SEARCH · Geology Reports

Results for “Minerals and the Environment”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 667 records · Page 37Linked to original sources

USGS2020

Mars orbiter for resources, ices, and environments (MORIE)

The MORIE mission concept study examined the science and technical trade space to address high priority questions related to ice reservoirs and environmental transitions. The study team converged on a medium-class SEP-enabled orbiter with seven instruments to unlock the extent and volume of subsurface ice and geologic sequence stratigraphy through time. Observations would include the first radar imaging from orbit, the first radar sounding directly over the poles, and surface mineral mapping at unprecedented spatial scales.

Planetary Science Decadal Survey, Planetary Missio↗

USGS2002

Strontium isotopic signatures of the streams and lakes of Taylor Valley, Southern Victoria Land, Antarctica: Chemical weathering in a polar climate

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different 87Sr/86Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system could be either the Cenozoic volcanic rocks that make up a small portion of the till deposited in the valley during the Last Glacial Maximum or from marble derived from the local basement rocks. The more radiogenic ratios from Lake Bonney originate from ancient salt deposits that flow into the lake from Taylor Glacier and the weathering of minerals with more radiogenic Sr isotopic ratios within the tills. The Sr isotopic data from the streams and lakes of Taylor Valley strongly support the notion documented by previous investigators that chemical weathering has been, and is currently, a major process in determining the overall aquatic chemistry of these lakes in this polar desert environment.

Aquatic Geochemistry↗

USGS2009

A synthesis of Martian aqueous mineralogy after 1 Mars year of observations from the Mars Reconnaissance Orbiter

Martian aqueous mineral deposits have been examined and characterized using data acquired during Mars Reconnaissance Orbiter's (MRO) primary science phase, including Compact Reconnaissance Imaging Spectrometer for Mars hyperspectral images covering the 0.4-3.9 ??m wavelength range, coordinated with higher-spatial resolution HiRISE and Context Imager images. MRO's new high-resolution measurements, combined with earlier data from Thermal Emission Spectrometer; Thermal Emission Imaging System; and Observatoire pour la Min??ralogie, L'Eau, les Glaces et l'Activiti?? on Mars Express, indicate that aqueous minerals are both diverse and widespread on the Martian surface. The aqueous minerals occur in 9-10 classes of deposits characterized by distinct mineral assemblages, morphologies, and geologic settings. Phyllosilicates occur in several settings: in compositionally layered blankets hundreds of meters thick, superposed on eroded Noachian terrains; in lower layers of intracrater depositional fans; in layers with potential chlorides in sediments on intercrater plains; and as thousands of deep exposures in craters and escarpments. Carbonate-bearing rocks form a thin unit surrounding the Isidis basin. Hydrated silica occurs with hydrated sulfates in thin stratified deposits surrounding Valles Marineris. Hydrated sulfates also occur together with crystalline ferric minerals in thick, layered deposits in Terra Meridiani and in Valles Marineris and together with kaolinite in deposits that partially infill some highland craters. In this paper we describe each of the classes of deposits, review hypotheses for their origins, identify new questions posed by existing measurements, and consider their implications for ancient habitable environments. On the basis of current data, two to five classes of Noachian-aged deposits containing phyllosilicates and carbonates may have formed in aqueous environments with pH and water activities suitable for life. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS1981

Sediment parameters for a fine-grained sediment deposit on the southeastern New England continental shelf

An area of fine-grained sediments south of Martha's Vineyard, Massachusetts, has been interpreted as a contemporary deposit. Textural analysis of cores from this area indicates that the deposit consists of sandy to clayey silts overlying a well sorted relict sand. The maximum thickness of the fine sediments is about 6 meters as determined from a core near the center of this deposit. The mineralogy of the <2 um size fraction is similar in both the fine sediments of the contemporary deposit and the underlying coarse sands. The assemblage consists of about 60% illite, 20% chlorite, and 10% kaolinite with minor amounts of mixed-layered clay and smectites. Heavy mineral analysis from a core near the center of the deposit reveals that opaque minerals, framboidal pyrite, muscovite, hornblende, garnet, and tourmaline constitute over 65% of the total downcore assemblage. Pyrite concentrations vary widely at some intervals and may reflect areas of micro-reducing conditions within the core or changes in source area with time. A persistent mica content indicates the presence of a low-energy environment throughout the depositional history of these fine sediments. Downcore organic carbon concentrations are generally uniform in the fine sediments and average about 1.5 percent. Surficial concentration from a core near the center of this feature is about 10 times greater than concentrations for coarse-grained sands on the surrounding shelf.

New England continental shelf↗

USGS1978

Conceptual models in exploration geochemistry-The Basin and Range Province of the Western United States and Northern Mexico

This summary of geochemical exploration in the Basin and Range Province is another in the series of reviews of geochemical-exploration applications covering a large region; this series began in 1975 with a summary for the Canadian Cordillera and Canadian Shield, and was followed in 1976 by a similar summary for Scandinavia (Norden). Rather than adhering strictly to the type of conceptual models applied in those papers, we have made use of generalized landscape geochemistry models related to the nature of concealment of ore deposits. This study is part of a continuing effort to examine and evaluate geochemical-exploration practices in different areas of the world. Twenty case histories of the application of geochemical exploration in both district and regional settings illustrate recent developments in techniques and approaches. Along with other published reports these case histories, exemplifying generalized models of concealed deposits, provide data used to evaluate geochemical-exploration programs and specific sample media. Because blind deposits are increasingly sought in the Basin and Range Province, the use of new sample media or anomaly-enhancement techniques is a necessity. Analysis of vapors or gases emanating from blind deposits is a promising new technique. Certain fractions of stream sediments show anomalies that are weak or not detected in conventional minus 80-mesh fractions. Multi-element analysis of mineralized bedrock may show zoning patterns that indicate depth or direction of ore. Examples of the application of these and other, more conventional methods are indicated in the case histories. The final section of this paper contains a brief evaluation of the applications of all types of sample media to geochemical exploration in the arid environment of the Basin and Range Province. ?? 1978.

Journal of Geochemical Exploration↗

USGS1996

Sulfur isotope geochemistry of ore and gangue minerals from the Silesian-Cracow Mississippi Valley-type ore district, Poland

Studies of the sulfur isotopic composition of ore and gangue minerals from the Silesian-Cracow Zn-Pb district were conducted to gain insights into processes that controlled the location and distribution of the ore deposits. Results of this study show that minerals from the Silesian-Cracow ore district have the largest range of sulfur isotope compositions in sulfides observed from any Mississippi Valley-type ore district in the world. The ??34S values for sulfide minerals range from +38 to -32 per mil for the entire paragenetic sequence but individual stages exhibit smaller ranges. There is a well developed correlation between the sulfur isotope composition and paragenetic stage of ore deposition. The first important ore stage contains mostly positive ??34S values, around 5 per mil. The second stage of ore formation are lower, with a median value of around -5 to -15 per mil, and with some values as low as -32 per mil. Late stage barite contains isotopically heavy sulfur around +32 per mil. The range in sulfur isotope compositions can be explained by contributions of sulfur from a variety of source rocks together with sulfur isotope fractionations produced by the reaction paths for sulfate reduction. Much of the variation in sulfur isotope compositions can be explained by bacterial reduction of sedimentary sulfate and disequilibrium reactions by intermediate-valency sulfur species, especially in the late-stage pyrite and sphalerite. Organic reduction of sulfate and thermal release of sulfur from coals in the Upper Silesian Coal Basin may have been important contributors to sulfur in the ore minerals. The sulfur isotopic data, ore mineral textures, and fluid inclusion data, are consistent with the hypothesis that fluid mixing was the dominant ore forming mechanism. The rather distinct lowering of ?? 34S values in sulfides from stage 2 to stage 3 is believed to reflect some fundamental change in the source of reduced sulfur and/or hydrology of the ore-forming environment. A change in the hydrology of the ore forming environment could be accomplished by extensional faulting that was coeval with ore formation. Late stage barite contains high values of ??34S which may reflect the final collapse of the hydrothermal system.

Prace - Panstwowego Instytutu Geologicznego↗

USGS1979

Hydrology and surface morphology of the Bonneville Salt Flats and Pilot Valley Playa, Utah

The Bonneville Salt Flats and Pilot Valley are in the western part of the Great Salt Lake Desert in northwest Utah. The areas are separate, though similar, hydrologic basins, and both contain a salt crust. The Bonneville salt crust covered about 40 square miles in the fall of 1976, and the salt crust in Pilot Valley covered 7 square miles. Both areas lack any noticeable surface relief (in 1976, 1.3 feet on the Bonneville salt crust and 0.3 foot on the Pilot Valley salt crust). The salt crust on the Salt Flats has been used for many years for automobile racing, and brines from shallow lacustrine deposits have been used for the production of potash. In recent years, there has been an apparent conflict between these two major uses of the area as the salt crust has diminished in both thickness and extent. Much of the Bonneville Racetrack has become rougher, and there has also been an increase in the amount of sediment on the south end of the racetrack. The Pilot Valley salt crust and surrounding playa have been largely unused. Evaporite minerals on the Salt Flats and the Pilot Valley playa are concentrated in three zones: (1) a carbonate zone composed mainly of authigenic clay-size carbonate minerals, (2) a sulfate zone composed mainly of authigenic gypsum, and (3) a chloride zone composed of crystalline halite (the salt crust). Five major types of salt crust were recognized on the Salt Flats, but only one type was observed in Pilot Valley. Geomorphic differences in the salt crust are caused by differences in their hydrologic environments. The salt crusts are dynamic features that are subject to change because of climatic factors and man's activities. Ground water occurs in three distinct aquifers in much of the western Great Salt Lake Desert: (1) the basin-fill aquifer, which yields water from conglomerate in the lower part of the basin fill, (2) the alluvial-fan aquifer, which yields water from sand and gravel along the western margins of both playas, and (3) the shallow-brine aquifer, which yields water from near-surface carbonate muds and crystalline halite and gypsum. The shallow-brine aquifer is the main source of brine used for the production of potash on the Salt Flats. Recharge to that part of the shallow-brine aquifer north of Interstate Highway 80 on the Salt Flats is mainly by infiltration of precipitation and wind-driven floods of surface brine. Discharge was mainly by evaporation at the playa surface and withdrawals from brine-collection ditches. Some water was transpired by phreatophytes, and some leaked into the alluvial fan along the western edge of the playa. Salt-scraping studies indicate that the amount of halite on the Salt Flats is directly related to the amount of recharge through the surface (which causes re-solution of halite) and the amount of evaporation at the surface (which causes crystallization of halite). Evaporation rates through sediment-covered salt crust and the gypsum surface were estimated at between 3x10 -4 and 4x10 -3 inches per day during the summer and fall of 1976. Evaporation rates through the surface of thick perennial salt crust were much higher. The concentration of dissolved solids in brine in the shallow-brine aquifer varies, but it generally increases from the edges of the playas toward areas of salt crust. Dissolved-solids concentration in the shallow brine ranges from less than 100,000 to more than 300,000 milligrams per liter on both playas. The increase in salinity toward areas of salt crust reflects the natural direction of brine movement through the aquifer toward the natural discharge area. On the Salt Flats, the percentages of dissolved potassium chloride and magnesium chloride in the shallow-brine aquifer generally increase from the edge of the playa to- ward the salt crust. The relative enrichment in potassium and magnesium reflects the many years of subsurface drainage toward the main discharge area (the salt crust) prior to man's withdrawal of brine. By artificially extracting brines from the carbonate muds, the percentages of potassium and magnesium have decreased while brine salinity has been maintained by re-solution of the salt crust. The configuration of the density-corrected potentiometric surface in the fall of 1976 indicates that brine in the shallow-brine aquifer under the Bonneville Racetrack was draining toward brine-collection ditches or a well field to the west. Ground-water divides have no effect on the movement of dissolved salt across the surface in wind-driven floods, and salt in surface brine was carried from the racetrack into the area of influence of the ditches by such surface movement. During 1976 on the Salt Flats, some brine was moving through the shallow-brine aquifer across lease and property boundaries. An evaluation of suggested remedial measures indicates that none will completely eliminate the conflict between uses or transform the Bonneville Salt Flats to its original state prior to man's activities in the area.

Utah↗

USGS2007

Barite-forming environments along a rifted continental margin, Southern California Borderland

The Southern California Continental Borderland (SCCB) is part of the broad San Andreas transform-fault plate boundary that consists of a series of fault-bounded, petroleum-generating basins. The SCCB has high heat flow and geothermal gradients produced by thinned continental crust and Neogene volcanism. Barite deposits in the SCCB occur along faults. Barite samples from two sea-cliff sites and four offshore sites in the SCCB were analyzed for mineralogy, chemical (54 elements) and isotopic (S, Sr) compositions, and petrography. Barite from Palos Verdes (PV) Peninsula sea-cliff outcrops is hosted by the Miocene Monterey Formation and underlying basalt; carbonate rocks from those outcrops were analyzed for C, O, and Sr isotopes and the basalt for S isotopes. Cold-seep barite from Monterey Bay, California was analyzed for comparison. SCCB offshore samples occur at water depths from about 500 to 1800 m. Those barites vary significantly in texture and occurrence, from friable, highly porous actively growing seafloor mounds to dense, brecciated, vein barite. This latter type of barite contrasts with cold-seep barite in being much more coarse grained, forms thick veins in places, and completely replaced rock clasts in breccia. The barite samples range from 94 to 99 wt% BaSO4, with low trace-element contents, except for high Sr, Zr, Br, U, and Hg concentrations compared to their crustal abundances. δ34S for SCCB offshore barites range from 21.6‰ to 67.4‰, and for PV barite from 62‰ to 70‰. Pyrite from PV sea-cliff basalt and sedimentary rocks that host the barites averages 7.8‰ and 2.2‰, respectively. Two offshore barite samples have δ34S values (21.6‰, 22.1‰) close to that of modern seawater sulfate, whereas all other samples are enriched to strongly enriched in 34S. 87Sr/86Sr ratios for the barites vary over a narrow range of 0.70830–0.70856 and are much lower than that of modern seawater and also lower than the middle Miocene seawater ratio, the time of deposition of the host rocks for the PV samples. This indicates that the mineralizing fluids were not unaltered seawater. We develop a model in which the barites precipitated both below the sediment–water interface and at the seafloor from low-temperature fluids that circulated along faults. The isotopic, chemical, and textural data indicate that the barites formed by several processes. Mesozoic and Cenozoic basement rocks (crystalline and overlying sedimentary rocks), Quaternary basin fill, turbidite fans, and seawater provided various elements for the barites in different environments. The fluids had a deep-seated source and were hydrothermal in the deeper parts of the system for all the barite types, including the seafloor cold-seep deposit, based on Sr isotopes and regional geothermal gradients. These deep-seated fluids mixed with other fluids as they ascended, including seawater at and near the seafloor. The high δ34S values may have resulted from extreme Rayleigh fractionation during bacterially mediated (semi)closed-system sulfate reduction, probably driven by the flux of methane- and hydrocarbon-bearing fluids through basement rocks and basin sediments. Early diagenetic dolomite and pyrite in the host Monterey Formation in the PV Headland also formed in a zone of sulfate reduction, but within sediment buried only centimeters to a few meters and with a predominantly seawater source for the sulfur. Dolomite occurring with vein barite in the PV Headland formed at temperatures in the range of 40–90 °C. The cold-seep barites have δ34S values near that of modern seawater, although still somewhat fractionated. The barites that precipitated below the sediment–water interface have higher δ34S values, suggesting that the fluids were relatively reduced with molar dissolved barium in excess of dissolved sulfate. Those samples were exposed at the seafloor by uplift along faults and are composed predominantly of massive, brecciated, and vein barite.

California↗

USGS2020

Plant biomass and rates of carbon dioxide uptake are enhanced by successful restoration of tidal connectivity in salt marshes

Salt marshes, due to their capability to bury soil carbon (C), are potentially important regional C sinks. Efforts to restore tidal flow to former salt marshes have increased in recent decades in New England (USA), as well as in some other parts of the world. In this study, we investigated plant biomass and carbon dioxide (CO 2 ) fluxes at four sites where restoration of tidal flow occurred five to ten years prior to the study. Site elevation, aboveground biomass, CO 2 flux, and porewater chemistry were measured in 2015 and 2016 in both restored marshes and adjacent marshes where tidal flow had never been restricted. We found that the elevation in restored marsh sites was 2–16 cm lower than their natural references. Restored marshes where porewater chemistry was similar to the natural reference had greater plant aboveground biomass, gross ecosystem production, ecosystem respiration, as well as net ecosystem CO 2 exchange (NEE) than the natural reference, even though they had the same plant species. We also compared respiration rates in aboveground biomass (AR) and soil (BR) during July 2016, and found that restored marshes had higher AR and BR fluxes than natural references. Our findings indicated that well-restored salt marshes can result in greater plant biomass and NEP, which has the potential to enhance rates of C sequestration at 10-yrs post restoration. Those differences were likely due to lower elevation and greater flooding frequency in the recently restored marshes than the natural marsh. The inverse relationship between elevation and productivity further suggests that, where sea-level rise rate does not surpass the threshold of plant survival, the restoration of these salt marshes may lead to enhanced organic and mineral sedimentation, extending marsh survival under increased sea level, and recouping carbon stocks that were lost during decades of tidal restriction.

Massachusetts↗

USGS2003

Geologic framework and hydrogeologic characteristics of the Edwards aquifer, Uvalde County, Texas

The Edwards aquifer in Uvalde County is composed of Lower Cretaceous carbonate (mostly dolomitic limestone) strata of the Devils River Formation in the Devils River trend and of the West Nueces, McKnight, and Salmon Peak Formations in the Maverick basin. Rocks in the Devils River trend are divided at the bottom of the Devils River Formation into the (informal) basal nodular unit. Maverick basin rocks are divided (informally) into the basal nodular unit of the West Nueces Formation; into lower, middle, and upper units of the McKnight Formation; and into lower and upper units of the Salmon Peak Formation. The Edwards aquifer overlies the (Lower Cretaceous) Glen Rose Limestone, which composes the lower confining unit of the Edwards aquifer. The Edwards aquifer is overlain by the (Upper Cretaceous) Del Rio Clay, the basal formation of the upper confining unit. Upper Cretaceous and (or) Lower Tertiary igneous rocks intrude all stratigraphic units that compose the Edwards aquifer, particularly in the southern part of the study area. The Balcones fault zone and the Uvalde salient are the principal structural features in the study area. The fault zone comprises mostly en echelon, high-angle, and down-to-the-southeast normal faults that trend mostly from southwest to northeast. The Uvalde salient—resulting apparently from a combination of crustal uplift, diverse faulting, and igneous activity—elevates the Edwards aquifer to the surface across the central part of Uvalde County. Downfaulted blocks associated with six primary faults—Cooks, Black Mountain, Blue Mountain, Uvalde, Agape, and Connor—juxtapose the Salmon Peak Formation (Lower Cretaceous) in central parts of the study area against Upper Cretaceous strata in the southeastern part. The carbonate rocks of the Devils River trend and the Maverick basin are products of assorted tectonic and depositional conditions that affected the depth and circulation of the Cretaceous seas. The Devils River Formation formed in a fringing carbonate bank—the Devils River trend— in mostly open shallow marine environments of relatively high wave and current energy. The West Nueces, McKnight, and Salmon Peak Formations resulted mostly from partly restricted to open marine, tidal-flat, and restricted deep-basinal environments in the Maverick basin. The porosity of the Edwards aquifer results from depositional and diagenetic effects along specific lithostratigraphic horizons (fabric selective) and from structural and solutional features that can occur in any lithostratigraphic horizon (non-fabric selective). In addition to porosity depending upon the effects of fracturing and the dissolution of chemically unstable (soluble) minerals and fossils, the resultant permeability depends on the size, shape, and distribution of the porosity as well as the interconnection among the pores. Upper parts of the Devils River Formation and the upper unit of the Salmon Peak Formation compose some of the most porous and permeable rocks in Uvalde County.

Texas↗

USGS2011

Magmatic-vapor expansion and the formation of high-sulfidation gold deposits: Chemical controls on alteration and mineralization

Large bulk-tonnage high-sulfidation gold deposits, such as Yanacocha, Peru, are the surface expression of structurally-controlled lode gold deposits, such as El Indio, Chile. Both formed in active andesite–dacite volcanic terranes. Fluid inclusion, stable isotope and geologic data show that lode deposits formed within 1500 m of the paleo-surface as a consequence of the expansion of low-salinity, low-density magmatic vapor with very limited, if any, groundwater mixing. They are characterized by an initial ‘Sulfate’ Stage of advanced argillic wallrock alteration ± alunite commonly with intense silicification followed by a ‘Sulfide’ Stage — a succession of discrete sulfide–sulfosalt veins that may be ore grade in gold and silver. Fluid inclusions in quartz formed during wallrock alteration have homogenization temperatures between 100 and over 500 °C and preserve a record of a vapor-rich environment. Recent data for El Indio and similar deposits show that at the commencement of the Sulfide Stage, ‘condensation’ of Cu–As–S sulfosalt melts with trace concentrations of Sb, Te, Bi, Ag and Au occurred at > 600 °C following pyrite deposition. Euhedral quartz crystals were simultaneously deposited from the vapor phase during crystallization of the vapor-saturated melt occurs to Fe-tennantite with progressive non-equilibrium fractionation of heavy metals between melt-vapor and solid. Vugs containing a range of sulfides, sulfosalts and gold record the changing composition of the vapor. Published fluid inclusion and mineralogical data are reviewed in the context of geological relationships to establish boundary conditions through which to trace the expansion of magmatic vapor from source to surface and consequent alteration and mineralization. Initially heat loss from the vapor is high resulting in the formation of acid condensate permeating through the wallrock. This Sulfate Stage alteration effectively isolates the expansion of magmatic vapor in subsurface fracture arrays from any external contemporary hydrothermal activity. Subsequent fracturing is localized by the embrittled wallrock to provide high-permeability fracture arrays that constrain vapor expansion with minimization of heat loss. The Sulfide Stage vein sequence is then a consequence of destabilization of metal-vapor species in response to depressurization and decrease in vapor density. The geology, mineralogy, fluid inclusion and stable isotope data and geothermometry for high-sulfidation, bulk-tonnage and lode deposits are quite different from those for epithermal gold–silver deposits such as McLaughlin, California that formed near-surface in groundwater-dominated hydrothermal systems where magmatic fluid has been diluted to less than about 30%. High sulfidation gold deposits are better termed ‘Solfataric Gold Deposits’ to emphasize this distinction. The magmatic-vapor expansion hypothesis also applies to the phenomenology of acidic geothermal systems in active volcanic systems and equivalent magmatic-vapor discharges on the flanks of submarine volcanoes.

Ore Geology Reviews↗

USGS2013

The impact environment of the Hadean Earth

Impact bombardment in the first billion years of solar system history determined in large part the initial physical and chemical states of the inner planets and their potential to host biospheres. The range of physical states and thermal consequences of the impact epoch, however, are not well quantified. Here, we assess these effects on the young Earth's crust as well as the likelihood that a record of such effects could be preserved in the oldest terrestrial minerals and rocks. We place special emphasis on modeling the thermal effects of the late heavy bombardment (LHB) – a putative spike in the number of impacts at about 3.9 Gyr ago – using several different numerical modeling and analytical techniques. A comprehensive array of impact-produced heat sources was evaluated which includes shock heating, impact melt generation, uplift, and ejecta heating. Results indicate that &sim;1.5–2.5 vol.% of the upper 20 km of Earth's crust was melted in the LHB, with only &sim;0.3–1.5 vol.% in a molten state at any given time. The model predicts that approximately 5–10% of the planet's surface area was covered by >1 km deep impact melt sheets. A global average of &sim;600–800 m of ejecta and &sim;800–1000 m of condensed rock vapor is predicted to have been deposited in the LHB, with most of the condensed rock vapor produced by the largest (>100-km) projectiles. To explore for a record of such catastrophic events, we created two- and three-dimensional models of post-impact cooling of ejecta and craters, coupled to diffusion models of radiogenic Pb*-loss in zircons. We used this to estimate what the cumulative effects of putative LHB-induced age resetting would be of Hadean zircons on a global scale. Zircons entrained in ejecta are projected to have the following average global distribution after the end of the LHB: &sim;59% with no impact-induced Pb*-loss, &sim;26% with partial Pb*-loss and &sim;15% with complete Pb*-loss or destruction of the grain. In addition to the relatively high erodibility of ejecta, our results show that if discordant ca. 3.9 Gyr old zones in the Jack Hills zircons are a signature of the LHB, they were most likely sourced from impact ejecta.

Chemie der Erde↗

USGS1974

Geology and mineral resources of the Lehighton and Palmerton quadrangles, Carbon and Northampton Counties, Pennsylvania

The Lehighton and Palmerton 73 1/2-minute quadrangles cover an area of about 112 square miles of diversified terrain in the folded Appalachian Mountain and Great Valley sections of the Valley and Ridge physiographic province in Carbon, Lehigh, and Northampton Counties, Pennsylvania. The Lehigh River and Blue Mountain are the prominent features of the topography. Rock units defined and mapped in the area are the lithified sediments that were deposited in a variety of offshore marine, marine shelf, marginal marine, and fluvial environments associated with two phases of basin filling. The rocks are separated into four lithotectonic units, each deformed semi-independently of adjacent lithotectonic units. Decollements presumably separate the lithotectonic units. Lithotectonic unit 1 consists of about 12,000 feet of slate and graywacke of the Middle and Upper Ordovician Martinsburg Formation. This unit contains mainly asymmetric, similar, and nearly isoclinal folds, with wave lengths of 1,000 to 3,000 feet and amplitudes of 400 to 2,000 feet, formed mainly by passive flow and slip. Lithotectonic unit 2 includes about 3,100 feet of sandstone, siltstone, shale, and conglomerate of the Shawangunk Formation (Ordovician(?) and Silurian), Bloomsburg Red Beds (Silurian), and the lower part of the Poxono Island Formation (Silurian). This unit contains mainly asymmetric and concentric folds, with wavelengths of about one mile and amplitudes of 1,500 to 5,000 feet, formed by flexural slip with minor passive slip and flow. Lithotectonic unit 3 contains about 750 feet of limestone, shale, siltstone, sandstone, and dolomite of the upper part of the Poxono Island Formation, Bossardville Limestone, and Decker Formation (all Silurian), the Coeymans and New Scotland Formations, Shriver Chert, and Ridgeley Formation of the Oriskany Group and the Schoharie-Esopus Formation (all Lower Devonian), and the Palmerton Formation and Buttermilk Falls Limestone (both Middle Devonian). This unit has asymmetric, concentric, similar, and flap folds, with wavelengths of 1,000 to 1,500 feet and amplitudes of about 1,550 feet, formed by flexural slip and flow and passive slip and flow. Lithotectonic unit 4 consists of more than 13,000 feet of sandstone, conglomerate, siltstone, and shale of the Middle Devonian Marcellus and Mahantango Formations, the Upper Devonian Trimmers Rock and Catskill Formations, the Devonian-Mississippian Spechty Kopf Forma tion, the Mississippian Pocono and Mauch Chunk Formations, and the Pennsylvanian Pottsville Formation. This unit contains nearly symmetric, concentric flexural-slip folds with wavelengths of more than five miles and amplitudes of about one mile. Surficial deposits occur throughout the mapped area and include: Pleistocene pre-lllinoian(?) till and outwash(?), lllinoian(?) till and outwash, Wisconsinan outwash, shale-chip rubble, boulder fields, and colluvium; and Holocene alluvium, landslide deposits, and man-made dumps. The rocks of the mapped area, except for the deeply weathered lime stones, generally have good slope stability and foundation support strength, moderate to low primary infiltration capacity and aquifer potential but moderate to high secondary values for these properties, moderate resistance to weathering, and are moderately difficult to difficult to excavate. All of these properties are strongly influenced by the abundant bedding, cleavage, and joint partings of the rocks. Similar evaluations for the surficial deposits indicate less desirable values except for the ease of excavation of most of the unconsolidated materials. Currently active and potential mineral resources are numerous in the Lehighton and Palmerton quadrangles and include slate, sand, paint ore, building stone, crushed rock, lightweight aggregate, clinker residue, clay, hydraulic cement, and roofing granules.

Pennsylvania↗

USGS2020

An overview of bioaerosol load and health impacts associated with dust storms: A focus on the Middle East

Dust storms are an important environmental problem worldwide. The main sources of dust storms include the Sahara, the Middle East, and central and northeastern Asia. Dust storms originating from these regions can be dispersed across oceans and in some cases globally. They occur throughout the year and vary in frequency and intensity. The biological agents (e.g., fungi, bacteria and viruses) and the mineral and chemical compositions of dust may have adverse effects on human health and quality of life. Desert dusts may cause respiratory diseases, cardiovascular diseases, cardiopulmonary diseases, mental health issues, injuries and death from transport accidents caused by poor visibility. This paper presents dust storm human health research conducted in the Middle East in both indoor and outdoor environments. Results illustrate that particle concentration and bioaerosol types in the atmosphere are affected by climate change and meteorological factors. Recent data trends indicate that annual dust aerosol concentrations have increased worldwide. According to studies conducted in the Middle East, the incidence of respiratory and cardiovascular mortality and hospital visits have increased dramatically following dust storm exposures but very few have demonstrated a regional causation. National and international collaborative efforts are needed to advance our understanding of the global implications of dust storms and what may be the most effective means of mitigation.

Middle East↗

USGS2024

Role of microbial Fe(III) reduction and solution chemistry in aggregation and settling of suspended particles in the Mississippi River Delta plain, Louisiana, USA

River-dominated delta areas are primary sites of active biogeochemical cycling, with productivity enhanced by terrestrial inputs of nutrients. Particle aggregation in these areas primarily controls the deposition of suspended particles, yet factors that control particle aggregation and resulting sedimentation in these environments are poorly understood. This study was designed to investigate the role of microbial Fe(III) reduction and solution chemistry in aggregation of suspended particles in the Mississippi Delta. Three representative sites along the salinity gradient were selected and sediments were collected from the sediment-water interface. Based on quantitative mineralogical analyses 88–89 wt.% of all minerals in the sediments are clays, mainly smectite and illite. Consumption of SO 4 2− and the formation of H 2 S and pyrite during microbial Fe(III) reduction of the non-sterile sediments by Shewanella putrefaciens CN32 in artificial pore water (APW) media suggest simultaneous sulfate and Fe(III) reduction activity. The pH PZNPC of the sediments was ≤3.5 and their zeta potentials at the sediment-water interface pH (6.9–7.3) varied from −35 to −45 mV, suggesting that both edges and faces of clay particles have negative surface charge. Therefore, high concentrations of cations in pore water are expected to be a predominant factor in particle aggregation consistent with the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. Experiments on aggregation of different types of sediments in the same APW composition revealed that the sediment with low zeta potential had a high rate of aggregation. Similarly, addition of external Fe(II) ( i.e. not derived from sediments) was normally found to enhance particle aggregation and deposition in all sediments, probably resulting from a decrease in surface potential of particles due to specific Fe(II) sorption. Scanning and transmission electron microscopy (SEM, TEM) images showed predominant face-to-face clay aggregation in native sediments and composite mixtures of biopolymer, bacteria, and clay minerals in the bioreduced sediments. However, a clear need remains for additional information on the conditions, if any, that favor the development of anoxia in deep- and bottom-water bodies supporting Fe(III) reduction and resulting in particle aggregation and sedimentation.

Clays and Clay Minerals↗

USGS1984

The Balmat-Edwards zinc-lead deposits; synsedimentary ore from Mississippi Valley-type fluids

Reconstruction of some aspects of the initial environment of ore deposition through detailed S, C, and O isotope studies of the Fowler orebody, and through reconnaissance trace element and S isotope studies of sphalerite concentrates and composite samples of ore from 22 orebodies; and (2) evaluation of the effects of high-grade metamorphism on the stable isotope geochemistry of both the ore and gangue minerals of a massive sulfide orebody. The delta 34 S values of pyrite, sphalerite, and galena in the Fowler orebody range from 11.5 to 17.5 per mil; anhydrite associated with ore ranges from 25.6 to 27.0 per mil. Average equilibration temperatures calculated from the delta 34 S differences between coexisting sulfur-bearing phases are 388 degrees C for pyrite-sphalerite, 338 degrees C for sphalerite-galena, 329 degrees C for pyrite-galena, and 602 degrees C for anhydrite-pyrite; all pairs display narrow temperature distributions. The delta 13 C and delta 18 O values of carbonates from the Fowler orebody range from -1.6 to 1.4 per mil and from 24.8 to 27.0 per mil, respectively; quartz delta 18 O values range from 23.0 to 27.0 per mil. The delta 34 S values of sphalerite concentrated from composite samples of the orebodies range from 12.7 to 14.7 per mil. This narrow range contrasts sharply with the wide variability of associated evaporitic anhydrite lenses, which range from 8 to 28 per mil. A stratigraphic increase in the delta 34 S value of the evaporitic anhydrite at Balmat, and large sulfide iron-formation occurrences near Balmat, imply that bacterial sulfate reduction occurred on an unusually large scale during Balmat sedimentation. The presence of such an increase in a sedimentary section may constitute a valuable exploration guide.

Economic Geology↗

USGS1985

Review of the use of magnetic concentrates in geochemical exploration

Magnetic concentrates recovered readily by hand magnet from alluvial sediments or panned concentrates have been used successfully in exploration as a geochemical sample medium for Cu, Zn, Co, Cr, Mo, Ni, V, Sn, and Be, particularly in arid environments where alluvial sediments may be contaminated by aeolian debris. Opportunity for this use arose recently as chemical and spectrographic techniques were developed to determine the abundances of a variety of trace elements in Fe-rich media. The use of analytical data from magnetic concentrates was introduced as one of several anomaly-enhancement techniques based on heavy minerals and intended to identify blind ore deposits. An extensive literature, reviewed here, on the relation of the chemical composition of the mineral magnetite, a main component of magnetic concentrates, to geologic conditions of origin, facilitates the interpretation of trace-element data in the context of association with ore deposits.

Open-File Report↗

USGS1996

Hydraulic characteristics and nutrient transport and transformation beneath a rapid infiltration basin, Reedy Creek Improvement District, Orange County, Florida

The Reedy Creek Improvement District disposes of about 7.5 million gallons per day (1992) of reclaimed water through 85 1-acre rapid infiltration basins within a 1,000-acre area of sandy soils in Orange County, Florida. The U.S. Geological Survey conducted field experiments in 1992 at an individual basin to examine and better understand the hydraulic characteristics and nutrient transport and transformation of reclaimed water beneath a rapid infiltration basin. At the time, concentrations of total nitrogen and total phosphorus in reclaimed water were about 3 and 0.25 milligrams per liter, respectively. A two-dimensional, radial, unsaturated/saturated numerical flow model was applied to describe the flow system beneath a rapid infiltration basin under current and hypothetical basin loading scenarios and to estimate the hydraulic properties of the soil and sediment beneath a basin. The thicknesses of the unsaturated and saturated parts of the surficial aquifer system at the basin investigated were about 37 and 52 feet, respectively. The model successfully replicated the field-monitored infiltration rate (about 5.5 feet per day during the daily flooding periods of about 17 hours) and ground-water mounding response during basin operation. Horizontal and vertical hydraulic conductivity of the saturated part of the surficial aquifer system were estimated to be 150 and 45 feet per day, respectively. The field-saturated vertical hydraulic conductivity of the shallow soil, estimated to be about 5.1 feet per day, was considered to have been less than the full-saturation value because of the effects of air entrapment. Specific yield of the surficial aquifer was estimated to be 0.41. The upper 20 feet of the basin subsurface profile probably served as a system control on infiltration because of the relatively low field-saturated, vertical hydraulic conductivity of the sediments within this layer. The flow model indicates that, in the vicinity of the basin, flow in the deeper, saturated zone was relatively slow compared to the more vigorous flow in the shallow saturated zone. The large radial component of flow below the water table in the vicinity of the basin implies that reclaimed water moves preferentially in the shallow part of the saturated zone upon reaching the water table. Therefore, there may be some vertical stratification in the saturated zone, with recently infiltrated water overlying ambient water. The infiltration capacity at the basin would be unaffected by a small (less than 10 feet) increase in background water-table altitude, because the water table would remain below the system control on infiltration. However, water-table rises of 15 and 20 feet were estimated to reduce the infiltration capacity of the basin by 8 and 25 percent, respectively. Model simulations indicate that increasing ponded depth within the basin from 4 to 12 inches and from 4 to 24 inches would increase basin infiltration capacity by less than 6 and 11 percent, respectively. A loading strategy at the basin that relies on long, uninterrupted flooding was shown to offer the possibility of inducing a more anaerobic environment conducive to denitrification while maintaining reclaimed-water disposal capacity. Field measurements indicated that transient, elevated concentrations or "spikes" of nitrate (as high as 33 milligrams per liter as nitrogen) occurred at the leading edge of the infiltrating water and in the shallow saturated zone following a prolonged basin rest period. This phenomenon probably is the result of mineralization and nitrification of organic nitrogen retained within the subsurface during earlier basin loading events. The organic nitrogen was retained in the shallow soil (due to adsorption/straining) and the shallow saturated zone (due to deposition under slacking pore-water velocity). The magnitude of the nitrate spikes appears to be influenced by the scheduling of basin loading, with short flooding and resting periods being most favorable to minimization of nitrate spikes. Removal of nitrogen by denitrification from the percolating reclaimed water is minimal in the vicinity of the basin, probably because of the lack of reducing conditions and a relative paucity of organic carbon substrates. It is speculated that longer flooding periods could induce reducing conditions that would be favorable for nitrogen removal from the system, but probably would lead to more pronounced nitrate spiking. Phosphorus concentrations were decreased by about 90 percent from concentrations in reclaimed water after moving through the upper 15 feet of the soil profile. This most likely was a result of adsorption onto abundant iron and aluminum hydrous oxyhydroxide coatings on sand grains. However, some phosphorus (coarse fraction, organic) passes through the shallow soil and accumulates below the water table under slacking pore-water velocity. This phosphorus is immobilized by adsorption, fixation, or precipitation reactions during basin rest periods.

Florida↗