till is clay-rich, has a high organic-carbon content, and contains an abundance of pyrite-rich shale fragments, (2) the ground water has low dissolved- oxygen concentrations, and (3) iron and manganese oxides and oxyhyroxides line the faces of fractures in the unsaturated zone. Although the aquifer system appears be protected from contamination in some areas, the fact that the surficial till is heterogeneous and of variable thickness suggests that the protection is not uniform. The protection can be breached by fractures or sand-and-gravel stringers, which are apparent in core samples but not noted on domestic-well logs.

Indiana, Michigan, Ohio↗