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At least 37 records · Page 2Linked to original sources
USGS2010

Trends in base flow, total flow, and base-flow index of selected streams in and near Oklahoma through 2008

The U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, investigated trends in base flow, total flow, and base-flow index of selected streams in Oklahoma and evaluated possible causes for trends. Thirty-seven streamflow-gaging stations that had unregulated or moderately regulated streamflow were selected for trend analysis. Statistical evaluation of trends in annual and seasonal (winter-spring and summer-autumn) base flow, total flow, and base-flow index at 37 selected streamflow-gaging stations in Oklahoma was performed by using a Kendall's tau trend test. This trend analysis also was performed for annual and seasonal precipitation for nine climate divisions in the study area, annual peak flows, the number of days where flow was zero or less than 1 cubic foot per second (both annually and seasonally), and annual winter groundwater levels for 35 shallow wells near the analyzed stations. Precipitation-adjusted trends using LOESS regressions and Kendall's tau were computed for annual and seasonal base-flow and total-flow volumes in order to identify the presence of underlying trends in streamflow that are not associated with annual or seasonal variations in precipitation. In general, upward trends in precipitation were detected for climate divisions in north-central Oklahoma and south-central and southeastern Kansas. More climate divisions had statistically significant upward trends in total precipitation for annual water years than in winter-spring or summer-autumn water years. Significant trends in annual or seasonal base-flow volume were detected for 22 stations, 19 of which had trends that were upward in direction. Significant trends in annual or seasonal total-flow volume were detected for 14 stations, 9 of which had trends that were upward in direction. Most stations that had significant upward trends in annual or seasonal total-flow volume also had significant upward trends in base-flow volume for the same period. Precipitation adjustment changed the results (significant only or significance and direction) of significant annual or seasonal trends in unadjusted base-flow volume for 12 stations and in unadjusted total-flow volume for 13 stations. Significant trends in annual or seasonal base-flow index were detected for 25 stations, 23 of which had trends that were upward in direction. Eighteen stations that had significant upward trends in annual or seasonal base-flow index also had significant upward trends in base-flow volume and no significant downward trends in total-flow volume during the same period, which indicated that upward trends in base-flow index were likely driven by increases in base flow at these stations. Trend results were highly variable throughout the State. However, some recurring patterns in locations of stations with similar trend results were detected. In general, significant downward trends in base-flow and total-flow volumes were detected for the three stations in the Oklahoma Panhandle. Significant upward trends in annual or seasonal base-flow volume before and after precipitation adjustment were detected for 12 stations in southwestern and central Oklahoma. In eastern Oklahoma, significant upward trends in annual or seasonal base-flow volume were only detected for 4 stations, and significant upward trends in annual or seasonal total-flow volume were only detected for 1 station. After precipitation adjustment no stations in this region had significant upward trends in either parameter, one station had significant downward trends in annual base-flow volume, and one station had significant downward trends in winter-spring total-flow volume. Increases in annual and seasonal precipitation, especially during a substantial wet period (1980-2000), may be one of the factors resulting in upward trends in base-flow volume and total-flow volume at many of the stations analyzed in this report. Eleven stations with significant upward trends in precipitation-adjust

Scientific Investigations Report↗
USGS2017

Trends in the quality of water in New Jersey streams, water years 1971–2011

In a study conducted by the U.S. Geological Survey in cooperation with the New Jersey Department of Environmental Protection and the Delaware River Basin Commission, trend tests were conducted on selected water-quality characteristics measured at stations on streams in New Jersey during selected periods over water years 1971‒2011. Tests were conducted on 3 nutrients (total nitrogen, filtered nitrate plus nitrite, and total phosphorus) at 28 water-quality stations. At 4 of these stations, tests were also conducted on 3 measures of major ions (specific conductance, filtered chloride, and total dissolved solids). Two methods were used to identify trends—Weighted Regressions on Time, Discharge, and Season (WRTDS) models and seasonal rank-sum tests. For this report, the use of WRTDS models included the use of the WRTDS Bootstrap Test (WBT). WRTDS models identified trends in flow-normalized annual concentrations and flow-normalized annual fluxes over water years 1980‒2011 and 2000‒11 for each nutrient, filtered chloride, and total dissolved solids. WRTDS models were developed for each nutrient at the 20 or 21 stations at which streamflow was measured or estimated. Trends in nutrient concentration were reported for these stations; trends in nutrient fluxes were reported only for 15–17 of these stations. The results of WRTDS models for water years 1980‒2011 identified more stations with downward trends in concentrations of either total nitrogen or total phosphorus than upward trends. For total nitrogen, there were downward trends at 9 stations and an upward trend at 1 station. For total phosphorus, there were downward trends at 8 stations and an upward trend at 1 station. For filtered nitrate plus nitrite, there were downward trends at 6 stations and upward trends at 6 stations. The result of the trend test in flux for a selected nutrient at a selected station (downward trend, no trend, or upward trend) usually matched the trend result in concentration. Seasonal rank-sum tests, the second method used, identified step trends in water-quality measured in different decades—1970s, 1980s, 1990s, and 2000s. Tests were conducted on all nutrients at 28 stations and on all measures of major ions at the 4 selected stations. Results of seasonal rank-sum tests between the 1980s and the 2000s identified more stations with downward trends in concentrations of total nitrogen (14) than stations with upward trends (2) and more stations with downward trends in concentrations of total phosphorus (18) than stations with upward trends (1). A combined dataset of trend results for concentrations over water years 1980‒2011 was created from the results of the two tests for the period. Results of WRTDS models were included in this combined dataset, if available. Otherwise, the results of the seasonal rank-sum tests between water-quality characteristics measured in the 1980s and 2000s were included. Trend results over water years 1980‒2011 in the combined dataset show that few of the 28 stations had upward trends in concentrations of either total nitrogen or total phosphorus. There were only 2 stations with upward trends in total nitrogen concentration and 1 station with an upward trend in total phosphorus concentration. Results for filtered nitrate plus nitrite show about the same number of stations with upward trends (9) as stations with downward trends (7). Results for all measures of major ions show upward trends at the four stations tested.

New Jersey↗
USGS2024

Peak streamflow trends in Missouri and their relation to changes in climate, water years 1921–2020

This report characterizes changes in peak streamflow in Missouri and the relation of these changes to climatic variability, and provides a foundation for future studies that can address nonstationarity in peak-streamflow frequency analysis in Missouri. Records of annual peak and daily streamflow at streamgages and gridded monthly climatic data (observed and modeled) were examined across four trend periods (100 years, water years 1921–2020; 75 years, 1946–2020; 50 years, 1971–2020; and 30 years, 1991–2020) for trends, change points (abrupt changes in the streamflow time series), and other statistical properties indicative of changing conditions. Peak streamflow magnitudes generally exhibit upward trends across the State for the 100-, 75-, and 50-year trend periods and only in southern Missouri for the 30-year trend period. The medians of the trend magnitudes (normalized by median peak streamflow) range from a 10-percent increase during the 30-year trend period to a 40-percent increase during the 100-year trend period. Changes in the 90-percent quantile of peak streamflow, which correspond to the 10-percent exceedance probability often used for the design of drainage structures, are not as substantial or widespread, showing consistent increases mainly in the southern part of the State in the 50- and 30-year trend periods. Streamgages with trends in peak streamflow often also have change points, or abrupt changes, in streamflow magnitude. Change points in peak streamflows generally follow that of the peak streamflow trends, with upward change points throughout most of the State at the 100- and 75-year trend periods and in southern Missouri at the 30-year trend period. Temporally, clusters upward of change points are observed in the 1970s through 1980s for the 100-, 75-, and 50-year trend periods and around 2006 and 2007 for the 50- and 30-year trend periods. A peaks-over-threshold analysis, which evaluates changes in the frequency of peak streamflows over a certain threshold, indicates that high flows have increased in frequency at 50 to 64 percent of streamgages in the 100- and 75-year trend periods. Most streamgages in the 50- and 30-year trend periods exhibit no change. Although the frequency of high flows has increased at some streamgages and trend periods in Missouri, these increases are not as widespread as the increases in the magnitude of peak streamflow. Upward trends in observed temperature and observed annual precipitation dominate in all trend periods, with no downward trends in precipitation and only two somewhat likely downward trends in temperature for the 100-year trend period. Increases in annual precipitation mostly are limited to southern Missouri for the 30-year trend period. The proportion of precipitation falling as snow has largely decreased in the study basins across the State, which is expected in response to increasing temperature. Upward trends in modeled annual runoff, which in this study incorporates only the effects of climatic variation, are observed in the same geographic areas where there are increases in observed annual precipitation. When peak streamflow and climatic trends are considered together, widespread upward trends in peak streamflows for the 100-, 75-, and 50-year trend periods and for the 30-year trend period mainly in southern Missouri (encompassing both trends and abrupt change) appear to be driven largely by increases in precipitation based on spatial patterns and statistical relations. The prevalence of nonstationarity in peak streamflow in Missouri has important implications for peak-flow frequency analysis. Winter and spring precipitation and the occurrence of extreme precipitation events are expected to increase across the State. If precipitation continues to increase as expected, peak-flow frequency estimates based on older records may no longer represent the hydrologic regime of today, and methods for nonstationary peak-flow frequency analysis may be needed.

Missouri↗
USGS2007

Nutrient and Suspended-Sediment Trends in the Missouri River Basin, 1993-2003

Trends in streamflow and concentration of total nitrogen, nitrite plus nitrate, ammonia, total phosphorus, orthophosphorus, and suspended sediment were determined for the period from 1993 to 2003 at selected stream sites in the Missouri River Basin. Flow-adjusted trends in concentration (the trends that would have occurred in the absence of natural changes in streamflow) and non-flow-adjusted trends in concentration (the overall trends resulting from natural and human factors) were determined. In the analysis of flow-adjusted trends, the removal of streamflow as a variable affecting concentration allowed trends caused by other factors such as implementation of best management practices to be identified. In the analysis of non-flow-adjusted trends, the inclusion of any and all factors affecting concentration allowed trends affecting aquatic ecosystems and the status of streams relative to water-quality standards to be identified. Relations between the flow-adjusted and non-flow-adjusted trends and changes in streamflow, nutrient sources, ground-water inputs, and implementation of management practices also were examined to determine the major factors affecting the trends. From 1993 to 2003, widespread downward trends in streamflow indicated that drought conditions from about 2000 to 2003 led to decreasing streamflow throughout much of the Missouri River Basin. Flow-adjusted trends in nitrite plus nitrate and ammonia concentrations were split nearly equally between nonsignificant and downward; at about one-half of the sites, management practices likely were contributing to measurable decreases in concentrations of nitrite plus nitrate and ammonia. Management practices had less of an effect on concentrations of total nitrogen; downward flow-adjusted trends in total nitrogen concentrations occurred at only 2 of 19 sites. The pattern of non-flow-adjusted trends in nitrite plus nitrate concentrations was similar to the pattern of flow-adjusted trends; non-flow-adjusted trends were split nearly equally between nonsignificant and downward. A substantial source of nitrite plus nitrate to these streams likely was ground water; because of the time required for ground water to travel to streams, there may have been a lag time between the implementation of some pollution-control strategies and improvement in stream quality, contributing to the nonsignificant trends in nitrite plus nitrate. There were more sites with downward non-flow-adjusted trends than flow-adjusted trends in both ammonia and total nitrogen concentrations, possibly a result of decreased surface runoff from nonpoint sources associated with the downward trends in streamflow. No strong relations between any of the nitrogen trends and changes in nutrient sources or landscape characteristics were identified. Although there were very few upward trends in nitrogen from 1993 to 2003, there were upward flow-adjusted trends in total phosphorus concentrations at nearly one-half of the sites. At these sites, not only were pollution-control strategies not contributing to measurable decreases in total phosphorus concentrations, there was likely an increase in phosphorus loading on the land surface. There were fewer upward non-flow-adjusted than flow-adjusted trends in total phosphorus concentrations; at the majority of sites, overall total phosphorus concentrations did not change significantly during this period. The preponderance of upward flow-adjusted trends and nonsignificant non-flow-adjusted trends indicates that in some areas of the Missouri River Basin, overall concentrations of total phosphorus would have been higher without the decrease in streamflow and the associated decrease in surface runoff during the study period. During the study period, phosphorus loads from fertilizer generally increased at over one-half of the sites in the basin. Upward flow-adjusted trends were related to increasing fertilizer use in the upstream drainage area, particularly in the 10 percent

Scientific Investigations Report↗
USGS2012

Nutrient and suspended-sediment trends, loads, and yields and development of an indicator of streamwater quality at nontidal sites in the Chesapeake Bay watershed, 1985-2010

The U.S. Geological Survey (USGS) updates information on loads of, and trends in, nutrients and sediment annually to help the Chesapeake Bay Program (CBP) investigators assess progress toward improving water-quality conditions in the Chesapeake Bay and its watershed. CBP scientists and managers have worked since 1983 to improve water quality in the bay. In 2010, the U.S. Environmental Protection Agency (USEPA) established a Total Maximum Daily Load (TMDL) for the Chesapeake Bay. The TMDL specifies nutrient and sediment load allocations that need to be achieved in the watershed to improve dissolved oxygen, water-clarity, and chlorophyll conditions in the bay. The USEPA, USGS, and state and local jurisdictions in the watershed operate a CBP nontidal water-quality monitoring network and associated database that are used to update load and trend information to help assess progress toward reducing nutrient and sediment inputs to the bay. Data collected from the CBP nontidal network were used to estimate loads and trends for two time periods: a long-term period (1985-2010) at 31 "primary" sites (with storm sampling) and a 10-year period (2001-10) at 33 primary sites and 16 "secondary" sites (without storm sampling). In addition, loads at 64 primary sites were estimated for the period 2006 to 2010. Results indicate improving flow-adjusted trends for nitrogen and phosphorus for 1985 to 2010 at most of the sites in the network. For nitrogen, 21 of the 31 sites showed downward (improving) trends, whereas 2 sites showed upward (degrading) trends, and 8 sites showed no trends. The results for phosphorus were similar: 22 sites showed improving trends, 4 sites showed degrading trends, and 5 sites indicated no trends. For sediment, no trend was found at 40 percent of the sites, with 10 sites showing improving trends and 8 sites showing degrading trends. The USGS, working with CBP partners, developed a new water-quality indicator that combines the results of the 10-year trend analysis with results from a greater number of sites (64 primary sites) where loads and yields of total nitrogen and phosphorus and sediment could be calculated. The new indicator shows fewer significant trends for the 10-year time period than for the long-term time period (1985-2010). For 2001-10, total nitrogen trends were downward (improving) at 14 sites and upward (degrading) at 2 sites; no trend was found at 17 sites. For total phosphorus, 12 sites showed improving trends, 4 sites showed degrading trends, and 17 sites showed no trend. For total sediment, most sites (21) did not exhibit a significant trend; 3 sites showed improving trends, and 10 sites showed degrading trends. Few significant trends were seen at the 16 secondary sites: improving trends for total nitrogen at 4 sites, improving trends for total phosphorus at 2 sites, and a degrading trend for sediment at 1 site. Total streamflow to the Chesapeake Bay was 20 percent higher in 2010 than in 2009 and is considered to be within the normal range of flow, whereas annual streamflow at 28 sites was greater in 2010 than in 2009. No trends in daily streamflow were detected at the 31 long-term sites. Combined loads for the farthest downstream nontidal monitoring sites (called "River Input Monitoring sites") increased 33 percent for total nitrogen, 120 percent for total phosphorus, and 330 percent for total sediment from 2009 to 2010. The large increase in phosphorus and sediment loads in 2010 was caused in large part by two large storm events that occurred during the spring in the Potomac River Basin. Yields (load per watershed area) of total nitrogen in the Chesapeake Bay watershed decreased from north to south (New York to Virginia). No spatial patterns were discernible for total phosphorus or sediment.

Delaware, Maryland, New York, Pennsylvania, Virgin↗
USGS2005

Trends in surface-water quality at selected National Stream Quality Accounting Network (NASQAN) stations, in Michigan

To demonstrate the value of long-term, water-quality monitoring, the Michigan Department of Environmental Quality (MDEQ), in cooperation with the U.S. Geological Survey (USGS), initiated a study to evaluate potential trends in water-quality constituents for selected National Stream Quality Accounting Network (NASQAN) stations in Michigan. The goal of this study is to assist the MDEQ in evaluating the effectiveness of water-pollution control efforts and the identification of water-quality concerns. The study included a total of nine NASQAN stations in Michigan. Approximately 28 constituents were analyzed for trend tests. Station selection was based on data availability, land-use characteristics, and station priority for the MDEQ Water Chemistry Monitoring Project. Trend analyses were completed using the uncensored Seasonal Kendall Test in the computer program Estimate Trend (ESTREND), a software program for the detection of trends in water-quality data. The parameters chosen for the trend test had (1) at least a 5-year period of record (2) about 5 percent of the observations censored at a single reporting limit, and (3) 40 percent of the values within the beginning one-fifth and ending one-fifth of the selected period. In this study, a negative trend indicates a decrease in concentration of a particular constituent, which generally means an improvement in water quality; whereas a positive trend means an increase in concentration and possible degradation of water quality. The results of the study show an overall improvement in water quality at the Clinton River at Mount Clemens, Manistee River at Manistee, and Pigeon River near Caseville. The detected trend for these stations show decreases in concentrations of various constituents such as nitrogen compounds, conductance, sulfate, fecal coliform bacteria, and fecal streptococci bacteria. The negative trend may indicate an overall improvement in agricultural practices, municipal and industrial wastewater-treatment processes, and effective regulations. Phosphorus data for most of the study stations could not be analyzed because of the data limitations for trend tests. The only station with a significant negative trend in total phosphorus concentration is the Clinton River at Mount Clemens. However, scatter-plot analyses of phosphorus data indicate decreasing concentrations with time for most of the study stations. Positive trends in concentration of nitrogen compounds were detected at the Kalamazoo River near Saugatuck and Muskegon River near Bridgeton. Positive trends in both fecal coliform and total fecal coliform were detected at the Tahquamenon River near Paradise. Various different point and nonpoint sources could produce such positive trends, but most commonly the increase in concentrations of nitrogen compounds and fecal coliform bacteria are associated with agricultural practices and sewage-plant discharges. The constituent with the most numerous and geographically widespread significant trend is pH. The pH levels increased at six out of nine stations on all the major rivers in Michigan, with no negative trend at any station. The cause of pH increase is difficult to determine, as it could be related to a combination of anthropogenic activities and natural processes occurring simultaneously in the environment. Trends in concentration of major ions, such as calcium, sodium, magnesium, sulfate, fluoride, chloride, and potassium, were detected at eight out of nine stations. A negative trend was detected only in sulfate and fluoride concentrations; a positive trend was detected only in calcium concentration. The major ions with the most widespread significant trends are sodium and chloride; three positive and two negative trends were detected for sodium, and three negative and two positive trends were detected for chloride. The negative trends in chloride concentrations outnumbered the positive trends. This result indicates a slight improvement in surface-water quality because chloride as a point source in natural water comes from deicing salt, sewage effluents, industrial wastes, and oil fields. For other major ions, such as magnesium and potassium, both positive and negative trends were detected. These changes in trends indicate changes in surface-water quality caused by a variety of point and non-point sources throughout Michigan, as well as natural changes in the environment.

Michigan↗
USGS2014

Pesticide trends in major rivers of the United States, 1992-2010

This report is part of a series of pesticide trend assessments led by the National Water-Quality Assessment Program of the U.S. Geological Survey. This assessment focuses on major rivers of various sizes throughout the United States that have large watersheds with a range of land uses, changes in pesticide use, changes in management practices, and natural influences typical of the regions being drained. Trends were assessed at 59 sites for 40 pesticides and pesticide degradates during each of three overlapping periods: 1992–2001, 1997–2006, and 2001–10. In addition to trends in concentration, trends in agricultural-use intensity (agricultural use) were also assessed at 57 of the sites for 35 parent compounds with agricultural uses during the same three periods. The SEAWAVE-Q model was used to analyze trends in concentration, and parametric survival regression for interval-censored data was used to assess trends in agricultural use. All trends are provided in downloadable electronic files. A subset of 39 sites was chosen to represent non-nested, generally independent basins for a national analysis of pesticide and agricultural-use trends for the most prevalent pesticides (15 pesticides and 2 degradation products). Graphical and numerical results are presented to provide a national overview of concentration and use trends. As another perspective on understanding pesticide concentration trends in large rivers in relation to multiple tributary watersheds, this report also presents a detailed assessment of concentration and use trends for simazine, metolachlor, atrazine, deethylatrazine, and diazinon for a set of 17 nested sites in the Mississippi River Basin (including the Ohio and Missouri River Basins), for the second and third trend periods. Pesticides strongly dominated by agricultural use—cyanazine, metolachlor, atrazine, and alachlor—had widespread agreement between concentration trends and agricultural-use trends. Pesticides with substantial use in agricultural and urban applications—simazine, tebuthiuron, Dacthal, pendimethalin, chlorpyrifos, malathion, diazinon, fipronil, carbofuran, and carbaryl—had concentration trends that were mostly explained by a combination of agricultural-use trends and concentration trends in urban streams that were evaluated in a separate companion study. The importance of the urban stream trends for explaining concentration trends in major rivers indicates the significance of nonagricultural uses of some pesticides to concentrations in major rivers despite the much smaller area of urban land use compared to agriculture. Deethylatrazine, a degradate of atrazine, was the only pesticide compound assessed that had frequent occurrences during 1997–2006 and 2001–10 of concentration trends in the opposite direction of use trends (atrazine use). The nested analysis for the Mississippi River indicates that most trends observed in the largest rivers—multiple Mississippi River sites, the Ohio River, and the Missouri River—are consistent with streamflow contributions and concentration trends observed at tributary sites. Streamflow (incorporated into the trend model and shown in the nested basin analysis), trends in agricultural use of pesticides (quantified in this report), and urban use of pesticides (represented by concentration trends in a companion study of urban streams) are all important influences on pesticide concentrations in streams and rivers. Consideration of these influences is vital to understanding trends in pesticide concentrations.

Scientific Investigations Report↗
USGS2008

Trends In Nutrient and Sediment Concentrations and Loads In Major River Basins of the South-Central United States, 1993-2004

Nutrient and sediment data collected at 115 sites by Federal and State agencies from 1993 to 2004 were analyzed by the U.S. Geological Survey to determine trends in concentrations and loads for selected rivers and streams that drain into the northwestern Gulf of Mexico from the south-central United States, specifically from the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf Basins. Trends observed in the study area were compared to determine potential regional patterns and to determine cause-effect relations with trends in hydrologic and human-induced factors such as nutrient sources, streamflow, and implementation of best management practices. Secondary objectives included calculation of loads and yields for the study period as a basis for comparing the delivery of nutrients and sediment to the northwestern Gulf of Mexico from the various rivers within the study area. In addition, loads were assessed at seven selected sites for the period 1980-2004 to give hydrologic perspective to trends in loads observed during 1993-2004. Most study sites (about 64 percent) either had no trends or decreasing trends in streamflow during the study period. The regional pattern of decreasing trends in streamflow during the study period appeared to correspond to moist conditions at the beginning of the study period and the influence of three drought periods during the study period, of which the most extreme was in 2000. Trend tests were completed for ammonia at 49 sites, for nitrite plus nitrate at 69 sites, and for total nitrogen at 41 sites. For all nitrogen constituents analyzed, no trends were observed at half or more of the sites. No regional trend patterns could be confirmed because there was poor spatial representation of the trend sites. Decreasing trends in flow-adjusted concentrations of ammonia were observed at 25 sites. No increasing trends in concentrations of ammonia were noted at any sites. Flow-adjusted concentrations of nitrite plus nitrate decreased at 7 sites and increased at14 sites. Flow-adjusted concentrations of total nitrogen decreased at 2 sites and increased at 12 sites. Improvements to municipal wastewater treatment facilities contributed to the decline of ammonia concentrations at selected sites. Notable increasing trends in nitrite plus nitrate and total nitrogen at selected study sites were attributed to both point and nonpointsources. Trend patterns in total nitrogen generally followed trend patterns in nitrite plus nitrate, which was understandable given that nitrite plus nitrate loads generally were 70-90 percent of the total nitrogen loads at most sites. Population data were used as a surrogate to understand the relation between changes in point sources and nutrient trends because data from wastewater treatment plants were inconsistent for this study area. Although population increased throughout the study area during the study period, there was no observed relation between increasing trends in nitrogen in study area streams and increasing trends in population. With respect to other nitrogen sources, statistical results did suggest that increasing trends in nitrogen could be related to increasing trends in nitrogen from either commercial fertilizer use and/or land application of manure. Loads of ammonia, nitrite plus nitrate, and total nitrogen decreased during the study period, but some trends in nitrogen loads were part of long-term decreases since 1980. For example, ammonia loads were shown to decrease at nearly all sites over the past decade, but at selected sites, these decreasing trends were part of much longer trends since 1980. The Mississippi and Atchafalaya Rivers contributed the highest nitrogen loads to the northwestern Gulf of Mexico as expected; however, nitrogen yields from smaller rivers had similar or higher yields than yields from the Mississippi River. Trend tests were completed for orthophosphorus at 34 sites and for total phosphorus at 52 sites. No trends were observed in abo

Scientific Investigations Report↗
USGS2009

Trends in Surface-Water Quality at Selected Ambient-Monitoring Network Stations in Kentucky, 1979-2004

Increasingly complex water-management decisions require water-quality monitoring programs that provide data for multiple purposes, including trend analyses, to detect improvement or deterioration in water quality with time. Understanding surface-water-quality trends assists resource managers in identifying emerging water-quality concerns, planning remediation efforts, and evaluating the effectiveness of the remediation. This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the Kentucky Energy and Environment Cabinet-Kentucky Division of Water, to analyze and summarize long-term water-quality trends of selected properties and water-quality constituents in selected streams in Kentucky's ambient stream water-quality monitoring network. Trends in surface-water quality for 15 properties and water-quality constituents were analyzed at 37 stations with drainage basins ranging in size from 62 to 6,431 square miles. Analyses of selected physical properties (temperature, specific conductance, pH, dissolved oxygen, hardness, and suspended solids), for major ions (chloride and sulfate), for selected metals (iron and manganese), for nutrients (total phosphorus, total nitrogen, total Kjeldahl nitrogen, nitrite plus nitrate), and for fecal coliform were compiled from the Commonwealth's ambient water-quality monitoring network. Trend analyses were completed using the S-Plus statistical software program S-Estimate Trend (S-ESTREND), which detects trends in water-quality data. The trend-detection techniques supplied by this software include the Seasonal Kendall nonparametric methods for use with uncensored data or data censored with only one reporting limit and the Tobit-regression parametric method for use with data censored with multiple reporting limits. One of these tests was selected for each property and water-quality constituent and applied to all station records so that results of the trend procedure could be compared among stations. Flow-adjustment procedures were used with these techniques at all stations to remove the effects of streamflow on water-quality variability. Flow adjustments were used for all constituents, except temperature. A decreasing trend indicates a decrease in concentration of a particular constituent; whereas, an increasing trend indicates an increase in concentration and potential degradation in water quality. Trend results varied statewide by station and by physical property and water-quality constituent. The results for all stations and all physical properties and water-quality constituents examined had at least one statistically significant (p-value <0.05) increasing or decreasing trend during the specified period of record. Water temperature and concentrations of dissolved oxygen had no significant decreasing trends at any station. Water temperature had one significant increasing trend at the South Fork Cumberland River near Blue Heron station. Specific conductance and concentrations of hardness had one significant decreasing trend at the South Fork Cumberland River near Blue Heron station. pH also had a significant decreasing trend at the Mud River near Gus station. Concentrations of total suspended solids had 1 increasing trend at the Kentucky River at High Bridge station and 10 decreasing trends with 5 of those stations located in the Cumberland River Basin. Major ions analyzed for trends included chloride and sulfate. Concentrations of chloride at the 37 stations had increasing trends at 15 stations, decreasing trends at 3 stations, and no significant trend in concentration over time at 19 stations. Most of the increasing trends in concentrations of chloride are located in the northern part of Kentucky, possibly indicating an increase in the use of road salts for road deicing and (or) the result of resource extraction (oil, gas, and coal). Increasing trends of sulfate concentrations were detected at seven stations, all located in the Appalachian

Scientific Investigations Report↗
USGS2021

Trends in groundwater levels in and near the Rosebud Indian Reservation, South Dakota, water years 1956–2017

The U.S. Geological Survey (USGS), in cooperation with the Rosebud Sioux Tribe, completed a study to characterize water-level fluctuations in observation wells to examine driving factors that affect water levels in and near the Rosebud Indian Reservation, which comprises all of Todd County. The study investigates concerns regarding potential effects of groundwater withdrawals and climate conditions on groundwater levels within an area that includes Todd County and a surrounding area that extends 10 miles north, east, and west of the county border. Characterization of water-level fluctuations in observation wells and relative driving factors was accomplished by statistical trend analysis. Two statistical methods were used for analysis of temporal trends for climatic and hydrologic data. To determine which trend analysis to use, applicable datasets were tested for statistically significant short-term persistence (STP). In the absence of significant STP, existence of statistical trends was determined using the standard Mann-Kendall test for probability values less than or equal to 0.10 (90-percent confidence level); however, a modified Mann-Kendall test was used for datasets where statistically significant STP was detected. Trend magnitudes were computed using the Sen’s slope estimator. Monthly data from the Parameter-elevation Regressions on Independent Slopes Model (PRISM) were aggregated to obtain annual and seasonal datasets for total precipitation, minimum air temperature ( T min ), and maximum air temperature ( T max ) for the study area and a surrounding buffer area. Trend tests for total precipitation, T min , and T max were completed for annual and seasonal time series for water years 1956–2017, which is about 2 years before the earliest available water-level measurements. A 2-year offset was arbitrarily selected because scrutiny of water-level and precipitation data indicated that responses of groundwater levels for many of the observation wells lagged major changes in precipitation patterns by about 2 years. Statistically significant upward trends were detected for annual precipitation and annual T min for almost all of the study area and the surrounding buffer area. Statistically significant downward trends in T max were detected for a very small part of the study area; however, the sparse spatial coverage reduces confidence that these are true trends. Spatial distributions of statistically significant trends in seasonal climate data were generally similar to the annual trends, but with substantial differences in the spatial density of the trends. Groundwater trends for 58 observation wells were analyzed for three separate water-level parameters (minimum, median, and maximum) because wells are measured sporadically and data are biased towards more frequent measurements during periods of heaviest irrigation demand. Trends in the time series of annual precipitation (from PRISM) starting 2 years earlier than for the associated water-level trend also were analyzed for the location of each individual observation well. Sen’s slope and Mann-Kendall probability values (p-values) were computed for the three water-level parameters and for the annual precipitation time series. Graphs showing results of trend analyses for each observation well also showed changes over time in the sum of licensed groundwater withdrawals within six specified radii (0.5, 1, 2, 3, 4, and 5 miles) of each well as a qualitative indicator of proximal groundwater demand. Of all 58 observation wells considered, 28 wells had significant upward trends for at least one of the three water-level parameters, 11 wells had significant downward trends for at least one water-level parameter, and 19 wells did not have any significant trends. Significant upward trends in annual precipitation were detected for 48 of the 58 wells. Results of trend analyses likely show the effects of groundwater withdrawals on water levels in the Ogallala aquifer in areas of substantial demand. Precipitation trends are significantly upward for 43 of the 48 wells completed in the Ogallala aquifer that were analyzed. Of the 48 Ogallala aquifer wells, 24 had significant upward trends for at least one water-level parameter (17 with all 3); however, 10 wells had statistically significant downward trends for at least one water-level parameter (8 with all 3 parameters). All but one of the wells with significant downward trends are located in the south-central part of the study area where licensed irrigation withdrawals are concentrated.

South Dakota↗
USGS2022

Trends in groundwater levels, and orthophosphate and nitrate concentrations in the Middle Snake River Region, south-central Idaho

The U.S. Geological Survey (USGS) evaluated nitrate and orthophosphate concentrations in groundwater for temporal trends (monotonic and step trends) for the middle Snake River region (Cassia, Gooding, Jerome, Lincoln, Minidoka, and Twin Falls Counties) in south-central Idaho using the Regional Kendall test (monotonic trends) and the Wilcoxon signed rank test (step trends). The study evaluated two trend periods: 2000–09 and 2010–19/20. The study area was divided into six hydrogeologic zones (HZs) that had similar geologic and hydrologic characteristics and that correlated with county boundaries where possible. Two well networks sampled by the USGS National Water Quality Program within the HZs were also evaluated. The northern Gooding County HZ had statistically significant increasing nitrate concentration trends for both the monotonic and step trends in the early trend period, while the Cassia and Jerome/Southern Gooding County HZs only had one of the statistical tests with statistically significant increasing nitrate concentrations. The Minidoka County HZ had conflicting results between the two statistical tests for the early time period with a statistically significant increasing monotonic trend in nitrate concentration and a statistically significant decreasing step trend. The differing results between these two statistical tests indicates the significance of concentration data during the middle of the time period. Both the Lincoln and Twin Falls County HZs did not have statistically significant trends for either test during either time period as well as the Northern Gooding County HZ for the latter time period. The Minidoka County HZ had statistically significant nitrate trends for both tests in the latter time period along with one of the trend tests for the Cassia and Jerome/Southern Gooding County HZ. Most of the nitrate concentration trend rates are low from 0.01 to 0.12 milligram per liter per year (mg/L/year) with the northern Gooding County HZ having the highest trend rate during the early time period of 0.28 mg/L/year for the step trend and 0.55 mg/L/year for the monotonic trend. All the HZs and both well networks had statistically significant increasing orthophosphate-concentrations trends in groundwater for the early time period except for the Lincoln County HZ and the step-trend for the Minidoka County HZ. Orthophosphate concentration trend rates for the early period were low, ranging from 0.001 to 0.015 mg/L/year. Only two HZs and the well networks had enough orthophosphate concentration data available in the latter time period to do statistical analysis. The two HZs (Minidoka and Southern Gooding/Jerome County) both have decreasing orthophosphate concentration trends, with only the monotonic trend for the Southern Gooding/Jerome County HZ being statistically significant at 90 percent with a rate of −0.001 mg/L/year. Groundwater levels in two well networks in the eastern Snake River Plain aquifer were also evaluated for trends (monotonic and step), with both networks having statistically significant declining groundwater levels for the 1993–2009 trend period. The latter trend period (2010–20) had statistically significant declining groundwater levels for the A&B well network and statistically significant increasing groundwater levels for the Jerome/Gooding well network, which is downgradient from an aquifer recharge area.

Idaho↗
USGS2024

Peak streamflow trends in Illinois and their relation to changes in climate, water years 1921–2020

This report characterizes changes in peak streamflow in Illinois and the relation of these changes to climatic variability, and provides a foundation for future studies that can address nonstationarity in peak-flow frequency analysis in Illinois. Records of annual peak and daily streamflow at streamgages and gridded monthly climatic data (observed and modeled) were examined across four trend periods (100 years, water years 1921–2020; 75 years, 1946–2020; 50 years, 1971–2020; 30 years 1991–2020) for trends, change points, and other statistical properties indicative of changing conditions. Median peak streamflows generally exhibit upward trends across the State for the 100- and 75-year trend periods and in northern and southern Illinois for the 50- and 30-year trend periods. The medians of the trend magnitudes (normalized by median peak streamflow) range from a 23-percent increase during the 30-year trend period to a 41-percent increase during the 100-year trend period. Streamgages with trends in peak streamflow often also have change points, or abrupt changes, in streamflow magnitude. More than two-thirds of streamgages at the 100- and 75-year trend periods exhibit a trend and change point in median peak streamflow in the same direction. Temporally, clusters of change points are observed in the late 1960s through early 1980s for the 100- and 75-year trend periods and around 2006 for the 50- and 30-year trend periods. Trends in the 90-percent quantile of peak streamflow, which correspond to the 10-percent exceedance probability often used for the design of drainage structures, increased about the same amount as the 50-percent quantile peak streamflows, except at the 100-year trend period, where the 50-percent quantile peak flow increased more for almost all streamgages. The frequency of high flows has also increased in Illinois, with increases in peaks-over-threshold observed across much of the State for the 100- and 75-year trend periods and in northern and southern Illinois for the 50- and 30-year trend periods. Upward trends in observed temperature and observed annual precipitation dominate in all trend periods, with clusters of likely upward trends observed in northern and southern Illinois at the 50- and 30-year trend periods. As expected in response to increasing temperature, the modeled proportion of precipitation falling as snow has largely decreased in the study basins across the State, and modeled potential evapotranspiration has increased. Upward trends in modeled annual runoff, which in this report incorporates only the effects of climatic variation, are observed in the same geographic areas where there are increases in observed annual precipitation. The widespread upward trends in the magnitude of median peak streamflows and the frequency with which high flows occur across the State at the 100- and 75-year trend periods and in northern and southern Illinois at the 50- and 30-year trend periods appear to be driven largely by increases in precipitation based on spatial patterns of these changes and statistical relations between streamflow and climate metrics. Other effects not considered in this report, like urbanization, may be important drivers for certain streamgages in the State. The prevalence of nonstationarity in peak streamflow in Illinois has important implications for peak-flow frequency analysis. Average annual precipitation and the occurrence of extreme precipitation events are expected to increase across the State. If precipitation continues to increase as expected, peak-flow frequency estimates based on older records may no longer represent the hydrologic regime of today, and methods for nonstationary peak-flow frequency analysis may be needed.

Illinois↗
USGS2009

Trends in pesticide concentrations in corn-belt streams, 1996-2006

Trends in the concentrations of commonly occurring pesticides in the Corn Belt of the United States were assessed, and the performance and application of several statistical methods for trend analysis were evaluated. Trends in the concentrations of 11 pesticides with sufficient data for trend assessment were assessed at up to 31 stream sites for two time periods: 1996–2002 and 2000–2006. Pesticides included in the trend analyses were atrazine, acetochlor, metolachlor, alachlor, cyanazine, EPTC, simazine, metribuzin, prometon, chlorpyrifos, and diazinon. The statistical methods applied and compared were (1) a modified version of the nonparametric seasonal Kendall test (SEAKEN), (2) a modified version of the Regional Kendall test, (3) a parametric regression model with seasonal wave (SEAWAVE), and (4) a version of SEAWAVE with adjustment for streamflow (SEAWAVE-Q). The SEAKEN test is a statistical hypothesis test for detecting monotonic trends in seasonal time-series data such as pesticide concentrations at a particular site. Trends across a region, represented by multiple sites, were evaluated using the regional seasonal Kendall test, which computes a test for an overall trend within a region by computing a score for each season at each site and adding the scores to compute the total for the region. The SEAWAVE model is a parametric regression model specifically designed for analyzing seasonal variability and trends in pesticide concentrations. The SEAWAVE-Q model accounts for the effect of changing flow conditions in order to separate changes caused by hydrologic trends from changes caused by other factors, such as pesticide use. There was broad, general agreement between unadjusted trends (no adjustment for streamflow effects) identified by the SEAKEN and SEAWAVE methods, including the regional seasonal Kendall test. Only about 10 percent of the paired comparisons between SEAKEN and SEAWAVE indicated a difference in the direction of trend, and none of these had differences significant at the 10-percent significance level. This consistency of results supports the validity and robustness of all three approaches as trend analysis tools. The SEAWAVE method is favored, however, because it has less restrictive data requirements, enabling analysis for more site/pesticide combinations, and can incorporate adjustment for streamflow (SEAWAVE-Q) with substantially fewer measurements than the flow-adjustment procedure used with SEAKEN. Analysis of flow-adjusted trends is preferable to analysis of non-adjusted trends for evaluating potential effects of changes in pesticide use or management practices because flow-adjusted trends account for the influence of flow-related variability. Analysis of flow-adjusted trends by SEAWAVE-Q showed that all of the pesticides assessed, except simazine and acetochlor, were dominated by varying degrees of concentration downtrends in one or both analysis periods. Atrazine, metolachlor, alachlor, cyanazine, EPTC, and metribuzin—all major corn herbicides, as well as prometon and chlorpyrifos, showed more prevalent concentration downtrends during 1996–2002 compared to 2000–2006. Diazinon had no clear trends during 1996–2002, but had predominantly downward trends during 2000–2006. Acetochlor trends were mixed during 1996–2002 and slightly upward during 2000–2006, but most of the trends were not statistically significant. Simazine concentrations trended upward at most sites during both 1996–2002 and 2000–2006. Comparison of concentration trends to agricultural-use trends indicated similarity in direction and magnitude for acetochlor, metolachlor, alachlor, cyanazine, EPTC, and metribuzin. Concentration downtrends for atrazine, chlorpyrifos, and diazinon were steeper than agricultural-use downtrends at some sites, indicating the possibility that agricultural management practices may have increasingly reduced transport to streams (particularly atrazine) or, for chlorpyrifos and diazinon, that nonagricultural uses declined substantially. Concentration uptrends for simazine generally were steeper than agricultural-use uptrends, indicating the possibility that nonagricultural uses of this herbicide increased during the study period.

Scientific Investigations Report↗
USGS2021

Trends in precipitation chemistry across the U.S. 1985–2017: Quantifying the benefits from 30 years of Clean Air Act amendment regulation

Acid rain was first recognized in the 1970s in North America and Europe as an atmospheric pollutant that was causing harm to ecosystems. In response, the U.S. Congress enacted Title IV of the Clean Air Act Amendments (CAA) in 1990 to reduce sulfur and nitrogen emissions from fossil fuel burning power plants. This study reports trends in wet-precipitation chemistry in response to emissions reductions implemented as part of the CAA. Trends were calculated for sulfate (SO 4 ), nitrate (NO 3 ) and ammonium (NH 4 ) from 1985 to 2017 at 168 stations operated by the National Atmospheric Deposition Program (NADP); stations were divided into 9 regions across the United States. Trend analyses were conducted for three time periods: Period 1 (1985–1999), Period 2 (2000–2017), and the entire study period (1985–2017). Seasonal and regional Kendall trend analyses reveal significant decreasing trends in mean wet-precipitation SO 4 concentrations in all 9 regions during the entire study period. The largest decreasing trends in monthly mean SO 4 precipitation-weighted concentrations were measured in the Mid-Atlantic (−1.29 μeq/l/yr), Midwest (−1.15 μeq/l/yr), and Northeast regions (−1.10 μeq/l/yr). The trends in monthly mean NO 3 concentrations were not as strong as those for SO 4 , but all of the regions had significant decreasing trends in NO 3 and again the Mid-Atlantic (−0.53 μeq/l/yr), Midwest (−0.44 μeq/l/yr), and Northeast regions (−0.50 μeq/l/yr) had the strongest trends. Trends were steepest during Period 2 for SO 4 and NO 3 , in fact for NO 3 86% of the stations had significant decreasing trends during Period 2 while only 8% of the stations had significant decreasing trends during Period 1. The stations with the highest concentrations of SO 4 and NO 3 at the beginning of the study had the strongest decreasing trends and the relations were stronger during Period 2 than Period 1. For NH 4 , 22% of the stations had statistically significant increasing trends in concentration during Period 1. The largest increasing trends in wet-precipitation NH 4 concentration occurred in the North-Central region during Period 1, Period 2 and throughout the entire study. By comparison, NH 4 trends in the Rocky-North and Rocky-South regions were about half as steep and trends in the South-Central and Midwest regions were about one-third as steep. We compared trends in SO 4 and NO 3 concentrations from NADP stations to emissions of sulfur dioxide and nitrogen oxides, respectively to determine whether there was a relation between emissions and wet-precipitation concentration trends within proximity to NADP stations. There was a statistically significant relation (r 2 = 0.62–0.69, p < 0.01) between the trend in SO 4 concentrations at individual NADP stations and total and mean sulfur dioxide (SO 2 ) emissions from power plants within a range of 750 km and 1000 km from each station. There were also significant relations between NO 3 concentration trends at NADP stations and power plant emissions of nitrogen oxides, but they were not nearly as strong (r 2 = 0.18–0.36, p < 0.01) as those for SO 4 and were strongest for emissions within a range of 1000 km and 1500 km from each NADP station. Decreases in wet-precipitation SO 4 concentrations were more consistent across regions and through time than decreases in NO 3 and SO 4 trends were more closely linked to stationary emissions sources than NO 3 trends. There were statistically significant increases in NH 4 wet-precipitation concentrations, as have been reported in previous studies, but this study found that those increases were strongest during Period 1 and were not consistent across the United States. During the first 3 years of the study period, wet-precipitation acidity was dominated by SO 4 in 8 of the 9 regions; by 2017 NO 3 dominated the acidity of wet-precipitation in 7 of the 9 regions. There has also been a downward shift in the NO 3 :NH 4 ratio of wet-precipitation as the emissions of nitrogen oxides have declined while ammonia emissions have remained essentially constant. This shift has resulted in an increase in wet-precipitation total nitrogen concentrations in 7 of the 9 regions and indicate that efforts to control NH 3 emissions will become increasingly important as emissions of nitrogen oxides continue to decline.

Atmospheric Environment↗
USGS2020

Trends in streamflow and precipitation for selected sites in the Elkhorn River Basin and in streamflow in the Salt Creek and Platte River Basins, Nebraska, 1961–2011

To better understand the streamflow trends at the streamgages in the Elkhorn River Basin in Nebraska, the U.S. Geological Survey (USGS) in cooperation with the Lower Elkhorn Natural Resources District further investigated streamflow trends at the eight streamgages on the Elkhorn River, Salt Creek, and the Lower Platte River that indicated a positive trend in streamflow characteristics and analyzed precipitation trends in the four basins upstream from the Elkhorn River Basin streamgages. An analysis of four streamgages in the Elkhorn River Basin, one streamgage in Salt Creek Basin, and three streamgages in the Lower Platte River Basin that had previously indicated trends in selected annual mean streamflow, annual low flows, fall low flows, and growing season monthly mean streamflows metrics were analyzed for the period from 1961 to 2011. A streamgage in the Upper Elkhorn River Basin (Elkhorn River at Neligh, Nebraska [USGS station 06798500; maintained by USGS from water years 1930 to 1993, maintained by Nebraska Department of Natural Resources from water years 1994 to 2019]) had significant positive trends in annual mean streamflow and insignificant trends for other streamflow metrics whereas the lower three sites (Logan Creek near Uehling, Nebr. [USGS station 06799500]; Maple Creek at Nickerson, Nebr. [USGS station 06800000]; and Elkhorn River at Waterloo, Nebr. [USGS station 06800500]) had significant positive trends for annual mean streamflow, for all durations of the annual low-flow periods (1-day, 2-day, 3-day, 7-day, 14-day, 30-day, 60-day, 90-day, and 183-day periods), for all durations of the low-flow periods in October–November (1-day, 2-day, 3-day, 7-day, 14-day, 30-day, and 60-day periods), and for monthly mean streamflow for July, August, and September. Upstream from the confluence of the Elkhorn River and the Platte River, the Platte River at North Bend, Nebr. (USGS station 06796000), streamgage indicated insignificant trends for most streamflow metrics. A streamgage in the Salt Creek Basin (Salt Creek at Greenwood, Nebr. [USGS station 06803555]) also indicated positive trends in some low-flows metrics. Streamflow at the Platte River at Louisville, Nebr. (USGS station 06805500), streamgage, downstream from the Salt Creek and Elkhorn River inflows, indicated significant positive trends in most annual and all October–November low flows and August mean streamflow but insignificant trends in annual mean streamflow and June, July, and September monthly mean streamflows. Streamflow records for the Platte River near Duncan, Nebr. (USGS station 06774000), streamgage only indicated a significant trend in the August mean streamflow; no other metrics had significant trends at the streamgage. The trend analyses are sensitive to the period that is analyzed for trends. Sites with the most significant trends for low-flow metrics for the period 1961–2011 have fewer significant trends for low-flow metrics for the period after 1980–2011. The results indicate that positive trends in low flows at the Salt Creek and Elkhorn River streamgages may be contributing to positive trends in low flows for the Platte River at Louisville, Nebr., streamgage. Likewise, streamflow in the Salt Creek and Elkhorn River Basins may be contributing to the positive trend in August mean streamflow for the Platte River at Louisville, Nebr., streamgage, three lower Elkhorn River streamgages, and the Salt Creek streamgage. Precipitation was also examined as a primary cause for streamflow trends in the Elkhorn River Basin. For the four streamgages in the Elkhorn River Basin, relations between precipitation and streamflow were examined on an annual and monthly basis using linear regression. In general, the goodness of fit for the linear relations was poor with coefficient of determination values of less than or equal to 0.10 for four of the eight relations. Only one significant increase in annual precipitation upstream from the four streamgages and the frequent detection of significant increases in streamflow after removing the effect of precipitation indicate that other factors besides precipitation may have played a role in the significant positive trends in low-flow periods in the lower Elkhorn River and its tributaries.

Nebraska↗
USGS2017

Groundwater-quality data in 12 GAMA study units: Results from the 2006–10 initial sampling period and the 2008–13 trend sampling period, California GAMA Priority Basin Project

The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey in cooperation with the California State Water Resources Control Board. From 2004 through 2012, the GAMA-PBP collected samples and assessed the quality of groundwater resources that supply public drinking water in 35 study units across the State. Selected sites in each study unit were sampled again approximately 3 years after initial sampling as part of an assessment of temporal trends in water quality by the GAMA-PBP. Twelve of the study units, initially sampled during 2006–11 (initial sampling period) and sampled a second time during 2008–13 (trend sampling period) to assess temporal trends, are the subject of this report. The initial sampling was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies in the 12 study units. In these study units, 550 sampling sites were selected by using a spatially distributed, randomized, grid-based method to provide spatially unbiased representation of the areas assessed (grid sites, also called “status sites”). After the initial sampling period, 76 of the previously sampled status sites (approximately 10 percent in each study unit) were randomly selected for trend sampling (“trend sites”). The 12 study units sampled both during the initial sampling and during the trend sampling period were distributed among 6 hydrogeologic provinces: Coastal (Northern and Southern), Transverse Ranges and Selected Peninsular Ranges, Klamath, Modoc Plateau and Cascades, and Sierra Nevada Hydrogeologic Provinces. For the purposes of this trend report, the six hydrogeologic provinces were grouped into two hydrogeologic regions based on location: Coastal and Mountain. The groundwater samples were analyzed for a number of synthetic organic constituents (volatile organic compounds, pesticides, and pesticide degradates), constituents of special interest (perchlorate and 1,2,3-trichloropropane), and natural inorganic constituents (nutrients, major and minor ions, and trace elements). Isotopic tracers (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) also were measured to help identify processes affecting groundwater quality and the sources and ages of the sampled groundwater. More than 200 constituents and water-quality indicators were measured during the trend sampling period. Quality-control samples (blanks, replicates, matrix-spikes, and surrogate compounds) were collected at about one-third of the trend sites, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. On the basis of detections in laboratory and field blank samples collected by GAMA-PBP study units, including the 12 study units presented here, reporting levels for some groundwater results were adjusted in this report. Differences between replicate samples were mostly within acceptable ranges, indicating low variability in analytical results. Matrix-spike recoveries were largely within the acceptable range (70 to 130 percent). This study did not attempt to evaluate the quality of water delivered to consumers. After withdrawal, groundwater used for drinking water typically is treated, disinfected, and blended with other waters to achieve acceptable water quality. The comparison benchmarks used in this report apply to treated water that is served to the consumer, not to untreated groundwater. To provide some context for the results, however, concentrations of constituents measured in these groundwater samples were compared with benchmarks established by the U.S. Environmental Protection Agency and the State of California. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most organic constituents that were detected in groundwater samples from the trend sites were found at concentrations less than health-based benchmarks. One volatile organic compound—perchloroethene—was detected at a concentration greater than the health-based benchmark in samples from one trend site during the initial and trend sampling periods. Chloroform was detected in at least 10 percent of the samples at trend sites in both sampling periods. Methyl tert -butyl ether was detected in samples from more than 10 percent of the trend sites during the initial sampling period. No pesticide or pesticide degradate was detected in greater than 10 percent of the samples from trend sites or at concentrations greater than their health-based benchmarks during either sampling period. Nutrients were not detected at concentrations greater than their health-based benchmarks during either sampling period. Most detections of major ions and trace elements in samples from trend sites were less than health-based benchmarks during both sampling periods. Arsenic and boron each were detected at concentrations greater than the health-based benchmark in samples from four trend sites during the initial and trend sampling periods. Molybdenum was detected in samples from four trend sites at concentrations greater than the health-based benchmark during both sampling periods. Samples from two of these trend sites had similar molybdenum concentrations, and two had substantially different concentrations during the initial and trend sampling periods. Uranium was detected at a concentration greater than the health-based benchmark only at two trend sites.

California↗
USGS2010

Trends in pesticide concentrations in urban streams in the United States, 1992-2008

Pesticide concentration trends in streams dominated by urban land use were assessed using data from 27 urban streams sampled as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sites were divided into four regions, Northeast, South, Midwest, and West, to examine possible regional patterns. Three partially overlapping 9-year periods (1992-2000, 1996-2004, and 2000-2008) were examined for eight herbicides and one degradation product (simazine, prometon, atrazine, deethylatrazine, metolachlor, trifluralin, pendimethalin, tebuthiuron, and Dacthal), and five insecticides and two degradation products (chlorpyrifos, malathion, diazinon, fipronil, fipronil sulfide, desulfinylfipronil, and carbaryl). The data were analyzed for trends in concentration using a parametric regression model with seasonality, flow-related variability, and trend, called SEAWAVE-Q. The SEAWAVE-Q model also was used to generate estimated daily concentration percentiles for each analysis period to provide a summary of concentration magnitudes. For herbicides, the largest 90th percentiles of estimated concentrations for simazine were in the South, prometon at some sites in all of the regions, atrazine and deethylatrazine in the South and Midwest, metolachlor in the Midwest and a few sites in the South, pendimethalin at scattered sites in all of the regions, and tebuthiuron in the South and a few sites in the Midwest and West. For insecticides, the largest 90th percentiles of estimated concentrations for diazinon and carbaryl were distributed among various sites in all regions (especially during 1996-2004), and fipronil at isolated sites in all of the regions during 2000-2008. Trend analysis results for the herbicides indicated many significant trends, both upward and downward, with varying patterns depending on period, region, and herbicide. Overall, deethylatrazine showed the most consistent pattern of upward trends, especially in the Northeast (2000-2008), South (1996-2004 and 2000-2008), and Midwest (1996-2004 and 2000-2008). Other herbicides showed less consistent upward trends, including simazine in the South (1996-2004), prometon in the Midwest (2000-2008), and atrazine in the South (1996-2004). The most consistent downward trends were for simazine in the Northeast and Midwest (1996-2004), prometon in the Northeast and Midwest (1996-2004) and West (1996-2004 and 2000-2008), and tebuthiuron in the South (1996-2004 and 2000-2008) and West (2000-2008). Strong similarity existed between the trends for atrazine and deethylatrazine during 1996-2004. During 2000-2008, however, there were mixed upward and downward trends in atrazine and predominantly upward trends in deethylatrazine. Ten sites with a downward trend in atrazine were paired with an upward trend in deethylatrazine and for three of these sites (1 in the South and 2 in the Midwest) both opposing trends were significant. Opposing trends showing a decrease in atrazine and an increase in deethylatrazine may indicate that decreases in atrazine from surface runoff are being offset in some cases by increases in deethylatrazine from groundwater for the latter analysis period. Trend results for insecticides indicated widespread significant downward trends for chlorpyrifos (especially 1996-2004), diazinon (1996-2004 and 2000-2008), and malathion (especially 1996-2004); widespread significant upward trends for fipronil and its degradation products (2000-2008); and mostly nonsignificant trends for carbaryl (1996-2004 and 2000-2008). The downward trends for chlorpyrifos and diazinon were consistent with the regulatory phaseout of residential uses of these insecticides and the upward trends for fipronil and its degradation products were consistent with its introduction in 1996 and subsequent increasing use as a possible substitute for chlorpyrifos and diazinon. The downward trends in malathion may be caused by voluntary substitution of pyrethroids or fipronil for malathio

Scientific Investigations Report↗
USGS2014

Trends in precipitation, streamflow, reservoir pool elevations, and reservoir releases in Arkansas and selected sites in Louisiana, Missouri, and Oklahoma, 1951–2011

The U.S. Geological Survey (USGS) and the U.S. Army Corps of Engineers (USACE) conducted a statistical analysis of trends in precipitation, streamflow, reservoir pool elevations, and reservoir releases in Arkansas and selected sites in Louisiana, Missouri, and Oklahoma for the period 1951–2011. The Mann-Kendall test was used to test for trends in annual and seasonal precipitation, annual and seasonal streamflows of 42 continuous-record USGS streamflow-gaging stations, annual pool elevations and releases from 16 USACE reservoirs, and annual releases from 11 dams on the Arkansas River. A statistically significant (p≤0.10) upward trend was observed in annual precipitation for the State, with a Sen slope of approximately 0.10 inch per year. Autumn and winter were the only seasons that had statistically significant trends in precipitation. Five of six physiographic sections and six of seven 4-digit hydrologic unit code (HUC) regions in Arkansas had statistically significant upward trends in autumn precipitation, with Sen slopes of approximately 0.06 to 0.10 inch per year. Sixteen sites had statistically significant upward trends in the annual mean daily streamflow and were located on streams that drained regions with statistically significant upward trends in annual precipitation. Expected annual rates of change corresponding to statistically significant trends in annual mean daily streamflows, which ranged from 0.32 to 0.88 percent, were greater than those corresponding to regions with statistically significant upward trends in annual precipitation, which ranged from 0.19 to 0.28 percent, suggesting that the observed trends in regional annual precipitation do not fully account for the observed trends in annual mean daily streamflows. Trends in annual maximum daily streamflows were similar to trends in the annual mean daily streamflows but were only statistically significant at seven sites. There were more statistically significant trends (28 of 42 sites) in the annual minimum daily streamflows than in the annual means or maximums. Statistically significant trends in the annual minimum daily streamflows were upward at 18 sites and downward at 10 sites. Despite autumn being the only season that had statistically significant upward trends in seasonal precipitation, statistically significant upward trends in seasonal mean streamflows occurred in every season but spring. Trends in the annual mean, maximum, and minimum daily pool elevations of USACE reservoirs were consistent between metrics for reservoirs in the White, Arkansas, and Ouachita River watersheds, while trends varied between metrics at DeQueen Lake, Millwood Lake, and Lake Chicot. Most of the statistically significant trends in pool elevation metrics were upward and gradual—Sen slopes were less than 0.37 foot per year—and were likely the result of changes in reservoir regulation plans. Trends in the annual mean and maximum daily releases from USACE reservoirs were generally upward in all HUC regions. There were few statistically significant trends in the annual mean daily releases because the reservoirs are operated to maintain a regulation stage at a downstream site according to guidelines set forth in the regulation plans of the reservoirs. The annual number of low-flow days was both increasing and decreasing for reservoirs in northern Arkansas and southern Missouri and generally increasing for reservoirs in southern Arkansas.

Arkansas;Louisiana;Missouri;Oklahoma↗