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USGS1980

The distribution and mobility of uranium in glassy and zeolitized tuff, Keg Mountain area, Utah, U.S.A.

The distribution and mobility of uranium in a diagenetically altered, 8 Ma old tuff in the Keg Mountain area, Utah, are modelled in this study. The modelling represents an improvement over similar earlier studies in that it: (1) considers a large number of samples (76) collected with good geologic control and exhibiting a wide range of alteration; (2) includes radiometric data for Th, K and RaeU (radium equivalent uranium) as well as U; (3) considers mineralogic and trace-element data for the same samples; and (4) analyzes the mineral and chemical covariation by multivariate statistical methods. The variation of U in the tuff is controlled mainly by its primary abundance in glass and by the relative abundance of non-uraniferous detritus and uraniferous accessory minerals. Alteration of glass to zeolite, even though extensive, caused no large or systematic change in the bulk concentration of U in the tuff. Some redistribution of U during diagenesis is indicated by association of U with minor alteration products such as opal and hydrous Fe-Mn oxide minerals. Isotopic studies indicate that the zeolitized tuff has been open to migration of U decay products during the last 0.8 Ma. The tuff of Keg Mountain has not lost a statistically detectable fraction of its original U, even though it has a high (??? 9 ppm) trace U content and has been extensively altered to zeolite. Similar studies in a variety of geological environments are required in order to identify the particular combination of conditions most favorable for liberation and migration of U from tuffs. ?? 1980.

Chemical Geology↗

USGS1975

Map showing fluorspar deposits in Colorado

Increased fluorine consumption (U.S. Bureau of Mines, 1946-1971) coupled with limited proved reserves has stimulated extensive exploration for fluorine and intensive research into developing new sources of fluorine or substitutes. A summary of the distribution, geochemical and geologic environments, and production history of selected fluorspar occurrences, deposits, and districts is provided here with the hope that this information will help to stimulate exploration and discovery of additional fluorspar resources in Colorado to augment our dwindling domestic supply.

Colorado↗

USGS2018

Cadmium isotope fractionation during coal combustion: Insights from two U.S. coal-fired power plants

Coal combustion, one of the principal energy sources of electricity in the United States, produces over 100 million tons of coal combustion products (CCPs) per year in the U.S. The reuse and disposal of CCPs has the potential to release toxic trace elements, including cadmium (Cd), into the environment. In this study, we investigated CCPs, including bottom ash (BA), economizer fly ash (EFA), and fly ash (FA), as well as feed coal (FC) and pulverized coal (PC) collected from two U.S. coal-fired power plants in New Mexico and Ohio with different coal supplies. The New Mexico plant uses high volatile C bituminous, low-sulfur coals mined from the San Juan Basin (Cretaceous Fruitland Formation) and the Ohio plant uses high volatile A bituminous, high-sulfur central Appalachian Basin coals (Upper Pennsylvanian Monongahela Formation). Mineralogical and elemental analysis showed that these CCP samples consist of ∼70% amorphous Al-Si-rich glasses and ∼30% mineral phases of quartz (SiO 2 ) and mullite (Ai 6 Si 2 O 13 ). The Cd isotope compositions (δ 114 Cd, normalized to NIST Cd standard 3108) of FA and EFA samples (ranging from −0.51 to +0.47‰) are distinctively heavier than those of BA samples (−0.75 to −0.52‰) in both power plants. We interpret this Cd isotope difference as a result of Cd condensation from the gas phase during flue gas cooling, instead of evaporation of Cd phase during coal combustion. Cd condensation is the main process to generate the isotopically heavy Cd signatures that preferentially partition on the fine FA particles. We also investigated Cd isotope compositions in different leachate products from a series of batch-leaching experiments with these CCPs, using diluted acetic acid, hydroxyl ammonium chloride, hydrogen peroxide followed by ammonium acetate, and 5% nitric acid, as a possible means to identify CCP-released Cd in the environment. Unusually and significantly heavier Cd isotope compositions were observed in each leachate of FA samples (+1.10 to +7.09‰), which fall far outside from the range of Cd isotope ratios observed in natural soils and rocks, but less so for the EFA samples (−0.43 to +1.18‰). Such an observation is consistent with the interpretation that isotopically heavy Cd preferentially partitions on the fine FA particles after coal combustion and is readily to be released during these leaching experiments. This study demonstrates that high-temperature coal combustion can lead to a very large degree of fractionation of Cd isotopes that can be used as a unique tracer for identifying anthropogenic metal inputs in the environment. The major Cd isotope fractionation process occurs as the Cd gas phase condenses on fine FA particles during the flue gas cooling stage after coal combustion.

New Mexico, Ohio↗

USGS2010

Chemical weathering in the Loch Vale Watershed, Rocky Mountain National Park, Colorado

Mineralogic, hydrologic, and geochemical data were used to determine the source of solutes to surface waters draining the Loch Vale Watershed (LVWS), an alpine-subalpine drainage located in the Front Range of Colorado. The flux of dissolved solids from LVWS is primarily controlled by interactions between snowmelt and materials derived from the local bedrock; the biomass has only a minor effect on solute budgets except for ammonium. LVWS is underlain by Precambrian granite and gneiss, the major minerals include quartz, microcline, plagioclase, biotite, and sillimanite. Small amounts of calcite were found along hydrothermally altered zones in the bedrock. Mass balance calculations indicate that the weathering of calcite contributes nearly 40% of the cations derived within the basin. The importance of calcite weathering in LVWS is a result of its chemical reactivity and the high rate of physical erosion in this alpine environment. The average cationic denudation rate in the drainage (390 eq/ha/yr) is similar to long-term rates in forested Adirondack watersheds (500–600 eq/ha/yr), but much lower than the average for the North American Continent (3800 eq/ha/yr). Surface waters in LVWS are susceptible to acidification should acid deposition from the atmosphere increase.

Colorado↗

USGS2018

Meurigite, a new fibrous iron phosphate resembling kidwellite

Meurigite is a new hydrated potassium iron phosphate related to kidwellite and with structural similarities to other late-stage fibrous ferric phosphate species. It has been found at four localities so far — the Santa Rita mine, New Mexico, U.S.A.; the Hagendorf-Sud pegmatite in Bavaria, Germany; granite pegmatite veins at Wycheproof, Victoria, Australia; and at the Gold Quarry Mine, Nevada, U.S.A. The Santa Rita mine is the designated type locality. Meurigite occurs as tabular, elongated crystals forming spherical and hemispherical clusters and drusy coatings. The colour ranges from creamy white to pale yellow and yellowish brown. At the type locality, the hemispheres may reach 2 mm across, but the maximum diameter reached in the other occurrences is usually less than 0.5 mm. A wide variety of secondary phosphate minerals accompanies meurigite at each locality, with dufrenite, cyrilovite, beraunite, rockbridgeite and leucophosphite amongst the most common. Vanadates and uranates occur with meurigite at the Gold Quarry mine. Electron microprobe analysis and separate determination of H 2 O and CO 2 on meurigite from the type locality gave a composition for which several empirical formulae could be calculated. The preferred formula, obtained on the basis of 35 oxygen atoms, is which simplies Qualitative analyses only were obtained for meurigite from the other localities, due to the softness and openness of the aggregates. Because of the fibrous nature of meurigite, it was not possible to determine the crystal structure, hence the exact stoichiometry remains uncertain. The lustre of meurigite varies from vitreous to waxy for the Santa Rita mine mineral, to silky for the more open sprays and internal surfaces elsewhere. The streak is very pale yellow to cream and the estimated Mohs hardness is about 3. Cleavage is perfect on {001} and fragments from the type material have a mean specific gravity of 2.96. The strongest lines in the X-ray powder pattern for the type material are ( d obs , I obs , hkl ) 3.216(100)404; 4.84(90)111; 3.116(80)205; 4.32(70)112; 9.41(60)201; 3.470(60)800. The X-ray data were indexed on the basis of a monoclinic unit cell determined from electron diffraction patterns. The cell parameters, refined by least squares methods, are a = 29.52(4), b = 5.249(6), c = 18.26(1) Å, β = 109.27(7)°, V = 2672(3) Å 3 , and Z = 4. The calculated density is 2.89 gcm −3 . The space group is either C 2, Cm or C 2 / m . X-ray powder data for meurigite are closely similar to those for kidwellite and phosphofibrite, but meurigite appears to be characterised by a strong 14 Å reflection. The relationship between these three minerals remains uncertain in the absence of structural data. On the available evidence, meurigite and kidwellite are not the respective K and Na-endmembers of a solid solution series. The meurigite cell parameters suggest it belongs to a structural family of fibrous ferric phosphates, such as rockbridgeite, dufrenite and beraunite, which have a discrete 5 Å fibre axis. Meurigite occurs in widely varying environments, its formation probably favoured by late-stage solutions rich in K rather than Na.

Mineralogical Magazine↗

USGS2008

Reconnaissance study of water quality in the mining-affected Aries River Basin, Romania

The Aries River basin of western Romania has been subject to mining activities as far back as Roman times. Present mining activities are associated with the extraction and processing of various metals including Au, Cu, Pb, and Zn. To understand the effects of these mining activities on the environment, this study focused on three objectives: (1) establish a baseline set of physical parameters, and water- and sediment-associated concentrations of metals in river-valley floors and floodplains; (2) establish a baseline set of physical and chemical measurements of pore water and sediment in tailings; and (3) provide training in sediment and water sampling to personnel in the National Agency for Mineral Resources and the Rosia Poieni Mine. This report summarizes basin findings of physical parameters and chemistry (sediment and water), and ancillary data collected during the low-flow synoptic sampling of May 2006.

Aries River Basin↗

USGS1994

Effects of sediment depositional environment and ground-water flow on the quality and geochemistry of water in aquifers in sediments of Cretaceous age in the coastal plain of South Carolina

The quality and geochemistry of ground water are significantly affected by the depositional environment of aquifer sediments. Cretaceous sediments in the Coastal Plain of South Carolina have been deposited in fluvial, delta-plain, marginal-marine, and marine environments. Depositional environments of sediments within a single aquifer may grade from nonmarine, fluvial, or upper delta plain near the updip limit of the aquifer to transitional, lower delta plain and to marine toward the coast. In nonmarine sediments the major source of inorganic carbon in the water is the decomposition of organic material. The major aqueous geochemical processes are the dissolution and alteration of silicate minerals. Silica makes up a major part of the dissolved constituents in water from these sediments. In transitional and marine sediments the major aqueous geochemical processes are (1) the dissolution of calcium carbonate by hydrolysis and by carbonic acid derived from the decomposition of organic material and (2) the exchange of calcium in solution for sodium on the marine-clay minerals. The clay minerals may also serve as buffers by neutralizing the hydroxyl ion produced by hydrolysis. The effects of incompletely flushed dilute saltwater on water quality increase toward the coast and toward the northeast.

South Carolina↗

USGS2011

Episodic soil succession on basaltic lava fields in a cool, dry environment

Holocene- to late Pleistocene-aged lava flows at Craters of the Moon National Monument and Preserve provide an ideal setting to examine the early stages of soil formation under cool, dry conditions. Transects were used to characterize the amount and nature of soil cover on across basaltic lava flows ranging in age from 2.1 to 18.4 ka. Results indicate that on flows <13 ka, very shallow organic soils (Folists in Soil Taxonomy) are the dominant soil type, providing an areal coverage of up to &sim;25%. On flows ≥13.9 ka, deeper mineral soils including Entisols, Aridisols, and Mollisols become dominant and the areal extent increases to ≥95% on flows older than 18.4 ka. These data suggest there are two distinct pedogenic pathways associated with lava flows of the region. The first pathway is illustrated by the younger flows, where Folists dominate. In the absence of a major source of loess, relatively little mineral material accumulates and soils provide only minor coverage of the lava flows. Our results indicate that this pathway of soil development has not changed appreciably over the past &sim;10 ka. The second pedogenic pathway is illustrated by the flows older than 13.9 ka. These flows have been subject to deposition of large quantities of loess during and after the last regional glaciation, resulting in almost complete coverage. Subsequent pedogenesis has given rise to Aridisols and Mollisols with calcic and cambic horizons and mollic epipedons. This research highlights the importance of regional climate change on the evolution of Craters of the Moon soilscapes.

Idaho↗

USGS2001

A metallogenic survey of alkalic rocks of Mt. Somma-Vesuvius volcano

Somma-Vesuvius is an alkaline volcano whose products (pumice, scoria and lava) have alkaline (Na2O+K2O) contents between 6 and 16 wt%, Mg number <50, SiO2 59-47 wt% and MgO 0-7.8 wt% (more than 50% of the samples have a content <2 wt%). Immobile-element ratios (Th/Yb, Ta/Yb, Ce/Yb) indicate a shoshonitic character, while the K2O content (4-10 wt%) is characteristic of ultrapotassic rocks. The behavior of selected metals is discussed by grouping them on the basis of the stratigraphic sequence and differentiating the volcanic activity between plinian and interplinian (Rolandi et al., 1998; Ayuso et al., 1998). This allows observation of the variation within each formation from 25.000y. BP to the last historic eruptive cycle (1631-1944 AD). The main processes to explain the wide distribution of the data presented are fractional crystallization of a mantle-derived magma, magma mixing, and contamination with heterogeneous lower and/or upper crust. Variation diagrams distinguish different behavior for groups of metals: Ag (0.01-0.2 ppm), Mo (1-8.8 ppm), W (1.3-13 ppm), Pb (16-250 ppm), Sb (0.2-2.6 ppm), Sc (0.2-61 ppm), Li (15-140 ppm) and Be (1-31 ppm) increase with increasing differentiation and tend to correlate with the incompatible trace elements (Th, Hf, etc). Cu (10-380 ppm), Au (2-143 ppb), Co (0.7-35.1 ppm) and Fe (1.3-6.2 wt%) decrease towards advanced stage of differentiation. Iron also identifies three magmatic groups. The ratio Fe3+/Fe2+ ranges between 0.2 and 1.8, and Fe2O3/ (Fe2O3+FeO) ranges between 0.2 and 0.8, giving rise to an oxidized environment; exceptions are in the samples belonging to the interplinian formations: I, II, medieval and 1631-1994 AD. Fluorine ranges between 0.1 and 0.4 wt% for the complete Mt. Somma-Vesuvius activity, except for the Ottaviano and Avellino plinian (0.8 wt%) events. Chlorine has a wider range, from 0.1 wt% to 1.6 wt%. Mt Somma-Vesuvius has some features similar to those of mineralized alkaline magmatic systems which coincide with the transition between subduction-related compression and extension-related to continental rifting. We infer that a prospective time for the formation of mineralization at Mt Somma-Vesuvius was during the 1631-1944 eruptive period.

Mineralogy and Petrology↗

USGS2016

New perspectives on a 140-year legacy of mining and abandoned mine cleanup in the San Juan Mountains, Colorado

The Gold King mine water release that occurred on 5 August 2015 near the historical mining community of Silverton, Colorado, highlights the environmental legacy that abandoned mines have on the environment. During reclamation efforts, a breach of collapsed workings at the Gold King mine sent 3 million gallons of acidic and metal-rich mine water into the upper Animas River, a tributary to the Colorado River basin. The Gold King mine is located in the scenic, western San Juan Mountains, a region renowned for its volcano-tectonic and gold-silver-base metal mineralization history. Prior to mining, acidic drainage from hydrothermally altered areas was a major source of metals and acidity to streams, and it continues to be so. In addition to abandoned hard rock metal mines, uranium mine waste poses a long-term storage and immobilization challenge in this area. Uranium resources are mined in the Colorado Plateau, which borders the San Juan Mountains on the west. Uranium processing and repository sites along the Animas River near Durango, Colorado, are a prime example of how the legacy of mining must be managed for the health and well-being of future generations. The San Juan Mountains are part of a geoenvironmental nexus where geology, mining, agriculture, recreation, and community issues converge. This trip will explore the geology, mining, and mine cleanup history in which a community-driven, watershed-based stakeholder process is an integral part. Research tools and historical data useful for understanding complex watersheds impacted by natural sources of metals and acidity overprinted by mining will also be discussed.

Colorado↗

USGS1998

Geologic studies in Alaska by the U.S. Geological Survey, 1996

This collection of 12 papers continues the annual series of U.S. Geological Survey (USGS) reports on geologic investigations in Alaska. The annual volume presents results from new or ongoing studies in Alaska that are of interest to scientists in academia, industry, land and resource managers, and the general public. The Geological Studies in Alaska volume reports the results of studies that cover a broad spectrum of earth science topics from many parts of the state (fig. 1). The papers in this volume are organized under the topics Environment and Climate, Resources, and Geologic Framework, in order to reflect the objectives and scope of USGS programs that are currently active in Alaska. Environmental studies are the focus of two articles in this volume: One study addresses the relation between glaciers and aquatic habitat on the Kenai River and another study evaluates the geochemistry of water draining chromite deposits in Alaska. Two papers address mineral resources in southwestern Alaska including a geochemical study of the Fortyseven Creek prospect and a geological and geochemical study of the Stuyahok area. Eight geologic framework studies apply a variety of techniques to a wide range of subjects throughout Alaska, including biostratigraphy, geochemistry, geochronology, paleomagnetism, sedimentology, and tectonics. Two bibliographies at the end of the volume list reports about Alaska in USGS publications released in 1996 and reports about Alaska by USGS authors in non-USGS publications in 1996.

Alaska↗

USGS1981

Geologic controls of uranium mineralization in the Tallahassee Creek uranium district, Fremont County, Colorado.

Two important orebodies have been defined by drilling in the Tallahassee Creek uranium district, Fremont County, Colorado, namely the Hansen and the Picnic Tree. Host rocks are respectively the upper Eocene Echo park Alluvium, and the lower Oligocene Tallahassee Creek Conglomerate. Average ore grade is about 0.08% U3O8. The principal source rock is the lower Oligocene Wall Mountain Tuff. Leaching and transportation of the uranium occurred in alkaline oxidizing ground water that developed during alteration of the ash in a semi-arid environment. The uranium was transported in the groundwater and deposited in a reducing environment controlled by carbonaceous material and associated pyrite. Localization of the ore was controlled by groundwater flow conditions and by the distribution of organic matter in the host rock. -from Author

Mountain Geologist↗

USGS2009

Changing sources of strontium to soils and ecosystems across the Hawaiian Islands

Strontium isotope ratios assist ecosystem scientists in constraining the sources of alkaline earth elements, but their interpretation can be difficult because of complexities in mineral weathering and in the geographical and environmental controls on elemental additions and losses. Hawaii is a "natural laboratory" where a number of important biogeochemical variables have either limited ranges or vary in systematic ways, providing a unique opportunity to understand the impact of time, climate, and atmospheric inputs on the evolution of base cation sources to ecosystems. There are three major sources of strontium (Sr) to these ecosystems, each with distinct isotopic compositions: basalt lava, Asian dust, and rainfall. We present Sr isotope and concentration data on both bulk soil digests and NH 4 Ac extracts from soil profiles covering a wide range of environments and substrate ages. Bulk soil material from dry climates and/or young substrate ages with > 80????g g - 1 Sr retain basalt-like Sr isotopic signatures, whereas those with Sr concentrations < 80????g g - 1 can have isotope signatures that range from basalt-like values to the more radiogenic values associated with continental dust. Although both dust accumulation and lava weathering are time- and rainfall-dependent, the overall concentration of Sr drops with increasing leaching even as quartz and mica derived from continental dust sources increase to > 40% by mass. At elevated dust levels, lava-derived Sr is low and dust-derived Sr is the dominant control of 87 Sr/ 86 Sr in bulk soils; however, 87 Sr/ 86 Sr of NH 4 Ac-extractable Sr largely reflects atmospheric deposition of marine aerosol in these situations. Overall, whole-soil Sr isotope values are controlled by complex interactions between Sr provided by lava weathering but partially lost by leaching, and Sr provided by dust but held in more resistant minerals. The isotopic composition of NH 4 Ac-extractable Sr and of the biota is controlled by lava weathering and rainfall contribution of Sr with only minor contributions from radiogenic dust sources. ?? 2009 Elsevier B.V.

Chemical Geology↗

USGS2010

Limited hydrologic response to Pleistocene climate change in deep vadose zones - Yucca Mountain, Nevada

Understanding the movement of water through thick vadose zones, especially on time scales encompassing long-term climate change, is increasingly important as societies utilize semi-arid environments for both water resources and sites viewed as favorable for long-term disposal or storage of hazardous waste. Hydrologic responses to Pleistocene climate change within a deep vadose zone in the eastern Mojave Desert at Yucca Mountain, Nevada, were evaluated by uranium-series dating of finely layered hyalitic opal using secondary ion mass spectrometry. Opal is present within cm-thick secondary hydrogenic mineral crusts coating floors of lithophysal cavities in fractured volcanic rocks at depths of 200 to 300 m below land surface. Uranium concentrations in opal fluctuate systematically between 5 and 550 μg/g. Age-calibrated profiles of uranium concentration correlate with regional climate records over the last 300,000 years and produce time-series spectral peaks that have distinct periodicities of 100- and 41-ka, consistent with planetary orbital parameters. These results indicate that the chemical compositions of percolating solutions varied in response to near-surface, climate-driven processes. However, slow (micrometers per thousand years), relatively uniform growth rates of secondary opal and calcite deposition spanning several glacial–interglacial climate cycles imply that water fluxes in the deep vadose zone remained low and generally buffered from the large fluctuations in available surface moisture during different climates.

Nevada↗

USGS1999

Utility of EXAFS in characterization and speciation of mercury-bearing mine wastes

Extensive mining of large mercury deposits located in the California Coast Range has resulted in mercury contamination of both the local environment and water supplies. The solubility, dispersal, and ultimate fate of mercury are all affected by its chemical speciation, which can be most readily determined in a direct fashion using EXAFS spectroscopy. EXAFS spectra of mine wastes collected from several mercury mines in the California Coast Range with mercury concentrations ranging from 230 to 1060 mg/kg (ppm) have been analyzed using a spectral database of mercury minerals and sorbed mercury complexes. While some calcines have been found to consist almost exclusively of mercuric sulfide, HgS, others contain additional, more soluble mercury phases, indicating a greater potential for the release of mercury into solution. This experimental approach can provide a quantitative measurement of the mercury compounds present and may serve as an indicator of the bioavailability and toxicity levels of mercury mine wastes.

Journal of Synchrotron Radiation↗

USGS1981

Geology and concepts of genesis of important types of uranium deposits

Uranium ore deposits occur in nearly every major rock type in the earth’s crust, and nearly all igneous, metamorphic, and sedimentary processes are capable of concentrating or dispersing uranium. However, only three types of deposits account for more than 70 percent of known Western World Reasonably Assured Resources (WWRAR): Precambrian quartz-pebble conglomerate type, Proterozoic unconformity type, and Phanerozoic sandstone type. Igneous-related processes in plutonic, volcanic, and magmatic-hydrothermal environments, considered important 25 years ago, now account for less than 10 percent of world resources known at present. The oldest known ore deposits were formed in conglomerates by placer processes under unique anoxic conditions. For the last 2.2 b.y., since oxygenation of the atmosphere, the genesis of both high- and low-temperature deposits has been dominated by three general geochemical processes: (1) oxidation of uranium to soluble U(VI) species permitting aqueous transport, perhaps most commonly as uranyl-carbonate complexes; (2) reduction, principally by C, S −2 , or Fe +2 species, to U(IV) to allow precipitation of uraninite (pitchblende), and coffinite, although the specific reductant commonly cannot be determined because these three tend to be associated geologically; and (3) igneous and metamorphic differentiation caused by exclusion of uranium from crystal structure of most rock-forming minerals. The geochemistry of uranium ore-forming processes has changed in time because of the evolution of life forms and their impact on the earth’s oxygen and carbon budgets. This evolution is reflected in changing predominance of ore types in geologic time: (1) pre-2.8 b.y. ago—no known uranium ore deposits; (2) ca. 2.8 to 2.2 b.y. ago—the first intràcratonic basins and anoxic atmosphere permitted accumulation of placer deposits of uraninite in quartz-pebble conglomerates; these deposits contain about 19 percent of the western world’s resources; (3) ca. 2.2 to 0.4 b.y. ago—following oxygenation of the atmosphere uranium was oxidized and transported as soluble U(VI) complexes to sites of reduction, commonly in organic carbon-rich marginal marine environments. Diagenesis, metamorphism, and near-surface redox enrichment subsequently formed unconformity-type, ultrametamorphic-type, and vein-type ore deposits which together contain more than 25 percent of the western world’s resources; (4) ca. 0.4 b.y. ago to present—after development of land plants the most important ore-forming process was redox-controlled deposition from ground water in continental sediments. Sandstone-type deposits, characteristic of this stage, contain about 40 percent of the western world’s resources.

Book chapter↗

USGS1981

Factors affecting the partitioning of Cu, Zn and Pb in boulder coatings and stream sediments in the vicinity of a polymetallic sulfide deposit

A sequential extraction scheme is utilized to determine the geochemical partitioning of Cu, Zn and Pb among hydrous Mn- and Fe-oxides, organics and residual crystalline silicates and oxides in the minus-80-mesh (< 0.18 mm) sediments and in boulder coatings from a stream in Lincoln County, Georgia (U.S.A.). The stream drains an area containing a CuZnPb-sulfide deposit (Magruder Mine). The boulder coatings contain mainly Mn-oxides and organics, with minor hydrous Fe-oxides. In the sediment, the chemically active phases are mainly hydrous Fe-oxides and organics, probably because Mn is leaching out of the sediments and precipitating on the exposed surfaces of boulders. In the boulder coatings, competition among Fe- and Mn-oxides and organics for Cu, Zn and Pb follows the order: Cu, organics > Fe-oxides > Mn-oxides; Zn, Mn-oxides {reversed tilde equals} organics > Fe-oxides; Pb, Fe-oxides > organics > Mn-oxides. In the sediments, organics are the most efficient scavengers of all three ore metals. These results emphasize the importance of organics as sinks for the ore metals, even in environments with high concentrations of Mn- and Fe-oxides. Of the ore metals, Zn appears to be the most mobile, and is partitioned most strongly into the coatings. However, anomaly contrast for hydromorphic Zn, normalized to the MnFe-oxide or organic content, is similar in sediments and coatings. Cu shows the highest anomaly on the boulder coatings, probably due to precipitation of a secondary Cu mineral. In contrast, detrital Pb in the pan concentrates shows a better anomaly than any hydromorphic Pb component. ?? 1981.

Chemical Geology↗

USGS1985

Geologic setting, petrology, and geochemistry of stratiform sphalerite-galena-barite deposits, Red Dog Creek and Drenchwater Creek areas, northwestern Brooks Range, Alaska

Similar stratiform sphalerite-galena-barite deposits occur in the Red Dog Creek area, De Long Mountains quadrangle, and in the Drenchwater Creek area, Howard Pass quadrangle, northwestern Brooks Range, Alaska. The deposits, located approximately 180 km apart, are hosted by Mississippian and Pennsylvanian strata of the Kagvik structural sequence of late Paleozoic and early Mesozoic age. This sequence is situated in the lowermost structural plate of a series of predominantly east-striking, shallow-dipping thrust plates that characterize the regional structure. The deposits occur in shale, tuff, tuffaceous sandstone, altered chert, and quartz exhalite. These units are in places interlayered with or adjacent to bedded or nodular barite or submarine keratophyre flows. Chert and shale commonly contain abundant highly altered, fine-grained feldspar, pumice lapilli, and mafic volcanic rock fragments.The main types of occurrences at Red Dog Creek are: (1) disseminated and stratiform sulfides thinly bedded in organic-rich Mississippian and Pennsylvanian shale and chert, (2) massive sulfide veins and breccia fillings in silicified Mississippian and Pennsylvanian shale, and (3) stratiform sulfide-bearing lenses subdivided into (3a) quartz-exhalite with up to several percent sulfides and barite, (3b) massive sulfide-quartz lenses with up to several percent barite, and (3c) barite-quartz lenses with up to several percent sulfides.At Drenchwater Creek sulfides and barite occur as: (1) disseminations in shale, chert, tuff, and tuffaceous sandstone; (2) disseminations to aggregates in quartz exhalite; and (3) occurrences in veins crosscutting cleavages in brecciated chert and shale.The stratiform sulfides occur in zones up to several thousand meters long and several tens of meters thick. Preliminary grades at Red Dog Creek are 17.1 percent zinc, 5.0 percent lead, and 2.4 oz silver per ton contained in at least 85 million tons.The range of sulfide sulfur isotope values at Red Dog Creek is -16.6 per mil to +3.6 per mil. Sphalerite averages 0.8 per mil. Pyrite is isotopically lighter than coexisting sphalerite in quartz exhalite and massive sulfide lenses. This isotopic relationship is compatible with paragenetic relationships which show pyrite crystallized both earlier and later than other sulfides. Galena is isotopically lighter than coexisting sphalerite. Three groups of geologically and isotopically distinct barites exist including isotopic values appropriate for derivation from late Paleozoic seawater sulfate.Early in the depositional sequence isotopically light pyrite formed from organically reduced seawater sulfate. Sphalerite, galena, late pyrite, and some barite precipitated from two sulfur-bearing solutions that mixed at the mineralization site. Isotopically light barite associated with sulfides precipitated from oxidized H 2 S without seawater sulfate contribution. Lead isotope data from Red Dog and Drenchwater Creeks are compatible with generation of lead in a Phanerozoic mature island-arc setting, a typical orogene, or possibly a back-arc type intracratonic basin.The stratiform sphalerite-galena-barite deposits probably formed in an incipient island-arc environment near a continental margin, containing magmas of keratophyric and andesitic composition, where metal-laden hydrothermal fluids discharged into a deep (?) water, low-energy environment. Later intense deformation, associated with plate docking and thrusting, disrupted and partly remobilized and stratiform deposits.

Alaska↗