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Sources and occurrence of chloroform and other trihalomethanes in drinking-water supply wells in the United States, 1986-2001

Chloroform and three other trihalomethanes (THMs)--bromodichloromethane, dibromochloromethane, and bromoform--are disinfection by-products commonly produced during the chlorination of water and wastewater. Samples of untreated ground water from drinking-water supply wells (1,096 public and 2,400 domestic wells) were analyzed for THMs and other volatile organic compounds (VOCs) during 1986-2001, or compiled, as part of the U.S. Geological Survey's National Water-Quality Assessment Program. This report provides a summary of potential sources of THMs and of the occurrence and geographical distribution of THMs in samples from public and domestic wells. Evidence for an anthropogenic source of THMs and implications for future research also are presented. Potential sources of THMs to both public and domestic wells include the discharge of chlorinated drinking water and wastewater that may be intentional or inadvertent. Intentional discharge includes the use of municipally supplied chlorinated water to irrigate lawns, golf courses, parks, gardens, and other areas; the use of septic systems; or the regulated discharge of chlorinated wastewater to surface waters or ground-water recharge facilities. Inadvertent discharge includes leakage of chlorinated water from swimming pools, spas, or distribution systems for drinking water or wastewater sewers. Statistical analyses indicate that population density, the percentage of urban land, and the number of Resource Conservation and Recovery Act hazardous-waste facilities near sampled wells are significantly associated with the probability of detection of chloroform, especially for public wells. Domestic wells may have several other sources of THMs, including the practice of well disinfection through shock chlorination, laundry wastewater containing bleach, and septic system effluent. Chloroform was the most frequently detected VOC in samples from drinking-water supply wells (public and domestic wells) in the United States. Although chloroform was detected frequently in samples from public and domestic wells and the other THMs were detected in some samples, no concentrations in samples from either well type exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level of 80 micrograms per liter for total THMs. Chloroform was detected in public well samples almost twice as frequently (11 percent) as in domestic well samples (5 percent). The other three THMs also were detected more frequently in public well samples than in domestic well samples. This detection pattern may be attributed to public wells having a higher pumping capacity than domestic wells. The higher capacity wells create a larger capture zone that potentially intercepts more urban and other land uses and associated point and nonpoint sources of contamination than the smaller capacity domestic wells. THM detection frequencies in domestic well samples show a pattern of decreasing frequency with increasing bromide content, that is in the order: chloroform > bromodichloromethane >= dibromochloromethane >= bromoform. This same pattern has been documented in studies of water chlorination, indicating that an important source of chloroform and other THMs in drinking-water supply wells may be the recycling of chlorinated water and wastewater. Mixtures of THMs commonly occur in public well samples, and the most frequently occurring are combinations of the brominated THMs. These THMs have limited industrial production, few natural sources, and small or no reported direct releases to the environment. Therefore, industrial, commercial, or natural sources are not likely sources of the brominated THMs in public and domestic well samples. The THM detection frequency pattern, the co-occurrence of brominated THMs, and other lines of evidence indicate that the recycling of water with a history of chlorination is an important source of these compounds in samples from drinking-water supply wells.

Scientific Investigations Report↗

Water use in the Apalachicola-Chattahoochee-Flint River Basin, Alabama, Florida, and Georgia, 2010, and water-use trends, 1985-2010

The Apalachicola-Chattahoochee-Flint (ACF) River Basin encompasses about 20,230 square miles in parts of Alabama, Florida, and Georgia. Increasing population growth and agricultural production from the 1970s to 2010 has prompted increases in water-resources development and substantially increased water demand in the basin. Since the 1980s, Alabama, Florida, Georgia, and the U.S. Army Corps of Engineers are parties to litigation concerning water management in the ACF River Basin. Estimating the 2010 water use in the ACF River Basin is one aspect of a multipart water resources study on the ACF River Basin that began in 2011. This ACF River Basin study is one focus area of the U.S. Geological Survey’s National Water Census program. The 2010 water-use estimates for the ACF River Basin are presented in this report. These estimates include an inventory of the quantity and sources of water withdrawn by category of use and location (State and river basin), and the surface-water returns in the ACF River Basin during 2010. Water-use trends from 1985 to 2010 in the basin also are presented. Offstream water-withdrawal data in the ACF River Basin are presented for each of the following categories: public supply, self-supplied domestic, self-supplied commercial, industrial, mining, agricultural (including crop irrigation, livestock, and aquaculture uses), and thermoelectric-power generation. Water-use data are compiled for the 14 subbasins in the ACF River Basin. For the counties in Alabama, Florida, and Georgia that are partially within the ACF River Basin, data are presented for only that part of the county that lies within the basin. A variety of Federal, State, local, private, and online sources in Alabama, Florida, and Georgia were used to gather surface-water and groundwater withdrawal, surface-water discharges (return flows), and water-use data for the ACF River Basin in 2010. The population in the ACF River Basin was 3.835 million in 2010, a 45-percent increase from the 1990 population of nearly 2.636 million. About 92 percent of the 2010 ACF population resided in Georgia with nearly 75 percent living in the Atlanta metropolitan area. In 2010, 1,645 million gallons per day (Mgal/d) of water were withdrawn from groundwater (576 Mgal/d) and surface-water (1,069 Mgal/d) sources in the ACF River Basin. About 89 percent of the groundwater and 83 percent of the surface-water withdrawals were from Georgia. About 5.6 percent of the total groundwater and nearly 4 percent of the total surface-water withdrawals in the ACF River Basin were from Florida, whereas about 5.3 percent of groundwater and nearly 16 percent of surface water were withdrawn in Alabama. Total water use (withdrawals plus public-supplied deliveries) in the ACF River Basin was 1,593 Mgal/d in 2010. About 56 Mgal/d of water withdrawn in the ACF River Basin was delivered (interbasin transfer) to basins beyond the ACF River Basin. About 564 Mgal/d of water was returned to surface-water bodies in the ACF River Basin. Most of that amount, 63 percent, was treated wastewater discharged by public wastewater-treatment facilities. Water used for once-through cooling by thermoelectric-power facilities accounted for nearly 24 percent of the surface-water returns in the basin. About 70 percent of all water withdrawals in the ACF River Basin were by self-supplied agricultural water users and public water suppliers. Agricultural withdrawals were greatest in the Flint River Basin (501 Mgal/d) with ground-water representing 84 percent of the withdrawals from that basin. Within the Flint River Basin, agricultural withdrawals were greatest in the Lower Flint River and Spring Creek subbasins. About 3.52 million people were served by public water suppliers in the ACF River Basin during 2010, and 88 percent of that population used surface water. Georgia had the largest public-supplied population, representing nearly 93 percent (3.17 million) of the public-supplied population in the ACF River Basin. Public water suppliers served 193,700 people (5.7 percent) in Alabama and 31,880 people in Florida (1.3 percent). Public-supply losses were estimated at 101 Mgal/d. Withdrawals for public supply (483 Mgal/d) and self-supplied industry (141 Mgal/d) were greatest in the Chattahoochee River Basin. Surface water accounted for 96 percent of all withdrawals in the Chattahoochee River Basin. Withdrawals for public supply were greatest in the Upper Chattahoochee River subbasin (366 Mgal/d), whereas self-supplied industrial withdrawals were greatest in the Lower Chattahoochee River subbasin (110 Mgal/d). Water-use trends in the ACF River Basin have varied during the 25 years between 1985 and 2010. Surface-water withdrawals declined between 1985 and 2000, sharply increased in 2000, and declined again between 2000 and 2010. In contrast, groundwater withdrawals increased between 1985 and 2000, declined in 2005, and increased between 2005 and 2010.

Alabama, Florida, Georgia↗

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

California↗

A Retrospective Analysis on the Occurrence of Arsenic in Ground-Water Resources of the United States and Limitations in Drinking-Water-Supply Characterizations

The Safe Drinking Water Act, as amended in 1996, requires the U.S. Environmental Protection Agency (USEPA) to review current drinking-water standards for arsenic, propose a maximum contaminant level for arsenic by January 1, 2000, and issue a final regulation by January, 2001. Quantification of the national occurrence of targeted ranges in arsenic concentration in ground water used for public drinking-water supplies is an important component of USEPA's regulatory process. Data from the U.S. Geological Survey (USGS) National Water Information System (NWIS) were used in a retrospective analysis of arsenic in the ground-water resources of the United States. The analysis augments other existing sources of data on the occurrence of arsenic collected in ground water at public water-supply systems.The USGS, through its District offices and national programs, has been compiling data for many years on arsenic concentrations collected from wells used for public water supply, research, agriculture, industry, and domestic water supply throughout the United States. These data have been collected for a variety of purposes ranging from simple descriptions of the occurrence of arsenic in local or regional ground-water resources to detailed studies on arsenic geochemistry associated with contamination sites. A total of 18,864 sample locations were selected from the USGS NWIS data base regardless of well type, of which 2,262 were taken from public water-supply sources. Samples with non-potable water (dissolved-solids concentration greater than 2,000 milligrams per liter and water temperature greater than 50o Celsius) were not selected for the retrospective analysis and other criteria for selection included the amount and type of ancillary data available for each sample. The 1,528 counties with sufficient data included 76 percent of all large public water-supply systems (serving more than 10,000 people) and 61 percent of all small public water-supply systems (serving more than 1,000 and less than 10,000 people) in the United States. The arsenic data were summarized for the selected counties by associating the arsenic concentrations measured in the ground-water resource with the numbers and sizes of public water-supply systems using ground water in those counties. Targeted arsenic concentrations of 1, 2, 5, 10, 20, and 50 ug/L were exceeded in the ground-water resource associated with 36, 25, 14, 8, 3, and 1 percent respectively of all public water-supply systems accounted for in the analysis.Contributions to uncertainty such as changes in sampling methods and changes in laboratory reporting appear to be less important to the national occurrence estimates than other factors such as temporal variability in arsenic concentrations at a given well, the types of wells sampled, and density and types of sampling locations. In addition, no attempt was made to quantify arsenic concentrations in relation to depth within aquifers. With these qualifications, the USGS data represent the ground-water resource in general and are not restricted to wells currently used for public drinking-water sources. In this way, the broad spatial extent, large number of water samples, and low detection limits used for the USGS data provide a unique source of information to determine where targeted concentrations of arsenic are likely to occur in the ground-water resources within much of the United States.These results indicate USGS data can be effectively used to augment national estimates of arsenic occurrence in the nation's ground-water resources if limitations are recognized. Existing estimates of the occurrence of arsenic in ground water that are used as a source of drinking water can be supplemented with the USGS arsenic concentration data when associated with the public water-supply data base. One such supplementary application is the additional insight gained by establishing relations between arsenic concentration data in the ground-water resource and small public wat

Water-Resources Investigations Report↗

Estimated use of water in Alabama in 2005

Water use in Alabama was about 9,958 million gallons per day (Mgal/d) during 2005. Estimates of withdrawals by source indicate that total surface-water withdrawals were about 9,467 Mgal/d (95 percent of the total withdrawals) and the remaining 491 Mgal/d (5 percent) were from ground water. More surface water than ground water was withdrawn for all categories except aquaculture, mining, and self-supplied residential. During 2005, estimated withdrawals by category and in descending order were: thermoelectric power, 8,274 Mgal/d; public supply, 802 Mgal/d; self-supplied industrial, 550 Mgal/d; irrigation, 161 Mgal/d; aquaculture, 75 Mgal/d; self-supplied residential, 39 Mgal/d; livestock, 28 Mgal/d; and mining, 28 Mgal/d. During 2005, about 83 percent of the water used in Alabama was for thermoelectric power to generate about 114,144 net gigawatt-hours of energy. Almost all of the thermoelectric-power water use (about 8,274 Mgal/d) was from surface water; nearly all of the water (98 percent) was used for once-through cooling, and most of that water was returned to a surface-water source. Public-supply and self-supplied residential withdrawals were about 8 percent of total water withdrawals and about 50 percent of total water withdrawals for all categories excluding thermoelectric power. The combined public-supply and self-supplied residential ground-water withdrawals were about 64 percent of total ground-water withdrawals for Alabama. Public-supply deliveries to residential customers were 41 percent of total public-supply withdrawals, or about 326 Mgal/d; combined industrial and commercial deliveries were 44 percent, or about 355 Mgal/d; and public use and losses accounted for the remaining 15 percent, or about 120 Mgal/d. Self-supplied industrial (550 Mgal/d) and mining (28 Mgal/d) withdrawals were about 6 percent of total water withdrawals and about 33 percent of total water withdrawals for all categories excluding thermoelectric power. Paper and allied products accounted for the largest self-supplied industrial surface-water withdrawals (301 Mgal/d), and chemical and allied products (12 Mgal/d) accounted for the largest ground-water withdrawals. Water withdrawals for the agricultural sector-irrigation (161 Mgal/d), aquaculture (75 Mgal/d), and livestock (28 Mgal/d)-were about 3 percent of total withdrawals and about 16 percent of total withdrawals for all categories excluding thermoelectric power. About 135,800 acres of crops, nursery stock, sod, and golf courses were irrigated in 2005. About 97 percent of these acres were irrigated with sprinkler irrigation systems. The statewide average application rate was 1.33 acre-feet per acre per year. The highest application rate, 3.74 acre-feet per acre per year, was for nursery stock. The largest total water withdrawals by county occurred in Limestone, Jackson, Colbert, and Mobile Counties, and were 60 percent of the total; these withdrawals primarily were used to meet the cooling needs at thermoelectric-power plants. Excluding thermoelectric power, the largest withdrawals by county were in Morgan, Mobile, Jefferson, Talladega, and Madison Counties. Water use was estimated at the hydrologic subbasin level for all categories except aquaculture, mining, and self-supplied residential. The Middle Tennessee-Elk subregion accounted for about 53 percent (5,185 Mgal/d) of the estimated total withdrawals by subbasin of 9,816 Mgal/d. About 92 percent of the water use in the Middle Tennessee-Elk subregion was for thermoelectric power, and more than 99 percent of the water was from surface water. Gross per capita use for all offstream uses was 2,185 gallons per day (gal/d) for the estimated 4.56 million Alabama residents in 2005. Public-supply per capita use was 199 gal/d for the estimated 4.04 million residents served by a public supplier; public-supplied residential per capita use was 81 gal/d. Self-supplied residential per capita use was 75 gal/d for the estimated 0.52 million self-supplied residential population. Average residential per capita use was 80 gal/d. Total water withdrawals decreased less than 1 percent from 9,990 Mgal/d in 2000 to 9,958 Mgal/d in 2005. Surface-water withdrawals decreased less than 5 percent from 9,950 Mgal/d in 2000 to 9,467 Mgal/d in 2005. In contrast, ground-water withdrawals increased about 12 percent from 440 Mgal/d in 2000 to 491 Mgal/d in 2005. By category, increases in irrigation (118 Mgal/d, about 274 percent), thermoelectric power (84 Mgal/d, about 1 percent), and aquaculture (65 Mgal/d, 620 percent) were offset by declines in self-supplied industrial (283 Mgal/d, about 34 percent), self-supplied residential (40 Mgal/d, about 50 percent); and public supply (32 Mgal/d, about 4 percent) from 2000 to 2005. Water use for livestock and mining was not estimated in 2000.

Scientific Investigations Report↗

Depth of groundwater used for drinking-water supplies in the United States

Groundwater supplies 35 percent of drinking water in the United States. Mapping the quantity and quality of groundwater at the depths used for potable supplies requires an understanding of locational variation in the characteristics of drinking-water wells (depth and open interval). Typical depths of domestic- and public-drinking-water supply wells vary by and within aquifer across the United States. The depths to the top and bottom of the zones from which drinking water is withdrawn are important predictor variables in regional- and national-scale statistical water models, but spatially extensive maps of the depths to drinking-water-supply sources are not consistently available in modeled regions. Therefore, it was necessary to generate a set of grids representing surfaces of the approximate common depth and length of open intervals in the wells from which water is withdrawn for domestic- and public-drinking-water supply (withdrawal zones) within the conterminous United States. Well data (about 7.6 million records) were compiled from several sources, including the U.S. Geological Survey’s National Water Information System (600,922 records), the U.S. Environmental Protection Agency’s Safe Drinking Water Information System dataset (66,540 records, primarily public-supply wells), a groundwater ambient monitoring dataset (31,448 records, primarily domestic-supply wells), individual State data (6,096,503 records), a national brackish aquifer study (96,885 records), and a glacial aquifer study (729,564 records). Fifty-seven principal aquifers and 65 secondary hydrogeologic regions have been designated in the conterminous United States. The principal aquifers and secondary hydrogeologic regions vary in depth, thickness, lithology, and transmissivity characteristics. Some principal aquifers underlie secondary hydrogeologic regions, and may in turn be overlain by glacial sediment or basin and valley fill aquifers, which may also be used as drinking-water sources. The principal aquifer and secondary hydrogeologic region polygons were merged with overlying sediment polygons, where present, including glacial sediment, coarse glacial sediment, and stream valley alluvium (alluvium) polygons, to generate unique hydrogeologic settings across the conterminous United States. A total of 288 distinct hydrogeologic settings resulted from the merging of principal aquifer, secondary hydrogeologic region, glacial sediment, coarse glacial sediment, and alluvium polygons. Each well was assigned to a hydrogeologic setting on the basis of location. Hydrogeologic setting well groupings were used to guide calculations of the median value for well depth and depth to and length of open intervals across the hydrogeologic setting. Where well data were sparse or missing, wells from hydrogeologic settings with similar well construction properties, geology, physiography, and topography were grouped and used to calculate the moving median depth (if less than five wells in a 100-kilometer [62.1-mile] radius) and to estimate open interval length (if not available within hydrogeologic setting). Grids were generated to represent what might be considered as the “typical” or “median” domestic- and public-supply well in an area. The well properties are defined with moving median grids of top depth, bottom depth, and length of open interval at a 1-square-kilometer (0.38-square-mile) grid cell scale. Median depths and open intervals of domestic- and public-supply wells varied by lithology of the hydrogeologic setting and overlying sediment. Overall, the median depths were 142 feet (43.3 meters) for all domestic-supply wells and 202 feet (61.6 meters) for all public-supply wells. The median open intervals were 21 feet (6.4 meters) for domestic-supply wells and 49 feet (14.9 meters) for public-supply wells. The shallowest median bottom open interval depths for domestic-supply wells were in the secondary hydrogeologic regions with coarse glacial sediment, which suggests that the wells are most commonly completed in the permeable coarse glacial sediment and not in the underlying secondary hydrogeologic region. Public-supply wells were completed at relatively shallow median depths when drilled in permeable sediment that overlie secondary hydrogeologic regions. When public-supply wells were completed in principal aquifers, the median depths were typically greater than wells completed in secondary hydrogeologic regions. Well data used in this study were limited to those available from national or State digital databases. Several quality-assurance checks were performed during data compilation, but a comprehensive quality assurance inspection for each of the data sources was outside the scope of this study. Grids defining typical open intervals in domestic- and public-supply wells are presented. Although there are many places where multiple aquifers are stacked, these results correspond primarily to the aquifer with the highest documented number of wells for each use.

Scientific Investigations Report↗

Estimated water use in Arkansas, 2010

The Arkansas Natural Resources Commission (ANRC) conducts an annual inventory of reported groundwater and surface-water withdrawals in Arkansas in cooperation with the U.S. Geological Survey (USGS). This report describes withdrawals from groundwater and surface-water resources in Arkansas for 2010. The report compiles withdrawals by county for 10 categories of water use—public supply, domestic (self-supplied), commercial (self-supplied), industrial (self-supplied), mining, livestock, aquaculture, irrigation, duck (hunting) clubs, and thermoelectric power generation. Water-use trends in Arkansas from 1965 to 2010 and sources of groundwater withdrawals also are described. During 2010, total withdrawals from groundwater and surface-water sources in Arkansas were 11,300 million gallons per day (Mgal/d). Of the total withdrawn, about 69 percent (7,790 Mgal/d) was from groundwater. Public-supply systems served about 94 percent of Arkansas’ population. Public-supply total withdrawals were 429 Mgal/d, with about 69 percent from surface-water sources. The statewide average of per capita residential use from public-supply systems was about 155 gallons per day (gal/d). The domestic (self-supplied) water use was 12.8 Mgal/d. Total commercial (self-supplied) water use was 11.7 Mgal/d. Total industrial (self-supplied) water use was 276 Mgal/d. Total mining water use was 44.3 Mgal/d. Total livestock water use was 39.0 Mgal/d. Total aquaculture water use was 268 Mgal/d. Irrigation water use totaled 8,720 Mgal/d. Total duck (hunting) club water use was 216 Mgal/d. Total thermoelectric power water use was 1,540 Mgal/d. The three water-use categories with the largest withdrawals and their effects on total water use were examined. Total water use in Arkansas has increased about 428 percent between 1965 and 2010. Total groundwater use increased about 533 percent and total surface-water use increased about 289 percent. Since about 2000, total water use in Arkansas has plateaued, peaking in 2005. The plateauing of total water use is the result of decreasing surface-water use in the irrigation, thermoelectric power, and public-supply categories offsetting the continuing increases in groundwater use in the irrigation category. An examination of total water use and irrigation water-use changes over time demonstrates the increasing dominance of groundwater withdrawals for irrigation on Arkansas’ total water use. Total irrigation water use in Arkansas between 1965 and 2010 has increased about 652 percent. Withdrawals for thermoelectric power water use in Arkansas have continuously accounted for about half of the State’s total surface-water use for the period 1965–2010. Thermoelectric power water use in Arkansas between 1965 and 2010 increased 264 percent. The percent of Arkansas’ population served by public water suppliers has continued to increase while the percentage of the State’s total water use withdrawn by public water suppliers has remained relatively constant. Public-supply water use in Arkansas between 1965 and 2010 increased about 238 percent. Regardless of continuing increases in population, since about 2000, total public-supply water use in Arkansas has plateaued at about 425 Mgal/d. Groundwater withdrawals comprised about 69 percent of the total amount of water used in Arkansas in 2010. Four aquifers in Arkansas account for more than 99 percent of the total groundwater withdrawals. The aquifers in deposits of Quaternary age supplied about 97 percent of all groundwater withdrawals. The Sparta-Memphis aquifer supplied about 2.5 percent of all groundwater withdrawals, the Wilcox aquifer supplied about 0.5 percent of all groundwater withdrawals, and the Paleozoic aquifer supplied about 0.3 percent of all groundwater withdrawals.

Arkansas↗

Status and understanding of groundwater quality in the northern Sierra Nevada foothills domestic-supply aquifer study units, 2015–17—California GAMA Priority Basin Project

Groundwater quality in the northern Sierra Nevada foothills region of California was investigated as part of California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring Assessment Priority Basin Project (GAMA-PBP). The region was divided into two study units: the Yuba-Bear watersheds (YBW) study unit and the American-Cosumnes-Mokelumne watersheds (ACMW) study unit. The GAMA-PBP made a spatially unbiased assessment of aquifer systems used for domestic drinking-water supply in the study region, which are predominantly composed of fractured, hard-rock aquifers of varying lithology. These assessments characterized the quality of raw groundwater to evaluate ambient conditions in the domestic-supply aquifer and not the quality of treated drinking water. The study included three components: (1) a status assessment , which characterized the quality of groundwater resources used for domestic drinking-water supply in the YBW and ACMW study units; (2) an understanding assessment , which evaluated natural and anthropogenic explanatory factors that could potentially affect groundwater quality in the study region; and (3) a comparative assessment between the groundwater resources used for domestic and public drinking-water supply in the study region. The status assessment was based on data collected by the GAMA-PBP from 74 sites in the YBW study unit during 2015–16 and 67 sites in the ACMW study unit from 2016 to 2017. To contextualize water-quality results, concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. The status assessment used a grid-based method to estimate proportions of groundwater resources with concentrations approaching or exceeding benchmark thresholds. This method provides spatially unbiased results and allows inter-comparability with similar groundwater-quality assessments. Inorganic constituents with health-based benchmarks were present at high relative concentration (RC), meaning they exceeded the benchmark threshold, in 5.4 and 10 percent of domestic-supply aquifer systems in the YBW and ACMW study units, respectively. Inorganic constituents with aesthetic-based benchmarks were detected at high-RCs in 20 and 28 percent of the YBW and ACMW study units, respectively. The inorganic constituents present at high RC were arsenic, barium, boron, molybdenum, strontium, nitrate, adjusted gross-alpha particle activity, chloride, total dissolved solids, specific conductance, iron, manganese, and hardness. Groundwater samples were tested for presence or absence of three microbial indicators (total coliform, Escherichia coli , and Enterococci ). At least one microbial indicator was present in 26 and 28 percent of the YBW and ACMW study units, respectively. At least one organic constituent was detected in 30 and 42 percent of the YBW and ACMW study units, respectively. Organic constituents were not present at high RC, but tetrachloroethene (PCE), trichloroethene (TCE), and toluene were detected in the YBW study unit at moderate RC (between the benchmark concentration and one-tenth of the benchmark concentration). Methyl tert -butyl ether (MTBE) and chloroform were present at low RC (less than one-tenth of the benchmark concentration) in the YBW and ACMW study units with detection frequencies greater than 10 percent. Perchlorate, a constituent of special interest, was detected in 31 and 41 percent of the YBW and ACMW study units, respectively, at either low or moderate RCs. Relations among select water-quality constituents and potential explanatory factors were evaluated using statistical and graphical approaches. Nitrate, microbial indicators, and perchlorate were all correlated to elevation-dependent variables relating to climate, land use, and recharge condition. Isotopic and dissolved noble-gas tracers indicated these water-quality constituents are associated with recharge conditions associated with irrigation during the summer dry-season, which is common in areas of rural-residential or agricultural land uses. Higher concentrations of iron and manganese were primarily associated with anoxic groundwater in aquifers of metasedimentary lithology. Increased hardness was primarily associated with anoxic groundwater in aquifers of mafic-ultramafic or metavolcanics lithologies at lower elevations in the study region in the Melones fault zone. Chloroform and MTBE were associated with shallow groundwater (wells depths less than 130 m) under oxic and anoxic redox conditions, respectively. The comparative assessment evaluated differences between the aquifer systems used for domestic- and public-supply in study region based on (1) well-construction characteristics, and (2) water quality. Analysis of over 60,000 well-completion reports in the study region showed that although domestic-supply wells span the deepest depth zones in regional aquifers, median depths for public-supply wells were significantly greater than those of domestic-supply wells in both study units. Water-quality data from more than 300 public-supply wells in the study region were assessed using a spatially weighted method for calculation aquifer-scale proportions and compared with the domestic-supply assessment results. Detections of inorganic constituents at high RC and detection frequencies for organic constituents were generally similar between the domestic- and public-supply aquifer systems in both study units, with a few notable exceptions in the ACMW study unit: nitrate was greater for the public- compared to domestic-supply aquifer system and both manganese, hardness, and MTBE were greater in the domestic- compared to public-supply aquifer system. These differences are likely related to contrasting land uses, aquifer lithologies, landscape positions, and depths characterizing domestic- and public-supply wells in the ACMW study unit. Overall, fewer samples from domestic-supply wells in the northern Sierra Nevada foothills exceeded health-based benchmarks compared to aesthetic-based benchmarks for groundwater quality. Exceedences of health-based benchmarks were primarily caused by nitrate and coliform bacteria, which were associated with recharge from diverted surface water used primarily for irrigation. Exceedences of aesthetic-based benchmarks were primarily caused by iron, managanese, and hardness, which were associated with geologic factors. Regional irrigation practices and aquifer lithology can affect groundwater quality in fractured-rock aquifers in the northern Sierra Nevada foothills used for domestic drinking-water supply.

California↗

Environmental presence and persistence of pharmaceuticals: An overview

Emerging contaminants (ECs) in the environment – that is, chemicals with domestic, municipal, industrial, or agricultural sources that are not commonly monitored but may have the potential for adverse environmental effects – is a rapidly growing field of research. The use of “emerging” is not intended to infer that the presence of these compounds in the environment is new. These chemicals have been released into the environment as long as they have been in production or, in the case of hormones and other endogenous compounds, since the rise of animal life. What is emerging is the interest by the scientific and lay communities in the presence of these chemicals in the environment, the analytical capabilities required for detection, and the subtle effects that very small concentrations of these chemicals appear to have on aquatic biota. In December 2006, Environmental Science & Technology devoted an entire special issue (volume 40, number 23) to the topic of ECs, illustrating the increased interest in the subject. Within the EGs, one particular class that has seen a substantial increase in research over the past 10 years is pharmaceuticals and personal-care products (PPCPs). This increased research interest can be demonstrated by several means, including requests for proposals from funding agencies, but the clearest indication of a focused effort to understand the introduction, transformation, and potential health and environmental effects of PPCPs and ECs, in general, is the number of published reports. This increase can be shown by examining six environmental journals that regularly publish PPCP-related papers – Chemosphere , Environmental Science & Technology , Environmental Toxicology and Chemistry , Science of the Total Environment , Water Research , and Water Science and Technology . In 1998 there were 22 papers published on pharmaceuticals, antibiotics, or drugs in these 6 journals; by 2006, this number increased sixfold to 132 papers (Figure 1.1). This growth can be attributed to a number of factors. The presence of pharmaceuticals in surface-water samples from Europe and the United States was documented in several sentinel papers. These ground-breaking works encouraged other scientists to examine the rivers, streams, lakes, and reservoirs in their regions for such chemicals. In addition, the intense public attention paid to news reports on the environmental detections of these chemicals and possible effects of aquatic life has made this issue visible to the wastewater-treatment, drinking-water treatment, and regulatory communities. This has driven the funding bodies associated with these communities to fund studies or request proposals that address the presence, fate, and effects of PPCPs in aquatic systems. The release of the first comprehensive reconnaissance of pharmaceuticals and other wastewater contaminants in the United States provides an example of the intense media interest in this topic. Within 6 days on online publication of this study, 72 newspapers across the United States had published articles describing the results, either locally written or based on international media syndicate reports. There also was substantial concurrent coverage by local and national radio and television outlets, including the Cable News Network, ABC World News Tonight , and National Public Radio. A substantial fraction of these news stories may be attributable to press releases and media briefings prior to publication. However, the interest by television and print journalists in reporting the results of a peer-reviewed journal article to the general public was motivated by the recognition that describing the presence of PPCPs in water supplies would be of interest to the public. To better convey the results of the study published by Koplin et al. to the public, a separate general-interest fact sheet was published to summarize the important points of the study. Because PPCPs are commonly and widely used by individuals, there is likely a preexisting, personal identification with these compounds that does not occur for the wide range of other organic and inorganic contaminants whose presence in the environment has previously been described. This greater public “name recognition” makes itself known through the media to the regulatory and technical community and has prompted interest in sponsoring research that defines the composition and concentrations of PPCPs in potential sources and their fate and effects following relase into the environment. Independent of the drivers that potentially fuel the interest in studies of PPCPs, it is clear that PPCP research has grown beyond surface-water studies to examine issues such as: • Presence in other matrices, such as groundwater, landfill leachates, sediments, and biosolids. • Environmental transport and fate in surface water, groundwater, and soils amended with reclaimed water or biosolids. • PPCP source elucidation, such as wastewater treatment plant (WWTP) effluents, confined animal feeding operations (CAFOs), and aquaculture. • Removal during wastewater and drinking-water treatment. • Effects on aquatic ecosystems, terrestrial ecosystems, and human health. The chapters in this book provide an extensive examination of current environmental pharmaceutical research and are divided into three sections: “Occurrence and Analysis of Pharmaceuticals in the Environment,” “Environment Fate and Transformations of Veterinary Pharmaceuticals,” and “treatment of Pharmaceuticals in Drinking Water and Wastewater.” The purpose of this introductory overview chapter is to outline current (2004-2006) knowledge about the presence and concentration of PPCPs as described in the published literature. Previous reviews should be consulted for discussions on pre-2004 publications. Those reviews will provide the reader with a comprehensive introduction to the topic of PPCPs in the environment. This chapter describes the sources of PPCPs and other organic contaminants often associated with human wastewater into the environment, the range of concentrations present in various environmental compartments, and the potential routes of removal/sequestration. An overview of the sources and fate of veterinary pharmaceuticals will be discussed in Chapter 5, “Fate and Transport of Veterinary Medicines in the Soil Environment.”

Book chapter↗

Forty-first annual report of the Director of the United States Geological Survey

The appropriations for the public work under the United States Geological Survey for the fiscal year 1919-20 comprised items amounting to $1,586,353.50. In general the results of the varied activities of the Geological Survey may be regarded as meeting with a constantly increasing measure of public approval, as shown by the larger use that is being made of this branch of the public service. Correspondence with all classes of citizens—ranchers and corporation officials, school children and university professors, prospectors and mining engineers—has continued to increase, and this gain has been evident in the requests both for specific information and for publications. Ten years ago a telegraphic request for a map or report was a notable incident; now telegrams of this kind are of daily occurrence. Especially gratifying has been the popular demand for topographic maps, the increase in sales this year being 70 per cent. The number of all publications—books and maps—distributed during the year exceeded the number printed this year, this disproving the common assertion that Government publications simply accumulate until they become only waste paper. Indeed, an embarrassing feature of much of the correspondence during the year has been the thousands of requests for reports that were out of print, and more reprints than usual of exhausted editions have been authorized to meet an insistent demand. The public is making use of the publications of the Geological Survey as never before.

Annual Report↗

Quality of ground water in the Biscayne Aquifer in Miami-Dade, Broward, and Palm Beach counties, Florida, 1996-1998, with emphasis on contaminants

The high permeability of the sand and limestone sediments and shallow water table of the Biscayne aquifer make ground water vulnerable to contamination by human activities. To assess potential contamination in the aquifer, untreated ground water was sampled from 30 public-supply wells (40-165 feet deep) in Broward, Miami-Dade, and Palm Beach Counties, 32 shallow wells (10-50 feet deep) in a recently urbanized (residential and light commercial) part of Broward County, and 3 shallow reference wells in Broward County. Results from sample analyses indicate that major ions, pH, dissolved oxygen, nutrients, and trace element concentrations were generally within the range indicative of background concentrations, except for: (1) substantially higher bromide concentrations in water from public-supply wells in southern Miami-Dade County; (2) a few relatively high (greater than 2 milligrams per liter) concentrations of nitrate in water from public-supply wells near agricultural lands in Miami-Dade and southern Broward Counties; and (3) a few relatively high concentrations of arsenic (greater than 10 micrograms per liter) in water from some shallow urban wells near golf courses. Pesticides were detected in every public-supply well, in most of the shallow, urban monitoring wells (78 percent), and in one reference well; however, no pesticide concentration exceeded any drinking-water standard. Fifteen different pesticides or their degradation products were detected. The most frequently detected pesticides were atrazine and tebuthiuron; less frequently detected were the herbicides diuron, fenuron, prometon, metolachlor, simazine, and 2,6-diethylaniline. Volatile organic compounds (VOCs) were detected in most of the public-supply wells (77 percent) and shallow, urban wells (91 percent) and in two of the three reference wells. Thirty-two different VOCs were detected in ground water in the Biscayne aquifer, with cis-1,2-dichloroethene the most frequently detected VOC in the public-supply wells, followed by methyl tert-butyl ether (MTBE), 1,4-dichlorobenzene, and chloroform. Toluene, p-isopropyltoluene, and 1,2,4-trimethylbenzene were the most frequently detected VOCs in the shallow, urban wells. Concentrations of all VOCs were less than the maximum contaminant level (MCL) for public drinking water, except in two samples from public-supply wells near industrialized areas that had vinyl chloride concentrations (3 and 5 micrograms per liter) above the MCL of 1 microgram per liter.

Open-File Report↗

Water Use in Wisconsin, 2005

The U.S. Geological Survey (USGS) Wisconsin Water Science Center is responsible for presenting data collected or estimated for water withdrawals and diversions every 5 years to the National Water-Use Information Program (NWUIP). This program serves many purposes such as quantifying how much, where, and for what purpose water is used; tracking and documenting water-use trends and changes; and providing these data to other agencies to support hydrologic projects. In 2005, data at both the county and subbasin levels were compiled into the USGS national water-use database system; these data are published in a statewide summary report and a national circular. This publication, Water Use in Wisconsin, 2005, presents the water-use estimates for 2005; this publication also describes how these water-use data were determined (including assumptions used), limitations of using these data, and trends in water-use data presented to the NWUIP. Estimates of water use in Wisconsin indicate that about 8,608 million gallons per day (Mgal/d) were withdrawn during 2005. Of this amount, about 7,622 Mgal/d (89 percent) were from surface-water sources and about 986 Mgal/d (11 percent) were from ground-water sources. Surface water used for cooling at thermoelectric-power plants constituted the largest portion of daily use at 6,898 Mgal/d. Water provided by public-supply water utilities is the second largest use of water and totaled 552 Mgal/d. Public supply served approximately 71 percent of the estimated 2005 Wisconsin population of 5.54 million people; two counties - Milwaukee and Dane - accounted for more than one-third of the public-supply withdrawal. Industrial and irrigation were the next major water uses at 471 and 402 Mgal/d, respectively. Non-irrigational agricultural (livestock and aquaculture) accounted for approximately 155 Mgal/d and is similar to the combined withdrawal for the remaining water-use categories of domestic, commercial, and mining (131 Mgal/d). Data on water use in Wisconsin by source of water and category of use have been compiled at 5-year intervals since 1950. During the past 55 years (1950-2005), water withdrawn to meet demands for public supply and self-supplied irrigation, industrial, commercial, domestic, and livestock increased 333 percent (1,117 Mgal/d). The greatest increases were for public supply, industrial, and irrigation, and are reflected in the increasing total per-capita water-use values. In recent (2000 and 2005) water-use estimation years, both public-supply and self-supplied domestic per-capita-use values have been declining. This can be attributed, at least in part, to a reduction in industrial-water deliveries, increased water-efficiency standards, and the implementation of leak-detection programs and water-conservation practices. However, when making comparisons to evaluate trends among other Wisconsin water-use estimation years, it is important to be aware of changes that may have occurred in estimation methods or objectives that create differences. Some changes that have occurred are the availability of data and information about water use, changes in data sources and estimation methods, and the inclusion and exclusion of certain water-use categories. These differences may have an effect on apparent trends and make comparing trends difficult.

Open-File Report↗

Review and bibliometric analysis of published literature citing data produced by the Gap Analysis Program (GAP)

The Gap Analysis Program (GAP) of the U.S. Geological Survey (USGS) produces geospatial datasets providing information on land cover, predicted species distributions, stewardship (ownership and conservation status), and an analysis dataset which synthesizes the other three datasets. The intent in providing these datasets is to support the conservation of biodiversity. The datasets are made available at no cost. The initial datasets were created at the state level. More recent datasets have been assembled at regional and national levels. GAP entered an agreement with the Policy Analysis and Science Assistance branch of the USGS to conduct an evaluation to describe the effect that using GAP data has on those who utilize the datasets (GAP users). The evaluation project included multiple components: a discussion regarding use of GAP data conducted with participants at a GAP conference, a literature review of publications that cited use of GAP data, and a survey of GAP users. The findings of the published literature search were used to identify topics to include on the survey. This report summarizes the literature search, the characteristics of the resulting set of publications, the emergent themes from statements made regarding GAP data, and a bibliometric analysis of the publications. We cannot claim that this list includes all publications that have used GAP data. Given the time lapse that is common in the publishing process, more recent datasets may be cited less frequently in this list of publications. Reports or products that used GAP data may be produced but never published in print or released online. In that case, our search strategies would not have located those reports. Authors may have used GAP data but failed to cite it in such a way that the search strategies we used would have located those publications. These are common issues when using a literature search as part of an evaluation project. Although the final list of publications we identified is not comprehensive, this set of publications can be considered a sufficient sample of those citing GAP data and suitable for the descriptive analyses we conducted.

Open-File Report↗

Estimated water withdrawals and use in Puerto Rico, 2015

Water withdrawals and use in Puerto Rico for 2015 were estimated at 2,372 million gallons per day (Mgal/d), which was 21 percent less than withdrawals and use for 2010. The 2015 total water withdrawal and use estimates were the lowest since 1990 and coincided with a substantial decline of 25 percent in saline-water withdrawals for thermoelectric-power cooling processes from 2010 to 2015. Freshwater withdrawals were 671 Mgal/d, or 28 percent of total water withdrawals, and saline-water withdrawals were 1,701 Mgal/d, or 72 percent of total withdrawals. Fresh surface-water withdrawals were estimated at 548 Mgal/d, 10 percent less than in 2010, whereas fresh groundwater withdrawals were estimated at 122 Mgal/d, 2 percent less than in 2010. Saline surface-water withdrawals were 25 percent less than in 2010. Freshwater withdrawals were greatest for public-supply water and irrigation in 2015 and, combined, accounted for 98 percent of Puerto Rico’s total freshwater withdrawals. Withdrawals in 2015 for public-supply water (576 Mgal/d) were 14 percent lower and withdrawals for irrigation (78 Mgal/d) were 104 percent greater than in 2010, possibly because of drought conditions in agricultural counties along the south and southeast coasts in 2015. The sources for public-supply water withdrawals in 2015 included surface water (88 percent) and groundwater (12 percent). Withdrawals for other uses, which account for the remaining 2 percent of Puerto Rico’s total freshwater withdrawals, were lower in 2015 than in 2010; specifically, withdrawals for domestic self-supplied use decreased by 78 percent, industrial withdrawals decreased by 15 percent, and withdrawals for livestock decreased by 25 percent. Freshwater withdrawals for thermoelectric power and mining were greater in 2015 than in 2010, increasing by 23 percent and 5 percent, respectively. The total population of Puerto Rico decreased by 7 percent from 2010 to 2015, from 3.73 million people in 2010 to 3.47 million people in 2015. The number of people who obtained potable water from public-supply water facilities in 2015 was about 3.47 million, or about 100 percent of the population of Puerto Rico. Public-supply water deliveries for domestic use accounted for 338 Mgal/d in 2015, which is 47 percent greater than in 2010, indicating an increase in domestic per capita use from 62 to 98 gallons per person per day from 2010 to 2015. Domestic self-supplied withdrawals were estimated at 0.52 Mgal/d in 2015, for an estimated 4,708 people (less than 1 percent of Puerto Rico’s population). All domestic self-supplied withdrawals were assumed to be from groundwater sources. Irrigation freshwater withdrawals were 78 Mgal/d in 2015 and accounted for 12 percent of the total freshwater withdrawals for all uses. Surface-water deliveries from irrigation districts accounted for 44 percent of total irrigation withdrawals, whereas groundwater withdrawals accounted for 56 percent. About 37,000 acres were irrigated in 2015, a decrease of 11 percent or about 4,000 acres compared to 2010. About 99 percent of the acreage was irrigated by micro-irrigation and sprinkler systems in 2015. About 65 percent of the irrigation withdrawals were accounted for by four municipalities: Santa Isabel, Salinas, Lajas, and Juana Díaz. Altogether, freshwater withdrawals for livestock, industrial, mining, and thermoelectric power accounted for 2 percent (16.2 Mgal/d) of freshwater withdrawals for all uses, 9 percent less than in 2010. About 71 percent of the freshwater withdrawn for these categories was from groundwater sources. In 2015, 50 percent of the total freshwater withdrawn in Puerto Rico was apportioned to six municipalities: Arecibo, Trujillo Alto, Toa Alta, Villalba, Aguada, and Mayagüez. Arecibo accounted for about 18 percent of the total freshwater withdrawals, predominantly for public-supply water use. Trujillo Alto, Toa Alta, Villalba, Aguada, and Mayagüez accounted for about 32 percent (213 Mgal/d) of the total freshwater withdrawals, which were predominantly for public-supply water uses. Withdrawals in some of these municipalities are subsequently distributed to other municipalities such as those in the San Juan metro area. The Puerto Rico Aqueduct and Sewer Authority water service area for the San Juan metro area (referred to as W–102) accounted for about 28 percent of the total water delivered from public-supply water facilities to domestic users, which includes about 34 percent of the total population of Puerto Rico.

Puerto Rico↗

Compilation and evaluation of data used to identify groundwater sources under the direct influence of surface water in Pennsylvania

A study was conducted to compile and evaluate data used to identify groundwater sources that are under the direct influence of surface water (GUDI) in Pennsylvania. In the early 1990s, the Pennsylvania Department of Environmental Protection (PADEP) implemented the Surface Water Identification Protocol (SWIP) for the identification of GUDI sources. Since the establishment of the SWIP, PADEP has classified more than 500 individual sources across Pennsylvania as GUDI, but Pennsylvania’s complex geology and physiography provide a challenge for a uniform method of GUDI determination. Components used in this study to compile and evaluate data associated with GUDI determination include: (1) a preliminary review of file information for 43 public water-supply wells, (2) quality control and addition of data to PADEP’s database for public water-supply systems to prepare data for analysis, and (3) exploratory evaluation of existing GUDI sources in the database with respect to hydrogeologic and source-construction characteristics that are currently utilized in the assessment methodology. Case files for 43 wells from PADEP’s Northcentral and Southcentral regions were reviewed to: (1) provide a better understanding of how the SWIP was applied in practice, (2) verify and compile missing data, and (3) find additional attributes not previously available that might explain a well’s categorization as GUDI. Review of file information showed that the SWIP outlined in PADEP technical guidance was usually followed, but for some sources, the GUDI determination was more complex and could not be easily summarized. Data compiled for study analyses provided by PADEP include source data derived from public water-supply system case files, a source-information database for public water-supply systems, and Microscopic Particulate Analysis (MPA) results and associated water-quality data for public water-supply system groundwater sources. Data from the Pennsylvania Drinking Water Information System (PADWIS) , which is PADEP’s database for public water-supply systems, were also used for this study. The PADWIS database originally included data for 12,147 groundwater sources (11,812 groundwater sources not under the direct influence of surface water (non-GUDI) wells and 335 GUDI wells). A subset (4,018 wells consisting of 3,842 non-GUDI wells and 175 GUDI wells) of the PADWIS database was created for an analysis and includes only community wells evaluated in accordance with the SWIP. MPA results for 631 community and noncommunity wells were compiled, along with associated water-quality data (alkalinity, chloride, Escherichia coli , fecal coliform, nitrate, pH, sodium, specific conductance, sulfate, total coliform, total dissolved solids, total residue, and turbidity) populated from the PADEP Bureau of Laboratories Sample Information System. Data compiled from sources other than PADEP include spatial data, both naturogenic (for example, average precipitation or distance to closest hydrologic feature) and anthropogenic (for example, percentage of developed or agricultural land cover within a specific vicinity of a public water-supply system well) data representing spatially derived variables. Comparison among wells in the PADWIS dataset subset using the nonparametric Kruskal-Wallis test showed that GUDI wells had significantly older median construction years, shallower depths, and static water levels closer to the land surface than non-GUDI wells and that carbonate aquifers had the highest percentages of wells designated as GUDI (12 percent; 57 wells). Further comparison of wells in the PADWIS database subset using the Spearman’s rho monotonic correlation test illustrated that public water-supply wells designated as GUDI largely occur in unconfined aquifers and have high average yield and shallow static water levels. Assessment of the MPA database subset using the Kruskal-Wallis test showed wells with MPA total risk-factor scores that exceeded zero had older median construction years and shallower casing depths than wells with MPA total risk-factor scores of zero and that carbonate aquifers had the highest percentages of wells with MPA total risk-factor scores exceeding zero (30 percent; 63 wells). Spearman’s rho correlations showed that wells completed in aquifers with depths to major water-bearing zones closer to the land-surface had higher total risk-factor scores resulting from MPA samples. Based on the results of the analyses described in this report, broad conclusions can be drawn regarding site-specific well characteristics as well as anthropogenic and naturogenic factors that could be responsible for a well being designated as GUDI, but the accuracy of these results is dependent on the quality of the data being analyzed. Ultimately, study results serve as an added resource for initial desktop screening of wells to determine if additional site-specific investigation is warranted and underscore the need for field evaluation.

Pennsylvania↗

Estimated water withdrawals and use in Illinois, 1988

The total amount of water withdrawn in Illinois during 1988 was about 18,756 million gallons per day (Mgal/d). About 1,170 Mgal/d, or 37 percent, of the total water withdrawn in Illinois, excluding withdrawals for thermoelectric-power generation, was ground water; about 1,998 Mgal/d of surface water was withdrawn and used, excluding withdrawals for thermoelectric-power generation. About 25 Mgal/d of the total ground water withdrawn was saline. Seventy-five percent of the total surface water, excluding withdrawals for thermoelectric-power generation, was withdrawn by public-supply facilities. Self-supplied industrial withdrawals were the next largest use of surface water. Thirty-nine percent of the total ground water was withdrawn by public-supply facilities. Irrigation was the next largest use of ground water. Sixty-two percent of the total water withdrawn, excluding thermoelectric withdrawals, in Illinois during 1988 was for public-supply facilities. Self-supplied withdrawals by industries and for irrigation were the next largest uses of water in Illinois during 1988. The total water withdrawn for thermoelectric-power generation was about 15,589 Mgal/d. Water withdrawn and delivered from public-supply facilities in Illinois during 1988 totaled about 1,956 Mgal/d. Surface water and ground water were the sources for about 1,495 and 462 Mgal/d, respectively, of the withdrawals for public supply. The total water obtained from Lake Michigan for public-water supply was about 1,214 Mgal/d. About 122 Mgal/d was withdrawn for self-supplied domestic purposes. Total self-supplied withdrawals and deliveries from public-water facilities for commercial use were about 654 Mgal/d. About 159 Mgal/d was self-supplied by the commercial establishments. Total irrigation water withdrawals were about 302 Mgal/d. Although irrigated acreage in Illinois has increased from 265,036 acres in 1986 to 281,370 acres in 1988, the most significant factor for the increased irrigation water use was the drought conditions throughout the entire State. Total estimated livestock withdrawals were about 56 Mgal/d. Total self-supplied withdrawals and deliveries from public-supply facilities for industrial purposes were about 743 Mgal/d. About 480 Mgal/d was self-supplied withdrawals by industrial facilities. A total of about 94 Mgal/d was withdrawn during mining activities. A total of about 34 Mgal/d was withdrawn during mining from ground-water sources; about 25 Mgal/d of the ground water withdrawn was saline.

Open-File Report↗

Estimated water withdrawals and use in Illinois, 1990

The total amount of water withdrawn in Illinois during 1990 was about 18,016 million gallons per day (Mgal/d). This amount was about 740 Mgal/d less than in 1988. The total water withdrawn for thermoelectric-power generation was about 15,170 Mgal/d; about 370 Mgal/d was consumptively used. About 936 Mgal/d, or 33 percent, of the total water withdrawn in Illinois during 1990 was ground water, excluding withdrawals for thermoelectric-power generation; about 1,911 Mgal/d of surface water was withdrawn and used, excluding withdrawals for thermoelectric-power generation. Seventy-four percent of the total surface water, excluding withdrawals for thermoelectric-power generation, was withdrawn by public-supply facilities. The next largest use of surface water was for self-supplied industrial withdrawals. Forty-seven percent of the total ground water was withdrawn by public-supply facilities. The next largest use of ground water was for irrigation. About 25 Mgal/d of the total ground water withdrawn was saline. Sixty-five percent of the total water withdrawn, excluding thermoelectric withdrawals, in Illinois during 1990 was for public-supply facilities. The next largest users of the total water withdrawn was for self-supplied withdrawals by industries and for irrigation. Water withdrawn and delivered from public-supply facilities in Illinois during 1990 totaled about 1,859 Mgal/d. Surface water and ground water were the sources for about 1,415 and 444 Mgal/d, respectively, of the withdrawals for public supply. The total water obtained from Lake Michigan for public-water supply was about 1,146 Mgal/d. About 115 Mgal/d was withdrawn for self-supplied domestic purposes. Total self-supplied withdrawals and deliveries from public-water facilities for commercial use were about 672 Mgal/d. About 173 Mgal/d was self- supplied by the commercial establishments. Total irrigation water withdrawals were about 78 Mgal/d. Total estimated livestock withdrawals were about 63 Mgal/d. Total self-supplied withdrawals and deliveries from public-supply facilities for industrial purposes were about 728 Mgal/d. About 464 Mgal/d was self-supplied withdrawals by industrial facilities. A total of about 94 Mgal/d was withdrawn during mining activities. A total of about 33 Mgal/d was withdrawn during mining from ground-water sources; about 25 Mgal/d of the ground water withdrawn was saline.

Open-File Report↗

Quality of water in the fractured-bedrock aquifer of New Hampshire

Over the past few decades, New Hampshire has experienced considerable population growth, which is forcing some communities to look for alternative public and private water supplies in the bedrock aquifer. Because the quality of water from the aquifer can vary, the U.S. Geological Survey statistically analyzed well data from 1,353 domestic and 360 public-supply bedrock wells to characterize the ground water. The domestic-well data were from homeowner-collected samples analyzed by the New Hampshire Department of Environmental Services (NHDES) Environmental Laboratory from 1984 to 1994. Bedrock water in New Hampshire often contains high concentrations of iron, manganese, arsenic, and radon gas. Water samples from 21 percent of the domestic bedrock wells contained arsenic above the U.S. Environmental Protection Agency (USEPA) 10 micrograms per liter (?g/L) drinking-water standard for public-water supplies, and 96 percent had radon concentrations greater than the USEPA-proposed 300 picocurie per liter (pCi/L) standard for public-water supplies. Some elevated fluoride concentrations (2 percent of samples) were above the 4 milligrams per liter (mg/L) USEPA drinking-water standard for public-water supplies. Water from the bedrock aquifer also typically is soft to moderately hard, and has a pH greater than 7.0. Variations in bedrock water quality were discernable when the data were compared to lithochemical groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of water in the bedrock aquifer of New Hampshire. Ground-water samples from the metasedimentary lithochemical group have greater concentrations of total iron and total manganese than do the felsic and mafic igneous lithochemical groups. Ground-water samples from the felsic igneous group have higher concentrations of total fluoride than do those from the other lithochemical groups. For arsenic, the calcareous metasedimentary group was identified, using the public-supply database, as having higher concentrations, on average, than the other lithochemical groups. The use of a radon-gas-potential classification of bedrock in the State indicated where high radon concentrations in the air and in water from private and public-supply wells were more likely to occur. In general, samples from the bedrock aquifer tend to have higher pH (are less acidic), greater hardness, much higher concentrations of iron, similar concentrations of manganese, and higher concentrations of fluoride and arsenic than do samples from stratified-drift aquifers in New Hampshire. An understanding of the water-quality conditions of water in bedrock aquifers is important from a public-health perspective because an increasing number of domestic bedrock wells are being drilled and relied upon as a source of drinking water in the State.

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