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Using hydrogeologic context and water budgets to evaluate the potential for groundwater contributions to contaminants in Lake Superior

This study presents a synthesis of the hydrogeology in the U.S. Lake Superior watershed and the contribution of groundwater to the water budget of the U.S. Lake Superior basin. Much of the shoreline of Lake Superior in Minnesota and Michigan is composed of hydrogeologic units contributing very little direct groundwater discharge to the lake. Groundwater in watersheds adjacent to the lake typically flows in short, local flow systems characterized by thin glacial sediments with active groundwater flow in fractured bedrock within the top 60–90 m below land surface. The complex groundwater system in Wisconsin’s Bayfield Peninsula has the largest groundwater reservoir near the lake, characterized by thick sand and gravel glacial deposits and underlying sandstone aquifer. Although these thick sandy glacial deposits are not in direct contact with the lake at the shoreline, groundwater discharge may still be significant via subsurface exposures beyond the shoreline or flow through the underlying sandstone aquifer. Overall, most groundwater in the watershed is contributed as indirect base flow in streams around the lakeshore and comprises about 60 percent of the upland water budget. Direct groundwater flow to the shoreline contributes 2 to 9 percent of the inflow. Identifying possible contamination sources through direct sampling of groundwater would be an inefficient way to detect problems if sources are unknown, particularly for some chemicals of concern such as PFAS, pesticides, PCBs, chloride, and nutrients. Evaluating the chemical characteristics of contamination is also important to consider in evaluating how groundwater may contribute to pollution in Lake Superior.

Lake Superior

Laboratory assessment for recovery of porcine circovirus 2 and porcine reproductive and respiratory syndrome virus using two types of commercially available hollow-fiber ultrafilters

Groundwater near swine farms is an uninvestigated reservoir for porcine reproductive and respiratory syndrome virus (PRRSV) and porcine circoviruses (PCVs). Enteric microorganisms are often collected from groundwater via dead-end ultrafiltration, but recovery of PRRSV and PCV with this method has not been assessed. We recovered PRRSV2 and PCV2 by dead-end ultrafiltration followed by polyethylene glycol (PEG) precipitation, nucleic acid extraction, and reverse-transcription quantitative real-time PCR. We also compared 2 commercial hemodialysis ultrafilters (Asahi Kasei Rexeed-25A, Nipro Elisio-25H) and compared PRRSV2 recovery in these filters to other waterborne microorganisms. On average, 8 ± 1% of PRRSV2 was recovered by dead-end ultrafiltration and PEG precipitation, compared to 25 ± 6% for adenovirus 41. Full-process recovery of bacteria in the same filters was 5–15%; Cryptosporidium parvum recovery was 42 ± 12%. PCV2 was detected in 4 of 12 replicate filters, but low stock concentrations precluded quantitative recovery estimates. Elisio-25H ultrafilters performed similarly to Rexeed-25A filters for all organisms tested and is an effective replacement for the Rexeed-25A, which is no longer available in the United States. Our recovery of PRRSV2 and PCV2 by dead-end ultrafiltration in the laboratory suggests that PRRSV2 detection limits are as low as 3–50 genomic copies/L in sample volumes of 100–1,500 L. Based on quantitative microbial risk assessment, these concentrations are relevant to PRRSV2 infection rates in the U.S. swine herd.

Journal of Veterinary Diagnostic Investigation

Ecohydrological response of a forested headwater catchment to a flash drought in the Southeastern U.S.

Flash droughts differ from traditionally defined droughts in their rapidity of intensification and often associated high vapor-pressure deficit. These droughts can lead to declines in streamflow and water table depth and induce water stress to vegetation at a greater rate than droughts that manifest over longer periods. However, little is known regarding the response of forested environments to flash drought because most studies of impacts have been conducted in agricultural settings. In this study we investigated water-use patterns of riparian trees using sap flow methods and examined the role of groundwater as a source of moisture over three periods that were delimited by antecedent soil moisture conditions. For a longer-term perspective we also examine monthly streamflow over the 35-year record. We observed that trees at only one monitoring plot showed a decrease in water use relative to evaporative demand during a flash drought. Total reverse sap flow (flow toward the roots rather than the canopy) greatly increased during the flash drought period, suggesting the likely occurrence of hydraulic redistribution to the excessively dry soils. Over the drought period groundwater became a more dominant source of moisture for sustaining forest water use. Monthly mean streamflow during the flash drought approached levels observed in past multiyear droughts. This is the first study, to our knowledge, to specifically investigate the response of multiple water budget components to flash drought in a humid forest. As more studies are conducted, a better understanding of the range of expected responses are likely to emerge.

Georgia

Transcriptional changes in wild Yukon River Chinook Salmon associated with Ichthyophonus infections

Objective We compared differentially expressed genes in Chinook Salmon Oncorhynchus tshawytscha with three divergent Ichthyophonus statuses (undetected, subclinical infections, or clinical disease; n = 100) to investigate associated transcriptomic responses. Disease associated with the fish parasite Ichthyophonus sp. was first diagnosed in adult Chinook Salmon from the Yukon River in the late 1980s and has subsequently been implicated in premature host mortality. Methods Chinook Salmon tissue sample collections and Ichthyophonus infection data were leveraged from a multi-agency collaboration during summer 2022 at three locations along the main-stem Yukon River that spanned nearly 2,000 km of freshwater migration (lower, middle, and upper river). We sequenced the transcriptome and compared this to infection status based on routine diagnostic procedures. Results Among the 17,569 genes for which messenger RNA was detected, we identified a transcription signature in the skeletal muscle that was associated with Ichthyophonus infections and included 53 differentially expressed genes. The differentially expressed genes and their pathways included those known for involvement in immune functions, energy synthesis, cellular breakdown, and reproduction—all processes that are known to be influenced by senescence during spawning migrations. Conclusions Results demonstrate a clear transcriptional difference between diseased fish (clinical disease group) and those in which Ichthyophonus was undetected, including identifying candidate markers for infection in this population. These results provide a foundation for development of nonlethal biomarkers to evaluate potential Ichthyophonus infections in Chinook Salmon based on gene transcription, protein products, or gene variants (e.g., polymorphisms).

Journal of Aquatic Animal Health

Multi-lithofacies alluvial characterization via airborne electromagnetic-borehole fusion using ordinary interval kriging and geologic constraints

Airborne electromagnetic (AEM) survey provides extensive spatial coverage and detailed resolution at the near surface and can be used to develop hydrogeological models. However, utilization of AEM data is not straightforward because AEM resistivity is an indirect measurement for inferring sediment types. This study develops an ordinary interval kriging (OIK) algorithm and a resistivity-to-multi-lithofacies (R2ML) data fusion workflow for multi-lithofacies alluvial characterization. OIK utilizes irregular interval data to construct three-dimensional (3D) resistivity fields from one-dimensional inverted AEM resistivity models. The R2ML workflow maps the resistivity field generated from OIK into a multi-facies lithological model, incorporating geologic constraints derived from well logs and geological observations. The numerical and real-world cases demonstrate that OIK is computationally efficient, accounts for 3D anisotropy, and minimizes the smoothing effect, thereby preserving resistivity contrasts and reducing interpolation uncertainty. The methodology is applied to lithologic characterization of the Mississippi River Valley alluvial aquifer (MRVA) in the Shellmound area, Mississippi, U.S. A frequency-domain AEM survey was conducted to support groundwater studies for the managed aquifer recharge (MAR) to the MRVA. The resulting lithological model, including four types of lithofacies—clay, very fine sand, fine-medium sands, and graveliferous sands, illustrates the geomorphological processes of the MRVA and implies potential MAR. The alignment between the lithological model and existing geological and hydrogeological investigations demonstrates that OIK and R2ML workflow effectively capture the subsurface architecture of the MRVA. The methods have broad applicability for characterizing alluvial aquifers through AEM-borehole data fusion, supporting sustainable groundwater management.

Mississippi

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

Applying U-Th disequilbrium for dating siliceous sinters

Continental hydrothermal systems are critical avenues for the crustal transport of heat and mass captured for geothermal energy and mineral exploration. Thus, understanding their temporal evolution and longevity is important for resource characterization. Deposits of microlaminated siliceous sinter, common surface expressions of high temperature reservoirs (> 170 °C), have the potential to trace hydrothermal histories. Geothermal reservoirs are often located within uranium-bearing silicic volcanic rock where subsurface fluid-rock interactions extract U into hydrothermal fluids. U incorporated in the surface sinter deposit has the potential to provide a U— Th disequilibrium dating option. We focus on samples from El Tatio geyser field in the Altiplano of northern Chile, the largest geothermal system in the Andes. Our resulting 230 Th/U ages, along with the water and deposit elemental compositions, suggest concentrations of U and Th vary predictably along the sinter apron. While distal facies containing the highest U concentrations (> 50 μg/g) are least affected by detrital Th corrections, they can display suspected open-system behavior. In contrast, more medial facies, where bacterial mats and other porous textures are co mmonly concentrated, have only trace amounts of U (< 0.1 μg/g), which leads to unreliable or geologically improbable dates. Proximal facies tend to date most consistently. By comparing existing 14 C ages with 230 Th/U results, 230 Th/U ages tend to be younger than the 14 C ages, supporting the presence of a 14 C-dead carbon influence. New data confirm that the onset of geothermal activity at El Tatio goes back to the late Pleistocene.

Altiplano, El Tatio geyser field

Improving crop-specific groundwater use estimation in the Mississippi Alluvial Plain: Implications for integrated remote sensing and machine learning approaches in data-scarce regions

Study region The Mississippi Alluvial Plain (MAP) in the United States (US). Study focus Understanding local-scale groundwater use, a critical component of the water budget, is necessary for implementing sustainable water management practices. The MAP is one of the most productive agricultural regions in the US and extracts more than 11 km 3 /year for irrigation activities. Consequently, groundwater-level declines in the MAP region pose a substantial challenge to water sustainability, and hence, we need reliable groundwater pumping monitoring solutions to manage this resource appropriately. New hydrological insights for the region We incorporate remote sensing datasets and machine learning to improve an existing lookup table-based model of groundwater use previously developed by the U.S. Geological Survey (USGS). Here, we employ Distributed Random Forests, an ensemble machine learning algorithm to predict annual and monthly groundwater use (2014–2020) throughout this region at 1-km resolution, using pumping data from existing flowmeters in the Mississippi Delta. Our model compares favorably with the existing USGS model, with higher R 2 (0.51 compared to 0.42 in the previous model), and lower root mean square error (RMSE) and mean absolute error (MAE)— 0.14 m and 0.09 m, respectively in our model, compared to 0.15 m and 0.1 m in the previous model. Therefore, this work advances our ability to predict groundwater use in regions with scarce or limited in-situ groundwater withdrawal data availability.

Journal of Hydrology Regional Studies

ShakeAlert® and schools: Incorporating earthquake early warning in school districts in Alaska, California, Oregon, and Washington

The U.S. Geological Survey-managed ShakeAlert® earthquake early warning system is the first public alerting system in the United States to provide rapid mass notification when an earthquake is detected. Although public alert delivery via mobile phones began in California in 2019 followed by Oregon and Washington in 2021, little is known about what might drive widespread implementation in at-risk institutional settings such as schools. For example, there has been limited research on how to best integrate earthquake early warning into existing emergency plans, alert systems, and drills to keep school children and personnel safe in an earthquake. To address this gap, in the spring of 2022, every school district superintendent in Alaska, California, Oregon, and Washington was sent a 15-min online survey. The survey assessed superintendent knowledge of ShakeAlert, preferences for alert messaging, and perceived opportunities and barriers to incorporating the system in schools. The results showed that superintendents had low awareness of ShakeAlert but held positive perceptions of the system's potential to enable life-saving protective actions. A major barrier to adoption included the perceived financial cost of implementing and maintaining the system. There were some statistically significant differences in state responses, and future research could investigate the specific needs of each state based on school district size and composition, hazard exposure, and earthquake experience. Together these findings can help inform targeted strategies to increase ShakeAlert adoption in schools and ultimately improve the safety of school children and staff during earthquakes.

Alaska, California, Oregon, Washington

Geophysical architecture and geochronology of the Neoarchean Mentor anorthosite intrusive complex, northwestern Minnesota: Largest anorthosite complex of the Superior Province?

The Neoarchean Mentor anorthosite intrusive complex (MAIC) lies within the Wawa subprovince in northwestern Minnesota, in a region where the Wawa, Quetico, and Wabigoon subprovinces are juxtaposed in close proximity. Archean rocks are entirely concealed, and interpretations are developed from aeromagnetic, gravity, and borehole samples. The MAIC includes both anorthosite (dense, weakly magnetized) and oxide-rich gabbro (strongly magnetized) lithologies. Anorthosite is coarse-grained to megacrystic, intensely altered, and locally brecciated. Pervasive epidote alteration enhanced the density of the anorthosite via introduction of higher-density mineral assemblages, explaining why the MAIC produces a significant gravity high. Oxide-rich gabbro forms a border phase of the MAIC and has potential for vanadium, chromium, and titanium mineralization, and produces a strong aeromagnetic high. The MAIC is interpreted to extend over an area of 640 km 2 , making it the largest known anorthosite complex of the Superior Province, as measured by preserved areal extent. Modeling indicates the MAIC extends more than 6 km into the subsurface. A new Pb–Pb zircon age of 2737.2 ± 4.5 Ma is interpretated as the crystallization age of anorthosite within the MAIC, showing that the MAIC formed well before the ca. 2690 Ma Shebandowanian orogeny, and raising new questions about correlations with other parts of the Wawa subprovince. A low-density batholith, here informally called the Fertile batholith, is interpreted to intrude the southern part of the MAIC. A new Pb–Pb zircon age of 2701.1 ± 6 Ma is interpreted as the magmatic age of the Fertile batholith.

Minnesota

New constraints on location and timing of the Great Lakes tectonic zone, central Upper Peninsula, Michigan, USA

The Great Lakes tectonic zone (GLTZ) forms the boundary between the Wawa–Abitibi and Minnesota River Valley subprovinces within the Archean Superior Province. The GLTZ is concealed for all of its 1100 km length, except for a segment in the central Upper Peninsula of Michigan. There, it is exposed as a northwest-striking mylonite zone along a 11 km segment, extending to the onlap of Paleozoic rocks to the east. Farther east, its location has been unknown. Here, we use aeromagnetic and gravity data to develop interpretations of the expression of the GLTZ and to define its extent under cover. Aeromagnetic gradients over the mylonite zone are interpreted to be produced by structurally juxtaposed rocks with varying magnetizations. Gravity data show a regional gradient along the GLTZ, produced by the juxtaposition of a dense greenstone belt on the north against lower-density gneisses and granites on the south. The GLTZ is interpreted to extend ∼55 km under cover to the east. The GLTZ is terminated on the east by the buried eastern arm of the ca. 1100 Ma Midcontinent Rift. An undeformed granitic dike that cuts the mylonitic foliation produces a U–Pb apatite age of 2523 ± 33 Ma, implying no major post-Archean shearing occurred, and is at odds with previous interpretations of major Proterozoic reactivation. A granite intrusion in the Minnesota River Valley subprovince produces a Pb–Pb zircon age of 2606.9 ± 3.6/7.4 Ma. This suggests that magmatism related to the Sacred Heart orogeny, previously known in Minnesota, extended to Michigan.

Michigan

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey

Top-down targeted network analysis of critical mineral commodities applied to international geochemistry database

The global demand for critical mineral commodities is rapidly increasing, making domestic production an important factor in supporting the economy and national security. Large scale, publicly available geochemical databases allow for the application of data informatics methods to interrogate critical mineral commodities data for correlations in deposit formation and distribution, particularly for identifying enrichment of multiple critical mineral commodities at the same deposit. In this study, we applied network analysis to the Critical Minerals Mapping Initiative (CMMI) ore geochemistry (Critical Minerals in Ores, CMiO) database to identify the high concentration (defined as 10× bulk crustal abundance) co-occurrence of different critical mineral commodities across a mineral system hierarchy from deposit environments to individual deposits. Identifying patterns or unique outliers in enrichment in network communities will allow for the location of secondary critical mineral commodity resources from under-utilized deposits. We find trends in the enrichment of critical mineral commodities in network-communities between the elements praseodymium (Pr), neodymium (Nd), terbium (Tb), and dysprosium (Dy) across multiple CMiO database deposit environments and groups down to specific deposit types and sites. A separate trend in network community deposition is observed as well between iridium (Ir) and platinum (Pt) in deposit environments, groups, types, and sites. Network analysis focused on critical minerals in magmatic-hydrothermal deposits identified multiple deposit sites from different deposit types within the CMiO database with concentrations of Dy, Nd, Tb, Pr, Ir, and Pt that are at least ten times greater than the crustal average. This approach can be applied to any target element(s) or deposit(s) of interest, allowing broad investigation of co-enriched critical mineral commodities.

Journal of Geochemical Exploration

Evaluation of water quality in the Langford Valley–Irwin Groundwater Subbasin, Fort Irwin National Training Center, California, 1993–2019

The U.S. Army Fort Irwin National Training Center (NTC), 120 miles northeast of Los Angeles in the Mojave Desert of California, obtains its potable water supply from the Bicycle Valley and Langford Valley groundwater basins; Langford Valley groundwater basin is further subdivided into the Langford Well Lake and Irwin groundwater subbasins. The Irwin groundwater subbasin contains younger, unconsolidated deposits that have a saturated thickness of as much as 200 feet (ft) and a lower aquifer within older unconsolidated deposits as thick as 650 ft. Groundwater recharge under predevelopment conditions (before 1941) occurred primarily from infiltration of intermittent streamflow in small washes that cross the Irwin groundwater subbasin. Since that time, groundwater recharge has increased because of growth of the NTC in recent years and as a result of other processes, including (1) infiltration of treated wastewater into the aquifer through ponds near the NTC wastewater treatment facility (WWTF) and (2) infiltration of imported water and treated wastewater used for landscape irrigation at base housing and athletic fields. Water samples were collected from 17 wells and analyzed for field parameters, chemical constituents, and isotope composition in the Irwin groundwater subbasin between 2014 and 2019. These data were supplemented with water-chemistry data collected during 1993–95 and at other times if available. Between 1993–95 and 2015–19, median dissolved solids and nitrate concentrations in water from wells in the Irwin groundwater subbasin increased from 620 to 1,030 milligrams per liter (mg/L) and from 2.8 to 4.5 mg/L as nitrogen, respectively. After 2014, dissolved solids and nitrate concentrations in water from wells near the NTC WWTF decreased as a result of changes in source water quality attributable to reverse osmosis of treated drinking water delivered within the Irwin groundwater subbasin and to increased levels of treatment at the NTC WWTF. Based on delta oxygen-18 and delta deuterium isotope data, increases in dissolved solids concentrations in water from most wells were consistent with evaporation prior to recharge and mobilization of soluble salts from the unsaturated zone. Arsenic and fluoride concentrations in water from wells decreased between 1993–95 and 2015–19 as the basin filled with treated wastewater, but 2015–19 concentrations generally exceeded the California State Water Resources Control Board maximum contaminant levels of 10 micrograms per liter for arsenic and 2 mg/L for fluoride. Most groundwater in the Irwin groundwater subbasin has unadjusted carbon-14 ages ranging from 18,400 to 12,350 years before present. However, water from well 10E3, located along the wash near the subbasin outflow in the southeastern part of the Irwin groundwater subbasin, contained measurable tritium, which is consistent with infiltration of intermittent streamflow and groundwater recharge from the wash after 1952. Chemical and isotopic data indicate that treated wastewater is present in water from most wells in the upper aquifer that underlies the Irwin groundwater subbasin. Wells were not sampled to adequately determine the extent of treated wastewater and changes in water quality within the lower aquifer that underlies the Irwin groundwater subbasin.

California

Exploring the uncertainty of machine learning models and geostatistical mapping of rare earth element potential in Indiana coals, USA

Rare earth elements and yttrium (REEs) have a wide range of applications in high- and low-carbon technologies. The strategic significance of REEs has grown due to their expanding applications in manufacturing industries and the constrained availability of these essential resources. This research explores the applicability of machine learning models and their uncertainty for assessing the REE potential in coal beds using various coal parameters as inputs. The work focuses on developing a predictive model based on geological variables, excluding considerations related to potential shifts in the commodities market. The Indiana Coal Quality Database was used as the data source. The promising and unpromising indicators derived from the outlook coefficient of samples from the database were used as the REE potential indicator for machine learning classification models. The filter-based approach with bootstrap was used to evaluate the importance of the coal parameters and their prediction uncertainties. Four machine learning methods (linear discriminant analysis (LDA), random forest (RF), support vector machine (SVM), and artificial neural networks (ANN), a data balancing and augmentation approach (Synthetic Minority Over-sampling Technique), and bootstrap resampling techniques were used for building the models and evaluating their prediction capabilities under uncertainty. It was determined that the SVM bootstrap model with ten-times balanced and augmented data provided superior results compared with other models. Finally, stochastic spatial maps of the REE potential within the coal basin were generated using sequential indicator simulation. The spatial maps of the REE potential showed that a 29% area of the Indiana section of the Illinois coal basin has economic potential of REEs, with 90% confidence.

Indiana

Complex hydrology and variability of nitrogen sources in a karst watershed

Streams draining karst areas with rapid groundwater transit times may respond relatively quickly to nitrogen reduction strategies, but the complex hydrologic network of interconnected sinkholes and springs is challenging for determining the placement and effectiveness of management practices. This study aims to inform nitrogen reduction strategies in a representative agricultural karst setting of the Chesapeake Bay watershed (Fishing Creek watershed, Pennsylvania) with known elevated nitrate contamination and a previous documented groundwater residence time of less than a decade. During baseflow conditions, streamflow did not increase with drainage area. Headwaters and the main stem lost substantial flow to sinkholes until eventually discharging along large springs downstream. Seasonal hydrologic conditions shift the flow and nitrogen load spatially among losing and gaining stream sections. A compilation of nitrogen source inputs with the geochemistry and the pattern of enrichment of δ 15 N and δ 18 O suggest that the nitrogen in streams and springs during baseflow represents a mixture of manure, fertilizer, and wastewater sources with low potential for denitrification. The pH and calcite saturation index increased along generalized flow paths from headwaters to springs and indicate shorter groundwater residence times in baseflow during the spring versus summer. Given the substantial investment in management practices, fixed monitoring sites could incorporate synoptic water sampling to properly monitor long-term progress and help inform management actions in karst watersheds. Although karst watersheds have the potential to respond to nitrogen reduction strategies due to shorter groundwater residence times, high nitrogen inputs, effectiveness of conservation practices, and release of legacy nutrients within the karst cavities could confound progress of water quality goals.

Pennsylvania

Fiber-imaged supershear dynamics in the 2024 Mw 7 Mendocino Fault earthquake

Fault structure and rupture physics are deeply intertwined, and observations of this coupling are critical for understanding earthquake behavior. Rupture propagation is observable at fine scales using dense seismic networks. Fiber-optic sensing allows for long-term deployments of ultradense arrays that enable high-resolution measurements of infrequent, large earthquakes. We recorded the 2024 moment magnitude ( M w ) 7 Mendocino Fault earthquake with a nearby fiber-optic array and imaged its behavior with seismic beamforming. The rupture propagated to the east at subshear velocity; stagnated near the Mendocino Triple Junction, a zone of structural complexity; and subsequently transitioned to supershear velocity. The correlation between source physics and structure shows how lithospheric heterogeneity affects first-order characteristics of earthquake ruptures. Our results also demonstrate the potential for fiber-optic sensing to improve real-time estimation of key parameters for early warning.

California

Long-term communication of aftershock forecasts: The Canterbury earthquake sequence in New Zealand

On 14 February 2016, a magnitude (M)5.7 earthquake struck in Christchurch New Zealand (Aotearoa in the Maori language). The shaking caused damage to historic facades, power outages, cliff collapses, rock falls, and liquefaction but no reported injuries or fatalities. This Valentine’s Day earthquake was an aftershock in the Canterbury earthquake sequence (CES), which began on 4 September 2010 with the M7.1 Darfield Earthquake and included the destructive and fatal M6.2 Christchurch aftershock on 22 February 2011. This study, eight months after the Valentine’s Day earthquake and six years after the initiation of the CES, is the first to explore long-term aftershock forecast information and communication needs. The exploratory study also aimed to gather feedback on aftershock scenarios, an alternative form for communicating the forecast. The qualitative study involved workshops with emergency managers, public health officials, and members of the public in Christchurch. Key findings for long-term communication throughout an earthquake sequence include: 1. divergent earthquake experiences affect aftershock communication response and information needs; 2. understanding aftershock sequence behavior is foundational to sense-making when large aftershocks occur; 3. strategic earthquake sequence updates from the trusted science agency and local agencies could serve as important reminders for earthquake preparedness; 4. communication of aftershock forecast uncertainty could aid with both the credibility of the information and living with uncertainty, and 5. inclusion of impact information and preparedness advice into aftershock forecast scenarios could provide links to actionable information. The paper derives implications for research and practice of long-term communications during an aftershock sequence.

Christchurch