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At least 721 records · Page 40Linked to original sources

USGS2012

An alternative process model of preferential contaminant travel times in the unsaturated zone: Application to Rainier Mesa and Shoshone Mountain, Nevada

Simulating contaminant transport in unsaturated zones with sparse hydraulic property information is a difficult, yet common, problem. When contaminant transport may occur via preferential flow, simple modeling approaches can provide predictions of interest, such as the first arrival of contaminant, with minimal site characterization. The conceptual model for unsaturated zone flow at Rainier Mesa and Shoshone Mountain, Nevada National Security Site, establishes the possibility of preferential flow through lithologies between potential radionuclide sources and the saturated zone. After identifying preferential flow as a possible contaminant transport process, we apply a simple model to estimate first arrival times for conservatively transported radionuclides to reach the saturated zone. Simulated preferential flow travel times at Rainier Mesa are tens to hundreds of years for non-ponded water sources and 1 to 2 months for continuously ponded water sources; first arrival times are approximately twice as long at Shoshone Mountain. These first arrival time results should then be viewed as a worst-case scenario but not necessarily as a timescale for a groundwater-contamination hazard, because concentrations may be very low. The alternative approach demonstrated here for estimating travel times can be useful in situations where predictions are needed by managers for the fastest arrival of contaminants, yet budgetary or time constraints preclude more rigorous analysis, and when additional model estimates are needed for comparison (i.e., model abstraction).

Nevada↗

USGS2010

Diatom changes in two Uinta mountain lakes, Utah, USA: Responses to anthropogenic and natural atmospheric inputs

Diatom assemblages in sediments from two subalpine lakes in the Uinta Mountains, Utah, show asynchronous changes that are related to both anthropogenic and natural inputs of dust. These lakes are downwind of sources of atmospheric inputs originating from mining, industrial, urban, agricultural and natural sources that are distributed within tens to hundreds of kilometers west and south of the Uinta Mountains. Sediment cores were retrieved from Marshall and Hidden lakes to determine the impacts of atmospheric pollution, especially metals. Paleolimnological techniques, including elemental analyses and 210 Pb and 239+240 Pu dating, indicate that both lakes began receiving eolian inputs from anthropogenic sources in the late 1800s with the greatest increases occurring after the early 1900s. Over the last century, sediments in Marshall Lake, which is closer to the Wasatch Front and receives more precipitation than Hidden Lake, received twice the concentrations of metals and phosphorus as Hidden Lake. Comparison of diatom and elemental data reveals coeval changes in geochemistry and diatom assemblages at Marshall Lake, but not at Hidden Lake; however, a major shift in diatom assemblages occurs at Hidden Lake in the seventeenth century. The change in diatoms at Marshall Lake is marked by the near disappearance of Cyclotella stelligera and C. pseudostelligera and an increase in benthic, metal-tolerant diatoms. This change is similar to changes in other lakes that have been attributed to metal pollution. The marked change in diatom assemblages at Hidden Lake indicates a shift in lake-water pH from somewhat acidic to circumneutral. We hypothesize that this change in pH is related to drought-induced changes in input of carbonate-rich desert dust.

Utah↗

USGS1980

The distribution and mobility of uranium in glassy and zeolitized tuff, Keg Mountain area, Utah, U.S.A.

The distribution and mobility of uranium in a diagenetically altered, 8 Ma old tuff in the Keg Mountain area, Utah, are modelled in this study. The modelling represents an improvement over similar earlier studies in that it: (1) considers a large number of samples (76) collected with good geologic control and exhibiting a wide range of alteration; (2) includes radiometric data for Th, K and RaeU (radium equivalent uranium) as well as U; (3) considers mineralogic and trace-element data for the same samples; and (4) analyzes the mineral and chemical covariation by multivariate statistical methods. The variation of U in the tuff is controlled mainly by its primary abundance in glass and by the relative abundance of non-uraniferous detritus and uraniferous accessory minerals. Alteration of glass to zeolite, even though extensive, caused no large or systematic change in the bulk concentration of U in the tuff. Some redistribution of U during diagenesis is indicated by association of U with minor alteration products such as opal and hydrous Fe-Mn oxide minerals. Isotopic studies indicate that the zeolitized tuff has been open to migration of U decay products during the last 0.8 Ma. The tuff of Keg Mountain has not lost a statistically detectable fraction of its original U, even though it has a high (??? 9 ppm) trace U content and has been extensively altered to zeolite. Similar studies in a variety of geological environments are required in order to identify the particular combination of conditions most favorable for liberation and migration of U from tuffs. ?? 1980.

Chemical Geology↗

USGS1969

Uranium, thorium, and lead systematics in Granite Mountains, Wyoming

Uranium, thorium and lead concentrations and isotopic compositions were determined on total rocks and a feldspar sample from widely separated parts of the Granite Mountains in central Wyoming. Linear relations defined by 206 Pb/ 204 Pb − 207 Pb/ 204 Pb and 208 Pb/ 204 Pb − 232 Th/ 204 Pb for the total rock samples define 2.8 billion-year isochrons. In contrast, 238 U/ 206 Pb ages are anomalously old by a factor of at least four. The low 238 U/ 204 Pb values, coupled with the radiogenic 206 Pb/ 204 Pb and radiogenic 207 Pb/ 204 Pb ratios, indicate that contents of uranium in near-surface rocks would have had to have been considerably greater than those presently observed to have generated the radiogenic lead. It is possible that more than 10 11 kg of uranium has been removed from the Granite Mountains, and the most feasible interpretation is that most of this uranium was leached from near-surface rocks at some time during the Cenozoic, thus providing a major source for the uranium deposits in the central Wyoming basins.

Wyoming↗

USGS1988

Pb, Sr, and Nd isotopic compositions of a suite of Late Archean, igneous rocks, eastern Beartooth Mountains: Implications for crust-mantle evolution

A series of compositionally diverse, Late Archean rocks (2.74–2.79 Ga old) from the eastern Beartooth Mountains, Montana and Wyoming, U.S.A., have the same initial Pb, Sr, and Nd isotopic ratios. Lead and Sr initial ratios are higher and Nd initial ratios lower than would be expected for rocks derived from model mantle sources and strongly indicate the involvement of an older crustal reservoir in the genesis of these rocks. Crustal contamination during emplacement can be ruled out for a variety of reasons. Instead a model involving subduction of continental detritus and contamination of the overlying mantle as is often proposed for modern subduction environments is preferred. This contaminated mantle would have all the isotopic characteristics of mantle enriched by internal mantle metasomatism but would require no long-term growth or changes in parent to daughter element ratios. This contaminated mantle would make a good source for some of the Cenozoic mafic volcanics of the Columbia River, Snake River Plain, and Yellowstone volcanic fields that are proposed to come from ancient, enriched lithospheric mantle. The isotopic characteristics of the 2.70 Ga old Stillwater Complex are a perfect match for the proposed contaminated mantle which provides an alternative to crustal contamination during emplacement. The Pb isotopic characteristics of the Late Archean rocks of the eastern Beartooth Mountains are similar to those of other Late Archean rocks of the Wyoming Province and suggest that Early Archean, upper crustal rocks were common in this terrane. The isotopic signatures of Late Archean rocks in the Wyoming Province are distinctive from those of other Archean cratons in North America which are dominated by a MORB-like, Archean mantle source (Superior Province) and/or a long-term depleted crustal source (Greenland).

Earth and Planetary Science Letters↗

USGS1995

40Ar/39Ar and 18O/16O studies of the Chegem ash-flow caldera and the Eldjurta Granite: Cooling of two late Pliocene igneous bodies in the Greater Caucasus Mountains, Russia

Volcanic and intrusive rocks of the Chegem caldera and the nearby Eldjurta (Eldzhurtinskiy) Granite record a late Pliocene episode of silicic magmatism in the north-central Caucasus Mountains. Surface exposures, created by the recent rapid uplift and erosion of the Caucasus Mountains, span a 2 km vertical section of Chegem caldera fill and 1150 m of the Eldjurta Granite; cored mineral-exploration drillholes in the Eldjurta Granite extend the sampling to a depth of 4 km. The unique sampling range available in these two young igneous bodies affords an excellent opportunity to study their denudation and cooling histories, which we examine by means of 40 Ar/ 39 Ar and 18 O/ 16 O measurements on an extensive sample suite. Total-fusion biotite and sanidine ages from eight Chegem Tuff samples, both intracaldera and outflow, are analytically indistinguishable with a weighted mean of 2.82 ± 0.02 Ma. A cross-cutting granodiorite porphyry intrusion has a sanidine total fusion age of 2.84 ± 0.03 Ma, and whole-rock incremental heating of a post-caldera andesite flow, which caps the caldera fill, yields an age of 2.82 ± 0.02 Ma. Thus, caldera formation and post-caldera resurgence and volcanism all occurred within a very short time (< 50,000 yr). Biotite total-fusion ages of ten Eldjurta Granite samples, including seven from ∼ 500 m intervals in the 4 km deep drillhole, show a systematic linear decrease in age with depth from 1.90 Ma near the roof contact of the granite to 1.56 Ma at a depth of 3700 m. Assuming these ages were set at the same temperature, this age/depth gradient implies an isotherm migration rate of 13 mm/yr between 1.90 and 1.56 Ma. This migration rate is due to a combination of rapid denudation and downward relaxation of isotherms, with cooling rates between 200 and 500°C/Ma during this period. Oxygen isotopic compositions of quartz, K-feldspar, plagioclase and biotite from the drillhole samples below the 800 m depth are fairly uniform and record primary igneous δ 18 O values with little evidence for subsolidus hydrothermal activity. However, in surface outcrop samples and in the shallowest drillhole sample, mineral δ 18 O values have been lowered by up to 3‰ by interaction with an external (meteoric-hydrothermal?) fluid. The primary mineral δ 18 O values of the Eldjurta Granite are distinctly higher than the corresponding phenocryst δ 18 O values in the Chegem volcanic rocks, indicating that the two bodies evolved as separxate magma batches.

Caucasus Mountains, Chegem Caldera↗

USGS1994

Anatexis, hybridization and the modification of ancient crust: Mesozoic plutonism in the Old Woman Mountains area, California

A compositionally expanded array of granitic (s.l.) magmas intruded the > 2 Ga crust of the Old Woman Mountains area between 160 and 70 Ma. These magmas were emplaced near the eastern (inland) edge of the Jurassic/Cretaceous arcs of western North America, in an area where magma flux, especially during the Jurassic, was considerably lower than to the west. The Jurassic intrusives and over half of the Cretaceous intrusives are predominantly metaluminous and variable in composition; a major Cretaceous suite comprises only peraluminous monzogranite. Only the Jurassic intrusions show clear evidence for the presence of mafic liquids. All units, including the most mafic rocks, reveal isotopic evidence for a significant crustal component. However, none of the Mesozoic intrusives matches in isotopic composition either average pre-intrusion crust or any major unit of the exposed crust. Elemental inconsistencies also preclude closed system derivation from exposed crust. Emplacement of these magmas, which doubled the volume of the mid- to upper crust, did not dramatically change its elemental composition. It did, however, affect its Nd and especially Sr isotopic composition and modify some of the distinctive aspects of the elemental chemistry. We propose that Jurassic magmatism was open-system, with a major influx of mantle-derived mafic magma interacting strongly with the ancient crust. Mesozoic crustal thickening may have led to closed-system crustal melting by the Late Cretaceous, but the deep crust had been profoundly modified by earlier Mesozoic hybridization so that crustal melts did not simply reflect the original crustal composition. The clear evidence for a crustal component in magmas of the Old Woman Mountains area may not indicate any fundamental differences from the processes at work elsewhere in this or other magmatic arcs where the role of pre-existing crust is less certain. Rather, a compositionally distinctive, very old crust may simply have yielded a more readily identifiable crustal fingerprint. The same processes that were involved here-mafic magma influx, hybridization, and remelting of hybridized crust-are likely to be typical of arc settings. ?? 1994.

LITHOS↗

USGS1989

Airborne imaging spectrometer data of the Ruby Mountains, Montana: Mineral discrimination using relative absorption band-depth images

Airborne imaging spectrometer data collected in the near-infrared (1.2–2.4 μm) wavelength range were used to study the spectral expression of metamorphic minerals and rocks in the Ruby Mountains of southwestern Montana. The data were analyzed by using a new data enhancement procedure—the construction of relative absorption band-depth (RBD) images. RBD images, like bandratio images, are designed to detect diagnostic mineral absorption features, while minimizing reflectance variations related to topographic slope and albedo differences. To produce an RBD image, several data channels near an absorption band shoulder are summed and then divided by the sum of several channels located near the band minimum. RBD images are both highly specific and sensitive to the presence of particular mineral absorption features. Further, the technique does not distort or subdue spectral features as sometimes occurs when using other data normalization methods. By using RBD images, a number of rock and soil units were distinguished in the Ruby Mountains including weathered quartz - feldspar pegmatites, marbles of several compositions, and soils developed over poorly exposed mica schists. The RBD technique is especially well suited for detecting weak near-infrared spectral features produced by soils, which may permit improved mapping of subtle lithologic and structural details in semiarid terrains. The observation of soils rich in talc, an important industrial commodity in the study area, also indicates that RBD images may be useful for mineral exploration.

Montana↗

USGS1981

Contemporary doming of the Adirondack Mountains: Further evidence from releveling

The Adirondack Mountains constitute an anomalously large, domical uplift on the Appalachian foreland. The dome has a NNE—SSW axis about 190 km long, and an east—west dimension of about 140 km. It has a structural relief of at least 1600 m, and a local topographic relief of up to 1200 m. First-order leveling in 1955, and again in 1973 along a north—south line at the eastern margin of the Adirondack shows an uplift rate of 2.2 mm/yr at the latitude of the center of the dome and a subsidence rate of 2.8 mm/yr at the northern end of the line near the Canadian border. The net amount of arching along this releveled line is 9 cm ± 2 cm (Isachsen, 1975). To test the idea that this arching represented an “edge effect” of contemporary doming of the Adirondacks as a whole, the National Geodetic Survey was encouraged to relevel a 1931 north—south line between Utica and Fort Covington (near the Canadian border) which crosses the center of the dome. The releveling showed that the mountain mass is undergoing contemporary domical uplift at a rate which reaches 3.7 mm/yr near the center of the dome (compare with 1 mm/yr for the Swiss Alps). Three other releveled lines in the area support this conclusion.

New York↗

USGS1989

Rocky Mountain Tertiary coal-basin models and their applicability to some world basins

Tertiary intermontane basins in the Rocky Mountain region of the United States contain large amounts of coal resources. The first major type of Tertiary coal basin is closed and lake-dominated, either mud-rich (e.g., North Park Basin, Colorado) or mud plus carbonate (e.g., Medicine Lodge Basin, Montana), which are both infilled by deltas. The second major type of Tertiary coal basin is open and characterized by a preponderance of sediments that were deposited by flow-through fluvial systems (e.g., Raton Basin, Colorado and New Mexico, and Powder River Basin, Wyoming and Montana). The setting for the formation of these coals varies with the type of basin sedimentation, paleotectonism, and paleoclimate. The mud-rich lake-dominated closed basin (transpressional paleotectonism and warm, humid paleoclimate), where infilled by sandy “Gilbert-type” deltas, contains thick coals (low ash and low sulfur) formed in swamps of the prograding fluvial systems. The mud- and carbonate-rich lake-dominated closed basin is infilled by carbonate precipitates plus coarse-grained fan deltas and fine-grained deltas. Here, thin coals (high ash and high sulfur) formed in swamps of the fine-grained deltas. The coarse-clastic, open basins (compressional paleotectonism and warm, paratropical paleoclimate) associated with flow-through fluvial systems contain moderately to anomalously thick coals (high to low ash and low sulfur) formed in swamps developed in intermittently abandoned portions of the fluvial systems. These coal development patterns from the Tertiary Rocky Mountain basins, although occurring in completely different paleotectonic settings, are similar to that found in the Tertiary, Cretaceous, and Permian intermontane coal basins in China, New Zealand, and India.

International Journal of Coal Geology↗

USGS1990

Flexure and faulting of sedimentary host rocks during growth of igneous domes, Henry Mountains, Utah

A sequence of sedimentary rocks about 4 km thick was bent, stretched and uplifted during the growth of three igneous domes in the southern Henry Mountains. Mount Holmes, Mount Ellsworth and Mount Hillers are all about 12 km in diameter, but the amplitudes of their domes are about 1.2, 1.85 and 3.0 km, respectively. These mountains record successive stages in the inflation of near-surface diorite intrusions that are probably laccolithic in origin. The host rocks deformed along networks of outcrop-scale faults, or deformation bands, marked by crushed grains, consolidation of the porous sandstone and small displacements of sedimentary beds. Zones of deformation bands oriented parallel to the beds and formation contacts subdivided the overburden into thin mechanical layers that slipped over one another during doming.

Journal of Structural Geology↗

USGS1977

Geochemistry of Precambrian mafic dikes, central Bighorn Mountains, Wyoming, U.S.A.

Precambrian quartz dolerites and metadolerites of the central Bighorn Mountains form dikes that intrude a Precambrian metamorphic and igneous terrane typical of the Laramide uplifts of the middle Rocky Mountains. They have a restricted range of major- and trace-element compositions and are typical of basalts in the middle stages of tholeiitic fractionation. Fractionation in the direction of iron enrichment occurred by removal of plagioclase. Average element concentrations of the two groups are nearly identical to one another, are comparable to those in Archean metabasalts from numerous shield areas, and are intermediate between those of modern oceanic tholeiites and continental tholeiites. These average concentrations suggest a depth of magma generation and thickness of crust intermediate between those for the oceanic and continental environments.

Wyoming↗

USGS1987

Development of the Archean crust in the medina mountain area, Wind River Range, Wyoming (U.S.A.)

Evidence for an extensive Archean crustal history in the Wind River Range is preserved in the Medina Mountain area in the west-central part of the range. The oldest rocks in the area are metasedimentary, mafic, and ultramafic blocks in a migmatite host. The supracrustal rocks of the Medina Mountain area (MMS) are folded into the migmatites, and include semi-pelitic and pelitic gneisses, and mafic rocks of probable volcanic origin. Mafic dikes intrude the older migmatites but not the MMS, suggesting that the MMS are distinctly younger than the supracrustal rocks in the migmatites. The migmatites and the MMS were engulfed by the late Archean granite of the Bridger, Louis Lake, and Bears Ears batholiths, which constitutes the dominant rock of the Wind River Range. Isotopic data available for the area include Nd crustal residence ages from the MMS which indicate that continental crust existed in the area at or before 3.4 Ga, but the age of the older supracrustal sequence is not yet known. The upper age of the MMS is limited by a 2.7 Ga Rb-Sr age of the Bridger batholith, which was emplaced during the waning stages of the last regional metamorphism. The post-tectonic Louis Lake and Bears Ears batholiths have ages of 2.6 and 2.5 Ga, respectively (Stuckless et al., 1985). At least three metamorphic events are recorded in the area: (1) an early regional granulite event (M 1 ) that affected only the older inclusions within the migmatites, (2) a second regional amphibolite event (M 2 ) that locally reached granulite facies conditions, and (3) a restricted, contact granulite facies event (M 3 ) caused by the intrusion of charnockitic melts associated with the late Archean plutons. Results from cation exchange geobarometers and geothermometers yield unreasonably low pressures and temperatures, suggesting resetting during the long late Archean thermal event.

Wyoming↗

USGS1995

Mountain wetlands: Efficient uranium filters — Potential impacts

Wetlands are common in montane and subalpine settings in the Rocky Mountains, Sierra Nevada, and other mountainous regions of the western U.S. Because they are efficient filters, many contain anomalous concentrations of uranium and other metals. Sorption by organic matter, complexing of the uranyl ion, (UO 2 ) 2+, with humic and fulvic acids, and action by bacteria has produced geochemical enrichment factors greater than 10000 to 1 between peat and uranium-bearing waters. Sediments in 67 of 145 Colorado wetlands sampled by the U.S. Geological Survey contain moderate (20 ppm) or greater concentrations of uranium (some as high as 3 000 ppm) based on dry weight. The proposed maximum contaminant level (MCL) for uranium in drinking water is 20 μg/1 or 20 ppb. By comparison, sediments in many of these wetlands contain 3 to 5 orders of magnitude more uranium than the proposed MCL. Wetlands near the workings of old mines (widespread in Colorado and other areas) may be trapping any number of additional metals/elements including Cu, Pb, Zn, As and Ag. Anthropogenic disturbances and natural changes may release uranium and other loosely bound metals presently contained in wetland sediments. Draining of wetlands with resulting oxidation of organic-rich sediments, acidification, and other environmental and geochemical changes may free relatively high concentrations of metals that have accumulated for thousands of years in the organic-rich sediments. Destruction of wetlands eliminates the natural filtration function which serves to protect water quality.

Ecological Engineering↗

USGS1994

Simulation of gas phase transport of carbon-14 at Yucca Mountain, Nevada, USA

We have simulated gas phase transport of Carbon-14 at Yucca Mountain, Nevada. Three models were established to calculate travel time of Carbon-14 from the potential repository to the mountain surface: a geochemical model for retardation factors, a coupled gas-flow and heat transfer model for temperature and gas flow fields, and a particle tracker for travel time calculation. The simulations used three parallel, east-west cross-sections that were taken from the Sandia National Laboratories Interactive Graphics Information System (IGIS). Assuming that the repository is filled with 30- year-old waste at an initial areal power density of 57 kw/acre, we found that repository temperatures remain above 60??C for more than 10,000 years. For a tuff permeability of 10-7 cm2, Carbon-14 travel times to the surface are mostly less than 1,000 years, for particles starting at any time within the first 10,000 years. If the tuff permeability is 10-8 cm2, however, Carbon- 14 travel times to the surface range from 3,000 to 12,000 years, for particle starting within the 10,000 years.

Waste Management↗

USGS2008

Thermal history of the unsaturated zone at Yucca Mountain, Nevada, USA

Secondary calcite, silica and minor amounts of fluorite deposited in fractures and cavities record the chemistry, temperatures, and timing of past fluid movement in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a high-level radioactive waste repository. The distribution and geochemistry of these deposits are consistent with low-temperature precipitation from meteoric waters that infiltrated at the surface and percolated down through the unsaturated zone. However, the discovery of fluid inclusions in calcite with homogenization temperatures (Th) up to ???80 ??C was construed by some scientists as strong evidence for hydrothermal deposition. This paper reports the results of investigations to test the hypothesis of hydrothermal deposition and to determine the temperature and timing of secondary mineral deposition. Mineral precipitation temperatures in the unsaturated zone are estimated from calcite- and fluorite-hosted fluid inclusions and calcite ??18O values, and depositional timing is constrained by the 207Pb/235U ages of chalcedony or opal in the deposits. Fluid inclusion Th from 50 samples of calcite and four samples of fluorite range from ???35 to ???90 ??C. Calcite ??18O values range from ???0 to ???22??? (SMOW) but most fall between 12 and 20???. The highest Th and the lowest ??18O values are found in the older calcite. Calcite Th and ??18O values indicate that most calcite precipitated from water with ??18O values between -13 and -7???, similar to modern meteoric waters. Twenty-two 207Pb/235U ages of chalcedony or opal that generally postdate elevated depositional temperatures range from ???9.5 to 1.9 Ma. New and published 207Pb/235U and 230Th/Uages coupled with the Th values and estimates of temperature from calcite ??18O values indicate that maximum unsaturated zone temperatures probably predate ???10 Ma and that the unsaturated zone had cooled to near-present-day temperatures (24-26 ??C at a depth of 250 m) by 2-4 Ma. The evidence of elevated temperatures persisting in ash flow tuffs adjacent to parent calderas for as much as ???8 Ma is a new finding, but consistent with thermal modeling. Simulations using the HEAT code demonstrate that prolonged cooling of the unsaturated zone is consistent with magmatic heat inputs and deep-seated (sub-water table) hydrothermal activity generated by the large magma body ???8 km to the north that produced the 15-11 Ma ash flows and ash falls that make up Yucca Mountain. The evidence discussed in this and preceding papers strongly supports unsaturated zone deposition of the secondary minerals from descending meteoric waters. Although depositional temperatures reflect conductive (and possibly vapor-phase convective) heating of the unsaturated zone related to regional magmatic sources until perhaps 6 Ma, depositional conditions similar to the present-day unsaturated zone have prevailed for at least the past 2-4 Ma.

Applied Geochemistry↗

USGS2009

Application of iron and zinc isotopes to track the sources and mechanisms of metal loading in a mountain watershed

Here the hydrogeochemical constraints of a tracer dilution study are combined with Fe and Zn isotopic measurements to pinpoint metal loading sources and attenuation mechanisms in an alpine watershed impacted by acid mine drainage. In the tested mountain catchment, δ 56 Fe and δ 66 Zn isotopic signatures of filtered stream water samples varied by ∼3.5‰ and 0.4‰, respectively. The inherent differences in the aqueous geochemistry of Fe and Zn provided complimentary isotopic information. For example, variations in δ 56 Fe were linked to redox and precipitation reactions occurring in the stream, while changes in δ 66 Zn were indicative of conservative mixing of different Zn sources. Fen environments contributed distinctively light dissolved Fe (<−2.0‰) and isotopically heavy suspended Fe precipitates to the watershed, while Zn from the fen was isotopically heavy (>+0.4‰). Acidic drainage from mine wastes contributed heavier dissolved Fe (∼+0.5‰) and lighter Zn (∼+0.2‰) isotopes relative to the fen. Upwelling of Fe-rich groundwater near the mouth of the catchment was the major source of Fe ( δ 56 Fe ∼ 0‰) leaving the watershed in surface flow, while runoff from mining wastes was the major source of Zn. The results suggest that given a strong framework for interpretation, Fe and Zn isotopes are useful tools for identifying and tracking metal sources and attenuation mechanisms in mountain watersheds.

Applied Geochemistry↗

USGS2009

Feldspar dissolution rates in the Topopah Spring Tuff, Yucca Mountain, Nevada

Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (∼60 wt%) and quartz polymorphs (∼35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10 −16 to 10 −17 mol s −1 kg tuff −1 with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10 −15 to 10 −16 mol s −1 kg tuff −1 for percolation fluxes of 15 mm a −1 and 1 mm a −1 , respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a −1 or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (∼50 mg L −1 ) may inhibit feldspar dissolution.

Nevada↗