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Correlation analysis of groundwater and hydrologic data, Kaloko-Honokōhau National Historical Park, Hawai‘i

Designated in 1978, Kaloko-Honokōhau National Historical Park is located on the west coast of the Island of Hawaiʻi. The Kaloko-Honokōhau National Historical Park encompasses about 1,200 acres of coastal land and nearshore ecosystems, which include wetlands, anchialine pools (landlocked bodies of brackish water with hydrologic connections to the ocean), fishponds, a fishtrap, and coral reefs. These nearshore ecosystems are dependent on groundwater discharge with a freshwater component and provide habitat for threatened and endangered, endemic species, such as the orangeblack Hawaiian damselfly ( Megalagrion xanthomelas ) and the Hawaiian coot (ʻAlae keʻokeʻo, Fulica alai ). The populations of these native species, however, are threatened because of habitat loss related to urban development and environmental changes. Kaloko-Honokōhau National Historical Park is within the Keauhou aquifer system and the North Kona District, which experienced a 52 percent resident-population increase between 2000 and 2020 and a 41 percent visitor increase between 2008 and 2019. To support the current water demand associated with this growing population, groundwater is the primary source of freshwater used in the North Kona District, with about 15 million gallons of groundwater withdrawn from the Keauhou aquifer system per day since 2009. With anticipated development, future (2015–35) groundwater withdrawal from the Keauhou aquifer system is projected to be about 55 percent greater than recent (2012–14) withdrawal. Because Kaloko-Honokōhau National Historical Park is located within a coastal aquifer, natural and human-induced changes can affect the quality and quantity of groundwater, which can threaten groundwater-dependent ecosystems. To improve understanding of recent groundwater conditions, the U.S. Geological Survey, in cooperation with the National Park Service, undertook this study to document correlations between hydrologic time-series datasets from sites in and near Kaloko-Honokōhau National Historical Park using the nonparametric (distribution-free) Kendall’s tau statistical test. For the statistical analyses, dependent variables representing the groundwater system include groundwater level, the groundwater-level difference between pairs of sites, and specific conductance, and independent variables include datasets of sea level, rainfall, and groundwater withdrawal. About 34 percent of the 140 non-time-lagged Kendall’s tau statistical tests evaluated in this report are statistically significant ( p -value ≤ 0.050) with generally weak (0.1 ≤ tau ≤ 0.2) to moderate (0.2 ≤ tau ≤ 0.3) correlations. Groundwater levels measured at monitoring sites have the strongest correlation with the multivariate El Niño–Southern Oscillation index and withdrawal from production wells at the nearby Kohanaiki Private Club Community. Specific conductance is not consistently and significantly correlated with the independent hydrologic variables investigated in this report. Because the relations between hydrologic variables are commonly not instantaneous, a second set of correlations was evaluated after applying a range of time lags to the independent variable datasets. Relative to the non-time-lagged case (the set of correlations that did not use time-lagged independent variables), some of the time-lagged independent variables improved correlations with some of the dependent variables. For a particular independent variable, similar time lags were expected between the independent variable and dependent variable at all four monitoring sites. However, different time lags among the four sites sometimes produced the strongest correlations. This study identified several correlations that are statistically significant and hydrologically plausible, but the correlations could indicate that multiple concurrent factors are controlling the observed groundwater-system response, which might be better addressed using multivariate analyses. This study only investigates bivariate correlations, which may not explain all the variance in the data. The correlations analyzed in this report are limited by the quantity of available hydrologic data in the area near Kaloko-Honokōhau National Historical Park and are based on 14 years of time-series data, which were aggregated to a relatively coarse monthly temporal resolution that represents the minimum resolution common to all datasets.

Hawaii

Seismic velocity changes from repetitive seismicity at Mauna Loa prior to and during its 2022 eruption

Mauna Loa’s short-lived eruption from late November to early December 2022 marked the culmination of nearly a decade of elevated seismic activity and geodetic inflation. The volcano has been monitored by a network of permanent, short period and broadband seismometers. I used the continuous waveform data from that network starting in 2012 to generate a catalog of seismicity that enhances the US Geological Survey Hawaiian Volcano Observatory’s public seismic catalog with four times the number of earthquakes, which were then grouped by waveform similarity. Analysis of subtle delays in the timing of arrivals of scattered waves between pairs of earthquakes in this catalog yields a history of small changes in the shallow seismic velocity structure of the volcano. Seismic velocities have been shown at other volcanoes to change during unrest and eruption. My results show a decrease in seismic velocity centered on the summit beginning in September 2022, corresponding to the onset of a vigorous precursory swarm of seismic activity and shallow inflation. During the eruption itself, I observe large changes due likely to dike opening along the northeast rift zone and deflation of the summit reservoir. However, seismic velocity changes associated with non-volcanic sources such as ground shaking from large earthquakes and meteorological influences at seasonal and diurnal time scales are also observed, and these dominate the velocity changes prior to the eruption. Proper accounting of these effects will be a requirement for use in real-time monitoring, and this work serves as a starting point in that endeavor for Mauna Loa.

Hawaii

Earthquake rupture arrest from depth‐dependent frictional stability on the Pütürge segment of the East Anatolian Fault Zone, Türkiye (Turkey)

Determining why earthquake ruptures stop is a central challenge in earthquake science and seismic hazard assessment. The Pütürge segment of the East Anatolian Fault Zone, Türkiye, exhibits shallow creep (<∼3 km depth) yet hosts M > 6.5 earthquake ruptures at greater depth. Here, we evaluate whether variations in frictional stability along this segment aided arrest of the 2020 M 6.7 Elaziğ and 2023 M 7.8 Pazarcık earthquake ruptures. Analysis of Sentinel‐1 Synthetic Aperture Radar imagery indicates the 2023 M 7.8 rupture propagated laterally into a metamorphic massif within the Pütürge segment, where slip rapidly decayed below detection limits. Creepmeters along this segment recorded no significant surface afterslip (<3 mm) in the following year. To investigate this fault‐slip behavior, we conducted triaxial friction experiments on Pütürge fault gouge sampled from an outcrop exposure. The gouge, composed primarily of muscovite, quartz, and calcite, is velocity strengthening at conditions approximating 0–2.5 km depth and velocity weakening at 4–5 km depth. This transition to velocity‐weakening friction is associated with enhanced comminution and shear localization observed microstructurally. Our results suggest that depth‐dependent frictional stability of the Pütürge fault segment facilitates rupture nucleation and propagation at depth while maintaining rupture‐arresting behavior near Earth’s surface.

Pütürge segment of the East Anatolian Fault Zone

Critical minerals in mine waste

Introduction Critical minerals are commodities with vulnerable supply chains that play a vital role in supporting the United States’ economy, national defense and security, emerging technologies, and energy independence. The prosperity of our Nation depends on generating a resilient supply of domestic critical minerals; mine waste may be an untapped source of these commodities. Mine waste from centuries of legacy mining persist on the landscape and may contain critical minerals and other valuable commodities previously deemed uneconomic to recover. At modern mines, the financial viability of recovering byproduct critical minerals, which are not the primary target, may be marginal and can ultimately destine them to mine waste. Further, mine waste can be a liability for the mining company or, at legacy mines, the taxpayer because of its effect on the landscape. The U.S. Geological Survey (USGS) has several initiatives to evaluate critical mineral resources in various types of waste. This factsheet highlights studies of mine waste carried out by USGS scientists at the Geology, Energy & Minerals Science Center in collaboration with other science centers funded through the USGS Mineral Resources Program. Recovery of critical minerals from mine waste can aid in remediation efforts and increase domestic supply of vital mineral resources.

Fact Sheet

Preventing overfitting when using tree-based methods for mapping hydrothermal favorability

Ensemble tree-based algorithms are robust tools for estimating sparsely distributed resources with non-linear dependencies (e.g., hydrothermal systems). These algorithms naturally accommodate the threshold conditions necessary to enable and support hydrothermal systems (e.g., having sufficient heat and permeability) and are simpler than many other non-linear machine learning strategies (e.g., artificial neural networks), which is an advantage when working with few labeled examples from which to learn. In previous work, we used eXtreme Gradient Boosting (XGBoost) to produce regional prediction and uncertainty maps of hydrothermal favorability; however, recent studies suggest that, even when properly applied, XGBoost has some risk of overfitting when there are few labeled examples from which to learn. To evaluate overfitting when constructing hydrothermal favorability maps with tree-based methods, we compare XGBoost with Extremely Randomized Trees (ExtraTrees), another ensemble tree-based algorithm that has the potential to underfit when using few labeled examples. We hold all other modeling parameters constant, resulting in two contrasting favorability maps of conventional geothermal resources for the Great Basin. Our results indicate that ExtraTrees demonstrably reduces overfitting compared with XGBoost. After considering overall performance, we conclude that ExtraTrees provides a more suitable modeling approach than XGBoost for the purposes of conventional hydrothermal resource assessments.

Conference Paper

Seismicity zoning at Coso geothermal field and stress changes from fluid production and migration

The Coso geothermal field is a major geothermal power production site in the western United States. It has been observed that low-magnitude seismic events ( M < 3.71) are unevenly distributed in three distinct zones, namely, nearfield (<3 km), midfield (3–6 km), and farfield (> 6 km) from the Coso geothermal plant. These zones exhibit distinct changes in earthquake location before and during geothermal production episodes that began in 1986. After 1986, the midfield region of the main flank experiences a significantly lower seismicity rate than the surrounding areas before production episodes. During 2014–2019, the farfield earthquakes cluster in the eastern and western parts of the greater Coso area, which is discernably different from how those pre-production earthquake events were distributed along the conjugate NW-SE and SW-NW trending structures across the main flank. Here, we analyze the stage of stress with finite-element-based poroelastic simulations to illustrate how the spatiotemporal evolution of the seismicity is associated with the pattern of stress perturbations caused by fluid migration amid the operations of geothermal power plants. Generally, ∼70% of co-production seismicity is found in zones of increased Coulomb stress between 2014 and 2019 at >99% confidence. Meanwhile, the midfield zone of seismic paucity overlaps with the zone of decreasing pore-fluid pressure. Overall, the results provide a physical explanation of how decadal geothermal operations at Coso have perturbed stress-field changes and contributed to the evolving characteristic seismic pattern, shedding insights into assessing the seismic hazard in other geothermal settings.

California

An inset groundwater-flow model to evaluate the effects of layering configuration on model calibration and assess managed aquifer recharge near Shellmound, Mississippi

The U.S. Geological Survey has developed a high-resolution inset groundwater-flow model in the Mississippi Delta as part of an interdisciplinary collaboration coordinated by the Mississippi Alluvial Plain project to provide a tool that stakeholders can use to support water-resource management decisions. Groundwater withdrawals from the Mississippi River Valley alluvial (MRVA) aquifer have been vital to support agricultural production in the region, but substantial groundwater-level declines near Shellmound, Mississippi, have caused concerns for long-term sustainability of the aquifer. To better understand the subsurface and try to mitigate the long-term groundwater-level declines, stakeholders have undertaken actions including a Groundwater Transfer and Injection Pilot (GTIP) project using a riverbank filtration-based managed aquifer recharge approach. The pilot project consisted of extracting groundwater near the Tallahatchie River and reinjecting it into the aquifer 3 kilometers west where water levels have substantially declined. A high-resolution airborne electromagnetic (AEM) survey was also completed to collect electrical resistivity data to support the GTIP project and the development of the groundwater model. The inset groundwater-flow model was developed to (1) integrate the AEM data into the optimal layering configuration of the MRVA aquifer that the available observation data can support through calibration, and (2) assess the potential effect of the GTIP project on the groundwater levels. The AEM data were processed into three different layering configurations leading to the development of model A (18 layers), model B (16 layers), and model C (8 layers), all at a 100- x 100-meter cell spatial resolution using the U.S. Geological Survey modular finite-difference flow model 6 code with Newton-Raphson formulation. The model development process integrated recent advances in modeling, such as the incorporation of AEM data, the use of outputs from the soil-water-balance (SWB) model, and the Aquaculture and Irrigation Water-Use Model, and was facilitated by robust automation using the open-source python packages Modflow-setup and SFRmaker. Using Parameter Estimation ++ Iterative Ensemble Smoother, the three numerical groundwater-flow models (models A, B, and C) were calibrated against a set of observations, which included aquifer groundwater levels, streamflows, stream stage, and aquifer transmissivity. Results indicate that the detailed representation of MRVA aquifer layers in model A produced the best calibrated model by history matching, and the integration of data representing surficial connectivity played a key role in improving groundwater recharge and enhancing the ability of the model to match groundwater levels in the cone of depression. A forecast model simulated the managed aquifer recharge approach, and the results indicated that, given average irrigation and recharge conditions (2010–15), the GTIP project has the potential to induce groundwater-level increases of as much as 3 meters around the injection site, but a sustained increase would require repetition in subsequent years of water transfer at 2022 rates or above.

Mississippi

Cursed? Why one does not simply add new data sets to supervised geothermal machine learning models

Recent advances in machine learning (ML) identifying areas favorable to hydrothermal systems indicate that the resolution of feature data remains a subject of necessary improvement before ML can reliably produce better models. Herein, we consider the value of adding new features or replacing other, low-value features with new input features in existing ML pipelines. Our previous work identified stress and seismicity as having less value than the other feature types (i.e., heat flow, distance to faults, and distance to magmatic activity) for the 2008 USGS hydrothermal energy assessment; hence, a fundamental question regards if the addition of new but partially correlated features will improve resulting models for hydrothermal favorability. Therefore, we add new maps for shear strain rate and dilation strain rate to fit logistic regression and XGBoost models, resulting in new 7-feature models that are compared to the old 5-feature models. Because these new features share a degree of correlation with the original relatively uninformative stress and seismicity features, we also consider replacement of the two lower-value features with the two new features, creating new 5-feature models. Adding the new features improves the predictive skill of the new 7-feature model over that of the old 5-feature model; albeit, that improvement is not statistically significant because the new features are correlated with the old features and, consequently, the new features do not present considerable new information. However, the new 5-feature XGBoost model has a statistically significant increase in predictive skill for known positives over the old 5-feature model at p = 0.06. This improved performance is due to the lower-dimensional feature space of the former than that of the latter. In higher-dimensional feature space, relationships between features and the presence or absence of hydrothermal systems are harder to discern (i.e., the 7-feature model likely suffers from the “curse of dimensionality”).

Geothermal Resources Council Transactions

Development of a hydrologic flow model of the Zuñi Salt Lake and surrounding areas, west-central New Mexico

The terminal Zuñi Salt Lake is in a maar in west-​central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. The U.S. Geological Survey (USGS), in cooperation with the Zuni Tribe of the Zuni Reservation, New Mexico, and Bureau of Reclamation, developed the Zuñi Salt Lake hydrologic flow model to simulate the steady-state conditions of the lake and surrounding groundwater-flow system. The model is a tool that can be used to analyze the potential hydrologic responses to resource development in the region under different water-use scenarios, which can support negotiations that could help protect future use of the lake. The USGS modular hydrologic model, MODFLOW 6, was used to simulate the hydrologic system of the lake and surrounding areas. To define the layering of the model, a three-dimensional hydrogeologic framework was constructed, which included seven informal hydrogeologic units and the locations of faults that truncate and offset the units. Calibration of the model was performed using the iterative ensemble smoother included in a parameter estimation software suite (PEST++). The iterative ensemble smoother approach resulted in a posterior parameter ensemble of model realizations with parameter and simulated values that show similar success in matching observations. Groundwater flux to the Zuñi Salt Lake simulated by using the posterior parameter distribution ranged from 26 to 730 acre-feet per year with a mean, median, and standard deviation of 530, 570, and 170 acre-feet per year, respectively. The relative contribution of groundwater discharge to the lake was simulated using a particle-tracking model for MODFLOW (MODPATH) to be from, in order of decreasing contribution, the Mesaverde, Cenozoic, Mancos, and Dakota hydrogeologic units. Simulations of future conditions using the ensemble of models can provide an empirical estimate of forecast uncertainty without substantial additional analysis.

New Mexico

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research

PFAS mixture composition and internal exposure profiles shape biological responses under field-realistic exposure

Per- and polyfluoroalkyl substances (PFAS) occur as complex mixtures, yet mixture-dependent biological effects under environmentally realistic exposure conditions remain poorly understood. We conducted multiyear (2018, 2019, 2021) continuous-flow, field-based exposures of male fathead minnows ( Pimephales promelas ) using a low-PFAS reference well (REF; sum of measured PFAS (∑PFAS) 0.1–0.2 μg L –1 ) and PFAS-contaminated groundwater from a fire-training area (FTA) at Joint Base Cape Cod, Massachusetts. Dilution treatments enabled separation of concentration and mixture effects. Groundwater from well FTA1 was perfluorooctanesulfonate (PFOS) dominated (∑PFAS 10–31 μg L –1 ), whereas groundwater from well FTA2 had higher concentrations and was enriched in perfluorooctanoate (PFOA) and diverse precursors (∑PFAS ∼ 80 μg L –1 ). Despite comparable plasma ∑PFAS and PFOS in FTA1–100% and FTA2–50% on day-7, cumulative mortality reached approximately 35% in FTA2–50% and 17% in FTA2–100%, and secondary sex trait expression was reduced by approximately 65–80% relative to REF, whereas sperm motility effects were mixture- and time-dependent. Plasma PFAS profiles were dominated by perfluorohexanesulfonate (PFHxS), PFOS, and sulfonamide precursors. Liver transcriptomics from REF-acclimated fish revealed robust disruption of metabolic, mitochondrial, and endocrine pathways that link PFAS mixture chemistry and internal exposure profiles to organismal outcomes, and testis transcriptomics provided complementary insight into reproductive impairment. These results indicate that PFAS mixture composition and internal exposure profiles, including precursor-associated differences, are important determinants of ecotoxicological outcomes under field-realistic conditions.

Massachusetts

Interplay between tectonics and submarine mass transport deposits in Cortes Basin: New high-resolution geophysics in the Outer California Borderland

The Outer California Borderland (OCB) is an active transform plate boundary offshore Southern California, where the relationship between faulting and submarine mass transport deposits (MTDs) remains poorly understood. Onshore paleoseismic data provide high-resolution earthquake records, whereas marine geophysical data capture longer-term histories. Offshore fault systems pose hazards to infrastructure and dense coastal populations, particularly when linked to submarine landslides. We present new high-resolution geophysical data set (cruise SR2303), including bathymetric and CHIRP sub-bottom data integrated with legacy seismic reflection data and chronostratigraphic constraints from ODP Site 1012 to examine Quaternary MTD recurrence and tectonic controls in the Cortes Basin, OCB. Bathymetry shows deformational features, including slide scarps and previously unmapped fault segments with evidence of Holocene activity. CHIRP profiles reveal 10 stacked MTDs in the East Cortes Basin and 8 in the West Cortes Basin, spanning ∼752 ka with an average recurrence of ∼83.6 ± 1 ka. Acoustic imaging shows 7 MTD intervals coinciding with fault offset increments and fault growth suggesting earthquake-triggered mass wasting. A strong association between MTD occurrences and sea-level extremes also supports glacio-eustatic contribution to slope failure. Stratigraphic correlations suggest quasi-synchronous MTDs across the eastern and western areas, likely triggered by larger eathquakes in the Quaternary. Although the identified MTDs occur relatively far from the Southern California coast, they still pose a potential tsunamigenic hazard requiring further assessment. Moreover, if linked to earthquakes along major strike-slip faults, for example, the Ferrelo fault, the MTDs may provide valuable proxies to constrain rupture scenarios and fault connectivity within the understudied OCB.

California

Invasion of perennial sagebrush steppe by shallow-rooted exotic cheatgrass reduces stable forms of soil carbon in a warmer but not cooler ecoregion

Soil organic carbon ('SOC') in drylands comprises nearly a third of the global SOC pool and has relatively rapid turnover and thus is a key driver of variability in the global carbon cycle. SOC is also a sensitive indicator of longer-term directional change and disturbance-responses of ecosystem C storage. Biome-scale disruption of the dryland carbon cycle by exotic annual grass invasions (mainly Bromus tectorum, 'Cheatgrass') threatens carbon storage and corresponding benefits to soil hydrology and nutrient retention. Past studies on cheatgrass impacts mainly focused on total C, and of the few that evaluated SOC, none compared the very different fractions of SOC, such as relatively unstable particulate organic carbon (POC) or relatively stable, mineral-associated organic carbon (MAOC). We measured SOC and its POC and MAOC constituents in the surface soils of sites that had sagebrush canopies but differed in whether their understories had been invaded by cheatgrass or not, in both warm and relatively colder ecoregions of the western USA. MAOC stocks were 36.1% less in the 0–10 cm depth and 46.1% less in the 10–20 cm depth in the cheatgrass-invaded stands compared to the uninvaded stands of the warmer Colorado Plateau, but not in the cooler and more carbon-rich Wyoming Basin ecoregion. In plots where cheatgrass increased SOC, it was via unstable POC. These findings indicate that cheatgrass effects on the distribution of soil carbon among POC and MAOC fractions may vary among ecoregions, and that cheatgrass can reduce forms of carbon that are otherwise considered stable and 'secure', i.e. sequestered.

Environmental Research Communications

Ductile and brittle Rio Grande Rift deformation in Oligocene granite records a two-stage rift history in southern Colorado

The timing and nature of early deformation in the Rio Grande Rift remains poorly constrained. We present evidence for the earliest structural signature of rift extension in the Sangre de Cristo Range, southern Colorado, based on new geologic mapping, structural analysis, rock magnetic data, and thermochronology. These analyses focus on the ~30.0 Ma granite of Chokecherry Canyon, which hosts discrete low-angle mylonitic shear zones and a distributed, gently SW-dipping protomylonitic fabric. Incremental stretching axes, stretching lineations, and Kmax magnetic lineations plunge gently WSW. Quartz microstructures and crystallographic orientations indicate dominantly coaxial strain in the protomylonite and general shear in the discrete shear zones. Quartz c-axis opening-angle thermometry suggests deformation at ~420–540°C. Thermal modeling of ⁴⁰Ar/³⁹Ar K-feldspar data indicates rapid post magmatic cooling below the brittle–plastic transition, supporting shear-zone formation immediately after emplacement. Slow cooling from ~20–13 Ma was followed by renewed rapid cooling at ~13 Ma, interpreted as the onset of extensional exhumation along the Sangre de Cristo Fault System. These results show that extension in the northern Rio Grande Rift was active by ~30 Ma, earlier than previously recognized. We propose a two-stage model for northern Rio Grande Rift evolution: Stage I (30–23 Ma) records ENE–WSW extension localized in low-angle mylonitic shear zones associated with mid-crustal intrusions; Stage II (≤18 Ma) reflects brittle high-angle normal faulting, focused exhumation, and rift narrowing. Stage I magmatism and deformation along the western range front likely established crustal weaknesses that guided later fault development.

Colorado

New Hampshire and Landsat

At its widest point, a mere 80 miles separate the eastern and western borders of New Hampshire. Its northern and southern borders are just 175 miles apart. Even so, few States can boast as much rugged natural beauty per mile as the Nation’s fifth smallest. Nestled within New Hampshire are 93 State parks teeming with moose, Ursus americanus (Pallas, 1780; black bears), coyotes, beavers, river otters, and foxes. The largest section of White Mountain National Forest cuts across north-central New Hampshire, drawing visitors to its lakes, streams, mountain peaks, and hardwood forests. New Hampshire also is home to Lake Winnipesaukee, the State’s largest lake, notable for its floating post offices, the annual “ice-out” contest that sees residents vying to guess the date its surface ice dissipates, and its supporting role in films such as “On Golden Pond” and “What About Bob?” However, the scenic forests of New Hampshire face challenges in the form of invasive species such as Lymantria dispar (Linnaeus, 1758; spongy moth), Adelges piceae (balsam woolly adelgid), and Agrilus planipennis (emerald ash borer). In recent years, New Hampshire’s lakes and streams have seen more cyanobacterial blooms as well. The U.S. Geological Survey Landsat Program offers a consistent, reliable, and historically unmatched source of Earth observations that can aid in the mapping, monitoring, and management of New Hampshire’s land and water resources. Here are a few ways Landsat data have been used in the Granite State.

New Hampshire

Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors

Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.

Life

Intense alteration on early Mars revealed by high-aluminum rocks at Jezero Crater

The NASA Perseverance rover discovered light-toned float rocks scattered across the surface of Jezero crater that are particularly rich in alumina ( ~ 35 wt% Al 2 O 3 ) and depleted in other major elements (except silica). These unique float rocks have heterogeneous mineralogy ranging from kaolinite/halloysite-bearing in hydrated samples, to spinel-bearing in dehydrated samples also containing a dehydrated Al-rich phase. Here we describe SuperCam and Mastcam-Z observations of the float rocks, including the first in situ identification of kaolinite or halloysite on another planet, and dehydrated phases including spinel and apparent partially dehydroxylated kaolinite. The presence of spinel in these samples is likely detrital in origin, surviving kaolinitization, pointing to an ultramafic origin. However, the association of low hydration with increased Al 2 O 3 abundances suggests heating-induced dehydration which could have occurred during the lithification or impact excavation of these rocks. Given the orbital context of kaolinite-bearing megabreccia in the Jezero crater rim, we propose an origin for these rocks involving intense aqueous alteration of the parent material, followed by dehydration/lithification potentially through impact processes, and dispersion into Jezero crater through flood or impact-related processes.

Communications Earth & Environment

Global maps of critical mineral production in 2023

Introduction The global production of many mineral commodities, especially critical minerals, is concentrated in a few countries that have mineral resources and the infrastructure necessary to mine and process those resources. For this reason, the type and amount of mineral production differ by country. For example, many countries produce such metallic ores as gold and silver, whereas only a few countries produce magnesium, niobium, platinum-group metals, and rare earths. The concentration of mining and processing in certain countries necessitates the existence of a global supply chain. A mineral supply chain is the sequence of mining and processing of minerals and manufacturing of products. Mineral supply chains are global in scale, complex, and dynamic. Supply chain data can be used to understand how a country’s mineral resources and various economic, technical, and environmental factors affect the complexity of global supply chains. This fact sheet summarizes the world’s leading countries (those accounting for 5 percent or more of a commodity’s global production in 2023) for production of select mineral commodities (mainly critical minerals) in the mining and processing stages. These countries and the minerals they produce are synthesized on global maps to communicate the status of, and potential risk to, mineral commodity supply chains from geographic production concentration. Trade data from United Nations Statistics Division (2025) is used to support assessments of the observed production data.

Fact Sheet