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USGS2007

Nutrient mass balance and trends, Mobile River Basin, Alabama, Georgia, and Mississippi

A nutrient mass balance - accounting for nutrient inputs from atmospheric deposition, fertilizer, crop nitrogen fixation, and point source effluents; and nutrient outputs, including crop harvest and storage - was calculated for 18 subbasins in the Mobile River Basin, and trends (1970 to 1997) were evaluated as part of the U.S. Geological Survey National Water Quality Assessment (NAWQA) Program. Agricultural nonpoint nitrogen and phosphorus sources and urban nonpoint nitrogen sources are the most important factors associated with nutrients in this system. More than 30 percent of nitrogen yield in two basins and phosphorus yield in eight basins can be attributed to urban point source nutrient inputs. The total nitrogen yield (1.3 tons per square mile per year) for the Tombigbee River, which drains a greater percentage of agricultural (row crop) land use, was larger than the total nitrogen yield (0.99 tons per square mile per year) for the Alabama River. Decreasing trends of total nitrogen concentrations in the Tombigbee and Alabama Rivers indicate that a reduction occurred from 1975 to 1997 in the nitrogen contributions to Mobile Bay from the Mobile River. Nitrogen concentrations also decreased (1980 to 1995) in the Black Warrior River, one of the major tributaries to the Tombigbee River. Total phosphorus concentrations increased from 1970 to 1996 at three urban influenced sites on the Etowah River in Georgia. Multiple regression analysis indicates a distinct association between water quality in the streams of the Mobile River drainage basin and agricultural activities in the basin.

Alabama, Georgia, Mississippi↗

USGS2019

The Missouri groundwater-level observation network

The Missouri groundwater-level observation well network is a series of wells across the State of Missouri in which groundwater levels are monitored in real time and periodically. The wells monitor the water levels in multiple key aquifers, such as the Ozark aquifer in the Salem and Springfield Plateaus and the Mississippi Alluvial Plain aquifer in the South-eastern Lowlands. As of 2018, 150 real-time sites are operated as a cooperative effort between the Missouri Department of Natural Resources (MoDNR) and the U.S. Geological Survey. This fact sheet describes the network and well data from the network.

Missouri↗

USGS2011

Forecast Mekong: navigating changing waters

The U.S. Geological Survey (USGS) is using research and data from the Mekong River Delta in Southeast Asia to compare restoration, conservation, and management efforts there with those done in other major river deltas, such as the Mississippi River Delta in the United States. The project provides a forum to engage regional partners in the Mekong Basin countries to share data and support local research efforts. Ultimately, Forecast Mekong will lead to more informed decisions about how to make the Mekong and Mississippi Deltas resilient in the face of climate change, economic stresses, and other impacts.

General Information Product↗

USGS2005

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin — Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

As part of a national analysis of the effects of land use on ground-water quality for the National Water-Quality Assessment Program, the U.S. Geological Survey sampled wells along a flow system in surficial glacial aquifers in the northwestern part of the Twin Cities metropolitan area during 1997 and 1998. In addition, a reconnaissance steady-state ground-water model was developed to estimate flowpaths and dates of ground-water recharge using a particle-tracking routine. Sediment samples collected during drilling had high horizontal hydraulic conductivities (ranging from about 3.1 to about 190 feet per day, based on sediment-size analysis of well cuttings), small organic carbon concentrations (ranging from less than 0.2 to 160 grams per kilogram), and pH values that were mostly alkaline (ranging from 4.9 to 8.2). Water samples were analyzed for physical properties, major ions, iron, manganese, nutrients, organic carbon, radon, pesticides, volatile organic compounds (VOCs), chlorofluorocarbons, tritium, and isotopes of nitrogen, hydrogen, and oxygen. Most of the water samples had small dissolved-oxygen concentrations (less than 1 milligram per liter). Calcium, magnesium, sodium, bicarbonate, sulfate, and chloride were the primary dissolved constituents in water samples. Nitrite plus nitrate as nitrogen (nitrate) concentrations were less than the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level of 10 mg/L. Nitrogen isotope ratios indicated that the sources of nitrate primarily were soils, animal waste, or denitrification that increased nitrogen isotope ratios in nitrate. Small concentrations of pesticides were detected in the shallow parts of the aquifer. The herbicide prometon was the most frequently detected pesticide. Herbicides applied to control grasses and weeds in corn (atrazine, simazine, and metolachlor) also were frequently detected in water samples. All pesticide and VOCs detected were below USEPA Maximum Contaminant Levels or Health Advisory Limits. Chlorofluorocarbon compounds and tritium concentrations were used to estimate dates of recharge of ground-water samples. In general, shallower ground-water samples were more recently recharged although most water sampled from the aquifer was recharged after 1955. Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Minnesota↗

USGS2013

Hydrogeology, distribution, and volume of saline groundwater in the southern midcontinent and adjacent areas of the United States

The hydrogeology, distribution, and volume of saline water in 22 aquifers in the southern midcontinent of the United States were evaluated to provide information about saline groundwater resources that may be used to reduce dependency on freshwater resources. Those aquifers underlie six States in the southern midcontinent—Arkansas, Kansas, Louisiana, Missouri, Oklahoma, and Texas—and adjacent areas including all or parts of Alabama, Colorado, Florida, Illinois, Kentucky, Mississippi, Nebraska, New Mexico, South Dakota, Tennessee, and Wyoming and some offshore areas of the Gulf of Mexico. Saline waters of the aquifers were evaluated by defining salinity zones; digitizing data, primarily from the Regional Aquifer-System Analysis Program of the U.S. Geological Survey; and computing the volume of saline water in storage. The distribution of saline groundwater in the southern midcontinent is substantially affected by the hydrogeology and groundwater-flow systems of the aquifers. Many of the aquifers in the southern midcontinent are underlain by one or more aquifers, resulting in vertically stacked aquifers containing groundwaters of varying salinity. Saline groundwater is affected by past and present hydrogeologic conditions. Spatial variation of groundwater salinity in the southern midcontinent is controlled primarily by locations of recharge and discharge areas, groundwater-flow paths and residence time, mixing of freshwater and saline water, and interactions with aquifer rocks and sediments. The volume calculations made for the evaluated aquifers in the southern midcontinent indicate that about 39,900 million acre-feet (acre-ft) of saline water is in storage. About 21,600 million acre-ft of the water in storage is slightly to moderately saline (1,000–10,000 milligrams per liter [mg/L] dissolved solids), and about 18,300 million acre-ft is very saline (10,000–35,000 mg/L dissolved solids). The largest volumes of saline water are in the coastal lowlands (about 16,300 million acre-ft), Mississippi embayment and Texas coastal uplands (about 12,000 million acre-ft), and Great Plains (about 8,170 million acre-ft) aquifer systems. Of the 22 aquifers evaluated in this report, the Maha aquifer in the Great Plains aquifer system contains both the largest total volume of saline water (about 6,280 million acre-ft) and the largest volume of slightly to moderately saline water (about 5,150 million acre-ft).

Alabama;Arkansas;Colorado;Florida;Illinois;Kansas;↗

USGS2012

Geologic controls on sediment distribution and transport pathways around the Chandeleur Islands, LA., USA

Geophysical surveys around the Chandeleur Islands provide the necessary data to map the thickness and distribution of the Holocene deposit associated with this barrier island system. This system rests uncomformably on St. Bernard Delta deposits of the Mississippi Delta plain and is thinnest under the central part of the island chain and thickest at the northern and southern ends. The zone of divergence in the bidirectional littoral transport system coincides with the thin central part. An estimate of northward littoral transport rate based on lithosome age and the volume of sediment that has accumulated at the northern end of the transport cell suggests the average transport rate over the life of the system is greater than present day fair-weather estimates. This difference may be attributed to changes in transport rates through the life of the system, to changes in the rate of sea-level rise or to storms playing a more dominant role than fair-weather waves in littoral transport.

Louisiana↗

USGS2021

Nitrogen and phosphorus sources and delivery from the Mississippi/Atchafalaya River Basin: An update using 2012 SPARROW models

Nitrogen (N) and phosphorus (P) inputs throughout the Mississippi/Atchafalaya River Basin (MARB) have been linked to the Gulf of Mexico hypoxia and water‐quality problems throughout the MARB. To describe N and P loading throughout the MARB, SPAtially Referenced Regression On Watershed attributes (SPARROW) models were previously developed based on nutrient inputs and management similar to 1992 and 2002. In this study, refined SPARROW models were developed with higher resolution basin delineation, updated (2012) source inputs, improved calibration (load) targets, and additional statistical techniques than used in the previous SPARROW models. Based on the refined models, consistent with past models, N and P loads/yields were the highest from the central part of the MARB (Corn Belt) and along the Mississippi River. Agricultural activities remained the most important N and P source, but more so for N because its input, which could now be distinguished from atmospheric deposition, could be estimated. Natural loss of P from geologic material throughout the MARB was an important source, contributing about 23% of the total P from the MARB, and resulted in specific areas, such as Kentucky and Tennessee, being larger sources of P than previously estimated. This information can help managers decide where efforts will have the largest effects (highest ranked areas) on reducing nutrient loading to the Gulf hypoxia and what are the most important sources of N and P in these areas.

Mississippi/Atchafalaya River Basin↗

USGS1970

Binary coefficients and clustering in biostratigraphy

The large data arrays common in biostratigraphy make subjective groupings difficult. Because of this, biostratigraphers have commonly based conclusions on the occurrences of relatively few species. The use of binary similarity coefficients, cluster analysis techniques, and digital computers allows a polythetic approach to biostratigraphy. The approach is free of circular and a priori reasoning in that it is established that assemblage zones (major clusters in a dendrogram) are present before the biostratigraphic utility of various taxa for the recognition of the zones is determined. A measure for determining the biostratigraphic fidelity of a species for established zones is proposed. Published data on the distribution of ostracodes and foraminifers from the Eocene and Oligocene of Mississippi and Alabama are used to demonstrate a method of using coefficients and clustering in establishing a zonation.

Alabama, Mississippi↗

USGS1966

Isotopic study of galenas from the upper Mississippi Valley, the Illinois-Kentucky, and some Appalachian Valley mineral districts

Analyses of lead isotopes in galena in carbonate rock ore deposits collected from several mineralized districts in the Central and Eastern Interior of the United States support previous studies in establishing that the galena is anomalously radiogenic ("J"type")- This study , using care-fully selected samples to test some géologie relationships, shows region-wide and distrietwide systematic variations in isotope ratios. The genetic implications of thèse variations are discussed. Two mechanisms of origin are considered to explain thèse variations in isotopic ratios. One involves mixing of leads from multiple sources, the other calls for variable lead-isotope ratios originating from a single source. Several source materials for the lead ores have been suggested; whether a single source has predominated, or two or more main sources have predominated is still unresolved. Slopes from Pb206/Pb204 versus Pb207/Pb204 plot are compatible with a contribution of lead by the 1300 ± 300 m.y. basement rocks that underlie the deposits. The spatial relationships of alkaline igneous rocks to several of the minerai districts in the Mississippi Valley région suggest a possible mag-matic source for the lead. Isotopic analyses of galenas closely associated with several of the intrusive rocks are similar in isotopic composition to adjacent ore leads, but genetic implications are ambiguous. Galena oc-curring in shales in the Mississippi Valley région outside mineralized districts contains ordinary lead. Théories that call upon such shales to be the major source of the lead in the depoaits of the Mississippi Valley type must explain this distinct différence in isotopic compositions. Galena collected from districts within the Appalachian Ridge and Valley Province contains notably less radiogenic lead than that from the Mississippi Valley minerai districts , and the lead is of the ordinary type.

Illinois, Kentucky↗

USGS2018

Assessment of undiscovered continuous oil and gas resources in the Upper Cretaceous Tuscaloosa marine shale of the U.S. Gulf Coast, 2018

Using a geology-based assessment methodology, the U.S. Geological Survey assessed mean undiscovered, technically recoverable continuous resources of 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas in the Upper Cretaceous Tuscaloosa marine shale in onshore and State waters of Louisiana, Mississippi, Alabama, and Florida in the U.S. Gulf Coast region.

Upper Cretaceous Tuscaloosa Marine Shale↗

USGS2000

Biomonitoring of Environmental Status and Trends (BEST) Program: Selected methods for monitoring chemical contaminants and their effects in aquatic ecosystems

This document describes the suite of biological methods of the U.S. Geological Survey- Biomonitoring of Environmental Status and Trends program for monitoring chemical contaminants and their effects on fish. The methods, which were selected by panels of experts, are being field-tested in rivers of the Mississippi River, Columbia River, and Rio Grande basins. General health biomarkers include a health assessment index based on gross observation; histopathological examination of selected organs and tissues; condition factor; and the heptosomatic and splenosomatic indices. Immune system indicators are plasma lysozyme activity and measures of splenic macrophage aggregates. Reproductive biomarkers include plasma concentrations of sex steroid hormones (17β-estradiol and 11-ketotestosterone) and vitellogenin, gonadal histopathology (including reproductive stage and, in females, gonadal atresia), and the gonadosomatic index. Indicators of exposure to polycyclic aromatic and polyhalogenated hydrocarbons are the H4IIE rat hepatoma cell bioassay (performed on solvent extracts of composite fish samples) and hepatic ethoxyresorufin- O -deethylase activity. Stable nitrogen isotope ratios are used to assess the trophic position of the fish and their exposure to sewage and other animal wastes. For each indicator we describe endpoint(s) and methods, and discuss the indicator?s value and limitations for contaminant monitoring and assessment.

Information and Technology Report↗

USGS2012

Tabulated Transmissivity and Storage Properties of the Floridan Aquifer System in Florida and Parts of Georgia, South Carolina, and Alabama

A goal of the U.S. Geological Survey Groundwater Resources Program is to assess the availability of fresh water within each of the principal aquifers in the United States with the greatest groundwater withdrawals. The Floridan aquifer system (FAS), which covers an area of approximately 100,000 square miles in Florida and parts of Georgia, Alabama, Mississippi, and South Carolina, is one such principal aquifer, having the fifth largest groundwater withdrawals in the Nation, totaling 3.64 billion gallons per day in 2000. Compilation of FAS hydraulic properties is critical to the development and calibration of groundwater flow models that can be used to develop water budgets spatially and temporally, as well as to evaluate resource changes over time. Wells with aquifer test data were identified as Upper Floridan aquifer (UFA), Lower Floridan aquifer (LFA), Floridan aquifer system (FAS, Upper Floridan with some middle and/or Lower Floridan), or middle Floridan confining unit (MCU), based on the identification from the original database or report description, or comparison of the open interval of the well with previously published maps. This report consolidates aquifer hydraulic property data obtained from multiple databases and reports of the U.S. Geological Survey, various State agencies, and the Water Management Districts of Florida, that are compiled into tables to provide a single information source for transmissivity and storage properties of the FAS as of October 2011. Transmissivity calculated from aquifer pumping tests and specific-capacity data are included. Values for transmissivity and storage coefficients are intended for use in regional or sub regional groundwater flow models; thus, any tests (aquifer pumping tests and specific capacity data) that were conducted with packers or for open intervals less than 30 feet in length are excluded from the summary statistics and tables of this report, but are included in the database. The transmissivity distribution from the aquifer pumping tests is highly variable. The transmissivity based on aquifer pumping tests (from 1,045 values for the UFA and FAS) ranges from 8 to about 9,300,000 square feet per day (ft 2 /d) and values of storage coefficient (646 reported) range from 3x10 -9 to 0.41. The 64 transmissivity values for the LFA range from about 130 to 4,500,000 ft 2 /d, and the 17 storage coefficient values range from 7x10 -8 to 0.03. The 14 transmissivity values for the MCU range from 1 to about 600,000 ft 2 /d and the 10 storage coefficient values range from 8x10 -8 to 0.03. Transmissivity estimates for the UFA and FAS for 442 specific capacity tests range from approximately 200 to 1,000,000 ft 2 /d.

Alabama, Florida, Georgia, South Carolina↗

USGS2002

Multibeam mapping of the West Florida Shelf, Gulf of Mexico

A zone of deep-water reefs is thought to extend from the mid and outer shelf south of Mississippi and Alabama to at least the northwestern Florida shelf off Panama City, Florida (Figure 1). The reefs off Mississippi and Alabama are found in water depths of 60 to 120 m (Ludwick and Walton, 1957; Gardner et al., 2001, in press) and were the focus of a multibeam echosounder (MBES) mapping survey by the U.S. Geological Survey (USGS) in 2000 (Gardner et al., 2000, Gardner et al., 2001, in press). If this deep-water-reef trend does exist along the northwestern Florida shelf, then it is critical to determine the accurate geomorphology and reef type that occur because of their importance as benthic habitats for fisheries. Georeferenced high-resolution mapping of bathymetry is a fundamental first step in the study of areas suspected to be critical habitats. Morphology is thought to be critical to defining the distribution of dominant demersal plankton/planktivores communities. Fish faunas of shallow hermatypic reefs have been well studied, but those of deep ahermatypic reefs have been relatively ignored. The ecology of deep-water ahermatypic reefs is fundamentally different from hermatypic reefs because autochthonous intracellular symbiotic zooxanthellae (the carbon source for hermatypic corals) do not form the base of the trophic web in ahermatypic reefs. Instead, exogenous plankton, transported to the reef by currents, serves as the primary carbon source. Thus, one of the principle uses of the morphology data will be to identify whether any reefs found are hermatypic or ahermatypic in origin.

Alabama;Florida;Mississippi↗

USGS2026

Background and geologic model for the 2024 U.S. Geological Survey assessment of undiscovered conventional petroleum resources in the Norphlet Formation, U.S. Gulf Coast

The Upper Jurassic Norphlet Formation is a stratigraphic unit located in the subsurface of the United States Gulf coastal plain and offshore Gulf of America (Gulf of Mexico). The Norphlet consists of clastic sediments derived from the southern Appalachian highlands, and was deposited in a continental dryland setting on the margins of the early Gulf of America rift basin. The formation contains a variety of sedimentary facies, including facies representing updip alluvial fans, wadis, red beds, and a widespread erg, or eolian sand sea. The erg facies form the primary reservoirs from which hydrocarbons sourced from the overlying Smackover Formation are produced. Development of the Norphlet began in earnest in the late 1960s, with new discoveries, including large fields at Flomaton, Hatters Pond, and Mobile Bay, continuing through the 2000s–2010s with the discovery of major oil fields in the offshore Desoto Canyon area. Onshore, Norphlet hydrocarbon traps typically are faulted salt anticlines, although many fields also have a stratigraphic trapping component because of the preservation of dune-scale bedforms. Thermal maturity across the Norphlet play varies significantly with depth, resulting in oil production transitioning downdip to natural gas liquids production, then dry gas production; production depths reach to greater than 21,000 feet. A 2024 U.S. Geological Survey assessment divided the Norphlet into four conventional assessment units defined by the type and frequency of trapping mechanisms, sedimentology, and thermal maturity of each area, with little potential for hydrocarbon development observed west of the Mississippi River. Although petroleum resources in the Norphlet were revised downward, it is probable that significant resources remain to be discovered.

Alabama, Florida, Mississippi↗

USGS1991

Selected water-quality characteristics in the upper Mississippi River basin, Royalton to Hastings, Minnesota

The upper Mississippi River basin from Royalton to Hastings, Minnesota, includes seven subbasins in east-central Minnesota that cover an area of 8,500 square miles. Results of a study, using data from the Minnesota Pollution Control Agency, Metropolitan Waste Control Commission, and the U.S. Geological Survey, indicate that selected water-quality characteristics differ significantly among subbasins. Results of the study also indicate that the quality of water leaving the basin at Hastings is affected primarily by inflow from the Minnesota River and by effluent from the Metropolitan sewage-treatment plant. Subbasins in the western part of the study area are underlain by prairie soils and cultivation of row crops is a common land use. Streams draining these subbasins have a median dissolved-solids concentration of 389 mg/L (milligrams per Liter) and a median concentration of nitrite plus nitrate nitrogen of 0.59 mg/L. Subbasins in the northern and eastern parts of the study area are underlain by more acidic podzol soils. Land use in these subbasins is less devoted to cultivated crops; forested areas, pastures, and wetlands are common. Streams draining these subbasins have a median dissolved- solids concentration of 184 mg/L and a median concentration of nitrite plus nitrate nitrogen of 0.17 mg/L. The quality of water changes dramatically in the most downstream subbasin, which includes the Twin Cities Metropolitan Area. On the basis of hourly data from automatic monitors, specific conductance increases from 345 / μ S/cm (microsiemens per centimeter) at 25° Celsius above the confluence with the Minnesota River to 467 / μ S/cm below it. Specific conductance increases to a median of 513 / μ S/cm where effluent from the Metropolitan sewage-treatment plant enters the Mississippi River. Dissolved-oxygen concentrations in the Mississippi River begin to decline below the confluence with the Minnesota River. Concentrations of dissolved oxygen reach a minimum median value in summer of 6.3 mg/L at a point about 9 miles downstream from the Metropolitan sewage-treatment plant. In winter, minimum median concentration is downstream at Lock and Dam 2, which is approximately 20 miles below the plant. Results of this study show that the quality of water in the Mississippi River as it leaves the accounting unit at Hastings is not representative of water quality in most of the accounting unit. Three water-quality regions have been identified, and sampling sites are needed in each region to assess the quality of streams throughout the study area adequately.

Minnesota↗

USGS2020

Late Quaternary evolution and stratigraphic framework influence on coastal systems along the north-central Gulf of Mexico, USA

Coastal systems in the Gulf of Mexico are threatened by reduced sediment supply, storm impacts and relative sea-level rise (RSLR). The geologic record provides insight into geomorphic evolution thresholds to these forcing mechanisms to help predict future barrier evolution in response to climate change. This study synthesizes ∼2100 km of geophysical data, 700 + sediment cores, and 62 radiocarbon dates to regionally map two lowstand sequence boundaries, multiple ravinement surfaces and fourteen depositional facies demonstrating stratigraphic and antecedent topographic influences on coastal evolution. The Mississippi-Alabama (MSAL) barriers are anchored by a marine isotope stage (MIS) 5e section of Dauphin Island coupled with an MIS 2 surface gradient change. Sand for the modern MSAL barriers were largely sourced through Holocene transgressive ravinement of relict valley fill deposits, providing up to 300 × 106 m3 of sand. Mud-filled MIS 2 tributaries correspond to areas of repeated storm breaching or tidal inlets. A Holocene geomorphic evolutionary model was created for Petit Bois and Dauphin Islands, highlighting RSLR rates, changes in sediment supply and the antecedent geologic framework. As the MIS 2 surface was flooded, tidal/wave scour supplied sand to migrating marine shoals. These transgressing shoals converted drowned paleovalleys to estuaries ∼9ka BP. Islands formed in their modern positions ∼6ka BP, when sediment supply was high and RSLR rates were 2 mm/yr. Between ∼4ka-1750 CE, islands prograded from reduced RSLR rates of 1-0.4 mm/yr and sufficient sand supply from alongshore/inner shelf sources. Currently, the islands experience 3.74 mm/yr of RSLR and reduced sediment supply, resulting in barrier degradation.

Alabama, Mississippi↗

USGS2022

Infiltration of late Palaeozoic evaporative brines in the reelfoot rift: A possible salt source for Illinois Basin formation waters and MVT mineralizing fluids

Salinities and homogenization temperatures of fluid inclusions in Mississippi Valley-type (MVT) deposits provide important insights into the regional hydrology of the Illinois basin/Reelfoot rift system in late Palaeozoic time. Although the thermal regime of this basin system has been plausibly explained, the origin of high salinities in the basin fluids remains enigmatic. Topographically driven flow appears to have been essential in forming these MVT districts, as well as many other districts worldwide. However, this type of flow is recharged by fresh water making it difficult to account for the high salinities of the mineralizing fluids over extended time periods. Results of numerical experiments carried out in this study provide a possible solution to the salinity problem presented by the MVT zinc-lead and fluorite districts at the margins of the basin system. Evaporative concentration of surface water and subsequent infiltration into the subsurface are proposed to account for large volumes of brine that are ultimately responsible for mineralization of these districts. This study demonstrates that under a range of geologically reasonable conditions, brine infiltration into an aquifer in the deep subsurface can coexist with topographically driven flow. Infiltration combined with regional flow and local magmatic heat sources in the Reelfoot rift explain the brine concentrations as well as the temperatures observed in the Southern Illinois and Upper Mississippi Valley districts.

Petroleum Geoscience↗

USGS2001

Occurrence, distribution, and transport of nutrients in Eastern Iowa Rivers

Eleven streams in the Wapsipinicon, Cedar, Iowa, and Skunk River basins in eastern Iowa were sampled monthly from March 1996 through September 1998 to assess the occurrence, distribution, and transport of nitrogen, phosphorus, and suspended sediment as part of the U.S. Geological Survey's National Water-Quality Assessment Program. At least one form of dissolved nitrogen and phosphorus was detected in every sample collected. Nitrate accounted for 92 percent of the dissolved nitrogen. About 22 percent of the samples contained nitrate that exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level of 10 milligrams per liter (mg/L) as nitrogen in drinking water. The median concentration of total nitrogen for surface water in the study area was 7.2 mg/L. Dissolved phosphorus was predominately in the form of orthophosphate. The median total phosphorus concentration for the study area was 0.22 mg/L. About 75 percent of the total phosphorus concentrations exceeded the U.S. Environmental Protection Agency recommended total phosphorus concentration of 0.10 mg/L or less to minimize algal growth in streams not discharging directly into lakes or impoundments. Median suspended-sediment concentration for the study area was 82 mg/L. Nitrogen, phosphorus, and suspended-sediment concentrations varied annually and seasonally. Nitrogen, phosphorus, and suspended-sediment concentrations increased each year of the study due to increased precipitation and runoff. Concentrations were typically higher in the spring after fertilizer application and runoff. In winter, nitrogen concentrations typically increased when there was little instream assimilation by aquatic plants and algae. Nitrogen and phosphorus concentrations decreased in late summer when there was less runoff and instream assimilation of nitrogen and phosphorus by aquatic plants and algae was high. Suspended-sediment concentrations were highest in early summer during runoff and lowest in January when there was ice cover with very little overland flow contributing to rivers and streams. Streams draining small- to medium-sized watersheds that have uniform land use and geology had significantly (p < 0.05) higher total dissolved-nitrogen concentrations (median, 8.2 mg/L) than did samples from large rivers (median, 6.2 mg/L) that drain basins with mixed land use and geology. Samples from large rivers typically had significantly (p< 0.05) higher total phosphorus and suspended-sediment concentrations than did samples from small rivers and streams. Concentrations varied between drainage basins due to land use and physiography. Basins that are located in areas with a higher percentage of row-crop agriculture typically had samples with higher nitrogen concentrations than did basins with less row-crop agriculture. In addition, basins that drain the Southern Iowa Drift Plain and the Des Moines Lobe typically had samples with higher total phosphorus and suspended-sediment concentrations than did basins that drain other landform regions. Total nitrogen and total phosphorus loads were typically proportional to the size of the drainage basin. Total nitrogen loads increased each year from 1996 through 1998 in conjunction with increased concentrations and runoff. However, total phosphorus loads in the Skunk River Basin decreased in 1997 due to less runoff. Total phosphorus loads followed the same pattern as total nitrogen loads with increases in 1998. Total nitrogen and total phosphorus loads varied seasonally and the highest loads typically occurred in early spring and summer after fertilizer application and runoff. Loads were lowest in January and September when there was little runoff to transport nitrogen and phosphorus to the rivers and streams. Total nitrogen loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 97,000, 120,000, and 230,000 metric tons respectively. Total phosphorus loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 6,900, 4,600, and 8,800 metric tons, respectively. The highest nitrogen and phosphorus yields typically occurred in streams draining small watersheds that were dominated by a single land use and geology. Sampling sites located in drainage basins with higher row-crop percentage typically had higher nitrogen and phosphorus yields. Sites that were located in the Des Moines Lobe and the Southern Iowa Drift Plain typically had higher phosphorus yields probably due to more erodible soils and steeper slopes.

Iowa↗