Geology topics

Research about Texas

Source-linked reports with geographic coverage including Texas.

At least 145 records · Page 8Linked to original sources

USGS2020

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Medina County, Texas

The karstic Edwards and Trinity aquifers are classified as major sources of water in south-central Texas by the Texas Water Development Board. During 2018–20 the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, mapped and described the geologic framework and hydrostratigraphy of the rocks composing the Edwards and Trinity aquifers in northern Medina County from field observations of the surficial expressions of the rocks. The thicknesses of the mapped lithostratigraphic members and hydrostratigraphic units were also estimated from field observations. The Cretaceous-age rocks (listed in ascending order) in the study area are part of the Trinity Group (lower and upper members of the Glen Rose Limestone), Edwards Group (Kainer Formation [and its stratigraphic equivalent, the Fort Terrett Formation] and Person Formation), Devils River Limestone, Washita Group (Georgetown Formation, Del Rio Clay, and Buda Limestone), Eagle Ford Group, Austin Group, Taylor Group, and Late Cretaceous igneous intrusive rocks. The groups and formations are composed primarily of relatively thick layers of clays, shales, and limestone. The igneous rocks are coarse-grained ultramafic in composition. The principal structural feature in northern Medina County is the Balcones fault zone, which is the result of late Oligocene and early Miocene extensional faulting and fracturing resulting from the eastern Edwards Plateau uplift. In the Balcones fault zone, most of the faults in the study area are high-angle to vertical, en echelon, normal faults that are predominately downthrown to the southeast. Hydrostratigraphically, the rocks exposed in the study area (listed in descending order from land surface as they appear in a stratigraphic column) are igneous, the upper confining unit to the Edwards aquifer, the Edwards aquifer, the upper zone of the Trinity aquifer, and the upper part of the middle zone of the Trinity aquifer. The karstic carbonate Edwards and Trinity aquifers developed as a result of their original depositional history, primary and secondary porosity, diagenesis, fracturing, and faulting. These factors have resulted in development of modified porosity, permeability, and transmissivity within and between the aquifers.

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USGS2020

Effects of urbanization on water quality in the Edwards aquifer, San Antonio and Bexar County, Texas

Overview Continuous water-quality monitoring data and chemical analysis of surface-water and groundwater samples collected during 2017–19 in the recharge zone of the Edwards aquifer were used to develop a better understanding of the surface-water/groundwater connection in and around Bexar County in south-central Texas. This fact sheet is provided to inform water-resource managers, city planners, the scientific community, and the general public about the effects of urbanization on water quality in the Edwards aquifer recharge zone.

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USGS2020

Temporal and spatial variability of water quality in the San Antonio segment of the Edwards aquifer recharge zone, Texas, with an emphasis on periods of groundwater recharge, September 2017–July 2019

Ongoing urbanization on the Edwards aquifer recharge zone in the greater San Antonio area raises concern about the potential adverse effects on the public water supply from development. To address this concern, the U.S. Geological Survey, in cooperation with the City of San Antonio, studied patterns of temporal and spatial changes in water quality at selected surface-water and groundwater sites in the Edwards aquifer recharge zone, with an emphasis on changes during periods of groundwater recharge. Water-quality characteristics were continuously monitored and discrete water samples were collected at two sets of paired surface-water (stream) and groundwater (well) sites during a 2-year period (2017–19) that included relatively dry conditions and a large recharge event in September 2018 when as much as 16 inches of rain fell in parts of the study area. Continuous monitoring of water-level altitude, specific conductance, and concentrations of nitrate in two wells completed in the Edwards aquifer provided high-resolution data showing detailed changes in water quality across a broad range of hydrologic conditions. Water levels in the wells responded rapidly (within hours to days) to recharge from both small and large rainfall and runoff events; changes in groundwater quality as a consequence of the influx of surface-derived recharge were indicated by changes in values of the monitored characteristics. A broad range in measured values of the stable isotopes of water expressed as delta deuterium and delta oxygen-18 in the water samples collected from two streams (Salado and West Elm Creeks), in comparison to the tight clustering of the values of these isotopes in groundwater samples, indicates that source waters (surface waters) of widely varying chemical characteristics become homogenized within the aquifer system. Concentrations of major ions, trace ions, and nutrient concentrations in stormwater runoff indicate a combination of land-derived and rainfall-derived constituents. The distribution of concentrations of nitrogen species (nitrite, nitrate, and nitrogen in ammonia) among sampling sites transitions from a more variable distribution in stormwater runoff to a more uniform distribution in groundwater in which the dominant form is nitrate. Differences in nitrate isotopic composition and concentration in groundwater across the study area are likely controlled by the relative contributions of natural and anthropogenic nitrogen (with the anthropogenic nitrogen component including a wastewater source) and by the process of nitrification. Among all measured constituents, pesticides detected in discrete stormwater-runoff samples provided the clearest indication that urbanization was adversely affecting water quality; specifically, the more urbanized surface-water site had a greater number of detections and greater variety of detected pesticides. Though temporal variability in the numbers and types of pesticides was evident, the overall proportion of pesticides was dominated by triazine herbicides including atrazine, atrazine degradates, and simazine. The observed hydrologic responses to rainfall and corresponding changes in water quality in wells are thought to result from the direct hydrologic connectivity of surface water and unconfined groundwater; however, patterns of groundwater-quality change indicate mixing from multiple sources such as ambient groundwater, recent surface-derived recharge, and possibly inflow from other aquifers. Therefore, understanding the connection between urbanization and groundwater quality cannot be inferred from the input of stormwater runoff alone as changes related to local and regional hydrologic conditions also need to be considered. It should be noted that a single study comparing the results from two site pairs is not able to support definitive conclusions about the full effect of urbanization on surface water/groundwater quality; however, this study does provide useful insights about the spatial and temporal variability of both stormwater runoff and unconfined groundwater that are consistent with expectations based on the current conceptual model that depicts the Edwards aquifer surface-water/groundwater system as a single water resource.

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USGS2020

Status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers, Houston-Galveston region, Texas, 2020

Since the early 1900s, most of the groundwater withdrawals in the Houston-Galveston region, Texas, have been from the three primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers. Withdrawals from these aquifers are used for municipal supply, commercial and industrial use, and irrigation. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of groundwater-level altitudes and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers in the Houston-Galveston region. This report contains regional-scale maps depicting approximate 2020 groundwater-level altitudes (represented by measurements made during December 2019 through March 2020) and long-term groundwater-level changes in the Chicot, Evangeline, and Jasper aquifers. In 2020, groundwater-level-altitude contours for the Chicot aquifer ranged from 150 feet (ft) below the North American Vertical Datum of 1988 (hereinafter referred to as “datum”) to 200 ft above datum. The 1977–2020 groundwater-level-change contours for the Chicot aquifer depict a large area of decline in groundwater-level altitudes (120 ft) in northwestern Harris County. The largest rise in groundwater-level altitudes in the Chicot aquifer from 1977 to 2020 (200 ft) was in southeastern Harris County. In 2020, groundwater-level-altitude contours for the Evangeline aquifer ranged from 250 ft below datum to 200 ft above datum. The 1977–2020 groundwater-level-change contours for the Evangeline aquifer depict broad areas where groundwater-level altitudes either declined or rose. The largest decline in groundwater-level altitudes (280 ft) was in southern Montgomery and northern Harris Counties. The largest rise in groundwater-level altitudes in the Evangeline aquifer from 1977 to 2020 (240 ft) was in southeastern Harris County. In 2020, groundwater-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum to 250 ft above datum. The 2000–20 groundwater-level-change contours for the Jasper aquifer depict groundwater-level declines throughout most of the study area where groundwater-level-altitude data from the Jasper aquifer were collected, with the largest decline (220 ft) in southern Montgomery County.

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USGS2020

Steps taken for calculating estimated ultimate recoveries of wells in the Eagle Ford Group and associated Cenomanian–Turonian strata, U.S. Gulf Coast, Texas, 2018

In 2018, the U.S. Geological Survey published an assessment of technically recoverable continuous oil and gas resources of the Eagle Ford Group and associated Cenomanian–Turonian strata in the U.S. Gulf Coast of Texas. Estimated ultimate recoveries (EURs) were calculated with production data from IHS Markit TM using DeclinePlus software in the Harmony interface. These EURs were a major component of the aforementioned quantitative resource assessment fact sheet. The calculated mean EURs for each oil assessment unit (AU) ranged from 113,000 barrels of oil in the Cenomanian–Turonian Mudstone Continuous Oil AU to 223,000 barrels of oil in the Submarine Plateau-Karnes Trough Continuous Oil AU. The calculated mean EURs for each gas AU ranged from 2.261 billion cubic feet of gas in the Submarine Plateau-Karnes Trough Continuous Gas AU to 3.116 billion cubic feet of gas in the Eagle Ford Marl Continuous Gas AU.

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USGS2020

Assessment of water and proppant quantities associated with petroleum production from the Eagle Ford Group, Gulf Coast, Texas, 2019

Building on a geology-based assessment of undiscovered, technically recoverable petroleum resources in the Eagle Ford Group in south Texas, the U.S. Geological Survey has estimated the required water and proppant demands and formation water production volumes associated with possible future development of these petroleum resources. The results of the water and proppant assessment are presented here, along with related drilling information and relevant water budget volumes for the region.

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USGS2020

The utility of zooarchaeological data to guide listing efforts for an imperiled mussel species (Bivalvia: Unionidae: Pleurobema riddellii)

The status of species in freshwater systems shift over time due to natural and anthropogenic causes. Determining the magnitude and cause of these shifts requires a long-term perspective. This process is complicated when there are also questions about the taxonomic validity of a species. Addressing these issues is important because both can undermine conservation and management efforts if incorrect. Pleurobema riddellii , Louisiana Pigtoe, is under review for protection under the U.S. Endangered Species Act, but its status in the Trinity River basin, where the taxon was described, remains in doubt due to questions about its taxonomy and occurrence within this basin. To address these questions, we compared shell morphometrics of P. riddellii dating to the late Holocene with modern P. riddellii , late Holocene Fusconaia sp., and modern Fusconaia sp. using multivariate analyses to test associations between the putative morphotypes. Based on these analyses, we demonstrate that P. riddellii was likely present in the Trinity during the late Holocene, which indicates questions about its taxonomic validity or presence in this basin are unfounded. Our study further highlights the role zooarchaeological studies can play in status assessments and their utility in better understanding biogeographic patterns for rare species.

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USGS2020

Procedure for calculating estimated ultimate recoveries of wells in the Wolfcamp shale of the Midland Basin, Permian Basin Province, Texas

In 2016, the U.S. Geological Survey published an assessment of technically recoverable continuous oil and gas resources of the Wolfcamp shale in the Midland Basin, Permian Basin Province, Texas. Estimated ultimate recoveries (EURs) were calculated with production data from IHS Markit TM using DeclinePlus software in the Harmony interface. These EURs were a major component of the quantitative resource assessment. For five of the six assessment units in the study, an industry operator in the Midland Basin provided information that was used to differentiate the Wolfcamp horizontal well landing zones. The IHS Markit TM production database does not distinguish between the Wolfcamp A, B, C, and D well landing zones. These different units of the Wolfcamp have different production patterns that are important for calculation of EURs. The calculated mean EURs for each assessment unit ranged from 99,000 barrels of oil in the Wolfcamp C to 142,000 barrels of oil in the Wolfcamp A.

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USGS2020

Hydrodynamic modeling results showing the effects of the Luce Bayou interbasin transfer on salinity in Lake Houston, TX

An overreliance on groundwater resources in the Houston (Texas) metropolitan area led to aquifer drawdowns and land subsidence, so regional water suppliers have been turning to surface water resources to meet water demand. Lake Houston, an important water supply reservoir 24 kilometers (15 miles) northeast of downtown Houston, requires new water supply sources to continue to meet water supply demands for the next several decades. The upcoming Luce Bayou Interbasin Transfer Project will divert up to 500 million gallons per day of Trinity River water into Lake Houston. Trinity River water has significantly different water quality than the Lake Houston tributaries. To evaluate the project’s potential effect on water quality, the U.S. Geological Survey used an enhanced version of a previously released Lake Houston hydrodynamic model. With a focus on salinity and water-surface elevations, the model combined data from 2009 to 2017 with simulated flow from the Luce Bayou Interbasin Transfer to evaluate potential outcomes from three hypothetical flow scenarios. Overall, these scenarios found that the Luce Bayou Interbasin Transfer would cause salinities to moderately rise over most of the modeled time (2009–2017), although salinities were buffered under 2011 drought conditions. Large inflow events equalized salinities under baseline conditions as well as the enhanced flow scenarios.

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USGS2020

Effects of huisache removal on rangeland evapotranspiration in Victoria County, south-central Texas, 2015–18

The U.S. Geological Survey and Desert Research Institute, in cooperation with the Natural Resources Conservation Service, Texas State Soil and Water Conservation Board, Victoria County Groundwater Conservation District, Victoria Soil and Water Conservation District, and the San Antonio River Authority, evaluated the hydrologic effects of Vachellia farnesiana var. farnesiana (huisache) removal on rangeland evapotranspiration in Victoria County, Texas. Measurements of evapotranspiration, rainfall, and related properties were made at two sites during March 2015 through August 2018. One site was predominantly grassland. The other site was dominated by dense huisache vegetation that was removed about halfway through the study period. The resulting evapotranspiration data were examined for differences between the locations and differences between the pre-removal (2015–16) and post-removal (2017–18) periods to assess the effects of huisache removal on evapotranspiration. Evapotranspiration measurements were made using the eddy-covariance technique and were supplemented by remote-sensing estimates of evapotranspiration derived from thermal and optical satellite images. A map of remotely sensed evapotranspiration was generated for the area surrounding the study sites for 2015 and demonstrates the capability of remote sensing to evaluate land-management effects on evapotranspiration for larger scale areas, such as a county or stream-basin area. During the pre-removal period (March 2015–December 2016), evapotranspiration was greater at the huisache site than at the grassland site. Evapotranspiration at the grassland site (average of the eddy-covariance evapotranspiration and average remotely sensed evapotranspiration) was 87.6 millimeters per month (mm/mo) and at the huisache site was 100.8 mm/mo, with the differences in evapotranspiration rates being attributed to the difference in site vegetation. After huisache was removed in January 2017, evapotranspiration at the huisache site was substantially lower than at the grassland site, the changes in evapotranspiration rates being attributed not only to removal of huisache vegetation but also to possible disruption of soil runoff and infiltration characteristics. During the post-removal period (February 2017–August 2018), evapotranspiration was 88.5 mm/mo at the grassland site and 72.9 mm/mo at the huisache site (average of the eddy-covariance and average remotely sensed evapotranspiration). The monthly differences in evapotranspiration between the grassland and huisache sites, determined by eddy-covariance and remote-sensing methods, were statistically significant between the pre-removal and post-removal periods. Also, the pre-removal period provided the best conditions to evaluate the differences between huisache site and grassland site evapotranspiration. During the pre-removal period, evapotranspiration from the huisache site as measured by the eddy-covariance method was, on average, 10.7 mm/mo greater than evapotranspiration measured at the grassland site. As determined by the average of the remotely sensed methods, huisache site evapotranspiration was 15.8 mm/mo greater than grassland site evapotranspiration. These average differences in evapotranspiration rates by the two methods indicate that evapotranspiration at the grassland site was, on average, 13.2 mm/mo less than that at the huisache site during the pre-removal period. This average difference in evapotranspiration rates also indicates potential increased groundwater recharge and (or) surface-water runoff at the grassland site.

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USGS2020

Water-quality comparison of the Gulf Coast aquifer system at various scales in Texas from National Water-Quality Assessment groundwater studies, 2013–15

One of the objectives of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Project is to assess groundwater quality in aquifers that are important sources of drinking water such as the coastal lowlands aquifer system, which is often referred to in Texas as the “Gulf Coast aquifer system.” The Gulf Coast aquifer system extends from Louisiana to Mexico and is a source of groundwater for several cities including Houston, Tex. The NAWQA groundwater studies in Texas in 2013–15 that assessed the Gulf Coast aquifer system included Principal Aquifer Surveys (PAS), Major Aquifer Studies (MAS), and Land Use Studies (LUS). These three study types are based on sampling networks of wells distributed in an area of interest. The PAS networks typically consist of public-supply wells that are relatively deep, the MAS networks typically consist of domestic-supply wells that are intermediate in depth, and the LUS networks typically consist of monitoring wells that are relatively shallow.

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USGS2020

Towards reproducible environmental modeling for decision support: A worked example

A fully worked example of decision-support-scale uncertainty quantification (UQ) and parameter estimation (PE) is presented. The analyses are implemented for an existing groundwater flow model of the Edwards aquifer, Texas, USA, and are completed in a script-based workflow that strives to be transparent and reproducible. High-dimensional PE is used to history-match simulated outputs to corresponding state observations of spring flow and groundwater level. Then a hindcast of a historical drought is made. Using available state observations recorded during drought conditions, the combined UQ and PE analyses are shown to yield an ensemble of model results that bracket the observed hydrologic responses. All files and scripts used for the analyses are placed in the public domain to serve as a template for other practitioners who are interested in undertaking these types of analyses.

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USGS2020

Water-quality comparison of the Gulf Coast aquifer system and Carrizo-Wilcox aquifer in Texas from National Water-Quality Assessment Project Principal Aquifer Surveys, 2013 and 2015

The U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Project assessed the quality of groundwater in aquifers that are important sources of drinking water in the United States. One major aquifer in Texas that was assessed by NAWQA in 2013 is the coastal lowlands aquifer system, which is often referred to in Texas as the “Gulf Coast aquifer system.” The coastal lowlands aquifer system supplies water for millions of people; self-supplied (private) well withdrawals in 2005 from this aquifer system were the sixth largest among all major aquifer systems in the Nation. A major aquifer in Texas that was assessed by NAWQA in 2015 is the Texas coastal uplands aquifer system; the Carrizo-Wilcox aquifer is one of several aquifers that compose this aquifer system in Texas. The rocks composing the Texas coastal uplands aquifer system extend east from Texas as part of the Mississippi embayment aquifer system and underlie areas of several States. The Texas coastal uplands aquifer system and Mississippi embayment aquifer system are often collectively referred to as the “Mississippi embayment-Texas coastal uplands aquifer system.” Self-supplied withdrawals from the Mississippi embayment-Texas coastal uplands aquifer system in 2005 were the eighth largest among all major aquifer systems in the Nation. The coastal lowlands aquifer system and Mississippi embayment-Texas coastal uplands aquifer system were assessed as part of the NAWQA Principal Aquifer Surveys (PAS), which were designed to evaluate constituent concentrations in water samples obtained from domestic and public-supply wells prior to any treatment. PAS assessments like these allow for the comparison of water-quality concentrations in untreated groundwater using preestablished benchmarks for the protection of human health and for aesthetic qualities such as taste, color, and odor. The use of preestablished benchmarks can provide a basis for comparison of groundwater quality among principal aquifers.

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USGS2020

Urban stream syndrome and contaminant uptake in salamanders of Central Texas

We studied the ecological health of springs experiencing varying levels of urban development to assess impacts to rare endemic salamanders ( Eurycea spp.) of Central Texas. We evaluated measures of invertebrate species richness, water quality, and contaminant uptake by salamanders to determine how springs and their inhabitants were being affected by urban growth and changing land-use patterns. The number of environmental contaminants present and concentrations of contaminants increased in both water and salamander tissues with increasing age of the developments (i.e., years postconstruction) and increasing levels of impervious cover (e.g., roads) in urban watersheds compared with nondeveloped sites. We conclude that urbanization and associated increases in pollutant loading in watersheds can result in a loss of spring biodiversity and the accumulation of persistent and potentially toxic pollutants in salamanders. Although we detected generally low levels of pollutants, the altered water quality and invertebrate composition observed at springs, coupled with the changing hydrology and chronic contaminant exposure inherent in urban landscapes, is cause for concern, with potential implications for the long-term health, survival, and recovery of salamanders.

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USGS2020

Monocrotophos and dicrotophos residues in birds as a result of misuse of organophosphates in Matagorda county Texas USA

About 1100 birds of 12 spp. [Red-winged blackbird ( Agelaius phoeniceus ), great-tailed grackle ( Quiscalus mexicanus ), brown-headed cowbird ( Molothrus ater ), mourning dove ( Zenaida macrours ), Eastern meadowlark ( Sturnella magna ), vesper sparrow ( Pooecetes gramineus ), common snipe ( Gallinago gallinago ), blue-winged teal ( Anas discors ), mottled duck ( Anas fulvigula ), common moorhen ( Gallinula chloropus ), redhead ( Aythya americana ) and ruddy turnstone ( Arenaria interpres )] died from organophosphate poisoning in Matagorda County on the Texas Gulf Coast in March and May 1982. Birds died from feeding on rice seed that was illegally treated with dicrotophos or monocrotophos and placed near rice fields as bait to attract and kill birds. Brain acetylcholinesterase inhibition of affected birds averaged 87% (range 82-89%), and contents of gastrointestinal tracts contained residues of dicrotophos (5.6-14 ppm) or monocrotophos (2.1-13 ppm). Rice seed collected at mortality sites contained 210 ppm dicrotophos or 950 ppm monocrotophos. Mortality from dicrotophos poisoning continued for almost 3 wk. The practice of illegally treating rice seed with either of the 2 organophosphates appears to be infrequent but widespread at present.

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USGS2020

Precipitation, temperature, groundwater-level elevation, streamflow, and potential flood storage trends within the Brazos, Colorado, Big Cypress, Guadalupe, Neches, Sulphur, and Trinity River basins in Texas through 2017

The U.S. Geological Survey (USGS), in cooperation with the U.S. Army Corps of Engineers (USACE), analyzed streamflow trends and streamflow-related variables through 2017 in seven important water-supply basins to provide information that can help water managers with the USACE and river authorities make future water management decisions. The primary purpose of this report is to document trends in long-term streamflow data at 114 selected USGS streamflow-gaging stations and 36 simulated reservoir-inflow stations in 7 river basins primarily in Texas: Brazos, Colorado, Big Cypress, Guadalupe, Neches, Sulphur, and Trinity. In this report, trends were considered statistically significant if their p -values were less than or equal to 0.05 ( p -value ≤0.05). Streamflow data selected for temporal trend analyses included annual minimum streamflow, annual peak streamflow, and streamflow volume. Precipitation, air temperature, and groundwater-level-elevation data were analyzed for trends that may help to explain changes observed in the streamflow statistics. Basins were divided into sections along county lines for precipitation analyses. Streamflow volumes were analyzed for associations with potential flood storage. The potential flood storage, defined as the difference between maximum storage and normal storage, was computed for each dam from the National Inventory of Dams database and accumulated over time based on the completion date of the dam. Precipitation and air temperature trends were analyzed for each of the eight climate divisions (High Plains, Trans-Pecos, Low Rolling Hills, Edwards Plateau, North Central Texas, South Central Texas, East Texas, and Upper Coast). Results of precipitation trend analyses indicated moderate upward trends in the Upper Coast and East Texas Climate Divisions analyzed on an annual time step from 1900 through 2017. These two climate divisions are in the eastern and southeastern parts of the State, and they receive more mean annual precipitation (45.88 and 46.09 inches, respectively) than the other climate divisions. The results of air temperature analyses indicated upward trends in annual mean air temperature within all climate divisions, with a mean slope of 0.02 degree Fahrenheit per year, or 1 degree every 50 years. Within the Brazos River Basin, results of precipitation trend analyses on an annual time step indicated that precipitation amounts are most likely increasing in the lower and middle sections of the basin. Downward trends in annual streamflow and in the ratio of streamflow volume to precipitation volume were indicated at 7 of the 15 stations in the upper sections of the basin. The lower sections of the basin had mostly downward trends in annual minimum streamflow, whereas upward trends in annual minimum streamflow were indicated in the upper sections of the basin. Downward trends in annual peak streamflow were indicated at many of the stations in the upper sections of the basin. At the same seven stations in the upper sections of the basin where there were downward trends in annual streamflow, there were also downward trends in the ratio of streamflow volume to precipitation volume. The data from the same seven stations indicated negative associations between potential flood storage volume and annual streamflow volume and downward trends in the ratio of annual streamflow volume to potential flood storage volume. With the known addition of 13,006,394 acre-feet of potential flood storage between 1900 and 2010 in the subbasins analyzed, streamflow volumes have decreased in the upper sections of the Brazos River Basin. Within the Colorado River Basin, results of precipitation trend analyses on an annual time step indicated no trends in the basin. Downward trends in annual streamflow were indicated at 16 stations in the upper sections of the basin, whereas no trends in annual streamflow were indicated in the lower section of the basin. In the lower section of the basin, one station that was operated as a continuous streamflow-gaging station through 2017 had a downward trend in annual minimum streamflow, and another station (operated through 2007) had an upward trend in annual minimum streamflow. In the upper sections of the basin, data from seven stations indicated upward trends in annual minimum streamflow, and data from six stations indicated downward trends. Data from 18 stations in the upper sections of the basin indicated downward trends in annual peak streamflow. Thirteen of the 16 stations in the upper sections of the basin with data that indicated downward trends in annual streamflow also have data that indicated downward trends in the ratio of streamflow volume to precipitation volume. Data from the same 13 stations indicated negative associations between potential flood storage volume and annual streamflow volume and downward trends in the ratio of annual streamflow volume to potential flood storage volume. With the known addition of 7,193,147 acre-feet of potential flood storage between 1891 and 2014 in the subbasins analyzed, streamflow volumes have decreased in the upper sections of the Colorado River Basin. Within the Big Cypress Basin, results of precipitation trend analyses on annual, seasonal, and monthly time steps indicated almost no trends in the basin as defined in this report. However, the annual precipitation p -value only slightly exceeded the p -value threshold for a statistically significant trend. Given the upward trend in precipitation in the East Texas Climate Division, which includes the Big Cypress Basin, and the low p -value for annual precipitation within the basin, precipitation in the basin may be increasing over time. Two annual streamflow trends, one upward and one downward, were in the upper parts of the basin. Data from USGS streamflow-gaging station 07346000 Big Cypress Bayou near Jefferson, Texas, indicated an upward trend in annual minimum streamflow and a downward trend in annual peak streamflow. The station is immediately downstream from Lake O’ the Pines; presumably, minimums have increased because of regulated releases, and annual peaks have decreased because of storage from the lake for flood control. Despite the known addition of 2,737,154 acre-feet of potential flood storage between 1898 and 2011 in the subbasins analyzed, there have not been widespread reductions in streamflow volumes in the Big Cypress Basin, except for within the drainage area for the farthest upstream station on the main stem downstream from Mount Pleasant, Texas. Within the Guadalupe River Basin, results of precipitation trend analyses on an annual time step indicated an upward trend in the lower section of the basin, but no trends in annual streamflow were indicated in the lower section of the basin. In the upper section of the basin, data from 1 of the 13 stations indicated an upward trend in annual streamflow. Data from 6 of the 13 stations in the upper section of the basin indicated a trend in annual minimum streamflow with 4 upward and 2 downward trends. Data from 2 of the 13 stations in the upper section of the basin indicated downward trends in annual peak streamflow. Despite the known addition of 2,016,534 acre-feet of potential flood storage between 1849 and 2013 in the subbasins analyzed, streamflow volumes have not decreased in the Guadalupe River Basin. Within the Neches River Basin, results of precipitation trend analyses on an annual time step indicated upward trends in the basin. None of the data from stations analyzed in the Neches River Basin indicated annual trends in streamflow despite upward trends in annual precipitation within the basin. Data from 9 of the 19 stations analyzed in the basin indicated upward trends in annual minimum streamflow. Data from one of the simulated-inflow stations indicated a downward trend in annual minimum streamflow into Sam Rayburn Reservoir. Data from two stations indicated downward trends in annual peak streamflow, and data from one small subbasin indicated an upward trend in annual peak streamflow. Despite the known addition of 4,839,609 acre-feet of potential flood storage between 1888 and 2008 in the subbasins analyzed, there have not been widespread reductions in streamflow volumes in the Neches River Basin. Within the Sulphur River Basin, results of precipitation trend analyses on an annual time step indicated a moderate upward trend within the basin. Data from only one of the stations, the simulated inflow to Jim Chapman Lake, indicated an annual upward trend in streamflow despite an upward trend in annual precipitation throughout the basin. Data from three of the six stations in the Sulphur River Basin indicated upward trends in annual minimum streamflow, and data from one of the six stations indicated a downward trend in annual peak streamflow. Despite the known addition of 6,933,361 acre-feet of potential flood storage between 1904 and 2006 in the subbasins analyzed, streamflow volumes have not decreased in the Sulphur River Basin. Within the Trinity River Basin, results of precipitation trend analyses on an annual time step indicated upward trends in most sections of the basin. Data from 8 of the 36 stations analyzed for trends in annual streamflow indicated upward trends, and all 8 stations are in the upper sections of the basin. None of the data from stations in the lower sections of the basin indicated trends in annual streamflow. Data from 16 of the 36 stations indicated upward trends in annual minimum streamflow. Upward trends in annual minimum streamflow could be the result of managed reservoir releases in combination with wastewater treatment plant releases in the large Dallas-Fort Worth metroplex in the upper sections of the basin. All the trends in annual peak streamflow were in the sections of the basin that include the Dallas-Fort Worth metroplex. Data from two stations, one USGS streamflow-gaging station and one simulated-inflow station, indicated upward trends in annual peak streamflow, and data from one streamflow-gaging station indicated a downward trend in annual peak streamflow. Of the basins included in this study, the Trinity River Basin has the second largest amount of potential flood storage of 8,947,349 acre-feet from dams added between 1890 and 2013. Eleven stations in the Trinity River Basin had positive associations between potential flood storage volume and annual streamflow volume, indicating that annual streamflow increases as potential flood storage increases. Data from 7 of the 11 stations also indicated upward trends in annual streamflow. The positive associations may be the result of increases in minimum streamflow, which could be the result of any combination of managed reservoir releases, wastewater treatment plant releases, or increased runoff from urbanized areas, particularly in the urbanized area of the Dallas-Fort Worth metroplex.

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USGS2020

Origin and geochemistry of formation waters from the lower Eagle Ford Group, Gulf Coast Basin, south central Texas

The lower Eagle Ford Group (LEFG) is one of the most productive continuous hydrocarbon plays in the United States but few associated produced waters data and minimal interpretation have been published. This effort focuses on results from compositional and isotopic data from 39 produced water samples collected from horizontal wells producing from the LEFG in south central Texas. The depth of the LEFG increases by approximately 1 km across the study area, from northwest (2.9 km) to southeast (3.9 km). Associated increases in calculated reservoir temperature (125-165 C), development of reservoir over-pressuring (400-800 bars total pressure), and increased thermal maturity (heavy oil to gas condensate) also occur along this trend. Produced water salinity starts at nearly 100 g/L in the shallowest samples and decreases linearly with depth to <35 g/L. Comparison of Br/Cl and ⁸⁷Sr/⁸⁶Sr data between LEFG produced waters and the Louann salt, suggests that halite recycling is the mechanism behind salinity greater than seawater. Decreasing salinity with depth and thermal maturity in the Gulf Coast Basin have previously been shown to be a result of release of inter-layer water during smectite to illite conversion. The produced water samples show increasing 18O and decreasing 2H with depth, which is attributed temperature-dependent isotope fractionation of O and H exchange between seawater and clays and calcite with increasing temperature. Multiple sources of data indicate that the waters in the LEFG are not connate, but rather entered the unit prior to smectite-illite conversion. Presence of allochthonous water in many major tight oil and shale gas plays in the U.S., including the LEFG, suggests there is unknown mechanism allowing for water advection into low permeability reservoirs.

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USGS2020

Examination of inertinite within immature Eagle Ford Shale at the nanometer-scale using atomic force microscopy-based infrared spectroscopy

The nanoscale molecular composition of sedimentary organic matter is challenging to characterize in situ given the limited tools available that can adequately interrogate its complex chemical structure. This is a particularly relevant issue in source rocks, as kerogen composition will strongly impact its reactivity and so is critical to understanding petroleum generation processes during catagenesis. The recent advent of tip-enhanced analytical methods, such as atomic force microscopy-based infrared spectroscopy (AFM-IR), has allowed for the major compositional features of kerogen and other types of in situ organic matter to be elucidated at spatial resolutions at or below 50 nm. Here AFM-IR was applied to examine inertinite, an important organic matter type, present in a thermally immature Eagle Ford calcareous mudstone. The data show that the nanoscale molecular composition of the examined inertinite is (i) less heterogeneous than solid bitumen in more thermally mature Eagle Ford samples and (ii) more hydrogen- and oxygen-rich than inertinite examined in the New Albany Shale.

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