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USGS2007

Cautions and suggestions for geochemical sampling in fractured rock

Collecting water samples for geochemical analyses in open bedrock boreholes or in discrete intervals of boreholes intersected by multiple fractures is likely to yield ambiguous results for ground water chemistry because of the variability in the transmissivity, storativity, and hydraulic head of fractures intersecting the borehole. Interpreting chemical analyses of water samples collected in bedrock boreholes requires an understanding of the hydraulic conditions in the borehole under the ambient flow regime in the aquifer as well as during sampling. Pumping in open boreholes, regardless of the pumping rate and the location of the pump intake, first draws water from the borehole and then from fractures intersecting the borehole. The time at which the volumetric rate of water entering the borehole from fractures is approximately equal to the pumping rate can be identified by monitoring the logarithm of drawdown in the borehole as a function of the logarithm of time. Mixing of water entering the borehole from fractures with water in the borehole must be considered in estimating the time at which the pump discharge is representative of aquifer water. In boreholes intersected by multiple fractures, after the contribution from the borehole volume has diminished, the contribution of fractures to the pump discharge will be weighted according to their transmissivity, regardless of the location of the pump intake. This results in a flux‐averaged concentration in the pump discharge that is biased by the chemical signature of those fractures with the highest transmissivity. Under conditions where the hydraulic head of fractures varies over the length of the borehole, open boreholes will be subject to ambient flow in the water column in the borehole. In some instances, the magnitude of the ambient flow may be similar to the designated pumping rate for collecting water samples for geochemical analyses. Under such conditions, the contributions to the pump discharge from individual fractures will be a function not only of the transmissivity of the fractures, but also of the distribution of hydraulic head in fractures intersecting the borehole. To reduce or eliminate the deleterious effects of conducting geochemical sampling in open boreholes, a straddle‐packer apparatus that isolates a single fracture or a series of closely spaced fractures is recommended. It is also recommended that open boreholes be permanently outfitted with borehole packers or borehole liners in instances where maintaining the hydraulic and chemical stratification in the aquifer is of importance. In a field example, a comparison of results from sampling in an open borehole and in discrete intervals of the same borehole showed dramatic differences in the concentrations of chemical constituents in the water samples, even though chemical field parameters stabilized prior to both open borehole and discrete interval sampling.

Groundwater Monitoring & Remediation↗
USGS2007

Laboratory comparison of polyethylene and dialysis membrane diffusion samplers

The ability of diffusion samplers constructed from regenerated cellulose dialysis membrane and low density, lay flat polyethylene tubing to collect volatile organic compounds and inorganic ions was compared in a laboratory study. Concentrations of vinyl chloride, cis ‐1, 2‐dichloroethene, bromochloromethane, trichloroethene, bromodichloromethane, and tetrachloroethene collected by both types of diffusion samplers reached equilibrium with the concentrations of these compounds in test solution within three days. Concentrations of bromide and iron collected by the dialysis membrane diffusion samplers reached equilibrium with the concentrations of these compounds in a test solution within three to seven days. No detectable concentrations of bromide or iron were found in polyethylene diffusion samplers even after 21 days. No measurable concentrations of aluminum, arsenic, barium, cadmium, chromium, iron, mercury, manganese, nickel, and lead, or sulfide, were leached out of dialysis membrane samplers over seven days. Compared with using a gas‐tight syringe to sample the diffusion sampler, clipping the bag and pouring the water sample into a sample vial resulted in only a small 6.2% average loss of volatile organic compounds. Dialysis membrane diffusion samplers offer promise for use in sampling ground water for inorganic constituents as well as volatile organic compounds.

Groundwater Monitoring & Remediation↗
USGS2007

Pharmaceuticals and other organic wastewater contaminants within a leachate plume downgradient of a municipal landfill

Ground water samples collected from the Norman Landfill research site in central Oklahoma were analyzed as part of the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program's national reconnaissance of pharmaceuticals and other organic waste water contaminants (OWCs) in ground water. Five sites, four of which are located downgradient of the landfill, were sampled in 2000 and analyzed for 76 OWCs using four research methods developed by the USGS. OWCs were detected in water samples from all of the sites sampled, with 22 of the 76 OWCs being detected at least once. Cholesterol (a plant and animal steroid), was detected at all five sites and was the only compound detected in a well upgradient of the landfill. N,Ndiethyltoluamide (DEET used in insect repellent) and tri(2-chloroethyl) phosphate (fire-retardant) were detected in water samples from all four sites located within the landfill-derived leachate plume. The sites closest to the landfill had more detections and greater concentrations of each of the detected compounds than sites located farther away. Detection of multiple OWCs occurred in the four sites located within the leachate plume, with a minimum of four and a maximum of 17 OWCs detected. Because the landfill was established in the 1920s and closed in 1985, many compounds detected in the leachate plume were likely disposed of decades ago. These results indicate the potential for long-term persistence and transport of some OWCs in ground water.

Oklahoma↗
USGS2007

Ground water flow modeling with sensitivity analyses to guide field data collection in a mountain watershed

In mountain watersheds, the increased demand for clean water resources has led to an increased need for an understanding of ground water flow in alpine settings. In Prospect Gulch, located in southwestern Colorado, understanding the ground water flow system is an important first step in addressing metal loads from acid-mine drainage and acid-rock drainage in an area with historical mining. Ground water flow modeling with sensitivity analyses are presented as a general tool to guide future field data collection, which is applicable to any ground water study, including mountain watersheds. For a series of conceptual models, the observation and sensitivity capabilities of MODFLOW-2000 are used to determine composite scaled sensitivities, dimensionless scaled sensitivities, and 1% scaled sensitivity maps of hydraulic head. These sensitivities determine the most important input parameter(s) along with the location of observation data that are most useful for future model calibration. The results are generally independent of the conceptual model and indicate recharge in a high-elevation recharge zone as the most important parameter, followed by the hydraulic conductivities in all layers and recharge in the next lower-elevation zone. The most important observation data in determining these parameters are hydraulic heads at high elevations, with a depth of less than 100 m being adequate. Evaluation of a possible geologic structure with a different hydraulic conductivity than the surrounding bedrock indicates that ground water discharge to individual stream reaches has the potential to identify some of these structures. Results of these sensitivity analyses can be used to prioritize data collection in an effort to reduce time and money spend by collecting the most relevant model calibration data.

Groundwater Monitoring & Remediation↗
USGS2011

Emerging contaminants at a closed and an operating landfill in Oklahoma

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty-eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.

Oklahoma↗
USGS2011

Borehole geophysical investigation of a formerly used defense site, Machiasport, Maine, 2003-2006

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, collected borehole geophysical logs in 18 boreholes and interpreted the data along with logs from 19 additional boreholes as part of an ongoing, collaborative investigation at three environmental restoration sites in Machiasport, Maine. These sites, located on hilltops overlooking the seacoast, formerly were used for military defense. At each of the sites, chlorinated solvents, used as part of defense-site operations, have contaminated the fractured-rock aquifer. Borehole geophysical techniques and hydraulic methods were used to characterize bedrock lithology, fractures, and hydraulic properties. In addition, each geophysical method was evaluated for effectiveness for site characterization and for potential application for further aquifer characterization and (or) evaluation of remediation efforts. Results of borehole geophysical logging indicate the subsurface is highly fractured, metavolcanic, intrusive, metasedimentary bedrock. Selected geophysical logs were cross-plotted to assess correlations between rock properties. These plots included combinations of gamma, acoustic reflectivity, electromagnetic induction conductivity, normal resistivity, and single-point resistance. The combined use of acoustic televiewer (ATV) imaging and natural gamma logs proved to be effective for delineating rock types. Each of the rock units in the study area could be mapped in the boreholes, on the basis of the gamma and ATV reflectivity signatures. The gamma and mean ATV reflectivity data were used along with the other geophysical logs for an integrated interpretation, yielding a determination of quartz monzonite, rhyolite, metasedimentary units, or diabase/gabbro rock types. The interpretation of rock types on the basis of the geophysical logs compared well to drilling logs and geologic mapping. These results may be helpful for refining the geologic framework at depth. A stereoplot of all fractures intersecting the boreholes indicates numerous fractures, a high proportion of steeply dipping fractures, and considerable variation in fracture orientation. Low-dip-angle fractures associated with unloading and exfoliation are also present, especially at a depth of less than 100 feet below the top of casing. These sub-horizontal fractures help to connect the steeply dipping fractures, making this a highly connected fracture network. The high variability in the fracture orientations also increases the connectivity of the fracture network. A preliminary comparison of all fracture data from all the boreholes suggests fracturing decreases with depth. Because all the boreholes were not drilled to the same depth, however, there is a clear sampling bias. Hence, the deepest boreholes are analyzed separately for fracture density. For the deepest boreholes in the study, the intensity of fracturing does not decline significantly with depth. It is possible the fractures observed in these boreholes become progressively tighter or closed with depth, but this is difficult to verify with the borehole methods used in this investigation. The fact that there are more sealed fractures at depth (observed in optical televiewer logs in some of the boreholes) may indicate less opening of the sealed fractures, less water moving through the rock, and less weathering of the fracture infilling minerals. Although the fracture orientation remained fairly constant with depth, differences in the fracture patterns for the three restoration sites indicate the orientation of fractures varies across the study area. The fractures in boreholes on Miller Mountain predominantly strike northwest-southeast, and to a lesser degree they strike northeast. The fractures on or near the summit of Howard Mountain strike predominantly east-west and dip north and south, and the fractures near the Transmitter Site strike northeast-southwest and dip northwest and southeast. The fracture populations for the boreholes on or near the summit of Howard Mountain show more variation than at the other two sites. This variation may be related to the proximity of the fault, which is northeast of the summit of Howard Mountain. In a side-by-side comparison of stereoplots from selected boreholes, there was no clear correspondence between fracture orientation and proximity to the fault. There is, however, a difference in the total populations of fractures for the boreholes on or near the summit of Howard Mountain and the boreholes near the Transmitter Site. Further to the southwest and further away from the fault, the fractures at the Transmitter Site predominantly strike northeast-southwest and northwest-southeast.Heat-pulse flowmeter (HPFM) logging was used to identify transmissive fractures and to estimate the hydraulic properties along the boreholes. Ambient downflow was measured in 13 boreholes and ambient upflow was measured in 9 boreholes. In nine other bedrock boreholes, the HPFM did not detect measurable vertical flow. The observed direction of vertical flow in the boreholes generally was consistent with the conceptual flow model of downward movement in recharge locations and upward flow in discharge locations or at breaks in the slope of land surface. Under low-rate pumping or injection rates [0.25 to 1 gallon per minute (gal/min)], one to three inflow zones were identified in each borehole. Two limitations of HPFM methods are (1) the HPFM can only identify zones within 1.5 to 2 orders of magnitude of the most transmissive zone in each borehole, and (2) the HPFM cannot detect flow rates less than 0.010 + or - 0.005 gal/min, which corresponds to a transmissivity of about 1 foot squared per day (ft2/d). Consequently, the HPFM is considered an effective tool for identifying the most transmissive fractures in a borehole, down to its detection level. Transmissivities below that cut-off must be measured with another method, such as packer testing or fluid-replacement logging. Where sufficient water-level and flowmeter data were available, HPFM results were numerically modeled. For each borehole model, the fracture location and measured flow rates were specified, and the head and transmissivity of each fracture zone were adjusted until a model fit was achieved with the interpreted ambient and stressed flow profiles. The transmissivities calculated by this method are similar to the results of an open-hole slug test; with the added information from the flowmeter, however, the head and transmissivity of discrete zones also can be determined. The discrete-interval transmissivities ranged from 0.16 to 330 ft2/d. The flowmeter-derived open-hole transmissivity, which is the combined total of each of the transmissive zones, ranged from 1 to 511 ft2/d. The whole-well open-hole transmissivity values determined with HPFM methods were compared to the results of open-hole hydraulic tests. Despite the fact that the flowmeter-derived transmissivities consistently were lower than the estimates derived from open-hole hydraulic tests alone, the correlation was very strong (with a coefficient of determination, R2, of 0.9866), indicating the HPFM method provides a reasonable estimate of transmissivities for the most transmissive fractures in the borehole. Geologic framework, fracture characterization, and estimates of hydraulic properties were interpreted together to characterize the fracture network. The data and interpretation presented in this report should provide information useful for site investigators as the conceptual site groundwater flow model is refined. Collectively, the results and the conceptual site model are important for evaluating remediation options and planning or implementing the design of a well field and borehole completions that will be adequate for monitoring flow, remediation efforts, groundwater levels, and (or) water quality. Similar kinds of borehole geophysical logging (specifically the borehole imaging, gamma, fluid logs, and HPFM) should be conducted in any newly installed boreholes and integrated with interpretations of any nearby boreholes. If boreholes are installed close to existing or other new boreholes, cross-hole flowmeter surveys may be appropriate and may help characterize the aquifer properties and connections between the boreholes.

Maine↗
USGS2012

Groundwater monitoring plan for the Missouri River alluvial aquifer in the vicinity of the City of Independence, Missouri, well field

Source contributions to monitoring and supply wells, contributing recharge areas, groundwater travel times, and current (2012) understanding of alluvial water quality were used to develop a groundwater monitoring plan for the Missouri River alluvial aquifer in the vicinity of the City of Independence, Missouri well field. The plan was designed to evaluate long-term alluvial water quality and assess potential changes in, and threats to, well-field water quality. Source contributions were determined from an existing groundwater flow model in conjunction with particle-tracking analysis and verified with water-quality data collected from 1997 through 2010 from a network of 68 monitoring wells. Three conjunctive factors - well-field pumpage, Missouri River discharge, and aquifer recharge - largely determined groundwater flow and, therefore, source contributions. The predominant source of groundwater to most monitoring wells and supply wells is the Missouri River, and this was reflected, to some extent, in alluvial water quality. To provide an estimate of the maximum potential lead time available for remedial action, monitoring wells where groundwater travel times from the contributing recharge areas are less than 2 years and predominately singular sources (such as the Missouri River or the land surface) were selected for annual sampling. The sample interval of the remaining wells, which have varying travel times and intermediate mixtures of river and land-surface contributions, were staggered on a 2-, 3-, or 4-year rotation. This was done to provide data from similar contributing areas and account for inherent aquifer variability yet minimize sample redundancy.

Missouri↗
USGS2022

A borehole test for chlorinated solvent diffusion and degradation rates in sedimentary rock

We present a new field measurement and numerical interpretation method (combined termed ‘test’) to parameterize the diffusion of trichloroethene (TCE) and its biodegradation products (DPs) from the matrix of sedimentary rock. The method uses a dual-packer system to interrogate a low-permeability section of the rock matrix adjacent to a previously contaminated borehole and uses the borehole monitoring history to establish the pre-test condition. TCE and its DPs are removed from the groundwater between the packers at the onset of the testing. The parameters estimated by fitting a radial diffusion model to the concentration history and borehole concentration data, also termed back-diffusion, are the tortuosity factor and sorption coefficients of TCE and DPs in the rock matrix and the TCE and DP biodegradation rate coefficients in the borehole. We demonstrate the equipment design and the interpretive method using a borehole accessing the grey mudstone at a TCE contaminated site in the Newark Basin. In this test, both nonreactive (bromide) and reactive (trichlorofluoroethene) tracers are used to constrain the estimated parameters; however, the bromide tracer was not needed to estimate the parameters in this test. The parameters estimated from the field test are consistent with values measured independently in laboratory experiments using field samples of similar lithology. From the interpretation, we compute the TCE and DP concentration distributions in the rock matrix prior to the test to illustrate how the results can be used to enhance understanding of contaminant distribution in the rock matrix.

Groundwater Monitoring and Remediation↗
USGS2023

A Monte-Carlo chemical budget approach to assess ambient groundwater flow in bedrock open boreholes

In low-permeability rocks, ambient groundwater flow in open boreholes may go undetected using conventional borehole-flowmeter tools and alternative approaches may be needed to identify flow. Understanding ambient flow in open boreholes is important for tracking of cross contamination in groundwater. Chlorinated volatile organic compound (CVOC) concentrations from three open boreholes set in a crystalline-rock aquifer (two of three open boreholes) and a siltstone aquifer (one of three open boreholes) were examined using a new approach and associated software program called the AFCE (Aqueous-Flow-Concentration-Estimator). The program allows comparison of coupled chemical datasets through a Monte-Carlo simulation and a chemical-budget approach to assess ambient groundwater flow in open boreholes. The coupled datasets required for the comparison include aqueous CVOC concentrations from groundwater samples from (1) discrete fractures, such as those measured from temporary deployment of straddle-borehole packer assemblies; and (2) the concentration of the open borehole (wellbore) water, as measured by a vertical profile of passive samplers from within the same open borehole. Because results from the passive samplers represent a composite mixture of the results from the discrete samples under ambient groundwater-flow conditions, potentially at unknown proportions, the comparison between coupled datasets affords the ability to discern likely water contributions of CVOC from discrete fractures (or fracture zones), and which fractures may be dominating the water chemistry of the open borehole.

Groundwater Monitoring and Remediation↗
USGS2007

Theory, construction and operation of simple tensiometers

The tensiometer, introduced by Richards and Gardner (1936) has been a tool often ignored in unsaturated zone investigations. Hazardous waste disposal studies that require values of unsaturated zone matric potentials will expand tensiometer use. Familiarity with operation and installation principles is necessary to ensure quality data collection. The essential elements of a tensiometer are a porous cup connected with tubing to a vacuum gauge; all are filled with water. When the porous cup is buried in unsaturated soil, the soil draws water through the cup wall, until the water tension inside the cup equals the surrounding soil-water tension. The tension is transmitted through the water filled tube to an accessible vacuum gauge (manometer or transducer) and is recorded manually or automatically. Although specialized tensiometers exist, the tensiometer presented here in detail is suited to diverse on-site applications. Constructed from readily available, inexpensive parts, it can measure as much as 0.85 bar of tension. Design features include a flushing system for removal of entrapped air or mercury, and an easily maintained modular network of nylon manometers and water-supply tubes. Good hydraulic connection between porous cup and soil and meticulous backfill procedures are necessary for accurate measurement of representative matric potentials. Proper and consistent use of tensiometers should yield reliable values of matric potentials, and lead to a better understanding of unsaturated zone processes.

Groundwater Monitoring and Remediation↗
USGS2025

Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida

In-situ chemical oxidation (ISCO) is a common method to remediate chlorinated ethene contaminants in groundwater. Monitoring the effectiveness of ISCO can be hindered because of insufficient observations to assess oxidant delivery. Advantageously, potassium permanganate, one type of oxidant, provides the opportunity to use its strong electrical signal as a surrogate to track oxidant delivery using time-series borehole geophysical methods, like electromagnetic (EM) induction logging. Here we report a passive ISCO (P-ISCO) experiment, using potassium permanganate cylinders emplaced in boreholes, at a chlorinated ethene contamination site, Naval Air Station Pensacola, Florida. The contaminants are found primarily at the base of a shallow sandy aquifer in contact with an underlying silty-clay confining bed. We used results of the time-series borehole logging collected between 2017 and 2022 in 4 monitoring wells to track oxidant delivery. The EM-induction logs from the monitoring wells showed an increase in EM response primarily along the contact, likely from pooling of the oxidant, during P-ISCO treatment in 2021. Interestingly, concurrent natural gamma-ray (NGR) logging showed a decrease in NGR response at 3 of the 4 wells possibly from the formation of manganese precipitates coating sediments. The coupling of time-series logging and well-chemistry data allowed for an improved assessment of passive ISCO treatment effectiveness.

Florida↗
USGS2025

Geochemical and hydrological investigations of historical data collected at the Lee Acres Landfill and Giant Bloomfield Refinery, New Mexico, 1985–2020

The Lee Acres Landfill and Giant Bloomfield Refinery are adjacent properties near the City of Farmington, New Mexico, each having undergone monitoring and remediation related to historical site activities. At the landfill, site cleanup has included the installation of a capillary barrier over former liquid waste lagoons and periodic monitoring of groundwater elevations and groundwater quality. At the refinery, remediation has focused on several petrochemical and crude oil release areas and included soil excavation, groundwater treatment, and regular monitoring of groundwater elevations and quality. Groundwater at both sites has higher concentrations of volatile organic compounds and trace metals than background aquifer concentrations. In 2022, the U.S. Geological Survey compiled the Lee Acres-Giant Bloomfield Refinery Database (LAGBRD), which contains publicly available groundwater-elevation data and organic and inorganic groundwater-quality data from both sites, spanning from 1985 to 2020. Data from the LAGBRD and precipitation data from other sources were used to better understand the cause of relatively high manganese concentrations observed in some groundwater wells at the site through comparison of groundwater chemistry to chemical end members, interpretation of spatial and temporal patterns in the groundwater chemistry, and interpretation of groundwater flow properties. In this study, elevated chloride concentrations in groundwater downgradient from the landfill have been attributed to landfill leachate based on the temporal and spatial variability of chloride concentrations and chloride-to-bromide ratios. Installation of a capillary barrier and surface-water runoff controls at the landfill in 2005 appears to have altered infiltration patterns at that site, resulting in a decrease in chloride at some wells but an increase in chloride and dissolved manganese at others. The timing and relation among groundwater elevation, chloride concentration, and manganese concentration suggest that leachate stored in the vadose zone provides a continued source of contamination to groundwater.

New Mexico↗
USGS2004

Natural Attenuation Software (NAS): A computer program for estimating remediation times of contaminated groundwater

This paper describes the development and application of a modeling system called Natural Attenuation Software (NAS). NAS was designed as a screening tool to estimate times of remediation (TORs), associated with monitored natural attenuation (MNA), to lower groundwater contaminant concentrations to regulatory limits. Natural attenuation processes that NAS models include advection, dispersion, sorption, biodegradation, and non-aqueous phase liquid (NAPL) dissolution. This paper discusses the three main interactive components of NAS: 1) estimation of the target source concentration required for a plume extent to contract to regulatory limits, 2) estimation of the time required for NAFL contaminants in the source area to attenuate to a predetermined target source concentration, and 3) estimation of the time required for a plume extent to contract to regulatory limits after source reduction. The model's capability is illustrated by results from a case study at a MNA site, where NAS time of remediation estimates compared well with observed monitoring data over multiple years.

Conference Paper↗
USGS2015

Hydrogeologic characterization and assessment of bioremediation of chlorinated benzenes and benzene in wetland areas, Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2009-12

Wetlands at the Standard Chlorine of Delaware, Inc. Superfund Site (SCD) in New Castle County, Delaware, are affected by contamination with chlorobenzenes and benzene from past waste storage and disposal, spills, leaks, and contaminated groundwater discharge. In cooperation with the U.S. Environmental Protection Agency, the U.S. Geological Survey began an investigation in June 2009 to characterize the hydrogeology and geochemistry in the wetlands and assess the feasibility of monitored natural attenuation and enhanced bioremediation as remedial strategies. Groundwater flow in the wetland study area is predominantly vertically upward in the wetland sediments and the underlying aquifer, and groundwater discharge accounts for a minimum of 47 percent of the total discharge for the subwatershed of tidal Red Lion Creek. Thus, groundwater transport of contaminants to surface water could be significant. The major contaminants detected in groundwater in the wetland study area included benzene, monochlorobenzene, and tri- and di-chlorobenzenes. Shallow wetland groundwater in the northwest part of the wetland study area was characterized by high concentrations of total chlorinated benzenes and benzene (maximum about 75,000 micrograms per liter [μg/L]), low pH, and high chloride. In the northeast part of the wetland study area, wetland groundwater had low to moderate concentrations of total chlorinated benzenes and benzene (generally not greater than 10,000 μg/L), moderate pH, and high sulfate concentrations. Concentrations in the groundwater in excess of 1 percent of the solubility of the individual chlorinated benzenes indicate that a contaminant source is present in the wetland sediments as dense nonaqueous phase liquids (DNAPLs). Consistently higher contaminant concentrations in the shallow wetland groundwater than deeper in the wetland sediments or the aquifer also indicate a continued source in the wetland sediments, which could include dissolution of DNAPLs and desorption from the sediments. When highly reducing, methanogenic, or sulfate-reducing conditions existed in the wetland groundwater, molar composition of the volatile organic compounds (VOCs) showed that chlorobenzene and benzene were predominant, indicating biodegradation of the chlorinated benzenes through reductive dechlorination pathways. Temporal changes in redox conditions between 2009 and 2011–12 have shifted the locations in the wetland study area where reductive dechlorination is evident. Microbial community analyses of sediment showed relatively high cell numbers and diversity of populations ( Dehalococcoides , Dehalobacter , Desulfitobacterium , and Geobacter ) that are known to contain species capable of reductive dechlorination, confirming groundwater geochemistry evidence of the occurrence of reductive dechlorination. Natural attenuation was not sufficient, however, to reduce total VOC concentrations along upward groundwater flowpaths in the wetland sediments, most likely due to the additional source of contaminants in the upper sediments. In situ microcosms that were unamended except for the addition of 13 C-labeled contaminants in some treatments, confirmed that the native microbial community was able to biodegrade the higher chlorinated benzenes through reductive dechlorination and that 1,2-dichlorobenzene, chlorobenzene, and benzene could be degraded to carbon dioxide through oxidation pathways. Microcosms that were bioaugmented with the anaerobic dechlorinating consortium WBC-2 and deployed in the wetland sediments showed reductive dechlorination of tri-, di-, and monochlorobenzene, and 13 C-chlorobenzene treatments showed complete degradation of chlorobenzene to carbon dioxide under anaerobic conditions. Experiments with a continuous flow, fixed-film bioreactor seeded with native microorganisms in groundwater from the wetland area showed both aerobic and anaerobic biodegradation of dichlorobenzenes, monochlorobenzene, and benzene, although monochlorobenzene and benzene degradation rates decreased under anaerobic conditions compared to aerobic conditions. In two bioreactors with established biofilms of WBC-2, percent removals of all chlorinated benzene compounds (medians of 86 to 94 percent) under anaerobic conditions were as high as those observed for the bioreactors seeded only with native microorganisms from the site groundwater, and benzene removal was greater in the WBC-2 bioaugmented bioreactors. The high percent removals in the WBC-2 bioreactors without the need for an acclimation period indicates that the same dechlorinators are involved in the chlorinated benzene degradation as those for the chlorinated ethanes and ethenes that the culture was developed to degrade. The ability of the WBC-2 culture to completely reduce the chlorinated benzenes and benzene, even in the presence of high sulfate and sulfide concentrations, is unique for known dechlorinating cultures. The availability of the established culture WBC-2, as well as the ability of the native wetland microbial community to degrade the site contaminants under anaerobic and aerobic conditions, provides flexibility in considering bioremediation options for the wetland areas at SCD.

Delaware↗
USGS2014

Time-lapse electrical geophysical monitoring of amendment-based biostimulation

Biostimulation is increasingly used to accelerate microbial remediation of recalcitrant groundwater contaminants. Effective application of biostimulation requires successful emplacement of amendment in the contaminant target zone. Verification of remediation performance requires postemplacement assessment and contaminant monitoring. Sampling-based approaches are expensive and provide low-density spatial and temporal information. Time-lapse electrical resistivity tomography (ERT) is an effective geophysical method for determining temporal changes in subsurface electrical conductivity. Because remedial amendments and biostimulation-related biogeochemical processes often change subsurface electrical conductivity, ERT can complement and enhance sampling-based approaches for assessing emplacement and monitoring biostimulation-based remediation. Field studies demonstrating the ability of time-lapse ERT to monitor amendment emplacement and behavior were performed during a biostimulation remediation effort conducted at the Department of Defense Reutilization and Marketing Office (DRMO) Yard, in Brandywine, Maryland, United States. Geochemical fluid sampling was used to calibrate a petrophysical relation in order to predict groundwater indicators of amendment distribution. The petrophysical relations were field validated by comparing predictions to sequestered fluid sample results, thus demonstrating the potential of electrical geophysics for quantitative assessment of amendment-related geochemical properties. Crosshole radar zero-offset profile and borehole geophysical logging were also performed to augment the data set and validate interpretation. In addition to delineating amendment transport in the first 10 months after emplacement, the time-lapse ERT results show later changes in bulk electrical properties interpreted as mineral precipitation. Results support the use of more cost-effective surface-based ERT in conjunction with limited field sampling to improve spatial and temporal monitoring of amendment emplacement and remediation performance.

Maryland↗
USGS2015

Screening tool to evaluate the vulnerability of down-gradient receptors to groundwater contaminants from uncapped landfills

A screening tool for quantifying levels of concern for contaminants detected in monitoring wells on or near landfills to down-gradient receptors (streams, wetlands and residential lots) was developed and evaluated. The tool uses Quick Domenico Multi-scenario (QDM), a spreadsheet implementation of Domenico-based solute transport, to estimate concentrations of contaminants reaching receptors under steady-state conditions from a constant-strength source. Unlike most other available Domenico-based model applications, QDM calculates the time for down-gradient contaminant concentrations to approach steady state and appropriate dispersivity values, and allows for up to fifty simulations on a single spreadsheet. Sensitivity of QDM solutions to critical model parameters was quantified. The screening tool uses QDM results to categorize landfills as having high, moderate and low levels of concern, based on contaminant concentrations reaching receptors relative to regulatory concentrations. The application of this tool was demonstrated by assessing levels of concern (as defined by the New Jersey Pinelands Commission) for thirty closed, uncapped landfills in the New Jersey Pinelands National Reserve, using historic water-quality data from monitoring wells on and near landfills and hydraulic parameters from regional flow models. Twelve of these landfills are categorized as having high levels of concern, indicating a need for further assessment. This tool is not a replacement for conventional numerically-based transport model or other available Domenico-based applications, but is suitable for quickly assessing the level of concern posed by a landfill or other contaminant point source before expensive and lengthy monitoring or remediation measures are taken. In addition to quantifying the level of concern using historic groundwater-monitoring data, the tool allows for archiving model scenarios and adding refinements as new data become available.

New Jersey↗