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Water-level declines in the Amargosa Valley area, Nye County, Nevada, 1962-84

Groundwater flow in the Amargosa Valley area is in Nevada complex and involves a valley fill aquifer and an underlying carbonate rock aquifer. Groundwater development in the area is in the valley fill aquifer, about 10 mi. south-west of Lathrop Wells. Water levels measured in selected wells in the area in 1984 are lower than those measured in 1962, demonstrating that water levels have undergone a net decline since 1962. An implied water level rise and resulting groundwater mound suggested on a map from a U.S. Bureau of Reclamation report appear to be based on the inadvertent misplotting of two wells. Data presented in this report indicate that the implied mound does not exist. (Lantz-PTT)

Water-Resources Investigations Report↗

Delineation of spatial extent, depth, thickness, and potential volume of aquifers used for domestic and public water-supply in the Central Valley, California

Identification of the groundwater resources used for drinking-water supplies is essential for the design of strategies to manage those resources. In this study, the spatial extent, depths, thicknesses, and volumes of groundwater aquifers used for domestic and public drinking-water supply were estimated from locations and well-construction data from 11,725 domestic-supply wells and 2,376 public-supply wells in the Central Valley, California. The data were compiled as part of the U.S. Geological Survey National Water Quality Assessment Project and California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The spatial distributions of the depth to top and bottom of well screens were interpolated using Empirical Bayesian Kriging across buffer areas surrounding domestic- and public-supply wells. These surfaces provide a measure of the likely maximum horizontal and vertical extent of the aquifer volume accessed for drinking water in the Central Valley during the past century. Well depth generally increased from north to south, and over time from 1905 to 2010. Well-construction depths were generally more consistent in the Sacramento Valley than in the San Joaquin Valley. The total potential aquifer volume accessed for public supply was calculated to be greater than domestic-supply access, even though the estimated spatial extent of domestic-supply wells was 1.5 times larger than the spatial extent of public-supply wells. Public-supply wells commonly have screen lengths greater than 51 meters, whereas domestic-supply wells typically have shorter screen lengths (overall median of 6 meters). Consequently, the accessed thickness and volume of the aquifer is on average 1.8 and 1.4 times greater for public-supply wells than domestic-supply wells, respectively. Results are presented as maps of areal extent, depth, and thickness of zones in the Central Valley aquifer system used for domestic and public drinking-water supplies.

California↗

Depth to water and water quality in groundwater wells in the Ogallala aquifer within the North Plains Groundwater Conservation District, Texas Panhandle, 2019–20, and comparison to 2012–13 conditions

The Ogallala aquifer is the primary source of water for agricultural and municipal purposes in the Texas Panhandle. Because most of the groundwater in the Texas Panhandle is withdrawn from the Ogallala aquifer, information on the quality of groundwater in the Ogallala aquifer in this part of Texas is useful for resource characterization. During 2012–13, the U.S. Geological Survey in cooperation with the North Plains Groundwater Conservation District (NPGCD), collected and analyzed water-quality samples from 30 groundwater monitoring wells in the Texas Panhandle. The results of the initial 2012–13 synoptic sampling were published in 2014 to help provide an initial characterization of the spatial and temporal variability of water quality in the NPGCD management area. This report documents the results of a followup synoptic sampling completed between March 2019 and July 2020 by the U.S. Geological Survey, in cooperation with the NPGCD, to further characterize the spatial and temporal characteristics of groundwater in the NPGCD management area; measurements of the depth to water, in feet below land surface, and water-quality samples were obtained from the same 30 monitoring wells that were sampled during 2012–13. The water-quality samples were analyzed for major ions, nutrients, trace elements, and selected organic compounds. Results from the 2019–20 synoptic sampling were compared to drinking-water standards and to the results from the 2012–13 synoptic sampling. Between the 2012–13 and 2019–20 sampling periods, the depth to water increased in 28 of the 30 wells, with a median difference of 18.17 feet. Results from major ion analyses indicate that most of the groundwater samples collected during 2019–20 were classified as magnesium-bicarbonate type, the same water type indicated for most samples during 2012–13. Dissolved-solids concentrations for the wells sampled during 2019–20 ranged from 260 to 774 milligrams per liter (mg/L) with a median dissolved-solids concentration of 316 mg/L, which was slightly higher than the median dissolved-solids concentration of 311 mg/L for the 2012–13 sampling period. Of the four nutrients analyzed, nitrate was the dominant nitrogen species, with a median nitrate concentration of 2.25 mg/L for the 2019–20 sampling period, which was a slight increase relative to the median nitrate concentration of 2.05 mg/L for the 2012–13 sampling period. Accounting for variability in analyses, median major ion concentrations and median concentrations for nutrient species were similar during the 2012–13 and 2019–20 sampling periods. None of the trace element concentrations exceeded any maximum contaminant level or secondary drinking-water standards. Median concentrations of trace elements from the 2012–13 sampling period were compared to those from the 2019–20 sampling period for constituents in cases where at least 50 percent of concentrations measured in the samples were detected at concentrations greater than the highest applicable laboratory reporting level, and variability in analyses was accounted for. Comparison results indicated that that median concentrations of two trace elements (lithium and uranium) increased, whereas median concentrations for two of the other trace elements measured (barium and molybdenum) decreased. Atrazine and deethylatrazine were the only organic compounds detected; both were detected in four of the six samples collected from different wells and analyzed for organic compounds. Concentrations of atrazine and deethylatrazine detections were all less than 0.05 micrograms per liter.

Texas↗

Technical Analysis of In-Valley Drainage Management Strategies for the Western San Joaquin Valley, California

The western San Joaquin Valley is one of the most productive farming areas in the United States, but salt-buildup in soils and shallow groundwater aquifers threatens this area?s productivity. Elevated selenium concentrations in soils and groundwater complicate drainage management and salt disposal. In this document, we evaluate constraints on drainage management and implications of various approaches to management considered in: *the San Luis Drainage Feature Re-Evaluation (SLDFRE) Environmental Impact Statement (EIS) (about 5,000 pages of documentation, including supporting technical reports and appendices); *recent conceptual plans put forward by the San Luis Unit (SLU) contractors (i.e., the SLU Plans) (about 6 pages of documentation); *approaches recommended by the San Joaquin Valley Drainage Program (SJVDP) (1990a); and *other U.S. Geological Survey (USGS) models and analysis relevant to the western San Joaquin Valley. The alternatives developed in the SLDFRE EIS and other recently proposed drainage plans (refer to appendix A for details) differ from the strategies proposed by the San Joaquin Valley Drainage Program (1990a). The Bureau of Reclamation (USBR) in March 2007 signed a record of decision for an in-valley disposal option that would retire 194,000 acres of land, build 1,900 acres of evaporation ponds, and develop a treatment system to remove salt and selenium from drainwater. The recently proposed SLU Plans emphasize pumping drainage to the surface, storing approximately 33% in agricultural water re-use areas, treating selenium through biotechnology, enhancing the evaporation of water to concentrate salt, and identifying ultimate storage facilities for the remaining approximately 67% of waste selenium and salt. The treatment sequence of reuse, reverse osmosis, selenium bio-treatment, and enhanced solar evaporation is unprecedented and untested at the scale needed to meet plan requirements. All drainage management strategies that have been proposed seek to reduce the amount of drainage water produced. One approach is to reduce the amount of drainage per irrigated acre. From modeling simulations performed for the SLDFRE EIS of the Westlands Area of the SLU, theoretical minimums that can be achieved range from approximately 0.16 to 0.25 acre-feet per acre per year (AF/acre/year). Minimum production rates from the Northerly Area of the SLU are theorized as being much higher, approximately 0. 42 to 0.28 AF/acre/year. Rates shown in the SLU Plans for drained acres from the two areas combined are 0.5 AF/acre/year at the subsurface drain stage and 0.37 AF/acre/year after a series of on-farm and regional measures are instituted. Land retirement is a key strategy to reduce drainage because it can effectively reduce drainage to zero if all drainage-impaired lands are retired. Land retirement alternatives considered in the SLDFRE EIS differ for the two areas analyzed in the SLU. The Northerly Area is to retire a nominal 10,000 acres and Westlands is to retire up to 300,000 acres. The initial land retirement option recently put forth in the SLU Plans predicted drainage volume reductions that are consistent with 200,000 acres of land retirement, but only 100,000 acres of land retirement was proposed. Within the proposed area of drainage there are, for all practical purposes, unlimited reservoirs of selenium and salt stored within the aquifers and soils of the valley and upslope in the Coast Ranges. Salt imported in irrigation water is estimated to be at least 1.5 million tons per year for the Westlands and Northerly Areas (SJVDIP, 1998). Analysis of the land retirement alternatives presented in the SLDFRE EIS indicates that land retirement of a minimum of only 100,000 acres results in the annual pumping to the surface of 20,142 pounds of selenium or about a million pounds of selenium over a 50 year period. Retiring 200,000 acres results in an annual pumping of 14,750 pounds of selenium; and reti

Open-File Report↗

Use of a Numerical Model to Simulate the Hydrologic System and Transport of Contaminants Near Joint Base Cape Cod, Western Cape Cod, Massachusetts

Historical training and operational activities at Joint Base Cape Cod (JBCC) on western Cape Cod, Massachusetts, have resulted in the release of contaminants into an underlying glacial aquifer that is the sole source of water to the surrounding communities. Remedial systems have been installed to contain and remove contamination from the aquifer. Groundwater withdrawals for public supply are expected to increase as the region continues to urbanize. Increases in water-supply withdrawals and wastewater return flow likely will affect the hydrologic system around JBCC and could affect the transport of any contamination that may remain in the aquifer following remediation of contamination from the JBCC. The U.S. Geological Survey, in cooperation with the Air Force Civil Engineer Center, developed a numerical, steady-state regional model of the Sagamore flow lens on western Cape Cod and evaluated the potential effects of future (2030) groundwater withdrawals on water levels, streamflows, hydraulic gradients, and advective transport near the JBCC. The aquifer consists generally of sandy sediments underlain by impermeable bedrock and is bounded laterally by a freshwater/saltwater interface. Data on the altitude of the bedrock surface, position of the freshwater/saltwater interface, lithology of the aquifer, spatial distribution of recharge, and hydrologic boundaries were incorporated into the three-dimensional, finite-difference groundwater flow model. Some inputs into the numerical model—aquifer properties, leakances, and recharge—are represented as parameters to facilitate estimation of optimal parameter values in an inverse calibration. A hybrid parameterization scheme, with both zones of piecewise constancy and pilot points, is used to represent hydraulic conductivity; other adjustable parameters include recharge, boundary leakance, and porosity. Data on water levels, the distribution of subsurface contamination, and groundwater ages were compiled, evaluated, and used to develop observations of long-term average hydraulic gradients and advective-transport patterns. These observations of steady-state hydrologic conditions were combined with the parameterized groundwater model in an inverse calibration to estimate model parameters that best fit the observations. Current (2010) and future (2030) conditions were simulated in the calibrated model to characterize the groundwater flow system and to determine potential effects of increased groundwater withdrawals on advective-transport patterns at the JBCC. Groundwater flow and advective transport are radially outward from a water-table divide in the northern part of the JBCC; flow diverges from the divide toward all points of the compass. Most groundwater flow and contaminant transport occur in shallow parts of the aquifer. On average, about one-half of the groundwater flux occurs in the shallowest 20 percent of the saturated thickness; shallow flow is even more predominant near streams and lakes. Projected (2030) increases in groundwater withdrawals decrease water levels by a maximum of about 1.2 feet in the northern part of the JBCC; drawdowns exceeding 1 foot generally are limited to areas near the largest increases in withdrawals, such as in the northern part of the JBCC, near Long Pond in Falmouth, and in eastern Barnstable. Streamflow decreases average about 6 percent; the largest decreases are in areas with the largest drawdowns. Changes in hydraulic-gradient directions at the water table exceed 1 degree in about 13 percent of the aquifer, generally near groundwater divides where gradient magnitudes are small and near large groundwater withdrawals. Predictions of advective transport from randomly selected locations at the water table are similar for current (2010) and future (2030) groundwater withdrawals. The results indicate that projected increases in groundwater withdrawals affect water levels and streamflows, but effects on hydraulic gradients and advective transport at the JBCC likely are small. Several underlying assumptions inherent in the model, including observations and weights used in the calibration, representation of local-scale heterogeneity, and simulation of the freshwater/saltwater interface, could affect model calibration and predictions; these assumptions were evaluated with alternative models and alternative inverse calibrations. Eight alternative calibrations were performed in which different, but reasonable, observations and weights were used. The preferred calibrated model had the best overall fit to the observations. Fine-grained silty sediments occur in many parts of the aquifer, and silt lenses can locally affect hydraulic gradients. A set of alternative models in which silts were represented with different correlation distances and hydraulic conductivities indicated that explicitly representing silt lenses could affect model calibration but that the implicit representation of local-scale heterogeneity may be sufficient at the regional scale to represent regional-scale hydraulic gradients. For the coastal boundary, two alternative models representing silty and sandy seabeds and their associated interface positions were developed to test the importance of the assumed coastal-boundary condition. The two alternative models resulted in different predictions of streamflow—streamflows increase with smaller (silty) seabed leakances. However, predictions of advective transport, particularly near the JBCC, generally were similar between the alternative and preferred calibrated models, indicating that the seabed leakance and associated interface position at the coastal boundary does not affect simulations of advective transport in inland parts of the aquifer.

Massachusetts↗

Groundwater quality in relation to drinking water health standards and hydrogeologic and geochemical characteristics for 47 domestic wells in Potter County, Pennsylvania, 2017

As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, water samples from 47 domestic wells in Potter County were collected from May through September 2017. The sampled wells had depths ranging from 33 to 600 feet in sandstone, shale, or siltstone aquifers. Groundwater samples were analyzed for physicochemical properties that could be evaluated in relation to drinking-water health standards, geology, land use, and other environmental factors. Laboratory analyses included concentrations of major ions, nutrients, bacteria, trace elements, volatile organic compounds (VOCs), ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. Results of this 2017 study show that groundwater quality generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded maximum contaminant levels (MCLs) for total coliform bacteria (69.6 percent), Escherichia coli (30.4 percent), arsenic, and barium; and secondary maximum contaminant levels (SMCLs) for field pH, manganese, sodium, iron, total dissolved solids, aluminum, and chloride. All of the analyzed VOCs were below limits of detection and associated drinking water criteria. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter in 80.9 percent of the samples. The field pH of the groundwater ranged from 4.6 to 9.0. Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH values outside this range. Calcium/bicarbonate waters were the predominant hydrochemical type for the sampled aquifers, with mixed water types for many samples, including variable contributions from calcium, magnesium, and sodium combined with bicarbonate, sulfate, chloride, and nitrate. Water from 45 wells had concentrations of methane greater than the 0.0002 milligrams per liter (mg/L) detection limit. One sample had the maximum value of 11 mg/L, which exceeds the Pennsylvania action level of 7 mg/L. Additionally, three other samples had concentrations of methane greater than 4 mg/L. Outgassing of such levels of methane from the water to air within a confined space can result in a potential hazard. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH with relatively elevated concentrations of iron, manganese, ammonia, lithium, fluoride, and boron. Other constituents, including barium, sodium, chloride, and bromide, commonly were elevated, but not limited to, those well-water samples with elevated methane. Low levels of ethane (as much as 1.2 mg/L) were present in eight samples with the highest methane concentrations. Five samples were analyzed for methane isotopes. The isotopic and hydrocarbon compositions in these five samples suggest the methane may be of microbial origin or a mixture of thermogenic and microbial gas, but differed from the compositions reported for mud-gas logging samples collected during drilling of gas wells. The concentrations of sodium (median 8.2 mg/L), chloride (median 7.64 mg/L), and bromide (median 0.02 mg/L) for the 47 groundwater samples collected for this study ranged widely and were positively correlated with one another and with specific conductance and associated measures of ionic strength. Sixty percent of the Potter County well-water samples had chloride concentrations less than 10 mg/L. Samples with higher chloride concentrations had variable bromide concentrations and corresponding chloride/bromide ratios that are consistent with sources such as road-deicing salt and septic effluent (low bromide) or brine (high bromide). Brines are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. It is also possible that valley wells were drilled close to or into the brine-freshwater interface, so brine signatures do not necessarily indicate contamination due to drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. Although 1 of 8 groundwater samples with the highest methane concentrations (greater than 0.2 mg/L) had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with road-deicing salt, the other 7 of 8 samples with elevated methane had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported. Approximately 50 percent of Potter County well-water samples, including two samples with the fourth (72.9 mg/L) and fifth (47.0 mg/L) highest chloride concentrations, have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt or septic effluent.

Pennsylvania↗

A pilot study to assess the influence of infiltrated stormwater on groundwater: Hydrology and trace organic contaminants

Underground infiltration basins (UIBs) mimic the natural hydrologic cycle by allowing stormwater to recharge local groundwater aquifers. However, little is known about the potential transport of organic contaminants to receiving groundwater. We conducted a pilot study in which we collected paired grab samples of stormwater runoff flowing into two UIBs (inflow) and shallow groundwater adjacent to the UIBs. Samples were collected coincident with three rain events and analyzed for volatile organic compounds, semi-volatile organic compounds, pharmaceuticals, and pesticides. Few contaminants were detected in groundwater, compared with inflow, and groundwater concentrations were typically an order of magnitude less. With one exception (trichloroethene), all groundwater concentrations were at least two orders of magnitude below available guidance or screening values. This short communication highlights information gaps in understanding the hydrologic connectivity between UIBs and receiving groundwater and potential consequent contaminant transport to the subsurface from varying climatic conditions.

Minnesota↗

Interaction of cold-water aquifers with exploited reservoirs of the Cerro Prieto geothermal system

Cerro Prieto geothermal reservoirs tend to exhibit good hydraulic communication with adjacent cool groundwater aquifers. Under natural state conditions the hot fluids mix with the surrounding colder waters along the margins of the geothermal system, or discharge to shallow levels by flowing up fault L. In response to exploitation reservoir pressures decrease, leading to changes in the fluid flow pattern in the system and to groundwater influx. The various Cerro Prieto reservoirs have responded differently to production, showing localized near-well or generalized boiling, depending on their access to cool-water recharge. Significant cooling by dilution with groundwater has only been observed in wells located near the edges of the field. In general, entry of cool water at Cerro Prieto is beneficial because it tends to maintain reservoir pressures, restrict boiling, and lengthen the life and productivity of wells.

Conference Paper↗

Sustainability of groundwater supplies in the Northern Atlantic Coastal Plain aquifer system

Groundwater is the Nation’s principal reserve of freshwater. It provides about half our drinking water, is essential to food production, and facilitates business and industry in developing economic well-being. Groundwater is also an important source of water for sustaining the ecosystem health of rivers, wetlands, and estuaries throughout the country. The decreases in groundwater levels and other effects of pumping that result from large-scale development of groundwater resources have led to concerns about the future availability of groundwater to meet all our Nation’s needs. Assessments of groundwater availability provide the science and information needed by the public and decision makers to manage water resources and use them responsibly. The U.S. Geological Survey (USGS) is conducting large-scale multidisciplinary regional studies of groundwater availability as part of its ongoing assessments of the principal aquifers of the Nation. These regional studies are intended to provide citizens, communities, and natural resource managers with knowledge of the status of the Nation’s groundwater resources and how changes in land use, water use, and climate have affected and are likely to affect those resources now and in the future.

Fact Sheet↗

An update of hydrologic conditions and distribution of selected constituents in water, Eastern Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2016–18

Since 1952, wastewater discharged to infiltration ponds (also called percolation ponds) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer and perched groundwater wells in the USGS groundwater monitoring networks during 2016–18. From March–May 2015 to March–May 2018, water levels in wells completed in the ESRP aquifer declined in the northern part of the INL and increased in the southwestern part. Water-level decreases ranged from 0.5 to 3.0 feet (ft) in the northern part of the INL and increases ranged from 0.5 to 3.0 ft in the southwestern part. Detectable concentrations of radiochemical constituents in water samples from wells in the ESRP aquifer at the INL generally decreased or remained constant during 2016–18. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2018, concentrations of tritium in water samples collected from 46 of 111 aquifer wells were greater than the reporting level of three times the sample standard deviation and ranged from 260±50 to 5,100±190 picocuries per liter (pCi/L). Tritium concentrations in water from 10 wells completed in deep perched groundwater above the ESRP aquifer near the Advanced Test Reactor (ATR) Complex generally were greater than or equal to the reporting level during at least one sampling event during 2016–18, and concentrations ranged from 150 ±50 to 12,900 ±200 pCi/L. Concentrations of strontium-90 in water from 17 of 60 ESRP aquifer wells sampled during April or October 2018 exceeded the reporting level, ranging from 2.2±0.7 to 363±19 pCi/L. Strontium-90 was not detected in the ESRP aquifer beneath the ATR Complex. During at least one sampling event during 2016–18, concentrations of strontium-90 in water from eight wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex equaled or exceeded the reporting levels, and concentrations ranged from 0.57±0.17 to 34.3±1.2 pCi/L. During 2016–18, concentrations of cesium-137 were less than the reporting level in all but one ESRP aquifer well, and concentrations of plutonium-238, -239, and -240 (undivided), and americium-241 were less than the reporting level in water samples from all ESRP aquifer wells. In April 2009, the dissolved chromium concentration in water from one ESRP aquifer well, USGS 65, south of the ATR Complex equaled the maximum contaminant level (MCL) of 100 micrograms per liter (μg/L). In April 2018, the concentration of chromium in water from that well had decreased to 76.0 μg/L, less than the MCL. Concentrations in water samples from 62 other ESRP aquifer wells sampled ranged from less than 0.6 to 21.6 μg/L. During 2016–18, dissolved chromium was detected in water from all wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex, and concentrations ranged from 4.2 to 98.8 μg/L. In 2018, concentrations of sodium in water from most ESRP aquifer wells in the southern part of the INL were greater than the western tributary background concentration of 8.3 milligrams per liter (mg/L). After the new percolation ponds were put into service in 2002 southwest of the Idaho Nuclear Technology and Engineering Center (INTEC), concentrations of sodium in water samples from the Rifle Range well increased steadily until 2008, when concentrations generally began decreasing. The increases and decreases were attributed to disposal variability in the new percolation ponds. During 2016–18, dissolved sodium concentrations in water from 18 wells completed in deep perched groundwater above the ESRP aquifer at the ATR Complex ranged from 6.37 to 143 mg/L. In 2018, concentrations of chloride in most water samples from ESRP aquifer wells south of the INTEC and at the Central Facilities Area exceeded the background concentrations. Chloride concentrations in water from wells south of the INTEC generally have decreased since 2002 when chloride disposal to the old percolation ponds was discontinued. After the new percolation ponds southwest of the INTEC were put into service in 2002, concentrations of chloride in water samples from one well rose steadily until 2008 then began decreasing. During 2016–18, dissolved chloride concentrations in deep perched groundwater above the ESRP aquifer from 18 wells at the ATR Complex ranged from 3.89 to 176 mg/L. In 2018, sulfate concentrations in water samples from ESRP aquifer wells in the south-central part of the INL exceeded the background concentration of sulfate and ranged from 22 to 151 mg/L. The greater-than-background concentrations in water from these wells probably resulted from sulfate disposal at the ATR Complex infiltration ponds or the old INTEC percolation ponds. In 2018, sulfate concentrations in water samples from wells near the Radioactive Waste Management Complex (RWMC) mostly were greater than background concentrations and could have resulted from well construction techniques and (or) waste disposal at the RWMC or the ATR complex. The maximum dissolved sulfate concentration in shallow perched groundwater above the ESRP aquifer near the ATR Complex was 215 mg/L in well CWP 3 in April 2016. During 2018, dissolved sulfate concentrations in water from wells completed in deep perched groundwater above the ESRP aquifer near the cold-waste ponds at the ATR Complex ranged from 65.8 to 171 mg/L. In 2018, concentrations of nitrate in water from most ESRP aquifer wells at and near the INTEC exceeded the western tributary background concentration of 0.655 mg/L. Concentrations of nitrate in wells southwest of the INTEC and farther away from the influence of disposal areas and the Big Lost River show a general decrease in nitrate concentration through time. Two wells south of the INTEC show increasing trends that could be the result of wastewater beneath the INTEC tank farm being mobilized to the aquifer. During 2016–18, water samples from several ESRP aquifer wells were collected and analyzed for volatile organic compounds (VOCs). Sixteen VOCs were detected. At least 1 and as many as 7 VOCs were detected in water samples from 15 wells. The primary VOCs detected include carbon tetrachloride, trichloromethane, tetrachloroethene, 1,1,1-trichloroethane, and trichloroethene. In 2016–18, concentrations for all VOCs were less than their respective MCLs for drinking water, except carbon tetrachloride in water from two wells and trichloroethene in one well. During 2016–18, variability and bias were evaluated from 37 replicate and 15 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were major ions, trace elements, nutrients, and VOCs. All radiochemical constituents had acceptable reproducibility except for gross alpha- and beta-particle radioactivity. The gross alpha- and beta-particle radioactivity samples that did not meet reproducibility criteria had low concentrations. Bias from sample contamination was evaluated from equipment, field, and source-solution blanks. Cadmium had a concentration slightly greater than its reporting level in a source-solution blank, and chloride and ammonia had concentrations that were slightly greater than their respective reporting levels in field and equipment blanks. Subtracting concentrations of chloride and ammonia in field blanks from the concurrently collected equipment blank indicates that adjusted concentrations for chloride and ammonia in the equipment blanks were less than their respective reporting levels. Therefore, no sample bias was observed for any of the sample periods.

Idaho↗

Leachate migration from an in situ oil-shale retort near Rock Springs, Wyoming

Geohydrologic factors influencing leachate movement from an in situ oil shale retort near Rock Springs, Wyoming, were investigated by developing models of groundwater flow and solute transport. Leachate, indicated by the conservative ion thiocyanate, has been observed 1/2 mi downgradient from the retort. The contaminated aquifer is part of the Green River Formation and consists of thin, permeable layers of tuff and sandstone interbedded with oil shale. Most solute migration has occurred in an 8-ft sandstone at the top of the aquifer. Groundwater flow in the study area is complexly 3-D and is characterized by large vertical variations in hydraulic head. The solute transport model was used to predict the concentration of thiocyanate at a point where groundwater discharges to the land surface. Leachates with peak concentrations of thiocyanate--45 mg/L or approximately one-half the initial concentration of retort water--were estimated to reach the discharge area during January 1985. Advantages as well as the problems of site specific studies are described. Data such as the distribution of thin permeable beds or fractures may introduce an unmanageable degree of complexity to basin-wide studies but can be incorporated readily in site specific models. Solute migration in the study area primarily occurs in thin permeable beds rather than in oil shale strata. Because of this behavior, leachate traveled far greater distances than might otherwise have been expected. The detail possible in site specific models permits more accurate prediction of solute transport than is possible with basin-wide models. A major problem in site specific studies is identifying model boundaries that permit the accurate estimation of aquifer properties. If the quantity of water flowing through a study area cannot be determined prior to modeling, the hydraulic conductivity and groundwater velocity will be estimated poorly. (Author's abstract)

Wyoming↗

An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2019–21

Since 1952, wastewater discharged to infiltration ponds (also called “percolation ponds”) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy (DOE), maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in both the aquifer and perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer and perched groundwater wells from the USGS groundwater monitoring networks during 2019–21. From March–May 2018 to March–May 2021, water levels in wells completed in the ESRP aquifer increased in the northern part of the INL and decreased in the southwestern part. Water-level increases ranged from 0.02 to 1.04 feet in the northern part and decreases ranged from 0.03 to 2.94 feet in the southwestern part of the INL. Detectable concentrations of radiochemical constituents in water samples from wells in the ESRP aquifer at the INL generally decreased or remained constant during 2019–21. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2021, tritium was detected above reporting levels in water samples collected from 46 of 105 aquifer wells and ranged from 150±50 to 4,280±150 picocuries per liter (pCi/L). Tritium concentrations from eight wells completed in deep perched groundwater near the Advanced Test Reactor Complex (ATRC) generally were greater than or equal to the reporting level during at least one sampling event during 2019–21, and concentrations ranged from 160±50 to 2,097±107 pCi/L. Concentrations of strontium-90 in water from 12 of 45 aquifer wells sampled in 2021 exceeded the reporting level, and concentrations ranged from 2.5±0.7 to 299±6 pCi/L. During 2021, concentrations of strontium-90 from five wells completed in deep perched groundwater at the ATRC equaled or exceeded the reporting levels, and concentrations ranged from 3±0.9 pCi/L to 27.8±1.3 pCi/L. Concentrations of cesium-137 were less than the reporting level in all but one aquifer well, and concentrations of plutonium-238, plutonium-239, -240 (undivided), and americium-241 were less than the reporting level in water samples from all aquifer wells sampled during this study period. Dissolved chromium concentrations in water samples from 64 ESRP aquifer wells ranged from less than (<) 0.5 to 76.4 micrograms per liter (μg/L). During 2019–21, dissolved chromium was detected in water from wells completed in deep perched groundwater above the ESRP aquifer at the ATRC, and concentrations ranged from <1 to 82.1 μg/L. In 2021, concentrations of dissolved sodium in water from most ESRP aquifer wells in the southern part of the INL were greater than the western tributary groundwater background concentration of 8.3 milligrams per liter (mg/L). During 2021, dissolved sodium concentrations in water from 15 wells completed in deep perched groundwater ranged from 11.7 to 122.5 mg/L. Variations in sodium concentrations in aquifer wells and perched groundwater zones are attributed to either migration of remnant water from the former chemical-waste ponds or disposal volume and composition variability in percolation ponds installed in 2008. In 2021, concentrations of chloride in most water samples from ESRP aquifer wells south of the Idaho Nuclear Technology and Engineering Center (INTEC) and at the Central Facilities Area (CFA) exceeded background concentrations. Chloride concentrations in water from wells south of the INTEC have generally decreased because of discontinued chloride disposal to the legacy percolation ponds since 2002 when the discharge of wastewater was discontinued. During 2019–21, dissolved chloride concentrations in deep perched groundwater above the ESRP aquifer from 18 wells at the ATRC ranged from 8.15 to 231 mg/L. In 2021, sulfate concentrations in water samples from ESRP aquifer wells in the south-central part of the INL that exceeded the background concentration of sulfate, ranged from 21 to 141 mg/L. The greater-than-background concentrations in water from these wells are attributed to sulfate disposal at the ATRC infiltration ponds or the legacy INTEC percolation ponds. In 2021, sulfate concentrations in water samples from aquifer wells near the Radioactive Waste Management Complex (RWMC) were mostly greater than background concentrations. The maximum dissolved sulfate concentration in shallow perched groundwater near the ATRC was 575 mg/L in 2021. During 2021, dissolved sulfate concentrations in water from wells completed in deep perched groundwater near the cold waste ponds at the ATRC ranged from 22.3 to 519 mg/L. In 2021, concentrations of nitrate in water from most ESRP aquifer wells at and near the INTEC exceeded the western tributary groundwater background concentration of 0.655 mg/L. Concentrations of nitrate in aquifer wells southwest of INTEC and farther away from the influence of disposal areas and the Big Lost River, in intermittent source of surface water recharge to the aquifer, show a general decrease in nitrate concentration over time. Two aquifer wells south of INTEC show increasing trends that could result from wastewater beneath the INTEC tank farm being mobilized to the aquifer. During 2019–21, water samples from several ESRP aquifer wells were collected and analyzed for volatile organic compounds (VOCs). Twelve VOCs were detected, and 1–4 VOCs were detected in water samples from 10 wells. The most frequently detected VOCs include carbon tetrachloride (tetrachloromethane), trichloromethane, tetrachloroethene, 1,1,1-trichloroethane, and trichloroethene. In 2019–21, concentrations for all VOCs were less than their respective maximum contaminant levels (MCLs) for drinking water, except carbon tetrachloride in one well, trichloroethene in two wells, and vinyl chloride in one well. During 2019–21, variability and bias were evaluated from 34 replicate and 14 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were major ions, trace elements, nutrients, and VOCs. All radiochemical constituents including gross alpha- and beta- radioactivity, strontium-90, cesium-137, and tritium, had acceptable reproducibility. Bias from sample contamination was evaluated from equipment, field, and source-solution blanks. Chloride and sulfate were detected slightly above their respective method detection limits in equipment and field blanks, but at concentrations well below the co-collected sample for that well. These chloride and sulfate detections in the field and equipment blanks were inconsequential because they weren’t detected above the analysis-specific variability for those constituents as determined by replicate sample result evaluation. None of the detections of nutrients and trace inorganic constituents were high enough to indicate environmental sample or analytical procedure bias.

Idaho↗

Flow of river water into a Karstic limestone aquifer. 1. Tracing the young fraction in groundwater mixtures in the Upper Floridan Aquifer near Valdosta, Georgia

The quality of water in the Upper Floridan aquifer near Valdosta, Georgia is affected locally by discharge of Withlacoochee River water through sinkholes in the river bed. Data on transient tracers and other dissolved substances, including Cl − , 3 H, tritiogenic helium-3 ( 3 He), chlorofluorocarbons (CFC-11, CFC-12, CFC-113), organic C (DOC), O 2 (DO), H 2 S, CH 4 , δ 18 O, δD, and 14 C were investigated as tracers of Withlacoochee River water in the Upper Floridan aquifer. The concentrations of all tracers were affected by dilution and mixing. Dissolved Cl − , δ 18 O, δD, CFC-12, and the quantity ( 3 H+ 3 He) are stable in water from the Upper Floridan aquifer, whereas DOC, DO, H 2 S, CH 4 , 14 C, CFC-11, and CFC-113 are affected by microbial degradation and other geochemical processes occurring within the aquifer. Groundwater mixing fractions were determined by using dissolved Cl − and δ 18 O data, recognizing 3 end-member water types in the groundwater mixtures: (1) Withlacoochee River water (δ 18 O=−2.5±0.3‰, Cl − =12.2±2 mg/l), (2) regional infiltration water (δ 18 O=−4.2±0.1‰, Cl − =2.3±0.1 mg/l), and (3) regional paleowater resident in the Upper Floridan aquifer (δ 18 O=−3.4±0.1‰, Cl − =2.6±0.1 mg/l) (uncertainties are ±1σ). Error simulation procedures were used to define uncertainties in mixing fractions. Fractions of river water in groundwater range from 0 to 72% and average 10%. The influence of river-water discharge on the quality of water in the Upper Floridan aquifer was traced from the sinkhole area on the Withlacoochee River 25 km SE in the direction of regional groundwater flow. Infiltration of water is most significant to the N and NW of Valdosta, but becomes negligible to the S and SE in the direction of general thickening of post-Eocene confining beds overlying the Upper Floridan aquifer.

Georgia↗

Nitrogen transport and transformations in a coastal plain watershed: Influence of geomorphology on flow paths and residence times

Nitrogen transport and groundwater‐surface water interactions were examined in a coastal plain watershed in the southeastern United States. Groundwater age dates, calculated using chlorofluorocarbon and tritium concentrations, along with concentrations of nitrogen species and other redox‐active constituents, were used to evaluate the fate and transport of nitrate. Nitrate is stable only in recently recharged (<10 years) water found in the upper few meters of saturated thickness in the upland portion of a surficial aquifer. Groundwater with a residence time between 10 and 30 years typically has low nitrate and elevated excess N 2 concentrations, indications that denitrification has reduced nitrate concentrations. Groundwater older than 30 years also has low nitrate concentrations but contains little or no excess N 2 , suggesting that this water did not contain elevated concentrations of nitrate along its flow path. Nitrate transport to streams varies between first‐ and third‐order streams. Hydrologic, lithologic, and chemical data suggest that the surficial aquifer is the dominant source of flow and nitrate to a first‐order stream. Iron‐reducing conditions occur in groundwater samples from the bed and banks of the first‐order stream, suggesting that direct groundwater discharge is denitrified prior to entering the stream. However, nitrogen from the surficial aquifer is transported directly to the stream via a tile drain that bypasses these reduced zones. In the alluvial valley of a third‐order stream the erosion of a confining layer creates a much thicker unconfined alluvial aquifer with larger zones of nitrate stability. Age dating and chemical information (SiO 2 , Na/K ratios) suggest that water in the alluvial aquifer is derived from short flow paths through the riparian zone and/or from adjacent streams during high‐discharge periods.

Water Resources Research↗

Groundwater contamination downstream of a contaminant penetration site. I. Extension-expansion of the contaminant plume

This study concerns the possible use of boundary layer (BL) approach for the analysis and evaluation of contaminant transport in groundwater due to contaminant penetration into the groundwater aquifer through a site of limited size. The contaminant penetration may occur through either the upper (surface) or lower (bedrock) boundary of the aquifer. Two general cases of contaminant penetration mechanisms are considered: (1) the contaminant is transferred through an interface between a contaminating and freshwater fluid phases, and (2) the contaminant arrives at groundwater by leakage and percolation. For the purpose of BL evaluation the contaminant plume is divided into three different sections: (1) the penetration section, (2) the extension-expansion section, and (3) the spearhead section. In each section a different BL method approach yields simple analytical expressions for the description of the contaminant plume migration and contaminant transport. Previous studies of the BL method can be directly applied to the evaluation of contaminant transport at the contaminant penetration section. The present study extends those studies and concerns the contaminant transport in the two other sections, which are located downstream of the penetration section. This study shows that the contaminant concentration profiles in sections 2 and 3 incorporate two BLs: (1) an inner BL adjacent to the aquifer bottom or surface boundary, and (2) an outer BL, which develops above or below the inner one. The method developed in the present study has been applied to practical issues concerning salinity penetration into groundwater in south central Kansas.

Journal of Environmental Science and Health - Part↗

Differentiating anthropogenic and natural sources of uranium by geochemical fingerprinting of groundwater at the Homestake Uranium Mill, Milan, New Mexico, USA

A multiparameter geochemical-isotopic fingerprinting approach was used to differentiate natural and anthropogenic signatures of uranium contamination near the Homestake uranium mill site (Site), near Milan, New Mexico, USA. The Site consists of two tailings piles from milling operations and groundwater contamination from these tailings have been noted. The Site lies within the lower San Mateo Creek Basin with multiple regional sources of U contamination from mining and mill operations and is underlain by a heterogeneous alluvial aquifer, which is underlain by basement rock of the Chinle Group and the lowermost San Andres-Glorieta aquifer. To help decipher signatures, several statistical approaches were used including PCA, NMDS, and cluster analysis. Trilinear piper diagrams indicate two end member water types at the Site, sulfate-Na-K and sulfate-Ca. Natural alluvial aquifer groundwater in this area, relatively unaffected by mining or milling, appears to be more dominated by bicarbonate than sulfate and the deeper San Andres-Glorieta aquifer that has a mixture of sulfate and bicarbonate. Uranium concentrations from the Site fall into three broad categories, less than the drinking water standard of 30 µg/L (n=3), from 30 to 100 µg/L (n=9) and greater than 100 µg/L (n=8). Component loadings in a principal component analysis are highest for uranium isotopes, 228Ra, gross alpha-beta, molybdenum, chloride, uranium, and sodium, which affect the similarities or differences among wells sampled. Results suggest that several alluvial wells upgradient from the Site have anthropogenic fingerprints from regional sources related to upgradient mining. Wells with higher uranium concentrations have uranium activity ratios close to 1, which is indicative of mining or milling signatures. These same wells have elevated radon activities. This information can be used to inform Site managers on the source of water related to uranium at the Site and provide an approach for geochemical fingerprinting.

New Mexico↗

Hydrogeology and water quality of sand and gravel aquifers in McHenry County, Illinois, 2009–14, and comparison to conditions in 1979

Baseline conditions for the sand and gravel aquifers (groundwater) in McHenry County, Illinois, were assessed using data from a countywide network of 44 monitoring wells collecting continuous water-level data from 2009–14. In 2010, water-quality data were collected from 41 of the monitoring wells, along with five additional monitoring wells available from the U.S. Geological Survey National Water Quality Assessment Program. Periodic water-quality data were collected from 2010–14 from selected monitoring wells. The continuous water-level data were used to identify the natural and anthropogenic factors that influenced the water levels at each well. The water-level responses to natural influences such as precipitation, seasonal and annual variations, barometric pressure, and geology, and to anthropogenic influences such as pumping were used to determine (1) likely hydrogeologic setting (degree of aquifer confinement and interconnections) that, in part, are related to lithostratigraphy; and (2) areas of recharge and discharge related to vertical flow directions. Water-level trends generally were determined from the 6 years of data collection (2009–14) to infer effects of weather variability (drought) on recharge. Precipitation adds an estimated 2.4 inches per year of recharge to the aquifer. Some of this recharge is subsequently discharged to streams and some is discharged to supply wells. A few areas in the eastern half of the county had higher average recharge rates, indicating a need for adequate protection of these recharge areas. Downward vertical flow gradients in upland areas indicate that recharge to the confined aquifer units occurs near upland areas. Upward vertical flow gradients in lowland areas indicate discharge at locations of surface water and groundwater interaction (wetlands, ponds, and streams). Monitoring wells were sampled for major and minor ions, metals, and nutrients and a subset of wells was sampled for trace elements, dissolved gases, pesticides, and volatile organic compounds. The results were compared to health ‑ based and aesthetically based standards, which include the U.S. Environmental Protection Agency Maximum Contaminant Level (EPA MCL), and EPA Secondary Maximum Contaminant Levels (SMCL), as well as EPA Health-based Standards Drinking Water Advisories. Health‑based standards were exceeded for arsenic in 22 percent, sodium in 20 percent, and nitrates in 2 percent of the monitoring wells sampled. Aesthetically based standards were exceeded for total dissolved solids in 33 percent, chloride in 11 percent, iron in 85 percent, and manganese in 30 percent of the wells sampled. Many of these same constituents, such as arsenic, iron, and manganese, are naturally occurring but become elevated in areas that have anoxic, mixed, and suboxic conditions. Some areas of potential vulnerability to anthropogenic-sourced constituents in the sand and gravel aquifers were evidenced by trace amounts of volatile organic compounds and pesticides detected in water-quality samples from shallow wells (total depth less of than 46 feet below land surface) near urban settings, and by the detection of elevated major ions (chloride, sodium, magnesium, and calcium) associated, in part, with road-salt applications. Source analysis for chloride indicates mixtures of road salt, water softeners, and sewage. Continuously measured specific conductance values were used as a surrogate for continuously measured chloride concentrations in the groundwater. The estimated chloride concentrations generally were highest in spring and lowest in summer, and occasionally peak during spring melt. Overall, the range of concentrations varied depending on the local thickness and hydraulic conductivity of the aquifer. Water levels and water quality from the countywide groundwater monitoring network were compared to water levels and water-quality results in 1979 from a previous U.S. Geological Survey study. Potentiometric surface maps show areas with inferred decreases of water levels near the southern and southeastern areas of McHenry County. Significant increases were noted for total dissolved solids and specific conductance. Chloride concentrations increased as much as 521 percent in three of six wells resampled in 2015 from the previous study.

Illinois↗

An update of hydrologic conditions and distribution of selected constituents in water, Snake River Plain aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2006-08

Since 1952, radiochemical and chemical wastewater discharged to infiltration ponds (also called percolation ponds), evaporation ponds, and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, maintains groundwater monitoring networks at the INL to determine hydrologic trends, and to delineate the movement of radiochemical and chemical wastes in the aquifer and in perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from aquifer and perched groundwater wells in the USGS groundwater monitoring networks during 2006-08. Water in the Snake River Plain aquifer primarily moves through fractures and interflow zones in basalt, generally flows southwestward, and eventually discharges at springs along the Snake River. The aquifer primarily is recharged from infiltration of irrigation water, infiltration of streamflow, groundwater inflow from adjoining mountain drainage basins, and infiltration of precipitation. From March-May 2005 to March-May 2008, water levels in wells generally remained constant or rose slightly in the southwestern corner of the INL. Water levels declined in the central and northern parts of the INL. The declines ranged from about 1 to 3 feet in the central part of the INL, to as much as 9 feet in the northern part of the INL. Water levels in perched groundwater wells around the Advanced Test Reactor Complex (ATRC) also declined. Detectable concentrations of radiochemical constituents in water samples from wells in the Snake River Plain aquifer at the INL generally decreased or remained constant during 2006-08. Decreases in concentrations were attributed to decreased rates of radioactive-waste disposal, radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In April or October 2008, reportable concentrations of tritium in groundwater ranged from 810 ? 70 to 8,570 ? 190 picocuries per liter (pCi/L), and the tritium plume extended south-southwestward in the general direction of groundwater flow. Tritium concentrations in water from wells completed in shallow perched groundwater at the ATRC were less than the reporting levels. Tritium concentrations in deep perched groundwater exceeded the reporting level in 11 wells during at least one sampling event during 2006-08 at the ATRC. Tritium concentrations from one or more zones in each well were reportable in water samples collected at various depths in six wells equipped with multi-level WestbayTM packer sampling systems. Concentrations of strontium-90 in water from 24 of 52 aquifer wells sampled during April or October 2008 exceeded the reporting level. Concentrations ranged from 2.2 ? 0.7 to 32.7 ? 1.2 pCi/L. Strontium-90 has not been detected within the eastern Snake River Plain aquifer beneath the ATRC partly because of the exclusive use of waste-disposal ponds and lined evaporation ponds rather than using the disposal well for radioactive-wastewater disposal at ATRC. At the ATRC, the strontium-90 concentration in water from one well completed in shallow perched groundwater was less than the reporting level. During at least one sampling event during 2006-08, concentrations of strontium-90 in water from nine wells completed in deep perched groundwater at the ATRC were greater than reporting levels. Concentrations ranged from 2.1?0.7 to 70.5?1.8 pCi/L. At the Idaho Nuclear Technology and Engineering Center (INTEC), the reporting level was exceeded in water from two wells completed in deep perched groundwater. During 2006-08, concentrations of cesium-137, plutonium-238, and plutonium-239, -240 (undivided), and americium-241 were less than the reporting level in water samples from all wells and all zones in wells equipped with multi-level WestbayTM packer sampling systems

Scientific Investigations Report↗