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At least 505 records · Page 28Linked to original sources

Monitoring storm tide and flooding from Hurricane Isaac along the Gulf Coast of the United States, August 2012

The U.S. Geological Survey (USGS) deployed a temporary monitoring network of water-level and barometric pressure sensors at 127 locations along the gulf coast from Alabama to Louisiana to record the timing, areal extent, and magnitude of hurricane storm tide and coastal flooding generated by Hurricane Isaac. This deployment was undertaken as part of a coordinated federal emergency response as outlined by the Stafford Act under a directed mission assignment by the Federal Emergency Management Agency. Storm tide, as defined by National Oceanic and Atmospheric Administration (NOAA; National Oceanic and Atmospheric Administration, 2008), is the water-level rise generated by a combination of storm surge and astronomical tide during a coastal storm. Hurricane Isaac initially made landfall on the coast of Louisiana in Plaquemines Parish on August 28, 2012, as a Category 1 hurricane on the Saffir–Simpson Hurricane Wind Scale (National Weather Service, 1974) and then stalled over southern Louisiana for several days, causing prolonged storm-tide impacts. A total of 188 water-level and wave-height sensors were deployed at 127 locations during August 27–28 prior to landfall. More than 90 percent of the sensors and all high-water marks (HWMs) were recovered and surveyed to North American Vertical Datum of 1988 (NAVD 88) within 7 days of the Isaac landfall. Only a handful of sensors in the Plaquemines Parish area of Louisiana could not be retrieved until weeks later due to prolonged flooding in the area. Data collected from this event can be used to evaluate the performance of storm-tide models for maximum and incremental water level and flood extent and the site-specific effects of storm tide on natural and anthropogenic features of the environment.

Alabama, Louisiana, Mississippi

Spatial and temporal variability of contaminants within estuarine sediments and native Olympia oysters: A contrast between a developed and an undeveloped estuary

Chemical contaminants can be introduced into estuarine and marine ecosystems from a variety of sources including wastewater, agriculture and forestry practices, point and non-point discharges, runoff from industrial, municipal, and urban lands, accidental spills, and atmospheric deposition. The diversity of potential sources contributes to the likelihood of contaminated marine waters and sediments and increases the probability of uptake by marine organisms. Despite widespread recognition of direct and indirect pathways for contaminant deposition and organismal exposure in coastal systems, spatial and temporal variability in contaminant composition, deposition, and uptake patterns are still poorly known. We investigated these patterns for a suite of persistent legacy contaminants including polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) and chemicals of emerging concern including pharmaceuticals within two Oregon coastal estuaries (Coos and Netarts Bays). In the more urbanized Coos Bay, native Olympia oyster ( Ostrea lurida ) tissue had approximately twice the number of PCB congeners at over seven times the total concentration, yet fewer PBDEs at one-tenth the concentration as compared to the more rural Netarts Bay. Different pharmaceutical suites were detected during each sampling season. Variability in contaminant types and concentrations across seasons and between species and media (organisms versus sediment) indicates the limitation of using indicator species and/or sampling annually to determine contaminant loads at a site or for specific species. The results indicate the prevalence of legacy contaminants and CECs in relatively undeveloped coastal environments highlighting the need to improve policy and management actions to reduce contaminant releases into estuarine and marine waters and to deal with legacy compounds that remain long after prohibition of use. Our results point to the need for better understanding of the ecological and human health risks of exposure to the diverse cocktail of pollutants and harmful compounds that will continue to leach from estuarine sediments over time.

Oregon

The contribution of particles washed from rooftops to contaminant loading to urban streams

Rooftops are both a source of and a pathway for contaminated runoff in urban environments. To investigate the importance of particle-associated contamination in rooftop runoff, particles washed from asphalt shingle and galvanized metal roofs at sites 12 and 102 m from a major expressway were analyzed for major and trace elements and PAHs. Concentrations and yields from rooftops were compared among locations and roofing material types and to loads monitored during runoff events in the receiving urban stream to evaluate rooftop sources and their potential contribution to stream loading. Concentrations of zinc, lead, pyrene, and chrysene on a mass per mass basis in a majority of rooftop samples exceeded established sediment quality guidelines for probable toxicity of bed sediments to benthic biota. Fallout near the expressway was greater than farther away, as indicated by larger yields of all contaminants investigated, although some concentrations were lower. Metal roofing was a source of cadmium and zinc and asphalt shingles a source of lead. The contribution of rooftop washoff to watershed loading was estimated to range from 6 percent for chromium and arsenic to 55 percent for zinc. Estimated contributions from roofing material to total watershed load were greatest for zinc and lead, contributing about 20 and 18 percent, respectively. The contribution from atmospheric deposition of particles onto rooftops to total watershed loads in stormwater was estimated to be greatest for mercury, contributing about 46 percent.

Chemosphere

Flow and sorption controls of groundwater arsenic in individual boreholes from bedrock aquifers in central Maine, USA

To understand the hydrogeochemical processes regulating well water arsenic (As) evolution in fractured bedrock aquifers, three domestic wells with [As] up to 478 μg/L are investigated in central Maine. Geophysical logging reveals that fractures near the borehole bottom contribute 70-100% of flow. Borehole and fracture water samples from various depths show significant proportions of As (up to 69%) and Fe (93-99%) in particulates (>0.45 μm). These particulates and those settled after a 16-day batch experiment contain 560-13,000 g/kg of As and 14-35% weight/weight of Fe. As/Fe ratios (2.5-20 mmol/mol) and As partitioning ratios (adsorbed/dissolved [As], 20,000-100,000 L/kg) suggest that As is sorbed onto amorphous hydrous ferric oxides. Newly drilled cores also show enrichment of As (up to 1300 mg/kg) sorbed onto secondary iron minerals on the fracture surfaces. Pumping at high flow rates induces large decreases in particulate As and Fe, a moderate increase in dissolved [As] and As(III)/As ratio, while little change in major ion chemistry. The δD and δ 18 O are similar for the borehole and fracture waters, suggesting a same source of recharge from atmospheric precipitation. Results support a conceptual model invoking flow and sorption controls on groundwater [As] in fractured bedrock aquifers whereby oxygen infiltration promotes the oxidation of As-bearing sulfides at shallower depths in the oxic portion of the flow path releasing As and Fe; followed by Fe oxidation to form Fe oxyhydroxide particulates, which are transported in fractures and sorb As along the flow path until intercepted by boreholes. In the anoxic portions of the flow path, reductive dissolution of As-sorbed iron particulates could re-mobilize As. For exposure assessment, we recommend sampling of groundwater without filtration to obtain total As concentration in groundwater.

Maine

Soils and paleosols

Soils are naturally occurring bodies that form in the interface between the geosphere, biosphere, hydrosphere , and atmosphere. They are the medium for much of the Earth's plant and animal growth. Soil morphology and how it evolves are functions of the soil-forming factors of climate, organisms, relief, parent material, and time. The expression of soil morphology takes the form of layers, called horizons, that differ in their color, particle size distribution, structure, chemistry, and organic matter content from the parent material. A fundamental soil mapping unit in the USA is the soil order and 12 soil orders have been defined on the basis of soil morphology, physical and chemical properties, and climate. Soil geography in the USA is explained by an examination of how these 12 soil orders are found in particular climates, under specific vegetation communities, how they develop from compositionally distinct parent materials, or how they are a result of the age of soil parent material. Paleosols are ancient soils, those that formed in the past. Three types of paleosols are recognized, buried soils (those covered by a younger sediment or rock), exhumed paleosols (formerly buried soils that are now exposed at the surface due to erosion of overlying materials), and relict paleosols (soils that occur at the land surface, but which formed in an environment, such as a climate or biome, very different from that at the present time). Paleosols can help define geologic contacts and can aid in elucidating past climates or vegetation regimes. Although there are rich geologic records of paleosols in the Quaternary, there is an increasing recognition of the importance of all these features in the longer, pre-Quaternary geologic record.

Book chapter

Introduction to recommended capabilities and instrumentation for volcano monitoring in the United States

Introduction The National Volcano Early Warning System (NVEWS) was authorized and partially funded by the U.S. Government in 2019. In response, the U.S. Geological Survey (USGS) Volcano Hazards Program asked its scientists to reflect on and summarize their views of best practices for volcano monitoring. The goal was to review and update the recommendations of a previous report (Moran and others, 2008) and to provide a more detailed analysis of capabilities and instrumentation for monitoring networks for U.S. volcanoes. This Scientific Investigations Report and its chapters reflect those USGS scientists’ views and summaries and will serve as a guide for future network upgrades funded through NVEWS. Given the well-documented hazards posed by volcanoes to population centers and aviation (for example, Blong, 1984; Scott, 1989; Neal and others, 1997, 2019; Guffanti and others, 2010; Shroder and Papale, 2014; Prata and Rose, 2015; Palmer, 2020), volcano monitoring is critical for ensuring public safety and for mitigating the impacts of volcanic activity. Accurate and timely forecasts are facilitated by well-designed monitoring networks that are in place long enough to allow for background behavior to be recognized and understood. Because precursory signals may be limited and unrest may progress rapidly to an eruption, our goal is to deploy monitoring systems that enable detection of the reactivation of dormant volcanoes as early as possible, allowing for public safety and risk mitigation. NVEWS planning is also informed by the results of Ewert and others (2005, 2018), whereby 161 U.S. volcanoes are currently categorized and ranked commensurate with their relative threat. In each chapter, author(s) considered the need for some redundancy of instrumentation and telemetry, given the likelihood of occasional equipment failure, particularly in extreme and remote environments. Establishing digital telemetry networks requires advanced planning, sighting, radio-shot testing, and, inevitably, troubleshooting in the field. This is harder to achieve rapidly during a crisis; thus, an important goal for monitoring U.S. volcanoes is to establish digital telemetry backbones with redundancy and extra capacity to absorb additional instruments should a volcano begin to exhibit signs of unrest (fig. A1). The National Telecommunications and Information Administration (NTIA) imposed new regulations in the United States, eliminating the use of older analog radios for many purposes, which had been one previous means for redundant data delivery. However, the resulting conversion from analog to digital systems usefully enables stations to accommodate new and multivariate real-time data streams (for example, Global Navigation Satellite System [GNSS] receivers, infrasound arrays, gas spectrometers, visible and infrared cameras, and broadband seismometers). We note that other USGS and broader national and international hazard programs can leverage NVEWS instrumentation plans. Examples of this include the following: Improved seismic coverage of volcanoes will increase the capability of the USGS Earthquake Hazards Program to detect and locate earthquakes, estimate ground shaking, and provide timely early warnings through the ShakeAlert Earthquake Early Warning System (Given and others, 2018). The National Oceanic and Atmospheric Administration’s Tsunami Program will benefit from additional seismic stations, particularly within the sparsely instrumented Aleutian Islands, Northern Mariana Islands, and American Samoa. Infrasound stations can detect signals from landslides, debris flows and lahars, floods, and weather events, providing benefits to the National Weather Service and the USGS Landslide Hazards Program.

Scientific Investigations Report

Comparison of mercury in water, bottom sediment, and zooplankton in two Front Range reservoirs in Colorado, 2008-09

The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, conducted a study to investigate environmental factors that may contribute to the bioaccumulation of mercury in two Front Range reservoirs. One of the reservoirs, Brush Hollow Reservoir, currently (2009) has a fish-consumption advisory for mercury in walleye (Stizostedion vitreum), and the other, Pueblo Reservoir, which is nearby, does not. Water, bottom sediment, and zooplankton samples were collected during 2008 and 2009, and a sediment-incubation experiment was conducted in 2009. Total mercury concentrations were low in midlake water samples and were not substantially different between the two reservoirs. The only water samples with detectable methylmercury were collected in shallow areas of Brush Hollow Reservoir during spring. Mercury concentrations in reservoir bottom sediments were similar to those reported for stream sediments from unmined basins across the United States. Despite higher concentrations of fish-tissue mercury in Brush Hollow Reservoir, concentrations of methylmercury in sediment were as much as 3 times higher in Pueblo Reservoir. Mercury concentrations in zooplankton were at the low end of concentrations reported for temperate lakes in the Northeastern United States and were similar between sites, which may reflect the seasonal timing of sampling. Factors affecting bioaccumulation of mercury were assessed, including mercury sources, water quality, and reservoir characteristics. Atmospheric deposition was determined to be the dominant source of mercury; however, due to the proximity of the reservoirs, atmospheric inputs likely are similar in both study areas. Water-quality constituents commonly associated with elevated concentrations of mercury in fish (pH, alkalinity, sulfate, nutrients, and dissolved organic carbon) did not appear to explain differences in fish-tissue mercury concentrations between the reservoirs. Low methylmercury concentrations in hypolimnetic water indicate low potential for increased methylmercury production following the development of anoxic conditions in summer. Based on the limited dataset, water-level fluctuations and shoreline characteristics appear to best explain differences in fish-tissue mercury concentrations between the reservoirs. Due to the shallow depth and the large annual water-level fluctuations at Brush Hollow Reservoir, proportionally larger areas of shoreline at Brush Hollow Reservoir are subjected to annual reflooding compared to Pueblo Reservoir. Moreover, presence of macrophyte beds and regrowth of terrestrial vegetation likely increase the organic content of near-shore sediments in Brush Hollow Reservoir, which may stimulate methylmercury production in littoral areas subject to reflooding. Results of a laboratory incubation experiment were consistent with this hypothesis.

Colorado

eMODIS: A User-Friendly Data Source

The U.S. Geological Survey's (USGS) Earth Resources Observation and Science (EROS) Center is generating a suite of products called 'eMODIS' based on Moderate Resolution Imaging Spectroradiometer (MODIS) data acquired by the National Aeronautics and Space Administration's (NASA) Earth Observing System (EOS). With a more frequent repeat cycle than Landsat and higher spatial resolutions than the Advanced Very High Resolution Spectroradiometer (AVHRR), MODIS is well suited for vegetation studies. For operational monitoring, however, the benefits of MODIS are counteracted by usability issues with the standard map projection, file format, composite interval, high-latitude 'bow-tie' effects, and production latency. eMODIS responds to a community-specific need for alternatively packaged MODIS data, addressing each of these factors for real-time monitoring and historical trend analysis. eMODIS processes calibrated radiance data (level-1B) acquired by the MODIS sensors on the EOS Terra and Aqua satellites by combining MODIS Land Science Collection 5 Atmospherically Corrected Surface Reflectance production code and USGS EROS MODIS Direct Broadcast System (DBS) software to create surface reflectance and Normalized Difference Vegetation Index (NDVI) products. eMODIS is produced over the continental United States and over Alaska extending into Canada to cover the Yukon River Basin. The 250-meter (m), 500-m, and 1,000-m products are delivered in Geostationary Earth Orbit Tagged Image File Format (Geo- TIFF) and composited in 7-day intervals. eMODIS composites are projected to non-Sinusoidal mapping grids that best suit the geography in their areas of application (see eMODIS Product Description below). For eMODIS products generated over the continental United States (eMODIS CONUS), the Terra (from 2000) and Aqua (from 2002) records are available and continue through present time. eMODIS CONUS also is generated in an expedited process that delivers a 7-day rolling composite, created daily with the most recent 7 days of acquisition, to users monitoring real-time vegetation conditions. eMODIS Alaska is not part of expedited processing, but does cover the Terra mission life (2000-present). A simple file transfer protocol (FTP) distribution site currently is enabled on the Internet for direct download of eMODIS products (ftp://emodisftp.cr.usgs.gov/eMODIS), with plans to expand into an interactive portal environment.

Open-File Report

Vanadium

Vanadium is used primarily in the production of steel alloys; as a catalyst for the chemical industry; in the making of ceramics, glasses, and pigments; and in vanadium redox-flow batteries (VRBs) for large-scale storage of electricity. World vanadium resources in 2012 were estimated to be 63 million metric tons, which include about 14 million metric tons of reserves. The majority of the vanadium produced in 2012 was from China, Russia, and South Africa. Vanadium is extracted from several different types of mineral deposits and from fossil fuels. These deposits include vanadiferous titanomagnetite (VTM) deposits, sandstone-hosted vanadium (with or without uranium) deposits (SSV deposits), and vanadium-rich black shales. VTM deposits are the principal source of vanadium and consist of magmatic accumulations of ilmenite and magnetite containing 0.2 to 1 weight percent vanadium pentoxide (V 2 O 5 ). SSV deposits are another important source; these deposits have average ore grades that range from 0.1 to greater than 1 weight percent V 2 O 5 . The United States has been and is currently the main producer of vanadium from SSV deposits, particularly those on the Colorado Plateau. Vanadium-rich black shales occur in marine successions that were deposited in epeiric (inland) seas and on continental margins. Concentrations in these shales regularly exceed 0.18 weight percent V 2 O 5 and can be as high as 1.7 weight percent V 2 O 5 . Small amounts of vanadium have been produced from the Alum Shale in Sweden and from ferrophosphorus slag generated during the reduction of phosphate to elemental phosphorus in ore from shales of the Phosphoria Formation in Idaho and Wyoming. Because vanadium enrichment occurs in beds that are typically only a few meters thick, most of the vanadiferous black shales are not currently economic, although they may become an important resource in the future. Significant amounts of vanadium are recovered as byproducts of petroleum refining, and processing of coal, tar sands, and oil shales may be important future sources. Vanadium occurs in one of four oxidation states in nature: +2, +3, +4, and +5. The V 3+ ion has an octahedral radius that is almost identical to that of (Fe 3+ ) and (Al 3+ ) and, therefore, it substitutes in ferromagnesian minerals. During weathering, much of the vanadium may partition into newly formed clay minerals, and it either remains in the +3 valence state or oxidizes to the +4 valence state, both of which are relatively insoluble. If erosion is insignificant but chemical leaching is intense, the residual material may be enriched in vanadium, as are some bauxites and laterites. During the weathering of igneous, residual, or sedimentary rocks, some vanadium oxidizes to the +5 valence state, especially in the intensive oxidizing conditions that are characteristic of arid climates. The average contents of vanadium in the environment are as follows: soils [10 to 500 parts per million (ppm)]; streams and rivers [0.2 to 2.9 parts per billion (ppb)]; and coastal seawater (0.3 to 2.8 ppb). Concentrations of vanadium in soils (548 to 7,160 ppm) collected near vanadium mines in China, the Czech Republic, and South Africa are many times greater than natural concentrations in soils. Additionally, if deposits contain sulfide minerals such as chalcocite, pyrite, and sphalerite, high levels of acidity may be present if sulfide dissolution is not balanced by the presence of acid-neutralizing carbonate minerals. Some of the vanadium-bearing deposit types, particularly some SSV and black-shale deposits, contain appreciable amounts of carbonate minerals, which lowers the acid-generation potential. Vanadium is a micronutrient with a postulated requirement for humans of less than 10 micrograms per day, which can be met through dietary intake. Primary and secondary drinking water regulations for vanadium are not currently in place in the United States. Vanadium toxicity is thought to result from an intake of more than 10 to 20 milligrams per day. Vanadium is essential for some biological processes and organisms. For example, some nitrogen-fixing bacteria require vanadium for producing enzymes necessary to convert nitrogen from the atmosphere into ammonia, which is a more biologically accessible form of nitrogen.

Professional Paper

CO 2 and CH 4 emissions from streams in a lake-rich landscape: Patterns, controls, and regional significance

Aquatic ecosystems are important components of landscape carbon budgets. In lake-rich landscapes, both lakes and streams may be important sources of carbon gases (CO 2 and CH 4 ) to the atmosphere, but the processes that control gas concentrations and emissions in these interconnected landscapes have not been adequately addressed. We use multiple data sets that vary in their spatial and temporal extent during 2001–2012 to investigate the carbon gas source strength of streams in a lake-rich landscape and to determine the contribution of lakes, metabolism, and groundwater to stream CO 2 and CH 4 . We show that streams emit roughly the same mass of CO 2 (23.4 Gg C yr −1 ; 0.49 mol CO 2 m −2 d −1 ) as lakes at a regional scale (27 Gg C yr −1 ) and that stream CH 4 emissions (189 Mg C yr −1 ; 8.46 mmol CH 4 m −2 d −1 ) are an important component of the regional greenhouse gas balance. Gas transfer velocity variability (range = 0.34 to 13.5 m d −1 ) contributed to the variability of gas flux in this landscape. Groundwater inputs and in-stream metabolism control stream gas supersaturation at the landscape scale, while carbon cycling in lakes and deep groundwaters does not control downstream gas emissions. Our results indicate the need to consider connectivity of all aquatic ecosystems (lakes, streams, wetlands, and groundwater) in lake-rich landscapes and their connections with the terrestrial environment in order to understand the full nature of the carbon cycle.

Global Biogeochemical Cycles

Monitoring storm tide and flooding from Hurricane Matthew along the Atlantic coast of the United States, October 2016

Introduction Hurricane Matthew moved adjacent to the coasts of Florida, Georgia, South Carolina, and North Carolina. The hurricane made landfall once near McClellanville, South Carolina, on October 8, 2016, as a Category 1 hurricane on the Saffir-Simpson Hurricane Wind Scale. The U.S. Geological Survey (USGS) deployed a temporary monitoring network of storm-tide sensors at 284 sites along the Atlantic coast from Florida to North Carolina to record the timing, areal extent, and magnitude of hurricane storm tide and coastal flooding generated by Hurricane Matthew. Storm tide, as defined by the National Oceanic and Atmospheric Administration, is the water-level rise generated by a combination of storm surge and astronomical tide during a coastal storm. The deployment for Hurricane Matthew was the largest deployment of storm-tide sensors in USGS history and was completed as part of a coordinated Federal emergency response as outlined by the Stafford Act (Public Law 92–288, 42 U.S.C. 5121–5207) under a directed mission assignment by the Federal Emergency Management Agency. In total, 543 high-water marks (HWMs) also were collected after Hurricane Matthew, and this was the second largest HWM recovery effort in USGS history after Hurricane Sandy in 2012. During the hurricane, real-time water-level data collected at temporary rapid deployment gages (RDGs) and long-term USGS streamgage stations were relayed immediately for display on the USGS Flood Event Viewer ( https://stn.wim.usgs.gov/FEV/#MatthewOctober2016 ). These data provided emergency managers and responders with critical information for tracking flood-effected areas and directing assistance to effected communities. Data collected from this hurricane can be used to calibrate and evaluate the performance of storm-tide models for maximum and incremental water level and flood extent, and the site-specific effects of storm tide on natural and anthropogenic features of the environment.

Florida, Georgia, North Carolina, South Carolina

Pharmaceuticals, hormones, pesticides, and other bioactive contaminants in water, sediment, and tissue from Rocky Mountain National Park, 2012–2013

Pharmaceuticals, hormones, pesticides, and other bioactive contaminants (BCs) are commonly detected in surface water and bed sediment in urban and suburban areas, but these contaminants are understudied in remote locations. In Rocky Mountain National Park (RMNP), Colorado, USA, BCs may threaten the reproductive success and survival of native aquatic species, benthic communities, and pelagic food webs. In 2012–2013, 67 water, 57 sediment, 63 fish, 10 frog, and 12 quality-control samples (8 water and 4 sediment) were collected from 20 sites in RMNP. Samples were analyzed for 369 parameters including 149 pharmaceuticals, 22 hormones, 137 pesticides, and 61 other chemicals or conditions to provide a representative assessment of BC occurrence within RMNP. Results indicate that BCs were detected in water and/or sediment from both remote and more accessible locations in RMNP. The most commonly detected BCs in water were caffeine, camphor, para-cresol, and DEET; and the most commonly detected BCs in sediment were indole, 3-methyl-1H-indole, para-cresol, and 2,6-dimethyl-naphthalene. Some detected contaminants, including carbaryl, caffeine, and oxycodone, are clearly attributable to direct local human input, whereas others may be transported into the park atmospherically (e.g., atrazine) or have local natural sources (e.g., para-cresol). One or more pharmaceuticals were detected in at least 1 sample from 15 of 20 sites. Most of the 29 detected pharmaceuticals are excreted primarily in human urine, not feces. Elevated net estrogenicity was observed in 18% of water samples, and elevated vitellogenin in blood was observed in 12% of male trout, both evidence of potential endocrine disruption. Hormone concentrations in sediment tended to be greater than concentrations in water. Most BCs were observed at concentrations below those not expected to pose adverse effects to aquatic life. Results indicate that even in remote locations aquatic wildlife can be exposed to pharmaceuticals, hormones, pesticides, and other bioactive contaminants.

Colorado

Fire and the Miocene expansion of C4 grasslands

C 4 photosynthesis had a mid-Tertiary origin that was tied to declining atmospheric CO 2 , but C 4 -dominated grasslands did not appear until late Tertiary. According to the ‘CO 2 -threshold’ model, these C 4 grasslands owe their origin to a further late Miocene decline in CO 2 that gave C 4 grasses a photosynthetic advantage. This model is most appropriate for explaining replacement of C 3 grasslands by C 4 grasslands, however, fossil evidence shows C 4 grasslands replaced woodlands. An additional weakness in the threshold model is that recent estimates do not support a late Miocene drop in p CO 2 . We hypothesize that late Miocene climate changes created a fire climate capable of replacing woodlands with C 4 grasslands. Critical elements were seasonality that sustained high biomass production part of year, followed by a dry season that greatly reduced fuel moisture, coupled with a monsoon climate that generated abundant lightning-igniting fires. As woodlands became more open from burning, the high light conditions favoured C 4 grasses over C 3 grasses, and in a feedback process, the elevated productivity of C 4 grasses increased highly combustible fuel loads that further increased fire activity. This hypothesis is supported by paleosol data that indicate the late Miocene expansion of C 4 grasslands was the result of grassland expansion into more mesic environments and by charcoal sediment profiles that parallel the late Miocene expansion of C 4 grasslands. Many contemporary C 4 grasslands are fire dependent and are invaded by woodlands upon cessation of burning. Thus, we maintain that the factors driving the late Miocene expansion of C 4 were the same as those responsible for maintenance of C 4 grasslands today.

Ecology Letters

Enhancements to the USGS Landsat Level 2 surface temperature and emissivity product for Collection 3 reprocessing

The Landsat program provides the longest continuous global record of thermal infrared observations of the Earth's surface, underpinning critical applications in climate monitoring, water resources, ecosystem dynamics, urban heat analysis, and natural hazard assessment. The release of a global inventory of Landsat Collection 2 Level 2 surface temperature products by the U.S. Geological Survey (USGS) marked a major milestone in operational provision of Landsat thermal infrared analysis-ready data. Ongoing validations and community uses of Collection 2 have identified opportunities to further improve accuracy, uncertainty characterization, and emissivity correction across diverse atmospheric and surface conditions. In preparation for the planned Landsat Collection 3 reprocessing of the Landsat data record in the late 2020s, the USGS is implementing a coordinated set of enhancements to the Level 2 surface temperature products. These include revised emissivity estimation that leverages external datasets, improved atmospheric characterization and uncertainty propagation, expanded dynamic range for high temperature targets, consideration of split window atmospheric correction algorithm for Landsat 8 and 9, and decoupling of thermal infrared processing from visible to shortwave infrared constraints to enable surface temperature retrievals under low or no solar illumination conditions. These changes are designed to improve product quality and consistency across the Landsat record. Beyond near-term performance gains, the Collection 3 design establishes a scalable processing architecture to accommodate the expanded spectral and radiometric measurement capabilities of the forthcoming Landsat 10 mission. By preserving continuity across the Landsat 4–9 record while enabling future algorithm evolution, Landsat Collection 3 will provide a foundation for long-term, multi-decadal Earth system thermal infrared observations.

Remote Sensing of Environment

The imager for Mars Pathfinder experiment

The imager for Mars Pathfinder (IMP), a stereoscopic, multispectral camera, is described in terms of its capabilities for studying the Martian environment. The camera's two eyes, separated by 15.0 cm, provide the camera with range‐finding ability. Each eye illuminates half of a single CCD detector with a field of view of 14.4×14.0° and has 12 selectable filters. The ƒ/18 optics have a large depth of field, and no focussing mechanism is required; a mechanical shutter is avoided by using the frame transfer capability of the 512×512 CCD. The resolving power of the camera, 0.98 mrad/pixel, is approximately the same as the Viking Lander cameras; however, the signal‐to‐noise ratio for IMP greatly exceeds Viking, approaching 350. This feature along with the stable calibration of the filters between 440 and 1000 nm distinguishes IMP from Viking. Specially designed targets are positioned on the Lander; they provide information on the magnetic properties of wind‐blown dust, measure the wind vectors, and provide radiometric standard reflectors for calibration. Also, eight low‐transmission filters are included for imaging the Sun directly at multiple wavelengths, giving IMP the ability to measure dust opacity and potentially the water vapor content. Several experiments beyond the requisite color panorama are described in detail: contour mapping of the local terrain, multispectral imaging of the surrounding rock and soil to study local mineralogy, viewing of three wind socks, measuring atmospheric opacity and water vapor content, and estimating the magnetic properties of wind‐blown dust. This paper is intended to serve as a guide to understanding the scientific integrity of the IMP data that will be returned from Mars starting on July 4, 1997.

Journal of Geophysical Research E: Planets

Sidescan-sonar imagery, multibeam bathymetry, and surficial geologic interpretations of the sea floor in Rhode Island Sound, off Sakonnet Point, Rhode Island

The U.S. Geological Survey (USGS) is working with the National Oceanic and Atmospheric Administration (NOAA) to interpret the surficial geology in estuaries and sounds along the northeastern coast of the United States. This report interprets the area covered by NOAA Survey H11320, about 72 km² of sea floor in eastern Rhode Island Sound (RIS), located about 8 km south of Sakonnet Point, Rhode Island (fig. 1). Previous work in RIS includes studies of both sea-floor processes and subsurface geologic framework. McMaster (1960) mapped surficial sediment samples in Narragansett Bay and RIS and McMaster and others (1968) conducted a seismic-reflection survey in Block Island Sound and RIS. O'Hara and Oldale (1980) collected seismic-reflection profiles, sidescan-sonar data, and vibracores in eastern RIS (fig. 2). They interpreted the geologic history, assessed sand and gravel resources, and evaluated the mining impact of these resources. McMaster's (1960) interpretation of the surficial sediment within this study area consisted of sand with several isolated areas of gravel. Several other sediment samples were previously obtained within the study area: three National Oceanographic Data Center (NODC) dredge samples from 1942 consisted of sand and one National Ocean Service (NOS) sample from 1939 was rocky (fig. 2; Poppe and others, 2003). The purpose of this report is to define the sea-floor morphology and sedimentary environments and interpret processes occurring on the sea floor using sidescan-sonar imagery, multibeam bathymetry, and historic seismic-reflection profiles.

Rhode Island

Interannual covariability between actual evapotranspiration and PAL and GIMMS NDVIs of northern Asia

This study examined the covariability between interannual changes in the normalized difference vegetation index (NDVI) and actual evapotranspiration (ET). To reduce possible uncertainty in the NDVI time series, two NDVI datasets derived from Pathfinder AVHRR Land (PAL) data and the Global Inventory Monitoring and Modeling Studies (GIMMS) group were used. Analyses were conducted using data over northern Asia from 1982 to 2000. Interannual changes over 19 years in the PAL-NDVI and GIMMS-NDVI were compared with interannual changes in ET estimated from model-assimilated atmospheric data and gridded precipitation data. For both NDVI datasets, the annual maximum correlation with ET occurred in June, which is the beginning of the vegetation growing season. The PAL and GIMMS datasets showed a significant, positive correlation between interannual changes in the NDVI and ET over most of the vegetated land area in June. These results suggest that interannual changes in vegetation activity predominantly control interannual changes in ET in June. Based on analyses of interannual changes in temperature, precipitation, and the NDVI in June, the study area can be roughly divided into two regions, the warmth-dominated northernmost region and the wetness-dominated southern region, indicating that interannual changes in vegetation and the resultant interannual changes in ET are controlled by warmth and wetness in these two regions, respectively.

Remote Sensing of Environment

A simple headspace equilibration method for measuring dissolved methane

Dissolved methane concentrations in the ocean are close to equilibrium with the atmosphere. Because methane is only sparingly soluble in seawater, measuring it without contamination is challenging for samples collected and processed in the presence of air. Several methods for analyzing dissolved methane are described in the literature, yet none has conducted a thorough assessment of the method yield, contamination issues during collection, transport and storage, and the effect of temperature changes and preservative. Previous extraction methods transfer methane from water to gas by either a "sparge and trap" or a "headspace equilibration" technique. The gas is then analyzed for methane by gas chromatography. Here, we revisit the headspace equilibration technique and describe a simple, inexpensive, and reliable method to measure methane in fresh and seawater, regardless of concentration. Within the range of concentrations typically found in surface seawaters (2-1000 nmol L -1 ), the yield of the method nears 100% of what is expected from solubility calculation following the addition of known amount of methane. In addition to being sensitive (detection limit of 0.1 ppmv, or 0.74 nmol L -1 ), this method requires less than 10 min per sample, and does not use highly toxic chemicals. It can be conducted with minimum materials and does not require the use of a gas chromatograph at the collection site. It can therefore be used in various remote working environments and conditions.

Limnology and Oceanography: Methods