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Geohydrologic summary of the Pearl River basin, Mississippi and Louisiana

Fresh water in abundance is contained in large artesian reservoirs in sand and gravel deposits of Tertiary and Quaternary ages in the Pearl River basin, a watershed of 8,760 square miles. Shallow, water-table reservoirs occur in Quarternary deposits (Pleistocene and Holocene) that blanket most of the uplands in .the southern half of the basin and that are present in smaller upland areas and along streams elsewhere. The shallow reservoirs contribute substantially to dry-weather flow of the Strong River and Bogue Chitto and of Holiday, Lower Little, Silver, and Whitesand Creeks, among others. About 3 billion acre-feet of ground water is in storage in the fresh-water section, which extends from the surface to depths ranging from about sea level in the extreme northern part of the basin to more than 3,000 feet below sea level in the southern part of the basin. Variations in low flow for different parts of the river basin are closely related to geologic terrane and occurrence of ground water. The upland terrace belt that crosses the south-central part of the basin is underlain by permeable sand and gravel deposits and yields more than 0.20 cubic feet per second per square mile of drainage area to streamflow, whereas the northern part of the basin, underlain by clay, marl, and fine to medium sand, yields less than 0.05 cubic feet per second per square mile of drainage area (based on 7-day Q2 minimum flow computed from records). Overall, the potential surface-water supplies are large. Because water is available at shallow depths, most of the deeper aquifers have not been developed anywhere in the basin. At many places in the south, seven or more aquifers could be developed either by tapping one sand in each well or by screening two or more sands in a single well. Well fields each capable, of producing several million gallons of water a day are feasible nearly anywhere in the Pearl River basin. Water in nearly all the aquifers is of good to excellent quality and requires little or no treatment for most uses. The water is a soft, sodium bicarbonate type and therefore has a low to moderate dissolved-solids content. Mineral content increases generally downdip in an aquifer. Excessive iron, common in shallow aquifers, is objectionable for some water uses. Water from the streams, except in salty tidal reaches, is less mineralized than ground water; in 10 sites the median dissolved-solids content in streamflow was 50 milligrams per liter or less. Moderately intensive ground-water development has been made in the Bogalusa area, Louisiana; at the Mississippi Test Facility, Hancock County, Miss. ; and in the Jackson area, Mississippi. Wells with pumping rates of 500 to 1,000 gallons per minute each are common throughout the Pearl River basin, and some deep wells flow more than 3,000 gallons per minute in the coastal lowland areas. Probably 20 million gallons per day of artesian water flows uncontrolled from wells in the southern part of the basin. Ground-water levels, except in the higher altitudes, are within 60 feet of the surface, and flowing wells are common in the valleys and in the coastal Pine Meadows. Decline of water level is a problem in only a few small areas. Saline water as a resource is available for development from aquifers and streams near the coast and from aquifers at considerable depth in most of the Pearl River basin. Pollution is a problem in oil fields and in reaches of some streams below sewage and other waste-disposal points. The basin estuary contains water of variable quality but has potential for certain water-use developments that will require special planning and management.

Water Supply Paper↗

Platinum deposits of the Goodnews Bay district, Alaska

Platinum placers were discovered in 1926 in a small area south of Goodnews Bay, in southwestern Alaska. Beginning in 1927, the placers were worked for 7 years by small-scale mining methods; in later years dragline excavators and a dredge were utilized. These deposits are important, not only because they are of high grade but because they are the only commercial source of platinum metals in the United States. The bedded rocks of this area are sedimentary and volcanic rocks of late Paleozoic(?) age that have been intruded by a variety of ultrabasic rocks. The platinum metals of the placers have been derived from a mass of dunite and related rocks that constitute the bedrock of Red Mountain in the upper valley of the Salmon River. The western headwater tributaries of this stream are the fluvial conduits that have produced all the placers in the valley of the river. The principal placers lie in two pay streaks, one in the valley floor of the Salmon River and the other in an ancient stream channel along the east side of this valley. The stream-channel deposit, called the bench pay streak, was formed in early Pleistocene time; its alluvial materials consist largely of clay derived from an ancient moraine believed to be of Nebraskan age. The valley-floor deposit, called the pay streak of the valley floor, consists of alluvial materials of fluvial and glaciofluvial origin whose ages range from Yarmouth to Holocene. Both channels contain high-grade placers that have yielded a large volume of platinum metals. The platinum metals of these deposits are contained mainly in two alloys intergrown in a pseudoeutectic fabric. The major alloy is mainly platinum, with a small amount of iridium, still smaller amounts of rhodium and palladium, and probably some osmium and ruthenium. The minor alloy is dominantly iridium and osmium with less platinum and still less ruthenium and rhodium. The compositions of these two alloys are somewhat variable but tend to approach constant mean values. A small amount of free gold is recovered with the platinum metals. In addition to these two alloys, minute amounts of five platinum minerals have been identified. The weighted mean percentages of platinum, iridium, osmium, ruthenium, rhodium, palladium, and gold, as mined from 1936 to 1972, are respectively 82.25, 11.32, 2.15, 0.17, 1.30, 0.38, and 2.43. The lodes from which these placers have been derived are, or have been, localized in the Red Mountain ridge, where the principal rocks are dunite and serpentinite. No lodes have been recognized, either because the platinum metals are sparsely distributed or because a large part of the platiniferous rock has been eroded. It is known, however, that the amounts of iridium, osmium, and ruthenium, or of osmiridium, decrease from south to north. Other generalizations regarding the composition and granularity of these metals have been deduced. The size and shape of the platinum lodes may have ranged from diffuse disseminations to high-grade concentrations in small loci. Under certain assumptions, the tenor of platinum metals in the dunite can be roughly approximated. Utilizing two totally different methods of computation, the mean tenor has been estimated to lie between 0.19 and 0.27 grain of platinum metals per cubic yard of dunite, or 0.014 to 0.023 gram per stere. No large low-grade deposits of commercial value are likely to be found, but it is possible that some small high-grade concentrations occur.

Alaska↗

Origin of the Sinai-Negev erg, Egypt and Israel: mineralogical and geochemical evidence for the importance of the Nile and sea level history

The Sinai–Negev erg occupies an area of 13,000 km 2 in the deserts of Egypt and Israel. Aeolian sand of this erg has been proposed to be derived from the Nile Delta, but empirical data supporting this view are lacking. An alternative source sediment is sand from the large Wadi El Arish drainage system in central and northern Sinai. Mineralogy of the Negev and Sinai dunes shows that they are high in quartz, with much smaller amounts of K-feldspar and plagioclase. Both Nile Delta sands and Sinai wadi sands, upstream of the dunes, also have high amounts of quartz relative to K-feldspar and plagioclase. However, Sinai wadi sands have abundant calcite, whereas Nile Delta sands have little or no calcite. Overall, the mineralogical data suggest that the dunes are derived dominantly from the Nile Delta, with Sinai wadi sands being a minor contributor. Geochemical data that proxy for both the light mineral fraction (SiO 2 /10–Al 2 O 3 + Na 2 O + K 2 O–CaO) and heavy mineral fraction (Fe 2 O 3 –MgO–TiO 2 ) also indicate a dominant Nile Delta source for the dunes. Thus, we report here the first empirical evidence that the Sinai–Negev dunes are derived dominantly from the Nile Delta. Linkage of the Sinai–Negev erg to the Nile Delta as a source is consistent with the distribution of OSL ages of Negev dunes in recent studies. Stratigraphic studies show that during the Last Glacial period, when dune incursions in the Sinai–Negev erg began, what is now the Nile Delta area was characterized by a broad, sandy, minimally vegetated plain, with seasonally dry anastomosing channels. Such conditions were ideal for providing a ready source of sand for aeolian transport under what were probably much stronger glacial-age winds. With the post-glacial rise in sea level, the Nile River began to aggrade. Post-glacial sedimentation has been dominated by fine-grained silts and clays. Thus, sea level, along with favorable climatic conditions, emerges as a major influence on the timing of dune activity in the Sinai–Negev erg, through its control on the supply of sand from the Nile Delta. The mineralogy of the Sinai–Negev dunes is also consistent with a proposed hypothesis that these sediments are an important source of loess in Israel.

Sinai-negev Erg↗

Geology and ground-water resources of the Lufkin area, Texas

This report covers Angelina County, Texas, of which Lufkin is the county seat, and parts of Nacogdoches and other adjacent counties. The area is underlain by a series of sands, clays, and shales of Eocene age that dip, in general, southward at an angle a little greater than that of the land surface, which also slopes southward, thus creating favorable artesian conditions. The formations cropping out in the area from north to south are the Wilcox group undifferentiated, the Carrizo sand, the Mont Selman formation, consisting of the Reklaw member, the Queen City sand member, and the Weches greensand member, the Sparta sand, the Cook Mountain and Yegua formations, and the Jackson group undifferentiated. Small supplies of potable water may be obtained from shallow wells in the outcrop areas of most of these formations. Only three of the formations appear to be likely to yield large supplies of water to wells, and in these the water is under sufficient artesian pressure in most places to cause wells to flow. The Yegua formation yields large amounts of water to some wells in the vicinity of Lufkin. However, the water is moderately mineralized and is not acceptable for municipal use except after dilution with surface water and treatment to reduce mineralization. Moreover, most of the wells in this formation yield only small quantities of water, which is highly mineralized. The Sparta sand appears to be likely to yield large supplies of water to wells throughout the northern part of Angelina County. The water, however, is moderately to highly mineralized and cannot be used for purposes that require water of good quality. The Carrizo sand promises to yield large quantities of water low in mineralization in northern Angelina County and southern Nacogdoches County. Computations indicate that the present southward flow through the formation is about 2,750,000 gallons a day, but pumping from wells and thus increasing the hydraulic gradient would greatly increase the flow. Considerable amounts of water will also be released from storage in the formation after pumping begins.

Water Supply Paper↗

Origin and character of loesslike silt in unglaciated south-central Yakutia, Siberia, U.S.S.R.

Loesslike silt mantles upland terraces and low plateaus throughout unglaciated south-central Yakutia but is thickest along the south side of the lower Aldan River valley and the east side of the Lena River valley. The silt is probably loess deposited during glacial advances by winds blowing southward from the Verkhoyansk Range and eastward across the broad vegetation-free flood plain of the braided Lena River. The well-sorted uniform tan silt is well displayed along the Aldan and Lena Rivers; the thickest exposure measured, more than 60 m, is on the Tyungyulyu Terrace on the east side of the Lena River. On the west side of the valley, it is 10-25 m thick but thins rapidly to a featheredge west of Yakutsk. Almost all scarps along the south side of the Aldan River are capped by 10-35 m of silt. The texture and mineral composition of the loess like silt are uniform throughout south-central Yakutia, whether it overlies limestone, poorly consolidated sandstone, alluvium, and glacial outwash. All silt samples examined contained a high percentage of quartz and feldspar. The silt stands in sheer cliffs and is massive, with little or no stratification. The origin of the loesslike silt has been ascribed to disintegration in place of country rock by a marine, estuarine, lacustrine, fluvial, residual, or eolian source, or to a combination of these processes. The marine and estuarine hypotheses have never had strong support, but the lacustrine, fluvial, and residual hypotheses have been advanced by many Soviet workers. The most widely accepted explanation of the origin of the upland silt is that it is a combination of lacustrine and alluvial deposits formed on great flood plains and marshy plains. This origin is unlikely, however, because there are no shorelines, wave-cut beaches, deltas, mudcracks, or ripple marks. Neither distinct stratification nor an appreciable amount of clay exists in the silt. Moreover, there is no definite upper boundary to the deposits, as would be expected of lacustrine deposits. The loesslike silt has also been described as a residual deposit formed by the breakdown, by freezing and thawing, of the underlying rocks. The silt bears no chemical, mineralogic, or textural relation to the underlying strata, however, and it is too thick to represent only breakdown of rocks in place. The widespread mantle of uniform loesslike silt is here considered to be windblown, derived from glacial outwash in braided streams and on broad plains, because: (1) it occurs as a surficial mantle; (2) it is lithologically independent of the underlying material; (3) it is stratified indistinctly or not at all, except in retransported material; (4) it is associated with sand dunes; (5) it contains fossils of land animals; (6) its sorting and texture are similar to that of loess and windblown dust from many places elsewhere in the world; (7) its grains are angular and relatively unweathered.

Professional Paper↗

Paleobiology of the Sand Beneath the Valders Diamicton at Valders, Wisconsin

Previously undescribed pollen, plant macrofossils, molluscs, and ostracodes were recovered from a 2.5-m-thick glaciolacustrine unit of silty sand and clay at Valders, Wisconsin. The interstadial sediment was deposited about 12,200 14C yr B.P. after retreat of the Green Bay lobe that deposited diamicton of the Horicon Formation, and before advance of the Lake Michigan lobe that deposited the red-brown diamicton of the Valders Member of the Kewaunee Formation. Fluctuations of abundance of Candona subtriangulata, Cytherissa lacustris, and three other species define four ostracode biozones in the lower 1.7 m, suggesting an open lake environment that oscillated in depth and proximity to glacial ice. Pollen is dominated by Picea and Artemisia, but the low percentages of many other types of longdistance origin suggest that the terrestrial vegetation was open and far from the forest border. The upper part of the sediment, a massive sand deposited in either a shallow pond or a sluggish stream, contains a local concentration of plant macrofossils. The interpretation of a cold open environment is supported by the plant macrofossils of more than 20 species, dominated by those of open mineral soils (Arenaria rubella, Cerastium alpinum type, Silene acaulis, Sibbaldia procumbens, Dryas integrifolia, Vaccinium uliginosum var. alpinum, Armeria maritima, etc.) that in North America occur largely in the tundra and open tundra-forest ecotone of northern Canada. Ice-wedge casts occur in the sand. ?? 1998 University of Washington.

Quaternary Research↗

The metal oxide fraction of pelagic sediment in the equatorial North Pacific Ocean: A source of metals in ferromanganese nodules

Pelagic sediment recovered at DOMES Site A in the equatorial North Pacific (151°W, 9° 15′N) consists of a surface homogeneous layer, approximately 10 cm thick, overlying a strongly mottled layer that is lighter in color. The radiolarian composition of both units is Quaternary. In areas where this sediment was only a few centimeters thick, the underlying sediment was early Tertiary. Clay mineralogy and major oxide composition of the two Quaternary sediments are uniform. Their similarity to continental shale suggests that the sediment has a terrigenous source. Clay mineralogy and major oxide composition of the Tertiary sediment also are uniform, although they differ markedly from the Quarternary sediment. In contrast to the major oxides, concentrations of Mn, Co, Cu, and Ni soluble in hydroxylamine hydrochlorideacetic acid are strongly different in the surface and subsurface Quaternary sediment. Mn and Ni exhibit pronounced depletions in the subsurface sediment, Ni slightly more than Mn. Cu is also depleted in the subsurface sediment, but less than Mn. It is also depleted in the subsurface Tertiary sediment, whereas the Mn concentration remains high. Concentration of Co relative to Mn increases into the subsurface Quaternary sediment to a constant Co:Mn ratio of 3 × 10 −2 . The trivalent REE (the REE exclusive of Ce) and Fe exhibit little down-core variation. Distribution of elements in these sediments is closely related to their concentration in associated surface ferromanganese nodules. The nodules are of two distinct types: those from the area where the Quaternary sediment is relatively thick have δ-MnO 2 as the dominant manganese mineral. The ratios of Ni:Mn, Cu:Mn, and Fe:Mn in these nodules approximate the corresponding ratios of the soluble fraction of surface sediment. Todorokite is the dominant mineral of nodules recovered from areas where the Quaternary sediment is thin. Relatively high Cu/Mn, Ni/Mn, and low Fe/Mn ratios of these nodules mirror differences between the soluble fraction of surface and subsurface Quaternary sediment. These compositional trends of sediment and nodules at DOMES Site A reflect a diagenetic origin for the todorokite nodules and a predominantly hydrogenous origin for the δ-MnO 2 nodules.

Geochimica et Cosmochimica Acta↗

Mineral, Energy, and Fertilizer Resources of the North Coast of Peru: Perspective from the Santa Rita B Archaeological Site

The Santa Rita B archaeological site is in the Chao Valley, approximately 65 km southeast of Trujillo, northern Peru. Location of Santa Rita B at the emergence of several drainages from the Andean cordillera is an important factor in the almost continuous occupation of the site over the past 3,000 years. Mineral resources are abundant throughout the Andes; however, the north coast of Peru was an important center for pre-Columbian mining, metallurgy, and craftsmanship. Success of the Chavin, Moche, Chimu, and other north coast cultures is directly related to the availability and exploitation of mineral and energy resources that include: gold (?silver), as electrum, mainly from placers, and copper from local oxide and carbonate occurrences and from sulfides related to copper porphyry occurrences in the cordillera. An alloy of these three metals is referred to as tumbaga, which is the primary material for Andean metalcraft. Anthracite was used for mirrors by north coast cultures and is available near Rio Chicama, Rio Santa, and east of Santa Rita B. These outcrops are a part of the Alto Chicama, Peru's largest coalfield, which extends from Rio Chicama, in the north, for 200 km southward to Rio Santa. Charcoal from the algorrobo tree and llama dung are considered to be the common pre-Columbian energy sources for cooking and metalwork; however, availability and the higher heat content of anthracite indicate that it was used in metallurgical applications. Bitumen is available from petroleum seeps near Talara, north of the study area, and may have been used as glue or as cement. Hematite, goethite, limonite, and manganese oxides from clay-altered volcanic rock may have provided color and material for ceramics. Guano from the Islas Gua?apes, Chinchas, and Ballestas was used as fertilizer for cotton and other crops.

Open-File Report↗

Hydrogeomorphic Classification of Wetlands on Mt. Desert Island, Maine, Including Hydrologic Susceptibility Factors for Wetlands in Acadia National Park

The U.S. Geological Survey, in cooperation with the National Park Service, developed a hydrogeomorphic (HGM) classification system for wetlands greater than 0.4 hectares (ha) on Mt. Desert Island, Maine, and applied this classification using map-scale data to more than 1,200 mapped wetland units on the island. In addition, two hydrologic susceptibility factors were defined for a subset of these wetlands, using 11 variables derived from landscape-scale characteristics of the catchment areas of these wetlands. The hydrologic susceptibility factors, one related to the potential hydrologic pathways for contaminants and the other to the susceptibility of wetlands to disruptions in water supply from projected future changes in climate, were used to indicate which wetlands (greater than 1 ha) in Acadia National Park (ANP) may warrant further investigation or monitoring. The HGM classification system consists of 13 categories: Riverine-Upper Perennial, Riverine-Nonperennial, Riverine- Tidal, Depressional-Closed, Depressional-Semiclosed, Depressional-Open, Depressional-No Ground-Water Input, Mineral Soil Flat, Organic Soil Flat, Tidal Fringe, Lacustrine Fringe, Slope, and Hilltop/Upper Hillslope. A dichotomous key was developed to aid in the classification of wetlands. The National Wetland Inventory maps produced by the U.S. Fish and Wildlife Service provided the wetland mapping units used for this classification. On the basis of topographic map information and geographic information system (GIS) layers at a scale of 1:24,000 or larger, 1,202 wetland units were assigned a preliminary HGM classification. Two of the 13 HGM classes (Riverine-Tidal and Depressional-No Ground-Water Input) were not assigned to any wetlands because criteria for determining those classes are not available at that map scale, and must be determined by more site-specific information. Of the 1,202 wetland polygons classified, which cover 1,830 ha in ANP, 327 were classified as Slope, 258 were Depressional (Open, Semiclosed, and Closed), 231 were Riverine (Upper Perennial and Nonperennial), 210 were Soil Flat (Mineral and Organic), 68 were Lacustrine Fringe, 51 were Tidal Fringe, 22 were Hilltop/Upper Hillslope, and another 35 were small open water bodies. Most small, isolated wetlands classified on the island are Slope wetlands. The least common, Hilltop/Upper Hillslope wetlands, only occur on a few hilltops and shoulders of hills and mountains. Large wetland complexes generally consist of groups of Depressional wetlands and Mineral Soil Flat or Organic Soil Flat wetlands, often with fringing Slope wetlands at their edges and Riverine wetlands near streams flowing through them. The two analyses of wetland hydrologic susceptibility on Mt. Desert Island were applied to 186 wetlands located partially or entirely within ANP. These analyses were conducted using individually mapped catchments for each wetland. The 186 wetlands were aggregated from the original 1,202 mapped wetland polygons on the basis of their HGM classes. Landscape-level hydrologic, geomorphic, and soil variables were defined for the catchments of the wetlands, and transformed into scaled scores from 0 to 10 for each variable. The variables included area of the wetland, area of the catchment, area of the wetland divided by the area of the catchment, the average topographic slope of the catchment, the amount of the catchment where bedrock crops out with no soil cover or excessively thin soil cover, the amount of storage (in lakes and wetlands) in the catchment, the topographic relief of the catchment, the amount of clay-rich soil in the catchment, the amount of manmade impervious surface, whether the wetland had a stream inflow, and whether the wetland had a hydraulic connection to a lake or estuary. These data were determined using a GIS and data layers mapped at a scale of 1:24,000 or larger. These landscape variables were combined in different ways for the two hydrologic susceptibility fact

Scientific Investigations Report↗

Freshwater resources and saline water near the Sac and Fox Nation tribal lands, eastern Lincoln County, Oklahoma

The purpose of this project was to evaluate the freshwater resources and possible sources of high-chloride and high-sulfate concentrations in parts of the aquifer near the Sac and Fox Nation tribal land in eastern Lincoln County, Oklahoma. Water-quality sampling and borehole geophysical data indicate the potential for fresh ground water on tribal land generally is greatest in the Vanoss Formation, in the SE1/4 sec. 21, T. 14 N., R. 06 E. and in the NE1/4 sec. 22, T. 14 N., R. 06 E. These locations avoid the flood-prone areas and borehole geophysical resistivity logs indicate the altitude of the base of fresh ground water is below 650 ft. The altitude of the base of fresh ground water is indicated to be generally near the surface under the W1/2 sec. 22, T. 14 N., R. 06 E., the SE1/4 sec. 22, SE1/4 SE1/4 NE1/4 sec. 21, and NE1/4 NW1/4 NW1/4 sec. 27. Conditions are more favorable for placement of fresh ground-water wells in sec. 34, T. 14 N., R. 06 E., where the tribe has leased water rights, than on tribal land in secs. 15, 16, 21, and 22, T. 14 N., R. 06 E. Sandstones overlain by or enclosed in thick clay and shale sequences are likely to be somewhat isolated from the flow system and retain some of the residual brine. Borehole geophysical logs suggest that sandstones near CH1, CM1, and WT1 have more clay and shale content than the sandstones near L2. Greater amounts of clay in the sandstones will retard the flushing of residual brines from the sandstones and could result in a shallow base of fresh water near CH1, CM1, and WT1. For these reasons and because circulation of fresh ground water is limited by discharge to the Deep Fork, general water quality under tribal land would probably be poorer than in the area where the tribe has leased water rights. Samples have chloride or sulfate concentrations greater than 250 milligrams per liter in the W1/2 sec. 22, T. 14 N., R. 06 E. Six cluster well samples from tribal land have chloride or sulfate concentrations above the suggested maximum contaminant levels set by U.S. Environmental Protection Agency. Water-quality data indicate there may be more than one source for the salinity in the very saline and briny samples near the tribal land. Two possible sources for chloride and sulfate in water-quality samples are shallow brines and deep oil brines. Probable sources of shallow brines in the study area are: 1) solution of minerals by fresh water moving through the aquifer and 2) residual brines deposited with the sediment. There are no salt or gypsum beds in the Vanoss, Ada, or Vamoosa Formations, but there may be nodules and finely disseminated minerals present in the formations. Residual brines could remain in sand stones and shales that have low hydraulic conductivity and have not been diluted by freshwater recharge. Data suggest both sources have mixed with the fresh ground water from the Vanoss Formation. This is indicated by the relations of the bromide/chloride concentration ratio to chloride concentration, delta deuterium to delta 18oxygen, and by delta 18oxygen to chloride molality relation.

Water-Resources Investigations Report↗

Water resources of the Big Sioux River Valley near Sioux Falls, South Dakota

The major sources of water in the Big Sioux River valley between Sioux Falls and Dell Rapids, S.Dak., are the Big Sioux River and the glacial outwash aquifer beneath the flood plain. The river and the aquifer are hydraulically connected. The Big Sioux River has an average annual discharge of 246 cubic feet per second, on the average exceeds bankfull stage every 2.3 years, and has moderate basin storage.. Periods of low flow are common in the late summer, fall, and winter. A low flow of 0.1 cubic foot per second has been recorded. The outwash aquifer is composed of permeable sand, sand and gravel, and some boulders. The aquifer underlies an area of 33 square miles and commonly has a saturated thickness of less than 30 feet. Aquifer tests and measurements of streamflow indicate a rate of streambed infiltration of about 6 gallons per day per square foot. Analyses of streambed samples and interpretations of lithology from an electric log indicate that the streambed sediments in the diversion channel of the Big Sioux River consist largely of relatively impermeable silts and clays. Under normal climatic conditions, most of the water pumped by the city of Sioux Falls is water that entered the aquifer by streambed infiltration. To evaluate the importance of the aquifer in the hydrologic system, both an electrical analog model and a digital model were programmed for storage depletion alone. These models were used to determine the water-level declines in the aquifer that would result from 1 year of withdrawal at a rate of 9-10 million gallons per day. Both models indicated that the existing well field can yield water at that rate for more than 1 year. The analog model was also used to determine the maximum average daily yield of the aquifer-river system for a 2-year period modeled for the minimum recorded stream discharge and for streambed infiltration as the only recharge. The maximum average yield under these conditions would be less than 24 million gallons per day. Most of the water pumped during this period would be from aquifer storage. Water from the river is generally less mineralized, softer, and easier to treat than ground water. Water pumped from wells near the river is similar in quality to the river water, but does not have the objectionable odors or tastes often present in water from the river.

South Dakota↗

Interpretation of K-Ar dates of illitic clays from sedimentary rocks aided by modeling

K-Ar dates of illitic clays from sedimentary rocks may contain "mixed ages," i.e., may have ages that are intermediate between the ages of end-member events. Two phenomena that may cause mixed ages are: (1) long-lasting reaction during the burial illitization of smectite: and (2) physical mixing of detrital and diagenetic components. The first phenomenon was investigated by simulation of illitization reactions using a nucleation and growth mechanism. These calculations indicate that values for mixed ages are related to burial history: for an equivalent length of reaction time, fast burial followed by slow burial produces much older mixed ages than slow burial followed by fast. The type of reaction that occurred in a rock can be determined from the distribution of ages with respect to the thickness of illite crystals. Dating of artificial mixtures confirms a non-linear relation between mixed ages and the proportions of the components. Vertical variation of K-Ar age dates from Gulf Coast shales can be modeled by assuming diagenetic illitization that overprints a subtle vertical trend (presumably of sedimentary origin) in detrital mineral content.

American Mineralogist↗

Water resources of the Rio Grande de Añasco-lower valley, Puerto Rico

A large amount of water suitable for most uses is available in the lower Rio Grande de Anasco Valley, the major source of which is the Rio Grande de Anasco which contributes about 95% of the surface water inflow to the lower valley. River flow at El Espino exceeds 100 cu ft/sec about 85% of the time and 200 cu ft/sec 50% of the time. Average daily flow for the driest months of the year (February, March, and April), is almost always <100 cu ft/sec. In contrast, the average daily flow for the wettest, months of the year (September, October, and November), is > 120 cu ft/sec. During the study period, flows of the Rio Canas averaged about 5 cu ft/sec. The lower valley is underlain by igneous rocks that have been eroded to depths of 350 ft or more below sea level. The valley is filled with 250 ft or more of limestone and clay, that in turn is overlain by as much as 100 ft of alluvium. The amount of groundwater available is unknown. There are large volumes of water in the saturated mostly fine-grained alluvium of Zone II, but as a whole the alluvium does not yield water readily to wells. Sand and gravel deposits associated with former river channels yield an estimated 100 to 150 gal/min to wells. The principal source of groundwater is the limestone of Zone III, that reportedly yields as much as 500 gal/min to wells. The quality of surface water especially that of Rio Grande de Anasco was very good. Specific conductance seldom exceeds 250 microsiemens/cm, even at low flows. Both salinity and sodium are low, falling in the Cl-S1 irrigation water classification. Water quality in the lower 5,000 ft or so of the river was affected by saltwater encroachment from the sea. The water quality of the other streams and canals in the lower valley was variable depending on susceptibility of saltwater encroachment, contamination from man-made sources, and concentration of minerals by evapotranspiration. Specific conductance however seldom exceeded 500 microsiemens/cm and the water usually falls in the C1-S2 classification. The quality of groundwater in the alluvial aquifer was about the same as that of the water of the Rio Grande de Anasco except where encroached by saltwater or contaminated. The water from the limestone was more mineralized than that of the alluvium (about 600 to 700 microsiemens/cm), and was somewhat similar to that of the smaller streams and canals in the valley.

Puerto Rico↗

Iron in the aquifer system of Suffolk County, New York, 1990-98

High concentrations of dissolved iron in ground water contribute to the biofouling of public-supply wells, and the treatment and remediation of biofouling are costly. Water companies on Long Island, N.Y., spend several million dollars annually to recondition, redevelop, and replace supply wells and distribution lines; treat dissolved iron with sequestering agents or by filtration; and respond to iron-related complaints by customers. This report summarizes the results of studies done by the U.S. Geological Survey, in cooperation with the Suffolk County Water Authority, to characterize the geochemistry and microbiology of iron in the aquifer system of Suffolk County. This information should be helpful for the siting and operation of supply wells. Concentrations of dissolved iron in Long Island's ground water, and the frequency of iron biofouling of wells, are highest in ground-water-discharge zones, particularly near the south shore. Ground water along a deep north-south flowpath of the Magothy aquifer in southwestern Suffolk County becomes anaerobic (oxygen deficient) and Fe(III) reducing at a distance of 8 to 10 kilometers south of the ground-water divide, and this change coincides with the downgradient increase in dissolved iron concentrations. The distribution of organic carbon, and the distribution and local variations in reactivity of Fe(III), in Magothy aquifer sediments have resulted in localized differences in redox microenvironments. For example, Fe(III)-reducing zones are associated with anaerobic conditions, where relatively large amounts of Fe(III) oxyhydroxide grain coatings are present, whereas sulfate-reducing zones are associated with lignite-rich lenses of silt and clay and appear to have developed in response to the depletion of available Fe(III) oxyhydroxides. The sulfate-reducing zones are characterized by relatively low concentrations of dissolved iron (resulting from iron-disulfide precipitation) and may be large enough to warrant water-supply development. Specific-capacity and water-quality data from wells screened in the Magothy aquifer indicate that water from biofouled wells contains higher median concentrations of total and dissolved iron and manganese, total phosphate, and dissolved sulfate, and lower median concentrations of dissolved oxygen and alkalinity, and lower pH, than does water from unaffected wells. Corresponding data from wells screened in the upper glacial aquifer indicate that water from biofouled wells contains higher median concentrations of total and dissolved manganese and dissolved sulfate, and lower pH, than does water from unaffected wells. Filamentous bacteria were detected in 31 (or 72 percent) of the 43 biofilm samples obtained from biofouled wells during reconditioning. The predominant filamentous organism was Gallionella ferruginea, a major biofouling agent in the upper glacial and Magothy aquifers throughout Suffolk County. Mineral-saturation indices indicate that most of the well-encrusting material is deposited when the wells are shut down. Furthermore, the use of treated water (which has a high pH and sometimes high concentrations of dissolved iron) for pump prelubrication when wells are shut down could greatly increase the rate of iron oxidation.

New York↗

Electrical structure of Newberry Volcano, Oregon

From the interpretation of magnetotelluric, transient electromagnetic, and Schlumberger resistivity soundings, the electrical structure of Newberry Volcano in central Oregon is found to consist of four units. From the surface downward, the geoelectrical units are (1) very resistive, young, unaltered volcanic rock, (2) a conductive layer of older volcanic material composed of altered tuffs, (3) a thick resistive layer thought to be in part intrusive rocks, and (4) a lower-crustal conductor. This model is similar to the regional geoelectrical structure found throughout the Cascade Range. Inside the caldera, the conductive second layer corresponds to the steep temperature gradient and alteration minerals observed in the USGS Newberry 2 test hole. Drill hole information on the south and north flanks of the volcano (test holes GEO N-1 and GEO N-3, respectively) indicates that outside the caldera the conductor is due to alteration minerals (primarily smectite) and not high-temperature pore fluids. On the flanks of Newberry the conductor is generally deeper than inside the caldera, and it deepens with distance from the summit. A notable exception to this pattern is seen just west of the caldera rim, where the conductive zone is shallower than at other flank locations. The volcano sits atop a rise in the resistive layer, interpreted to be due to intrusive rocks. The intrusive material has served as a heat source to produce enhanced hydrothermal alteration and, perhaps in the case of the west-flank anomaly, elevated fluid temperatures. While no public drill hole information is available to confirm this hypothesis, the west-flank anomaly appears to be a good geothermal target. In addition to the possibility that a region on the west side of the volcano could be favorable for prospecting, part of the resistive structure under the center of the volcano could be due to a vapor-dominated environment with temperatures above 300°C. In other parts of the Cascades, pervasive alteration has produced mixed layer clays and zeolites, resulting in low-resistivity anomalies. Low resistivities cannot be assumed to indicate high-temperature pore fluids. The use of electrical methods that measure resistivity as a function of excitation frequency, such as spectral induced polarization, may provide a way of obtaining information about the type and extent of alteration.

Journal of Geophysical Research Solid Earth↗

Preliminary geologic and geophysical data of the UE25a-3 exploratory drill hole, Nevada Test Site, Nevada

The UE25a-3 drill hole, located in the Calico Hills area, southwestern part of the Nevada Test Site, was drilled as part of an effort to evaluate the Calico Hills area as a possible nuclear waste repository site. The purpose of the drill hole was to verify the existence of an intrusive crystalline body in the subsurface and to determine the stratigraphy, structure, and nature of fractures of the cored rocks. Cored samples were obtained for mineral, chemical, and material property analyses. Continuous cores were taken from 30.5 m (100ft) to total depth of 771.2 m (2,530.1 ft) of units J and I{?) (Late Mississippian age) of the Eleana Formation. The drill hole penetrated 416.1 m (1 ,365ft) of argillite, and 304.5 m (999ft) of thermally altered argillite of unit J, and 50.6 m (166ft) of marble of unit I(?). No crystalline rocks were intersected by the drill hole. Numerous high-angle faults and brecciated zones were intersected by the drill hole. The units cored were intensely fractured with fracture analysis of the core consisting of frequency of fractures, dips of fractures, open and closed (sealed) fractures and types of fracture sealing or coating material. Twenty-four hundred and thirty fractures, representing approximately 30 percent of the fractures present, indicate an average fracture frequency of 13.2 fractures per meter, predominantly high-angle dips with 66 percent of the fractures closed. Fractures in the argillite interval are sealed or coated predominantly with kaolinite, nacrite, and dickite. Calcite, chlorite, and magnetite are present in fractures in the altered argillite interval. Fractures in the marble interval are sealed or coated with calcite, dolomite, and ferruginous clay. The core index indicates that the lower half of the drilled interval is more competent than the upper half. Borehole geophysical logs were run by the Birdwell Division of Seismograph Service Corporation for geologic correlations and lithologic characterizations. The logs include: caliper, density, resistivity, spontaneous potential, Vibroseis, 3-D velocity, neutron, and gamma-ray logs. Lithologic boundaries and structures correlate to responses in the logs.

Nevada↗

Fine-grained rutile in the Gulf of Maine: Diagenetic origin, source rocks, and sedimentary environment of deposition

The Gulf of Maine, an embayment of the New England margin, is floored by shallow, glacially scoured basins that are partly filled with late Pleistocene and Holocene silt and clay containing 0.7 to 1.0 wt percent TiO 2 , chiefly in the form of silt-size rutile. Eleven basins in the gulf are estimated to contain 479 X 10 6 metric tons of TiO 2 (to a depth of 10 m) in the U.S. exclusive economic zone and 168 X 10 6 in Canada, based on analyses of surface sediment and of cores 10 to 20 m long. The U.S. annually consumes approximately 1 X 10 6 metric tons of TiO 2 , of which 73 percent is imported. The inferred amount of fine-grained TiO 2 in the basins is large, and we interpret it to be predominantly rutile; but no attempt has been made yet to mine and beneficiate the fine-grained ore.Sedimentary rocks of Nova Scotia, New Brunswick, and northern Maine contain fine-grained rutile crystals and have been the major source of the fine-grained sediment in the Gulf of Maine basins during and after the Wisconsinan glaciation. We conclude that much of the rutile in the Gulf of Maine mud formed diagenetically in poorly cemented Carboniferous and Triassic coarse-grained sedimentary rocks of Nova Scotia and New Brunswick after the dissolution of titanium-rich detrital minerals (ilmenite, ilmenomagnetite). Another major source of rutile is the generally finer grained Paleozoic sedimentary rocks of northern Maine (and possibly northwestern New Brunswick) which contain recycled diagenetic rutile that most likely originated in sandstones. Additional Wisconsinan sources of fine-grained, diagenetic TiO 2 probably include sedimentary rocks of inferred Triassic age that underlie the Gulf of Maine.The diagenesis of rutlie in coarse sedimentary rocks (especially arkose and graywacke) followed by erosion, segregation, and deposition (and including recycling of fine-grained rutile from shales) can serve as a model for predicting and prospecting for unconsolidated deposits of fine-grained TiO 2 .Gulf of Maine mud is comparable in TiO 2 content to typical shale. A determination of whether the fine-grained TiO 2 in shales primarily occurs as detrital titanium minerals from metamorphic and igneous sources or as recycled, diagenetic titanium oxides from sedimentary sources may assist in interpreting shale provenance and environment of deposition.

Economic Geology↗

A preliminary report on the artesian water supply of Memphis, Tennessee

Memphis is located in the part of the Gulf Coastal Plain known as the Mississippi embayment. It is underlain by unconsolidated sand and clay formations of Tertiary and Cretaceous age. The Wilcox group, of Tertiary age, and the Ripley formation, of Cretaceous age, are excellent aquifers, and all the water consumed in Memphis is derived from them. The maximum pumpage from the Wilcox group was reached about 1920; in that year an estimated average of 37,575,000 gallons a day was pumped. In 1928 the average daily pumpage from the Wilcox group was about 33,984,000 gallons, and in addition to this the Memphis Artesian Water Department pumped an average of 4,616,000 gallons a day from the Ripley formation. The static level at Memphis varies with the pumpage and the stage of the Mississippi River. The original static level was about 235 feet above mean sea level. In 1928 the average static level at the Auction Avenue plant was 202 feet above mean sea level, which was about 33 feet lower than the original level. The yield is therefore about a million gallons a day for each foot of drawdown. The drawdown is not excessive, and additional pumpage can be developed without undue lowering of head. The water from both the Wilcox group and the Ripley formation is fairly soft and has a moderately low content of dissolved mineral matter. The iron content is sufficiently high to be objectionable, but the iron is easily removed by aeration followed by either settling or filtration for removal of sediment.

Tennessee↗