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USGS2024

SUTRA— A code for simulation of saturated-unsaturated, variable-density groundwater flow with solute or energy transport—Documentation of the version 4.0 enhancements—Freeze-thaw capability, saturation and relative-permeability relations, spatially varying properties, and enhanced budget and velocity outputs

Version 4.0 of the Saturated-Unsaturated Transport (SUTRA) software code provides the capability to simulate the freezing and thawing of groundwater during energy transport simulations under saturated and unsaturated conditions. In addition to the types of hydrogeologic processes that SUTRA has been able to simulate in the past, this version can be used to study the effects of the freeze-thaw process on the flow and energy dynamics of hydrogeologic systems. The freeze-thaw simulation capability accounts for the latent heat of fusion and allows thermal property values to vary with changing total-water saturation, liquid-water saturation, and ice saturation. It allows the effective permeability of the porous medium to change as a result of freezing and thawing. This version also provides several user-selectable relations for the dependence of total-water saturation on fluid pressure, the dependence of liquid-water saturation on temperature during freezing and thawing, and the dependence of relative permeability on liquid saturation, as well as three user-selectable formulae for defining the bulk thermal conductivity of a mixture of solid grains, liquid water, ice, and air. For unsaturated simulations without freezing, the selectable total-water saturation relations eliminate the need for the user to program these and their associated relative-permeability functions, as had been required in previous SUTRA versions. Optional nonlinear dependence of fluid density on temperature, which covers the range from supercooled (about −50 degrees Celsius) to superheated (about 400 degrees Celsius), is also provided. Additionally, this version makes it possible to spatially vary parameters that, in previous versions of SUTRA, were required to be spatially uniform: solid-matrix properties, adsorption parameters, and parameters for production of solute mass or energy. Spatial variation is also allowed for the newly included freeze-thaw process parameters. Additional enhancements provide (1) output of water-mass and energy budgets that include values of all component terms in the governing balance equations, and (2) output of Darcy velocities (fluid fluxes), in addition to the velocity output provided by previous SUTRA versions. These enhanced outputs allow fuller interpretation of simulation results, especially for freeze-thaw phenomena. The set of processes simulated by this version of SUTRA are useful for studying a wide range of hydrogeologic system types, conditions, and questions. For cryohydrogeologic simulations, however, this version of the code is limited in that (1) it does not simulate thermomechanical effects of freeze-thaw, (2) pressure changes due to water density change during freezing are neglected, (3) ice saturation cannot exceed the initial porosity of the simulated medium, and (4) cryosuction, the migration of liquid water toward freezing fronts, is neglected. Furthermore, this version does not account for air flow or for water vaporization and sublimation under unsaturated conditions.

Techniques and Methods↗
USGS2025

3D Converted wave reverse time migration imaging

We describe a newly developed method for recovering high-resolution images of seismic discontinuities, such as subducting slabs, in 3D. Our method makes use of converted S → P or P → S waves observed by dense arrays of seismometers to infer the locations and relative strengths of seismic discontinuities at depth in a target region. Observed direct and converted waves are backpropagated to their times of origin. The time-reversed wavefield is then separated into its constituent P and S components via the Helmholtz decomposition, and those separated wavefields are used to compute imaging functions that characterize the locations and relative strengths of seismic discontinuities. Imaging functions may be designed to use either S → P or P → S waves, so that users can target those arrivals expected to be most dominant in a given dataset. We have previously demonstrated the efficacy of our method in two dimensions, and we now present a 3D implementation of our technique which addresses the significant computational challenges posed by the size of volumetric wavefield data in three dimensions. Through a series of synthetic examples, we demonstrate that our method is capable of recovering the fine scale structure of a subducting slab given realistic station coverage and earthquake sources. We investigate optimal seismic station geometries for our technique and explore image interpretability in regions with poor data coverage. We find that linear station geometries yield more optimal, interpretable imaging functions than collections of small arrays can. We also show that our method can successfully recover bothS → P or P → S images when realistic shear earthquake sources are used, and we explore the additional computational challenges presented by the high frequency content of S waves. Our results demonstrate the potential for our technique to recover high-resolution information about subducting slabs in real-world regions, given that relatively sparse seismic arrays with only approximately 100 stations are capable of recovering interpretable imaging functions from just a few realistic earthquake sources for multiple discontinuities at significant depth in an area of approximately 400~sq~km.

Seismica↗
USGS2025

Bølling-Allerød productivity in the subarctic Pacific driven by seasonal upwelling

The Bølling-Allerød deglacial event is marked by high diatom productivity and opal deposition throughout the subarctic Pacific. This opal could either constitute a strengthened biological pump and thus carbon sequestration, or a weakened biological pump and release of marine-sequestered CO 2 to the atmosphere. We quantify silicic acid supply at IODP Site U1340 in the Bering Sea using biogenic opal and δ 30 Si of Coscinodiscus , a diatom genus. These records, along with diatom environmental indicators, suggest the Bølling-Allerød had high silicic acid availability related to a shift from stratification to seasonal upwelling dynamics. We thus propose the primary cause of the high productivity event was increased macronutrient supply from vertical exchange that injected old, nutrient-rich, CO 2 -rich waters into the surface. Enhanced CO 2 release from the subarctic Pacific may help explain critical intervals of CO 2 rise that occur at the onsets of the Bølling-Allerød and PreBoreal.

Geophysical Research Letters↗
USGS2025

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York↗
USGS1999

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming↗
USGS2025

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper↗
USGS2026

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews↗
USGS2025

Lunar grid systems, coordinate systems, and map projections for the Artemis missions and lunar surface navigation

Foreward This document contains design specifications of a navigational standard for the Moon, including a Lunar Transverse Mercator system, a Lunar Polar Stereographic system, a Lunar Grid Reference System, and a unique coordinate structure, Artemis Condensed Coordinates, for Artemis mission navigation and lunar surface science. The National Aeronautics and Space Administration (NASA) Artemis campaign seeks to place humans on the Moon for the first time since the Apollo missions. Early Artemis missions are heavily focused on the lunar south pole, which promises to return valuable data on the Moon’s geologic record, amongst other mission objectives. Coordinate systems in use today for the lunar south pole provides crew members on the surface neither an efficient nor intuitive means to communicate their position and orientation. A novel grid coordinate system, the Lunar Grid Reference System, is proposed to address these concerns for use in real-time extravehicular activity operations on the lunar surface. The many stakeholders involved in the Artemis missions will need a common system to communicate position and orientation while astronauts are operating on the lunar surface. To that end, Artemis crew members will need that system to be efficient and intuitive to promote efficient extravehicular activity timelines and reduce confusion. In the context of this document, these characteristics are addressed on the design of lunar coordinate systems: Efficient.—The number of characters required to communicate a location within a desired precision level in both local and global contexts, and how many steps are required for a recipient or sender to interpret a location. Intuitive.—How well the system aligns with human perceptual abilities, and whether the system yields distances that have the same relationship to actual lunar surface distance in all directions from the point where a person is located. Technological systems are currently being investigated to supplement the crew members’ ability to locate and orient themselves and other assets on the lunar surface; however, it is unlikely that those systems will be fully operational for the first few landed missions. Even with future positional aids, crew members will still need an efficient and intuitive means to communicate position and orientation. In addition, if technological systems fail, the crews will require land navigation skills and have maps available, thus providing further motivation for a crew-centric coordinate system. The contents of this U.S. Geological Survey (USGS) document detail a comprehensive framework for standardizing lunar crewed surface navigation within NASA and outlines the protocols, methods, and designs necessary for achieving consistency and interoperability across relevant space mission teams and lunar surface navigators. Key components of this document include designs of map projections, projected coordinate reference systems (Lunar Transverse Mercator and Lunar Polar Stereographic systems), and a grid system (Lunar Grid Reference System and Artemis Condensed Coordinates) for the Moon. The work proposed in this document seeks to accomplish something similar to the National Geospatial-Intelligence Agency (NGA) document SIG 0012 (NGA, 2014a), but for using grid systems for the Moon. This report incorporates initial feedback and input from NASA’s Artemis Geospatial Data Team, NASA’s Flight Operations Directorate, National Geodetic Survey, USGS Astrogeology Science Center, and NGA and is intended to serve as a resource for all involved with the Artemis missions, as well as for engineers designing and operating lunar infrastructure.

Techniques and Methods↗
USGS2025

Ambient field seismology in critical zone hydrological sciences

Passive ambient noise monitoring is an emerging tool in environmental seismology, leveraging the ambient seismic field to assess temporal variations in shallow subsurface properties. This review focuses on the potential and challenges of using scattered coda waves from noise correlation functions to monitor critical zone dynamics. The sensitivity of seismic velocities to various environmental factors, including precipitation, snowmelt, atmospheric pressure, and groundwater fluctuations, underscores the method’s versatility. While coda waves excel in detecting subtle changes due to their scattered nature, ballistic waves provide higher spatial resolution, albeit with challenges in source stability. Advances in seismic sensing, including distributed acoustic sensing and low-cost geophone networks, have enabled high-resolution monitoring of hydrological processes, subsurface deformation, and seismic hazards. Integrating seismic data with hydrological models provides insights into water storage, pore pressure changes, and soil moisture dynamics. However, limitations in spatial resolution, calibration with ground truth data, and coupled effects between environmental factors remain key challenges. This review emphasizes the importance of interdisciplinary approaches in refining methodologies, enhancing sensor deployments, and addressing data gaps. Passive seismic monitoring offers opportunities to understand critical zone processes and their broader impacts on seismic hazards and environmental sustainability.

Comptes Rendus. Géoscience↗
USGS2025

Triple-oxygen isotopic evidence of prolonged direct bioleaching of pyrite with O2

Sulfate is often touted as containing atmospheric oxygen whose isotopic signature can constrain redox, environmental conditions, and biological activity. Yet, the amount and isotopic fractionation associated with air-O 2 incorporation during sulfate formation is still debated, making its verification difficult. In this study, we identify a distinct, microbially dominated environment with the potential to preserve maximum signals of air-O 2 in sulfate. We report triple-oxygen isotope data for sulfate produced from pyrite oxidation in microbial and abiotic experiments, and from natural dissolved sulfate from the Rio Tinto, Spain, an acid mine drainage site. The oxygen isotope systematics of sulfate in these environments define a unique kinetic isotope effect associated with initial stage pyrite oxidation by Acidithiobacillus ferrooxidans that preserves >80 % oxygen from air-O 2 in sulfate. Unlike experiments, which evolve toward water-oxygen dominated sulfate on short time scales, Rio Tinto, Spain hosts a microbe rich environment with distinct geochemistry that maintains high O 2 -oxygen in sulfate. Therefore, in addition to containing isotopic records from water and air, sulfates can also contain a biosignature that is promising for understanding conditions on Mars and early Earth.

Earth and Planetary Science Letters↗
USGS2024

Joint pilot fish habitat framework

This story map will take you through the process of exploring and testing methods necessary for a higher resolution, seamless fish habitat assessment across both inland and estuarine waters through the lens of our joint pilot assessment Fish habitat assessments attempt to relate past, current, or future landscape conditions to the state of fish species occurrence, distribution, abundance, or community and habitat condition in streams, rivers, or estuaries. Previous fish habitat assessments, such as the National Fish Habitat Assessment, conducted separate and disconnected assessments for inland waters and estuaries. In this project, National Oceanic and Atmospheric Administration ( NOAA ) and U.S. Geological Survey ( USGS ) researchers created a seamless spatial framework to allow assessments that integrate influences on fish habitat from headwaters to the estuary. This effort began when the Chesapeake Bay Program Fish Habitat Action Team expressed interest in a Baywide fish habitat assessment spanning tidal salt, tidal fresh, warm non-tidal, and cold non-tidal waters. However, the complexity of the myriad of implementation details to consider when developing such an assessment necessitated the need for a tributary-specific pilot assessment. To conduct this pilot assessment, a NOAA/USGS joint partnership was formed with cooperation and support from the Chesapeake Bay Agreement and Chesapeake Bay Fish Habitat Action Team (FHAT).

Maryland↗
USGS2026

Thermal detectability of subsurface water ice on Mars: A comparative analysis for the Subsurface Water Ice Mapping (SWIM) Project

We have developed a new global map of shallow ground ice distribution, SWIM23, based on Mars Global Surveyor Thermal Emission Spectrometer data and made systematic comparisons between this new map and two similar, previously developed data products. We have explored the origin of differences between the three ice maps by detailing technical and procedural differences in their development, by making global pixel-by-pixel comparisons, and by carrying out a series of one-dimensional thermal simulations to explore fundamental physical limitations of thermal ice-detection techniques. These efforts and the production of a composite thermal ice-consistency map supported integration of multiple geophysical data products relevant to ice detection in the upper meter of the Martian regolith into the larger Mars Subsurface Water Ice Mapping project. Our work also highlights fundamental physical limitations to thermal ice detection as a technique, particularly the rapid fall-off in ice detection sensitivity at depths >30 cm, which produces maximum uncertainty in the presence and depth of ice within regions preferred for potential human landing sites. A future Mars orbiter mission designed to detect ice and support crewed landing site selection in the midlatitude region should give payload priority to an instrument capable of probing the 1–5 m depth range (i.e., a high-frequency radar), over a next-generation thermal spectrometer, which is unlikely to offer clarity on ice table depths or lateral continuity of the ice table in the locations of highest interest.

Planetary Science Journal↗
USGS2026

Groundwater dependency and hydroclimatic influences on riparian and upland vegetation productivity, Upper San Pedro, Arizona, United States

In arid and semi-arid regions, groundwater sustains vegetation through subsurface water access, yet the responses of groundwater-dependent ecosystems (GDEs) to changing hydroclimate and groundwater availability are relatively understudied. This study investigates seasonal and spatial patterns in vegetation greenness using Landsat Enhanced Vegetation Index (EVI) values across riparian and upland zones in the semi-arid Upper San Pedro (USP) watershed, southern Arizona, which experiences a bimodal precipitation regime. We paired 25 years (2000–2024) of EVI and depth to groundwater (DTG) data from 89 wells and climate metrics (precipitation and vapour pressure deficit) to quantify the sensitivity of vegetation to subsurface moisture as well as atmospheric moisture supply and demand. Vegetation at wells near the USP riparian area showed strong associations between EVI and DTG anomalies during the monsoon season, indicating sustained groundwater use even during this wet period when summer precipitation is abundant. In contrast, upland vegetation that lacked access to groundwater showed minimal sensitivity in EVI to DTG and was generally less responsive to vapour pressure deficit. Interestingly, the riparian GDEs were not decoupled from precipitation and climate variability. These results underscore the importance of groundwater for maintaining riparian productivity and highlight the utility of remote sensing in identifying vegetation-climate-groundwater linkages across heterogeneous dryland landscapes.

Arizona↗
USGS2000

Water-quality conditions and relation to drainage-basin characteristics in the Scituate Reservoir Basin, Rhode Island, 1982-95

The Scituate Reservoir Basin covers about 94 square miles in north central Rhode Island and supplies more than 60 percent of the State of Rhode Island's drinking water. The basin includes the Scituate Reservoir Basin and six smaller tributary reservoirs with a combined capacity of about 40 billion gallons. Most of the basin is forested and undeveloped. However, because of its proximity to the Providence, Rhode Island, metropolitan area, the basin is subject to increasing development pressure and there is concern that this may lead to the degradation of the water supply. Selected water-quality constituent concentrations, loads, and trends in the Scituate Reservoir Basin, Rhode Island, were investigated locate parts of the basin likely responsible for exporting disproportionately large amounts of water-quality constituents to streams, rivers, and tributary reservoirs, and to determine whether water quality in the basin has been changing with time. Water-quality data collected between 1982 and 1995 by the Providence Water Supply Board PWSB) in 34 subbasins of the Scituate Reservoir Basin were analyzed. Subbasin loads and yields of total coliform bacteria, chloride, nitrate, iron, and manganese, estimated from constituent concentrations and estimated mean daily discharge records for the 1995 water year, were used to determine which subbasins contributed disproportionately large amounts of these constituents. Measurements of pH, color, turbidity, and concentrations of total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese made between 1982 and 1995 by the PWSB were evaluated for trends. To determine the potential effects of human-induced changes in drainage- basin characteristics on water quality in the basin, relations between drainage-basin characteristics and concentrations of selected water-quality constituents also were investigated. Median values for pH, turbidity, total coliform bacteria, sodium, alkalinity, chloride, nitrate, and iron were largest in subbasins with predominately residential land use. Median instantaneous loads reflected drainage-basin size. However, loads normalized by drainage area (median instantaneous yields) also were largest in residential areas where point and non-point sources are likely, and in areas of poorly drained soils. Significant trends in water-quality constituents from 1982 to 1995 in the Scituate Reservoir Basin indicate that the quality of the water resources in the basin may be slowly changing. Scituate Reservoir subbasins with large amounts of residential land use showed increasing trends in alkalinity and chloride. In contrast, subbasins distributed throughout the drainage basin showed increasing trends in pH, color, nitrate, and iron concentrations, indicating that these characteristics and constituents may be affected more by atmospheric deposition. Although changing, water-quality constituent concentrations in the Scituate Reservoir Basin only occasionally exceeded Rhode Island and USEPA water-quality guidelines and standards. Result of correlation analysis between pH, color, turbidity, and concentrations total coliform bacteria, sodium, alkalinity, chloride, nitrate, orthophosphate, iron, and manganese and land use, geology, wetlands, slope, soil drainability, and roads indicated that the percentage of wetlands, roads, and slope appear have the greatest effect on water-quality in the Scituate Reservoir Basin. The percentage of urban, residential, and commercial land use also are important, but to a lesser degree than wetlands, roads, and slope. Finally, geology appears to have the least effect on water quality compared to other drainage-basin characteristics investigated.

Rhode Island↗
USGS2025

VIPER site analysis

We needed to evaluate available orbital data of NASA’s Volatiles Investigating Polar Exploration Rover (VIPER) mission area in order to derive a variety of maps to help the science team identify scientifically interesting places for the rover to visit and to provide scientific context for our mission. Some of these maps also fulfilled engineering and mission design needs to enable safe and efficient landing and roving. We incorporated data from the Lunar Reconnaissance Orbiter Camera, the Lunar Orbital Laser Altimeter, the Mini-RF instrument, the Chandrayaan-2 Orbital High Resolution Camera, the Korean Pathfinder Lunar Orbiter’s Shadowcam, the Kaguya Spectral Profiler and Multiband Imager, and the Chandrayaan-1 Moon Mineralogy Mapper. We used a variety of techniques to build these maps, including stereogrammetry, shape-from-shading, ice stability depth and surface temperature calculations, and the horizon method for solar illumination and direct-to-Earth communications maps. Altogether, these maps allowed us to survey for boulders, evaluate features in permanently shadowed regions that VIPER might explore, provide mineralogic context for what VIPER’s instruments may learn, estimate the ages and radar properties of craters in the VIPER mission area, and evaluate the potential for gravity traverses with the rover. These data and techniques provided a rich set of information from which both the VIPER science team and engineering teams were able to draw in order to plan a safe landing and to plan a VIPER surface mission that will be both scientifically valuable and robust from an operational perspective.

The Planetary Science Journal↗
USGS2025

Gaps in water quality modeling of hydrologic systems

This review assesses gaps in water quality modeling, emphasizing opportunities to improve next-generation models that are essential for managing water quality and are integral to meeting goals of scientific and management agencies. In particular, this paper identifies gaps in water quality modeling capabilities that, if addressed, could support assessments, projections, and evaluations of management alternatives to support ecosystem health and human beneficial use of water resources. It covers surface water and groundwater quality modeling, dealing with a broad suite of physical, biogeochemical, and anthropogenic drivers. Modeling capabilities for six constituents (or constituent categories) are explored: water temperature, salinity, nutrients, sediment, geogenic constituents, and contaminants of emerging concern. Each constituent was followed through the coupled atmospheric-hydrologic-human system, with prominent modeling gaps described for a diverse array of relevant inputs, processes, and human activities. Commonly identified modeling gaps primarily fall under three types: (1) model gaps, (2) data gaps, and (3) process understanding gaps. In addition to potential solutions for addressing specific individual modeling limitations, some broad approaches (e.g., enhanced data collection and compilation, machine learning, reduced-complexity modeling) are discussed as ways forward for tackling multiple gaps. This gap analysis establishes a framework of diverse approaches that may support improved process representation, scale, and accuracy of models for a wide range of water quality issues.

Water↗
USGS2026

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont↗
USGS1998

Assessment of the hydraulic connection between ground water and the Peace River, west-central Florida

The hydraulic connection between the Peace River and the underlying aquifers along the length of the Peace River from Bartow to Arcadia was assessed to evaluate flow exchanges between these hydrologic systems. Methods included an evaluation of hydrologic and geologic records and seismic-reflection profiles, seepage investigations, and thermal infrared imagery interpretation. Along the upper Peace River, a progressive long-term decline in streamflow has occurred since 1931 due to a lowering of the potentiometric surface of the Upper Floridan aquifer by as much as 60 feet because of intensive ground-water withdrawals for phosphate mining and agriculture. Another effect from lowering the potentiometric surface has been the cessation of flow at several springs located near and within the Peace River channel, including Kissengen Spring, that once averaged a flow of about 19 million gallons a day. The lowering of ground-water head resulted in flow reversals at locations where streamflow enters sinkholes along the streambed and floodplain. Hydrogeologic conditions along the Peace River vary from Bartow to Arcadia. Three distinctive hydrogeologic areas along the Peace River were delineated: (1) the upper Peace River near Bartow, where ground-water recharge occurs; (2) the middle Peace River near Bowling Green, where reversals of hydraulic gradients occur; and (3) the lower Peace River near Arcadia, where ground-water discharge occurs. Seismic-reflection data were used to identify geologic features that could serve as potential conduits for surface-water and ground-water exchange. Depending on the hydrologic regime, this exchange could be recharge of surface water into the aquifer system or discharge of ground water into the stream channel. Geologic features that would provide pathways for water movement were identified in the seismic record; they varied from buried irregular surfaces to large-scale subsidence flexures and vertical fractures or enlarged solution conduits. Generally, the upper Peace River is characterized by a shallow, buried irregular top of rock, numerous observed sinkholes, and subsidence depressions. The downward head gradient provides potential for the Peace River to lose water to the ground-water system. Along the middle Peace River area, head gradients alternate between downward and upward, creating both recharging and discharging ground-water conditions. Seismic records show that buried, laterally continuous reflectors in the lower Peace River pinch out in the middle Peace River streambed. Small springs have been observed along the streambed where these units pinch out. This area corresponds to the region where highest ground-water seepage volumes were measured during this study. Further south, along the lower Peace River, upward head gradients provide conditions for ground-water discharge into the Peace River. Generally, confinement between the surficial aquifer and the confined ground-water systems in this area is better than to the north. However, localized avenues for surface-water and ground-water interactions may exist along discontinuities observed in seismic reflectors associated with large-scale flexures or subsidence features. Ground-water seepage gains or losses along the Peace River were quantified by making three seepage runs during periods of: (1) low base flow, (2) high base flow, and (3) high flow. Low and high base-flow seepage runs were performed along a 74-mile length of the Peace River, between Bartow and Nocatee. Maximum losses of 17.3 cubic feet per second (11.2 million gallons per day) were measured along a 3.2-mile reach of the upper Peace River. The high-flow seepage run was conducted to quantify losses in the Peace River channel and floodplain between Bartow and Fort Meade. Seepage losses calculated during high-flow along a 7.2-mile reach of the Peace River, from the Clear Springs Mine bridge to the Mobil Mine bridge, were approximately 10 percent of the river flow, or 118 cubic feet per second. Calculated seepages along the Peace River in Hardee and De Soto Counties were inconclusive, because most seepages were within the range of discharge measurement error. Two continuous aerial thermal infrared imagery surveys were conducted to locate sites of ground-water discharge along the Peace River. Although temperature and hydrologic conditions were ideal to observe spring flow using thermal infrared imaging techniques, no sources of ground-water discharge were identified using this method. Diffuse ground-water seepage may, however, provide significant ground-water discharge.

Florida↗