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At least 541 records · Page 30Linked to original sources

Eolian deposits in the Neoproterozoic Big Bear Group, San Bernardino Mountains, California, USA

Strata interpreted to be eolian are recognized in the Neoproterozoic Big Bear Group in the San Bernardino Mountains of southern California, USA. The strata consist of medium- to large-scale (30 cm to > 6 m) cross-stratified quartzite considered to be eolian dune deposits and interstratified thinly laminated quartzite that are problematically interpreted as either eolian translatent climbing ripple laminae, or as tidal-flat deposits. High index ripples and adhesion structures considered to be eolian are associated with the thinly laminated and cross-stratified strata. The eolian strata are in a succession that is characterized by flaser bedding, aqueous ripple marks, mudcracks, and interstratified small-scale cross-strata that are suggestive of a tidal environment containing local fluvial deposits. The eolian strata may have formed in a near-shore environment inland of a tidal flat. The Neoproterozoic Big Bear Group is unusual in the western United States and may represent a remnant of strata that were originally more widespread and part of the hypothetical Neoproterozoic supercontinent of Rodinia. The Big Bear Group perhaps is preserved only in blocks that were downdropped along Neoproterozoic extensional faults. The eolian deposits of the Big Bear Group may have been deposited during arid conditions that preceded worldwide glacial events in the late Neoproterozoic. Possibly similar pre-glacial arid events are recognized in northern Mexico, northeast Washington, Australia, and northwest Canada.

California

A marine biogeochemical perspective on black shale deposition

Deposition of marine black shales has commonly been interpreted as having involved a high level of marine phytoplankton production that promoted high settling rates of organic matter through the water column and high burial fluxes on the seafloor or anoxic (sulfidic) water-column conditions that led to high levels of preservation of deposited organic matter, or a combination of the two processes. Here we review the hydrography and the budgets of trace metals and phytoplankton nutrients in two modern marine basins that have permanently anoxic bottom waters. This information is then used to hindcast the hydrography and biogeochemical conditions of deposition of a black shale of Late Jurassic age (the Kimmeridge Clay Formation, Yorkshire, England) from its trace metal and organic carbon content. Comparison of the modern and Jurassic sediment compositions reveals that the rate of photic zone primary productivity in the Kimmeridge Sea, based on the accumulation rate of the marine fraction of Ni, was as high as 840 g organic carbon m − 2 yr −1 . This high level was possibly tied to the maximum rise of sea level during the Late Jurassic that flooded this and other continents sufficiently to allow major open-ocean boundary currents to penetrate into epeiric seas. Sites of intense upwelling of nutrient-enriched seawater would have been transferred from the continental margins, their present location, onto the continents. This global flooding event was likely responsible for deposition of organic matter-enriched sediments in other marine basins of this age, several of which today host major petroleum source rocks. Bottom-water redox conditions in the Kimmeridge Sea, deduced from the V:Mo ratio in the marine fraction of the Kimmeridge Clay Formation, varied from oxic to anoxic, but were predominantly suboxic, or denitrifying. A high settling flux of organic matter, a result of the high primary productivity, supported a high rate of bacterial respiration that led to the depletion of O 2 in the bottom water. A high rate of burial of labile organic matter, albeit a low percentage of primary productivity, in turn promoted anoxic conditions in the sediment pore waters that enhanced retention of trace metals deposited from the water column.

Earth-Science Reviews

Thermodynamic model for uplift and deflation episodes (bradyseism) associated with magmatic-hydrothermal activity at the Campi Flegrei (Italy)

Campi Flegrei (CF) is a large volcanic complex located west of the city of Naples, Italy. Repeated episodes of bradyseism (slow vertical ground movement) near the town of Pozzuoli have been documented since Roman times. Bradyseismic events are interpreted as the consequence of aqueous fluid exsolution during magma solidification on a slow timescale (10 3 –10 4 yr) superimposed upon a shorter (1–10 yr) timescale for the episodic expulsion of fluid from a deep (~ 3–5 km) lithostatically-pressured low-permeability reservoir to an overlying hydrostatic reservoir. Cycles of inflation and deflation occur during short duration transient events when connectivity is established between deep and shallow hydrothermal reservoirs. The total seismic energy released (4 × 10 13 J) during the 1983–1984 bradyseismic crisis is consistent with the observed volume change (uplift) and consistent with the notion that seismic failure occurs in response to the shear stress release induced by volume change. Fluid transport and concomitant propagation of hydrofractures as fluid expands from lithostatic to hydrostatic pressure during decompression leads to ground surface displacement. Fluid decompression occurs along the fluid isenthalp (Joule–Thompson expansion) during transient periods of reservoir connectivity and leads to mineral precipitation. Each kilogram of fluid precipitates about 3 × 10 − 3 kg of silica along a typical decompression path along the isenthalp. Mineral precipitation modifies the permeability and acts to reseal connection paths thereby isolating lithostatic and hydrostatic reservoirs ending one bradyseism phase and beginning another. Crystallization and exsolution of the magmatic fluid generates ≈ 7 × 10 15 J of mechanical ( P Δ V ) energy, and this is sufficient to accomplish the observed uplift at CF. Although magma emplacement is the ultimate origin of bradyseism, fresh recharge of magma is not a prerequisite. Instead, short to intermediate timescale phenomena associated with fluid decompression and expansion in the crust with large variations in permeability, including permeability anisotropy, are the key elements at CF.

Naples

Insights on the 2009 South Pacific tsunami in Samoa and Tonga from field surveys and numerical simulations

An M w ≈ 8.1 earthquake south of the Samoan Islands on 29 September 2009 generated a tsunami that killed 189 people. From 4 to 11 October, an International Tsunami Survey Team surveyed the seven major islands of the Samoan archipelago. The team measured locally focused runup heights of 17 m at Poloa and inundation of more than 500 m at Pago Pago. A follow-up expedition from 23 to 28 November surveying the three main islands of Tonga's northernmost Niua group revealed surprising 22 m runup and 1 km inundation. We analyze the extreme tsunami runup and complex impact distribution based on physical and societal observations combined with numerical modeling. That an outer rise/outer trench slope (OR/OTS) event is responsible for a tsunami disaster in the Pacific calls for care in identifying and defining tsunami hazards. Evacuation exercises conducted in Samoa in the preceding year may have limited the human toll; however, cars were identified as potential death traps during tsunami evacuations. This event highlights the extreme hazards from near source tsunamis when the earthquake's shaking constitutes the de facto warning, and further underscores the importance of community based education and awareness programs as essential in saving lives.

Earth-Science Reviews

Flow speed estimated by inverse modeling of sandy sediment deposited by the 29 September 2009 tsunami near Satitoa, east Upolu, Samoa

Sandy deposits from the 29 September 2009 tsunami on the east coast of Upolu, Samoa were investigated to document their characteristics and used to apply an inverse sediment transport model to estimate tsunami flow speed. Sandy deposits 6 to 15 cm thick formed from ~ 25 to ~ 250 m inland. Sedimentary layers in the deposits, that are defined by vertical grain size variation and contacts, are interpreted to have formed during onshore runup of two waves. Deposits at 3 locations (100, 170, and 240 m inland) contained two layers that are predominately normally graded (~ 80%), but contained massive sections (~ 15%) and inversely graded sections (~ 5%) at their bases. About 75% of the total thickness of normally graded intervals exhibits a signature of sediment falling out of suspension at their top. This type of grading, termed suspension grading here, was first recognized in turbidity current deposits and is characterized by the entire distribution shifting finer upwards in a layer as high-settling velocity, coarser material deposits first and low-settling velocity finer material deposits last. The Jaffe and Gelfenbaum (2007) inverse sediment transport model was applied to intervals within layers that exhibited suspension grading to estimate tsunami flow speed and was able to reproduce the general trends of the observed suspension grading. A key unknown input in the modeling is the bottom roughness. For a bottom roughness parameterization using a Manning's n of 0.03 (equivalent to a z 0 ~ 0.006 m for the observed flow depths of 2–3 m) flow speeds calculated for the 2 layers at the 3 locations were 3.8, 3.6, and 3.7 m/s (bottom layer/earlier wave) and 4.4, 4.4, and 4.1 m/s (top layer/later wave) at 100, 170, and 240 m inland, respectively. These estimates are consistent with the ~ 3–8 m/s tsunami flow speed from boulder transport calculations and result in Froude numbers of ~ 0.7–1.0 when maximum measured flow depths are used. Because the inverse model assumes the deposit was formed by sediment falling out of suspension care must be taken to model only intervals of the deposit exhibiting suspension grading. Including intervals deposited by either bedload or suspended load transport convergences result in higher, and sometimes unrealistic, tsunami flow speed estimates.

Satitoa, Upolu

Secular trends in the geologic record and the supercontinent cycle

Geologic secular trends are used to refine the timetable of supercontinent assembly, tenure, and breakup. The analysis rests on what is meant by the term supercontinent, which here is defined broadly as a grouping of formerly dispersed continents. To avoid the artificial pitfall of an all-or-nothing definition, quantitative measures of “supercontinentality” are presented: the number of continents, and the area of the largest continent, which both can be gleaned from global paleogeographic maps for the Phanerozoic. For the secular trends approach to be viable in the deep past when the very existence of supercontinents is debatable and reconstructions are fraught with problems, it must first be calibrated in the Phanerozoic against the well-constrained Pangea supercontinent cycle. The most informative geologic variables covering both the Phanerozoic and Precambrian are the abundances of passive margins and of detrital zircons. Both fluctuated with size of the largest continent during the Pangea supercontinent cycle and can be quantified back to the Neoarchean. The tenure of Pangea was a time represented in the rock record by few zircons and few passive margins. Thus, previously documented minima in the abundance of detrital zircons (and orogenic granites) during the Precambrian (Condie et al., 2009a, Gondwana Research 15, 228–242) now can be more confidently interpreted as marking the tenures of supercontinents. The occurrences of carbonatites, granulites, eclogites, and greenstone-belt deformation events also appear to bear the imprint of Precambrian supercontinent cyclicity. Together, these secular records are consistent with the following scenario. The Neoarchean continental assemblies of Superia and Sclavia broke up at ca. 2300 and ca. 2090 Ma, respectively. Some of their fragments collided to form Nuna by about 1750 Ma; Nuna then grew by lateral accretion of juvenile arcs during the Mesoproterozoic, and was involved in a series of collisions at ca. 1000 Ma to form Rodinia. Rodinia broke up in stages from ca. 1000 to ca. 520 Ma. Before Rodinia had completely come apart, some of its pieces had already been reassembled in a new configuration, Gondwana, which was completed by 530 Ma. Gondwana later collided with Laurentia, Baltica, and Siberia to form Pangea by about 300 Ma. Breakup of Pangea began at about 180 Ma (Early Jurassic) and continues today. In the suggested scenario, no supercontinent cycle in Earth history corresponded to the ideal, in which all the continents were gathered together, then broke apart, then reassembled in a new configuration. Nuna and Gondwana ended their tenures not by breakup but by collision and name change; Rodinia's assembly overlapped in time with its disassembly; and Pangea spalled Tethyan microcontinents throughout much of its tenure. Many other secular trends show a weak or uneven imprint of the supercontinent cycle, no imprint at all. Instead, these secular trends together reveal aspects of the shifting background against which the supercontinents came and went, making each cycle unique. Global heat production declined; plate tectonics sped up through the Proterozoic and slowed down through the Phanerozoic; the atmosphere and oceans became oxidized; life emerged as a major geochemical agent; some rock types went extinct or nearly so (BIF, massif-type anorthosite, komatiite); and other rock types came into existence or became common (blueschists, bioclastic limestone, coal).

Earth-Science Reviews

A unifying model for planform straightness of ripples and dunes in air and water

Geologists, physicists, and mathematicians have studied ripples and dunes for more than a century, but despite considerable effort, no general model has been proposed to explain perhaps the most fundamental property of their morphology: why are some bedforms straight, continuous, parallel, and uniform in planform geometry (i.e. two-dimensional) whereas others are irregular (three-dimensional)? Here we argue that physical coupling along the crest of a bedform is required to produce straight crests and that along-crest flow and sand transport provide effective physical mechanisms for that coupling. Ripples and dunes with the straightest and most continuous crests include longitudinal and oblique dunes in unidirectional flows, wave ripples, dunes in reversing flows, wind ripples, and ripples migrating along a slope. At first glance, these bedforms appear quite different (ripples and dunes; air and water; transverse, oblique, and longitudinal orientations relative to the net sand-transport direction), but they all have one property in common: a process that increases the amount of along-crest sand transport (that lengthens and straightens their crests) relative to the across-crest transport (that makes them migrate and take the more typical and more three-dimensional planform geometry). In unidirectional flows that produce straight bedforms, along-crest transport of sand is caused by along-crest flow (non-transverse bedform orientation), gravitational transport along an inclined crest, or ballistic splash in air. Bedforms in reversing flows tend to be straighter than their unidirectional counterparts, because reverse transport across the bedform crest reduces the net across-crest transport (that causes the more typical irregular geometry) relative to the along-crest transport (that smoothes and straightens planform geometry).

Earth-Science Reviews

Current research issues related to post-wildfire runoff and erosion processes

Research into post-wildfire effects began in the United States more than 70 years ago and only later extended to other parts of the world. Post-wildfire responses are typically transient, episodic, variable in space and time, dependent on thresholds, and involve multiple processes measured by different methods. These characteristics tend to hinder research progress, but the large empirical knowledge base amassed in different regions of the world suggests that it should now be possible to synthesize the data and make a substantial improvement in the understanding of post-wildfire runoff and erosion response. Thus, it is important to identify and prioritize the research issues related to post-wildfire runoff and erosion. Priority research issues are the need to: (1) organize and synthesize similarities and differences in post-wildfire responses between different fire-prone regions of the world in order to determine common patterns and generalities that can explain cause and effect relations; (2) identify and quantify functional relations between metrics of fire effects and soil hydraulic properties that will better represent the dynamic and transient conditions after a wildfire; (3) determine the interaction between burned landscapes and temporally and spatially variable meso-scale precipitation, which is often the primary driver of post-wildfire runoff and erosion responses; (4) determine functional relations between precipitation, basin morphology, runoff connectivity, contributing area, surface roughness, depression storage, and soil characteristics required to predict the timing, magnitudes, and duration of floods and debris flows from ungaged burned basins; and (5) develop standard measurement methods that will ensure the collection of uniform and comparable runoff and erosion data. Resolution of these issues will help to improve conceptual and computer models of post-wildfire runoff and erosion processes.

Earth-Science Reviews

Nature's refineries — Metals and metalloids in arc volcanoes

Chemical data for fumaroles and for atmospheric gas and ash plumes from active arc volcanoes provide glimpses of the rates of release of metal and metalloids, such as Tl and Cd, from shallow and mid-crust magmas. Data from copper deposits formed in ancient volcanoes at depths of up to about 1500 m in the fractures below paleo-fumaroles, and at around 2000–4000 m in association with sub-volcanic intrusions (porphyry copper deposits) provide evidence of sub-surface deposition of Cu–Au–Ag–Mo and a range of other minor elements including Te, Se, As and Sb. These deposits, or ‘sinks’, of metals consistently record sustained histories of magmatic gas streaming through volcanic systems interspersed by continuing intrusive and eruptive activity. Here we integrate data from ancient and modern volcanic systems and show that the fluxes of metals and metalloids are controlled by a) the maintenance of fracture permeability in the stressed crust below volcanoes and b) the chemical processes that are triggered as magmatic gas, initially undersaturated with metals and metalloids, expands from lithostatic to very low pressure conditions through fracture arrays. The recognition of gas streaming may also account for the phenomenon of ‘excess degassing’, and defines an integral, but generally understated, component of active volcanic systems – a volcanic gas core – that is likely to be integral to the progression of eruptions to Plinean state. Destabilization of solvated molecular metal and metalloid species in magmatic gas mixtures and changes in their redox state are triggered, as it expands to the surface by abrupt pressure drops, or throttles' in the fracture array that guides expansion to the surface. The electronically harder, low electronegativity metals, such as copper and iron, deposit rapidly in response to expansion followed more slowly by arsenic with antimony as sulfosalts. Heavy, large radius, softer elements such as bismuth, lead, and thallium along with cadmium are strongly fractionated along the way, eventually venting their excess along with SO 2 , CO 2 , and other components of the carrier gas, into the atmosphere. These elements, many of which are toxic, may also be dispersed by mixing with groundwater in the permeable crust below volcanoes and generate potential health risks due to Hg, As, and Se contamination of drinking water resources.

Earth-Science Reviews

Wildland fire ash: Production, composition and eco-hydro-geomorphic effects

Fire transforms fuels (i.e. biomass, necromass, soil organic matter) into materials with different chemical and physical properties. One of these materials is ash, which is the particulate residue remaining or deposited on the ground that consists of mineral materials and charred organic components. The quantity and characteristics of ash produced during a wildland fire depend mainly on (1) the total burned fuel (i.e. fuel load), (2) fuel type and (3) its combustion completeness. For a given fuel load and type, a higher combustion completeness will reduce the ash organic carbon content, increasing the relative mineral content, and hence reducing total mass of ash produced. The homogeneity and thickness of the ash layer can vary substantially in space and time and reported average thicknesses range from close to 0 to 50 mm. Ash is a highly mobile material that, after its deposition, may be incorporated into the soil profile, redistributed or removed from a burned site within days or weeks by wind and water erosion to surface depressions, footslopes, streams, lakes, reservoirs and, potentially, into marine deposits. Research on the composition, properties and effects of ash on the burned ecosystem has been conducted on material collected in the field after wildland and prescribed fires as well as on material produced in the laboratory. At low combustion completeness (typically T < 450 °C), ash is organic-rich, with organic carbon as the main component. At high combustion completeness (T > 450 °C), most organic carbon is volatized and the remaining mineral ash has elevated pH when in solution. It is composed mainly of calcium, magnesium, sodium, potassium, silicon and phosphorous in the form of inorganic carbonates, whereas at T > 580 °C the most common forms are oxides. Ash produced under lower combustion completeness is usually darker, coarser, and less dense and has a higher saturated hydraulic conductivity than ash with higher combustion completeness, although physical reactions with CO 2 and when moistened produce further changes in ash characteristics. As a new material present after a wildland fire, ash can have profound effects on ecosystems. It affects biogeochemical cycles, including the C cycle, not only within the burned area, but also globally. Ash incorporated into the soil increases temporarily soil pH and nutrient pools and changes physical properties such as albedo, soil texture and hydraulic properties including water repellency. Ash modifies soil hydrologic behavior by creating a two-layer system: the soil and the ash layer, which can function in different ways depending on (1) ash depth and type, (2) soil type and (3) rainfall characteristics. Key parameters are the ash's water holding capacity, hydraulic conductivity and its potential to clog soil pores. Runoff from burned areas carries soluble nutrients contained in ash, which can lead to problems for potable water supplies. Ash deposition also stimulates soil microbial activity and vegetation growth. Further work is needed to (1) standardize methods for investigating ash and its effects on the ecosystem, (2) characterize ash properties for specific ecosystems and wildland fire types, (3) determine the effects of ash on human and ecosystem health, especially when transported by wind or water, (4) investigate ash's controls on water and soil losses at slope and catchment scales, (5) examine its role in the C cycle, and (6) study its redistribution and fate in the environment.

Earth-Science Reviews

Desert wetlands in the geologic record

Desert wetlands support flora and fauna in a variety of hydrologic settings, including seeps, springs, marshes, wet meadows, ponds, and spring pools. Over time, eolian, alluvial, and fluvial sediments become trapped in these settings by a combination of wet ground conditions and dense plant cover. The result is a unique combination of clastic sediments, chemical precipitates, and organic matter that is preserved in the geologic record as ground-water discharge (GWD) deposits. GWD deposits contain information on the timing and magnitude of past changes in water-table levels and, therefore, are a potential source of paleohydrologic and paleoclimatic information. In addition, they can be important archeological and paleontological archives because desert wetlands provide reliable sources of fresh water, and thus act as focal points for human and faunal activities, in some of the world's harshest and driest lands. Here, we review some of the physical, sedimentological, and geochemical characteristics common to GWD deposits, and provide a contextual framework that researchers can use to identify and interpret geologic deposits associated with desert wetlands. We discuss several lines of evidence used to differentiate GWD deposits from lake deposits (they are commonly confused), and examine how various types of microbiota and depositional facies aid in reconstructing past environmental and hydrologic conditions. We also review how late Quaternary GWD deposits are dated, as well as methods used to investigate desert wetlands deeper in geologic time. We end by evaluating the strengths and limitations of hydrologic and climatic records derived from GWD deposits, and suggest several avenues of potential future research to further develop and utilize these unique and complex systems.

Earth-Science Reviews

Analyzing high resolution topography for advancing the understanding of mass and energy transfer through landscapes: A review

The study of mass and energy transfer across landscapes has recently evolved to comprehensive considerations acknowledging the role of biota and humans as geomorphic agents, as well as the importance of small-scale landscape features. A contributing and supporting factor to this evolution is the emergence over the last two decades of technologies able to acquire high resolution topography (HRT) (meter and sub-meter resolution) data. Landscape features can now be captured at an appropriately fine spatial resolution at which surface processes operate; this has revolutionized the way we study Earth-surface processes. The wealth of information contained in HRT also presents considerable challenges. For example, selection of the most appropriate type of HRT data for a given application is not trivial. No definitive approach exists for identifying and filtering erroneous or unwanted data, yet inappropriate filtering can create artifacts or eliminate/distort critical features. Estimates of errors and uncertainty are often poorly defined and typically fail to represent the spatial heterogeneity of the dataset, which may introduce bias or error for many analyses. For ease of use, gridded products are typically preferred rather than the more information-rich point cloud representations. Thus many users take advantage of only a fraction of the available data, which has furthermore been subjected to a series of operations often not known or investigated by the user. Lastly, standard HRT analysis work-flows are yet to be established for many popular HRT operations, which has contributed to the limited use of point cloud data. In this review, we identify key research questions relevant to the Earth-surface processes community within the theme of mass and energy transfer across landscapes and offer guidance on how to identify the most appropriate topographic data type for the analysis of interest. We describe the operations commonly performed from raw data to raster products and we identify key considerations and suggest appropriate work-flows for each, pointing to useful resources and available tools. Future research directions should stimulate further development of tools that take advantage of the wealth of information contained in the HRT data and address the present and upcoming research needs such as the ability to filter out unwanted data, compute spatially variable estimates of uncertainty and perform multi-scale analyses. While we focus primarily on HRT applications for mass and energy transfer, we envision this review to be relevant beyond the Earth-surface processes community for a much broader range of applications involving the analysis of HRT.

Earth-Science Reviews

A review of single-sample-based models and other approaches for radiocarbon dating of dissolved inorganic carbon in groundwater

Numerous methods have been proposed to estimate the pre-nuclear-detonation 14 C content of dissolved inorganic carbon (DIC) recharged to groundwater that has been corrected/adjusted for geochemical processes in the absence of radioactive decay ( 14 C 0 ) - a quantity that is essential for estimation of radiocarbon age of DIC in groundwater. The models/approaches most commonly used are grouped as follows: (1) single-sample-based models, (2) a statistical approach based on the observed (curved) relationship between 14 C and δ 13 C data for the aquifer, and (3) the geochemical mass-balance approach that constructs adjustment models accounting for all the geochemical reactions known to occur along a groundwater flow path. This review discusses first the geochemical processes behind each of the single-sample-based models, followed by discussions of the statistical approach and the geochemical mass-balance approach. Finally, the applications, advantages and limitations of the three groups of models/approaches are discussed. The single-sample-based models constitute the prevailing use of 14 C data in hydrogeology and hydrological studies. This is in part because the models are applied to an individual water sample to estimate the 14 C age, therefore the measurement data are easily available. These models have been shown to provide realistic radiocarbon ages in many studies. However, they usually are limited to simple carbonate aquifers and selection of model may have significant effects on 14 C 0 often resulting in a wide range of estimates of 14 C ages. Of the single-sample-based models, four are recommended for the estimation of 14 C 0 of DIC in groundwater: Pearson's model, (Ingerson and Pearson, 1964; Pearson and White, 1967), Han & Plummer's model (Han and Plummer, 2013), the IAEA model (Gonfiantini, 1972; Salem et al., 1980), and Oeschger's model (Geyh, 2000). These four models include all processes considered in single-sample-based models, and can be used in different ranges of 13 C values. In contrast to the single-sample-based models, the extended Gonfiantini & Zuppi model (Gonfiantini and Zuppi, 2003; Han et al., 2014) is a statistical approach. This approach can be used to estimate 14 C ages when a curved relationship between the 14 C and 13 C values of the DIC data is observed. In addition to estimation of groundwater ages, the relationship between 14 C and δ 13 C data can be used to interpret hydrogeological characteristics of the aquifer, e.g. estimating apparent rates of geochemical reactions and revealing the complexity of the geochemical environment, and identify samples that are not affected by the same set of reactions/processes as the rest of the dataset. The investigated water samples may have a wide range of ages, and for waters with very low values of 14 C, the model based on statistics may give more reliable age estimates than those obtained from single-sample-based models. In the extended Gonfiantini & Zuppi model, a representative system-wide value of the initial 14 C content is derived from the 14 C and δ 13 C data of DIC and can differ from that used in single-sample-based models. Therefore, the extended Gonfiantini & Zuppi model usually avoids the effect of modern water components which might retain ‘bomb’ pulse signatures. The geochemical mass-balance approach constructs an adjustment model that accounts for all the geochemical reactions known to occur along an aquifer flow path (Plummer et al., 1983; Wigley et al., 1978; Plummer et al., 1994; Plummer and Glynn, 2013), and includes, in addition to DIC, dissolved organic carbon (DOC) and methane (CH 4 ). If sufficient chemical, mineralogical and isotopic data are available, the geochemical mass-balance method can yield the most accurate estimates of the adjusted radiocarbon age. The main limitation of this approach is that complete information is necessary on chemical, mineralogical and isotopic data and these data are often limited. Failure to recognize the limitations and underlying assumptions on which the various models and approaches are based can result in a wide range of estimates of 14 C 0 and limit the usefulness of radiocarbon as a dating tool for groundwater. In each of the three generalized approaches (single-sample-based models, statistical approach, and geochemical mass-balance approach), successful application depends on scrutiny of the isotopic ( 14 C and 13 C) and chemical data to conceptualize the reactions and processes that affect the 14 C content of DIC in aquifers. The recently developed graphical analysis method is shown to aid in determining which approach is most appropriate for the isotopic and chemical data from a groundwater system.

Earth-Science Reviews

Is “morphodynamic equilibrium” an oxymoron?

Morphodynamic equilibrium is a widely adopted yet elusive concept in the field of geomorphology of coasts, rivers and estuaries. Based on the Exner equation, an expression of mass conservation of sediment, we distinguish three types of equilibrium defined as static and dynamic, of which two different types exist. Other expressions such as statistical and quasi-equilibrium which do not strictly satisfy the Exner conditions are also acknowledged for their practical use. The choice of a temporal scale is imperative to analyse the type of equilibrium. We discuss the difference between morphodynamic equilibrium in the “real world” (nature) and the “virtual world” (model). Modelling studies rely on simplifications of the real world and lead to understanding of process interactions. A variety of factors affect the use of virtual-world predictions in the real world (e.g., variability in environmental drivers and variability in the setting) so that the concept of morphodynamic equilibrium should be mathematically unequivocal in the virtual world and interpreted over the appropriate spatial and temporal scale in the real world. We draw examples from estuarine settings which are subject to various governing factors which broadly include hydrodynamics, sedimentology and landscape setting. Following the traditional “tide-wave-river” ternary diagram, we summarize studies to date that explore the “virtual world”, discuss the type of equilibrium reached and how it relates to the real world.

Earth-Science Reviews

The added value of time-variable microgravimetry to the understanding of how volcanoes work

During the past few decades, time-variable volcano gravimetry has shown great potential for imaging subsurface processes at active volcanoes (including some processes that might otherwise remain “hidden”), especially when combined with other methods (e.g., ground deformation, seismicity, and gas emissions). By supplying information on changes in the distribution of bulk mass over time, gravimetry can provide information regarding processes such as magma accumulation in void space, gas segregation at shallow depths, and mechanisms driving volcanic uplift and subsidence. Despite its potential, time-variable volcano gravimetry is an underexploited method, not widely adopted by volcano researchers or observatories. The cost of instrumentation and the difficulty in using it under harsh environmental conditions is a significant impediment to the exploitation of gravimetry at many volcanoes. In addition, retrieving useful information from gravity changes in noisy volcanic environments is a major challenge. While these difficulties are not trivial, neither are they insurmountable; indeed, creative efforts in a variety of volcanic settings highlight the value of time-variable gravimetry for understanding hazards as well as revealing fundamental insights into how volcanoes work. Building on previous work, we provide a comprehensive review of time-variable volcano gravimetry, including discussions of instrumentation, modeling and analysis techniques, and case studies that emphasize what can be learned from campaign, continuous, and hybrid gravity observations. We are hopeful that this exploration of time-variable volcano gravimetry will excite more scientists about the potential of the method, spurring further application, development, and innovation.

Earth-Science Reviews

Distinguishing brackish lacustrine from brackish marine deposits in the stratigraphic record: A case study from the late Miocene and early Pliocene Bouse Formation, Arizona and California, USA

Brackish marine and brackish continental environments are fundamentally different from a compositional perspective. Brackish water is often defined as having salinity lower than that of standard seawater but higher than that of freshwater, but less regard is given to the origin of the salts involved. The simple dilution of standard seawater by freshwater in a coastal or estuarine setting constitutes a brackish environment, but so do lakes where continental fresh water is impounded and becomes more saline through a variety of solute evolution pathways. The range of potential compositions of brackish lake water is diverse and includes water with “seawater-like” compositions. Isolated brackish lake environments located hundreds of kilometers inland can evolve towards sodium chloride-dominated, low alkalinityenvironments that mimic the composition of brackish seawater environments. These types of lakes can harbor a variety of continentally invasive but typically marine organisms, including but not limited to algae, foraminifers, mollusks, diatoms, and crustaceans . Distinguishing brackish marine from brackish lake environments in the geologic record can be difficult. In this paper, the enigmatic late Miocene and early Pliocene southern Bouse Formation of southern Arizona and California, USA, considered by many to represent a marine transgression along the lower Colorado River corridor, is discussed within a broad framework that incorporates hydrochemical, biogeographical, and species niche concepts. A brackish lake interpretation provides a powerful platform that can comprehensively account for the enigmatic mixed marine and continental fossil assemblage and possible tidal rhythmites that feature prominently in the southern Bouse Formation controversy. A review of the broader regional (paleo)environmental context for the southern Bouse supports a sodium chloride-dominated, low alkalinity, mildly brackish (10-5 ppt) Colorado River-fed lake depositional environment that was populated by an intriguing but predictable array of euryhaline, opportunistic, and continentally invasive marginal marine organisms.

Arizona, California

Igneous rocks in the Fish Creek Mountains and environs, Battle Mountain area, north-central Nevada: A microcosm of Cenozoic igneous activity in the northern Great Basin, Basin and Range Province, USA

The Great Basin of the western United States, the northern component of the Basin and Range Province, is a region of Cenozoic lithospheric extension with multiple periods and types of igneous activity. The composition and volume of Cenozoic magmas reflect a complex interaction between mantle-derived magmas and highly diverse crust, where both mantle sources and magmatic processes were modulated by tectonic environment. The Fish Creek Mountains in north-central Nevada underwent multiple igneous events ranging from ca. 40 Ma to 1 Ma that span all of the complex Cenozoic tectono-magmatic episodes of the Great Basin. The Fish Creek Mountains, therefore, is an ideal location to evaluate the different sources and processes involved in magma generation. Many plutons were emplaced in the region between about 40 and 38 Ma, several of which host base and precious metal deposits. Between 36 and 33 Ma, lava fields and calderas of the 37–19 Ma Ignimbrite Flare-up were emplaced. Both these and the preceding plutons resulted from southwestward rollback of the Farallon plate beneath North America during by far the most voluminous phase of Cenozoic magmatism. The lavas range from rare basalt and basaltic andesite to andesite, dacite, and rhyolite, have continental arc-like incompatible element patterns, and high initial 87 Sr/ 86 Sr and low εNd that require a metasomatized lithospheric mantle source combined with minor crustal component. Ignimbrites of the 34.4 Ma Cove Mine (trachydacite to rhyolite) and 34.0 Ma Caetano calderas (rhyolite to high-silica rhyolite) are abundantly porphyritic, include hydrous phases, were largely derived from partial melts of crustal rocks, but likely include 20–30% of a mantle-derived component. Igneous activity ceased in the region as the rollback-arc migrated to the southwest, but at 24.9 Ma a new caldera formed in the southern Fish Creek Mountains that was filled by ignimbrites of the Fish Creek Mountains Tuff. Intracaldera rhyolite ignimbrites range from aphyric, pumice-rich deposits at the base to progressively more quartz-feldspar phyric ignimbrites at higher levels; all flow units lack hydrous phases. No contemporaneous mafic or intermediate igneous activity accompanied caldera formation, but initial 87 Sr/ 86 Sr values in the Fish Creek Mountains tuffs are lower than in the Caetano Tuff, suggesting a greater mantle contribution to the 24.9 Ma ignimbrites. After another hiatus in igneous activity, the region was intruded and overlain by basalt to rhyolite dykes and lavas of the northern Nevada rift between 16.8 and 15.1 Ma. The primarily tholeiitic igneous suite is of the same age, chemistry, and isotopic composition as the Grande Ronde Formation of the Columbia River flood basalts, and evolved members (trachydacite and rhyolite) are crustally contaminated. The youngest northern Nevada rift lava is an alkali olivine basalt with isotopic affinity to basalts of the eastern Snake River Plain. After 10 Ma of quiescence, the region was locally covered by mafic lava flows with high-alumina olivine tholeiite compositions, represented by the 5.4 Ma Pumpernickel Valley flows. Their mid-ocean ridge-like incompatible element compositions indicate a depleted mantle source for the lavas, but radiogenic isotopic compositions indicate that the lavas of this region include a significant contribution from a mafic to ultramafic, high- 87 Sr/ 86 Sr source. The final igneous event in the Fish Creek Mountains region, the 4.0 to 1.0 Ma Buffalo Valley volcanic field, includes flows and spatter cones of transitional to alkalic basalt that are divided into two geochemical groups with identical isotopic compositions. They represent variable, low percent partial melts of the asthenosphere at different depths, yielding different rare earth element characteristics. Similar to the Lunar Crater volcanic field, the Buffalo Valley rocks represent a rare case where the lithosphere in the central Great Basin is now thin enough to allow melting of the underlying asthenosphere. Cenozoic magmatism in the northern Great Basin exhibits several transitions in magma sources and tectonic setting with time. Magmatism began as pre-extension, subduction-related, primarily lithospherically-derived magmas emplaced on/in tectonically-thickened crust. The onset of extension was partially driven by impingement of the Yellowstone plume that resulted in emplacement of rift-related volcanic and intrusive rocks in the northern Nevada rift, followed by the eruption of extension-related HAOT lavas along the northwest margin of the Great Basin. Finally, lithospheric thinning allowed for partial melting of the asthenosphere and eruption of alkaline basaltic lavas.

Nevada

Debris-flow monitoring and warning: Review and examples

Debris flows represent one of the most dangerous types of mass movements, because of their high velocities, large impact forces and long runout distances. This review describes the available debris-flow monitoring techniques and proposes recommendations to inform the design of future monitoring and warning/alarm systems. The selection and application of these techniques is highly dependent on site and hazard characterization, which is illustrated through detailed descriptions of nine monitoring sites: five in Europe, three in Asia and one in the USA. Most of these monitored catchments cover less than ∼10 km 2 and are topographically rugged with Melton Indices greater than 0.5. Hourly rainfall intensities between 5 and 15 mm/h are sufficient to trigger debris flows at many of the sites, and observed debris-flow volumes range from a few hundred up to almost one million cubic meters. The sensors found in these monitoring systems can be separated into two classes: a class measuring the initiation mechanisms, and another class measuring the flow dynamics. The first class principally includes rain gauges, but also contains of soil moisture and pore-water pressure sensors. The second class involves a large variety of sensors focusing on flow stage or ground vibrations and commonly includes video cameras to validate and aid in the data interpretation. Given the sporadic nature of debris flows, an essential characteristic of the monitoring systems is the differentiation between a continuous mode that samples at low frequency (“non-event mode”) and another mode that records the measurements at high frequency (“event mode”). The event detection algorithm, used to switch into the “event mode” depends on a threshold that is typically based on rainfall or ground vibration. Identifying the correct definition of these thresholds is a fundamental task not only for monitoring purposes, but also for the implementation of warning and alarm systems.

Earth-Science Reviews