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Walter E. Dean

Publications and source records attributed to Walter E. Dean.

86 records · Page 5Linked to original sources

Carbonate and organic-carbon cycles and the history of upwelling at Deep Sea Drilling Project Site 532, Walvis Ridge, South Atlantic Ocean

Detailed carbonate and organic-carbon stratigraphies were constructed from samples collected every 20 cm in a 250-m hydraulic piston core recovered at DSDP Site 532 on Walvis Ridge. This sampling interval represents about one sample every 5000 yr., based on sediment accumulation rates calculated from nannofossil biostratigraphic zones. All samples were analyzed for percent CaCO 3 , resulting in a detailed carbonate stratigraphy for the past 5.0 m.y. The samples for the top 110 m of section were also analyzed for organic carbon in order to construct a detailed organiccarbon stratigraphy for the last 2.5 m.y. The recovered section has distinct dark-light color cycles with average periodicities of 55, 58, and 30 k.y. for the Quaternary, upper Pliocene, and lower Pliocene, respectively. Periodicities of carbonate cycles are similar to the color cycles; most carbonate minima correspond to the dark parts of color cycles. The average periodicity for carbonate cycles is about 36 k.y. Darker parts of color cycles usually contain higher concentrations of organic carbon, but the organic-carbon record does not follow the cyclicity of the color cycles in detail, at least for the last 2.5 m.y. Organic-carbon cycles have an average periodicity of about 34 k.y. for the Quaternary and upper Pliocene. The cycles of CaCO 3 and color have periodicities similar to those reported from carbonate stratigraphies from the northeast Atlantic, Caribbean, and eastern equatorial Pacific. The carbonate cycles at Site 532 are the result of external forcing, probably related to global climate, that affected fluctuations in both sediment supply from the African continental margin and productivity of siliceous organisms. The organic-carbon cycles have similar periodicities and similar changes in periodicities to those of the CaCO 3 cycles. Semiquantitative estimates of diatom abundance from smear slides and concentrations of biogenic SiO 2 calculated from chemical analyses suggest that upwelling at Site 532 was minor until about 3 m.y. ago. The Benguela-Current upwelling system either began at that time or, more likely, migrated into the area of Site 532, where it prevailed until some time between about 1.2 and 0.5 m.y. ago. The increase and decline of upwelling in the area of Site 532, however, did not disturb the trend of cyclicities of carbonate and organic carbon. The latest change in conditions at Site 532 was an increase in intensity of bottom currents during the past 0.5 m.y. that winnowed nannofossils, diatoms, and clay and left a lag deposit represented by a foraminifer-rich fades

Initial Reports of the D.S.D.P.

Geologic evolution of Hess Rise, central North Pacific Ocean

Cores from four Deep Sea Drilling Project (DSDP) sites (310, 464, 465, and 466) and seismic-reflection profiles provide data that are used to interpret the geological evolution and paleoenvironments of Hess Rise, a prominent oceanic plateau in the central North Pacific Ocean. Hess Rise apparently formed in the Southern Hemisphere along the western flank of the Pacific-Farallon Ridge 110 to 100 m.y. B.P. Core stratigraphies and lithologies show the response of sedimentation to subsidence and northward movement of Hess Rise on the Pacific plate. Oceanic islands, which crowned Hess Rise during its early evolution, were eroded and subsequently subsided below sea level. Major structural trends include three northwest-trending (∼327°) arms, or ridges, and an east-northeast-trending southern Hess Rise that parallels the Mendocino Fracture Zone (060°). Normal faults offset basement as much as 3,000 m along the southern edge and 1,500 m on the western flank of Hess Rise. Many faults were active during sedimentation. Tholeiitic basalt from the base of Hole 464, trachyte from the base of Hole 465A, and alkalic basalt clasts within sediment of Hole 466 show the diversity of rock types that constitute the igneous basement. A major rock unit is middle Cretaceous limestone, chalk, and minor chert that form the basal sedimentary unit. Some limestone samples, rich in organic carbon, reflect accumulation above the carbonate compensation depth (CCD) within a mid-water oxygen minimum zone. The organic-carbon-rich sediments probably were deposited on the submarine slopes of islands and banks that were at upper bathyal depths as Hess Rise crossed the wide equatorial divergence where increased upwelling and biogenic productivity contributed to high accumulation rates. The source of organic matter was mostly lipid-rich, autochthonous, marine organic matter. Analyses of sediment samples from across the Cretaceous-Tertiary boundary at Site 465 show that there was a significant decrease in surface water temperature and biological productivity. An abrupt increase in transition metals and iridium suggests that an outside source, perhaps extraterrestrial, was the cause for many of the sudden oceanographic, geochemical, and biological changes at the boundary.

GSA Bulletin

Continuous subaqueous deposition of the Permian Castile evaporites, Delaware Basin, Texas and New Mexico

Structures that are common in the Castile Formation (Ochoan) of the Delaware Basin, Texas and New Mexico (Fig. 1) include fine planar laminations, breccias, microfolded laminae, and nodular anhydrite. These structures, particularly the laminae, have been used to demonstrate the subaqueous depositional history of the Castile (Anderson and Kirkland, 1966; Anderson et al., 1972; Dean et al., 1975; Dean and Anderson, 1978). Kirkland and Anderson (1970) showed that the microfolds in the Castile are related to larger folds generated by tectonic compression. Breccia beds and chimneys and their relations to vertical and lateral salt dissolution in the Delaware Basin were discussed by Anderson et al. (1972), Anderson (1978), Anderson et al. (1978), and Anderson and Kirkland (1980). In this workshop we will describe and illustrate these structures and summarize how they have been used to understand the depositional and postdepositional history of a major evaporite deposit for which there is no modern analog.

New Mexico, Texas

Tertiary carbonate-dissolution cycles on the Sierra Leone Rise, eastern equatorial Atlantic Ocean

Most of the Tertiary section on Sierra Leone Rise off northwest Africa consists of chalk, marl, and limestone that show cyclic alterations of clay-rich and clay-poor beds about 20–60 cm thick. On the basis of biostratigraphic accumulation rates, the cycles in Oligocene and Miocene chalk have periods which average about 44,000 years, and those in Eocene siliceous limestone have periods of 4000–27,000 years. Several sections were sampled in detail to further define the cycles in terms of content of CaCO 3 , clay minerals, and relative abundances of calcareous nannofossils. Extending information gained by analyses of Pleistocene cores from the continental margin of northwest Africa to the Tertiary cycles on Sierra Leone Rise, both dilution by noncarbonate material and dissolution of CaCO 3 could have contributed to the observed relative variations in clay and CaCO 3 . However, dissolution of CaCO 3 as the main cause of the carbonate-clay cycles on the Sierra Leone Rise, rather than dilution by clay, is suggested by the large amount of change (several thousand percent) in terrigenous influx required to produce the observed variations in amount of clay and by the marked increase in abundance of dissolution-resistant discoasters relative to more easily dissolved coccoliths in low-carbonate parts of cycles. The main cause of dissolution of CaCO 3 was shoaling of the carbonate compensation depth (CCD) during the early Neogene and climatically induced fluctuations in the thickness of Antarctic Bottom Water.

Marine Geology

Origin of organic-carbon-rich mid-Cretaceous limestones, Mid-Pacific Mountains and southern Hess Rise

Limestones of mid-Cretaceous age containing as much as 8.6 percent organic carbon were cored at one site (463) in the Mid-Pacific Mountains and at two sites (465, 466) on southern Hess Rise, central North Pacific Ocean, during Leg 62 of the Deep Sea Drilling Project. In the Mid-Pacific Mountains, three layers containing more than 2% organic carbon are associated with volcanic ash in silicified limestone of early Aptian age (—112-113 m.y. old), a time when the site was south of the equator and considerably shallower than at present (2525 m). The beds of laminated, organiccarbon-rich limestone, implying deposition in an oxygen-deficient environment, are interbedded with normal pelagic limestones. This sequence lies on interbedded pelagic limestones and clastic limestones containing locally derived shallow-water carbonate debris, and it is overlain by interbedded green, gray, and pink limestones. The organic-carbonrich strata on southern Hess Rise are dark-olive, laminated limestones with rare interbeds of altered volcanic ash of the late Aptian to early Cenomanian ( — 98 to 103 m.y. old), a time when the site was passing under the equatorial highproductivity zone and subsiding from shallow to intermediate water depths. The organic-carbon-rich limestone sequence overlies volcanic basement (trachyte) in this part of Hess Rise. The association of volcanogenic sediments with organic-carbon-rich strata on Hess Rise is not as striking as in the Mid-Pacific Mountains, but the occurrences do suggest a coincidence of mid-plate volcanic activity and accumulation of organic matter at intermediate water depths in the tropical North Pacific Ocean during the mid-Cretaceous. Pyrolysis assays indicate that most of the organic matter in the limestone on Hess Rise is composed of lipid-rich kerogen derived from marine organisms. Limestones from the Mid-Pacific Mountains contain lower concentrations of organic matter. Pyrolysis assays and extractable hydrocarbons indicate that the organic matter in samples from Hole 463 is also predominantly of marine origin, and that contributions of terrigenous organic matter were probably minor. Analyses of stable carbon isotopes indicate that the organic carbon in all analyzed samples is isotopically light (δ13C 24 to - 29‰) relative to most modern marine organic carbon (δ13C - 9 to - 30%), and that the lightest carbon (δ13C 28 to - 29‰) is also the most lipid-rich. The organic-carbon-rich mid-Cretaceous limestones on Hess Rise, the Mid-Pacific Mountains, and other elevated plateaus and seamounts in the Pacific Ocean are approximately equivalent in age (mid-Cretaceous, -85-120 m.y.) to organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean and parts of the Indian Ocean. However, strata of equivalent age deposited in the Pacific Ocean at greater depths do not contain any carbon rich horizons. This observation, together with the evidence that the plateau sites were considerably shallower and close to the equator during the mid-Cretaceous, suggests that an expanded mid-water oxygen minimum, together with local restrictions in circulation, may have resulted in the preservation of organic matter in an oxygen-deficient environment where the oxygen minimum impinged on elevated platforms such as Hess Rise and the Mid-Pacific Mountains.

Initial reports of the Deep Sea Drilling Project

The geology of Hess Rise, central north Pacific Ocean

The geology of Hess Rise is interpreted from studies of morphology and structure, igneous petrology, sediment lithofacies, seismic stratigraphy, and paleoenvironments. Hess Rise probably formed at a triple junction, between 116 and 95 m.y. ago, in the equatorial zone of the southern hemisphere. A large archipelago, formed by volcanism, subsequently moved northward as part of the Pacific Plate and subsided. A Late Cretaceous-early Tertiary tectonic and(or) volcanic event created oceanic islands and probably influenced the normal subsidence rate. The lithofacies reflect both the northward movement under various surface water masses of differing productivity and the subsidence history, which influenced calcareous-sediment accumulation and dissolution. Hess Rise is informally divided into three physiographic or morphologic provinces: northern Hess Rise, the central platform, and southern Hess Rise. Southern Hess Rise is further subdivided into the northwestern ridge, Mellish Bank, and the eastern ridge. The structure of Hess Rise is dominated by normal faults which bound grabens and horsts. The west and south boundaries of the rise are fault scarps. Most faults trend about 345 ° on northern Hess Rise, 039° to 060° on southern Hess Rise. Igneous rocks are tholeiitic basalt on northern Hess Rise at Site 464, and trachyte at Site 465 on southern Hess Rise. The tholeiite probably is not a mid-ocean-ridge basalt; more likely it is a transitional basalt erupted during off-ridge volcanism. The trachyte at Site 465 was erupted either in shallow water or subaerially; it represents a late-stage differentiate of alkali-basalt magma. Geochemically, the trachyte is similar to late-stage eruptives on many oceanic islands. The alkali basalt clasts in Upper Cretaceous calcareous ooze at Site 466 probably record a Late Cretaceous-early Tertiary tectonic event that brought old crust above sea level, where it was eroded; alternatively, volcanism may have built the islands. Cores recovered from Holes 464, 310, 310A, 465,465A, and 466 (north to south) show three major lithofacies: limestone of mid-Cretaceous (Albian-Cenomanian) age, calcareous ooze and chalk of Late Cretaceous to Quaternary age, and pelagic clay that is Late Cretaceous to Quaternary in age at Site 464 and Eocene in age at Site 310. Minor lithofacies in the carbonates and pelagic clay include siliceous microfossils and chert. The limestone contains as much as 8.6% by weight of organic carbon. The organic-carbon-rich sediments apparently were deposited along the sides of Hess Rise, above the CCD and within a mid-water oxygen minimum, as the rise crossed the highly productive equatorial divergence. Surface sediments are influenced by present-day near-surface water-mass productivity and the depth of deposition. Above about 3000 meters calcareous ooze is deposited, and below about 4000 meters pelagic clay is dominant. Between 3000 meters and 4000 meters, greater clay contents correlate with increased water depth. The seismic stratigraphy interpreted from single-channel seismic-reflection records can be correlated with the lithofacies. Three major acoustic units apparently vary in age, composition, thickness, and geographic distribution. The lowest acoustic unit generally is acoustically opaque; it corresponds to volcanic basement. In places, however, the top parts of this unit may be well-lithified limestone or chert. The middle acoustic unit, in general strongly layered acoustically, is Albian and Cenomanian limestone, chalk, and chert on southern Hess Rise and Albian and Cenomanian chert, chalk, limestone, and clay stone on northern Hess Rise. The middle unit probably is Albian to at least lower Tertiary chalk, chert, and nannofossil ooze on the central platform. The upper acoustic unit is weakly stratified to acoustically transparent and corresponds to Upper Cretaceous to Recent nannofossil ooze on southern Hess Rise and to pelagic clay of the same age on northern Hess Rise. On the central platform, it probably corresponds to Eocene to Recent nannofossil ooze, marl, and pelagic clay

Initial Reports of the D.S.D.P.

The geologic history of the Mid-Pacific Mountains in the central North Pacific Ocean; A synthesis of deep-sea drilling studies

The Mid-Pacific Mountains constitute one of the largest aseismic rises in the central North Pacific Ocean. They have been generated by mid-plate volcanic events prior to Barremian time, but their volcanic activity continued through the remainder of the Cretaceous. Evidence of the latest stages of this volcanism are the trachytic ashes included in mid- and Late Cretaceous sediments and the presence of guyots atop the main volcanic pedestal. The thermal and volcanic history of the oldest part of the Pacific Plate and its plate tectonic movements since Cretaceous time have led to considerable horizontal and vertical movements of the Mid-Pacific Mountains. Reconstruction of their subsidence and evidence from the sediments from Site 463 suggest that they once, in Cretaceous time, constituted large, tropical volcanic islands which were covered by vegetation and which shed their erosional debris over the adjacent island slopes. Neritic fossils in Maastrichtian sediments document the presence of shoal areas until the end of the Mesozoic. Since then they have subsided to their present water depth. The horizontal movements of the Pacific Plate have carried the Mid-Pacific Mountains from a position well south of the Cretaceous equator to their present position under the unproductive surface waters of the subtropical central North Pacific Ocean. Site 463, on the western Mid-Pacific Mountains, probably crossed the equator in Maastrichtian time. Shallow-water-derived calcareous fossils are incorporated into the pelagic sediments covering the Mid-Pacific Mountains. They have been displaced from their source areas along the flanks of seamounts over the adjacent regions during times of low sea-level stands. Debris of land plants in Aptian sediments documents the presence of emergent volcanoes during that time. The pelagic sediments penetrated at Site 463 consist largely of a sequence of Cretaceous chalks, limestones, and cherts which accumulated fast and which document the presence of highly productive surface water masses around the former volcanic islands and above the shoals. The development of oxygen-deficient depositional environments and the lack of evidence for intensive reworking suggest at the same time very sluggish water movements in the meso- and bathypelagic environment during Early and mid-Cretaceous times. The Cenozoic calcareous oozes, on the other hand, are very condensed. They are interrupted in several places by hiatuses, and despite their position well above the CCD they show effects of dissolution and poor preservation of the calcareous faunas and floras. The frequency of reworked pelagic material together with the hiatuses indicate episodes of intensive renewal of the meso- and bathypelagic water masses which generated intensive sea-floor erosion and which were probably triggered by the climatic deterioration in the polar regions

Initial Reports of the D.S.D.P.

The heliothermic lake: a direct method of collecting and storing solar energy

Heliothermic lakes contain a sun-heated layer of warm, saline water beneath a surface layer of cooler, less saline water. The two layers are separated by a chemocline, a stratum in which salinity increases progressively with depth. The chemocline, the position of which varies from lake to lake, functions as a heat trap. Most sunlight that penetrates this stratum is transformed into heat, which cannot escape by radiation because water is opaque to infrared light, and which cannot escape by convection because the specific gravity of the dense water below the chemocline is not significantly decreased by the increasing temperature. Heat can escape only by conduction through the chemocline, and water or brine is a very poor conductor. As a result, the temperature within and commonly below the chemocline rises. Under ideal conditions of a clear solution, high isolation, and a suitable salinity distribution, the temperature of the chemocline will increase to the boiling point. The lower part of the chemocline in a shallow (0.8-m) manmade heliothermic lake at Sedom, Israel, for example, reached a temperature of 96°C (205°F) in spite of a brine with poor light transmissibility. About 30 natural heliothermic lakes have been reported. The best known, Lake Ursului, occurs in Transylvania, Romania (latitude, 46°35'N). During four consecutive summers, 1899 to 1902, this lake had temperatures of 60-70°C (140-158°F) at a depth of 1-2 m. Heliothermic conditions have persisted in this lake for at least 28 and probably for more than 77 years. The most unusual, Lake Vanda, Victoria Land, Antarctica (latitude, 77°35'S), has a temperature of 26°C near the base of the chemocline at a depth of 61 despite a mean atmospheric temperature of -20°C. Sunlight penetrates into the chemocline through 5 m of remarkably clear ice. Maintenance of the chemocline is the chief problem preventing commercial use of manmade heliothermic lakes for the collection and storage of solar energy. The most effective means of preserving this stratum from destruction by diffusion and wind mixing may be the use of salts, such as sodium sulfate and sodium borate, whose solubilities are markedly influenced by temperature. The chemoclines of ponds constructed with such salts, in theory, would persist indefinitely and could be of great size.

Open-File Report

Factors contributing to the formation of ferromanganese nodules in Oneida Lake, New York

Oneida Lake is a large, shallow, eutrophic lake situated in the Ontario lowlands of central New York State. It contains the most concentrated deposit of freshwater ferromanganese nodules (in terms of amount per unit area) yet reported in the literature. The mineralogy and bulk chemistry of these saucer-shaped nodules are similar to the mineralogy and bulk chemistry of deep-sea ferromanganese nodules, but the nodules in Oneida Lake contain considerably lower concentrations of trace metals, especially cobalt, nickel, and copper. Budgets for iron and manganese in waters from Oneida Lake and its tributaries indicate that approximately 122 t (metric tons) of iron and 23 t of manganese are lost each year from the lake waters, presumably by incorporation into sediments and ferromanganese nodules. Estimates based on nodule abundance and age of the lake suggest that iron and manganese are being incorporated into ferromanganese nodules at rates of 13 and 22 t/yr, respectively. Most iron lost from the lake waters is apparently incorporated into sediments, which contain an average of 10 times more iron than manganese. Most manganese lost from the lake waters is apparently incorporated into ferromanganese nodules, which contain an average of 1.7 times more manganese than iron. In Oneida Lake, very high rates of phytoplankton productivity, combined with almost continuous wind mixing to the bottom, provide high-pH and high-Eh conditions in most of the lake. Algae also provide an effective means of concentrating and transporting iron and manganese and thereby aid in the extensive development of ferromanganese nodule deposits.

New York