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At least 307 records · Page 17Linked to original sources
USGS2008

Response of macroinvertebrate communities to remediation-simulating conditions in Pennsylvania streams influenced by acid mine drainage

We compared naturally alkaline streams with limestone lithology to freestone streams with and without acid mine drainage (AMD) to predict benthic macroinvertebrate community recovery from AMD in limestone-treated watersheds. Surrogate-recovered (limestone) and, in many cases, freestone systems had significantly higher macroinvertebrate densities; diversity; taxa richness; Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa; EPT/chironomid ratios; scraper/collector - gatherer ratios; herbivores; collector - filterers; and scrapers. AMD-influenced systems had significantly greater numbers of Diptera and collector - gatherers. An entire trophic level (herbivores) was 'restored' in surrogate-recovered streams, which also showed greater trophic specialization. Indicator analysis identified seven taxa (within Crustacea, Diptera, Nematoda, Trichoptera, and Ephemeroptera) as significant indicators of limestone systems and six taxa (within Ephemeroptera, Plecoptera, Tricoptera, Coleoptera, and Mollusca) as significant freestone indicators, all useful as biological indicators of recovery from AMD. ?? Springer Science+Business Media B.V. 2007.

Environmental Monitoring and Assessment↗
USGS2022

Temperature variations in the northern Gulf of Alaska across synoptic to century-long time scales

Surface and subsurface moored buoy, ship-based, remotely sensed, and reanalysis datasets are used to investigate thermal variability of northern Gulf of Alaska (NGA) nearshore, coastal, and offshore waters over synoptic to century-long time scales. NGA sea surface temperature (SST) showed a larger positive trend of 0.22 ± 0.10 °C per decade over 1970–2021 compared to 0.10 ± 0.03 °C per decade over 1900–2021. Over synoptic time scales, SST covariance between two stations is small (<10%) when separation exceeds 100 km, while stations separated by 500 km retain 50% of their co-variability for seasonal and longer fluctuations. Relative to in situ sensor data, remotely sensed SST data has limited accuracy in some NGA settings, capturing 60–70% of the daily SST anomaly in coastal and offshore waters, but often <25% nearshore. North Pacific and NGA leading modes of SST variability leave 25–50% of monthly variance unresolved. Analysis of the 2014–2016 Pacific marine heatwave shows that NGA coastal surface temperatures warmed contemporaneously with offshore waters through 2013, but deep inner shelf waters (200–250 m) exhibited delayed warming. Offshore surface waters cooled from 2014 to 2016, while shelf waters continued to warm from the combined effects of local air-sea and advective heat fluxes. We find that annually averaged Sitka air temperature is a leading predictor (r 2 = 0.37, p < 0.05) for following-year NGA coastal water column temperature. Our results can inform future environmental monitoring designs, assist forward-looking projections of marine conditions, and show the importance of in situ measurements for nearshore studies that require knowledge of thermal conditions over time scales of days and weeks.

Alaska↗
USGS2011

Geologic map of Big Bend National Park, Texas

The purpose of this map is to provide the National Park Service and the public with an updated digital geologic map of Big Bend National Park (BBNP). The geologic map report of Maxwell and others (1967) provides a fully comprehensive account of the important volcanic, structural, geomorphological, and paleontological features that define BBNP. However, the map is on a geographically distorted planimetric base and lacks topography, which has caused difficulty in conducting GIS-based data analyses and georeferencing the many geologic features investigated and depicted on the map. In addition, the map is outdated, excluding significant data from numerous studies that have been carried out since its publication more than 40 years ago. This report includes a modern digital geologic map that can be utilized with standard GIS applications to aid BBNP researchers in geologic data analysis, natural resource and ecosystem management, monitoring, assessment, inventory activities, and educational and recreational uses. The digital map incorporates new data, many revisions, and greater detail than the original map. Although some geologic issues remain unresolved for BBNP, the updated map serves as a foundation for addressing those issues. Funding for the Big Bend National Park geologic map was provided by the United States Geological Survey (USGS) National Cooperative Geologic Mapping Program and the National Park Service. The Big Bend mapping project was administered by staff in the USGS Geology and Environmental Change Science Center, Denver, Colo. Members of the USGS Mineral and Environmental Resources Science Center completed investigations in parallel with the geologic mapping project. Results of these investigations addressed some significant current issues in BBNP and the U.S.-Mexico border region, including contaminants and human health, ecosystems, and water resources. Funding for the high-resolution aeromagnetic survey in BBNP, and associated data analyses and interpretation, was from the USGS Crustal Geophysics and Geochemistry Science Center. Mapping contributed from university professors and students was mostly funded by independent sources, including academic institutions, private industry, and other agencies.

Texas↗
USGS2018

Temporal trends in water-quality constituent concentrations and annual loads of chemical constituents in Michigan watersheds, 1998–2013

In 1998, the Michigan Department of Environmental Quality and the U.S. Geological Survey began the Water Chemistry Monitoring Program for select streams in the State of Michigan. Objectives of this program were to provide assistance with (1) statewide water-quality assessments, (2) the National Pollutant Discharge Elimination System permitting process, and (3) water-resource management decisions. As part of this program, water-quality data collected from 1998 to 2013 were analyzed to identify potential trends for select constituents that were sampled. Sixteen water-quality constituents were analyzed at 32 stations throughout Michigan. Trend analysis on the various water-quality data was done using either the uncensored Seasonal Kendall test or through Tobit regression. In total, 79 trends were detected in the constituents analyzed for 32 river stations sampled for the study period—53 downward trends and 26 upward trends were detected. The most prevalent trend detected throughout the State was for ammonia, with 11 downward trends and 1 upward trend estimated. In addition to trends, constituent loads were estimated for 31 stations from 2002 to 2013 for stations that were sampled 12 times per year. Loads were computed using the Autobeale load computation program, which used the Beale ratio estimator approach to estimate an annual load. Constituent loads were the largest in large watershed streams with the highest annual flows such as the Saginaw and Grand Rivers. Likewise, constituent loads were the smallest in smaller tributaries that were sampled as part of this program such as the Boardman and Thunder Bay Rivers.

Michigan↗
USGS2014

Ecoregions of Arizona (poster)

Ecoregions denote areas of general similarity in ecosystems and in the type, quality, and quantity of environmental resources; they are designed to serve as a spatial framework for the research, assessment, management, and monitoring of ecosystems and ecosystem components. By recognizing the spatial differences in the capacities and potentials of ecosystems, ecoregions stratify the environment by its probable response to disturbance. These general purpose regions are critical for structuring and implementing ecosystem management strategies across federal agencies, state agencies, and nongovernment organizations that are responsible for different types of resources within the same geographical areas. The Arizona ecoregion map was compiled at a scale of 1:250,000. It revises and subdivides an earlier national ecoregion map that was originally compiled at a smaller scale. The approach used to compile this map is based on the premise that ecological regions can be identified through the analysis of the spatial patterns and the composition of biotic and abiotic phenomena that affect or reflect differences in ecosystem quality and integrity. These phenomena include geology, physiography, vegetation, climate, soils, land use, wildlife, and hydrology. The relative importance of each characteristic varies from one ecological region to another regardless of the hierarchical level. A Roman numeral hierarchical scheme has been adopted for different levels of ecological regions. Level I is the coarsest level, dividing North America into 15 ecological regions. Level II divides the continent into 50 regions. At level III, the continental United States contains 105 ecoregions and the conterminous United States has 85 ecoregions. Level IV is a further subdivision of level III ecoregions. Arizona contains arid deserts and canyonlands, semiarid shrub- and grass-covered plains, woodland- and shrubland-covered hills, lava fields and volcanic plateaus, forested mountains, glaciated peaks, and river alluvial floodplains. Ecological diversity is remarkably high. There are 7 level III ecoregions and 52 level IV ecoregions in Arizona and many continue into ecologically similar parts of adjacent states. This poster is part of a collaborative project primarily between the U.S. Geological Survey (USGS), USEPA National Health and Environmental Effects Research Laboratory (Corvallis, Oregon), USEPA Region IX, U.S. Department of Agriculture (USDA)–Natural Resources Conservation Service (NRCS), The Nature Conservancy, and several Arizona state agencies. The project is associated with an interagency effort to develop a common national framework of ecological regions. Reaching that objective requires recognition of the differences in the conceptual approaches and mapping methodologies applied to develop the most common ecoregion-type frameworks, including those developed by the USDA–Forest Service, the USEPA, and the NRCS. As each of these frameworks is further refined, their differences are becoming less discernible. Collaborative ecoregion projects, such as this one in Arizona, are a step toward attaining consensus and consistency in ecoregion frameworks for the entire nation.

Arizona↗
USGS2005

Distribution and density of moose in relation to landscape characteristics: Effects of scale

We analyzed the relation between early winter distribution and density of female moose (Alces alces L.) and habitat heterogeneity in interior Alaska. We tested for effects of vegetation type, topography, distance to rivers and towns, occurrence and timing of fire, and landscape metrics. A spatial linear model was used to analyze effects of independent variables organized at multiple scales. Because densities of moose vary widely as a result of differences in management and other factors, a spatial response surface of the log of moose density was fit to remove large-scale effects. The analysis revealed that the densest populations of moose occurred closer to towns, at moderate elevations, near rivers, and in areas where fire occurred between 11 and 30 years ago. Furthermore, moose tended to occur in areas with large compact patches of varied habitat and avoided variable terrain and nonvegetated areas. Relationships of most variables with moose density occurred at or below 34 km2, suggesting that moose respond to environmental variables within a few kilometres of their location. The spatial model of density of moose developed in this study represents an important application for effective monitoring and management of moose in the boreal forest. ?? 2005 NRC.

Conference Paper↗
USGS2007

Geochemical effects of induced stream-water and artificial recharge on the Equus Beds Aquifer, South-Central Kansas, 1995-2004

Artificial recharge of the Equus Beds aquifer is part of a strategy implemented by the city of Wichita, Kansas, to preserve future water supply and address declining water levels in the aquifer of as much as 30 feet caused by withdrawals for water supply and irrigation since the 1940s. Water-level declines represent a diminished water supply and also may accelerate migration of saltwater from the Burrton oil field to the northwest and the Arkansas River to the southwest into the freshwater of the Equus Beds aquifer. Artificial recharge, as a part of the Equus Beds Ground-Water Recharge Project, involves capturing flows larger than base flow from the Little Arkansas River and recharging the water to the Equus Beds aquifer by means of infiltration or injection. The geochemical effects on the Equus Beds aquifer of induced stream-water and artificial recharge at the Halstead and Sedgwick sites were determined through collection and analysis of hydrologic and water-quality data and the application of statistical, mixing, flow and solute-transport, and geochemical model simulations. Chloride and atrazine concentrations in the Little Arkansas River and arsenic concentrations in ground water at the Halstead recharge site frequently exceeded regulatory criteria. During 30 percent of the time from 1999 through 2004, continuous estimated chloride concentrations in the Little Arkansas River at Highway 50 near Halstead exceeded the Secondary Drinking-Water Regulation of 250 milligrams per liter established by the U.S. Environmental Protection Agency. Chloride concentrations in shallow monitoring wells located adjacent to the stream exceeded the drinking-water criterion five times from 1995 through 2004. Atrazine concentrations in water sampled from the Little Arkansas River had large variability and were at or near the drinking-water Maximum Contaminant Level of 3.0 micrograms per liter as an annual average established by the U.S. Environmental Protection Agency. Atrazine concentrations were much smaller than the drinking-water criterion and were detected at much smaller concentrations in shallow monitoring wells and diversion well water located adjacent to the stream probably because of sorption on aquifer sediment. Before and after artificial recharge, large, naturally occurring arsenic concentrations in the recharge water for the Halstead diversion well and recharge site exceeded the Maximum Contaminant Level of 10 micrograms per liter established by the U.S. Environmental Protection Agency for drinking water. Arsenic and iron concentrations decreased when water was recharged through recharge basins or a trench; however, chemical precipitation and potential biofouling eventually may decrease the artificial recharge efficiency through basins and trenches. At the Sedgwick site, chloride concentrations infrequently exceeded regulatory criteria. Large concentrations of atrazine were treated to decrease concentrations to less than regulatory criteria. Recharge of treated stream water through recharge basins avoids potentially large concentrations of arsenic and iron that exist at the Halstead diversion site. Results from a simple mixing model using chloride as a tracer indicated that the water chemistry in shallow monitoring well located adjacent to the Little Arkansas River was 80 percent of stream water, demonstrating effective recharge of the alluvial aquifer by the stream. Results also indicated that about 25 percent of the water chemistry of the diversion well water was from the shallow part of the aquifer. Additionally, diverting water through a diversion well located adjacent to the stream removed about 75 percent of the atrazine, probably through sorption to aquifer sediment, and decreased the need for additional water treatment to remove atrazine.

Kansas↗
USGS2023

Interaction of a legacy groundwater contaminant plume with the Little Wind River from 2015 through 2017, Riverton Processing site, Wyoming

The Riverton Processing site was a uranium mill 4 kilometers southwest of Riverton, Wyoming, that prepared uranium ore for nuclear reactors and weapons from 1958 to 1963. The U.S. Department of Energy completed surface remediation of the uranium tailings in 1989; however, groundwater below and downgradient from the tailings site and nearby Little Wind River was not remediated. Beginning in 2010, a series of floods along the Little Wind River began to mobilize contaminants in the unsaturated zone, resulting in substantial increases of uranium and other contaminants of concern in monitoring wells completed inside the contaminant plume. In 2011, the U.S. Department of Energy started a series of university and Government agency retrospective and field investigations to understand the processes controlling contaminant increases in the groundwater plume. The goals of the field investigations described in this report were to (1) identify and quantify the contaminant flux and potential associated biological effects from groundwater associated with the legacy plume as it enters a perennial stream reach, and (2) assess chemical exposure and potential effects to biological receptors from the interaction of the contaminant plume and the river. Field investigations along the Little Wind River were completed by the U.S. Geological Survey during 2015–17 in cooperation with the U.S. Department of Energy Office of Legacy Management to characterize: (1) seepage areas and seepage rates; (2) pore-water and bed sediment chemistry and hyporheic exchange and reactive loss; and (3) exposure pathways and biological receptors. All data collected during the study are contained in two U.S. Geological Survey data releases, available at https://doi.org/10.5066/F7BR8QX4 and https://doi.org/10.5066/P9J9VJBR . A variety of tools and methods were used during the field characterizations. Streambed temperature mapping, electrical resistivity tomography, electromagnetic induction, fiber-optic distributed temperature sensing, tube seepage meters, vertical thermal sensor arrays, and an environmental tracer (radon) were used to identify areas of groundwater seepage and associated seepage rates along specific sections of the study reach of the river. Drive points, minipiezometers, diffusive equilibrium in thin-film/diffusive gradients in thin-film probes, bed-sediment samples, and equal discharge increment sampling methods were used to characterize pore-water chemistry, estimate hyporheic exchange and reactive loss of selected chemical constituents, and quantify contaminant loadings entering the study reach. Sampling and analysis of surface sediments, filamentous algae, periphytic algae, and macroinvertebrates were used to characterize biological exposure pathways, metal uptake, and receptors. Areas of focused groundwater discharge identified by the fiber-optic distributed temperature sensing surveys corresponded closely with areas of elevated electrical conductivity identified by the electromagnetic induction survey results in the top 5 meters of sediment. During three monitoring periods in 2016, the mean vertical seepage rate measured with tube seepage meters was 0.45 meter per day, ranging from −0.02 to 1.55 meters per day. Five of the 11 locations where vertical thermal profile data were collected along the study reach during August 2017 indicated mean upwelling values ranging from 0.11 to 0.23 meter per day. Radon data collected from the Little Wind River during June, July, and August 2016 indicated a consistent inflow of groundwater to the central part of the study reach, in the area congruous with the center of the previously mapped groundwater plume discharge zone. During August 2017, the greatest attenuation of uranium from reactive loss in pore-water samples was observed at three locations along the study reach, at depths between 6 and 15 centimeters, and similar trends in molybdenum attenuation were also observed. Bed-sediment concentration profiles collected during 2017 also indicated attenuation of uranium and molybdenum from groundwater during hyporheic mixing of surface water with the legacy plume during groundwater upwelling into the river. Streamflow measurements combined with equal discharge increment water sampling along the study reach indicated an increase in dissolved uranium concentrations in the downstream direction during 2016 and 2017. Net uranium load entering the Little Wind River study reach was about 290 and 435 grams per day during 2016 and 2017, respectively. Biological samples indicated that low levels of uranium and molybdenum exposure were confined to the benthos in the Little Wind River within and immediately downstream from the perimeter of the groundwater plume. Concentrations of molybdenum and uranium in filamentous algae were consistently low at all sites in the study reach with no indication of increased exposure of dissolved bioavailable molybdenum or uranium at sites next to or downstream from the groundwater plume. Comparison of the August 2017 results from electromagnetic induction, tube seepage meters, vertical thermal profiling, and pore-water chemistry surveys were in general agreement in identifying areas with upwelling groundwater conditions along the study reach. However, the electroconductivity values measured with electromagnetic induction in the top 100 centimeters of sediment did not agree with sodium concentrations measured in pore-water samples collected at similar streambed depths. Differences and similarities between multiple methods can result in additional insights into hydrologic and biogeochemical processes that may be occurring along a reach of a river system interacting with shallow groundwater inputs. It may be advantageous to apply a variety of geophysical, geochemical, hydrologic, and biological tools at other Uranium Mill Tailings Remedial Action ( https://www.energy.gov/sites/prod/files/2014/10/f19/UMTRCA.pdf ) sites during the investigation of legacy contaminant plume interactions with surface-water systems.

Wyoming↗
USGS1984

Isotope composition of sulphate in acid mine drainage as measure of bacterial oxidation

The formation of acid waters by oxidation of pyrite-bearing ore deposits, mine tailing piles, and coal measures is a complex biogeochemical process and is a serious environmental problem. We have studied the oxygen and sulphur isotope geochemistry of sulphides, sulphur, sulphate and water in the field and in experiments to identify sources of oxygen and reaction mechanisms of sulphate formation. Here we report that the oxygen isotope composition of sulphate in acid mine drainage shows a large variation due to differing proportions of atmospheric- and water-derived oxygen from both chemical and bacterially-mediated oxidation. 18O-enrichment of sulphate results from pyrite oxidation facilitated by Thiobacillus ferrooxidans in aerated environments. Oxygen isotope analysis may therefore be useful in monitoring the effectiveness of abatement programmes designed to inhibit bacterial oxidation. Sulphur isotopes show no significant fractionation between pyrite and sulphate, indicating the quantitative insignificance of intermediate oxidation states of sulphur under acid conditions.

Nature↗
USGS2010

Hydrologic Data for Deep Creek Lake and Selected Tributaries, Garrett County, Maryland, 2007-08

Introduction Recent and ongoing efforts to develop the land in the area around Deep Creek Lake, Garrett County, Maryland, are expected to change the volume of sediment moving toward and into the lake, as well as impact the water quality of the lake and its many tributaries. With increased development, there is an associated increased demand for groundwater and surface-water withdrawals, as well as boat access. Proposed dredging of the lake bottom to improve boat access has raised concerns about the adverse environmental effects such activities would have on the lake. The Maryland Department of Natural Resources (MDDNR) and the U.S. Geological Survey (USGS) entered into a cooperative study during 2007 and 2008 to address these issues. This study was designed to address several objectives to support MDDNR?s management strategy for Deep Creek Lake. The objectives of this study were to: Determine the current physical shape of the lake through bathymetric surveys; Initiate flow and sediment monitoring of selected tributaries to characterize the stream discharge and sediment load of lake inflows; Determine sedimentation rates using isotope analysis of sediment cores; Characterize the degree of hydraulic connection between the lake and adjacent aquifer systems; and Develop an estimate of water use around Deep Creek Lake. Summary of Activities Data were collected in Deep Creek Lake and in selected tributaries from September 2007 through September 2008. The methods of investigation are presented here and all data have been archived according to USGS policy for future use. The material presented in this report is intended to provide resource managers and policy makers with a broad understanding of the bathymetry, surface water, sedimentation rates, groundwater, and water use in the study area. The report is structured so that the reader can access each topic separately using any hypertext markup (HTML) language reader. In order to establish a base-line water-depth map of Deep Creek Lake, a bathymetric survey of the lake bottom was conducted in 2007. The data collected were used to generate a bathymetric map depicting depth to the lake bottom from a full pool elevation of 2,462 feet (National Geodetic Vertical Datum of 1929). Data were collected along about 90 linear miles across the lake using a fathometer and a differentially corrected global positioning system. As part of a long-term monitoring plan for all surface-water inputs to the lake, streamflow data were collected continuously at two stations constructed on Poland Run and Cherry Creek. The sites were selected to represent areas of the watershed under active development and areas that are relatively stable with respect to development. Twelve months of discharge data are provided for both streams. In addition, five water-quality parameters were collected continuously at the Poland Run station including pH, specific conductance, temperature, dissolved oxygen, and turbidity. Water samples collected at Poland Run were analyzed for sediment concentration, and the results of this analysis were used to estimate the annual sediment load into Deep Creek Lake from Poland Run. To determine sedimentation rates, cores of lake-bottom sediments were collected at 23 locations. Five of the cores were analyzed using a radiometric-dating method, allowing average rates of sedimentation to be estimated for the time periods 1925 to 2008, 1925 to 1963, and 1963 to 2008. Particle-size data from seven cores collected at locations throughout the study area were analyzed to provide information on the amount of fine material in lake-bed sediments. Groundwater levels were monitored continuously in four wells and weekly in nine additional wells during October, November, and December of 2008. Water levels were compared to recorded lake levels and precipitation during the same period to determine the effect of lake-level drawdown and recovery on the adjacent aquifer systems. Water use in the Deep Creek Lake wa

Open-File Report↗
USGS2016

Discharge, water temperature, and water quality of Warm Mineral Springs, Sarasota County, Florida: A retrospective analysis

Warm Mineral Springs, located in southern Sarasota County, Florida, is a warm, highly mineralized, inland spring. Since 1946, a bathing spa has been in operation at the spring, attracting vacationers and health enthusiasts. During the winter months, the warm water attracts manatees to the adjoining spring run and provides vital habitat for these mammals. Well-preserved late Pleistocene to early Holocene-age human and animal bones, artifacts, and plant remains have been found in and around the spring, and indicate the surrounding sinkhole formed more than 12,000 years ago. The spring is a multiuse resource of hydrologic importance, ecological and archeological significance, and economic value to the community. The pool of Warm Mineral Springs has a circular shape that reflects its origin as a sinkhole. The pool measures about 240 feet in diameter at the surface and has a maximum depth of about 205 feet. The sinkhole developed in the sand, clay, and dolostone of the Arcadia Formation of the Miocene-age to Oligocene-age Hawthorn Group. Underlying the Hawthorn Group are Oligocene-age to Eocene-age limestones and dolostones, including the Suwannee Limestone, Ocala Limestone, and Avon Park Formation. Mineralized groundwater, under artesian pressure in the underlying aquifers, fills the remnant sink, and the overflow discharges into Warm Mineral Springs Creek, to Salt Creek, and subsequently into the Myakka River. Aquifers described in the vicinity of Warm Mineral Springs include the surficial aquifer system, the intermediate aquifer system within the Hawthorn Group, and the Upper Floridan aquifer in the Suwannee Limestone, Ocala Limestone, and Avon Park Formation. The Hawthorn Group acts as an upper confining unit of the Upper Floridan aquifer. Groundwater flow paths are inferred from the configuration of the potentiometric surface of the Upper Floridan aquifer for September 2010. Groundwater flow models indicate the downward flow of water into the Upper Floridan aquifer in inland areas, and upward flow toward the surface in coastal areas, such as at Warm Mineral Springs. Warm Mineral Springs is located in a discharge area. Changes in water use in the region have affected the potentiometric surface of the Upper Floridan aquifer. Historical increase in groundwater withdrawals resulted in a 10- to 20-foot regional decline in the potentiometric surface of the Upper Floridan aquifer by May 1975 relative to predevelopment levels and remained at approximately that level in May 2007 in the area of Warm Mineral Springs. Discharge measurements at Warm Mineral Springs (1942–2014) decreased from about 11–12 cubic feet per second in the 1940s to about 6–9 cubic feet per second in the 1970s and remained at about that level for the remainder of the period of record. Similarity of changes in regional water use and discharge at Warm Mineral Springs indicates that basin-scale changes to the groundwater system have affected discharge at Warm Mineral Springs. Water temperature had no significant trend in temperature over the period of record, 1943–2015, and outliers were identified in the data that might indicate inconsistencies in measurement methods or locations. Within the regional groundwater basin, Warm Mineral Springs is influenced by deep Upper Floridan aquifer flow paths that discharge toward the coast. Associated with these flow paths, the groundwater temperatures increase with depth and toward the coast. Multiple lines of evidence indicate that a source of warm groundwater to Warm Mineral Springs is likely the permeable zone of the Avon Park Formation within the Upper Floridan aquifer at a depth of about 1,400 to 1,600 feet, or deeper sources. The permeable zone contains saline groundwater with water temperatures of at least 95 degrees Fahrenheit. The water quality of Warm Mineral Springs, when compared with other springs in Florida had the highest temperature and the greatest mineralized content. Warm Mineral Springs water is characterized by a slight-green color, with varying water clarity, low dissolved oxygen (indicative of deep groundwater), and a hydrogen sulfide odor. Water-quality samples detected ammonium-nitrogen and nitrates, but at low concentrations. The drinking water standard for nitrate adopted by the U.S. Environmental Protection Agency is 10 milligrams per liter, measured as nitrogen. Water samples collected at spring vents by divers on April 29, 2015, had concentrations of 0.9 milligram per liter nitrate-nitrogen at vent A and 0.04–0.05 milligram per liter at vents B, C, and D. Typically, the water clarity is highest in the morning (about 30 feet Secchi depth) and often decreases throughout the day. Analysis of existing data provided some insight into the hydrologic processes affecting Warm Mineral Springs; however, data have been sparsely and discontinuously collected since the 1940s. Continuous monitoring of hydrologic characteristics such as discharge, water temperature, specific conductance, and water-quality indicators, such as nitrate and turbidity (water clarity), would be valuable for monitoring and development of models of spring discharge and water quality. In addition, water samples could be analyzed for isotopic tracers, such as strontium, and the results used to identify and quantify the sources of groundwater that discharge at Warm Mineral Springs. Groundwater flow/transport models could be used to evaluate the sensitivity of the quality and quantity of water flowing from Warm Mineral Springs to changes in climate, aquifer levels, and water use.

Florida↗
USGS2007

A GIS-based groundwater travel time model to evaluate stream nitrate concentration reductions from land use change

Excessive nitrate-nitrogen (nitrate) loss from agricultural watersheds is an environmental concern. A common conservation practice to improve stream water quality is to retire vulnerable row croplands to grass. In this paper, a groundwater travel time model based on a geographic information system (GIS) analysis of readily available soil and topographic variables was used to evaluate the time needed to observe stream nitrate concentration reductions from conversion of row crop land to native prairie in Walnut Creek watershed, Iowa. Average linear groundwater velocity in 5-m cells was estimated by overlaying GIS layers of soil permeability, land slope (surrogates for hydraulic conductivity and gradient, respectively) and porosity. Cells were summed backwards from the stream network to watershed divide to develop a travel time distribution map. Results suggested that groundwater from half of the land planted in prairie has reached the stream network during the 10 years of ongoing water quality monitoring. The mean travel time for the watershed was estimated to be 10.1 years, consistent with results from a simple analytical model. The proportion of land in the watershed and subbasins with prairie groundwater reaching the stream (10-22%) was similar to the measured reduction of stream nitrate (11-36%). Results provide encouragement that additional nitrate reductions in Walnut Creek are probable in the future as reduced nitrate groundwater from distal locations discharges to the stream network in the coming years. The high spatial resolution of the model (5-m cells) and its simplicity may make it potentially applicable for land managers interested in communicating lag time issues to the public, particularly related to nitrate concentration reductions over time. ?? 2007 Springer-Verlag.

Environmental Geology↗
USGS2024

Analysis of factors affecting plume remediation in a sole-source aquifer system, southeastern Nassau County, New York

Several plumes of dissolved, chlorinated solvents, including trichloroethylene, have been identified in a sole-source aquifer near the former Northrop Grumman Bethpage Facility and Naval Weapons Industrial Reserve Plant sites in southeastern Nassau County, New York. Past investigations have documented that the groundwater contamination originated from this industrial area and now extends to the south, in the direction of groundwater flow. The intermixed plumes are commonly referred to as the “Navy Grumman groundwater plume.” Detailed groundwater-flow modeling was needed for the New York State Department of Environmental Conservation (NYSDEC) to evaluate design options necessary for the construction, operation, optimization, maintenance, and monitoring of a groundwater extraction and treatment cleanup plan selected in a December 2019 Amended Record of Decision by the NYSDEC to comprehensively address these plumes. Consequently, the NYSDEC began a cooperative study with the U.S. Geological Survey in 2020 to better understand the local hydrogeologic framework using two independent approaches to characterize aquifer heterogeneity and update an existing regional groundwater-flow model to provide transient boundary conditions for new inset groundwater-flow models of the plume area. We developed these detailed inset models for the two independent aquifer characterizations using history-matching techniques coupled with a novel approach to risk-based management optimization of the remedial design. We also used the updated regional model to assess this optimized groundwater extraction and treatment design for potential saltwater intrusion. The ensembles of parameters resulting from history matching provided a platform with which to evaluate capture by water-supply and remedial wells using particle-tracking techniques. Using the ensemble to select a risk stance, we performed multiobjective optimization to identify various configurations of remedial pumping that are consistent with external constraints and that favor potentially competing objectives. Multiple solutions provide tradeoffs that NYSDEC can consider. In general, pumping redistribution may help to prevent further contamination migration downgradient. These and other study results are intended to support decisions for the remedial design focused on the local area encompassing the full extent of the Navy Grumman groundwater plume.

New York↗
USGS2005

Freshwater mussel shells as environmental chronicles: Geochemical and taphonomic signatures of mercury-related extirpations in the North Fork Holston River, Virginia

This study utilized freshwater mussel shells to assess mercury (Hg) contamination in the North Fork Holston River that extirpated (caused local extinctions of) a diverse mussel fauna. Shells (n = 366) were collected from five sites situated upstream (two sites), just below (one site), and downstream (two sites) of the town of Saltville, Virginia, where Hg was used to produce chlorine and caustic soda from 1950 to 1972. Shell samples were used to test the (1) utility of geochemical signatures of shells for assessing the spatial variation in Hg levels in the river relative to the contamination source and (2) value of taphonomy (postmortem shell alteration) for distinguishing sites that differ in extirpation histories. Geochemical signatures of 40 shells, analyzed using atomic absorption spectroscopy, indicated a strong longitudinal pattern. All shells from the two upstream sites had low Hg concentrations (<5-31 ??g/kg), shells directly below Saltville had variable, but dramatically higher concentrations (23-4637 ??g/kg), and shells from the two downstream sites displayed intermediate Hg levels (<5-115 ??g/kg) that declined with distance from Saltville. Two pre-industrial shells, collected at Saltville in 1917, yielded very low Hg estimates (5-6 ??g/kg). Hg signatures were consistent among mussel species, suggesting that Hg concentrations were invariant to species type; most likely, highly variable Hg levels, both across sites and through time, overwhelmed any interspecific differences in Hg acquisition. Also, a notable postmortem incorporation of Hg in mussel shells seemed unlikely, as the Hg content was not correlated with shell taphonomy (r = 0.18; p = 0.28). The taphonomic analysis (n = 366) showed that the degree of shell alteration reliably distinguished sites with different extirpation histories. At Saltville, where live mussels have been absent for at least 30 years, shells were most heavily altered and fragmented. Conversely, fresh-looking shells abounded upstream, where reproducing mussel populations are still present. In summary, relic shells offered valuable spatiotemporal data on Hg concentrations in a polluted ecosystem, and shell taphonomic signatures discriminated sites with different extirpation histories. The shell-based strategies exemplified here do not require sampling live specimens and may augment more standard strategies applied to environmental monitoring. The approach should prove especially useful in areas with unknown extirpation and pollution histories. ?? 2005 American Chemical Society.

Environmental Science & Technology↗
USGS2013

The vegetation outlook (VegOut): a new method for predicting vegetation seasonal greenness

The vegetation outlook (VegOut) is a geospatial tool for predicting general vegetation condition patterns across large areas. VegOut predicts a standardized seasonal greenness (SSG) measure, which represents a general indicator of relative vegetation health. VegOut predicts SSG values at multiple time steps (two to six weeks into the future) based on the analysis of "historical patterns" (i.e., patterns at each 1 km grid cell and time of the year) of satellite, climate, and oceanic data over an 18-year period (1989 to 2006). The model underlying VegOut capitalizes on historical climate-vegetation interactions and ocean-climate teleconnections (such as El Niño and the Southern Oscillation, ENSO) expressed over the 18-year data record and also considers several environmental characteristics (e.g., land use/cover type and soils) that influence vegetation's response to weather conditions to produce 1 km maps that depict future general vegetation conditions. VegOut provides regionallevel vegetation monitoring capabilities with local-scale information (e.g., county to sub-county level) that can complement more traditional remote sensing-based approaches that monitor "current" vegetation conditions. In this paper, the VegOut approach is discussed and a case study over the central United States for selected periods of the 2008 growing season is presented to demonstrate the potential of this new tool for assessing and predicting vegetation conditions.

GIScience and Remote Sensing↗
USGS2005

Water-quality trend analysis and sampling design for streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

The Bureau of Reclamation is considering several alternatives to meet the future municipal, rural, and industrial water-supply needs in the Red River of the North (Red River) Basin, and an environmental impact statement is being prepared to evaluate the potential effects of the various alternatives on the water quality and aquatic health in the basin in relation to the historical variability of streamflow and constituent concentration. Therefore, a water-quality trend analysis was needed to determine the amount of natural water-quality variability that can be expected to occur in the basin, to determine if significant water-quality changes have occurred as a result of human activities, to explore potential causal mechanisms for water-quality changes, and to establish a baseline from which to monitor future water-quality trends. This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, to analyze historical water-quality trends in two dissolved major ions, dissolved solids, three nutrients, and two dissolved trace metals for nine streamflow-gaging stations in the basin. Annual variability in streamflow in the Red River Basin was high during the trend-analysis period (1970-2001). The annual variability affects constituent concentrations in individual tributaries to the Red River and, in turn, affects constituent concentrations in the main stem of the Red River because of the relative streamflow contribution from the tributaries to the main stem. Therefore, an annual concentration anomaly, which is an estimate of the interannual variability in concentration that can be attributed to long-term variability in streamflow, was used to analyze annual streamflow-related variability in constituent concentrations. The concentration trend is an estimate of the long-term systematic changes in concentration that are unrelated to seasonal or long-term variability in streamflow. Concentrations that have both the seasonal and annual variability removed are called standardized concentrations. Numerous changes that could not be attributed to natural streamflow-related variability occurred in the standardized concentrations during the trend-analysis period. During various times from the late 1970's to the mid-1990's, significant increases occurred in standardized dissolved sulfate, dissolved chloride, and dissolved- solids concentrations for eight of the nine stations for which water-quality trends were analyzed. Significant increases also occurred from the early 1980's to the mid-1990's for standardized dissolved nitrite plus nitrate concentrations for the main-stem stations. The increasing concentrations for the main-stem stations indicate the upward trends may have been caused by human activities along the main stem of the Red River. Significant trends for standardized total ammonia plus organic nitrogen concentrations occurred for most stations. The fitted trends for standardized total phosphorus concentrations for one tributary station increased from the late 1970's to the early 1980's and decreased from the early 1980's to the mid-1990's. Small but insignificant increases occurred for two main-stem stations. No trends were detected for standardized dissolved iron or dissolved manganese concentrations. However, the combination of extreme high-frequency variability, few data, and the number of censored values may have disguised the streamflow-related variability for iron. The time-series model used to detect historical concentration trends also was used to evaluate sampling designs to monitor future water-quality trends. Various sampling designs were evaluated with regard to their sensitivity to detect both annual and seasonal trends during three 4-month seasons. A reasonable overall design for detecting trends for all stations and constituents consisted of eight samples per year, with monthly sampling from April to August and bimonthly sampling from October to February.

Scientific Investigations Report↗
USGS2021

Synoptic analysis of a decade of daily measurements of SO2 emission in the troposphere from volcanoes of the global ground-based Network for Observation of Volcanic and Atmospheric Change

Volcanic plumes are common and far-reaching manifestations of volcanic activity during and between eruptions. Observations of the rate of emission and composition of volcanic plumes are essential to recognize and, in some cases, predict the state of volcanic activity. Measurements of the size and location of the plumes are important to assess the impact of the emission from sporadic or localized events to persistent or widespread processes of climatic and environmental importance. These observations provide information on volatile budgets on Earth, chemical evolution of magmas, and atmospheric circulation and dynamics. Space-based observations during the last decades have given us a global view of Earth's volcanic emission, particularly of sulfur dioxide ( SO 2 ). Although none of the satellite missions were intended to be used for measurement of volcanic gas emission, specially adapted algorithms have produced time-averaged global emission budgets. These have confirmed that tropospheric plumes, produced from persistent degassing of weak sources, dominate the total emission of volcanic SO 2 . Although space-based observations have provided this global insight into some aspects of Earth's volcanism, it still has important limitations. The magnitude and short-term variability of lower-atmosphere emissions, historically less accessible from space, remain largely uncertain. Operational monitoring of volcanic plumes, at scales relevant for adequate surveillance, has been facilitated through the use of ground-based scanning differential optical absorption spectrometer (ScanDOAS) instruments since the beginning of this century, largely due to the coordinated effort of the Network for Observation of Volcanic and Atmospheric Change (NOVAC). In this study, we present a compilation of results of homogenized post-analysis of measurements of SO 2 flux and plume parameters obtained during the period March 2005 to January 2017 of 32 volcanoes in NOVAC. This inventory opens a window into the short-term emission patterns of a diverse set of volcanoes in terms of magma composition, geographical location, magnitude of emission, and style of eruptive activity. We find that passive volcanic degassing is by no means a stationary process in time and that large sub-daily variability is observed in the flux of volcanic gases, which has implications for emission budgets produced using short-term, sporadic observations. The use of a standard evaluation method allows for intercomparison between different volcanoes and between ground- and space-based measurements of the same volcanoes. The emission of several weakly degassing volcanoes, undetected by satellites, is presented for the first time. We also compare our results with those reported in the literature, providing ranges of variability in emission not accessible in the past. The open-access data repository introduced in this article will enable further exploitation of this unique dataset, with a focus on volcanological research, risk assessment, satellite-sensor validation, and improved quantification of the prevalent tropospheric component of global volcanic emission.

Earth System Science Data↗
USGS2006

Comparison of macroinvertebrate community structure between two riffle-based sampling protocols in Wyoming, Colorado, and Montana, 2000-2001

Samples of benthic macroinvertebrates were collected side-by-side from riffles at 12 stream sites in Wyoming, Colorado, and Montana during 2000-2001, following protocols established by the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program and the U.S. Environmental Protection Agency Environmental Monitoring and Assessment Program (EMAP). Samples from riffles were collected following NAWQA protocols, using a sampler with 425-micron net mesh-opening size from a total area of 1.25 m2 per sample in multiple riffles. Samples also were collected following EMAP protocols, using a sampler with 500-micron net mesh-opening size from a total area of 0.72 m2 per sample in multiple riffles. The taxonomic identification and enumeration of the samples followed procedures established for each program. Benthic macroinvertebrate community structure was compared between the data sets using individual metrics, a multimetric index, and multivariate analysis. Comparisons between the macroinvertebrate community structures were made after sequentially adjusting both data sets for: (1) ambiguous taxa, (2) taxonomic inconsistencies, and (3) differences in laboratory subsampling. After removal of ambiguous taxa, pair-wise differences in total taxa richness and Ephemeroptera taxa richness were statistically significant (p < 0.05). Differences between the data sets generally were not significant for richness of other taxa, tolerant taxa, semi-voltine taxa, functional feeding groups, diversity, and dominance. Sample scores calculated using the Wyoming Stream Integrity Index were not significantly different between the two data sets. After reconciling both data sets for taxonomic inconsistencies, total taxa richness and Ephemeroptera taxa richness remained significantly different between the data sets. After adjusting the data for differences in laboratory subsampling, the differences in taxa richness were no longer significant. Bray-Curtis similarity coefficients and non-metric multi-dimensional scaling were used to examine macroinvertebrate community structure. Similarity in community structure between sites was affected to a greater extent by taxa reconciliation than by adjustment for subsampling.

Scientific Investigations Report↗