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Sample descriptions and geophysical logs for cored well BP-3-USGS, Great Sand Dunes National Park and Preserve, Alamosa County, Colorado

The BP-3-USGS well was drilled at the southwestern corner of Great Sand Dunes National Park in the San Luis Valley, south-central Colorado, 68 feet (ft, 20.7 meters [m]) southwest of the National Park Service’s boundary-piezometer (BP) well 3. BP-3-USGS is located at latitude 37°43ʹ18.06ʺN. and longitude 105°43ʹ39.30ʺW., at an elevation of 7,549 ft (2,301 m). The well was drilled through poorly consolidated sediments to a depth of 326 ft (99.4 m) in September 2009. Water began flowing from the well after penetrating a clay-rich layer that was first intercepted at a depth of 119 ft (36.3 m). The base of this layer, at an elevation of 7,415 ft (2,260 m) above sea level, likely marks the top of a regional confined aquifer recognized throughout much of the San Luis Valley. Approximately 69 ft (21 m) of core was recovered (about 21 percent), almost exclusively from clay-rich zones. Coarser grained fractions were collected from mud extruded from the core barrel or captured from upwelling drilling fluids. Natural gamma-ray, full waveform sonic, density, neutron, resistivity, spontaneous potential, and induction logs were acquired. The well is now plugged and abandoned. This report presents lithologic descriptions from the well samples and core, along with a compilation and basic data processing of the geophysical logs. The succession of sediments in the well can be generalized into three lithologic packages: (1) mostly sand from the surface to about 77 ft (23.5 m) depth; (2) interbedded sand, silt, and clay, decreasing in overall grain size downward, from 77 to 232 ft (23.5 to 70.7 m) depth; and (3) layers of massive clay alternating with layers of fine sand to silt from 232 to 326 ft (70.7 to 99.4 m), the total depth of the well. The topmost clay layers of the deepest package have a blue tint, prompting a correlation with the “blue clay” of the San Luis Valley that is commonly considered as the top of the confined aquifer. However, a confining clay was intercepted 113 ft (34.4 m) higher than the blue clay in BP-3-USGS. Most of the geophysical logs have good correspondence to the lithologic variations in the well. Exceptions are the gamma-ray log, which is likely affected by naturally occurring radiation from abundant volcanic detritus, and one interval within the deepest lithologic package, which appears to be abnormally electrically conductive. Resistivity logs and variations in sand versus clay content within the well are consistent with electrical resistivity models derived from time-domain electromagnetic geophysical surveys for the area. In particular, the topmost blue clay corresponds to a strong electrical conductor that is prominent in the electromagnetic geophysical data throughout the park and vicinity. BP-3-USGS was sited to test hypotheses developed from geophysical studies and to answer questions about the history and evolution of Pliocene and Pleistocene Lake Alamosa, which is represented by lacustrine deposits sampled by the well. The findings reported here represent a basis from which future studies can answer these questions and address other important scientific questions in the San Luis Valley regarding geologic history and climate change, groundwater hydrology, and geophysical interpretation.

Colorado↗

Geologic Cross Section D-D' Through the Appalachian Basin from the Findlay Arch, Sandusky County, Ohio, to the Valley and Ridge Province, Hardy County, West Virginia

Geologic cross section D-D' is the second in a series of cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section D-D' provides a regional view of the structural and stratigraphic framework of the Appalachian basin from the Findlay arch in northwestern Ohio to the Valley and Ridge province in eastern West Virginia, a distance of approximately 290 miles. The information shown on the cross section is based on geological and geophysical data from 13 deep drill holes, several of which penetrate the Paleozoic sedimentary rocks of the basin and bottom in Mesoproterozoic (Grenville-age) crystalline basement rocks. This cross section is a companion to cross section E-E' (Ryder and others, 2008) that is located about 25 to 50 mi to the southwest. Although specific petroleum systems in the Appalachian basin are not identified on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and preferred migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on information shown on the cross section. Cross section D-D' lacks the detail to illustrate key elements of coal systems (such as paleoclimate, coal quality, and coal rank), but it does provide a general geologic framework (stratigraphic units and general rock types) for the coal-bearing section. Also, cross section D-D' may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Scientific Investigations Map↗

Sediment distribution and hydrologic conditions of the Potomac aquifer in Virginia and parts of Maryland and North Carolina

Sediments of the heavily used Potomac aquifer broadly contrast across major structural features of the Atlantic Coastal Plain Physiographic Province in eastern Virginia and adjacent parts of Maryland and North Carolina. Thicknesses and relative dominance of the highly interbedded fluvial sediments vary regionally. Vertical intervals in boreholes of coarse-grained sediment commonly targeted for completion of water-supply wells are thickest and most widespread across the central and southern parts of the Virginia Coastal Plain. Designated as the Norfolk arch depositional subarea, the entire sediment thickness here functions hydraulically as a single interconnected aquifer. By contrast, coarse-grained sediment intervals are thinner and less widespread across the northern part of the Virginia Coastal Plain and into southern Maryland, designated as the Salisbury embayment depositional subarea. Fine-grained intervals that are generally avoided for completion of water-supply wells are increasingly thick and widespread northward. Fine-grained intervals collectively as thick as several hundred feet comprise two continuous confining units that hydraulically separate three vertically spaced subaquifers. The subaquifers are continuous northward but merge southward into the single undivided Potomac aquifer. Lastly, far southeastern Virginia and northeastern North Carolina are designated as the Albemarle embayment depositional subarea, where both coarse- and fine-grained intervals are of only moderate thickness. The entire sediment thickness functions hydraulically as a single interconnected aquifer. A substantial hydrologic separation from overlying aquifers is imposed by the upper Cenomanian confining unit. Potomac aquifer sediments were deposited by a fluvial depositional complex spanning the Virginia Coastal Plain approximately 100 to 145 million years ago. Westward, persistently uplifted granite and gneiss source rocks sustained a supply of coarse-grained sand and gravel. Immature, high-gradient braided streams deposited longitudinal bars and channel fills across the Norfolk arch subarea. By contrast, across the Salisbury and Albemarle embayment subareas, mature, medium- to low-gradient meandering streams deposited medium- to coarse-grained channel fills and point bars segregated from fine-grained overbank deposits. The Virginia depositional complex merged northward across the Salisbury embayment subarea with another complex in Maryland. Here, additional sediments were received from schist source rocks that underwent three cycles of initial uplift and rapid erosion followed by crustal stability and erosional leveling. Because of the predominance of coarse-grained sediments, transmissivity, hydraulic conductivity, and regional velocities of lateral flow through the Potomac aquifer are greatest across the Norfolk arch depositional subarea, but decrease progressively northward with increasingly fine-grained sediments. Confining units hydraulically separate the Potomac aquifer from overlying aquifers, as indicated by large vertical hydraulic gradients. By contrast, most of the Potomac aquifer internally functions hydraulically as a single interconnected aquifer, as indicated by uniformly small vertical gradients. Most fine-grained sediments within the aquifer do not hydraulically separate overlying and underlying coarse-grained sediments. Across the Salisbury embayment depositional subarea, however, hydraulic separation among the vertically spaced subaquifers is imposed by the intervening confining units. The Potomac aquifer is the largest and most heavily used source of groundwater in the Virginia Coastal Plain. Water-level declines as great as 200 feet create the potential for saltwater intrusion. Conventional stratigraphic correlation has been generally ineffective at accurately characterizing complexly distributed fluvial sediments that compose the Potomac aquifer. Consequently, the aquifer’s internal hydraulic connectivity and overall hydrologic function have not been well understood. Water-supply planning and development efforts have been hampered, and interpretations of regulatory criteria for allowable water-level declines have been ambiguous. An investigation undertaken during 2010–11 by the U.S. Geological Survey, in cooperation with the Virginia Department of Environmental Quality, provides a comprehensive regional description of the spatial distribution of Potomac aquifer sediments and their relation to hydrologic conditions. Altitudes and thicknesses of 2,725 vertical sediment intervals represent the spatial distribution of Potomac aquifer sediments in the Virginia Coastal Plain and adjacent parts of Maryland and North Carolina. Sediment intervals are designated as either dominantly coarse or fine grained and were determined by interpretation of geophysical logs and ancillary information from 456 boreholes. Sediment-interval and borehole summary statistical data indicate regional trends in sediment lithology and stratigraphic continuity, upon which three structurally based and hydrologically distinct sediment depositional subareas are designated. Broad patterns of sediment deposition over time are inferred from published sediment pollen-age data. Discrepancies in previously drawn hydrostratigraphic relations between southeastern Virginia and northeastern North Carolina are partly resolved based on borehole geophysical logs and a recently documented geologic map and corehole. A conceptual model theorizes the depositional history of the sediments and geologically accounts for their distribution. Documented pumping tests of the Potomac aquifer at 197 locations produced 336 values of transmissivity and 127 values of storativity. Based on effective aquifer thicknesses, 296 values of sediment hydraulic conductivity and 113 values of sediment specific storage are calculated. Vertical hydraulic gradients are calculated from 9,479 pairs of water levels measured between November 17, 1953, and October 4, 2011, in 129 closely spaced pairs of wells. Borehole sediment-interval and related data provide a means to achieve high yielding production wells in the Potomac aquifer by site-specific targeting of drilling operations toward water-bearing coarse-grained sand and gravel. Advance knowledge of the potential of different parts of the aquifer also aids in planning optimal groundwater-development areas. Depositional subareas further provide a possible context for resource management. Current (2013) regulatory limits on water-level declines are relative to top surfaces of subdivided upper, middle, and lower Potomac aquifers across the entire Virginia Coastal Plain, but have the potential to exceed the same limit relative to a single undivided Potomac aquifer. By contrast, designation of the sediments as a single aquifer in the Norfolk arch and Albemarle embayment subareas—and as a series of vertically spaced subaquifers and intervening confining units in the Salisbury embayment subarea—best reflects understanding of the Potomac aquifer and can avoid the potential for excessive water-level declines. Simulation modeling to evaluate effects of groundwater withdrawals could be designed similarly, including vertical discretization and (or) zonation of the Potomac aquifer based on depositional subareas and a geostatistical distribution of aquifer properties derived from borehole sediment-interval data. Further resource-management information needs extend beyond the developed part of the Potomac aquifer, particularly across the Northern Neck and Middle Peninsula where only the shallowest part of the aquifer is known, and include structural aspects such as faults, basement bedrock, and the Chesapeake Bay impact crater.

Maryland, North Carolina, Virginia↗

Hydrologic assessment of the shallow groundwater flow system beneath the Shinnecock Nation tribal lands, Suffolk County, New York

Defining the distribution and flow of shallow groundwater beneath the Shinnecock Nation tribal lands in Suffolk County, New York, is a crucial first step in identifying sources of potential contamination to the surficial aquifer and coastal ecosystems. The surficial or water table aquifer beneath the tribal lands is the primary source of potable water supply for at least 6 percent of the households on the tribal lands. Oyster fisheries and other marine ecosystems are critical to the livelihood of many residents living on the tribal lands, but are susceptible to contamination from groundwater entering the embayment from the surficial aquifer. Contamination of the surficial aquifer from flooding during intense coastal storms, nutrient loading from fertilizers, and septic effluent have been identified as potential sources of human and ecological health concerns on tribal lands. The U.S. Geological Survey (USGS) facilitated the installation of 17 water table wells on and adjacent to the tribal lands during March 2014. These wells were combined with other existing wells to create a 32-well water table monitoring network that was used to assess local hydrologic conditions. Survey-grade, global-navigation-satellite systems provided centimeter-level accuracy for positioning wellhead surveys. Water levels were measured by the USGS during May (spring) and November (fall) 2014 to evaluate seasonal effects on the water table. Water level measurements were made at high and low tide during May 2014 to identify potential effects on the water table caused by changes in tidal stage (tidal flux) in Shinnecock Bay. Water level contour maps indicate that the surficial aquifer is recharged by precipitation and upgradient groundwater flow that moves from the recharge zone located generally beneath Sunrise Highway, to the discharge zone beneath the tribal lands, and eventually discharges into the embayment, tidal creeks, and estuaries that bound the tribal lands to the east, south, and west. Water levels in many of the wells in the network fluctuated in response to precipitation, upgradient groundwater flow, and tidal flux in Shinnecock Bay. Water level altitudes ranged from 6.66 to 0.47 feet (ft) above the North American Vertical Datum of 1988 during the spring measurement period, and from 5.25 to -0.24 ft (NAVD 88) during fall 2014. Historically, annual and seasonal precipitation seem to indicate long-term water level trends in an index well located in the town of Southampton, correlates with changes in storage in the upper glacial aquifer, but does not necessarily indicate water level extremes in the shallow groundwater system. To place the study period in perspective, calendar year 2014 was the 32d wettest year on record, with precipitation for the year totaling 48.1 inches, a 2.6-percent increase from the annual average (46.9 inches per year), based on 81 years of complete record at the National Oceanographic and Atmospheric Administration, National Weather Service cooperative meteorological station at Bridgehampton, New York. Estimated recharge to the water table beneath the tribal lands from precipitation for 2014 is 25.4 inches. Tidal flux caused water levels in wells to fluctuate from 0.30 to -0.24 ft during May 2014. Water levels in wells located north of Old Fort Pond and beneath the southernmost extent of the tribal lands were most influenced by tidal flux. During June 2014, hydrographs indicate that tidal flux influenced water levels by 0.48 ft in a well located near the southernmost extent of the tribal lands approximately 0.3 miles north of Shinnecock Bay, and was zero at a well located approximately 0.5 miles south of Montauk Highway, and 0.4 miles west of Heady Creek, near the geographic center of the tribal lands. Tidal-influence delay time (time interval between peak high-tide stage and corresponding peak high-water level) ranged from 1.75 hours at the well located near the southernmost extent of the tribal lands, to more than 4 hours at a well located north of Old Fort Pond, near the northwestern part of the tribal lands. Estimated hydraulic-conductivity values derived from the results of specific-capacity tests that were completed at nine observation wells during March 2015 were used to calculate average linear velocity. Average linear velocity along conceptualized flow-path segments of the upper glacial aquifer located beneath the tribal lands was estimated using an assumed effective porosity value, and hydraulic-conductivity and hydraulic-head values that were interpolated from measured values. Groundwater travel times were estimated by dividing the length of the flow-path segment by the average linear velocity along the flow-path segment. Total estimated groundwater travel time along a conceptualized flow path, beginning near Sunrise Highway and terminating at Shinnecock Bay, is approximately 45 years using a porosity value of 30 percent. A surficial-silty unit was identified from approximately 0 to 10 ft below land surface at multiple locations beneath the tribal lands. The lithology of the surficial unit was verified by interpreted gamma log results obtained from select wells, and auger-rig drill cuttings from an observation well located near the geographic center of the tribal lands. The altitude of the unit varies with topography and was delineated along a cross section line that trends north-south along the approximate centerline (spine) of the tribal lands. The altitude of the hydrogeologic contact between the upper glacial and the Magothy aquifers generally decreases from northwest to southeast, occurs at a depth ranging from about 150 to 200 ft beneath the tribal lands, and was identified at two locations north of the tribal lands, near Sunrise Highway and Sebonac Road. Results of electrical geophysical surveys indicate that the depth to the freshwater/saltwater interface decreases from north to south with decreasing water level altitude, and the Magothy and upper glacial aquifers contain saltwater at varying depths along the north-south trending section. Results of the surveys also indicate that the Magothy aquifer beneath the tribal lands contains brackish and salty water and is not considered a source of potable water supply. In general, depth to the interface increases with increasing geographic distance from the coastline. Low water table altitudes can result in increased saltwater encroachment into the surficial aquifer beneath the tribal lands. This upward movement and shallow depth of the freshwater/saltwater interface can jeopardize water quality in wells that supply water for domestic use.

New York↗

Geohydrology and water quality of the unconsolidated aquifers in the Enfield Creek Valley, town of Enfield, Tompkins County, New York

From 2013 to 2018, the U.S. Geological Survey, in cooperation with the Town of Enfield and the Tompkins County Planning Department, studied the unconsolidated aquifer in the Enfield Creek Valley in the town of Enfield, Tompkins County, New York. The valley will likely undergo future development as the population of Tompkins County increases and spreads out from the metropolitan areas. The Town of Enfield, Tompkins County, and the New York State Departments of Health and Environmental Conservation need geohydrologic information to help planners develop a more comprehensive approach to water-resource management in Tompkins County. The Enfield Creek Valley is underlain by an unconfined aquifer that consists of saturated alluvium, alluvial-fan deposits, and ice-contact (kame) sand and gravel. A confined aquifer of discontinuous ice-contact sand and gravel overlies bedrock. Depth to bedrock in the valley ranges from about 50 feet below land surface from just north of the Enfield Creek divide in the northern part of the aquifer to the confluence of Fivemile Creek to at least 140 feet below land surface from Fivemile Creek to where the valley orientation changes from north-south to northwest-southeast. Depth to bedrock is much shallower from the valley orientation change to the southeastern part of the aquifer because Enfield Creek has carved through overlying sediments into bedrock as the creek drops 450 feet into the Cayuga Inlet Valley. A small buried valley running south to north was identified within the Fivemile Creek drainage along the western edge of the town. However, the valley fill consists of glacial till, and no sand-and-gravel aquifer is present. The unconfined aquifers are recharged by direct infiltration of precipitation, surface runoff, and shallow subsurface flow from hillsides, and by seepage loss from streams overlying the aquifer. The confined aquifers are recharged mostly by precipitation that enters the adjacent valley walls, by groundwater flowing from bordering till or bedrock, and by flow from the bottom of the valley. Also, some recharge may be occurring where confining units are absent or from confining units with sediments of moderate permeability. Groundwater discharges to Enfield Creek, its tributaries, and wetlands and is lost through evapotranspiration from the water table or is withdrawn from domestic, commercial, and agricultural wells. About 700 individual well owners depend on the unconsolidated aquifers for their water supply. An estimated 28,300,000 gallons per year are withdrawn. Groundwater samples were collected from eight test wells drilled for this study, and six surface-water samples were collected from five locations on Enfield Creek. Of the eight wells sampled, two were finished in unconfined sand-and-gravel aquifers, two were finished in confined sand-and-gravel aquifers, and four were finished at or near the shale bedrock surface. Water quality in the study area generally met State and Federal drinking-water standards. However, some samples exceeded maximum contaminant levels for barium (25 percent of samples) and secondary maximum containment levels for chloride (25 percent), dissolved solids (25 percent of samples), iron (70 percent of samples), and manganese (75 percent of samples). Groundwater from 75 percent of the wells sampled for methane had concentrations greater than the Office of Surface Mining Reclamation and Enforcement recommended action level of 10 to 28 milligrams per liter. The two deepest wells sampled, TM1075 and TM1077, had the highest specific conductance, chloride, and sodium concentrations of all wells sampled. The chloride/bromide ratios of these samples suggest the source may represent a mixture of saline formation waters with shallow dilute groundwater and may receive recharge contribution from two tributaries overlying bedrock to the west and southwest of the aquifer. In general, the highest yields are from wells completed within about 50 feet below land surface, which may tap either type of aquifer.

New York↗

Stratigraphic framework and depositional sequences in the Lower Silurian regional oil and gas accumulation, Appalachian Basin: From Licking County, Ohio, to Fayette County, West Virginia

The Lower Silurian regional oil and gas accumulation was named by Ryder and Zagorski (2003) for a 400-mile (mi)-long by 200-mi-wide hydrocarbon accumulation in the central Appalachian basin of the Eastern United States and Ontario, Canada. From the early 1880s to 2000, approximately 300 to 400 million barrels of oil and eight to nine trillion cubic feet of gas have been produced from the Lower Silurian regional oil and gas accumulation (Miller, 1975; McCormac and others, 1996; Harper and others, 1999). Dominant reservoirs in the regional accumulation are the Lower Silurian "Clinton" and Medina sandstones in Ohio and westernmost West Virginia and coeval rocks in the Lower Silurian Medina Group (Grimsby Sandstone (Formation) and Whirlpool Sandstone) in northwestern Pennsylvania and western New York. A secondary reservoir is the Upper Ordovician(?) and Lower Silurian Tuscarora Sandstone in central Pennsylvania and central West Virginia, a more proximal eastern facies of the "Clinton" sandstone and Medina Group (Yeakel, 1962; Cotter, 1982, 1983; Castle, 1998). The Lower Silurian regional oil and gas accumulation is subdivided by Ryder and Zagorski (2003) into the following three parts: (1) an easternmost part consisting of local gas-bearing sandstone units in the Tuscarora Sandstone that is included with the basin-center accumulation; (2) an eastern part consisting predominantly of gas-bearing "Clinton" sandstone-Medina Group sandstones that have many characteristics of a basin-center accumulation (Davis, 1984; Zagorski, 1988, 1991; Law and Spencer, 1993); and (3) a western part consisting of oil- and gas-bearing "Clinton" sandstone-Medina Group sandstones that is a conventional accumulation with hybrid features of a basin-center accumulation (Zagorski, 1999). With the notable exception of the offshore part of Lake Erie (de Witt, 1993), the supply of oil and (or) gas in the hybrid-conventional part of the regional accumulation continues to decline because of the many wells drilled there since the late 1880s. However, new gas and local oil continues to be discovered in the deeper basin-center part (Zagorski, 1991; Pees, 1994; Petroleum Information Corporation, 1994). In general, only small quantities of gas have been produced from the Tuscarora Sandstone fields because of their generally poor reservoir quality and because of the low energy (Btu) content of the gas (Avary, 1996). Although fracture porosity is the dominant porosity type in the Tuscarora Sandstone gas reservoirs (Avary, 1996), there are several fields, such as Indian Creek, where intergranular porosity seems to be important (Bruner, 1983; Castle and Byrnes, 2005). In order to better understand the character and origin of the Lower Silurian regional oil and gas accumulation and its component parts, six cross sections were drawn through the Lower Silurian strata in parts of New York, Ohio, Pennsylvania, and West Virginia. The locations of all six cross sections are shown on sheet 2 (figs. 1 and 2) of this report. Each cross section shows the stratigraphic framework, depositional setting, sequence stratigraphy, and hydrocarbon-producing intervals of the Lower Silurian sandstone reservoirs and adjoining strata. Cross section F–F′ presented here is about 215 mi long and trends northwestward, approximately normal to the depositional strike of the Lower Silurian sandstone system, and extends through large stretches of the basin-center and hybrid-conventional parts of the Lower Silurian regional oil and gas accumulation.

Ohio, West Virginia↗

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews↗

Detailed north-south cross section showing environments of deposition, organic richness, and thermal maturities of lower Tertiary rocks in the Uinta Basin, Utah

The Uinta Basin of northeast Utah has produced large amounts of hydrocarbons from lower Tertiary strata since the 1960s. Recent advances in drilling technologies, in particular the development of efficient methods to drill and hydraulically fracture horizontal wells, has spurred renewed interest in producing hydrocarbons from unconventional low-permeability dolomite and shale reservoirs in the lacustrine, Eocene Green River Formation. The Eocene Green River Formation was deposited in Lake Uinta, a long-lived saline lake that occupied the Uinta Basin, the Piceance Basin to the east, and the intervening Douglas Creek arch. The focus of recent drilling activity has been the informal Uteland Butte member of the Green River Formation and to a much lesser extent the overlying R-0 oil shale zone of the Green River Formation. Initial production rates ranging from 500 to 1,500 barrels of oil equivalent per day have been reported from the Uteland Butte member from horizontal well logs that are as long as 4,000 feet (ft);. The cross section presented here extends northward from outcrop on the southern margin of the basin into the basin’s deep trough, located just south of the Uinta Mountains, and transects the area where this unconventional oil play is developing. The Monument Butte field, which is one of the fields located along this line of section, has produced hydrocarbons from conventional sandstone reservoirs in the lower part of the Green River Formation and underlying Wasatch Formation since 1981. A major fluvial-deltaic system entered Lake Uinta from the south, and this new line of section is ideal for studying the effect of the sediments delivered by this drainage on hydrocarbon reservoirs in the Green River Formation. The cross section also transects the Greater Altamont-Bluebell field in the deepest part of the basin, where hydrocarbons have been produced from fractured, highly overpressured marginal lacustrine and fluvial reservoirs in the Green River, Wasatch, and North Horn Formations since 1970. Datum for the cross section is sea level so that hydrocarbon source rocks and reservoir rocks could be integrated into the structural framework of the basin.

Utah↗

Hydrogeologic framework of the Wood River Valley aquifer system, south-central Idaho

The Wood River Valley contains most of the population of Blaine County and the cities of Sun Valley, Ketchum, Hailey, and Bellevue. This mountain valley is underlain by the alluvial Wood River Valley aquifer system, which consists primarily of a single unconfined aquifer that underlies the entire valley, an underlying confined aquifer that is present only in the southernmost valley, and the confining unit that separates them. The entire population of the area depends on groundwater for domestic supply, either from domestic or municipal-supply wells, and rapid population growth since the 1970s has caused concern about the long-term sustainability of the groundwater resource. As part of an ongoing U.S. Geological Survey effort to characterize the groundwater resources of the Wood River Valley, this report describes the hydrogeologic framework of the Wood River Valley aquifer system. Although most of the Wood River Valley aquifer system is composed of Quaternary-age sediments and basalts of the Wood River Valley and its tributaries, older igneous, sedimentary, or metamorphic rocks that underlie these Quaternary deposits also are used for water supply. It is unclear to what extent these rocks are hydraulically connected to the main part of Wood River Valley aquifer system and thus whether they constitute separate aquifers. Paleozoic sedimentary rocks in and near the study area that produce water to wells and springs are the Phi Kappa and Trail Creek Formations (Ordovician and Silurian), the Milligen Formation (Devonian), and the Sun Valley Group including the Wood River Formation (Pennsylvanian-Permian) and the Dollarhide Formation (Permian). These sedimentary rocks are intruded by granitic rocks of the Late Cretaceous Idaho batholith. Eocene Challis Volcanic Group rocks overlie all of the older rocks (except where removed by erosion). Miocene Idavada Volcanics are found in the southern part of the study area. Most of these rocks have been folded, faulted, and metamorphosed to some degree, thus rock types and their relationships vary over distance. Quaternary-age sediment and basalt compose the primary source of groundwater in the Wood River Valley aquifer system. These Quaternary deposits can be divided into three units: a coarse-grained sand and gravel unit, a fine-grained silt and clay unit, and a single basalt unit. The fine- and coarse-grained units were primarily deposited as alluvium derived from glaciation in the surrounding mountains and upper reaches of tributary canyons. The basalt unit is found in the southeastern Bellevue fan area and is composed of two flows of different ages. Most of the groundwater produced from the Wood River Valley aquifer system is from the coarse-grained deposits. The altitude of the pre-Quaternary bedrock surface in the Wood River Valley was compiled from about 1,000 well-driller reports for boreholes drilled to bedrock and about 70 Horizontal-to-Vertical Spectral Ratio (HVSR) ambient-noise measurements. The bedrock surface generally mimics the land surface by decreasing down tributary canyons and the main valley from north to south; it ranges from more than 6,700 feet in Baker Creek to less than 4,600 feet in the central Bellevue fan. Most of the south-central portion of the Bellevue fan is underlain by an apparent topographically closed area on the bedrock surface that appears to drain to the southwest towards Stanton Crossing. Quaternary sediment thickness ranges from less than a foot on main and tributary valley margins to about 350 feet in the central Bellevue fan. Hydraulic conductivity for 81 wells in the study area was estimated from well-performance tests reported on well-driller reports. Estimated hydraulic conductivity for 79 wells completed in alluvium ranges from 1,900 feet per day (ft/d) along Warm Springs Creek to less than 1 ft/d in upper Croy Canyon. A well completed in bedrock had an estimated hydraulic conductivity value of 10 ft/d, one well completed in basalt had a value of 50 ft/d, and three wells completed in the confined system had values ranging from 32 to 52 ft/d. Subsurface outflow of groundwater from the Wood River Valley aquifer system into the eastern Snake River Plain aquifer was estimated to be 4,000 acre-feet per year. Groundwater outflow beneath Stanton Crossing to the Camas Prairie was estimated to be 300 acre-feet per year.

Idaho↗

Water quality and hydrology of the Silver River Watershed, Baraga County, Michigan, 2005-08

The Silver River Watershed comprises about 69 square miles and drains part of northeastern Baraga County, Michigan. For generations, tribal members of the Keweenaw Bay Indian Community have hunted and fished in the watershed. Tribal government and members of Keweenaw Bay Indian Community are concerned about the effect of any development within the watershed, which is rural, isolated, and lightly populated. For decades, the area has been explored for various minerals. Since 2004, several mineral-exploration firms have been actively investigating areas within the watershed; property acquisition, road construction, and subsurface drilling have taken place close to tributary streams of the Silver River. The U.S. Geological Survey, in cooperation with Keweenaw Bay Indian Community, conducted a multi-year water-resources investigation of the Silver River Watershed during 2005-08. Methods of investigation included analyses of streamflow, water-quality sampling, and ecology at eight discrete sites located throughout the watershed. In addition, three continuous-record streamgages located within the watershed provided stage, discharge, specific conductance, and water-temperature data on an hourly basis. Water quality of the Silver River Watershed is typical of many streams in undeveloped areas of Upper Michigan. Concentrations of most analytes typically were low, although several exceeded applicable surface-water-quality standards. Seven samples had concentrations of copper that exceeded the Michigan Department of Environmental Quality standards for wildlife, and one sample had concentrations of cyanide that exceeded the same standards. Concentrations of total mercury at all eight sampling sites exceeded the Great Lakes Basin water-quality standard, but the ratio of methylmercury to total mercury was similar to the 5 to 10 percent found in most natural waters. Concentrations of arsenic and chromium in bed sediments were near the threshold-effect concentration. A qualitative ecological assessment of fishes and macroinvertebrates showed that intolerant salmonids were present at most sampled sites, and macroinvertebrate communities were indicative of near-excellent or excellent conditions at all eight sites. This baseline information will aid in an ongoing monitoring effort designed to protect the water resources of the

Scientific Investigations Report↗

Groundwater chemistry and water-level elevations in bedrock aquifers of the Piceance and Yellow Creek watersheds, Rio Blanco County, Colorado, 2013–16

The Piceance and Yellow Creek watersheds in Rio Blanco County, Colorado, are known to contain important energy resources (oil shale and natural gas) and mineral resources (nahcolite). The primary sources of fresh groundwater in the Piceance and Yellow Creek watersheds are bedrock aquifers in the Uinta and Green River Formations. The aquifers are divided into an upper and lower aquifer separated by a regionally extensive semiconfining layer. These aquifers provide water to streams and springs in the watersheds and are an important resource to people living and working in the area. Development of energy and mineral resources has the potential to affect the quality of groundwater in several ways. The Bureau of Land Management and the U.S. Geological Survey began groundwater monitoring in 2010 to characterize the groundwater quality and water-level elevations of shallow bedrock aquifers in the Piceance and Yellow Creek watersheds. The purpose of this report is to present ground-water chemistry and water-level elevations collected during 2013–16. Comparisons are made to data that were collected from the bedrock aquifers from 2010 to 2012 to identify the potential for changes in water quality and water-level elevations. Appreciable changes in water-level elevations and hydraulic gradient were observed in early April 2015 in two wells completed in the upper and lower aquifers. The hydraulic gradient between the two wells was consistently downward from the upper aquifer to the lower aquifer during 2010–15; however, in early April 2015, the gradient changed from downward to upward between the two aquifers. Overall, water-level elevations declined by about 14 and 11 feet in the upper and lower aquifers, respectively, from 2013 to 2016. Previously published data estimated groundwater ages at 1,200 years old in the upper aquifer and 9,600 years old in the lower aquifer. These groundwater ages indicate that ground-water was recharged over thousands of years. With such long periods of time for aquifer recharge, declines in water-level elevation over short time steps (a few months) have important implications for sustainable management of this resource. Solution mining activities or drilling for oil and natural gas in the area could be related to the changes observed in water-level elevations in these wells; however, further investigation would be needed to evaluate causation. Changes in major-ion chemistry were evaluated in the bedrock aquifer using time series plots of select major-ion data from 2010 to 2016. Major-ion chemistry was variable for a single well from 2010 to 2016 where alkalinity and sulfate were the most variable constituents. One possible explanation for the observed changes in major-ion chemistry may be that the sample depth for that well no longer represents the most appreciable flow in the borehole. On a larger scale, potential changes in flow within the borehole may indicate changes in the regional flow system. Methane and volatile organic compound concentrations were evaluated using a similar approach to that of major ions and had similar findings. Methane concentrations in wells sampled from 2010 to 2016 were generally constant. The only exception was observed at a single well where the range of methane concentrations was from 57.4 (2010) to 4.02 milligrams per liter (2013). This is the same well where changes in water-level elevation, hydraulic gradient, and major-ion chemistry were observed, providing multiple lines of evidence to indicate change in the bedrock aquifers. Sampling of a well located in an area with little energy development but where faults or fractures could provide a path for the migration of fluids indicate mixing of groundwater between the upper and lower aquifers.

Colorado↗

Hydrogeologic characteristics and water quality of a confined sand unit in the surficial aquifer system, Hunter Army Airfield, Chatham County, Georgia

An 80-foot-deep well (36Q397, U.S. Geological Survey site identification 320146081073701) was constructed at Hunter Army Airfield to assess the potential of using the surficial aquifer system as a water source to irrigate a ballfield complex. A 300-foot-deep test hole was drilled beneath the ballfield complex to characterize the lithology and water-bearing characteristics of sediments above the Upper Floridan aquifer. The test hole was then completed as well 36Q397 open to a 19-foot-thick shallow, confined sand unit contained within the surficial aquifer system. A single-well, 24-hour aquifer test was performed by pumping well 36Q397 at a rate of 50 gallons per minute during July 13-14, 2011, to characterize the hydrologic properties of the shallow, confined sand unit. Two pumping events prior to the aquifer test affected water levels. Drawdown during all three pumping events and residual drawdown during recovery periods were simulated using the Theis formula on multiple changes in discharge rate. Simulated drawdown and residual drawdown match well with measured drawdown and residual drawdown using values of horizontal hydraulic conductivity and specific storage, which are typical for a confined sand aquifer. Based on the hydrologic parameters used to match simulated drawdown and residual drawdown to measured drawdown and residual drawdown, the transmissivity of the sand was determined to be about 400 feet squared per day. The horizontal hydraulic conductivity of the sand was determined to be about 20 feet per day. Analysis of a water-quality sample indicated that the water is suitable for irrigation. Sample analysis indicated a calcium-carbonate type water having a total dissolved solids concentration of 39 milligrams per liter. Specific conductance and concentrations of all analyzed constituents were below those that would be a concern for irrigation, and were below primary and secondary water-quality criteria levels.

Georgia↗

Bathymetric surveys at highway bridges crossing the Missouri River in Kansas City, Missouri, using a multibeam echo sounder, 2010

Bathymetric surveys were conducted by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, on the Missouri River in the vicinity of nine bridges at seven highway crossings in Kansas City, Missouri, in March 2010. A multibeam echo sounder mapping system was used to obtain channel-bed elevations for river reaches that ranged from 1,640 to 1,800 feet long and extending from bank to bank in the main channel of the Missouri River. These bathymetric scans will be used by the Missouri Department of Transportation to assess the condition of the bridges for stability and integrity with respect to bridge scour. Bathymetric data were collected around every pier that was in water, except those at the edge of the water or in extremely shallow water, and one pier that was surrounded by a large debris raft. A scour hole was present at every pier for which bathymetric data could be obtained. The scour hole at a given pier varied in depth relative to the upstream channel bed, depending on the presence and proximity of other piers or structures upstream from the pier in question. The surveyed channel bed at the bottom of the scour hole was between 5 and 50 feet above bedrock. At bridges with drilled shaft foundations, generally there was exposure of the upstream end of the seal course and the seal course often was undermined to some extent. At one site, the minimum elevation of the scour hole at the main channel pier was about 10 feet below the bottom of the seal course, and the sides of the drilled shafts were evident in a point cloud visualization of the data at that pier. However, drilled shafts generally penetrated 20 feet into bedrock. Undermining of the seal course was evident as a sonic 'shadow' in the point cloud visualization of several of the piers. Large dune features were present in the channel at nearly all of the surveyed sites, as were numerous smaller dunes and many ripples. Several of the sites are on or near bends in the river, resulting in a deep channel thalweg on the outside of the bend at these sites. At structure A5817 on State Highway 269, bedrock exposure was evident in the channel thalweg. The surveyed channel bed at a given site from this study generally was lower than the channel bed obtained during Level II scour assessments in 2002. At piers with well-defined scour holes, the frontal slopes of the holes were somewhat less than recommended values in the literature, and the shape of the holes appeared to be affected by the movement of dune features into and around the holes. The channel bed at all of the surveyed sites was lower than the channel bed at the time of construction, and an analysis of measurement data from the U.S. Geological Survey continuous streamflow-gaging station on the Missouri River at Kansas City, Missouri (station number 06893000), confirmed a lowering trend of the channel-bed elevations with time at the gaging station. The size of the scour holes observed at the surveyed sites likely was affected by the moderate flood conditions on the Missouri River at the time of the surveys. The scour holes likely would be substantially smaller during conditions of low flow.

Scientific Investigations Report↗

Compressional-wave seismic velocity, bulk density, and their empirical relations for geophysical modeling of the Midcontinent Rift System in the Lake Superior region

Compressional-wave seismic velocity (velocity) and bulk density (density) data were compiled from published sources for rock suites and earth materials that are significant for geophysical modeling of the Mesoproterozoic Midcontinent Rift System in the Lake Superior region. The data include laboratory measurements of outcrop and drill core samples, seismic refraction studies, and a sonic log from a 1.5-kilometer-deep exploration well. Rock suites of the Midcontinent Rift System include basalts of the Mesoproterozoic Keweenawan Supergroup, Oronto Group sedimentary rocks (divided into arenaceous versus argillaceous units), and several sedimentary formations overlying the Oronto Group that have been correlated across the area. Intrusive units include diabase, gabbro, and felsic igneous rocks. Other geologic units important for geophysical modeling in the Lake Superior region include Archean crystalline crust, Paleoproterozoic metasedimentary and crystalline rocks, lower Mesoproterozoic sedimentary rocks, and Holocene to Pleistocene surficial deposits. Empirical velocity-density relations for each rock suite were determined by comparing the compiled data to published relations, such as the Nafe-Drake curve, Gardner’s relation, and best-fit equations developed for different rock types from laboratory studies. Graphical representations of these velocity-density relations provide a way to easily understand how velocity and density differ between tectonic settings and by rock type. Overlaps in velocity and density ranges for different geologic units are significant and have especially important implications for geologic interpretation of seismic data. Important examples include similar velocities but differing densities for argillaceous Oronto Group versus units overlying the Oronto Group and arenaceous Oronto Group versus basalt of the Keweenawan Supergroup. Similar densities but differing velocities were found for diabase versus gabbro. In addition, expected velocity ranges by rock type show that high-velocity intervals (6.9–7.1 kilometers per second) interpreted as basalt in previous seismic-reflection studies more likely indicate diabase or gabbro, suggesting that these interpretations may warrant additional consideration.

Lake Superior↗

Completion summary for borehole TAN-2312 at Test Area North, Idaho National Laboratory, Idaho

In 2017, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, drilled and constructed borehole TAN-2312 for stratigraphic framework analyses and long-term groundwater monitoring of the eastern Snake River Plain aquifer at the Idaho National Laboratory in southeast Idaho. The location of borehole TAN-2312 was selected because it was downgradient from TAN and believed to be the outer extent of waste plumes originating from the TAN facility. Borehole TAN-2312 initially was cored to collect continuous geologic data, and then re-drilled to complete construction as a monitor well. The final construction for borehole TAN-2312 required 16- and 10-inch (in.) diameter carbon-steel well casing to 37 and 228 feet below land surface (ft BLS), respectively, and 9.9-in. diameter open-hole completion below the casing to 522 ft BLS. Depth to water is measured near 244 ft BLS. Following construction and data collection, a temporary submersible pump and water-level access line were placed near 340 ft BLS to allow for aquifer testing, for collecting periodic water samples, and for measuring water levels. Borehole TAN-2312 was cored continuously, starting at the first basalt contact (about 37 ft BLS) to a depth of 568 ft BLS. Not including surface sediment (0–37 ft), recovery of basalt and sediment core at borehole TAN-2312 was about 93 percent; however, core recovery from 170 to 568 ft BLS was 100 percent. Based on visual inspection of core and geophysical data, basalt examined from 37 to 568 ft BLS consists of about 32 basalt flows that range from approximately 3 to 87 ft in thickness and 4 sediment layers with a combined thickness of approximately 76 ft. About 2 ft of total sediment was described for the saturated zone, observed from 244 to 568 ft BLS, near 296 and 481 ft BLS. Sediment described for the saturated zone were composed of fine-grained sand and silt with a lesser amount of clay. Basalt texture for borehole TAN-2312 generally was described as aphanitic, phaneritic, and porphyritic. Basalt flows varied from highly fractured to dense with high to low vesiculation. Geophysical and borehole video logs were collected after core drilling and after final construction at borehole TAN-2312. Geophysical logs were examined synergistically with available core material to suggest zones where groundwater flow was anticipated. Natural gamma log measurements were used to assess sediment layer thickness and location. Neutron and gamma-gamma source logs were used to identify fractured areas for aquifer testing. Acoustic televiewer logs, fluid logs, and electromagnetic flow meter results were used to identify fractures and assess groundwater movement when compared against neutron measurements. Furthermore, gyroscopic deviation measurements were used to measure horizontal and vertical displacement for borehole TAN-2312. After construction of borehole TAN-2312, a single-well aquifer test was completed September 27, 2017, to provide estimates of transmissivity and hydraulic conductivity. Estimates for transmissivity and hydraulic conductivity were 1.51×102 feet squared per day and 0.23 feet per day, respectively. During the 220-minute aquifer test, well TAN-2312 had about 23 ft of measured drawdown at sustained pumping rate of 27.2 gallons per minute. The transmissivity and hydraulic conductivity estimates for well TAN-2312 were lower than the values determined from previous aquifer tests in other wells near Test Area North. Water samples were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for most of the inorganic constituents showed concentrations near background levels for eastern regional groundwater. Water samples for stable isotopes of oxygen, hydrogen, and sulfur indicated some possible influence of irrigation on the water quality. The volatile organic compound data indicated that this well had some minor influence by wastewater disposal practices at Test Area North.

Idaho↗

Gold-silver mining districts, alteration zones, and paleolandforms in the Miocene Bodie Hills Volcanic Field, California and Nevada

The Bodie Hills is a ~40 by ~30 kilometer volcanic field that straddles the California-Nevada state boundary between Mono Lake and the East Walker River. Three precious metal mining districts and nine alteration zones are delineated in Tertiary-Quaternary volcanic and Mesozoic granitic and metamorphic rocks that comprise the volcanic field. Cumulative production from the mining districts, Bodie, Aurora, and Masonic, is 3.4 million ounces of gold and 28 million ounces of silver. Small amounts of mercury were produced from the Potato Peak, Paramount-Bald Peak, and Cinnabar Canyon-US 395 alteration zones; a native sulfur resource in the Cinnabar Canyon-US 395 alteration zone has been identified by drilling. There are no known mineral resources in the other six alteration zones, Red Wash-East Walker River, East Brawley Peak, Sawtooth Ridge, Aurora Canyon, Four Corners, and Spring Peak. The mining districts and alteration zones formed between 13.4 and 8.1 Ma in predominantly ~15–9 Ma volcanic rocks of the Bodie Hills volcanic field. Ages of hydrothermal minerals in the districts and zones are the same as, or somewhat younger than, the ages of volcanic host rocks. Based on volcanic stratigraphy, geochronology, remnant paleosurfaces, and paleopotentiometric surfaces in mining districts and alteration zones, present landforms in the Bodie Hills volcanic field reflect incremental construction of stratovolcanoes and large- to small-volume flow-domes, magmatic inflation, and fault displacements. Landform evolution began with construction of the 15–13 Ma Masonic and 13–12 Ma Aurora volcanic centers in the northwestern and northeastern parts of the field, respectively. Smaller volcanoes erupted at ~11–10 Ma in, between, and south of these centers as erosional detritus accumulated north of the field in Fletcher Valley. Distally sourced, 9.7–9.3 Ma Eureka Valley Tuff filled drainages and depressions among older volcanoes and was partly covered by nearly synchronous eruptives during construction of four large 10–8 Ma volcanoes, in the southern part of the field. The lack of significant internal fault displacement, distribution of Eureka Valley Tuff, and elevation estimates derived from floras, suggest that the Bodie Hills volcanic field attained present elevations mostly through volcano construction and magmatic inflation, and that maximum paleoelevations (>8,500 ft) at the end of large volume eruptions at ~8 Ma are similar to present elevations.

California, Nevada↗

Distribution of methyl tert-butyl ether (MTBE) and selected water-quality constituents in the surficial aquifer at the Dover National Test Site, Dover Air Force Base, Delaware, 2001

A joint study by the Dover National Test Site, Dover Air Force Base, Delaware, and the U.S. Geological Survey was conducted from June 27 through July 18, 2001, to determine the spatial distribution of the gasoline oxygenate additive methyl tert-butyl ether and selected water-quality constituents in the surficial aquifer underlying the Dover National Test Site. This report provides a summary assessment of the distribution of methyl tert-butyl ether and a preliminary screening of selected constituents that may affect natural attenuation and remediation demonstrations at the Dover National Test Site. The information gathered during this study is designed to assist potential remedial investigators who are considering conducting a methyl tert-butyl ether remedial demonstration at the test site. In addition, the study supported a planned enhanced bioremediation demonstration and assisted the Dover National Test Site in identifying possible locations for future methyl tert-butyl ether remediation demonstrations. A direct-push drill rig was used to collect a total of 147 ground-water samples (115 VOC samples and 32 quality-assurance samples) at varying depths. Volatile organic compounds were above the method reporting limits in 59 of the 115 ground-water samples. The concentrations ranged from below detection limits to maximum values of 12.4 micrograms per liter of cis-1,2-dichloro-ethene, 1.14 micrograms per liter of trichloro-ethene, 2.65 micrograms per liter of tetrachloro-ethene, 1,070 micrograms per liter of methyl tert-butyl ether, 4.36 micrograms per liter of benzene, and 1.8 micrograms per liter of toluene. Vinyl chloride, ethylbenzene, p,m-xylene, and o-xylene were not detected in any of the samples collected during this investigation. Methyl tert-butyl ether was detected in 47 of the 115 ground-water samples. The highest concentrations of methyl tert-butyl ether were detected in the surficial aquifer from ?4.6 to 6.4 feet mean sea level; however, methyl tert-butyl ether was detected as deep as ?9.5 feet mean sea level. Increased methane concentrations and decreased dissolved oxygen concentrations that were found in association with the ground-water samples that contained methyl tert-butyl ether are preliminary indicators that will assist in determining if natural attenuation of methyl tert-butyl ether is occurring in the surficial aquifer. A full assessment of natural attenuation of methyl tert-butyl ether at the site is beyond the scope of this study, but the data collected during the study will be useful in selecting appropriate remedial methyl tert-butyl ether demonstrations.

Delaware↗

Aquifer geometry, lithology, and water levels in the Anza–Terwilliger area—2013, Riverside and San Diego Counties, California

The population of the Anza–Terwilliger area relies solely on groundwater pumped from the alluvial deposits and surrounding bedrock formations for water supply. The size, characteristics, and current conditions of the aquifer system in the Anza–Terwilliger area are poorly understood, however. In response to these concerns, the U.S. Geological Survey, in cooperation with the High Country Conservancy and Rancho California Water District, undertook a study to (1) improve mapping of groundwater basin geometry and lithology and (2) to resume groundwater-level monitoring last done during 2004–07 in the Anza–Terwilliger area. Inversion of gravity data, including new data collected for this study, was done to estimate the thickness of the alluvial deposits that form the Cahuilla and Terwilliger groundwater basins and to understand the geometry of the underlying basement complex. After processing of the gravity data, the thickness of the alluvial aquifer materials was modeled by using all available lithology, density, and geophysical data. The thickest alluvial deposits (greater than 500 feet) are in the northern part of the study area along the south side of the San Jacinto fault zone, in the southern part of the Cahuilla groundwater basin, and in the western part of the Terwilliger groundwater basin. Through most of the area of alluvial materials, the thickness of the alluvium estimated from gravity data is less than 400 feet. Analysis of more than 900 drillers’ logs indicated that in areas having relatively thick alluvium, particularly along the San Jacinto fault zone and in the Terwilliger Valley, the alluvium is predominantly composed of sands and gravels. Fine-textured sediments appeared to be discontinuous rather than forming laterally extensive, low-permeability layers. More than 500 drillers’ logs indicated only bedrock is present, indicating that the fractured bedrock is an important source of groundwater, primarily for domestic use, in the study area. The depths of the holes drilled into the bedrock indicated that fractures potentially supplying water to wells persist in the upper few hundred feet and that the permeable zone of the fractured bedrock extends to depths greater than weathered zones in the upper part of the basement complex. Water-level data were collected from 59 wells during fall 2013. These data indicated that hydraulic head did not vary substantially with well depth and that the measured water levels in bedrock and alluvium were similar. Large offsets in groundwater altitude across the San Jacinto fault zone indicated that the fault zone is a barrier to groundwater flow in the northeastern part of the Anza Valley. On the basis of data from 33 wells, water levels mostly declined between the fall of 2006 and the fall of 2013; the median decline was 5.1 feet during this period, for a median rate of decline of about 0.7 feet/year. Based on data from 40 wells, water-level changes between fall 2004 and fall 2013 were variable in magnitude and trend, but had a median decline of 2.4 feet and a median rate of decline of about 0.3 feet/ year. These differences in apparent rates of groundwater-level change highlight the value of ongoing water-level measurements to distinguish decadal, or longer term, trends in groundwater storage often associated with climatic variability and trends. Fifty-four long-term hydrographs indicated the sensitivity of groundwater levels to climatic conditions; they also showed a general decline in water levels across the study area since 1986 and, in some cases, dating back to the 1950s.

California↗